Title of Invention

A LOW CARBON WELDED TUBE AND PROCESS OF MANUFACTURE THEREOF

Abstract

The present invention relates to low carbon welded tubes and process of manufacture thereof. Manufacture of welded tubes utilising draw bench processes is energy intensive process due to the need of multiple pass (to enhance mechanical properties, in particular tensile and yield strength) to reduce the diameter of the hollow to desired dimensions as only 20 to 35% reduction achievable in a single pass. Further, there is substantial material loss with every pass and poor control on dimensional stability and surface finish of the tube. The present invention provides a synergistic combination of induction and /or resistance heat treatment of the hollow and the cold rolling process resulting in remarkable reduction in energy consumption, and at the same time enhancing quality of the resulting tubes with improved dimensional stability, closeness of tolerance, reduced thickness variation, concentricity and substantial reduction in material wastage.

Full Text

FORM - 2 THE PATENTS ACT, 1970 (39 OF 1970) PROVISIONAL SPECIFICATION (See Section 10) TITLE OF INVENTION "A Low Carbon Welded Tube, System and Process of Manufacture Thereof Arihant Domestic Appliances Limited Gat No 1261, Village Sanaswadi, Pune-Nagar Road, Taluka - Shirur, District - Pune , Pin-412208 The following specification particularly describes the nature of the invention Field of Invention The present invention relates to a low carbon welded tube and process of manufacture thereof. In particular, the invention relates to a cold rolled low carbon welded tube, system and process of manufacturing of the same. Background of the Invention Tubes are used in diverse applications such as automobile, boilers, textiles, construction, scaffolding, energy sector, hydraulic cylinders, gas springs etc. The tubes are either manufactured from carbon steel or using alloying elements. If the carbon percentage is in the range of 0.01 to 0.4, the tubes are conventionally known as low carbon steel tubes. There are two categories of tubes viz. seamless and welded. Seamless tubes are manufactured by the extruding the stock whereas welded tube is manufactured from the formed stripe that is welded at the seam. The seamless tubes are used for the critical applications wherein end applications demands stringent dimensional tolerances, surface finish and mechanical properties such as yield strength and tensile strength. The welded tube manufacturing processes generally comprise of steps that include √ stripe cutting according to the final tube size; √ forming of the stripe; √ Electric Resistance Welding (ERW) welding along the seam of the formed stripe to produce hollow; √ pointing operation wherein part of the tube is squeezed to provide holding margin / region for the draw bench gripper which is used to pull the tube through the draw bench. The squeezed portion which is left is a process waste; √ drawing process wherein the hollow is drawn through a draw bench to reduce the tube diameter to a desired level; √ straightening; S heat treatment to release stresses and √ surface treatment. Generally, a multiple passes are necessary to complete the operation thereby making the process highly energy intensive with generation of waste at every stage of the cycle. The reduction of tube diameter from the hollow (formed tube in welded condition) is necessary for achieving desired dimensions and enhancing mechanical properties such as yield, tensile, percentage elongation and hardness of the tube. The tensile and yield strength is proportional to the percentage reduction of the hollow to final tube diameter. Using draw bench, the reduction of the tube diameter is limited to 25% only in one pass. Generally the hollow used is of cross section that is 40% to 50 % more than that of the final drawn tube. This necessitates passing the tube for more than once, generally known as multiple pass through the draw bench to achieve desired dimensions and mechanical properties. It is to be underlined that for each of the pass through draw bench, it is necessary to heat treat the tube and provide pointing region which is of the order of 7% of the length of the tube. Thus for every pass there is a loss of 7% of the material is wasted and substantial energy is consumed for heat treatment. Further the processes of tube straightening and surface treatment is to be repeated. The use of draw bench also imposes limitation on the dimensional stability / maintaining closeness of tolerance. Therefore, the manufacture of tube for the critical / precision