Title of Invention

ACTIVE MATRIX BACKPLANE FOR CONTROLLING CONTROLLED ELEMENTS AND METHOD OF MANUFACTURE THEREOF

Abstract An electronic device is formed from electronic elements (70, 74) deposited on a substrate (10). The electronic elements are deposited on the substrate by advancing the substrate through a plurality of deposition vacuum vessels (4-1 to 4-12), with each deposition vacuum vessel having at least one material deposition source (8-1 to 8-12) and a shadowmask (12-1 to 12-12) positioned therein. The material from at least one material deposition source (8) positioned in each deposition vacuum vessel (4) is deposited on the substrate (10) through the shadowmask (12) positioned in the deposition vacuum vessel (4) to form on the substrate (10) a circuit comprised of an array of electronic elements. The circuit is formed solely by the successive deposition of materials on the substrate (10).
Full Text ACTIVE MATRIX BACKPLANE FOR CONTROLLING CONTROLLED ELEMENTS
AND METHOD OF MANUFACTURE THEREOF
BACKGROUND OF THE INVENTION
Field of the Invention
[0001] The present invention relates to a substrate having electronic elements formed thereon
which can be utilized for controlling controlled elements and a method of manufacturing the
electronic elements on the substrate. The present invention also relates to a substrate having
electronic elements and controlled elements formed thereon, where the electronic elements can
be operated to control the controlled elements, and a method of manufacturing the electronic
elements and the controlled elements on the substrate.
Description of Related Art
[0002] Active matrix backplanes are widely used in flat panel displays for routing signals to
pixels of the display to produce viewable pictures. Presently, active matrix backplanes for flat
panel displays are formed by performing a series of processes. Exemplary processing steps to
produce a poly-silicon active matrix backplane include the following steps:
[0003] As can be seen, the poly-silicon active matrix backplane fabrication process includes
numerous deposition and etching steps in order to define appropriate patterns of the backplane.
[0004] Because of the number of steps required to form a poly-silicon active matrix
backplane, foundries of adequate capacity for volume production of poly-silicon backplanes are
very expensive. The following is a partial list of exemplary equipment needed for manufacturing
poly-silicon active matrix backplanes.
[0005] Because of the nature of the poly-silicon active matrix backplane fabrication process,
the foregoing equipment must be utilized in a class one (1) or class ten (10) clean room. In
addition, because of the amount of equipment needed and the size of each piece of equipment the
clean room must have a relatively large area which can be relatively expensive.
[0006] Moreover, poly-silicon is reproduced by recrystallization of amorphous silicon. This
results in non-uniform grain size and carrier mobility, which then also translates into poor
control of thin film transistor threshold voltages, particularly in large size circuits. These factors
. have so far limited the use of poly-silicon to small area backplanes used in LCD projectors.
[0007] It is, therefore, an object of the present invention to overcome the above limitations and
others by providing an electronic device that includes a substrate having electronic elements
formed thereon, which can be utilized for controlling controlled elements wherein the process of
forming the electronic elements on the substrate is less complicated and less expensive than the
process of forming electronic elements on backplanes using the poly-silicon active matrix
backplane fabrication process described above. Still other objects will become apparent to those
of ordinary skill in the art upon reading and understanding the following detailed description.
SUMMARY OF THE INVENTION
[0008] The present invention is a method of forming an electronic device. The method
includes providing a substrate and depositing semiconductor material, conductive material and
insulating material on the substrate through shadowmasks in the presence of a vacuum. The
insulating material, the semiconductor material and the conductive material co-act to form an
electronic element on the substrate.
[0009] The substrate can be flexible, transparent, electrically non-conducting or electrically
conducting with an electrical insulator disposed between the electronic element and the
electrically conductive part of the substrate.
[0010] The electronic element can be a thin film transistor. The method can also include
depositing light emitting material on the substrate through a shadowmask in the presence of a
vacuum in a manner whereby the light emitting material emits light in response to a control
signal applied to the thin film transistor a diode, a memory element or a capacitor.
[0011] The invention is also a method of forming an electronic device that includes advancing
a substrate through a plurality of deposition vacuum vessels, with each deposition vacuum vessel
having at least one material deposition source and a shadowmask positioned therein. Material
from the at least one material deposition source positioned in each deposition vacuum vessel is
deposited on the substrate through the shadowmask positioned in the deposition vacuum vessel
to form on the substrate a circuit comprised of an array of electronic elements. The circuit is
formed solely by the successive deposition of materials on the substrate.
[0012] The plurality of deposition vacuum vessels can be interconnected. The substrate can
be an elongated sheet that is advanced along its length through the plurality of deposition
vacuum vessels whereupon at least one part of the substrate advances sequentially through each
deposition vacuum vessel wherein it receives deposits of materials from the deposition sources
positioned in the deposition vacuum vessels.
[0013] The substrate can include along its length a plurality of spaced portions which can be
advanced through the plurality of vacuum vessels whereupon each portion receives a deposit of
material from the deposition source positioned in each vacuum vessel.
[0015] Where the electronic elements are thin film transistors, the depositing step includes, for
each thin film transistor: depositing a layer of semiconductor material, e.g., Cadmium Selenide,
Tellurium, Indium - Arsenide, or the like, on the substrate; depositing a first layer of
semiconductor compatible conductive material, e.g., Gold-Indium, relative to the semiconductor
material and the substrate in a manner to form therewith a source and drain of the thin film
transistor; depositing a first insulator layer relative to the semiconductor material, the source and
the drain in a manner to form therewith a gate insulator; and depositing as second layer of
conductive compatible conductive material, e.g., Gold-Indium, relative to the gate insulator, the
semiconductor material, the source and the drain in a manner to form therewith a gate of the thin
film transistor. A second insulator layer can be deposited relative to the second layer of
conductive material and the first insulator layer in a manner whereupon at least part of the
second layer of conductive material is exposed through a window in the second insulator layer. A
third layer of semiconductor compatible conductive material can be deposited relative to the
