Title of Invention

FUNGICIDAL MIXTURES

Abstract ABSTRACT FUNGICIDAL MIXTURES A fungicidal mixture, comprising (1) triticonazole of the formula I or salts or adducts with metal ions thereof; and (2) pyraclostrobin of the formula II and at least one acylalanine selected from the group consisting of (3) metalaxyl-M of the formula III and (4) kiralaxyl of the formula IV in a synergistically effective amount, wherein the weight ratio of triticonazole of the formula I to pyraclostrobin of the formula II and metalaxyl-M of the formula III or kiralaxyl of the formula IV is from 100 to 1 : 100 to 1 :100 to 1 and fungicidal compositions thereof.
Full Text Fungicidal mixtures
Description
5 The present invention relates to fungicidal mixtures comprising
(1) triticonazole of the formula I

or salts or adducts thereof
and
(2) pyraclostrobin of the formula II

and
(3) at least one acylalanine selected from the group consisting of metalaxyl-M of the
formula III


in a synergistically effective amount.
Moreover, the invention relates to a method for controlling harmful fungi using mixtures
of the compounds I to III, to the use of the compounds I to III for preparing such
mixtures and to compositions comprising these mixtures.
Triticonazole of the formula I is described in EP-A 0 378 953.
Pyraclostrobin of the formula II is known from EP-A 0 804 421.
Metalaxyl-M of the formula III is described in WO 96/01559.
Kiralaxyl of the formula IV is known from WO 00/76960.
Moreover, mixtures of triticonazole of the formula I with other fungicides are known
from WO 98/54969.
It is an object of the present invention, with a view to reducing the application rates and
broadening the activity spectrum of the known compounds I to IV, to provide mixtures
which, at a reduced total amount of active compounds applied, have improved activity
against harmful fungi (synergistic mixtures).


We have found that this object is achieved by the mixture of triticonazole,
pyraclostrobin and metalaxyl-M or kiralaxyl defined at the outset. Moreover, we have
found that simultaneous, that is joint or separate, application of the compounds I to III
or I, II and IV or successive application of the compounds I to III or I, II and IV allows
better control of harmful fungi than is possible with the individual compounds.



is described in WO 00/76960.
Owing to the basic character of its nitrogen atoms, the compound I is capable of
forming salts or adducts with inorganic or organic acids and with metal ions,
respectively.
Examples of inorganic acids are hydrohalic acids, such as hydrogen fluoride, hydrogen
chloride, hydrogen bromide and hydrogen iodide, sulfuric acid, phosphoric acid and
nitric acid.
Suitable organic acids are, for example, formic acid, carbonic acid, and alkanoic acids,
such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also
glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid,
cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids having straight-chain or
branched alkyl radicals of 1 to 20 carbon atoms), arylsulfonic acids or aryldisulfonic
acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two sulfonic
acid groups), alkylphosphonic acids (phosphonic acids having straight-chain or
branched alkyl radicals of 1 to 20 carbon atoms), arylphosphonic acids or
aryldiphosphonic acids (aromatic radicals, such as phenyl and naphthyl, which carry
one or two phosphoric acid groups), where the alkyl or aryl radicals may carry further
substituents, for example p-toluenesulfonic acid, salicylic acid, p-aminosalicylic acid, 2-
phenoxybenzoic acid, 2-acetoxybenzoic acid, etc.
Suitable metal ions are in particular the ions of the elements of the second main group,
in particular calcium and magnesium, of the third and fourth main group, in particular
aluminum, tin and lead and also of the elements of transition groups one to eight, in
particular chromium, manganese, iron, cobalt, nickel, copper, zinc, and others.
Particular preference is given to the metal ions of the elements of transition groups of
the fourth period. The metals can be present in the various valencies that they can
assume.

