Title of Invention

A POLYALDIMINE AND A PROCESS FOR THE PREPARATION THEREOF

Abstract This invention relates to a polyaldimine which is obtainable from at least one polyamine A having aliphatic primary amino groups such as herein described, and at least one aldehyde B of the formula where Y1 and Y2 either independently of one another are an alkyl, aryl or arylalkyl group, which optionally may in each case be substituted, optionally may in each case contain heteroatoms and optionally may in each case contain unsaturated components; or Y1 andY2 are connected to one another to form a carbocyclic or heterocyclic ring which has a ring size of between 5 and 8, preferably 6, atoms and optionally contains one or two singly unsaturated bonds; and R1 stands either for a linear or branched alkyl chain having 11 to 30 carbon atoms, optionally at least one heteroatom, in particular with at least one ether oxygen, or for a singly or multiply unsaturated linear or branched hydrocarbon chain having 11 to 30 carbon atoms; or for or for where R2 is a linear or branched or cyclic alkylene chain having 2 to 16 carbon atoms, optionally at least one heteroatom, in particular with at least one ether oxygen, or is a singly or multiply unsaturated linear or branched or cyclic hydrocarbon chain having 2 to 16 carbon atoms, and R3 is a linear or branched alkyl chain having 1 to 8 carbon atoms.
Full Text Technical Field and Prior Art
The invention relates to innovative polyaldimines. These polyaldimines
are odorless and are obtainable from polyamines having aliphatic primary
amino groups, also referred to below as primary aliphatic polyamines, and from
an odorless aldehyde. The hydrolysis of the polyaldimines reforms the
aforementioned aldehydes and the aforementioned polyamines.
Aldimines are substances from a class of compounds which has long
been known perse, having been described, for example, in R.W. Layer, Chem.
Rev. 1963, 63, 489-510. It is known that aldimines on contact with water can
undergo hydrolysis to give the corresponding aldehydes and amines. In the
absence of water, aldimines are extremely stable compounds. Because of this
quality they are used, for example, in order to bind, and/or to protect, amines or
aldehydes. Thus, as described for example in US 3,420,800 and
US 3,567,692, aldimines are used in polyurethane chemistry, where in
combination with isocyanates they produce stable, storable compositions.
Within such compositions the aldimines are also referred to as "latent curing
agents", since in the presence of water (in the form for example of humidity
from the air) they release amines, which are able to react with the isocyanates
and so lead to crosslinking.
Aldehydes generally are extremely intensely odorous substances, a
fact which, for those who have close contact with such aldehydes is unpleasant
and may trigger headaches, nausea or other health problems. Consequently
many aldehydes, and the aldimines derived from them, are of only limited
possibility for use, since it is always necessary to ensure effective ventilation or
else respiratory protection must be worn.
In order to avoid such restrictions on application there is a great need
for polyaldimines which are odorless and which on being hydrolyzed release
aldehydes which are likewise odorless.
To the skilled worker it is clear that the term "odorless" is difficult to
define. Here and throughout the document it is intended to mean

"imperceptible or only slightly perceptible (smellable) to human beings
possessing the sense of smell".
There have to date been a variety of attempts to reduce the odor of
polyaldimines and/or of the aldehydes released in the course of their
hydrolysis.
US 6,136,942 describes one-component polyurethanes which
comprise 3-phenyloxybenzaldimines of aliphatic polyamines, and similar
compounds, and are said to exhibit low-odor curing. The odor of the aromatic
aldehydes released when these curing agents are employed, however, is
markedly perceptible and for many applications it is intolerable.
US 4,469,831 describes the use of 2,2-dimethyl-3-(isobutyroxy)-
propanealdimines of aliphatic polyamines as curing agents for one-component
polyurethanes. Compositions are obtained with purportedly little odor. The
aldehyde which is released when the polyaldimines described are employed,
however, gives rise to a long-lasting, pungent odor, which is intolerable for
many applications.
US 4,853,454 describes, inter alia, a one-component polyurethane
composition which comprises substituted 2,2-dimethylpropanealdimines of
aliphatic polyamines. The aldehydes released when the polyaldimines
described are hydrolyzed are said, owing to their high vapor pressure, to lead
to compositions purportedly of very low odor. When the polyaldimines
described are employed, however, there are, here as well, unpleasant odors,
perceptible over a long period, which makes these substances likewise
unsuitable for odor-sensitive applications.
US 4,720,535 describes moisture-curing polyurethane compositions
which comprise substituted 2,2-dimethylpropanealdimines of aromatic
polyamines. The use of the polyaldimines described is unsuitable owing to the
aromatic polyamines used. On the one hand, aromatic polyamines are
generally much more toxic than their aliphatic counterparts, and on the other
hand, polyaldimines of aromatic polyamines are much less reactive than those
of aliphatic polyamines, both in respect of the hydrolysis of the aldimine groups
and, mostly, in respect of a subsequent reaction with components that are
reactive toward amines. It is known, moreover, that aromatic polyamines are

discolored under the effect of light. Furthermore, the majority of the aldehydes
described here likewise give rise to an odor varying from markedly perceptible
to strong.
To date there are no polyaldimines of aliphatic polyamines available
which are odorless and on hydrolysis release odorless aldehydes.
Problem and Solution
The problem addressed by the present invention was therefore to
provide odorless polyaldimines whose aldimine groups hydrolyze rapidly on
contact with water and the aldehydes released in the course of said hydrolysis
do not give rise to any perceptible odor. Both the polyaldimines and their
hydrolysis products should as far as possible be toxicologically
unobjectionable.
Surprisingly it has been found that the aforementioned problem can be
solved by means of polyaldimines as claimed in claim 1. The polyaldimines of
the invention are obtainable from at least one polyamine having aliphatic
primary amino groups and at least one aldehyde in accordance with the
formula specified later on.
A fact surprising and not obvious to the skilled worker is that
polyaldimines of this kind have a sufficiently high reactivity as curing agents for
systems containing amine-reactive components. The skilled worker would have
expected such polyaldimines, owing to their hydrophobic structure, to be poorly
accessible for the water required for the hydrolysis of the aldimine groups, and
that, consequently, their hydrolysis would proceed only slowly and
incompletely. Unexpectedly, however, such polyaldimines hydrolyze quickly
and completely on contact with moisture. Their reactivity is comparable with
that of substantially less hydrophobic polyaldimines, as are described, for
example, in US 4,469,831.
The preparation of the aldehydes used for the polyaldimines uses
readily available, inexpensive raw materials and is accomplished surprisingly
simply by means of the esterificaticn of carboxylic acids of low volatility,
examples being long-chain fatty acids, with (i-hydroxy aldehydes, especially 3-

