Title of Invention

"SYNTHETIC STAPLE FIBER FOR AN AIR-LAID NONWOVEN FABRIC"

Abstract The present invention relates to a synthetic staple fiber for an air-laid nonwoven fabric, characterized in that it has a fiber length of 0.1 to 45 mm and a cross-sectional shape having 1 to 30 concave portions wherein the concave portion has a ratio (D/L) of the maximum depth (D) to the maximum opening width (L) in the range of 0.1 to 0.5. The above synthetic staple fiber exhibits good air opening characteristics and is suitable for producing an air-laid nonwoven fabric having excellent quality.
Full Text SPECIFICATION
SYNTHETIC STAPLE FIBERS FOR AN AIR-LAID NONWOVEN FABRIC
TECHNICAL FIELD
The present invention relates to synthetic staple
fibers for an air-laid nonwoven fabric. More
particularly, the present invention relates to synthetic
staple fibers for an air-laid nonwoven fabric which
exhibit a good air opening property and are appropriate
to produce an air-laid nonwoven fabric having excellent
quality.
BACKGROUND ART
Currently, nonwoven fabrics have been widely used in
fields of daily commodities, sanitary materials and
medical treatment materials. Moreover, in recent years,
a research on, and a development of, an air-laid nonwoven
fabric capable of being produced at a high speed, and
having excellent bulkiness, air-permeability and liquid
permeability have advanced. Many proposals have been
made for such air-laid nonwoven fabrics in which staple
fibers consisting of a synthetic resin, for example, a
polyolefin resin and a polyester resin and having
excellent handing property and mechanical properties are
used (e.g., Patent Reference 1, and the like).
A high air opening property is important to the
staple fibers for the air-laid nonwoven fabric, and thus
the quality of the resultant air-laid nonwoven fabric is
controlled by the opening property of the staple fibers.
For example, according to the investigation performed by
the inventors of the present invention, the staple fibers
for an air-laid nonwoven fabric having sheath layers
formed from a high density polyethylene and located at
the peripheral surfaces of the staple fibers, for
example, poly(ethylene terephthalate)/high density
polyethylene core-in-sheath type composite fibers and
polypropylene/high density polyethylene core-in-sheath
type composite fibers as described in Patent Reference 2
exhibit an improved high air opening property. In the
air laid web formed from the above-mentioned conjugate
staple fibers, the contents of unopened fiber bundles, in
each of which several tens of staple fibers are arranged
in parallel with each other, pill-like defects formed by
entanglement of staple fibers are low and thus the
resultant nonwoven fabric has an improved web quality
compared with conventional fabrics.
However, even when the staple fibers as disclosed in
the Patent Reference 1, and the conjugate fibers as
disclosed in Patent Reference 2, namely conjugate fibers
having high density polyethylene sheath components, are
employed, the resultant nonwoven fabric is unsatisfactory
in quality, because the water content, the individual
fiber thickness and crimping condition of the staple
fibers or the conjugate staple fibers influences on
generation of defects on the resultant nonwoven fabric,
and the generation of the defects has not yet been
sufficiently controlled.
Patent Reference 1: WO 97/48846
Patent Reference 2: Japanese Unexamined Patent
Publication (Kokai) No. 11-81116
DISCLOSURE OF THE INVENTION
(Problems to Be Solved by the Invention)
An object of the present invention is to provide
synthetic staple fibers for an air-laid nonwoven fabric,
having good air opening property and enabling a nonwoven
fabric having excellent quality to be produced, without
specifically limiting the type of the synthetic polymers
for forming the fibers, the individual fiber thickness,
the crimping conditions and the water content.
(Means for Solving the Problems)
In order to solve the above problems, the inventors
of the present invention have intensively carried out
investigations, while they have paid attention to the
cross-sectional profile of staple fibers. As a result,
the inventors of the present invention have found that
some types of staple fibers having specific crosssectional
profiles are hardly influenced by the water
content of the fibers, have a good air opening property
and enable an air-laid nonwoven fabric having an
excellent quality to be produced. The present invention
was completed on the basis of the finding. The inventors
of the present invention have further continued the
investigation, and found that the air opening property of
the staple fibers is affected by the thickness of the
fibers, the number of crimp of the fibers and the type of
the polymeric material from which the fibers are formed.
In this connection, it has been further found that the
above-mentioned various problems can be simultaneously
solved by appropriately establish the cross-sectional
profile of the staple fibers.
The synthetic staple fibers, of the present
invention, for an air-laid nonwoven fabric, which staple
fibers have a fiber length of 0.1 to 45 mm and a crosssectional
profile having 1 to 30 concavities each
satisfies the requirement; D/L = 0.1 to 0.5, wherein D
represents a largest distance between a tangent line
drawn to a pair of convexities from which an opening of
the concavity is defined, and a bottom of the concavity,
measured in a direction at right angles to the tangent
line, and L represents a distance between two points of
contact of the pair of convexities with the tangent line.
The synthetic staple fibers of the present
invention, for an air-laid nonwoven fabric, preferably
have a water content of 0.6% by mass or more but not more
than 10% by mass.
The synthetic staple fibers of the present
invention, for an air-laid nonwoven fabric, preferably
have a thickness of 5 dtex or less.
The synthetic staple fibers of the present
invention, for an air-laid nonwoven fabric, preferably
have a number of crimps of 0 to 5 crimps/25 mm or 15 to
40 crimps/25 mm.
In the synthetic staple fibers, of the present
invention, for an air-laid nonwoven fabric, preferably,
in each of the staple fibers, at least a portion of the
peripheral surface of the staple fiber is formed from at
least one member selected from the group consisting of
polyester resins, polyamide resins, polypropylene resins,
high pressure method low density polyethylene resins,
linear low density polyethylene resins and elastomer
resins.
The synthetic staple fiber, of the present
invention, for an air-laid nonwoven fabric optionally
further comprises at least one functional agent adhered
to the surface of the staple fiber, in an amount of 0.01
to 10% by mass on the basis of the mass of the staple
fiber.
In the synthetic staple fiber of the present
invention for an air-laid nonwoven fabric, the functional
agent is selected from the group consisting of deodorant
functional agents, antibacterial functional agents, flame
retardant functional agents and insect-repellent
functional agents.
(Effect of Invention)
An air-laid nonwoven fabric having few defects and
being excellent in quality can be obtained using the
synthetic staple fibers of the present invention even
with a high water content at which conventional staple
fibers are difficult to open. Moreover, according to the
present invention, even at small thickness, a high number
of crimps or a low number of crimps (including no crimp),
or, even in the presence of a resin or functional agent
having a high friction value and coated on the surfaces
of the staple fibers, the resultant synthetic staple
fibers can be easily opened and converted to a nonwoven
fabric having a high quality.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 show an explanatory cross-sectional profile
of an embodiment of the staple fibers of the present
invention,
Figs. 2-(a), (b) and (c) respectively show
explanatory views of melt-spinning holes for noncomposite
fibers,
Figs. 2-(A), (B) and (C) respectively show
explanatory cross-sectional view of the non-composite
fibers produced by using the melt-spinning holes shown in
Figs. 2- (a), (b) and (c),
Figs. 3-(d), (e), (f) and (g) respectively show
explanatory view of melt-spinning holes for core-insheath
type composite fibers, and
Figs. 3-(D), (E), (F) and (G) respectively show
explanatory cross-sectional view of a core-in-sheath type
composite fibers produced by using the melt-spinning
holes as shown in Figs. 3-(d), (e), (f) and (g).