In many crops, dressing with fungicides delays or reduces emergence and results in a
poorer establishment of the stand when the cultivation is started.
The mixtures of the compounds I to III or I, II and IV, or the simultaneous, that is joint or
separate, use of one of the compounds I to IV, are/is distinguished in that these
negative effects on the plants which, depending on the dosage, may also occur with
triticonazole or pyraclostrobin, both when applied on their own and when applied as the
2-component mixture with III or IV, do not occur, or are not as pronounced. In addition,
the mixtures have excellent activity against a broad spectrum of phytopathogenic fungi,
in particular from the classes of the Ascomycetes, Basidiomycetes, Deuteromycetes
and Peronosporomycetes (syn. Oomycetes). Some of them are systemically active and
can be used in crop protection as foliar fungicides, as fungicides for seed dressing and
as soil fungicides.
They are particularly important for controlling a multitude of fungi on various cultivated
plants, such as bananas, cotton, vegetable species (for example cucumbers, beans,
tomatoes and cucurbits), barley, grass, oats, coffee, potatoes, corn, fruit species, rice,
rye, soybeans, grapevines, wheat, ornamental plants, sugar cane and also on a large
number of seeds.
They are especially suitable for controlling the following plant diseases:
- Altemaria species on vegetables, rapeseed, sugar beet and fruit and rice,
- Aphanomyces species on sugar beet and vegetables,
- Bipolaris and Drechslera species on corn, cereals, rice and lawns,
- Blumeria graminis (powdery mildew) on cereals,
- Botrytis cinerea (gray mold) on strawberries, vegetables, flowers and grapevines,
- Bremia lactucae on lettuce,
- Cercospora species on corn, soybeans, rice and sugar beet,
- Cochliobolus species on com, cereals, rice (e.g., Cochliobolus sativus on cereals,
Cochliobolus miyabeanus on rice),
- Colletotricum species on soybeans and cotton,
- Drechslera species on cereals and corn,
- Exserohilum species on corn,
- Erysiphe cichoracearum and Sphaerotheca fuliginea on cucurbits,
- Fusarium and Verticillium species on various plants,
- Gaeumanomyces graminis on cereals,
- Gibberella species on cereals and rice (e.g., Gibberella fujikuroi on rice),
- Grain staining complex on rice,
- Helminthosporium species on corn and rice,
- Michrodochium nivale on cereals,
- Mycosphaerella species on cereals, bananas and peanuts,
- Phakopsara pachyrhizi and Phakopsara meibomiae on soybeans,

- Phomopsis species on soybeans and sunflowers,
- Phytophthora infestans on potatoes and tomatoes,
- Plasmopara viticola on grapevines,
- Podosphaera leucotricha on apples,
- Pseudocercosporella herpotrichoides on cereals,
- Pseudoperonospora species on hops and cucurbits,
- Puccinia species on cereals and corn,
- Pyrenophora species on cereals,
- Pyricularia oryzae, Corticium sasakii, Sarocladium oryzae, S. attenuatum, Entyloma
oryzae on rice,
- Pyricularia grisea on lawns and cereals,
- Pythium spp. on lawns, rice, corn, cotton, rapeseed, sunflowers, sugar beet,
vegetables and other plants,
- Rhizoctonia species on cotton, rice, potatoes, lawns, corn, rapeseed, potatoes,
sugar beet, vegetables and other plants,
- Sclerotinia species on rapeseed and sunflowers,
- Septoria tritici and Stagonospora nodorum on wheat,
- Erysiphe (syn. Uncinula) necator on grapevines,
- Setospaeria species on corn and lawns,
- Sphacelotheca reilinia on corn,
- Thievaliopsis species on soybeans and cotton,
- Tilletia species on cereals,
- Ustilago species on cereals, corn and sugar beet, and
- Venturia species (scab) on apples and pears.
The mixtures according to the invention are also suitable for controlling harmful fungi
such as Paecilomyces variotii in the protection of materials (for example wood, paper,
paint dispersions, fibers or fabrics) and in the protection of stored products.
The compounds I to III or I, II and IV can be applied simultaneously, that is jointly or
separately, or in succession, the sequence, in the case of separate application,
generally not having any effect on the result of the control measures.
When preparing the mixtures, it is preferred to employ the pure active compounds I to
III or I, II and IV, to which further active compounds against harmful fungi or against
other pests, such as insects, arachnids or nematodes, or else herbicidal or growth-
regulating active compounds or fertilizers can be added according to need.
Usually, mixtures of the compounds I to III or I, II and IV are employed. However, in
certain cases mixtures of the compounds I to III or I, II and IV with, if appropriate, a
plurality of active components may be advantageous, such as, for example, mixtures of