hydroxypivalaldehyde. Surprisingly this reaction step can be carried out without
solvent. Depending on the carboxylic acid used, the resulting aldehydes are
solid or liquid at room temperature. Subsequently they can be reacted
effectively with polyamines to give the corresponding polyaldimines. Since the
entire preparation operation can be carried out without solvent, there is no
need for distillative removal of solvents, which on the one hand simplifies the
preparation operation and on the other hand prevents any residues of solvent
in the polyaldimine being able to give rise to a nuisance odor.
Finally it has been found that the polyaldimines of the invention are
suitable for use in moisture-reactive compositions which comprise components
that are reactive toward amines. These compositions are stable on storage in
the absence of moisture.
Summary of the Invention
The present invention relates to polyaldimines which are obtainable
from at least one polyamine A having aliphatic primary amino groups and at
least one aldehyde B. These polyaldimines, and also the aldehydes B formed
during their hydrolysis, are odorless. Additionally disclosed are processes for
preparing these polyaldimines and aldehydes B, and processes for hydrolyzing
the polyaldimines.
Finally a description is given of the use of these polyaldimines in
compositions as adhesive, sealant, coating or covering.
The polyaldimines of the invention are notable in that they are
odorless, hydrolyze rapidly on contact with water, do not give rise to any
perceptible odor during and after their hydrolysis, and are stable on storage in
the absence of water in compositions which comprise components that are
reactive toward amines.
Detailed Description of the Invention
The present invention relates to polyaldimines which are obtainable
from at least one polyamine A having aliphatic primary amino groups and at
least one aldehyde B having the formula (I):

/
where Y1 and Y2 on the one hand independently of one another are an
alkyl, aryl or arylalkyl group, which if desired may in each case be substituted,
if desired may in each case contain heteroatoms and if desired may in each
case contain unsaturated components. Preferably Y1 = Y2 = methyl.
On the other hand Y1 and Y2 can be connected to one another to form
a carbocyclic or heterocyclic ring which has a ring size of between 5 and 8,
preferably 6, atoms and if desired contains one or two singly unsaturated
bonds.
The radical R1 stands either for a linear or branched alkyl chain having
11 to 30 carbon atoms, with or without at least one heteroatom, in particular
with at least one ether oxygen, or for a singly or multiply unsaturated linear or
branched hydrocarbon chain having 11 to 30 carbon atoms, or for a radical of
the formula (II) or (III).

In the formulae (II) and/or (III) R2 is a linear or branched or cyclic
alkylene chain having 2 to 16 carbon atoms, with or without at least one
heteroatom, in particular with at least one ether oxygen, or is a singly or
multiply unsaturated linear or branched or cyclic hydrocarbon chain having 2 to
16 carbon atoms, and R3 is a linear or branched alkyl chain having 1 to 8
carbon atoms. Y1 and Y2 have the definition already specified, and the dashed
lines in the formulae denote the connection points.
By "poly" in "polyaldimine" or "polyamine" are meant molecules which formally
contain two or more of the functional groups in question.
The term "polyamines having aliphatic primary amino groups" refers in the
present document always to compounds which formally contain two or more

NH2 groups which are attached to an aliphatic, cycloaliphatic or arylaliphatic
radical. They consequently differ from the aromatic amines, in which the amino
groups are attached directly to an aromatic radical, such as in aniline or
2-aminopyridine, for example.
The polyaldimine is preparable from at least one polyamine A having
aliphatic primary amino groups and at least one aldehyde B by a condensation
reaction with the elimination of water. Condensation reactions of this kind are
very well known and are described, for example, in Houben-Weyl, "Methoden
der organischen Chemie", Vol. XI/2, page 73 ff. In this reaction the aldehyde B
is used stoichiometrically or in a stoichiometric excess in relation to the primary
amino groups of the polyamine A.
Normally such condensation reactions are carried out in the presence of a
solvent which allows the water formed during the reaction to be removed
azeotropically. For the preparation of the polyaldimines of the invention,
however, preference is given to a preparation process without use of solvents,
where the water formed during the condensation is removed from the reaction
mixture directly by means of vacuum. The solvent-free preparation removes
the need for distillative removal o? the solvent after preparation has taken
place, thereby simplifying the preparation procedure. Moreover, in this way the
polyaldimine is free from solvent residues, which could at the least cause a
nuisance odor.
Suitable polyamines A having aliphatic primary amino groups for
preparing the polyaldimines are customary polyamines such as are used, for
example, in polyurethane or epoxy chemistry. Examples that may be
mentioned include the following: aliphatic polyamines such as ethylenediamine,
1,2- and 1,3-propanediamine, 2-methyl-1,2-propanediamine, 2,2-dimethyl-
1,3-propanediamine, 1,3- and 1,4-butanediamine, 1,3- and 1,5-pentane-
diamine, 1,6-hexanediamine, 2,2,4- and 2,4,4-trimethylhexamethylenediamine
and mixtures thereof, 1,7-heptanediamine, 1,8-octanediamine, 4-aminomethyl-
1,8-octanediamine, 1,9-nonanediamine, 1,10-decanediamine, 1,11 -undecane-
diamine, 1,12-dodecanediamine, methylbis(3-aminopropyl)amine, 1,5-diamino-