second layer of conductive material and through the window in the second insulator layer to
form an output pad.
[0016] The first conductive material can be deposited in a manner to form with one of the
source and the drain of at least one thin film transistor a first address bus and the second
conductive material can be deposited in a manner to form with the other of the source and the
drain of the at least one thin film transistor a second address bus. Each address bus is
individually addressable. Each thin film transistor in a column or a row of the array of thin film
transistors forming the circuit is connected to a common address bus.
[0017] The circuit can also include a plurality of deposited light emitting elements, with
the thin film transistors disposed between the substrate and the light emitting elements.
[0018] To form each light emitting element, a hole transport material is deposited on the
substrate in electrical communication with a power terminal of the thin film transistor associated
with the light emitting element. Next, a light emitting material of each light emitting element is
deposited over at least part of the hole transport material in alignment with or adjacent to the
power terminal associated with the thin film transistor for the light emitting element. An
electron transport material of each light emitting element is then deposited over at least part of
the light emitting material of each light emitting element. Lastly, a conductive material of each
light emitting element is deposited over at least part of the electron transport material thereof.
BRIEF DESCRIPTION OF THE DRAWINGS
[0019] Fig. 1 is a diagrammatic side view of an exemplary in-line production system for
the manufacture of electronic elements and controlled elements on a substrate in accordance with
the present invention;
[0020] Fig. 2 is a view of an isolated portion of a shadowmask utilized in the production
system shown in Fig. 1;
[0021] Fig. 3 is a cross-sectional view of a portion of the substrate shown in Fig. 1
having an electronic element and a controlled element deposited thereon via the production
system shown in Fig. 1; and
[0022] Figs. 4-9 are views of a sequential deposition of materials on a portion of
substrate in Fig. 1 to form electronic elements thereon via the production system shown in Fig. 1.
DETAILED DESCRIPTION OF THE INVENTION
[0023] The present invention is an electronic device that includes one or more electronic
elements deposited on a substrate for controlling one or more controlled elements that may be
separate from or an integral part of the electronic device and a method of manufacture thereof.
In the following description, the electronic device described is an active matrix backplane having
an array of organic light emitting diodes (OLEDs) which are deposited on the active matrix
backplane and which are selectively controlled thereby. However, this is not to be construed as
limiting the invention since any type of electronic element, such as a thin film transistor, a diode,
a capacitor or a memory element, can be formed on the substrate for controlling any type of
controlled element that may, or may not, be formed on the substrate. The present invention will
now be described with reference to the accompanying figures where like reference numbers
correspond to like elements.
[0024] „ With reference to Fig. 1, an exemplary production system 2 for producing an
electronic device in accordance with the present invention, e.g., an active matrix backplane
having OLEDs thereon, includes a plurality of vacuum vessels connected in series. The plurality
of vacuum vessels includes a plurality of deposition vacuum vessels 4, an annealing vacuum
vessel 20 and a test vacuum vessel 22. Each deposition vacuum vessel 4 includes a deposition
source 8 that is charged with a desired material to be deposited onto a substrate 10 via a
shadowmask 12 which is also positioned in the deposition vacuum vessel 4.
[0025] Each shadowmask 12-1 - 12—12 includes a pattern of apertures 14, e.g., slots,
holes, etc., formed in a sheet 16. Fig. 2 shows a view of shadowmask 12-1 from the
perspective of deposition source 8-1 of deposition vacuum vessel 4-1.The pattern of apertures
14 formed in sheet 16 of each shadowmask 12-1 - 12-12 corresponds to a desired pattern of
material to be deposited on substrate 10 from deposition sources 8-1 - 8-12 in deposition vacuum
vessel 4-1 - 4-12, respectively, as substrate 10 is advanced through each deposition vacuum
vessel 4-1 - 4-12.
[0026] In the embodiment of production system 2 illustrated in Fig. 1, vacuum vessels 4-
1 - 4-6 are utilized for depositing materials on substrate 10 to form one or more electronic
elements on substrate 10. Each electronic element can be a thin film transistor (TFT), a diode, a
memory element or a capacitor. For purpose of the following description, the one or more
electronic elements will be described as a matrix of TFTs. However, this is not to be construed
as limiting the invention. Vacuum vessels 4-7 - 4-11 are utilized for depositing materials on
substrate 10 that form one or more controlled elements, e.g., OLEDs, that can be controlled by
the TFT matrix deposited in deposition vacuum vessels 4-1 - 4-6. Deposition vacuum vessel 4-
12 is utilized for depositing a protective seal over substrate 10 to protect the TFT matrix and the
controlled elements deposited thereon from moisture and undesirable foreign particles, such as
dust, dirt, and the like. If the one or more electronic elements deposited in deposition vacuum
vessels 4-1 - 4-6 are to be utilized to control controlled elements not deposited on substrate 10 in
vacuum vessels 4-7 - 4-11, these vacuum vessels 4-7 - 4-11 can be omitted and deposition
vacuum vessel 4-12 can be positioned to receive substrate 10 when it is advanced from test
vacuum vessel 22. Alternatively, vacuum vessels 22 and 4-7 — 4-12 can be omitted and a storage
vessel 39 can be positioned to receive substrate 10 when it is advanced from anneal vacuum
vessel 20. For purpose of illustration, deposition vacuum vessels 4-7 - 4-11 will be described as
depositing the materials necessary to form OLEDs on substrate 10. However, this is not to be
construed as limiting the invention. In addition, the number, purpose and arrangement of
vacuum vessels 4, 20 and 22 is not to be construed as limiting the invention since such number,
purpose and arrangement of vacuum vessels 4, 20 and 22 can be modified as needed by one of
ordinary skill in the art for depositing one or more materials required for a particular application.
[0027] Anneal vacuum vessel 20 is positioned to receive substrate 10 when it is advanced
from deposition vacuum vessel 4-6. Anneal vacuum vessel 20 includes heating elements 24
which are utilized to heat the materials deposited on substrate 10 in deposition vacuum vessels
4-1 - 4-6 to a suitable annealing temperature. After annealing, substrate 10 is advanced into test
vacuum vessel 22 which includes a probe assembly 26 having probes (not shown) which can be
moved into contacting or non-contacting relation, as required, with the TFT matrix deposited on
substrate 10 for testing by test equipment 28.
{0028] When testing of the TFT matrix on substrate 10 in test vacuum vessel 22 is
complete, substrate 10 is advanced through deposition vacuum vessels 4—7 - 4-12 where the