applications is limited using this process. It is well established fact that the seamless tubes are used and preferred for critical application and hence are expensive. Conventionally, welded tubes are not being preferred for critical / precision application due to the danger of cracking, weld opening, failure under pressure. Following are the details of the prior art search: United States Patent Application 20050076975 discloses a low carbon alloy steel tube and a method of manufacturing the same, in which the steel tube consists essentially of, by weight: about 0.06% to about 0.18% carbon; about 0.5% to about 1.5% manganese; about 0.1% to about 0.5% silicon; up to about 0.015% sulfur; up to about 0.025% phosphorous; up to about 0.50% nickel; about 0.1% to about 1.0% chromium; about 0.1% to about 1.0% molybdenum; about 0.01% to about 0.10% vanadium; about 0.01% to about 0.10% titanium; about 0.05% to about 0.35% copper; about 0.010% to about 0.050% aluminum; up to about 0.05% niobium; up to about 0.15% residual elements; and the balance iron and incidental impurities. The steel has a tensile strength of at least about 145 ksi and exhibits ductile behayior at temperatures as low as -60° C Japanese Patent JP3077576 discloses the welded tube manufactured by forming a strip steel containing 20°C/s, heating them to 600 to 700°C, then cooling them to the room temperature at 15kW (2) 0.4 Japanese Patent JP09164425 discloses the welded tube manufactured by forming a strip steej containing SO.05% C and 10 to 14% Cr, by weight, into a pipe shape, subjecting both butted edge parts whose temperature is between the room temperature and 1000°C, to laser beam welding by the following conditions (1) and (2), and are heated in between 850 and 1000°C, cooling them to 20°C/s, heating them to 600 to 700°C, then cooling them to the room temperature at15kW (2) 0.4 manufactured by heating the above-mentioned welded tube to 700-900°C, then cooling It to the room temperature at Japanese Patent JP11254030 discloses a stainless steel strip incorporating, by weight, 12.0-15.0% Cr, 1.0-5.0% Ni, Japanese Patent JP11343519 discloses a hot rolled steel plate, which has a composition, by weight, consisting of 10 min and then is subjected to a post heat treatment. At this time, the post heat treatment satisfies conditions shown in the formula: 2000xMo+T2 (20+logt2)>T1 (20+logt1) wherein T1 and t1 are a temp, and a time of annealing, T2, t2 are a temp, and a time of post heat treatment. Japanese Patent JP2000126896 discloses the method for manufacturing the low carbon martensitic stainless steel welded: tube by which a low carbon martensitic stainless steel strip is continuously formed into a tubular shape with plural roll-forming stands, and both edge parts to be butted of the formed tubular steel is heated and subjected to laser beam gelding, fin pass rolls for holding the interval between both these edge parts at a prescribed distance and squeeze side rolls for pressurizing and butting both these edge parts are provided and also a lifting-roll device 7 is arranged between the final fin pass roll 3a and the squeeze side rolls 6. The gap G in the height direction of both edges is measured and butt gelding is executed while adjusting the amount of lift with the lifting-roll device 7 based on the measured results. EP0217751 discloses a process is described for manufacturing steel tubes and steel pipes by electric welding of strips so formed to get a complete hollow bar, wherein the steel strip is pre-heated before forming. The pre-heating temperature is preferably near to the welding temperature and possibly, at the exit from a furnace which may be electric, e.g. of the induction type, a gas furnace or an oil furnace, etc. and before the forming unit there can be provided means capable of accomplishing an edge conditioner step. Japanese Patent JP10128413 discloses three mandrels 2 are respectively arranged in the insides of three tube stocks 1 which are arranged in parallel, three pairs of grooved rolls 5 are coaxially connected, each pair of grooved roils is arranged on the peripheral surface of each tube stock so that the inside face of the groove 6 of the roll is brought into contact with the outer peripheral surface of each tube stock and three tubes are simultaneously rolled. The mandrel 2 has a rolling part 3 whose diameter is gradually decreased in the rolling direction and the distance between the groove bottom and the center axis 7 of the roll of the grooved roll 5 is continuously changed in accordance with the change of the diameter of the rolling part. The groove shape