2-methylpentane (MPMD), 1,3-diaminopentane (DAMP), 2,5-dimethyl-
1,6-hexamethylenediamine, cycloaliphatic polyamines such as 1,2-, 1,3- and
1,4-diaminocyclohexane, bis(4-aminocyclohexyl)methane, bis(4-amino-
3-methylcyclohexyl)methane, bis(4-amino-3-ethylcyclohexyl)methane,
bis(4-amino-3,5-dimethylcyclohexyl)methane, 1-amino-3-aminomethyl-3,5,5-tri-
methylcyclohexane (= isophoronediamine or IPDA), 2- and 4-methyl-
1,3-diaminocyclohexane and mixtures thereof, 1,3- and 1,4-bis(aminomethyl)-
cyclohexane, 1-cyclohexylamino-3-aminopropane, 2,5(2,6)-bis(aminomethyl)-
bicyclo[2.2.1]heptane (NBDA, manufactured by Mitsui Chemicals), 3(4),8(9)-
bis(aminomethyl)tricyclo[5.2.1.026]decane, 1,4-diamino-2,2,6-trimethylcyclo-
hexane (TMCDA), 3,9-bis(3-aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane,
1,3- and 1,4-xylylenediamine, aliphatic polyamines containing ether groups,
such as bis(2-aminoethyl)ether, 4,7-dioxadecane-1,10-diamine, 4,9-dioxa-
dodecane-1,12-diamine and higher oligomers thereof, polyoxyalkylene-
polyamines having in theory two or three amino groups, obtainable for example
under the name Jeffamine® (manufactured by Huntsman Chemicals), and also
mixtures of the aforementioned polyamines.
Preferred polyamines are 1,6-hexamethylenediamine, MPMD, DAMP,
2,2,4- and 2,4,4-trimethylhexamethylenediamine, 4-aminomethyl-1,8-octane-
diamine, IPDA, 1,3- and 1,4-xylylenediamine, 1,3- and 1,4-bis(aminomethyl)-
cyclohexane, bis(4-aminocyclohexyl)methane, bis(4-amino-3-methylcyclo-
hexyl)methane, 3(4),8(9)-bis(aminomethyl)tricyclo[5.2.1.026]decane, 1,2-, 1,3-
and 1,4-diaminocyclohexane, polyoxyalkylene polyamines having in theory two
or three amino groups, especially Jeffamine® EDR-148, Jeffamine® D-230,
Jeffamine® D-400 and Jeffamine® [-403, and, in particular, mixtures of two or
more of the aforementioned polyamines.
The polyaldimine is prepared using at least one aldehyde B having the
formula (I):

In one preferred preparation method of the aldehyde B a starting
compound is a G-hydroxy aldehyde of formula (IV), which can be prepared, for
example, from formaldehyde (or paraformaldehyde or oligomeric forms of
formaldehyde, such as 1,3,5-trioxane) and an aldehyde of formula (V) in a
crosslinked aldol addition, in situ if appropriate.

The li-hydroxy aldehyde of formula (IV) is reacted with a carboxylic
acid to give the corresponding ester, specifically either with a long-chain fatty
acid R1-COOH, to give the corresponding fatty acid ester, and/or with a
dicarboxylic acid monoalkyl ester HOOC-R2-COOR3, to give the aldehyde B
having the radical according to formula (III); and/or with a dicarboxylic acid
HOOC-R2-COOH, to give the aldehyde B, in that case a dialdehyde, having
the radical according to formula (II). The formulae (II) and (III) and R1, R2 and
R3 have the definition already described. This esterification can take place
without the use of solvents in accordance with known methods, described for
example in Houben-Weyl, "Methoden der organischen Chemie", Vol. VIII,
pages 516-528.
Normally such esterification reactions are carried out in the presence of a
solvent, which after the reaction has taken place is removed again, by means
of distillation for example, together where appropriate with excess alcohol
which has not reacted in the esterification. In the case of one preferred process
for preparing the aldehyde B, however, no solvent at all is used. In that case
the G-hydroxyaldehyde according to formula (IV) is reacted, without the use of
solvents, directly with the carboxylic acid or with the carboxylic acid mixture,
the water formed during the esterification being removed under vacuum. Since
the carboxylic acids used for the esterification are virtually odorless, traces

thereof in the polyaldimines likewise do not give rise to any nuisance odor. For
this reason, and on account of the solvent-free preparation, it is possible to
dispense with the purification of the aldehydes, following their preparation, by
means of costly and inconvenient methods, such as by rectification or
crystallization, for example, and so the preparation procedure is made very
much simpler.
Of course, esterification reactions using solvents are also possible; they are,
however, not preferred, since they necessitate a subsequent, costly and
inconvenient separation of the solvent, or else the polyaldimines, owing to
solvent residues, cannot be prepared odorlessly.
In the case of the use of dicarboxylic acids a mixture of aldehydes B
having the radicals according to formula (II) and according to formula (III) is
obtained if, for example, first some of the carboxylic acid groups are esterified
with the S-hydroxy aldehyde according to formula (IV) and subsequently the
remaining carboxylic acid groups are esterified with an alkyl alcohol (R3-OH).
A mixture of this kind can be used directly to prepare the polyaldimine.
Preferred aldehydes according to formula (V) for reaction with
formaldehyde to give B-hydroxy aldehydes according to formula (IV) are the
following: isobutyraldehyde, 2-methylbutyraldehyde, 2-ethylbutyraldehyde,
2-methylvaleraldehyde, 2-ethylcaproaldehyde, cyclopentanecarboxaldehyde,
cyclohexanecarboxaldehyde, 1,2,3,6-tetrahydrobenzaldehyde, 2-methyl-
3-phenylpropionaldehyde, 2-phenylpropionaldehyde and diphenyl-
acetaldehyde. Isobutyraldehyde is particularly preferred.
Preferred (i-hydroxy aldehydes according to formula (IV) are the
products from the reaction of formaldehyde with the aldehydes according to
formula (V) specified in the foregoing as being preferred.
3-Hydroxypivalaldehyde is particularly preferred.
As suitable carboxylic acids for esterification with the R-hydroxy
aldehydes according to formula (IV) mention may be made, for example, of the
following: lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid,
palmitic acid, margaric acid, stearic acid, nonadecanoic acid, arachidic acid,
palmitoleic acid, oleic acid, erucic acid, linoleic acid, linolenic acid, elaeostearic

acid, arachidonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid,
suberic acid, azelaic acid, sebacic acid, 1,12-dodecanedioicc acid, maleic acid,
fumaric acid, hexahydrophthalic acid, hexahydroisophthalic acid,
hexahydroterephthalic acid, 3,6,9-trioxaundecanedioic acid and similar
derivatives of polyethylene glycol, dehydrogenated ricinoleic acids, and also
fatty acids from the industrial saponification of natural oils and fats such as, for
example, rapeseed oil, sunflower oil, linseed oil, olive oil, coconut oil, oil palm
kernel oil and oil palm oil.
Preference is given to lauric acid, myristic acid, palmitic acid, stearic
acid, oleic acid, linoleic acid, linolenic acid, succinic acid, adipic acid, azelaic
acid and sebacic acid and technical mixtures of fatty acids which comprise
these acids.
The reaction of at least one polyamine A having aliphatic primary
amino groups with at least one aldehyde B gives rise, for example, to
polyaldimines of the schematic formulae (VI) and (VII)