materials forming the OLEDs are deposited on the TFT matrix and the seal coat is deposited over
the TFT matrix and'OLEDs.
[0029] Each vacuum vessel 4, 20 and 22 is connected to a source of vacuum (not shown)
for establishing a suitable vacuum therein. More specifically, the source of vacuum establishes a
suitable vacuum in deposition vacuum vessels 4—1 - 4-12 to enable a charge of desired material
positioned in deposition sources 8-1 - 8-12 to be deposited on substrate 10 in a manner known in
the art, e.g., sputtering, vapor phase deposition, etc., through the apertures 14 of the sheets 16 of
shadowmasks 12-1-12-12.
[0030] In the following description of exemplary production system 2 , substrate 10 will
be described as being a continuous flexible sheet which is initially disposed on a dispensing reel
34 that dispenses substrate 10 into deposition vacuum vessel 4-1. Dispensing reel 34 is
positioned in a preload vacuum vessel 35 which is connected to a source of vacuum (not shown)
for establishing a suitable vacuum therein.. However, production system 2 can be configured to
continuously process a plurality of individual substrates 10. Each deposition vacuum vessel 4
includes supports or guides 36 that avoid sagging of substrate 10 as it is advanced through
deposition vacuum vessels 4-1—4-12.
[0031] In operation of production system 2, the material positioned in each deposition
source 8-1 - S-12 is deposited on substrate 10 in the presence of a suitable vacuum as substrate
10 is advanced through deposition vacuum vessel 4-1 - 4-12 whereupon plural progressive
patterns are formed on substrate 10. More specifically, substrate 10 has plural portions that are
positioned for a predetermined interval in each vacuum vessel 4, 20 and 22. During this
predetermined interval, material is deposited from one or more of the deposition sources 8 onto
the'portion of substrate 10 positioned in the corresponding deposition vacuum vessel 4, the
materials deposited on the portion of substrate 10 positioned in anneal vacuum vessel 20 are
annealed and the TFT matrix deposited on the portion of the substrate 10 positioned in test
vacuum vessel 22 is tested. After this predetermined interval, substrate 10 is step advanced
whereupon the plural portions of substrate 10 are advanced to the next vacuum vessel 4, 20 or 22
in series for additional processing, as applicable. This step advancement continues until each
portion of substrate 10 has passed through all of vacuum vessels 4, 20 and 22. Thereafter, each
portion of substrate 10 exiting deposition vacuum vessel 4-12 is separated from the remainder of
substrate 10 by cutter 36 whereafter this cut portion of substrate 10 is stored flat on a suitable
storage means 38 positioned in a storage vacuum vessel 39. Alternatively, each portion of
substrate 10 exiting deposition vacuum vessel 4-12 is received on a take-up reel (not shown)
positioned in a storage vacuum vessel 39. Storage vacuum vessel 39 is connected to a source of
vacuum (not shown) for establishing a suitable vacuum therein.
[0032] The description of substrate 10 as being a continuous flexible sheet is not to be
construed as limiting the invention since substrate 10 can also be rigid and/or of any desired size
or shape, e.g., one or more individual sheets, that can be positioned concurrently in one or more
vacuum vessels 4, 20 and 22. For example, substrate 10 can be rigid and in the form of an
elongated rectangle that can be positioned in one or more vacuum vessels 4, 20 and 22.
[0033] Next, a sequence of steps utilized to form an active matrix OLED display will be
described with reference to Figs. 3-9 and with continuing reference to Fig. 1.
[0034] As shown in Fig. 3, substrate 10 includes an electrically conductive layer 50
having an insulator 52 on one surface thereof. A portion of substrate 10 is fed into deposition
vacuum vessel 4-1 with electrical insulator layer 52 facing deposition source 8-1. In this
exemplary deposition sequence, deposition 8-1 source is charged with a semiconductor material
54. This semiconductor material 54 is deposited by deposition source 8-1 on the surface of
electrical insulator layer 52 opposite electrically conductive layer 50 through shadowmask 12-1.
Fig. 4 shows an isolated view of the portion of substrate 10 that received the deposit of
semiconductor material 54 on the surface of electrical insulator 52 to form pairs of transistors 70
and 74, shown best in Fig. 7.
[0035] The alignment of each shadowmask 12 to the portion of substrate 10 positioned in-
the corresponding deposition vacuum vessel 4 is critical. To this end, the portion of substrate 10
positioned in each deposition vacuum vessel 4 can include one or more fiducial marks or points
(not shown) that an ah'gning means (not shown) positioned in each deposition vacuum vessel 4
can utilize for positioning the corresponding shadowmask 12 relative to the portion of substrate
10 received in the deposition vacuum vessel 4. Each aligning means can include optical or
mechanical means for determining a position of the corresponding shadowmask to the fiducial
marks on the portion of substrate 10 received in the corresponding deposition vacuum vessel 4.
Each aligning means can also include drive means coupled to the corresponding shadowmask to
perform x and y positioning of the shadowmask 12 relative to the one or more fiducial marks on
the portion of substrate 10. This drive means can also include means for moving the
shadowmask 12 into contact with the portion of substrate 10 for deposition of material thereon.
Once the deposition of material onto substrate 10 in each deposition vacuum vessel 4 is
complete, the drive means can separate the corresponding shadowmask 12 from the portion of
substrate 10 received therein. This separation avoids shadowmask 12 from contacting the
materials deposited on substrate 10 as substrate 10 is advanced into the next vacuum vessel 4, 20
or 22.
[0036] After deposition of semiconductor material 54 on electrical insulator layer 52 in
deposition vacuum vessel 4-1, the portion of substrate 10 in deposition vacuum vessel 4-1 is
advanced into deposition vacuum vessel 4-2. Deposition source S-2 in deposition vacuum vessel
4-2 is charged with a semiconductor compatible conductive material 56 which is deposited on
the portion of substrate 10 in deposition vacuum vessel 4-2 via shadowmask 12-2 to form the
partem of conducting material 56 shown in Fig. 5.
[0037] If substrate 10 has an elongated form, whereupon portions of substrate 10 can be
positioned in two or more deposition vacuum vessels 4, 20 or 22, advancing the portion of
substrate 10 from deposition vacuum vessel 4-1 into deposition vacuum vessel4-2 advances
another portion of substrate 10 into deposition vacuum vessel 4-1. In this manner, materials in
different deposition vacuum vessels 4 can be deposited on different portions of substrate 10 at or
about the same time. Similarly, annealing and testing of electronic elements deposited on
various portions of substrate 10 can occur at or about the same time as one or more materials are
being deposited on other portions of substrate 10. Thus, the exemplary production system 2
shown in Fig. 1 has the advantage of being able to simultaneously process plural portions of
substrate 10 thereby maximizing the rate each portion of substrate 10 is processed to produce a
completed electronic device.