and dimensions of the three sets of the grooved rolls 5 and mandrels 2 are set so that the distributions of their working ratios are mutually substantially same and, by the one set of combination, the rolled tube having the diameter dimension different from that of the rolled tubes which are rolled with the other sets of combinations is obtained. Japanese Patent JP58144455 discloses a roll material for Pilger rolling comprising 1.5W2.5% C, 0.2W 1.2% Si, 0.2W1.2% Mn, 0.5W2.0% Cr, 4W8% V and the remainder Fe and inevitable impure elements, capable of obtaining necessary hardness in the surface layer part thereof by proper heat treatment, rich in internal toughness, excellent in anti-wear property and having good grindability and long life is obtained. In the above mentioned composition, C permits to precipitate a large amount of carbide of V to impart anti-wear property to the roll material and strengthen the matrix of steel. V is contained in a degree generating no macro-segregation of V, and Cr is contained in a degree capable of affording proper tempering property. Japanese Patent JP2005060796 discloses the welded Steel tube having the composition composed by mass% of 0.02-0.2% C, 700°C rolling-finishing temperature and Japanese Patent JP3485980 discloses a clad steel tube is manufactured by achieving the cladding by welding of the corrosion resistant or heat resistant Ni-Cr-Mo alloy with a steel tube made of carbon steel, alloy steel, stainless steel, heat resistant steel or the like as the stock tube. The cold working or warm working of rolling, drawing, etc., of the clad steel tube is achieved, and the heat treatment is further achieved at the recrystallization temperature or at a higher temperature. Heating is made for the prescribed period of time at the temperature of >1100°C as the heat treatment of the solid solution of the Ni-Cr-Mo alloy at the outer circumferential part of the clad steel tube to realize the recrystallization. The heat treatment is achieved according to the material at the inner circumferential part of the clad steel tube to realize the recrystallization. Rolling and drawing is achieved not in the hot condition, but in the cold or warm condition because the high temperature strength of the base metal is different from that of the layer, cladded by welding, and the uniform working is not achieved in the hot condition and flaws are generated. Japanese Patent JP2001303196 discloses a hot rolled or jcoid rolled hoop stock, which has a composition consisting of 0.01-0.003% in a state of solid solution) of N and the balance Fe with inevitable impurities and containing, if necessary, at least one kind selected from 0.005-0.040% Nb, 0.005-0.50% Ti, 0.005-0.020% B, 0.02-1.5% Cu, 0.02-1.0% Ni, 0.02-1.0% Cr, 0.02-1.0% Mo, 0.0020-0.02% Ca and 0.0020-0.02% REM, is formed into cylindrical shape and the resultant seam is subjected to electric resistance welding, followed by sizing at 0.3-10% drawing rate of outer peripheral length. Japanese Patent JP2001303195 discloses a hot rolled or cold rolled hoop stock, which has a composition consisting of 0.01- Japanese Patent JP2001303192 discloses a hot rolled or cold rolled hoop stock, having a composition which consists of, by mass, 0.001-0.01% C, £1.0% Si, £2.0% Mn, £0.15% P, £0.015% S, 0.01-0.10% Al, 0.01-0.10% Nb, 0.001-0.010% B, either or both of £0.10% Ti and £0.10% Zr, and the balance Fe with inevitable impurities and contains, if necessary, either or both of 0.002-0.5% Mo and 0.02-1.0% Cr and in which C, Nb, Ti and Zr are contained in amounts within the range satisfying (12/48)(Ti(%)/C(%))+(12/93)(Nb(%)/C(%))+(12/91)(Zr(%)/C(%))>1.0, is formed into cylindrical shape and the resultant seam is subjected to electric resistance welding, followed by sizing at 0.3-10% drawing rate of outer peripheral length. Japanese Patent JP2618563 discloses a slab of a material steel which has a composition consisting of, by weight, 0.10-0.20% C, 0.15-0.50% Si, 1.3-2.5% Mn, 0.005-0.020% P, 0.0005-0.0060% S, 0.01-0.08% Al, 0.02-0.2% Ti, 0.0010-0.0030% B, 0.002-0.005% N, 0.3-0.7% Cr, 0.3-1.0% Mo, and the balance Fe with inevitable impurities and further containing, if necessary, 0.01-0.10% Nb is hot-rolled. The finishing temp, is regulated to a value between 950°C and the Ar transformation point, and coiling is 3 done at 450-700°C. The resulting hot rolled coil is formed into a jyjpel by means of resistance welding and then subjected, if necessary, to normalizing, annealing, and cold drawing. By this method, the resistance welded steel tube having a dimensional accuracy of £±0.15mm outside diameter and