where n is 2, 3 or 4 and Q is intended to represent the radical of a
polyamine A having aliphatic primary amino groups after all of the primary
amino groups have been removed; and

where m is an integer from 0 to 10 and Q is identical or different in the
same molecule and in each case is intended to represent the radical of a
polyamine A having aliphatic primary amino groups after all of the primary

amino groups have been removed. The radicals Y1, Y2, R1 and R2 in the
formulae (VI) and (VII) have the definition already described.
If a dialdehyde B having the radical according to formula (II) is used for
preparing a polyaldimine then advantageously either it is used in a mixture with
a monoaldehyde B, in a proportion such that average values for m in the range
from 1 to 10 are obtained for the polyaldimine from formula (VII), or it is
metered so that there is an excess of aldehyde groups in relation to the amino
groups when the polyaldimine is prepared, the aldehyde excess being chosen
such that average values for m likewise in the range from 1 to 10 are obtained
for the polyaldimine from formula (VII). In both ways a mixture of oligomeric
polyaldimines having a readily manageable viscosity is obtained.
As polyaldimine it is also possible to use mixtures of different
polyaldimines, including, in particular, mixtures of different polyaldimines
prepared with the aid of different polyamines A having primary aliphatic amino
groups, reacted with different or identical aldehydes B, including, in particular,
mixtures of polyaldimines prepared with the aid of polyamines having different
numbers of primary aliphatic amino groups, i.e., different values for m.
The polyaldimines of the invention are odorless. The polyaldimines are
stable on storage in the absence of moisture, alone or else in combination with
components that are reacted toward amines, such as isocyanates, for
example. On contact with water there is rapid hydrolysis, in the course of which
aliphatic polyamines and aldehydes are liberated. Water in this case can be
brought into contact in the liquid or gaseous aggregate state with the
polyaldimine. Accordingly, in such a hydrolysis process, for example, water in
the form of atmospheric moisture may act on the polyaldimine or on a
polyaldimine-containing composition. A further example of such contacting is
the incorporation by mixing of water or of a water-containing component or of a
water-releasing component.
The reaction of components that are reactive toward amines with a
polyaldimine which is subjected to a hydrolysis need not necessarily take place
via the stage of the polyamine. Reactions are of course also possible with
intermediates in the hydrolysis of the polyaldimine to the polyamine. It is

conceivable, for example, for the hydrolyzing polyaldimine to react in the form
of a hemiaminal directly with the components that are reactive toward amines.
The polyaldimines of the invention are used, among other things, as a
source of polyamines. Polyaldimines of this kind can be used, for example, in
compositions which comprise components that are reactive toward amines,
such as compounds containing isocyanate groups, for example. On contact
with water, polyamines are released, which react in the manner described
above with the aforementioned components that are reactive toward amines
and, for example, crosslink them.
The polyaldimines of the invention are particularly suitable as curing
agents for use in adhesives, sealants, coatings, foams, paints and floor
coverings.
The polyaldimines are especially suitable for compositions containing
isocyanate groups, both in one-component systems, as moisture-reactive
latent curing agents, and in two-component systems, as curing agents with
retarded reaction, whose hydrolytic activation, by means of atmospheric
moisture for example, which must take place before the curing reaction, allows
long processing times (pot lives).
The polyaldimines of the invention are used with advantage in
particular in those applications which do not permit any odor pollution by the
product, before, during or after its application. The polyaldimines of the
invention can of course also be used anywhere where odor does not play a
critical part.
Examples
All percentage figures, unless indicated otherwise, refer to weight
percentages.
Polyamines Used:
alpha.omega-Polyoxypropylenediamine (Jeffamine® D-230,
Huntsman): total primary amines content > 97%; amine content = 8.22 mmol
NH2/g.

1,3-Xylylenediamine (MXDA; Mitsubishi Gas Chemical): MXDA content
> 99%; amine content = 14.56 mmol NH2/g.
1,6-Hexamethylenediamine (HDA): HDA content ^ 99.0%; amine
content = 17.21 mmol NH2/g.
1,5-Diamino-2-methylpentane (MPMD; DuPont): MPMD content >
98.5%; amine content =17.11 mmol NH2/g.
Polvols used:
Acclaim® 4200 N (Bayer): linear polypropylene oxide polyol having a
theoretical OH functionality 2, an average molecular weight of about 4000, an
OH number of about 28 mg KOH/g and a degree of unsaturation of about
0.005 meq/g.
Caradol® MD34-02 (Shell): nonlinear polypropylene oxide-polyethylene
oxide polyol, ethylene oxide-terminated, having a theoretical OH functionality of
3, an average molecular weight of about 4900, an OH number of about 35 mg
KOH/g and a degree of unsaturation of about 0.08 meq/g.
Description of Test Methods:
The infrared spectra were measured on an FT-IR instrument 1600 from
Perkin-Elmer (horizontal ATR measuring unit with ZnSe crystal); the samples
were applied undiluted in the form of films. The absorption bands are given in
wavenumbers (crrT1).
The viscosity was measured at 20°C on a cone/plate viscometer from
Haake(PK100/VT-500).
The skin-forming time (time until freedom from tack, "tack-free time")
was determined at 23°C and 50% relative humidity.
Tensile strength and breaking elongation were determined on films
cured for 7 days at 23°C and 50% relative humidity in accordance with
DIN EN 53504 (pulling speed: 200 mm/min).