[0038] As shown in Figs. 3 and 5, a portion of conducting material 56 is deposited
overlapping opposite sides or opposite ends of semiconductor material portions 54-1 - 54-2 to
define source structures 58-1 and 58-2 and drain structures 60-1 - 60-2 for transistors 74 and 70,
respectively.
[0039] Electrically conductive layer 50 of substrate 10 can be utilized as a power or
ground bus depending on the application. To this end, as shown in Fig. 3, conducting material
56 forming each source 58 can be in electrical communication with electrically conductive layer
50 of substrate 10 by way of a through-hole or via 63 in electrical insulator layer 52. The via 63
utilized to connect each source 58 to electrically conductive layer 50 can be formed in electrical
insulator layer 52 prior to introducing substrate 10 into any vacuum vessels 4,20 or 22.
[0040] In the foregoing description, each source 5S is described as being connected to
electrically conductive layer 50 by way of via 63 in electrical insulator layer 52. However, each
source 58 can be connected to electrically conductive layer 50 by way of two or more vias 63.
Alternatively, depending on the application, each drain 60 can be connected to electrically
conductive layer 50 by way of two or more vias 63 in electrical insulator layer 52 while each
source 58 remains electrically isolated from electrically conductive layer 50 by electrical
insulator layer 52. The decision to connect each source 58 or each drain 60 to electrically
conductive layer 50 by way of one or more vias 63 in electrical insulator layer 52 is a decision
that can be readily made by one of ordinary skill in the art depending upon, among other things,
the intended use of the electronic elements formed on substrate 10 and/or the intended use of
electrically conductive layer 50 as a power bus or a ground bus.
[0041] When the deposition of conducting material 56 is complete, the portion of
substrate 10 in deposition vacuum vessel 4-2 is advanced to deposition vacuum vessel 4-3.
Deposition source 8-3 is charged with an insulating material 62 which is deposited on the portion
of substrate 10 positioned in deposition vacuum vessel 4-3 through shadowmask 12-3 in the
pattern shown in Fig. 6.
[0042] As shown in Figs. 3 and 6, insulating material 62 can cover all or part of each
source 58 and each drain 60 formed by the deposition of conducting material 56 over
semiconductor material 54. In addition, insulating material 62 can also cover portions of
conducting material 56 that are to comprise a power bus 64 for each source 58-2.
[0043] Next, the portion of substrate 10 positioned in deposition vacuum vessel 4-3 is
advanced to deposition vacuum vessel 4-4. Deposition source 8-4 is charged with a conducting
material 66 which is deposited on the portion of substrate 10 positioned in deposition vacuum
vessel 4-4 through shadowmask 12-4 in the pattern shown in Fig. 7. The conducting material
portion 66-4 overlapping the rightward extension of each source 58-2 and the conducting
material 56 in alignment with the portion of conducting material 66-4 completes the power bus
64 for the source 58-2 and for any like sources (not shown) in the same column as source 58-2.
The conducting material portion 66-3 to the left of each source 58-2 forms a column bus 68 for
source 58-1 and for any like sources (not shown) in the same column as source 58-2. The
conducting material portion 66-2 is connected to drain 60-1 and covers a portion of the insulating
material 62 that partially covers source 58-2 and drain 60-2 and is in spaced parallel relation with
semiconducting material 54-2. Conducting material portion 66-2 defines a gate structure 69 that
together with source 58-2, drain 60-2, insulating material portion 62-2 and semiconductor
material 54-2 forms transistor 70.
[0044] A conducting material portion 66-1 deposited above each transistor 70
overlapping the horizontally oriented insulating material portion 62-1 forms a row select bus 72.
More specifically, conducting material portion 66-1 above each transistor 70 forms with source
58-1, drain 60-1, semiconductor material 54-1 and the insulating material 62-1 therebetween a
transistor 74 that controls the conductive state of transistor 70 having its gate structure 69
coupled to drain 60-1 of transistor 74. For example, transistor 74-1 controls the conduction state
of transistor 70-1, and transistor 74-2 controls the conduction state of transistor 70-2.
[0045] In Fig. 7, row select bus 72 below each illustrated transistor 70 is utilized to select
the row of transistors 74 below those shown in Fig. 7. To this end, it is to be appreciated that
Fig. 7 only shows an isolated portion of substrate 10 having only portions of the materials
utilized to form two pairs of transistors 74 and 70. The materials utilized to form other pairs of
transistors 74 and 70 of the active matrix have been omitted from Figs. 4-9 for simplicity of
illustration.
[0046] With continuing reference to Fig. 7, when row select bus 72 above transistors 70'
1 and 70-2 is selected, transistor 70-1 and 70-2 are responsive to the voltages applied to the
column buses 68 associated with each transistor 74-1 and 74-2, respectively. Thus, when ar
appropriate voltage is applied to row select bus 72 above the illustrated transistors 70, the voltag€
applied to sources 58-1 of transistor 74-1 and 74-2 via their corresponding column buses 68
control the amount of current flowing in transistor 70-1 and 70-2, respectively. Thus, by simpl>
controlling the voltage applied to each column bus 68 when an appropriate voltage is applied to
the corresponding row bus, the amount of current flowing in each transistor 70 can be selectively
controlled.
[0047] It is to be appreciated that each instance of conducting material portion 66, source
58, drain 60 and insulating material portion 62 defines a capacitor. More specifically,
conducting material portion 66 defines a first plate of a capacitor which insulating material
portion 62 holds in spaced relation to source 58 and drain 60 which, individually or collectively,
define a second plate of the capacitor. If the leakage current thereof is sufficiently low, each
capacitor can be utilized as a binary memory element.
[0048] With reference to Fig. 8, and with ongoing reference to Figs. 1 and 3-7, after the
deposition of conducting material 66 is complete, the portion of substrate 10 in deposition
vacuum vessel 4-4 is advanced into deposition vacuum vessel 4-5. Deposition source 8-5 is
charged with an insulating material 76 which is deposited over substantially all of the material
previously deposited on substrate 10 in the pattern shown in Fig. 8. In this pattern, however,
portions 78-1 and 78-2 of drains 60-2 of transistor 70-1 and 70-2, respectively, are not covered
by insulating material 76. In addition, the input ends of each power bus 64 and the input end of
each column bus 68 are not covered by insulating material 76. Still further, the input end (not
shown) of each row bus 72 is also not covered by insulating material 76. In the embodiment
shown in Figs. 4-9, the input end of each power bus 64 and the input end of each column bus 68
are at the top of the figure and the input end (not shown) of each row select bus 72 is to the right
of the figure.
[0049] When the deposition of insulating material 76 is completed, the portion of
substrate 10 in deposition vacuum vessel 4-5 is advanced into deposition vacuum vessel 4-6.