BEST MODE FOR CARRYING OUT THE INVENTION
The synthetic staple fibers, of the present
invention, for an air-laid nonwoven fabric have a fiber
length of 0.1 to 45 mm and a cross-sectional profile, at
right angles to the longitudinal axis of the fiber,
having 1 to 30 concavities each, satisfies the
requirement:
D/L = 0.1 to 0.5
wherein D represents a largest depth of the concavity,
namely a largest distance between a tangent line drawn to
a pair of convexities from which an opening of the
concavity is defined, and a bottom of the concavity,
measured in a direction at right angles to the tangent
line, and L represents a largest opening distance, namely
a distance between two points of contact of the pair of
convexities with the tangent line.
Fig. 1 is an explanatory view of a cross-sectional
profile of an embodiment of the staple fibers of the
present invention.
In Fig. I, a staple fiber 1 has three lobar
convexities 2a, 2b and 2c and three concavities 3a, 3b,
and 3c formed between the convexities. One concavity,
for example, the concavity 3a has a largest opening
distance L which is represented by a distance between
contacts 4a and 4b of a tangent line 4 drawn to contours
of two convexities 2a and 2b by which the two end
portions of the opening of the concavity 3a are defined,
with the contours of the two convexities 2a and 2b.
Also, the largest depth D of the concavity 3a represent a
largest distance between the tangent line 4 and the
contours of the concavity 3a. The L and D values of
other concavities 3b and 3c can be determined in the same
manner as mentioned above.
In the cross-sectional profile of the synthetic
staple fibers of the present invention, the D/L ratios of
all the concavities must be in the range of from 0.1 to
0.5.
In the staple fibers of the present invention, if
the fiber length is less than 0.1 mm, the resultant
nonwoven fabric exhibits an insufficient mechanical
strength, or the resultant staple fibers are agglomerated
to form fiber masses which are difficult to open. Also,
if the fiber length of the staple fibers of the present
invention is more than 45 mm, the resultant staple fibers
exhibit an insufficient opening property. Preferably,
the fiber length of the staple fibers of the present
invention is in the range of from 1 to 45 mm, more
preferably from 3 to 40 mm.
Further, in the cross-sectional profile of the
staple fibers of the present invention, the ratio D/L
value is less than 0.1, the open spaces formed between
the staple fibers in the resultant nonwoven fabric
decrease to cause the fibers located adjacent to each
other to be approximately brought into close contact with
each other and thus a function of trapping water from the
fibers decrease, and the resultant staple fibers exhibit
an insufficient air opening property.
Accordingly, in this case, the desired air-laid
nonwoven fabric having a high quality cannot be obtained.
Also, if the ratio D/L value is more than 0.5, sometimes,
a convexity of a staple fiber fits in a concavity of
another staple fiber located adjacent to the staple fiber
and thus the air opening property of the staple fibers
decreases. Preferably the D/L ratio value is in the
range of from 0.15 to 0.35, more preferably from 0.20 to
0.30.
In the cross-sectional profile of the staple fibers
of the present invention, when the number of the
concavities is 1 or more per fiber, the above-mentioned
effects can be attained, and the larger the number of the
concavities, the better the air opening property of the
resultant staple fibers. However, if the number of the
concavities is more than 30 per fiber, the D/L ratio
value is difficult to control within the above-mentioned
range. Preferably, the number of the concavities is 2 to
20 per fiber, more preferably 3 to 10 per fiber.
In the case of the conventional staple fibers, an
increase in water content of the fibers to 0.6% by mass
or more, causes the air opening property of the resultant
staple fibers to decrease, and thus the resultant
nonwoven fabric exhibit a degraded quality. Compared
with this, in the case of the staple fibers of the
present invention, the air opening property is good even
when the water content is high. The reason for the
above-mentioned performance of the staple fibers of the
present invention is assumed to be that the water, which
usually promotes the agglomeration of the staple fibers
with each other, is trapped in the concavities formed in
the peripheries of the staple fibers and thus the amount
of water which promotes the agglomeration of the staple
fibers decreases. If the water content is too high, the
air opening property of the staple fibers even in the
case where the staple fibers are those of the present
invention, decreases and becomes insufficient. Thus, the
water content of the staple fibers of the present
invention may be 0.6% by mass or more but preferably not
more than 10% by mass, more preferably not more than 3%
by mass.
Also, the inventors of the present invention have
found that, not only in the case where the water content
is high as mentioned above, but also in the case where
the thickness of the fibers is small, the number of
crimps is high, the number of crimps is low or the number
of crimps is zero, or the fiber surface is coated with a
resin or a functional agent having a high frictional
property, the resultant synthetic staple fibers of the
present invention exhibit a good air opening property,
and thus an air-laid nonwoven fabric having a high
quality can be produced from the staple fibers of the
present invention.
The conventional staple fibers having a thickness of
5 dtex or less, particularly 2.5 dtex or less, are
difficult to open by the air opening method, and thus an
air-laid nonwoven fabric having a high quality is
difficult to obtain. Compared with this, the staple
fibers of the present invention have appropriate
concavities formed on the peripheries of the fibers, to
cause sufficient spaces to be formed between staple
fibers adjacent to each other. Therefore, even when the
staple fibers are densely massed, an air flow can easily
penetrate into the gaps between the staple fibers to
sufficiently open the staple fibers, and thus an air-laid
nonwoven fabric having a high quality can be obtained.
However, even in the case of the staple fibers of the
present invention, there is a tendency that, if the
thickness of the staple fiber is too low, the air opening
property of the staple fibers becomes insufficient.
Therefore, the thickness of the staple fibers of the
present invention is preferably in the range of from 0.1
to 5 dtex, more preferably from 0.1 to 2 dtex.
When the conventional staple fibers are opened,
there is a problem that the low number of crimps on the
staple fibers in the range of from 0 to 5 crimps/25 mm
including no crimp, cause non-opened fiber bundles to be
formed with a high frequency, and a high number of crimps
on the staple fibers in the range of from 15 crimps/25 mm
or more causes the staple fibers to be entwined with each
other during the air opening procedure to form fiber
pills. Compared with this, the staple fibers of the
present invention have an improved air opening property
for the reasons as mentioned above and, thus, the
generation of the non-opened fiber bundles and the fiber
pills can be reduced and an air-laid nonwoven fabric
having excellent quality can be produced from the staple
fibers. Accordingly, when the staple fiber of the
present invention having a crimp number selected from low
crimp number range is used, a non-bulky, smooth and flat
nonwoven fabric can be obtained, and when the staple
fibers of the present invention having a crimp number
selected from high crimp number range are used, a bulky
nonwoven fabric having a high porosity can be obtained.
In every case, the resultant nonwoven fabric has a very
low non-opened fiber bundle and fiber pill defect number,
and excellent quality. In any case, as mentioned above,
if the crimp number is too large, the generation of the
pills is promoted, in the high crimp number range, the
number of crimps is preferably in the range of from 15 to
40 crimps/25 mm, more preferably from 15 to
30 crimps/25 mm. The above-mentioned crimps may be twodimensional
crimps in the zig-zag form, or cubic crimps
in a spiral or omega (Q) form.
