Title of Invention

"MONOLITHIC POLARIZATION CONTROLLED ANGLE DIFFUSERS AND A METHOD OF MANUFACTURING THE SAME"

Abstract A monolithic polarization controlled angle diffuser includes a system having a first surface and a second surface, a controlled angle diffuser pattern for providing an angular distribution at an illumination plane, the controlled angle diffuser pattern being on one of the first and second surfaces of the substrate, and a polarizing pattern on one of the first and second surfaces of the substrate. The controlled angle diffuser pattern includes at least two controlled angle diffuser elements. Each controlled angle diffuser element outputs different angular distributions. The polarizing pattern includes at least two polarizing elements. Each polarizing element corresponds to a respective controlled angle diffuser element. The at least two polarizing elements output polarizations are rotated with respect to one another.
Full Text MONOLITHIC POLARIZATION CONTROLLED ANGLE DIFFUSERS AND A
METHOD OF MANUFACTURING THE SAME
1. Field of the Invention
[0001 ] The present invention is related to a polarization controlled angle diffuser
and method of manufacturing such a polarization controlled angle diffuser. More
particularly, the present invention is related to a monolithic polarization controlled
angle diffuser and method of manufacturing such a polarization controlled angle
diffuser.
2. Description of Related Art
[0002] Diffusers use diffractive elements to control an angle of illumination in a
variety of systems, e.g., in a lithographic system. As a critical dimension in
micro-lithography continues to be reduced, the effect of polarization on imaging
performance in lithographic systems becomes more influential. If these effects are
not accounted for, the imaging enhancement expected from using a higher numerical
aperture (N.A.) lens system and/or immersion lithography may not be realized. If the
polarization state of illumination could be optimized while
controlling the angular distribution of the illumination, the adverse affects of the
polarization may be minimized.
SUMMARY OF THE INVENTION
[0003] It is therefore a feature of the present invention to provide a polarization
controlled angle diffuser and method of manufacturing such a polarization
controlled angle diffuser, which substantially overcomes one or more of the
problems noted above in connection with the related art.
[0004] It is a feature of the present invention to provide a polarization controlled
angle diffuser that is monolithic. As used herein, "monolithic" is to mean that the
elements of the controlled angle diffuser and the polarization control are each
provided on a continuous surface. Thus, while the monolithic polarization

controlled angle diffuser of the present invention may be realized on a single
surface, it is not to be so limited, and the controlled angle diffuser elements and
the polarization elements may be on different surfaces of a substrate or even on
different substrates.
[0005] It is another feature of the present invention to provide a polarization
controlled angle diffuser that maintains its efficiency.
[0006] It is yet another feature of the present invention to provide a polarization
controlled angle diffuser that minimizes zero drder light.
[0007] It is still another object of the present invention to provide a polarization
controlled angle diffuser that may readily be interchanged with current diffusers.
[0008] It is yet another object of the present invention to provide a polarization
controlled angle diffuser that may easily be manufactured.
[0009] At least one of the above and other features and advantages of the
present invention may be realized by providing a monolithic polarizing controlled
angle diffuser, including a system having at least two parallel, planar surfaces, a
controlled angle diffuser pattern for providing an angular distribution at an
illumination plane, the controlled angle diffuser pattern being on one of the at
least two parallel surfaces, the controlled angle diffuser pattern including at least
two controlled angle diffuser elements, each controlled diffuser element
outputting different angular distributions, and a polarizing pattern on one of the at
least two surfaces, the polarizing pattern including at least two polarizing
elements, the at least two polarizing elements outputting polarizations rotated
with respect to one another, each of the at least two polarizing elements
corresponding to a respective one of the at least two controlled angle diffuser
elements.
[0010] The system may include a substrate on which the polarizing pattern is
formed. At least one of the at least two polarizing elements may be featureless.