Deposition source 8-6 is charged with a conducting material 80 that is deposited on substrate 10
through shadowmask 12-6 in the pattern shown in Fig. 9. As shown in Fig. 3, each portion 78
where insulating material 76 is not deposited in deposition vacuum vessel 4-5 defines a via
through which conducting material 80 makes contact with drain 60-2 of the corresponding
transistor 70. Conducting material 80 deposited above each transistor 70 defines an output pad
84, the voltage of which can be controlled by the associated pairs of transistors 70 and 74, e.g.,
transistors 70-1 and 74-1..
[0050] After conducting material 80 has been deposited, the portion of substrate 10 is
advanced from deposition vacuum vessels 4-6 into anneal vacuum vessel 20 where one or more
heating elements 24 are controlled to provide an appropriate annealing heat to the materials
deposited on the portion of substrate 10 in deposition vacuum vessel 4-1 — 4-6.
[0051] The above described deposition steps and materials and the circuit produced
thereby are for the purpose of illustration and are not to be construed as limiting the present
invention since the deposition sequence, the deposition materials and/or the circuit produced
thereby are matters of design choice that can be made by one of ordinary skill in the art. For
example, the source and drain structures of each transistor can be reversed, the configuration and
interconnections of the TFTs forming the circuit can be modified to suit a particular application,
each TFT can be addressed individually or groups of TFT's can be addressed in any desired
pattern, and so forth.
[0052] Each column bus 68 and row select bus 52 can be coupled to suitable row and
column control logic (not shown) which can be formed on substrate 10 at the same time each
transistor 70 and each transistor 74 is formed thereon. Specifically, each shadowmask 12 can
include an appropriate pattern of apertures 14 in sheet 16 thereof which enable the formation on
substrate 10 of appropriate row and column control logic at the same time each transistor 70 and
each transistor 74 are formed thereon.
[0053] Depending upon the intended use of substrate 10 having plural thin film
transistors 70 and 74 formed thereon, the annealing process may be the last step that the portion
of substrate 10 receives. If so, the output of anneal vacuum vessel 20 is coupled to storage
means 38 winch stores the portion of substrate 10 for subsequent processing or use. However, if
the portion of substrate 10 is to be exposed to additional processing steps, e.g., to form OLEDs
on output pads 84, the portion of substrate 10 can be advanced into test vacuum vessel 22 for
testing thereof.
[0054] In test vacuum vessel 22, the probes of probe assembly 26 are moved into
contacting or non-contacting relation, as required, with the various buses 64, 68 and 72 and
output pads 84. Thereafter, under the control of test equipment 28 via probe assembly 26, the
transistor pair 70 and 74 associated with each output pad 84 can be tested.
[0055] If such test fails, the portion of substrate 10 failing the test is identified or
designated accordingly, and, preferably, receives no further processing. However, if such test
passes, the portion of substrate 10 can be subjected to further processing as shown in Fig. 1.
[0056] In the case where each output pad receives depositions to form an OLED, the
portion of substrate 10 is advanced from test vacuum vessel 22 into deposition vacuum vessel 4-
7. Deposition source 8-7 is charged with a hole transport material such as NPB (C44H32N2)
which is deposited through shadowmask 12-7 to form a hole transport layer 90 on each output
pad 84 as shown in Fig. 3.
[0057] After deposition of hole transport layer 90, the portion of substrate 10 is advanced
into deposition vacuum vessel 4-8. Deposition source 8-8 comprises two separately controllable
deposition sources for depositing an emitter layer 92 comprised of an emitter material deposited
by one deposition source and a dopant deposited by the other deposition source. In the case
where deposition source 8-8 is utilized to form a red light emitting diode, the emitter material
can be 98% - 99.5% by weight of DCM (C23H21N3O) and 2% - 0.5% by weight of DMQA
(C22H16N2O3). During deposition, deposition source 8-8 is controlled to deposit the emitter
material and the dopant in the foregoing percentages to form emitter layer 92 on the hole
transport layer 90 of ever}' third output pad 84.
[0058] After emitter layer 92 is deposited to a sufficient extent, deposition source 8-8 is
controlled to terminate the deposition of dopant material while continuing the deposition of
emitter material. This continued deposition of emitter material absent dopant forms an electron
transport layer 94 on the just deposited emitter layer 92 as shown in Fig. 3.
[0059] When the deposition of materials in deposition vacuum vessel 4-S is complete, the
portion of the substrate is sequentially stepped through deposition vacuum vessels 4-9 and 4-10
where deposition sources 8-9 and S-10, respectively, deposit green and blue emitter layers 92 and
electron transport layers 94 in the manner discussed above to form a plurality of a color triads on
the portion of substrate 10. Each color triad includes separately controllable red, green and blue
OLEDs.
[0060] To form green OLEDs, deposition source 8-9 co-deposits emitter material, such
as Alq3 (C27H18AIN3O3), and dopant, such as Coumarin 153 (C16H14F3O2), to form the emitter
layers 92 of the green light emitting diodes and deposits only the emitter material to form the
electron transport layer 94 of the green light emitting diodes. To form the blue OLEDs,
deposition source 8-10 co-deposits an emitter material, such as PPD (C52H36N2), and dopant,
such as perylene (C20H12), to form the emitter layer 92 of the blue light emitting diodes and
deposits only the emitter material to form the electron transport layer 94 of the blue light
emitting diodes.
[0061] After each layer 90, 92 and 94 has been deposited on the output pads 84 to form
the color triads discussed above, the portion of substrate 10 is advanced into deposition vacuum
vessel 4-11. Deposition source 8-11 is charged with a conductive material 96 which is deposited
through shadowmask 12-11 onto the layer of electron transport material 94 of each OLED. More
preferably, providing conductive material 96 does not contact any of the conducting material 80
forming each output pad 84, conducting material 96 is deposited as a contiguous layer over all of
the OLEDs formed on the portion of substrate 10. In this manner, it is only necessary to contact
tins contiguous layer of conducting material at a few points in order to form a cathode 98 for all
of the OLEDs formed on the portion of substrate 10. In tins configuration, the layer of
conductive material 96 acts as a common cathode structure for all of the OLEDs formed on the
portion of substrate 10 while the output pad 84 associated with each OLED operates as an anode
structure for the OLED structure associated therewith. If conductive material 96 is only
deposited over the OLED structure associated with each output pad 84, it will be necessary to
connect each deposit of conducting material 96 to an appropriate cathode bias source.
[0062] After conducting material 96 has been deposited, the portion of substrate 10 is