The staple fibers of the present invention may
comprise only one type of resin or may be a composite
fibers comprising two or more sections formed from two or
more types of resins and combined into a fiber form, or a
polymer blend fibers formed from a blend of two or more
types of resins. Preferably, in the staple fiber of the
present invention, at least a portion of a surface of the
fiber is formed from at least one member selected from
polyester resins, polyamide resins, polypropylene resins,
high-pressure-method low-density polyethylene resins,
linear low-density polyethylene resins and elastomer
resins. In this type of staple fiber, of the present
invention, the effects of the present invention is
particularly exhibited. Namely, the conventional staple
fibers formed from the above-mentioned types of resins
have a high frictional property between fibers and thus
cannot exhibit a sufficient opening property. Compared
with this, in the staple fibers of the present invention,
the specific cross-sectional profile of the fibers
enables the contact area of the staple fibers with each
other to be small and, thus, the friction of the staple
fibers with each other during the air opening procedure
to be reduced, the air opening property of the staple
fibers to be enhanced, and a high quality air-laid
nonwoven fabric to be produced.
The staple fibers of the present invention in which
the above-mentioned synthetic resin is located in the
fiber surfaces include single phase fibers formed from a
member of the above-mentioned resins, polymer blend
fibers formed from a polymer blend in which a member of
the above-mentioned resins is melt, mixed in an amount of
50% or more by mass based on the mass of the fibers, with
an other resin, core-in-sheath or eccentric core-insheath
type composite fibers in which a member of the
above-mentioned resins is contained as a sheath
component, islands-in-sea type composite fibers in which
a member of the above-mentioned resins is contained as a
sea component, and side-by-side type, multi-layered type
and segment pie type composite fibers in which a member
of the above-mentioned resins is located in the surfaces
The polyester resins usable for forming the staple
fibers of the present invention include (1) aromatic
polyesters, for example, polyethylene terephthalate,
polytrimethylene terephthalate, polybutylene
terephthalate, polyhexamethylene terephthalate and
polyethylene naphthalate; (2) polymers and copolymers
comprising poly(a-hydroxycarboxylic acid), for example,
polyglycolic acid or polylactic acid; (3) poly(cohydroxyalkanoate)
s selected from poly (e-caprolactone) and
poly(p-propiolactone); (4) poly(p-hydroxyalkanoate)s
selected from poly-3-hydroxypropionate, poly-3-
hydroxybutyrate, poly-3-hydroxycaproate), poly-3-
hydroxyheptanoate, poly-3-hydroxyoctanoate, and
copolymers of the above-mentioned polymers with poly-3-
hydroxyvalerate or poly-4-hydroxybutylate; (5) aliphatic
polyesters selected from polyethylene oxalate,
polyethylene succinate, polyethylene adipate,
polyethylene azelate, polybutylene adipate, polybutylene
sebacate, polyhexamethylene sebacate, polyneopentyl
oxalate and copolymers of the above-mentioned polymeric
compounds; and copolymers of the above-mentioned
polymers (1), (2), (4) and (5) with an acid component
comprising at least one member selected from, for
example, isophthalic acid, succinic acid, adipic acid,
ocbacic acid, azelaic acid, 2,6 naphthalene dicarboxylic
acid and metal sulfoisophthalic acids, for example, 5-
sodium sulfoisophthalic acid, and/or a glycol component
comprising at least one member selected from ethylene
glycol, diethylene glycol, 1,3-trimethyleneglycol, 1,4-
butanediol, 1,6-hexanediol, cyclohexanediol,
cyclohexanedimethanol, polyethyleneglycol,
polytrimethyleneglycol and polytetramethyleneglycol.
The elastomer resins usable for the staple fibers of
the present invention include thermoplastic elastomers,
for example, polyurethane elastomers, polyolefin
elastomers, polyester elastomers.
The polypropylene resins usable for the staple
fibers of the present invention include polypropylene
homomolymers and crystalline copolymers of a major
component comprising propylene with a minor component
comprising ethylene or an a-olefin, for example, butene-
1, hexene-1, octene-1, or 4-methylpentene-l.
The polyamide resins usable for the staple fibers of
the present invention include nylon 6, nylon 66 or
nylon 12.
The other resins usable for the staple fibers of the
present invention include, for example, high density
polyethylene, medium density polyethylene, high pressureprocessed
low density polyethylene, linear low density
polyethylene, and fluorine-containing resins.
The above-mentioned fiber-forming synthetic resins
optionally contain various additives, for example,
delustering agents, heat stabilizers, anti-foam agents,
tinting agents, flame retardants, antioxidants,
ultraviolet ray-absorbers, fluorescent brightening agents
and coloring pigments.
The staple fibers of the present invention can be
produced by, for example, the following procedures.
Namely, a fiber-forming synthetic resin is meltextruded
through a melt-spinneret for producing filaments
having a desired cross-sectional profile, the extruded
filamentary melt streams are taken up at a speed of 500
to 2000 m/min, to produce undrawn filament yarn. In this
procedure, a single type of polymer or a polymer blend is
used, the resin is melted, the resin melt is extruded
through a melt-spinning hole as shown in Fig. 2(a) or (b)
to produce a fiber having a cross-sectional profile as
shown in Fig. 2(A) or (B). The fiber having the crosssectional
profile as shown in Fig. 2(A) have the same
three concavities as those in the fiber having the crosssectional
profile as shown in Fig. 1. Also, in the
cross-sectional profile as shown in Fig. 2-(B), a single
concavity is formed. The fibers shown in Figs. 2-(A) and
(B) are formed from a single type of fiber-forming
synthetic resin or a blend of two or more fiber-forming
synthetic resins. In the case of a core-in-sheath type
composite fiber, two types of resins are melted, the two
types of resin melts are combined in a cylindrical nozzle
arranged upstream to the melt-spinning hole to form a
core-in-sheath structure, and the combined melt stream is
extruded through a melt spinneret having melt-spinning
holes as shown in Figs. 3-(d) to (f), to produce
composite fibers having the cross-sectional profiles as
shown in Figs. 3-(D) to (F). Also, in the melt spinning
procedure as mentioned above, a cooling air is blown
toward the resin melt filamentary streams to cool and
solidify the melt streams. In this procedure, the D/L
ratio of the cross-sectional profile of the resultant
fibers can be controlled within the range of from 0.1 to
0.5, by appropriately controlling the flow rate of the
cooling air and the location at which the cooling air
flow comes into contact with the filamentary melt
streams. The resultant undrawn filament yarn is drawn in
air at room temperature or in hot water at a temperature
of 60 to 95°C in a single stage or a plurality of stages,
at a total draw ratio of 1.2 to 5.0. The drawn filament
yarn is oiled with an oiling agent, is optionally crimped
by using a stuffing crimper and, thereafter, is cut into
a desired fiber length, to provide the staple fibers of
the present invention.
The fiber having the cross-sectional profile shown
in Fig. 3-(D) is constituted from a fiber-forming
synthetic resin for forming a core portion 11 and another
fiber-forming synthetic resin for forming a sheath
portion 12, to form a core-in-sheath type composite
structure having three concavities. The fiber having the
cross-sectional profile shown in Fig. 3-(E) is formed
from a core portion 11-forming synthetic resin and a
sheath portion 12-forming synthetic resin different from
each other into a core-in-sheath composite structure
having a single concavity. The fiber having the crosssectional
profile shown in Fig. 3-(F) is constituted from
a core portion 11-forming synthetic resin and a sheath
portion-forming synthetic resin into a core-in-sheath
type composite structure having 8 concavities.