the compounds I to III with the compound IV or further fungicides or mixtures of the
compounds I, II and IV with further fungicides.
The mixing ratio (weight ratio) of the compounds I, II and III or IV is chosen such that a
synergistic fungicidal action occurs, for example compound I: compound II: compound
III or compound IV such as 100 to 1 : 100 to 1 : 100 to 1, in particular 10 to 1 : 10 to 1 :
10 to 1, for example 5 to 1 : 5 to 1 : 5 to 1, in particular 3 to 1 : 3 to 1 : 3 to 1, preferably
2 to 1 : 2 to 1 : 2 to 1. The mixing ratio includes, for example, the mixtures I: II: III or IV
such as 100 : 1 : 1 to 1 : 100 : 1 to 1 : 1 : 100. The synergistic action of the mixture
manifests itself in that the fungicidal action of the mixture I + II + III or IV is greater than
the sum of the fungicidal actions of I and of II and of III or IV.
The further active components are, if desired, added in a ratio of from 20:1 to 1:20 to
the compounds I to III or I, II and IV.
Depending on the type of compound and the desired effect, the application rates of the
mixtures according to the invention are, especially in the case of areas under
agricultural cultivation, from 5 g/ha to 2000 g/ha, preferably from 20 to 900 g/ha, in
particular from 50 to 750 g/ha.
Correspondingly, the application rates for the compound I are generally from 1 to 1000
g/ha, preferably from 10 to 900 g/ha, in particular from 20 to 750 g/ha.
Correspondingly, the application rates for the active compound II are generally from 1
to 1000 g/ha, preferably from 10 to 900 g/ha, in particular from 40 to 750 g/ha.
Correspondingly, the application rates for the active compound III or IV are generally
from 1 to 1000 g/ha, preferably from 10 to 900 g/ha, in particular from 40 to 750 g/ha.
In the treatment of seed, application rates of mixture are generally from 1 to
1000 g/100 kg of seed, preferably from 1 to 750 g/100 kg, in particular from 5 to
500g/100kg.
The method for controlling harmful fungi is carried out by the separate or joint
application of the compounds I to III or I, II and IV or a mixture of the compounds I to III
or I, II and IV by spraying or dusting the seeds, the plants or the soil before or after
sowing of the plants or before or after emergence of the plants.
The mixtures according to the invention, or the compounds I to III or I, II and IV can be
converted into the customary formulations, for example solutions, emulsions,
suspensions, dusts, powders, pastes and granules. The use form depends on the

particular intended purpose; in each case, it should ensure a fine and even distribution
of the compound according to the invention.
The formulations are prepared in a known manner, for example by extending the active
compound with solvents and/or carriers, if desired using emulsifiers and dispersants.
Solvents/auxiliaries suitable for this purpose are essentially:
- water, aromatic solvents (for example Solvesso products, xylene), paraffins (for
example mineral oil fractions), alcohols (for example methanol, butanol, pentanol,
benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone),
pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, fatty acid
dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures may
also be used,
carriers such as ground natural minerals (for example kaolins, clays, talc, chalk)
and ground synthetic minerals (for example highly disperse silica, silicates);
emulsifiers such as nonionogenic and anionic emulsifiers (for example
polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and
dispersants such as lignosulfite waste liquors and methylcellulose.
Suitable for use as surfactants are alkali metal, alkaline earth metal and ammonium
salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid,
dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty
alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore
condensates of sulfonated naphthalene and naphthalene derivatives with
formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol
and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol,
octylphenol, nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether,
tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol
ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers,
ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters,
lignosulfite waste liquors and methylcellulose.
Substances which are suitable for the preparation of directly sprayable solutions,
emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling
point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or
animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene,
paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol,
ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, highly polar
solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water.
Powders, materials for spreading and dustable products can be prepared by mixing or
concomitantly grinding the active substances with a solid carrier.