Japanese Patent JP08103867 discloses a clad steel tube is manufactured by achieving the cladding by welding of the corrosion resistant or heat resistant Ni-Cr-Mo alloy with a (steel tube made of carbon steel, alloy |tee(, stainless Steel, heat resistant steel or the like as the stock tube. The cold working or warm working of rolling, drawing, etc., of the clad |teel tube is achieved, and the heat treatment is further achieved at the recrystallization temperature or at a higher temperature. Heating is made for the prescribed period of time at the temperature of >1100°C as the heat treatment of the solid solution of the Ni-Cr-Mo alloy at the outer circumferential part of the clad jsteel Jube to realize the recrystallization. The heat treatment is achieved according to the material at the inner circumferential part of the clad steet tube to realize the recrystallization. Rolling and drawing is achieved not in the hot condition, but in the cold or warm condition because the high temperature strength of the base metal is different from that of the layer cladded by welding, and the uniform working is not achieved in the hot condition and flaws are generated Japanese Patent JP06010046 discloses a slab of a material Steel which has a composition consisting of, by weight, 0.10-0.20% C, 0.15-0.50% Si, 1.3-2.5% Mn, 0.005-0.020% P, 0.0005-0.0060% S, 0.01-0.08% Al, 0.02-0.2% Ti, 0.0010-0.0030% B, 0.002-0.005% N, 0.3-0.7% Cr, 0.3-1.0% Mo, and the balance Fe with inevitable impurities and further containing, if necessary, 0.01-0.10% Nb is hot-rolled. The finishing temp, is regulated to a value between 950°C and the Ar transformation point, and coiling is 3 done at 450-700°C. The resulting hot rolled coil is formed into a fube by means of resistance Welding' and then subjected, if necessary, to normalizing, annealing, and cold drawing. By this method, the resistance welded jsteel fube having a dimensional accuracy of Japanese Patent JP05287371 discloses in a resistance welded] steel tube having a componental compsn. obtd. by incorporating., by weight, 0.15 to 0.40% C, 0.05 to 0.50% Si, 2.0 to 3.0% Mn, 0.005 to 0.020% P, 0.0005 to 0.0060% S, 0.01 to 0.08% A!, 0.01 to 0.20%, Ti, 0.001 to 0.003% B, 0.002 to 0.0050% N, 0.1 to 1.0% Mo and 0.1 to 0.3% V with one or more kinds of 0.1 to 0.7% Cr and 0.01 to 0.20% Nb, and the balance Fe with inevitable impurities, after the tube making, normalizing is executed as heat treatment. If required, normalizing is furthermore executed in the process of cold: drawing and after the cold drawing. In this way, the objective resistance gelded steel tube having >l50kgf/mm2 tensile strength and >10% elongation can be obtd Japanese Patent JP04365815 discloses a steel having a composition consisting of, by weight, £0.01% C, 500°C coiling temp. The resulting hot rolled steel plate is cooled, formed into tubular state, and subjected to electric resistance welding. The resulting jsteel fuSe is heat-treated at 700-900°C and finished by means of cold reduction. By this method, the number of drawing times can be reduced by the increase in reduction of area per time at drawing and manufacturing costs can be remarkably reduced. Further, the extention of use can be expected by the increase in workability Japanese Patent JP01108346 discloses the |teet for electric welded $teel tube has a composition consisting of, by weight, 0.003W0.20% C, Japanese Patent JP3030602 discloses at the time of producing a resistance welded steel tube by using a hot-rolled coil sheet 1 with ribs, the gap of break down roll 3a of a forming line are made > (stock thickness + rib height + 2mm) and ≤4mm, and the reduction amount at a coil edge part at the time of resistance welding with fin pass rolls 4 is made > 0.1 x (stock thickness + rib height) and made >0.3%, 51.2% of the length of circumference of the outermost face of steel tube before reduction and then the resistance welded steel tube 10 is produced. Therefore, when forming, crushing of ribs and welding of mutual ribs are suppressed, the productivity is improved, the production cost is decreased, and further, the spectacle as the steel tube is improved. Japanese Patent JP2006136927 discloses a cold pilger rolling process, in the preventing method of the end crack by heating an end part of the tube stock before rolling, the end crack of a rolled stock is prevented by heating the end part of the tube stock before the pilger rolling. In a rolling with a cold pilger mill, in the heating device of the end part of the tube stock before rolling, the end part of the itube stock is heated by discharging the tube stock before