There is no limitation to the composition of the
oiling agent usable for the above-mentioned procedures.
Preferably, an oiling agent comprising 30 to 90% by mass
of an alkalic metal salt of an alkylphosphoric acid
having 10 to 20 carbon atoms and 10 to 70% by mass of a
polydimethylsiloxane and/or a polyoxyethylenepolyoxypropylene-
graft copolymerized polysiloxane, to
promote the opening property of the fibers. Preferably,
the oiling agent is applied at an amount of 0.01 to 5% by
mass. If the application amount of the oiling agent is
less than 0.01% by mass, when the resultant staple fibers
are subjected to an air-laid nonwoven fabric-producing
procedure, static electricity is easily generated, and if
the application amount of the oiling agent is more than
5% by mass, the resultant staple fibers are easily
adhered to each other to form staple fiber bundles, and
thus exhibit a degraded air opening property. When the
staple fibers of the present invention having the
specific irregular cross-sectional profile, as the
contact area of the staple fibers with each other become
small, and the influence of the change in frictional
property of the staple fibers due to the application of
the oiling agent becomes small on the air opening
property of the resultant staple fibers, the variety in
means for impacting a function, for example,
hydrophilicizing function, water-repellent function,
antibacterial function, deodorant function or aromatic
function to the fibers can be expanded.
The melt-spinning holes shown in Fig. 2-(c) and
Fig. 3-(g) are used for producing conventional staple
fibers (comparative) having the cross-sectional profiles
as shown in Fig. 2-(C) and Fig. 3-(G). The cross-
sectional profile shown in Fig. 2-(C) is circular, and in
the core-in-sheath type cross-sectional profile shown in
Fig. 3-(G), a core portion 11 having a circular crosssectional
profile is arranged within a sheath portion 12
having a circular'cross-sectional profile.
To produce an air-laid nonwoven fabric from the
staple fibers of the present invention, a conventional
method can be used. By using the staple fibers of the
present invention, the air-laid nonwoven fabric having a
high quality can be produced. Particularly, the number
of defects which is represented by a total number of nonopened
fiber bundles and fiber pills having a diameter of
5 mm or more, contained in 1 g of the resultant web, is
preferably 10 or less. The term "non-opened fiber
bundles" represents fiber bundles formed from the nonopened
fibers bundled in parallel to each other and
having a cross-sectional major axis of 1 mm or more.
When the staple fibers of the present invention are
used, the number of defects generated during the
production of the air-laid nonwoven fabric is extremely
small, and thus a desired web can be formed with high
stability.
The synthetic staple fibers of the present invention
optionally contains various functional agents, for
example, at least one member selected from deodorant
functional agents, antibacterial functional agents, flame
retardant functional agents and insect-repellent
functional agents. In the staple fibers of the present
invention, the functional agent may be mixed into the
fiber-forming synthetic resin and preferably the
functional agent is applied and fixed to the peripheral
surfaces of the staple fibers.
In the conventional staple fibers for the air-laid
nonwoven fabric, an increase in the application amount of
the functional agent on the staple fiber surfaces,
particularly in an application amount of 0.05% by mass or
more, causes the air opening property of the resultant
staple fibers to be reduced and the quality of the
resultant nonwoven fabric to be degraded. When the
staple fibers of the present invention are used, the air
opening property of the staple fiber is good even when
the functional agent is applied in a large amount as
mentioned above. The reasons for this advantage is
assumed that the functional agent, or a solution or
emulsion thereof is trapped in the concavities formed on
the peripheral surfaces of the staple fibers, and as a
result, the distribution density of the functional agent
adhered to the fiber surfaces is reduced.
In view of the functioning property, the concavities
allow the functional agent to be held in a large amount
in the concavities, and thus, the functional agent can be
held in an amount sufficient to exhibit the desired
function on the surface of the staple fibers. Even when
the functional agent is applied in the state of a liquid,
the resultant functional agent-coated layer on the staple
fiber surfaces exhibit a high resistance to removal
during the formation of the air-laid nonwoven fabric in
which a high speed air flow is applied to the staple
fiber, due to a high surface tension of the coating
layer. Thus, the functional agent layer on the staple
fibers of the present invention exhibit a high
durability. However, if the functional agent is applied
in too a high amount, the air opening property of the
staple fibers may be degraded. The amount of the
functional agent to be imparted to the staple fibers of
the present invention is preferably in the range of from
0.01 to 10% by mass, more preferably from 0.01 to 3% by
mass. In the method for applying and fixing the
functional agent, to evenly drop the functional agent in
the concavities of the staple fibers with a high
efficiency, the functional agent is preferably applied in
the state of a liquid, such as a solution in water or an
organic solvent or an emulsion, prepared by dissolving or
emulsifying the functional agent in the state of a
liquid, paste, or solid in water or an organic solvent
(for example, alcohols or acetone). If the functional
agent is applied in the state of a paste or solid, the
functional agent is distributed in a high distribution
density on portions other than the concavities, of the
staple fibers, and this distribution may cause the air
opening property of the staple fibers to be degraded.
Preferably, the functional agent is applied to the fibers
in the form of a filament tow by a conventional oiling
method, for example, an oiling roller method or spray
method, and then the functional agent-finished filament
tow is cut into staple fibers.
There is no limitation to the type of the functional
agent. The functional agent usable for the present
invention includes surface treatment functional agents
which are difficult to be applied in the state of a blend
with the oiling agent, for example, deodorants,
antibacterial agent, flame retardants and insect (vermin)
repellent agents.
In the deodorants, organic deodorants soluble in
water or an organic solvent and capable of evenly
dispersing are preferably employed rather than inorganic
deodorants. As an example, a liquid extract obtained by
extract-separating from leaf portions of theaceae plants,
for example, camellia. In practice, green Lea dry
distillation extract S-100 (trademark), made by
SHIRAIMATSU SHINYAKU K.K, is usable. To effectively
function, the deodorant is preferably retained in an
amount of 0.01% by mass or more, more preferably 0.02% by
mass or more, on the staple fibers.
The antibacterial agent includes, as an example,
tertiary ammonium antibacterial agents. In practice,
NIKKANON RB (trademark, N-polyoxyethylene-N,N,Ntrialkylammonium
salt), made by NIKKA KAGAKU K.K. is
preferably used. Also, amino glycosides (glycosides of
aminosaccharide with monosaccharide, multi- or
polysaccharide), for example, ST-7, ST-8, ST-9, ST-835,
ST-836, and ST-845 (trademark), made by K.K. BIOMATERIAL,
are preferable examples of the antibacterial agent. To
effectively function, the antibacterial agent is
preferably retained in an amount of 0.01% by mass or
more, more preferably 0.02% by mass or more, on the
staple fibers.
The flame retardants include, for example,
halogenated cycloalkane compounds. The term "halogenated
cycloalkane compounds" includes compounds in which at
least one hydrogen atom in cyclic saturated hydrocarbons,
or saturated hydrocarbon compounds having at least one
cyclic saturated hydrocarbon structure is substituted by
a halogen atom. The halogenated cycloalkane compounds
include, for example, 1,2, 3, 4, 5,6-hexabromocyclohexane,
1,2,3,4- or 1,2,4,6-tetrabromocyclooctane and
1,2,5,6,9,10-hexabromocyclododecane, 1,2-bis(3,4-
dibromocyclohexyl)1,2-dibromoethane, and substituted
compounds in which the bromine atoms in the mentioned
bromocompounds, are substituted by chlorine atoms. The
flame retardants usable for the present invention are not
limited to the above-mentioned compounds. To impart a
good flame retardant property, the halogenated
cycloalkane compounds are preferably retained in an
amount of 0.5% by mass or more on the staple fibers.