Granules, for example coated granules, impregnated granules and homogeneous
granules, can be prepared by binding the active compounds to solid carriers. Examples
of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay,
limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate,
magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as,
for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and
products of vegetable origin, such as cereal meal, tree bark meal, wood meal and
nutshell meal, cellulose powders and other solid carriers.
In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1
to 90% by weight, of the active compounds. The active compounds are employed in a
purity of from 90% to 100%, preferably 95% to 100% (according to NMR spectrum).
The following are examples of formulations: 1. Products for dilution with water
A) Water-soluble concentrates (SL)
10 parts by weight of a compound according to the invention are dissolved in 90 parts
by weight of water or of a water-soluble solvent. As an alternative, wetting agents or
other auxiliaries are added. The active compound dissolves upon dilution with water.
This gives a formulation having an active compound content of 10% by weight.
B) Dispersible concentrates (DC)
20 parts by weight of a compound according to the invention are dissolved in 70 parts
by weight of cyclohexanone with addition of 10 parts by weight of dispersant, for
example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active
compound content is 20% by weight.
C) Emulsifiable concentrates (EC)
15 parts by weight of a compound according to the invention are dissolved in 75 parts
by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil
ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The
formulation has an active compound content of 15% by weight.
D) Emulsions (EW, EO)
25 parts by weight of a compound according to the invention are dissolved in 35 parts
by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil
ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by
weight of water by means of an emulsifying machine (e.g. Ultraturrax) and made into a
homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an
active compound content of 25% by weight.

E) Suspensions (SC, OD)
In an agitated ball mill, 20 parts by weight of a compound according to the invention are
comminuted with addition of 10 parts by weight of dispersants and wetting agents and
70 parts by weight of water or an organic solvent to give a fine active compound
suspension. Dilution with water gives a stable suspension of the active compound. The
active compound content in the formulation is 20% by weight.
F) Water-dispersible granules and water-soluble granules (WG, SG)
50 parts by weight of a compound according to the invention are ground finely with
addition of 50 parts by weight of dispersants and wetting agents and prepared as
water-dispersible or water-soluble granules by means of technical appliances (for
example extrusion, spray tower, fluidized bed). Dilution with water gives a stable
dispersion or solution of the active compound. The formulation has an active
compound content of 50% by weight.
G) Water-dispersible powders and water-soluble powders (WP, SP)
75 parts by weight of a compound according to the invention are ground in a rotor-
stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica
gel. Dilution with water gives a stable dispersion or solution of the active compound.
The active compound content of the formulation is 75% by weight.
2. Products to be applied undiluted
H) Dustable powders (DP)
5 parts by weight of a compound according to the invention are ground finely and
mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable
product having an active compound content of 5% by weight.
J) Granules (GR, FG, GG, MG)
0.5 part by weight of a compound according to the invention is ground finely and
associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-
drying or the fluidized bed. This gives granules to be applied undiluted having an active
compound content of 0.5% by weight.
K) ULV solutions (UL)
10 parts by weight of a compound according to the invention are dissolved in 90 parts
by weight of an organic solvent, for example xylene. This gives a product to be applied
undiluted having an active compound content of 10% by weight.
The active compounds can be used as such, in the form of their formulations or the use
forms prepared therefrom, for example in the form of directly sprayable solutions,
powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable

products, materials for spreading, or granules, by means of spraying, atomizing,
dusting, spreading or pouring. The use forms depend entirely on the intended
purposes; they are intended to ensure in each case the finest possible distribution of
the active compounds according to the invention.
Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable
powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions,
pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can
be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier.
However, it is also possible to prepare concentrates composed of active substance,
wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such
concentrates are suitable for dilution with water.
The active compound concentrations in the ready-to-use preparations can be varied
within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from
0.01 to1%.
The active compounds may also be used successfully in the ultra-iow-volume process
(ULV), it being possible thereby to apply formulations comprising over 95% by weight
of active compound, or even to apply the active compound without additives.
Oils of various types, wetters, adjuvants may be added to the active compounds, even,
if appropriate, not until immediately prior to use (tank mix). These agents are typically
admixed with the compositions according to the invention in a weight ratio of from
1:100 to 100:1, preferably from 1:10 to 10:1.
The compounds I to III or I, II and IV or the mixtures or the corresponding formulations
are applied by treating the harmful fungi, the plants, seeds, soils, areas, materials or
spaces to be kept free from them with a fungicidally effective amount of the mixture or,
in the case of separate application, with the compounds I to III or I, II and IV.
Application can be carried out before or after infection by the harmful fungi.
The fungicidal effect of the individual compounds and the mixtures according to the
invention was demonstrated by the following tests:
The active compounds were prepared separately or jointly as a stock solution with
25 mg of active compound which was made up to 10 ml using a mixture of acetone
and/or DMSO and the emulsifier Uniperol® EL (wetting agent having emulsifying and
dispersing action based on ethoxylated alkylphenols) in a volume ratio of
solvent/emulsifier of 99 to 1. The mixture was then made up with water to 100 ml. This
stock solution was diluted with the solvent/emulsifier/water mixture described to the
concentration of active compounds stated below.

The visually determined percentages of infected leaf areas were converted into
efficacies in % of the untreated control:
The efficacy (E) is calculated as follows using Abbot's formula:
E = (1-α/)-100
a corresponds to the fungicidal infection of the treated plants in % and
3 corresponds to the fungicidal infection of the untreated (control) plants in %
An efficacy of 0 means that the infection level of the treated plants corresponds to that
of the untreated control plants; an efficacy of 100 means that the treated plants were
not infected.
The expected efficacies of mixtures of active compounds were determined using
Colby's formula (Colby, S.R. "Calculating synergistic and antagonistic responses of
herbicide combinations", Weeds, 15, pp. 20-22, 1967) and compared with the observed
efficacies.
Colby's formula:
E = x + y-xy/100
E expected efficacy, expressed in % of the untreated control, when using the
mixture of the active compounds A and B at the concentrations a and b
x efficacy, expressed in % of the untreated control, when using the active
compound A at the concentration a
y efficacy, expressed in % of the untreated control, when using the active
compound B at the concentration b
Use example
Seed treatment of Bentgrass
Seeds of bentgrass were seed-treated with the products and concentrations listed.
Triticonazol and Pyraclstrobin were used as 200g/l FS-formulation. Metalaxyl-M als a 17.7
% LS-formulation.
Treated seeds were planted at the day of treatment and then kept under humid conditions
in the greenhouse. 7 days after plating the ground coverage by emerged plants were
estimated in percentage.


The data show that the negative effect of the mixture of TTZ and Pyraclostrobin can be
over compensated by Metalaxyl-M.
We claim:
1. A fungicidal mixture, comprising
5 (1) triticonazole of the formula I

or salts or adducts with metal ions thereof;
10 and
(2) pyraclostrobin of the formula II
15
and at least one acylalanine selected from the group consisting of
(3) metalaxyl-M of the formula III
20
and