advanced from deposition vacuum vessel 4-11 to deposition vacuum vessel 4-12. Deposition
source 8-12 is charged with a sealing material 98 which is deposited through a shadowmask 12-
12 onto substantially all of the exposed surface of the materials deposited on the portion of
substrate 10. To enable electrical contact to be made with buses 64, 68, 72 and the one or more
deposits of conducting material 96, sealing material 98 is not deposited on the input ends of
buses 64, 68, 72 nor is sealing material 98 deposited on all or part of the one or more deposits of
conducting material 96. Sealing material 98 is configured to avoid moisture and particulate
matter from contacting any of the deposited materials other than those portions of the deposited
materials that have been intentionally left exposed.
[0063] Alternatively, deposition vacuum vessel 4-12 can be considered to be
representative of a plurality of series connected deposition vacuum vessels disposed between
deposition vacuum vessel 4-11 and storage vacuum vessel 39. Each of these series connected
deposition vacuum vessels can include a deposition source 8 charged with a suitable material
which is deposited through a shadowmask 12 on one or more portions of substrate 10 as it is
advanced therethrough to form a protective seal thereover. A system which can be adapted for
use in the embodiment of production system 2 shown in Fig. 1 is the Guardian tool, designed
by Vitec Systems, Inc. of San Jose, California. This system includes series connected deposition
vacuum vessels for depositing a liquid monomer on substantially all of the exposed surfaces of
materials deposited on the portion of substrate 10 to create a microscopically flat surface. The
liquid monomer is then hardened (polymerized) into a solid polymer film. A first layer of
transparent ceramic is then deposited to create a first barrier, and a second polymer layer is
applied to protect the barrier and create a second flat surface. This barrier/polymer combination
is repeated as necessary until a desired level of impermeability is achieved.
[0064] In the foregoing description, it has been assumed that substrate 10 is a continuous
sheet. After sealing material 98 is deposited, the portion of substrate 10 in deposition vacuum
vessel 4-12 is advanced therefrom whereupon cutter 36 cuts the portion of substrate 10 from the
remainder of substrate 10. Thereafter, the cut portion of substrate 10 is stored in storage means
38 of storage vacuum vessel 39 for subsequent processing or use. Alternatively, cutter 36 can be
replaced with a take-up reel (not shown) which receives substrate 10 as it is advanced from
deposition vacuum vessel 4-12.
[0065] The deposition of materials through shadowmasks 12 described above is for the
purpose of illustrating the invention and is in no way to be construed as limiting the invention.
As would be apparent to one of ordinary skill in the art, more than one shadowmask 12 may be
required in a single deposition vacuum vessel 4 in order to form the pattern described. For
example, in order to deposit insulating material 76 in the manner shown in Fig. 8, two or more
shadowmasks 12 may be employed, either simultaneously or one at a time, to deposit the pattern
of insulating material 76 shown. To this end, deposition vacuum vessel 4-5 may include means
(not shown) for exchanging the various shadowmasks needed to deposit the pattern of insulating
material 76 shown. Alternatively, deposition vacuum vessel 4-5 can be considered to be
representative of a plurality of series connected deposition vacuum vessels disposed between
deposition vacuum vessels 4-4 and 4-6. Each of these series connected deposition vacuum
vessels can include a deposition source 8 charged with insulating material 76 which is deposited
through a shadowmask 12 on a select portion of substrate 1.0 as it is advanced therethrough.
Collectively, the deposition of insulating material 76 by these series connected deposition
vacuum vessels would produce the pattern of insulating material 76 shown in Fig. 8. Similarly,
the deposition of conducting material 66 to form conducting material portions 66-1 - 66-4 may
require a plurality of shadowmasks 12, each having a different pattern of apertures 14 therein,
interchangeably positionable in deposition vacuum vessel 4-4. Alternatively, deposition vacuum
vessel 4-4 can be considered to be representative of a plurality of series connected deposition
vacuum vessels disposed between deposition vacuum vessels 4-3 and 4-5. Each of these series
connected deposition vacuum vessels can include a deposition source 8 charged with conducting
material 66 which is deposited through one of the shadowmasks on a select portion of substrate
10 as it is advanced therethrough. Collectively, the deposition of conducting material 66 by
these series connected deposition vacuum vessels would produce the pattern of conducting
material 66 shown in Fig. 7. Similar comments apply in respect of any other shadowmask 12
where the volume of apertures 14 therein adversely affects the structural rigidity of the sheet 16
forming the shadowmask 12.
[0066] As can be seen from the foregoing, the present invention enables formation of one
or more electronic elements on a substrate by successive deposition of materials on the substrate.
Importantly, each electronic element is formed without the need for subtractive processing, i.e.,
the removal of material. This represents an important improvement over the prior art in that the
formation of these electronic elements can occur by a continuous sequence of depositions
whereby the throughput rate of producing substrates having such electronic elements formed
thereon is substantially improved. In addition, the present invention enables certain controlled
elements, such as OLEDs, to be deposited on the electronic elements in. order to form complete
systems, such as an array of color triads for a display.
[0067] Electronic elements formed on substrate 10 in the foregoing manner can be
utilized for numerous applications other than OLEDs for forming pixels of a display. For
example, the electronic elements deposited on the substrate can be used for large area arrays for
acoustic or x-ray imaging, arrays for optical image processing, high voltage arrays for plasma
display panels and large area adaptive and learning networks. In addition, substrate 10 is not
limited to having an electrical insulating layer 52 overlaying an electrically conductive layer 50.
To this end, substrate 10 can be formed from paper, plastic or any other material upon which
suitable materials can be deposited.
[0068] The invention has been described with reference to one preferred embodiment.
Obvious modifications and alterations will occur to others upon reading and understanding the
preceding detailed description. For example, the described sequence can be modified as
necessary to suit a particular application. To this end, controlled elements can be deposited first
followed by the deposit of the electronic elements. Accordingly, the invention is not in any way
to be construed as being limited by the foregoing description, but, rather, it is intended that the
invention be construed as including all such modifications and alterations insofar as they come
within the scope of the appended claims or the equivalents thereof^
WE CLAIM
1. A method of forming an electronic device comprising the steps of:
(a) advancing a substrate (10) through a plurality of series connected deposition
vacuum vessels (4), with each deposition vacuum vessel (4) having at least
one material deposition source (8) and a shadowmask (12) positioned
therein; and
(b) depositing on the substrate (10) in the presence of a vacuum in each
deposition vacuum vessel (4) the material (54, 56, 62, 66, 76, 80, 90, 92, 94,
96, or 98) from the at least one material deposition source (8) positioned in
the deposition vacuum vessel (4) through the shadowmask (12) positioned
therein to form on the substrate (10) a circuit comprised of an array of
electronic elements (70, 72), wherein the physical layout of the circuit is
formed solely by the successive deposition of materials on the substrate (10).
2. The method as claimed in claim 1, wherein the substrate (10) is at least one
of (i) electrically conductive, (ii) flexible and (iii) transparent.
3. The method as claimed in claim 2, wherein, when the substrate (10) is
electrically conductive, an electrical insulator (52) separates the circuit from
the substrate (10).
4. The method as claimed in claim 1, wherein the substrate (10) is an elongated
sheet that is advanced along its length through the plurality of deposition
vacuum vessels (4) whereupon at least one part of the substrate (10)
advances sequentially through each deposition vacuum vessels (4) and the
one part of the substrate (10) receives deposits of materials (54, 56, 62, 66,
76, 80, 90, 92, 94, 96, or 98) from the deposition sources (8) positioned in
the deposition vacuum vessels (4).
5. The method as claimed in claim 4, wherein the substrate (10) defines along
its length a plurality of spaced parts which are advanced through the plurality
of vacuum vessels (4) whereupon each part receives a deposit of material
(54, 56, 62, 66, 76, 80, 90, 92, 94, 96 or 98) from the deposition source (8)
positioned in each vacuum vessel (4).
6. The method as claimed in claim 1, wherein the electronic elements are thin
film transistors (TFT) (70, 74); and step (b) comprises the steps of:
depositing a semiconducting material (54) of each TFT (70, 74); depositing a
first conductive material (56) in a manner to form with the semiconducting
material (54) of each TFT (70, 74) a source (58) and a drain (60) therefore;
depositing a first, gate insulator (62) on at least part of each of the
semiconducting material (54), the source (58) and the drain (60) of each TFT
(70, 74); depositing a second conductive material (66) on at least part of the
gate insulator (62) of each TFT (70, 74) in a manner to form a gate (69)
therefor; and depositing a second insulator (76) over the second conductive
(66) material of each TFT (70, 74) in a manner whereupon at least a part of
the first conductive material (56) is exposed through the second insulator
(76).
7. The method as claimed in claim 6, wherein step (b) comprises depositing a
third conductive material (80) to form an output pad (84) for at least one TFT
(70, 74), wherein the output pad (84) covers the second insulator (76) and
the exposed part of the first conductive material (56) so that the third
conductive material (80) is in electrical communication with the exposed part
of the first conductive material (56).
8. The method as claimed in claim 6, wherein the first conductive material (56)
is deposited in a manner to form with one of the source (58) and the drain
(60) of at least one TFT (70, 74) a first address bus (68); the second
conductive material (66) is deposited in a manner to form with the other of
the source (58) and the drain (60) of the at least one TFT (70, 74) a second
address bus (72); and each address bus (68, 72) is individually addressable.
9. The method as claimed in claim 6, wherein; TFTs (70, 74) in each column or
row of TFTs (70, 74) are connected to a common address bus (68, 72) of the
circuit; and each address bus (68, 72) is individually addressable.
10.The method as claimed in claim 6, wherein the semiconducting material (54)
is cadmium selenide (CdSe).
11.The method as claimed in claim 6, wherein the first insulator (62), the second
conductive material (66) and the second insulator (76) are deposited in a
manner that leaves at least part of the first conductive material (56) forming
one of the source (58) and the drain (60) of each TFT (70,74) exposed.
12.The method as claimed in claim 1, wherein the electronic elements are thin
film transistors (TFTs) (70, 74); and the circuit formed in step (b) comprises a
plurality of deposited light emitting elements (90, 92, 94), with the TFTs (70,
74) disposed between the substrate (10) and the light emitting elements (90,
92, 94).
13.The method as claimed in claim 12, wherein step (b) comprises the steps of:
depositing a hole transport material (90) of each light emitting element (90,
92, 94) on the substrate in electrical communication with a power terminal
(58, or 60) of the TFT (70, 74) associated with the light emitting element;
depositing a light emitting material (92) of each light emitting element over at
least part of the hole transport material (90) in alignment with or adjacent to
the power terminal (58, or 60) associated with the TFT (70, 74) for the light
emitting element; depositing an electron transport material (94) of each light
emitting element over at least part of the light emitting material (92) of each
light emitting element; and depositing a conductive material (96) of each light
emitting element over at least part of the electron transport material (940
thereof.
14.The method as claimed in claim 13, wherein the conductive material (96) is
deposited substantially over the entire circuit.
15. The method as claimed in claim 13, wherein the plurality of light emitting
elements (90, 92, 94) is comprised of plural red, plural green and plural blue
light emitting elements.
16.The method as claimed in claim 1, wherein: the electronic elements are thin
film transistors (TFT) (70,74); and step (b) comprises the steps of: depositing
a layer of semiconductor material (54) on the substrate (10); depositing a
first layer of semiconductor compatible conductive material (56) relative to
the semiconductor material (54) and the substrate (10) in a manner to form
therewith a source (58) and drain (60) of each thin film transistor (70,74);
depositing a first insulator layer (62) relative to the semiconductor material
(54), the source (58) and the drain (60) in a manner to from therewith a gate
insulator; and depositing a second layer of conductive material (66) relative
to the gate insulator, the semiconductor material (54) the source (58) and
the drain (60) in a manner to form therewith a gate (69) of the thin film
transistor (70,74).
17.The method as claimed in claim 16, wherein step (b) comprises the steps of:
depositing a second insulator layer (76) relative to the second layer of
conductive material (66) and the first insulator layer (62) in a manner
whereupon at least part of the first layer of conductive material (56) is
exposed through a window (78) in the second insulator layer (76); and
depositing a third layer of conductive material (80) through the window (78)
in the second insulator layer (76) to form an output pad (84).
18. The method as claimed in claim 1, comprising the steps: testing (22) the
array of electronic elements in the presence of a vacuum; and as a function
of such test passing or failing, designating the substrate (10) accordingly.