The vermin-repellent agents include pyrethroid
components, for example, 3-phenoxybenzyl-dl-cis/trans-3-
(2, 2-dichlorovinyl)-2,2-dimethyl-cyclopropane-lcarboxylate
(Common name: Permetrin), (3-
phenoxyphenyl)methyl ester of 2-dimethyl-3-(2-
methylpropenyl)cyclopropane carboxylic acid (Common name:
Phenotrin). To function effectively, the verminrepellent
agent is preferably retained in an amount of
0.01% by mass or more, more preferably 0.1% by mass or
more, on the staple fibers.
EXAMPLES
The present invention will be further explained in
detail the following examples which are not intended to
limit the scope of the present invention in any way.
In each of the examples and comparative examples the
following measurements were carried out.
(1) Intrinsic Viscosity
The intrinsic viscosity was measured at a
temperature of 35°C in o-chlorophenol as a solvent.
(2) Melt Flow Rate (MFR)
The melt flow rate of the synthetic resin subjected
to the measurement was determined in accordance with the
method described in JIS K 7210.
(3) Melting Point (Tm)
The melting point (Tm) was represented by an
endothermic peak temperature in a DSC curve prepared
according to the differential scanning calorimetric
measurement (DSC) described in JIS K 7121.
(4) Softening Point (Ts)
A test piece having a length of 126 mm, a width of
12 mm and a thickness of 3 mm was prepared from a
synthetic resin subjected to the measurement. A Vicat
softening test was carried out on the test piece in
accordance with JIS K 7206, and the heat transfer medium
temperature was measured when a needle indenter was
intruded to the depth of 1 mm.
(5) Thickness
The thickness of staple fibers subjected to the
measurement was measured in accordance with the method
described in JIS L1015 7.5.1 A.
(6) Fiber Length
The fiber length of the staple fibers subjected to
the measurement was measured in accordance with the
method described in JIS L 1015, 7.4.1 C method.
(7) Number of Crimps, Percentage of Crimp
Individual filaments were taken out from a crimped
filament tow before the tow was cut into a desired fiber
length, and the number of crimps and the percentage of
crimp of the individual filaments were measured in
accordance with the method described in JIS L 1015 7.12.
(8) Pickup of Oiling Agent
Fibers having a mass (F) were subjected to an
extraction with methanol at 30°C in a liquor ratio of 1:20
for 10 minutes. The dry mass (E) of an extraction
residue was measured. The measured dry mass (E) was
dividing with the fiber mass (F). The resultant quotient
in % represented the pickup of the oiling agent on the
fibers.
(9) Water Content of Staple Fibers
The water content of staple fibers was determined in
accordance with the method described in JIS L 1015 7.2.
(10) Ratio D/L of Concavity
A microscopic photograph of a cross sectional
profile of a staple fiber (section photograph) was taken,
and the contour of the cross-sectional profile of the
fiber was traced on a tracing paper sheet, D and L, as
explained below, were determined with a ruler, and the
ratio D/L was calculated in accordance with the following
equation:
D/L ratio = D/L x 100
wherein L represents a longest width of opening of the
concavity (represented by a distance between a tangent
line drawn to a pair of convexities defining the opening
of the concavity and two points of contact of the tangent
line with the two convexities, and D represents a largest
depth of the concavity (measured from the tangent line in
the direction at right angles to the tangent line.
(11) Number of Defects of Air-Laid Web
An air-laid web composed of 100% of staple fibers
and having a basis mass of 30 g/m2 was produced by using a
forming drum unit (600 mm wide, the form of holes of the
forming drum: rectangular 2.4 mm x 20 mm, opening area:
40%) under the conditions of the rate of drum rotation of
200 rpm; the number of rotation of a needle roll of 900
rpm; and the transportation speed of the web of 30 m/min.
Ten samples each having a mass of 1 g were randomly
collected from 10 respective sites of the web. For each
sample, the number of non-opened fiber bundles having a
cross-sectional major axis of 1 mm or more) and pills
having a diameter of 5 mm or more per g of the sample,
was counted. The average of the total number of defects
per g of the web sample was calculated. When the number
of defects was 10 or less, the web passed the test.
Example 1
A high density polyethylene (HOPE) having a MFR of
20 g/10 min and a Tm of 131°C and a poly(ethylene
terephthalate) (PET) vacuum dried at 120°C for 16 hours
and having an intrinsic viscosity [r\] of 0.61 and a Tm of
256°C were melted separately from each other by separate
extruders to prepare a polyethylene melt having a
temperature of 250°C and a polyester melt having a
temperature of 280°C. The polyethylene melt was used as a
sheath component A and the polyester melt was used as a
core component B. The sheath component (A) resin melt
streams and the core component B resin melt streams were
combined in a combination mass ratio A:B of 50:50 through
a melt-spinneret for forming a core-in-sheath type
composite yarn having 450 extrusion holes in the form as
shown in Fig. 3(d), to form a core-in-sheath type
composite resin melt streams, and the resultant core-insheaLh
Lype composite streams were melt-extruded through
the spinneret. In this melt-spinning procedure, the
spinneret temperature was established at 280°C, and the
extrusion rate was established at 150 g/min. Then, the
extruded composite filamentary resin melt streams was air
cooled with a cooling air flow having a temperature of
30°C at a location 30 mm below the spinneret, and wound at
a speed of 1,150 m/min, to provide an undrawn filament
yarn. The undrawn filament yarn was drawn at a draw
ratio of 3 in hot water at 75°C. An oiling agent
comprising 80 parts by mass of potassium salt of
laurylphosphoric acid and 20 parts by mass of
polyoxyethylene-modifled silicons was imparted in a
pickup of the oiling agent of 0.22% by mass to the drawn
filament yarn. The oiling agent-applied drawn filament
yarn was crimped with plane zigzag type crimps in the
number of crimps of 17 crimps/25 mm and a percentage of
crimp of 8%, by using a stuffing crimper. The resultant
filament yarn was then dried at 105°C for 60 minutes, and
cut with a rotary cutter into a fiber length of 5 mm.
The resultant staple fibers had a thickness of 1.1 dtex,
and had a cross sectional profile as shown in Fig. 3-(D).
The test results are shown in Table I.
Examples 2 and 3 and Comparative Example 1
In each of Examples 2 to 3 and Comparative Example
I, core-in-sheath type composite staple fibers were
produced in the same manner as in Example 1 except that
the extrusion holes of the spinneret were changed to
those having a cross-sectional profiles as shown in
Fig. 3-(e), -(f) and -(g). The test results are shown in
Table 1.
Comparative Example 2
Core-in-sheath type composite staple fibers were
produced under the same conditions as in Example 1,
except that the cooling position of the extruded
composite filamentary resin melt streams was changed to a
location 70 mm below the spinneret. The test results are
shown in Table 1.
Example 4
Core-in-sheath type composite staple fibers were
produced under the same conditions as in Example 1,
except that no stuffing crimper was employed not to
impart crimps to the staple fibers. Table 1 shows the
test results.