The polarizations of the at least two polarizing elements may be rotated by 90°
with respect to one another.
[0011] The polarizing pattern may have a subwavelength structure. The
polarizing pattern may have varied etch depths. The etch depth d may be
determined by the equation:
d=λ/2∆n
where A is a wavelength at which the diffuser is to be used and An is a
difference between refractive indices of the substrate for orthogonal polarization
states of the polarizing pattern. A period of the polarizing pattern may be
selected to maximize An.
[0012] The substrate on which the polarizing pattern is formed may be birfringent.
An etch depth may be determined in accordance with a difference between an
ordinary refractive index and an extraordinary refractive index of the substrate.
The period of the polarizing pattern may be selected to equal a size of one of the
at least two controlled angle diffuser elements.
[0013] The controlled angle diffuser elements may be diffractive elements. The
controlled angle diffuser elements may on the same substrate as the polarizing
elements, either on the same side of the substrate or on opposite sides of the
substrate. The controlled angle diffuser pattern may include an alternating array
of x dipoles and y dipoles.
[0014] At least one of the above and other features and advantages of the
present invention may be realized by providing a method of making a monolithic
polarizing controlled angle diffuser including creating a controlled angle diffuser
design having at least two controlled angle diffuser elements outputting different
angular distributions, creating a polarizing pattern having at least two polarizing
elements, the at least two polarizing elements outputting polarizations rotated
with respect to one another, transferring the controlled angle diffuser design to a
surface of a system having at least two surfaces, and transferring the polarizing

pattern to one of the at least two surfaces, each of the at least two polarizing elements
corresponding to a respective one of the at least two controlled angle diffuser elements.
[0015] The transferring the polarizing pattern may include etching a substrate of the
system to an etch depth d determined by the equation:
d=λ/2∆n
where λ is a wavelength at which the diffuser is to be used and An is a different
between refractive indices of the substrate for orthogonal polarization states of the
polarizing pattern. The period of the polarizing pattern may be selected to maximize An.
[0016] The transferring the polarizing pattern may include etching a birefringent
substrate to an etch depth determined in accordance with a difference between an
ordinary refractive index and an extraordinary refractive index of the birefringent
substrate. The period of the polarizing elements is selected to equal a size of one of the at
least two controlled angle diffuser elements.
[0017] The at least two surfaces may be on a single substrate. The polarizing elements
and the controlled angle diffuser elements may be on the same side or on opposite sides
of the substrate. The transferring of the polarizing pattern may occur before transferring
the controlled angle diffuser design.
BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS
[0018] The above and other features and advantages of the present invention will become
more apparent to those of ordinary skill in the art by describing in detail exemplary
embodiments thereof with reference to the attached drawings in which:
[0019] FIG. 1 illustrates a cross-sectional view of a model of a pattern in accordance with
an embodiment of the present invention;
[0020] FIG. 2 is a plot of duty cycle versus index of refraction for both polarizations and
both grating periods for the model of FIG. 1;

[0021] FIG. 3 illustrates a cross-sectional view of a half wave plate in accordance
with an embodiment of the present invention;
[0022] FIG. 4 illustrates a schematic cross-sectional view of a half-wave plate in
accordance with an embodiment of the present invention;
[0023] FIG. 5 illustrates a schematic top view of outputs of individual portions of
an example of a controlled angle diffuser pattern;
[0024] FIG. 6 illustrates an output of the controlled angle diffuser pattern of FIG. 5
in conjunction with a polarizing pattern of an embodiment of the present
invention; and
[0025] FIG. 7 illustrates a top view of the controlled angle diffuser pattern
providing the outputs of FIG. 5.
DETAILED DESCRIPTION OF THE INVENTION
[0026] The present invention will now be described more fully hereinafter with
reference to the accompanying drawings, in which exemplary embodiments of
the invention are shown. The invention may, however, be embodied in different
forms and should not be construed as limited to the embodiments set forth
herein. Rather, these embodiments are provided so that this disclosure will be
thorough and complete, and will fully convey the scope of the invention to those
skilled in the art. In the figures, the dimensions of layers and regions are
exaggerated for clarity of illustration. Like reference numerals refer to like
elements throughout.
[0027] In accordance with the present invention, the polarization of the diffuser is
controlled in accordance with an etch depth of the material. This polarization
control pattern may be on the same surface, on an opposite surface of the same
substrate or even on different surfaces as the controlled angle diffuser pattern.
The surfaces on which the controlled angle diffuser and the polarization pattern
are to be formed may be parallel and planar to one another. Examples of
appropriate controlled angle diffusers may be found in U.S. Patent No.