The formation of bubbles was assessed qualitatively from the amount
of bubbles which occurred in the course of curing (7 days at 23°C and 50%
relative humidity) of the films used for the mechanical tests (film thickness
2 mm).
The odor of the aldehydes or of the polyaldimines or of the
compositions, respectively, was assessed by nasal odor sampling at a distance
of 10 cm on the material applied as a film at room temperature. For
compositions this was performed a first time on the material applied
immediately beforehand and a second time 7 days thereafter on the material
cured at 23°C and 50% relative humidity.
The hydrolysis of the polyaldimines was carried out by adding the
stoichiometric amount of 0.1 N HCI, relative to the aldimine groups, to 10 ml of
each polyaldimine and briefly mixing it in. After one hour the odor of the
hydrolyzed polyaldimine was assessed by nasal odor sampling at a distance of
10 cm on the material applied as a film at room temperature.
Preparation of polvaldimines
Polyaldimines PA1 to PA7 were prepared using aldehydes A1 to A6, whose
preparation is described below:
Example 1 (aldehyde A1)
A round-bottomed flask with reflux condenser, thermometer and water
separator (Dean Stark) was charged with 40.5 g of formaldehyde (37% in
water, methanol-free), 36.0 g of isobutyraldehyde, 100.0 g of lauric acid and
1.0 g of 4-toluenesulfonic acid and placed under a nitrogen atmosphere. The
mixture was heated in an oil bath at 90°C with vigorous stirring until the reflux
rate had dropped significantly. At that point the bath temperature was raised to
120°C and the mixture was boiled at reflux to constant temperature. Then the
reflux cooling was switched off and the bath temperature was raised to 140°C,
at which point water began to separate. After two hours the bath temperature
was raised to 170°C and the apparatus was evacuated under a water jet

vacuum for 90 minutes. A total of around 35 ml of distillate collected in the
separator. The reaction mixture was cooled to room temperature and stored
under a nitrogen atmosphere. The resulting product, an odorless oil of low
viscosity with a bright orange color, was identified by mass spectroscopy as
2,2-dimethyl-3-oxopropyl laurate. Yield: 140 g.
IR: 2954, 2923, 2853, 2707 (CHO), 1733 (C=O), 1466, 1418, 1402, 1375,
1248, 1234, 1157, 1112, 1023, 998, 938, 892, 774, 722.
Example 2 (aldehyde A2)
As described for aldehyde A1, 42.8 g of formaldehyde (37% in water,
methanol-free), 38.0 g of isobutyraldehyde, 150.0 g of stearic acid and 1.0 g of
4-toluenesulfonic acid were reacted with the separation of around 37 ml of
water. The resulting product, an odorless material which was solid at room
temperature with a bright orange color, was identified by mass spectroscopy as
2,2-dimethyl-3-oxopropyl stearate. Yield: 192 g.
IR: 2955, 2915, 2849, 2712 (CHO), 1732 (C=O), 1468, 1416, 1378, 1311,
1293, 1273, 1255, 1235, 1215, 1193, 1166, 1104, 1018, 988, 940, 892, 810,
777, 720.
Example 3 (aldehyde A3)
A round-bottomed flask with reflux condenser, thermometer and water
separator (Dean Stark) was charged with 11.0 g of paraformaldehyde, 40.0 g
of 2-methylvaleraldehyde, 64.0 g of lauric acid and 0.5 g of 4-toluenesulfonic
acid and placed under a nitrogen atmosphere. The mixture was heated in an oil
bath at 100°C with vigorous stirring until the reflux rate had dropped
significantly. Then the reflux cooling was switched off and the bath temperature
was raised to 130°C, at which point water began to separate. After 30 minutes
the bath temperature was raised to 170°C and the apparatus was evacuated
under a water jet vacuum for 90 minutes. A total of around 14 ml of distillate
collected in the separator. The reaction mixture was subsequently rectified
under a high vacuum. The resulting product, a colorless and odorless oil of low
viscosity (boiling point 143°C at 0.1 mbar), was identified by mass
spectroscopy as 2-methyl-2-propyl-3-oxopropyl laurate. Yield: 70.0 g.

IR: 2956, 2923, 2852, 2706 (CHO), 1734 (C=O), 1466, 1417, 1398, 1378,
1347, 1233, 1156, 1112, 1074, 1011, 975, 934, 919, 885, 856, 777, 739, 722.
Example 4 (aldehyde mixture A4)
As described for aldehyde A1, 60.2 g of formaldehyde (37% in water,
methanol-free), 53.5 g of isobutyraldehyde, 100.0 g of sebacic acid and 1.0 g
of 4-toluenesulfonic acid were reacted with the separation of around 52 ml of
water. The reaction mixture obtained was cooled to 100°C, admixed with
19.0 g of n-butanol, and stirred at 100°C for 30 minutes and then the bath
temperature was raised again to 140°C, whereupon water began to separate
again. After one hour the bath temperature was raised to 170°C and the
apparatus was evacuated under a water jet vacuum for 90 minutes. A total of
around 57 ml (52 ml + 5 ml) of distillate collected in the separator. The resulting
product, an odorless oil bright orange in color, consisted of a mixture of bis(2,2-
dimethyl-3-oxopropyl)sebacate, butyl(2,2-dimethyl-3-oxopropyl)sebacate and
dibutyl sebacate (identified by means of GC-MS). Yield: 168 g.
IR: 2933, 2855, 2708 (CHO), 1731 (C=O), 1465, 1369, 1240, 1161, 1099,
1026, 937, 893, 774, 726.
Example 5 (aldehyde mixture A5)
As described for aldehyde A1, 22.3 g of paraformaldehyde, 53.5 g of
isobutyraldehyde, 49.5 g of lauric acid, 50.0 g of sebacic acid and 1.0 g of
4-toluenesulfonic acid were reacted with the separation of just under 14 ml of
water. The resulting product, an odorless oil bright orange in color, consisted of
a mixture of 2,2-dimethyl-3-oxopropyl laurate and bis(2,2-dimethyl-3-oxopropyl)
sebacate (identified by means of GC-MS). Yield: 161 g.
Example 6 (aldehyde A6)
A round-bottomed flask with thermometer and water separator (Dean Stark)
was charged with 51.0 g of 3-hydroxypivalaldehyde (dimeric form), 100.0 g of
lauric acid and 1.0 g of 4-toluenesulfonic acid and placed under a nitrogen
atmosphere. The mixture was heated in an oil bath to 140°C with vigorous
stirring, whereupon water began to separate. After two hours the bath