An electronic device is formed from electronic elements (70, 74) deposited on a substrate (10). The electronic
elements are deposited on the substrate by advancing the substrate through a plurality of deposition vacuum vessels (4-1 to 4-12),
with each deposition vacuum vessel having at least one material deposition source (8-1 to 8-12) and a shadowmask (12-1 to 12-12)
positioned therein. The material from at least one material deposition source (8) positioned in each deposition vacuum vessel (4) is
deposited on the substrate (10) through the shadowmask (12) positioned in the deposition vacuum vessel (4) to form on the substrate
(10) a circuit comprised of an array of electronic elements. The circuit is formed solely by the successive deposition of materials on
the substrate (10).

Documents:

1965-kolnp-2004-abstract.pdf

1965-KOLNP-2004-CLAIMS 1.1.pdf

1965-kolnp-2004-claims.pdf

1965-KOLNP-2004-CORRESPONDENCE 1.1.pdf

1965-kolnp-2004-correspondence 1.2.pdf

1965-kolnp-2004-correspondence.pdf

1965-kolnp-2004-description (complete).pdf

1965-kolnp-2004-drawings.pdf

1965-kolnp-2004-examination report 1.1.pdf

1965-kolnp-2004-examination report.pdf

1965-kolnp-2004-form 1.pdf

1965-kolnp-2004-form 13 1.1.pdf

1965-kolnp-2004-form 13.pdf

1965-kolnp-2004-form 18 1.1.pdf

1965-kolnp-2004-form 18.pdf

1965-kolnp-2004-form 2.pdf

1965-kolnp-2004-form 26 1.1.pdf

1965-kolnp-2004-form 3 1.1.pdf

1965-kolnp-2004-form 3.pdf

1965-kolnp-2004-form 5 1.1.pdf

1965-kolnp-2004-form 5.pdf

1965-KOLNP-2004-FORM-27-1.pdf

1965-KOLNP-2004-FORM-27.pdf

1965-kolnp-2004-granted-abstract.pdf

1965-kolnp-2004-granted-claims.pdf

1965-kolnp-2004-granted-description (complete).pdf

1965-kolnp-2004-granted-drawings.pdf

1965-kolnp-2004-granted-form 1.pdf

1965-kolnp-2004-granted-form 2.pdf

1965-kolnp-2004-granted-specification.pdf

1965-kolnp-2004-pa.pdf

1965-kolnp-2004-reply to examination report 1.1.pdf

1965-kolnp-2004-reply to examination report.pdf

1965-kolnp-2004-specification.pdf


Patent Number 243336
Indian Patent Application Number 1965/KOLNP/2004
PG Journal Number 41/2010
Publication Date 08-Oct-2010
Grant Date 06-Oct-2010
Date of Filing 21-Dec-2004
Name of Patentee ADVANTECH GLOBAL, LTD
Applicant Address COMMENCE CHAMBERS, PO BOX 2208, ROAD, TOWN TORTOLA, BRITISH VIRGIN
Inventors:
# Inventor's Name Inventor's Address
1 BRODY, THOMAS P 5823 KENTUCKY AVENUE, PITTSBURGH, PA 15232
2 MALMBERG, PAUL, R. 130 GORDON STREET, PITTSBURGH, PA 15218
3 STAPLETON, ROBERT, E. (DECEASED) N/A
PCT International Classification Number H01L
PCT International Application Number PCT/US2003/015682
PCT International Filing date 2003-05-19
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 10/255,972 2002-09-26 U.S.A.
2 60/386,525 2002-06-05 U.S.A.