5,850,300, the entire contents of which are herein incorporated by reference for
all purposes. If the polarization control pattern is on an opposite side of a
substrate from the controlled angle diffuser pattern, then front to back alignment
will be needed.
[0028] The polarization control may be realized in two manners. First, if the
substrate is a non-birefringent material, e.g., fused silica, then a sub-wavelength
structure will be designed to change or rotate the polarization state. A model for
creating such a structure is shown in FIG. 1. The birefringent curves from this
structure are shown in FIG. 2. A structure for a half-wave plate created based on
this model is shown in FIG. 3.
[0029] In FIG. 1, the reflection of a diffractive pattern 10, here a binary pattern, in
a fused silica substrate 20 was modeled for both parallel and perpendicular
polarizations. A duty cycle of this pattern was varied from 0 to 100% at 1 %
increments for both polarizations. A period of this pattern was checked for 0.9
and 0.5 of the wavelength of interested in the substrate material. When the
wavelength of interest is in the deep ultraviolet (DUV), e.g., 193 nm, and fused
silica, have an index of refraction of about 1.56, is the substrate material, these
wavelengths are about 111 nm and 61 nm, respectively. As can be seen from
FIG. 2, the greatest birefringence occurs at about a 44% duty cycle using 111 nm
as the grating period. Thus, these parameters are selected for creating a half-
wave plate 30 shown in FIG. 3. The half-wave plate 30 includes a pattern 32 of
depth d, a period of 111 nm and a duty cycle of 44%. For the half-wave plate 30,
the depth d is set to be λ/(2∆n), where An is the difference in refractive indices
for the different polarization states. In fused silica, for the period of 111 nm, this
difference is 0.16.
[0030] If the material of the substrate is birefringent, e.g., crystal quartz or
calcium fluoride (CaF), such patterning is not needed. Instead, this material only
needs to be selectively etched for every other part to an appropriate depth to

realize the desired polarization rotation. No high resolution patterns are needed,
as with the sub-wavelength pattern of the first embodiment. An example of this is
shown in FIG. 4, in which a half-wave plate 40 includes etched portions 42 and
unetched portions 44 to provide the different rotations. Thus, the unetched
portions 44 may be featureless. While no pattern is required, the etch depth to
realize the desired rotations are typically an order of magnitude higher than for
the patterned approach, e.g., on the order of several microns. The etch depth is
determined in accordance with the refractive index difference between the
ordinary and extraordinary direction in the birefringent material.
[0031] As a specific example, polarized quadrupole illumination may be realized
in accordance with an embodiment of the present invention. First, a dipole
illuminator would be designed. Such a dipole illuminator may be designed using
a diffractive approach, as set forth in U.S. Patent No. 5,850,300. As shown in
FIG. 5, an output of each cell of an array of cells 50 includes a plurality of x
dipole illumination cells 52, which are oriented along the x-axis, and a plurality of
y dipole illumination cells 54, which are oriented along the y-axis. These x dipole
illumination cells 52 and y dipole illumination cells 54 are arranged in a two-
dimensional array of alternating x and y orientations.
[0032] If the substrate is not a birefringent material, and the input light is to be
polarized, then a polarizing pattern rotating the polarization may be provided for
every other illumination cell, i.e., all dipole illumination cells of the same
orientation. The polarizing pattern would be created using the design technique
of FIG. 3 and then transferred to a surface and aligned with the controlled angle
diffuser pattern. Of course, if the incoming light is not polarized, the polarizing
pattern may include a polarization element for each dipole illumination cell. If the
substrate is birefringent, every other illumination cell, i.e., all dipole illumination
cells of the same orientation, would have an etched portion as taught in
connection with FIG. 4:

[0033] The composite output of a substrate having this controlled angle diffuser
pattern therein would be a quadrupole 60 as shown in FIG. 6, without the arrows
indicating polarization orientation in the quadrupole 60. In the particular example
shown in FIG. 6, the polarization is rotated by 90° in the quadrupole 60. An x
dipole illumination 62 and a y dipole illumination 64 have orthogonal
polarizations, as indicated by the arrows therein.
[0034] An example of an actual mask 70 used to create the illumination shown in
FIGS. 5 and 6 is illustrated in FIG. 7. Here, the mask 70 includes a plurality of x
dipole illuminators 72, which are oriented along the x-axis, and a plurality of y
dipole illuminators 74, which are oriented along the y-axis. Each dipole
illuminator 72, 74 of this array would have the desired dimensions of the
conventional individual elements, e.g., about 2 mm.
[0035] The controlled angle diffuser pattern of the mask 70 may then be
transferred to a substrate, e.g., by lithography or replication, followed by etching.
The polarization pattern in accordance with either embodiment of the present
invention may be transferred to either the same or the opposite surface of the
substrate, e.g., by lithography or replication, followed by etching. Alternatively,
the transfer of the polarizing pattern may be transferred to another substrate.
These substrates may be secured together. This securing may occur on a wafer
level, after which the secured wafers may be vertically separated to form dies
including at least two controlled angle diffuser elements and at least two
polarizing elements. Each of the two controlled diffuser element outputs different
angular distributions. Each polarizing element corresponds to a respective
controlled angle diffuser element. Each of the two polarizing elements outputs
polarizations rotated with respect to one another.
[0036] Exemplary embodiments of the present invention have been disclosed
herein and, although specific terms are employed, they are used and are to be
interpreted in a generic and descriptive sense only and not for purpose of

limitation. For example, the polarizing pattern could be transferred to the
substrate before the controlled angle diffuser pattern. Accordingly, it will be
understood by those of ordinary skill in the art that various changes in form and
details may be made without departing from the spirit and scope of the present
invention as set forth in the following claims.

We claim:
1. A monolithic polarizing controlled angle diffuser, comprising:
a system having at least two parallel, continuous planar surfaces, at least one of the
at least two parallel, continuous planar surfaces being a surface of a substrate:
a controlled angle diffuser pattern for providing an angular distribution at an
illumination plane, the controlled angle diffuser pattern being on one of the at least
two parallel continuous surfaces, the controlled angle diffuser pattern including at
least two controlled angle diffuser elements integral with the one of the at least two
continuous surfaces, each controlled diffuser element outputting different angular
distributions, the at least two controlled angle diffuser elements defining a
monolithic controlled angle diffuser pattern; and
a polarizing pattern on the surface of the substrate, the polarizing pattern including
at least two polarizing elements, each polarizing element corresponding to a
respective controlled angle diffuser element, the at least two polarizing elements
outputting polarizations rotated with respect to one another, the at least two
polarizing elements defining a monolithic polarizing pattern.
2. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the polarizing pattern comprises a subwavelength structure.
3. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the polarizing pattern comprises varied etch depths.
4. The monolithic polarizing controlled angle diffuser as claimed in claim 2, wherein
an etch depth d is determined by the equation:
d=λ/2∆n

where A, is a wavelength at which the diffuser is to be used and ∆n is a difference
between refractive indices of the substrate for orthogonal polarization states of the
polarizing pattern.
5. The monolithic polarizing controlled angle diffuser as claimed in claim 4, wherein a
period of the polarizing pattern is selected to maximize ∆n.
6. The monolithic polarizing controlled angle diffuser as claimed in claim 3, wherein
an etch depth is determined in accordance with a difference between an ordinary
refractive index and an extraordinary refractive index of the substrate.
7. The monolithic polarizing controlled angle diffuser as claimed in claim 6, wherein a
period of the polarizing pattern is selected to equal a size of one of the at least two
controlled angle diffuser elements.
8. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
controlled angle diffuser elements are diffractive elements.
9. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the substrate is birefringent.
10. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the controlled angle diffuser elements are on the substrate.
11. The monolithic polarizing controlled angle diffuser as claimed in claim 10, wherein
the polarizing pattern and the controlled angle diffuser elements are on a same side
of the substrate.
12. The monolithic polarizing controlled angle diffuser as claimed in claim 10, wherein
the polarizing pattern and the controlled angle diffuser elements are on different
sides of the substrate.

13. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein at
least one of the at least two polarizing elements is featureless.
14. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the polarizations of the at least two polarizing elements are rotated by 90° with
respect to one another.
15. The monolithic polarizing controlled angle diffuser as claimed in claim 1, wherein
the controlled angle diffiiser pattern comprises an alternating array of x dipoles and
y dipoles.
16. A method of making a monolithic polarizing controlled angle diffuser comprising:
creating a controlled angle diffuser design having at least two controlled angle
diffuser elements outputting different angular distributions;
creating a polarizing pattern having at least two polarizing elements, the at least two
polarizing elements outputting polarizations rotated with respect to one another;
transferring the controlled angle diffuser design to a surface of a system having at
least two continuous surfaces, at least one of the at least two parallel, continuous
planar surfaces being a surface of a substrate, to form a controlled angle diffuser
pattern having at least two controlled angle diffuser elements integral with one of the
at least two continuous surfaces, the at least two controlled angle diffuser elements
defining a monolithic controlled angle diffuser pattern; and
transferring the polarizing pattern to the surface of the substrate each of the at least
two polarizing elements corresponding to a respective one of the at least two
controlled angle diffuser elements, the at least two controlled polarizing elements
defining a monolithic polarizing pattern.

17. The method as claimed in claim 16, wherein transferring the polarizing pattern
includes etching a substrate of the system to an etch depth d determined by the
equation:
d=λ/2∆n where λ is a wavelength at which the diffuser is to be used and ∆n is a
different between refractive indices of the substrate for orthogonal polarization
states of the polarizing pattern.
18. The method as claimed in claim 17, further comprising selecting a period of the
polarizing pattern to maximize ∆n.
19. The method as claimed in claim 16, wherein transferring the polarizing pattern
includes etching a birefringent substrate to an etch depth determined in accordance
with a difference between an ordinary refractive index and an extraordinary
refractive index of the birefringent substrate.
20. The method as claimed in claim 19, wherein a period of the polarizing elements is
selected to equal a size of one of the at least two controlled angle diffuser elements.
21. The method as claimed in claim 16, wherein the at least two surfaces are on a
substrate.
22. The method as claimed in claim 21, wherein the polarizing elements and the
controlled angle diffuser elements are on a same side of the substrate.
23. The method as claimed in claim 21, wherein the polarizing elements and the
controlled angle diffuser elements are on different sides of the substrate.
24. The method as claimed in claim 21, wherein transferring the polarizing pattern
occurs before transferring the controlled angle diffuser design.



MONOLITHIC POLARIZATION CONTROLLED ANGLE DIFFUSERS AND
METHODS OF MANUFACTURE OF THE SAME

ABSTRACT

A monolithic polarization controlled angle diffuser includes a system having a first
surface and a second surface, a controlled angle diffuser pattern for providing an angular
distribution at an illumination plane, the controlled angle diffuser pattern being on one of
the first and second surfaces of the substrate, and a polarizing pattern on one of the first and
second surfaces of the substrate. The controlled angle diffuser pattern includes at least two
controlled angle diffuser elements. Each controlled angle diffuser element outputs different
angular distributions. The polarizing pattern includes at least two polarizing elements. Each
polarizing element corresponds to a respective controlled angle diffuser element. The at
least two polarizing elements output polarizations are rotated with respect to one another.

Documents:

00925-kolnp-2007-correspondence-1.1.pdf

00925-kolnp-2007-correspondence-1.2.pdf

00925-kolnp-2007-form-1-1.1.pdf

00925-kolnp-2007-form-13.pdf

00925-kolnp-2007-form-3-1.1.pdf

00925-kolnp-2007-form-3-1.2.pdf

00925-kolnp-2007-form-5-1.1.pdf

00925-kolnp-2007-p.a.pdf

00925-kolnp-2007-priority document.pdf

0925-kolnp-2007 abstract.pdf

0925-kolnp-2007 claims.pdf

0925-kolnp-2007 correspondence others.pdf

0925-kolnp-2007 description(complete).pdf

0925-kolnp-2007 drawings.pdf

0925-kolnp-2007 form-1.pdf

0925-kolnp-2007 form-2.pdf

0925-kolnp-2007 form-3.pdf

0925-kolnp-2007 form-5.pdf

0925-kolnp-2007 international publication.pdf

0925-kolnp-2007 international search authority report.pdf

0925-kolnp-2007 pct other.pdf

0925-kolnp-2007 pct request form.pdf

925-KOLNP-2007-(25-01-2012)-ABSTRACT.pdf

925-KOLNP-2007-(25-01-2012)-CLAIMS.pdf

925-KOLNP-2007-(25-01-2012)-CORRESPONDENCE.pdf

925-KOLNP-2007-(25-01-2012)-DESCRIPTION (COMPLETE).pdf

925-KOLNP-2007-(25-01-2012)-DRAWINGS.pdf

925-KOLNP-2007-(25-01-2012)-FORM 1.pdf

925-KOLNP-2007-(25-01-2012)-FORM 13.pdf

925-KOLNP-2007-(25-01-2012)-FORM 2.pdf

925-KOLNP-2007-(25-01-2012)-FORM 5.pdf

925-KOLNP-2007-(25-01-2012)-OTHERS.pdf

925-KOLNP-2007-(25-01-2012)-PA.pdf

925-KOLNP-2007-ASSIGNMENT.pdf

925-KOLNP-2007-CORRESPONDENCE OTHERS 1.3.pdf

925-KOLNP-2007-CORRESPONDENCE.pdf

925-KOLNP-2007-EXAMINATION REPORT.pdf

925-KOLNP-2007-FORM 13 1.1.pdf

925-KOLNP-2007-FORM 13.pdf

925-KOLNP-2007-FORM 18 1.1.pdf

925-kolnp-2007-form 18.pdf

925-KOLNP-2007-FORM 3 1.3.pdf

925-KOLNP-2007-FORM 3-1.2.pdf

925-KOLNP-2007-FORM 3.pdf

925-KOLNP-2007-FORM 5.pdf

925-KOLNP-2007-GRANTED-ABSTRACT.pdf

925-KOLNP-2007-GRANTED-CLAIMS.pdf

925-KOLNP-2007-GRANTED-DESCRIPTION (COMPLETE).pdf

925-KOLNP-2007-GRANTED-DRAWINGS.pdf

925-KOLNP-2007-GRANTED-FORM 1.pdf

925-KOLNP-2007-GRANTED-FORM 2.pdf

925-KOLNP-2007-GRANTED-SPECIFICATION.pdf

925-KOLNP-2007-OTHERS 1.1.pdf

925-KOLNP-2007-OTHERS.pdf

925-KOLNP-2007-PA.pdf

925-KOLNP-2007-PRIORITY DOCUMENT.pdf

925-KOLNP-2007-REPLY TO EXAMINATION REPORT 1.1.pdf

925-KOLNP-2007-REPLY TO EXAMINATION REPORT.pdf

925-KOLNP-2007-TRANSLATED COPY OF PRIORITY DOCUMENT.pdf

abstract-00925-kolnp-2007.jpg


Patent Number 253309
Indian Patent Application Number 925/KOLNP/2007
PG Journal Number 28/2012
Publication Date 13-Jul-2012
Grant Date 11-Jul-2012
Date of Filing 15-Mar-2007
Name of Patentee DIGITAL OPTICS CORPORATION EAST
Applicant Address 9815 DAVID TAYLOR DRIVE, CHARLOTTE, NC 28262.
Inventors:
# Inventor's Name Inventor's Address
1 MARC D. HIMEL 18716 NAUTICAL DRIVE, UNIT 3, CORNELIUS, NC 28031.
2 ALAN D. KATHMAN 4700 LONE TREE LANE, CHARLOTTE, NC 28262
PCT International Classification Number G03F 7/20
PCT International Application Number PCT/US2005/030780
PCT International Filing date 2005-08-30
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/714,506 2004-08-31 U.S.A.