the pilger rolling from a tube stock table with a kicker, placing it on a free roller after the kicker is lowered in a fixed state to a kicker stopper, advancing it by the dead weight and bringing the end part of the fube stock into close contact with a heating nozzle. Review of the prior art reveals that the low carbon (0.01 to 0.4%) welded tubes using cold rolling process are not reported in the prior art rather alloy steel tubes are being reported to the great extent. The use of welded tubes for precision application is also not reported. Further the draw bench process in the manufacture of welded tubes suffer from limitations such as: √ Need of multiple pass (to enhance mechanical properties, in particular tensile and yield strength) to reduce the diameter of the hollow to desired dimensions as the maximum reduction in single pass is only 20 to 25% √ Repetitions of number of processes such as heat treatment, pointing, surface treatment with each pass √ Substantial material loss in during each of the pass √ Substantial energy consumption in each of the process in each pass √ Poor control on dimensional stability of the tube √ Limitation on achieving surface finish of the tube The necessity is constantly felt to provide low carbon welded tube using cold roll process so as to achieve surface finish, closeness of tolerance and mechanical properties at par with the seamless tubes and provide process of manufacture of such tube. Summary of the Invention The main object of the invention is to provide a low carbon cold rolled welded tube. Another object of the invention is to provide a process of manufacture for low carbon welded tube. Yet another object of the invention is to achieve dimensional tolerances, surface finish and mechanical properties such as yield strength and tensile strength at par with the seamless tubes. Another object of the invention is to obviate the problems associated with draw bench process of manufacture. Yet another object of the invention is to obviate multiple passes during the tube manufacture. Another object of the invention is to provide heating process for the welded tube. Yet another object of the invention is to reduce cycle time for production of the welded tubes. Another object of the invention is to provide a system for cold rolling process. Yet another object of the invention is to provide rolls for the cold rolling process. Yet another object of the invention is to provide tube feeding mechanism for the cold rolling process. Thus in accordance with the invention, the process for manufacture of the welded tubes comprises steps of: √ stripe cutting according to the final tube size; √ forming of the stripe; √ electric resistance welding along the seam of the formed stripe to produce hollow wherein the coil in the proximity of the tube and welding rolls induces a magnetic field that is concentrated on the open seam by the impeder which is disposed inside the tube resulting a flow of electrons on the edges of the strip to generate heat along the seam to fusion temperature. The weld rolls then fuse the open seam to complete the welding process to produce hollow; √ heat treatment using induction means that comprises of AC power supply, induction coil wherein hollow is disposed in the said coil wherein the power supply sends alternating current through the coil resulting in generation of magnetic field that induces eddy currents in the hollow that results in heating the hollow uniformly √ optional surface treatment of the hollow; √ cold rolling process wherein the hollow is reciprocated under cam shaped profiled rolls wherein in the first step the tube is moved forward under the rolls. The profiles of the rolls are shaped so that on rotation they bite into the tube to force it down onto the mandrel wherein the mandrel is disposed inside the tube. The mandrel is then moved back to drag the tube against the rolls and smooth its outside diameter, the cycle is repeated wherein the low carbon cold rolled welded tube comprises of Carbon % in the range of 0.18 to 0.38, Mn % in the range of 0.41 to 1.33, Silicon % in the range of 0.01 to 0.25, Sulphur % in the range of 0.004 to 0.011, Phosphorous % in the range of 0.007 to 0.019, Aluminum % in the range of 0.025 to 0.05 and Niobium % in particular grades in the range of 0.01 to 0.03 wherein the said ranges cover the grades such as SAE 1020, SAE 1026, SAE 1541, SAE 1010, SAE 1012, SAE 1018, SAE 1006, SAE 1018, SAE 1527, SAE 1010 (modified), IS 1079 Gr.D, IS 7048 Gr.3, IS 7048 Gr.D, DIN 17100 St.52.3 In another aspect of the invention mandrel is provided with internal passages