temperature was raised to 170°C and the apparatus was evacuated under a
water jet vacuum for 90 minutes. A good 9 ml of distillate in all collected in the
separator. The reaction mixture was then cooled to room temperature and
stored under a nitrogen atmosphere. The resulting product, an odorless oil of
low viscosity with a bright orange color was identified by mass spectroscopy as
2,2-dimethyl-3-oxopropyl laurate and was no different from aldehyde A1 from
example 1. Yield: 141 g.
Example 7 (polyaldimine PA1)
A round-bottomed flask w/.s charged with 140.0 g of aldehyde A1 and
placed under a nitrogen atmosphere and the flask was cooled by means of a
water bath. With vigorous stirring and continued cooling, 48.6 g of Jeffamine®
D 230 were added from a dropping funnel at such a slow rate that the
temperature of the mixture did not climb above 40°C. Thereafter the volatile
constituents were distilled off completely under a water jet vacuum at 80°C.
The resulting reaction product, liquid at room temperature, was completely
odorless and had an aldimine content, determined as the amine content, of
2.17 mmol NH2/g and a viscosity at 20°C of 700 mPa-s.
IR: 2956, 2923, 2853, 1738 (C=O), 1667 (C=N), 1466, 1375, 1344, 1250, 1236,
1155, 1109, 1023, 1006, 932, 873, 722.
Example 8 (polyaldimine PA2)
As described for polyaldimine PA1, 192.0 g of aldehyde A2 were
reacted with 57.0 g of Jeffamine® D-230. Removal of the volatile constituents
at 80°C under a water jet vacuum gave a reaction product of creamy
consistency at room temperature that was completely odorless and had an
aldimine content, determined as the amine content, of 1.93 mmol NH2/g.
IR: 2956, 2919, 2851, 1739 (C=O), 1667 (C=N), 1467, 1396, 1375, 1247, 1157,
1111,1021,1003,932,873,721.
Example 9 (polyaldimine PA3)
As described for polyaldimine PA1, 30.0 g of aldehyde A3 were
reacted with 7.6 g of HDA. Removal of the volatile constituents at 80°C under a

water jet vacuum gave a colorless reaction product which was liquid at room
temperature, was completely odorless and had an aldimine content,
determined as the amine content, of 2.72 mmol NH2/g.
IR: 2955, 2922, 2852, 1737 (C=O), 1667 (C=N), 1466, 1419, 1376, 1343, 1233,
1162, 1112, 1070, 1021, 1008, 939, 885, 863, 740, 722.
Example 10 (polyaldimine PA4)
As described for polyaldimine PA1, 168.0 g of aldehyde mixture A4
were reacted with 72.0 g of Jeffamine® D-230. Removal of the volatile
constituents at 80°C under a water jet vacuum gave a reaction product which
was liquid at room temperature, was completely odorless and had an aldimine
content, determined as the amine content, of 2.49 mmol NhVg and a viscosity
at20oCof6700mPas.
IR: 2964, 2928, 2855, 1734 (C=O), 1667 (C=N), 1458, 1374, 1243, 1160, 1106,
1020,934,874,726.
Example 11 (polyaldimine PA5)
As described for polyaldimine PA1, 140.0 g of aldehyde A1 were
reacted with 26.0 g of MXDA. Removal of the volatile constituents at 80°C
under a water jet vacuum gave a reaction product which was liquid at room
temperature, was completely odorless and had an aldimine content,
determined as the amine content, of 2.33 mmol NH2/g.
IR: 2954, 2922, 2853, 1737 (C=O), 1668 (C=N), 1608, 1466, 1395, 1374, 1367,
1302, 1249, 1232, 1158, 1113, 1020, 1006, 920, 781, 744, 722, 701.
Example 12 (polyaldimine PA6)
As described for polyaldimine PA1, 161.0 g of aldehyde mixture A5
were reacted with 33.0 g of MPMD. Removal of the volatile constituents at
80°C under a water jet vacuum gave a reaction product which was liquid at
room temperature, was completely odorless and had an aldimine content,
determined as the amine content, of 3.05 mmol NH2/g and a viscosity at 20°C
of 13 000mPas.

Example 13 (polyaldimine PA7)
As described for polyaldimine PA1, 141.0 g of aldehyde A6 were
reacted with 23.2 g of HDA. Removal of the volatile constituents at 80°C under
a water jet vacuum gave a reaction product which was liquid at room
temperature, was completely odorless and had an aldimine content,
determined as the amine content, of 2.50 mmol NH2/g.
IR: 2954, 2923, 2853, 1737 (C=O), 1669 (C=N), 1466, 1395, 1374, 1248, 1230,
1157, 1112, 1020, 1004, 933, 722.
Example 14 (polyaldimine PA8) (comparative)
A round-bottomed flask was charged with 100.0 g of Jeffamine® D-230.
With effective cooling and vigorous stirring, 75.0 g of isobutyraldehyde were
added from a dropping funnel. After 12 hours' stirring the volatile constituents
were distilled off. The resulting reaction product, liquid at room temperature,
had a very strong aldehyde odor and had an aldimine content, determined as
the amine content, of 5.66 mmol NH2/g.
Example 15 (polyaldimine PA9) (comparative)
A round-bottomed flask was charged with 62.0 g of Jeffamine® D-230.
With effective cooling and vigorous stirring, 89.5 g of 2,2-dimethyl-3-iso-
butyroxypropanal were added from a dropping funnel. After 10 minutes' stirring
the volatile constituents were distilled off. The resulting reaction product, liquid
at room temperature, had a strong aldehyde odor and had an aldimine content,
determined as the amine content, of 3.58 mmol NH2/g.
Example 16 (polyaldimine PA10) (comparative)
As described for polyaldimine PA9, 45.0 g of MXDA were reacted with
115.0 g of 2,2-dimethyl-3-isobutyroxypropanal. The resulting reaction product,
liquid at room temperature, had a strong aldehyde odor and had an aldimine
content, determined as the amine content, of 4.43 mmol NH2/g.
Results: Properties of the polyaldimines
Table 1 shows how strongly any odor of the polyaldimines described is

perceptible, on the one hand on smelling the product prepared ("odor after
preparation") and on the other hand in the course of hydrolysis, in other words
on release of the respective aldehyde ("odor after hydrolysis").
Table 1: Odor of the polyaldimines.