(4) kiralaxyl of the formula IV

5 in a synergistically effective amount, wherein the weight ratio of triticonazole of the
formula I to pyraclostrobin of the formula II and metalaxyl-M of the formula III or
kiralaxyl of the formula IV is from 100 to 1 : 100 to 1 : 100 to 1.
2. The mixture of claim 1, wherein the weight ratio of triticonazole of the formula I to
10 pyraclostrobin of the formula II and metalaxyl-M of the formula III or kiralaxyl of
the formula IV is from 10 to 1 : 10 to 1 : 10 to 1.
3. A fungicidal composition, comprising the fungicidal mixture according to claim 1
and a solid or liquid carrier.
15
20
25
ABSTRACT
FUNGICIDAL MIXTURES
A fungicidal mixture, comprising
(1) triticonazole of the formula I

or salts or adducts with metal ions thereof;
and
(2) pyraclostrobin of the formula II

and at least one acylalanine selected from the group consisting of
(3) metalaxyl-M of the formula III


and
(4) kiralaxyl of the formula IV

in a synergistically effective amount, wherein the weight ratio of triticonazole of the
formula I to pyraclostrobin of the formula II and metalaxyl-M of the formula III or
kiralaxyl of the formula IV is from 100 to 1 : 100 to 1 :100 to 1 and fungicidal
compositions thereof.

Documents:

01740-kolnp-2008-claims.pdf

01740-kolnp-2008-correspondence others.pdf

01740-kolnp-2008-description complete.pdf

01740-kolnp-2008-form 1.pdf

01740-kolnp-2008-form 3.pdf

01740-kolnp-2008-form 5.pdf

01740-kolnp-2008-international exm report.pdf

01740-kolnp-2008-pct priority document notification.pdf

01740-kolnp-2008-pct request form.pdf

1740-KOLNP-2008-(25-08-2011)-ABSTRACT.pdf

1740-KOLNP-2008-(25-08-2011)-AMANDED CLAIMS.pdf

1740-KOLNP-2008-(25-08-2011)-CERTIFIED COPIES(OTHER COUNTRIES).pdf

1740-KOLNP-2008-(25-08-2011)-DESCRIPTION (COMPLETE).pdf

1740-KOLNP-2008-(25-08-2011)-EXAMINATION REPORT REPLY RECIEVED.pdf

1740-KOLNP-2008-(25-08-2011)-FORM 1.pdf

1740-KOLNP-2008-(25-08-2011)-FORM 2.pdf

1740-KOLNP-2008-(25-08-2011)-OTHERS PATENT DOCUMENTS.pdf

1740-KOLNP-2008-(25-08-2011)-OTHERS.pdf

1740-KOLNP-2008-(25-08-2011)-PA.pdf

1740-KOLNP-2008-ASSIGNMENT.pdf

1740-KOLNP-2008-CLAIMS 1.1.pdf

1740-KOLNP-2008-CORRESPONDENCE 1.1.pdf

1740-KOLNP-2008-CORRESPONDENCE 1.2.pdf

1740-KOLNP-2008-FORM 13.pdf

1740-kolnp-2008-form 18.pdf

1740-KOLNP-2008-FORM 3.1.pdf

1740-KOLNP-2008-GPA.pdf


Patent Number 252748
Indian Patent Application Number 1740/KOLNP/2008
PG Journal Number 22/2012
Publication Date 01-Jun-2012
Grant Date 29-May-2012
Date of Filing 30-Apr-2008
Name of Patentee BASF SE
Applicant Address 67056 LUDWIGSHAFEN
Inventors:
# Inventor's Name Inventor's Address
1 YPEMA HENDRIK 111 MINT HILL DRIVE, CARY, NC 27519
2 FROESE NATHAN 286 PINEVIEW DRIVE, WINKLER, MANITOBA R6M 1Y5
3 STIERL REINHARD NIAO SONG SHIANG, NO. 1-9 DONG SHAN ROAD, 83345 KAOHSIUNG COUNTY
4 HOPF ANDREAS AM HAUSELBERG 24, 67434 NEUSTADT
PCT International Classification Number A01N 37/46
PCT International Application Number PCT/EP2006/068098
PCT International Filing date 2006-11-06
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/735194 2005-11-10 U.S.A.