for lubricant that open at the mandrel and internal tube diameter interface to facilitate lubrication at the said surface. In yet another aspect of invention resistance heating is used in place of induction heat treatment process. Description of the Invention Features and advantages of the invention will become apparent in the following detailed description and preferred embodiments. The process for manufacture of the welded tubes comprises steps of: √ stripe cutting according to the final tube size; √ forming of the stripe; √ electric resistance welding along the seam of the formed stripe to produce hollow wherein the coil in the proximity of the tube and welding rolls induces a magnetic field that is concentrated on the open seam by the impeder which is disposed inside the tube resulting a flow of electrons on the edges of the strip to generate heat along the seam to fusion temperature. The weld rolls then fuse the open seam to complete the welding process to produce hollow; √ heat treatment using induction means that comprises of AC power supply, induction coil wherein hollow is disposed in the said coil wherein the power supply sends alternating current through the coil resulting in generation of magnetic field that induces eddy currents in the hollow that results in heating the hollow uniformly √ optional surface treatment of the hollow; √ cold rolling process wherein the hollow is reciprocated under cam shaped profiled rolls wherein in the first step the tube is moved forward under the rolls. The profiles of the rolls are shaped so that on rotation they bite into the tube to force it down onto the mandrel wherein the mandrel is disposed inside the tube. The mandrel is then moved back to drag the tube against the rolls and smooth its outside diameter, the cycle is repeated The low carbon cold rolled wefded tube comprises of Carbon % in the range of 0.18 to 0.38, Mn % in the range of 0.41 to 1.33, Silicon % in the range of 0.01 to 0.25, Sulphur % in the range of 0.004 to 0.011, Phosphorous % in the range of 0.007 to 0.019, Aluminum % in the range of 0.025 to 0.05 and Niobium % in particular grades in the range of 0.01 to 0.03 but not limited to it. The said ranges cover the grades such as SAE 1020, SAE 1026, SAE 1541, SAE 1010, SAE 1012, SAE 1018, SAE 1006, SAE 1018, SAE 1527, SAE 1010 (modified), IS 1079 Gr.D, IS 7048 Gr.3, IS 7048 Gr.D, DIN 17100 St.52.3 The welding of the rolled stripe at the seams is carried out by means of high frequency resistance welder that comprises of induction coil and impeder wherein induction coil induces the electrical current in the metal due to magnetic field generated by the induction coil resulting in generation of heat at the edges of strips and thus resulting in fusion of both the edges with each other wherein the composition of the weld is that of the parent material by virtue of the fusion of patent material itself. The welded tubes are induction annealed uniformly over the length of the tube such that the difference of hardness of the welded area / heat affected zone and parent material is substantially reduced resulting in substantial reduction of the welding related stresses. In one of the embodiments system is provided for forming the stripe and further welding the same so as to substantially reduced springing back tendency of the partially formed stripe. In another embodiment mandrel is provided with internal passages for lubricant that open at the mandrel and internal tube diameter interface to facilitate lubrication at the said surface. In another embodiment mandrel is provided with tapered profile. In another embodiment hollow is surface treated to facilitate lubrication at the inner diameter surface and mandrel during the process of cold rolling. In another embodiment a system is provided to control tube feed increment and rotational angle in tandem according to the size of the tube. In another embodiment driving system is provided to couple and coordinate process of rotation of the rolls and tube feeding. Thus it is evident from the present invention that the synergistic combination of induction and /or resistance heat treatment of the hollow and the cold rolling process results in obviating problems of multiple pass encountered during draw bench process leading to substantially reducing the energy consumption of the tube manufacture process, enhancing quality of the tubes by improving their dimensional stability, closeness of tolerance, reduced thickness variation, concentricity and substantial reduction in material wastage. Arihant Domestic Appliances Limited Date : 24/4/2009 Applicant,