*Ref. = comparative
The polyaldimines PA1 to PA7 of the invention have no odor, either
before or after hydrolysis. The comparative polyaldimines PA8 to PA10, in
contrast, all smell strongly or very strongly, not only PA8, which releases
isobutyraldehyde, but also PA9 and PA10, which were both prepared
according to US 4,469,831 and release 2,2-dimethyl-3-isobutyroxypropanal.
Examples of use of the polvaldimines
Examples that may be given of the possible use of the polyaldimines of
the invention include, below, their use in compositions containing isocyanate
groups.
Compositions Z1 to Z11 were prepared using polyurethane
prepolymers PP1 and PP2, whose preparation is described below:
Polyurethane prepolymer PP1
259 g of polyol Acclaim® 4200 N, 517 g of polyol Caradol® MD34-02,
124 g of 4,4'-methylenediphenyl diisocyanate (MDI; Desmodur® 44 MC L,
Bayer) and 100 g of diisodecyl phthalate were reacted by a known method at
80°C to give an NCO-terminated polyurethane prepolymer. The reaction
product had a titrimetrically determined free isocyanate group content of
2.30%, based on the polyurethane prepolymer, and a viscosity at 20°C of

Polyurethane prepolymer PP2
845 g of polyol Acclaim® 4200 N and 115 g of 4,4'-methylenediphenyl
diisocyanate (MDI; Desmodur® 44 MC L, Bayer) were reacted by a known
method at 80°C to give an NCO-terminated polyurethane prepolymer. The
reaction product had a titrimetrically determined free isocyanate group content
of 1.96% and a viscosity at 20°C of 37 Pas.
Example 17 (PU compositions Z1 to Z7)
The polyurethane prepolymers and polyaldimines listed in table 2 were
mixed homogeneously in the stated NH2/NCO ratio (i.e., equivalents of
aldimine groups per equivalents of isocyanate groups of the polyurethane
prepolymer). Benzoic acid (200mg/100g of polyurethane prepolymer) was
added to each mixture, which was again mixed homogeneously and dispensed
immediately into airtight tubes, which were stored at 60°C for 15 hours. Then a
portion of each mixture was poured into a PTFE-coated metal sheet (film
thickness about 2 mm) and cured for 7 days at 23°C and 50% relative humidity,
after which the mechanical properties of the through-cured film were
measured. The remaining contents of the tube were used to determine the
storage stability, by measurement cf the viscosity before and after storage for
7 days at 60°C. The results of the tests are set out in table 2.

Table 2: Polyurethane compositions with the polyaldimines of the
invention.

*Value at max. elongation (1300%)
The results of table 2 show that compositions Z1 to Z7, which contain
the polyaldimines PA1 to PA7 of the invention, are all stable on storage, have
good reactivity (skin-forming time) and cure without bubbles. In the cured state
they possess good mechanical properties and neither during application nor
later give off a nuisance odor.
Example 18 (PU compositions Z8 to Z11) (comparative)
Example 18 (comparative) was carried out in the same way as for
example 17 but using the polyaldimines PA8 to PA10 prepared in accordance
with the prior art. The results of the tests are set out in table 3.


Table 3: Polyurethane compositions prepared in accordance with the prior art.
(n.m. = not measurable)
The results of table 3 show that the polyurethane composition Z8,
containing the polyaldimine PA8, is not stable on storage. The mixture had
gelled even before the first viscosity measurement. Moreover, on application,
Z8 has a very strong odor.
The polyurethane compositions Z9 and Z10, formulated in accordance with
US 4,469,831, do have good storage stability and reactivity and in the cured
state possess good mechanical properties; the aldehyde released in the course
of hydrolysis, however, gives rise to a strong and long-lasting odor, which is
unacceptable for many applications.
Polyurethane composition Z11, which contains no latent curing agent, is indeed
odorless and also stable on storage; the reactivity, however, is low (very long

/
skin-forming time), and curing is accompanied by the formation of a large
number of bubbles, so that the effective mechanical properties of the cured
composition were impossible to determine.

WE CLAIM;
1. A polyaldimine which is obtainable from
at least one polyamine A having aliphatic primary amino groups
such as herein described,
and
at least one aldehyde B of the formula

where Y1 and Y2 either
independently of one another are an alkyl, aryl or arylalkyl group,
which optionally may in each case be substituted, optionally may
in each case contain heteroatoms and optionally may in each case
contain unsaturated components;
or Yi and Y2
are connected to one another to form a carbocyclic or heterocyclic
ring which has a ring size of between 5 and 8, preferably 6, atoms
and optionally contains one or two singly unsaturated bonds;
and
R1 stands either
for a linear or branched alkyl chain having 11 to 30 carbon atoms,
optionally at least one heteroatom, in particular with at least one
ether oxygen, or for a singly or multiply unsaturated linear or
branched hydrocarbon chain having 11 to 30 carbon atoms;
or for


or for

where R2 is a linear or branched or cyclic alkylene chain having 2
to 16 carbon atoms, optionally at least one heteroatom, in
particular with at least one ether oxygen, or is a singly or multiply
unsaturated linear or branched or cyclic hydrocarbon chain having
2 to 16 carbon atoms,
and
R3 is a linear or branched alkyl chain having 1 to 8 carbon atoms.
2. The polyaldimine as claimed in claim 1, wherein the polyamine A
having aliphatic primary amino groups is selected from the group
consisting of 1,6-hexamethylenediamine, l,5-diamino-2-
methylpentane (MPMD), 1,3-diaminopentane (DAMP),
isophoronediamine (IPDA), 2,2,4- and 2,4,4-
trimethyihexamethylenediamine, 4-aminomethyl-1,8-octanediamine,
1,3- and 1,4-xylylenediamine, 1,3- and 1,4-bis(aminomethyl)
cyclohexane, bis(4-aminocyclohexyl)methane, bis(4-amino-3-
methylcyclohexyl)methane, 3(4),8(9)-bis(aminomethyl)tricyclo
[5.2.1.02-6]decane,l,2-,l,3- and 1,4-diaminocyclohexane,
polyoxyalkylene polyamines having two or three amino groups,
and also mixtures of two or more of the aforementioned polyamines.