Comparative Example 3
Core-in-sheath type composite staple fibers were
produced under the same conditions as in Comparative
Example 1, except that no stuffing crimper was used, not
to impart crimps to the staple fibers. Table 1 shows the
results.
Examples 5 to 6
In each of Examples 5 and 6, core-in-sheath type
composite staple fibers were produced, in the same manner
as in Example 1 except that the number of crimps was
changed to 5 crimps/25 mm in Example 5 and to
40 crimps/25 mm in Example 6 by controlling the feed rate
of the drawn filament yarn to the stuffing crimper and
the stuffing pressure to the filament yarn. Table 1
shows the test results.
Example 7 and Comparative Example 4
Core-in-sheath type composite staple fibers were
produced in Example 7, in the same manner as in
Comparative Example 1, and in Comparative Example 4, in
the same manner as in Comparative Example 1, except that
the oiling agent-applied, drawn filament yarn was dried
at 105°C, moisturized and cut into a fiber length of 0.1
mm by using a Guillotine cutter. The resultant staple
fibers of Example 7 and Comparative Example 4
respectively had a water content of 10% by mass. Table 1
shows the test results.
Example 8
Core-in-sheath type composite staple fibers were
produced in the same manner as in Example 1 except that
the extrusion holes of the spinneret were changed to
those having Lhn HHtne cross-sectional profile as in
Fig. 3-(f), except that the number of the radial slits
was changed to 30. Table 1 shows the test results.
Example 9
Core-in-sheath type composite staple fiber were
produced in the same manner as in Example 1 except that
the fiber length was changed to 45 mm. Table 1 shows the
test results.
(Table Removed)
Example 10
A poly(ethylene terephthalate) (PET) vacuum dried at
120°C for 16 hours and having an intrinsic viscosity [r\]
of 0.61 and a Tm of 256°C was melted at a temperature of
280°C and the resultant resin melt was extruded through a
melt spinneret having 450 extrusion holes with the form
as shown in Fig. 2-(a). The spinneret temperature was
controlled to 280°C, and the extrusion rate was controlled
to 150 g/min. Moreover, the extruded filamentary resin
melt streams were air-cooled by blowing cooling air at
30°C at a location 35 mm below the spinneret, and the
resultant filament bundle were wound at a speed of 1,000
- 25 -
m/min to provide an undrawn filament yarn. The undrawn
filament yarn was drawn at a draw ratio of 3.2 in hot
water at 70°C, and then further drawn at a draw ratio of
1.15 in hot water at 90°C. The resultant drawn filament
yarn was oiled with an oiling agent comprising potassium
salt of laurylphosphoric acid and polyoxyethylenemodified
silicone in a mass ratio of 80/20 in a pickup of
the oiling agent of 0.18% by mass. Then the oiled
filament yarn was subjected to a crimping step using a
stuffing crimper to impart plane zigzag-type crimps to
the oiled filament yarn at the number of crimps of
16 crimps/25 mm and a percentage of crimp of 12%. The
resultant yarn was then dried at 130°C for 60 minutes, the
dried drawn filament yarn was cut into a fiber length of
5 mm with a rotary cutter. The resultant staple fibers
had a thickness of 1.0 dtex, and had a cross sectional
profile as shown in Fig. 2-(A). Table 2 shows the test
results.
Example 11 and Comparative Example 5
In each of Example 11 and Comparative Example 5,
staple fibers were produced in the same manner as in
Example 10, except that the extrusion holes of the
spinneret were changed to those having a cross-sectional
profile as shown in Fig. 2-(b) for Example 1 and in
Fig. 2-(c) for Comparative Example 5. Table 2 shows the
test results.
Comparative Example 6
Staple fibers were produced in the same manner as in
Example 10, except that the extruded filamentary resin
melt streams were cooled at a location 70 mm below the
spinneret. Table 2 shows the test results.
Comparative Example 7
Staple fibers were produced in the same manner as in
Example 10, except that the cooling portion of the
extruded filamentary resin melt streams was changed to a
location 20 mm below the spinneret. Table 2 shows the
resultant crimped filament yarn was then dried at 55°C for
60 minutes, and cut into a fiber length of 5 mm with a
rotary cutter. The resultant staple fibers had a
thickness of 1.7 dtex and a cross sectional profile as
shown in Fig. 3-(D). Table 3 shows the test results.
Comparative Example 10
Staple fibers were produced in the same manner as in
Example 14 except that the form of the extrusion holes
was changed to that shown in Fig. 3-(g). Table 3 shows
the test results.
Example 15
A polyester elastomer (EL) vacuum dried at 35°C for
48 hours, having an intrinsic viscosity [r\] of 0.8 and a
Tm of 152°C, and comprising hard segments comprising a 15%
by mole of isophthalic acid-copolymerized poly(butylene
terephthalate) and the soft segments comprising a
poly(tetramethylene glycol) having an average molecular
weight of 1,500, and a poly(ethylene terephthalate) (PET)
dried at 120°C for 16 hours and having an intrinsic
viscosity [TJ] of 0.61 and a Tm of 256°C, were separately
melted with separate extruders to provide a EL melt
having a temperature of 240°C and a PET melt having a
temperature of 280°C. The EL melt was used for sheath
component A, and the PET melt was used tor a core
component B. The EL melt and the PET melt were extruded
in a mass ratio A/B = 50/50 through a melt-spinneret
having 450 extrusion holes as shown in Fig. 3-(d) for a
core-in-sheath type composite fiber, to form core-insheath
type composite filamentary resin melt streams. In
this procedure, while the spinneret temperature was
controlled to 280°C, and the extrusion rate was controlled
to 310 g/min. Moreover, the extruded filamentary resin
melt streams were air cooled with cooling air at 30°C at a
location 30 mm below the spinneret, and the resultant
undrawn filament yarn was wound at a speed of 1,100
m/min. The resultant undrawn filament yarn was then
drawn at a draw ratio of 2.6 in hot water at 70°C, and
further drawn at a draw ratio of 1.15 in hot water at
90°C. Then the drawn filament yarn was oiled with a
oiling agent comprising potassium salt of
laurylphosphoric acid and polyoxyethylene-modifled
silicone in a mass ratio of 80:20 in a pickup of the
oiling agent 0.25% by mass. The oiled filament yarn was
fed into a stuffing crimper to impart plane zigzag type
crimps at a number of crimps of 8 crimps/25 mm and a
percentage of crimp of 6%. The resultant crimped
filament yarn was then dried at 70°C for 60 minutes, and
cut into a fiber length of 5 mm with a rotary cutter.
The resultant staple fibers had a thickness of 2.5 dtex
and a cross sectional profile as shown in Fig. 3-(D).
Table 3 shows the test results.
Comparative Example 11
Staple fibers were produced in the same manner as in
Example 15 except that the extrusion holes of the
spinneret were changed to those having a form as shown in
Fig. 3-(g). Table 3 shows the test results.