Documents:

1092-MUM-2009--CLAIMS(AMENDED)-(9-4-2012).pdf

1092-MUM-2009--CORRESPONDENCE(9-4-2012).pdf

1092-MUM-2009-ABSTRACT(12-10-2009).pdf

1092-MUM-2009-CLAIMS(12-10-2009).pdf

1092-MUM-2009-CLAIMS(AMENDED)-(9-4-2012).pdf

1092-MUM-2009-CORRESPONDENCE(19-1-2012).pdf

1092-MUM-2009-CORRESPONDENCE(27-3-2012).pdf

1092-MUM-2009-CORRESPONDENCE(28-7-2011).pdf

1092-MUM-2009-CORRESPONDENCE(9-4-2012).pdf

1092-MUM-2009-CORRESPONDENCE(IPO)-(12-11-2009).pdf

1092-MUM-2009-CORRESPONDENCE-(27-3-2012).pdf

1092-MUM-2009-DESCRIPTION(COMPLETE)-(12-10-2009).pdf

1092-mum-2009-description(provisional).doc

1092-mum-2009-description(provisional).pdf

1092-MUM-2009-DRAWING(12-10-2009).pdf

1092-MUM-2009-FORM 1(12-10-2009).pdf

1092-MUM-2009-FORM 1(24-4-2009).pdf

1092-mum-2009-form 1.pdf

1092-MUM-2009-FORM 13(27-3-2012).pdf

1092-MUM-2009-FORM 18(12-10-2009).pdf

1092-MUM-2009-FORM 2(TITLE PAGE)-(12-10-2009).pdf

1092-MUM-2009-FORM 2(TITLE PAGE)-(PROVISIONAL)-(24-4-2009).pdf

1092-mum-2009-form 2(title page).pdf

1092-mum-2009-form 2.doc

1092-mum-2009-form 2.pdf

1092-MUM-2009-FORM 26(27-3-2012).pdf

1092-MUM-2009-FORM 3 (18-5-2012).pdf

1092-MUM-2009-FORM 3(12-10-2009).pdf

1092-MUM-2009-FORM 3(18-5-2012).pdf

1092-MUM-2009-FORM 3(19-1-2012).pdf

1092-MUM-2009-FORM 3(24-4-2009).pdf

1092-MUM-2009-FORM 3(27-3-2012).pdf

1092-MUM-2009-FORM 3(28-7-2011).pdf

1092-mum-2009-form 3.pdf

1092-MUM-2009-FORM 5(12-10-2009).pdf

1092-MUM-2009-FORM 9(12-10-2009).pdf

1092-MUM-2009-PCT-IPEA-409(19-1-2012).pdf

1092-MUM-2009-PCT-ISA-220 (19-1-2012).pdf

1092-MUM-2009-PCT-ISA-220(19-1-2012).pdf

1092-MUM-2009-PETITION UNDER RULE-137(18-5-2012).pdf

1092-MUM-2009-REPLY TO EXAMINATION REPORT(19-1-2012).pdf