3. The polyaldimine as claimed in either of the preceding claims, wherein
the aldehyde B used for preparing the polyaldimine is obtainable by
means of an esterification reaction of a S-hydroxy aldehyde with a
carboxylic acid, in particular without use of a solvent, the S-hydroxy
aldehyde being prepared, in situ if appropriate, from formaldehyde,
and/or paraformaldehyde, and from a second aldehyde, this second
aldehyde being selected from the group consisting of isobutyraldehyde,
2-methylbutyraldehyde, 2-ethylbutyraldehyde, 2-methylvaleraldehyde, 2-
ethylcaproaldehyde, cyclopentanecarboxaldehyde,
cyclohexanecarboxaldehyde, 1,2,3,6-tetrahydrobenzaldehyde, 2-methyl-
3-phenylpropionaldehyde, 2-phenylpropionaldehyde and
diphenylacetaldehyde, preferably isobutyraldehyde.
4. The polyaldimine as claimed in claim 3, wherein the carboxylic acid
used for preparing the aldehyde B is selected from the group consisting
of lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic
acid, linolenic acid, succinic acid, adipic acid, azelaic acid and sebacic
acid.
5. The polyaldimine as claimed in any one of the preceding claims,
wherein for preparing the polyaldimine the aldehyde B is used
stoichiometrically or in a stoichiometric excess in relation to the primary
amino groups of the polyamine A.
6. The polyaldimine as claimed in any one of the preceding claims,
wherein Y1 =Y2 =methyl.

7. A process for preparing a polyaldimine as claimed in any one of
claims 1-6, comprising reacting an aldehyde B with a polyamine A having
aliphatic primary amino groups.
8. The process for preparing a polyaldimine as claimed in claim 7, further
comprising a step of preparing an aldehyde B from a carboxylic acid and
a S-hydroxy aldehyde, in particular without use of a solvent, the 6-
hydroxy aldehyde being prepared, in situ if appropriate, from
formaldehyde, and/or paraformaldehyde or oligomeric forms of
formaldehyde, and from a second aldehyde.
9. The process for preparing a polyaldimine as claimed in claim 7, further
comprising a step of preparing an aldehyde B from a carboxylic acid and
3-hydroxypivalaldehyde, in particular without use of a solvent, 3-
hydroxypivalaldehyde being prepared, in situ if appropriate, from
formaldehyde, and/or paraformaldehyde, and from isobutyraldehyde.

10. The process for preparing a polyaldimine as claimed in claim 7, 8 or
9, wherein no solvents are used during the preparation of the
polyaldimine and/or of the aldehyde.
11. The polyaldimine as claimed in claims 1 to 6 having components that
are reactive toward amines, used in adhesive, sealant, coating or
covering compositions.
12. The polyaldimine as claimed in claim 11, wherein the components
that are reactive toward amines are isocyanate groups.

13. A hydrolysis process wherein a polyaldimine as claimed in any one of
claims 1-6 is brought into contact with water in the gaseous aggregate
state, in particular in the form of atmospheric moisture, and aldehyde B
is released.
14. A hydrolysis process wherein a polyaldimine as claimed in any one
claims 1-6 is brought into contact with water in the form of a water-
containing component or a water-releasing component, and aldehyde B
is released.
15. The hydrolysis process as claimed in claim 13 or 14, wherein the
polyaldimine is present in a composition which comprises components
that are reactive toward amines.


This invention relates to a polyaldimine which is obtainable from
at least one polyamine A having aliphatic primary amino groups
such as herein described,
and
at least one aldehyde B of the formula

where Y1 and Y2 either
independently of one another are an alkyl, aryl or arylalkyl group,
which optionally may in each case be substituted, optionally may
in each case contain heteroatoms and optionally may in each case
contain unsaturated components;
or Y1 andY2
are connected to one another to form a carbocyclic or heterocyclic
ring which has a ring size of between 5 and 8, preferably 6, atoms
and optionally contains one or two singly unsaturated bonds;
and
R1 stands either
for a linear or branched alkyl chain having 11 to 30 carbon atoms,
optionally at least one heteroatom, in particular with at least one
ether oxygen, or for a singly or multiply unsaturated linear or
branched hydrocarbon chain having 11 to 30 carbon atoms;
or for


or for
where R2 is a linear or branched or cyclic alkylene chain having 2
to 16 carbon atoms, optionally at least one heteroatom, in
particular with at least one ether oxygen, or is a singly or multiply
unsaturated linear or branched or cyclic hydrocarbon chain having
2 to 16 carbon atoms,
and
R3 is a linear or branched alkyl chain having 1 to 8 carbon atoms.

Documents:

281-KOLNP-2005-(07-12-2011)-FORM-27.pdf

281-kolnp-2005-correspondence-1.1.pdf

281-kolnp-2005-correspondence.pdf

281-kolnp-2005-examination report-1.1.pdf

281-kolnp-2005-examination report.pdf

281-kolnp-2005-form 18-1.1.pdf

281-kolnp-2005-form 18.pdf

281-kolnp-2005-form 26-1.1.pdf

281-kolnp-2005-form 26.pdf

281-kolnp-2005-form 3-1.1.pdf

281-kolnp-2005-form 3.pdf

281-kolnp-2005-form 5-1.1.pdf

281-kolnp-2005-form 5.pdf

281-kolnp-2005-granted-abstract-1.1.pdf

281-kolnp-2005-granted-abstract.pdf

281-kolnp-2005-granted-claims-1.1.pdf

281-kolnp-2005-granted-claims.pdf

281-kolnp-2005-granted-description (complete)-1.1.pdf

281-kolnp-2005-granted-description (complete).pdf

281-kolnp-2005-granted-form 1-1.1.pdf

281-kolnp-2005-granted-form 1.pdf

281-kolnp-2005-granted-form 2-1.1.pdf

281-kolnp-2005-granted-form 2.pdf

281-kolnp-2005-granted-specification-1.1.pdf

281-kolnp-2005-granted-specification.pdf

281-kolnp-2005-others-1.1.pdf

281-kolnp-2005-others.pdf

281-kolnp-2005-reply to examination report-1.1.pdf

281-kolnp-2005-reply to examination report.pdf


Patent Number 247599
Indian Patent Application Number 281/KOLNP/2005
PG Journal Number 17/2011
Publication Date 29-Apr-2011
Grant Date 26-Apr-2011
Date of Filing 25-Feb-2005
Name of Patentee SIKA TECHNOLOGY AG.
Applicant Address ZUGERSTRASSE 50, CH-6340 BAAR
Inventors:
# Inventor's Name Inventor's Address
1 BURCKHARDT, URS ALLENMOOSSTRASSE 66, CH-8057, ZURICH
PCT International Classification Number C07C 251/08
PCT International Application Number PCT/EP2003/008040
PCT International Filing date 2003-07-23
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 02016792.2 2002-07-26 EUROPEAN UNION