Example 16
A polypropylene (PP) having a MFR of 50 g/10 min and
a Tm of 158°C and a poly (ethylene terephthalate) (PET)
vacuum dried at 120°C tor 16 hours and having an intrinsic
viscosity [r\] of 0.61 and a Tm of 256°C were separately
melted with separate extruders. The PP melt having a
temperature of 260°C was used for a sheath component A and
the PET melt having a temperature of 280°C was used for a
core component (B). The PP melt and the PET melt were
fed in a mass ratio A/B of 50:50 to a core-in-sheath type
composite spinneret having 450 extrusion holes with a
shape as shown in Fig. 3-(d) and extruded through the
spinneret to provide core-in-sheath type composite
filamentary streams. In this procedure, the spinneret
temperature was controlled to 280°C, and the extrusion
rate was controlled to 190 g/min. Moreover, the extruded
filamentary resin melt streams were air cooled with a
cooling air flow at 30°C at a location 30 mm below the
spinneret, and wound the resultant undrawn filament yarn
was at a speed of 1,150 m/min. The undrawn filament yarn
was drawn at a draw ratio of 2.9 in hot water at 75°C, and
then oiled with an oiling agent comprising potassium salt
of laurylphosphoric acid and polyoxyethylene-modified
silicone in a mass ratio of 80:20 in a pickup of the
oiling agent 0.25% by mass. The oiled filament yarn was
fed to a stuffing crimper to impart plane zigzag type
crimps to the drawn yarn at a number of crimps of
13 crimps/25 mm and a percentage of crimps of 11%. The
resultant crimped filament yarn was then dried at 105°C
for 60 minutes, and then cut into a fiber length of 5 mm
with a rotary cutter. The resultant staple fibers had a
thickness of 1.5 dtex and a cross-sectional profile as
shown in Fig. 3-(D). Table 3 shows the test results.
Comparative Example 12
Staple fibers were produced in the same manner as in
Example 16, except that the extrusion holes of the
spinneret were changed to those as shown in Fig. 3-(g).
Table 3 shows the test results.
Example 17
A high pressure-processed low density polyethylene
(LDPE) having a MFR of 20 g/10 min and a Tm of 113°C and a
poly(ethylene terephthalate) (PET) vacuum dried at 120°C
for 16 hours and having an intrinsic viscosity [r|] of
0.61 and a Tm of 256°C were separately melted with
separate extruders, to provide a LDPE melt having a
temperature of 250°C and a PET melt having a temperature
of 280°C. The LDPE melt was used for a sheath component A
and the PET melt was used for a core component B. The
LDPE melt and the PET melt were extruded at a mass ratio
A/B of 50:50 through a core-in-sheath type composite
spinneret having 450 extrusion holes as shown in
Fig. 3-(d) to form core-in-sheath type composite
filamentary resin melt streams. In this procedure, the
spinneret temperature was 280°C, and the extrusion rate
was 200 g/min. Moreover, the extruded filamentary resin
melt streams were air cooled with a cooling air flow at
30°C at a location 30 mm below the spinneret, and the
resultant undrawn filament yarn was wound at a speed of
1,100 m/min. The undrawn filament yarn was drawn at a
draw ratio of 2.8 in hot water at 75°C, and oiled with an
oiling agent comprising potassium salt of
laurylphosphoric acid and polyoxyethylene-modified
silicone at a mass ratio of 80:20 in a pickup of the
oiling agent of 0.25% by mass. The oiled filament yarn
was fed to a stuffing crimper to impart plane zigzag type
crimps to the drawn filament yarn at a number of crimps
of 14 crimps/25 mm and in a percentage of crimp of 11%.
The resultant filament yarn was then dried at 95°C for 60
minutes, and cut into a fiber length of 5 mm with a
rotary cutter. The resultant staple fibers had a
thickness of 1.7 dtex and a cross-sectional profile as
shown in Fig. 3-(D). Table 3 shows the test results.
Comparative Example 13
Staple fibers were produced in the same manner as in
Example 17 except that the extrusion holes of the
spinneret were changed to thooc having a shape ds shown
in Fig. 3-(g). Table 3 shows the test results.
Example 18
A linear low density polyethylene (LLDPE) having a
MFR of 30 g/10 min and a Tm of 122°C and a poly (ethylene
terephthalate) (PET) vacuum dried at 120°C for 16 hours
and having an intrinsic viscosity [r|] of 0.61 and a Tm of
256°C were separately melted with separate extruders, to
prepare a LLDPE melt having a temperature of 250°C and a
PET melt having a temperature of 280°C, the LLDPE melt was
used for a sheath component A and the PET melt was used
for a core component B. The LLDPE melt and the PET melt
were extruded in a mass ratio A:B of 50:50 through a
core-in-sheath type composite spinneret having
450 extrusion holes, having the form as shown in
Fig. 3-(d), to provide core-in-sheath type composite
filamentary resin melt streams. In this procedure, the
spinneret temperature was 280°C, and the injection amount
was 200 g/min. Moreover, the extruded filamentary resin
melt streams were air cooled with a cooling air flow at
30°C at a location 30 mm below the spinneret, and the
resultant undrawn filament yarns was wound at a speed of
1,100 m/min. The undrawn filament yarn was drawn at a
draw ratio of 2.8 in hot water at 75°C and oiled with an
oiling agent comprising potassium salt of
laurylphosphoric acid and polyoxyethylene-modified
silicone in a mass ratio of 80:20 in a pickup of the
oiling agent of 0.25% by mass. The oiled filament yarn
was fed into a stuffing crimper to impart plane zigzag
type crimps to the drawn filament yarn at a number of
crimps of 13 crimps/25 mm and at a percentage of crimp of
11%. The resultant yarn was then dried at 95°C for 60
minutes, and cut into a fiber length of 5 mm with a
rotary cutter. The resultant staple fibers had a
thickness of 1.7 dtex and a cross sectional profile as
shown in Fig. 3-(D). Table 3 shows the test results.
Comparative Example 14
Staple fibers were produced in the same manner as in
Example 18 except that the extrusion holes of the
spinneret were changed to those having a form as shown in
Fig. 3-(g). Table 3 shows the test results.
(Table Removed)
Example 19
A high density polyethylene (HOPE) having a MFR of
20 g/10 min and a Tm of 131°C and a poly(ethylene
terephthalate) (PET) vacuum dried at 120°C for 16 hours
and having an intrinsic viscosity [r|] of 0.61 and a Tm of
256°C were melted separately from each other by separate
extruders to prepare a polyethylene melt having a
temperature of 250°C and a polyester melt having a
temperature of 280°C. The polyethylene melt was used as a
sheath component A and the polyester melt was used as a
core component B. The sheath component (A) resin melt
streams and the core component B resin melt streams were
combined in a combination mass ratio A:B of 50:50 through
a melt-spinneret for forming a core-in-sheath type
composite yarn having 450 extrusion holes in the form as
shown in Fig. 3 (d), to form a core-in-sheath type
composite resin melt streams, and the resultant core-in-
sheath type composite streams were melt-extruded through
the melt spinneret. In this melt-spinning procedure, the
spinneret temperature was established at 280°C, and the
extrusion rate was established at 150 g/min. Then, the
extruded composite filamentary resin melt streams were
air cooled with a cooling air flow having a temperature
of 30°C at a location 30 mm below the spinneret, and wound
at a speed of 1,150 m/min, to provide an undrawn filament
yarn. The undrawn filament yarn was drawn at a draw
ratio of 3 in hot water at 75°C. An oiling agent
comprising 80 parts by mass of potassium salt of
laurylphosphoric acid and 20 parts by mass of
polyoxyethylene-modified silicone was imparted in a
pickup of the oiling agent of 0.19% by mass to the drawn
filament yarn. The oiling agent-applied drawn filament
yarn was crimped with plan zigzag type crimps in the
number of crimps of 12 crimps/25 mm and a percentage of
crimp of 7%, by using a stuffing crimper. The resultant
filament yarn was then dried at 105°C for 60 minutes, and
then subjected to a procedure in which an aqueous
solution of a deodorant functional agent S-100
(trademark, green tea dry distillation extract, made by
SHIRAIMATSU SHINYAKU K.K.), in a concentration of 10% by
mass was applied to the crimped filament yarn to an
extent such that the aqueous solution is picked up in an
amount of 1% by mass on the filament yarn (a theoretical
pickup of the deodorant functional agent was 0.1% by mass
on the basis of the mass of the filament yarn), by using
an oiling roller. Then the deodorant-functioned filament
yarn was cut with a rotary cutter into a fiber length of
5 mm. The resultant staple fibers had a thickness of 1.1
dtex, and had a cross sectional profile as shown in
Fig. 3-(D). The test results are shown in Table 4.
Examples 20 and 21 and Comparative Example 15
In each of Examples 20 and 21 and Comparative
Example 15, staple fibers were produced in the same
manner as in Example 19, except that the extrusion holes
of the spinneret were changed respectively those as shown
in Fig. 3-(e), (f) and (g).
The test results are shown in Table 4.
Example 22
Core-in-sheath type composite staple fibers were
produced in the same manner as in Example 19 except that
the extrusion holes of the spinneret were changed to
those having the same cross-sectional profile as in
Fig. 3-(f), except that the number of the radial slits
was changed to 30. Table 4 shows the test results.
Example 23 and Comparative Example 16
In Example 23 and Comparative Example 16, core-insheath
type composite staple fibers were produced in the
same manner as in Example 19 (for Example 23) and
Comparative Example 15 (for Comparative Example 16),
except that in place of the deodorant functional agent S-
100, a 5% by mass aqueous solution of an antibacterial
functional agent, NIKKANON RB (trademark, Npolyoxyethylene-
N,N,N-trialkyl ammonium salt) was applied
to the crimped filament yarn to an extent such that the
aqueous solution of the antibacterial functional agent
was picked up in an amount of 5% by mass on the filament
yarn (the theoretical pickup of the antibacterial
functional agent was 0.25% by mass on the basis of the
mass of the filament yarn).
Table 4 shows the test results.
Example 24 and Comparative Example 17
In Example 24 and Comparative Example 17, core-insheath
type composite staple fibers were produced in the
same manner as in Example 19 and Comparative Example 15,
respectively, except that in place of the deodorant
functional agent S-100, an aqueous emulsion of flame
retardant YM88 (trademark, hexabromocyclododecane, made
by DAIICHI KOGYO SEIYAKU K.K.) in a concentration of 10%
by mass was applied to the crimped filament yarn to an
extent such that the aqueous emulsion of the flame
retardant functional agent is picked up in an amount of
10% by mass on the filament yarn (the theoretical pickup
of the flame retardant functional agent was 1.0% by mass
on the basis of the mass of the filament yarn). The test
results are shown in Table 4.
Example 25 and Comparative Example 18
In Example 25 and Comparative Example 18, core-insheath
type composite staple fibers were produced in the
same manner as in Example 19 (for Example 25) and
Comparative Example 15 for Comparative Example 18, except
that, in place of the deodorant functional agent S-100, a
10% by mass aqueous liquid of d-Phenotrin was applied to
the crimped filament yarn to an extent such that d-
Phenotrin was picked up in an amount of 5% by mass on the
filament yarn (the theoretical pickup of d-Phenotrin was
0.5% by mass on the basis of mass of the filament yarn).
The test results are shown in Table 4.
Example 26
A poly(ethylene terephthalate) (PET) vacuum dried at
120°C for 16 hours and having an intrinsic viscosity [r|]
of 0.61 and a Tm of 256°C was melted at a temperature of
280°C and the resultant resin melt was extruded through a
melt spinneret having 450 extrusion holes with the form
as shown in Fig. 2-(a). The spinneret temperature was
conliolled Lu 280"C, and Lhe exliusion rale was conlioiled
to 150 g/min. Moreover, the extruded filamentary resin
melt streams were air-cooled by blowing a cooling air
flow at 30°C at a location 35 mm below the spinneret, and
the resultant filament bundle were wound at a speed of
1,000 m/min to provide an undrawn filament yarn. The
undrawn filament yarn was drawn at a draw ratio of 3.2 in
hot water at 70°C, and then further drawn at a draw ratio
of 1.15 in hot water at 90°C. The resultant drawn
filament yarn was oiled with an oiling agent comprising
potassium salt of laurylphosphoric acid and
polyoxyethylene-modified silicone in a mass ratio of
80/20 in a pickup of the oiling agent of 0.18% by mass.
Then the oiled filament yarn was subjected to a crimping
step using a stuffing crimper to impart plane zigzag type
crimps to the oiled filament yarn at the number of crimps
of 16 crimps/25 mm and a percentage of crimp of 12%. The
resultant yarn was then dried at 130°C for 60 minutes, the
dried drawn filament yarn was subjected to a procedure in
which a 10% by mass aqueous solution of a deodorant
functional agent, S-100 (trademark, green tea dry
distillation extract) was applied to the crimped filament
yarn to an extent such that the deodorant functional
agent was picked up in an amount of 1% by mass on the
filament yarn (the theoretical pickup of the deodorant
functional agent was 0.1% by mass on the basis of the
mass of the filament yarn), by using an oiling roller.
Then the deodorant-functional filament yarn was cut into
a fiber length of 5 mm with a rotary cutter. The
resultant staple fibers had a thickness of 1.0 dtex, and
had a cross sectional profile as shown in Fig. 2-(A).
Table 4 shows the test results.
Example 27 and Comparative Example 19
In each of Example 27 and Comparative Example 19,
staple fibers were produced in the same manner as in
Example 26, except that the extrusion holes of the
spinneret were changed to those having a cross-sectional
profile as shown in Fig. 2-(b) for Example 27 and in
Fig. 2-(c) for Comparative Example 19. Table 4 shows the
test results.
INDUSTRIAL APPLICABILITY
The synthetic staple fibers of the present invention
have the above-mentioned fiber length and irregular
cross-sectional profile having a specific D/L ratio
value. Due to these properties, the staple fibers of the
present invention can form a uniform air-laid nonwoven
fabric having reduced defects even under a high watercontent
condition under which the conventional staple
fibers exhibit a degraded opening property and make it
difficult to produce an air-laid nonwoven fabric having a
high grade, and even when the staple fibers have a low
thickness, a high degree of crimping, a low degree of
crimping (including no crimp) and/or a high water
content, and even when the staple fibers is formed from a
high frictional resin. Accordingly, the synthetic staple
fibers of the present invention greatly contributes to
diversifying the constitution and function of air-laid nonwoven fabrics.




We claim:
1. Synthetic staple fibers for an air-laid nonwoven fabric, which staple fibers have a fiber length of 0.1 to 45 mm and a cross-sectioned profile having 1 to 30 concavities each satisfies the requirement: D/L = 0.1 to 0.5, wherein D represents a largest distance between a tangent line drawn to a pair of convexities from which an opening of the concavity is defined, and a bottom of the cancavity, measured in a direction at right angles to the tangent line, and L represents a distance between two points of contact of the pair of convexities with the tangent line.
2. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 1, having a water content of 0.6% by mass or more but not more than 10% by mass.
3. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 1, having a thicknessof 5 dtex or less.
4. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 1, having a number of crimps of 0 to 5 crimps/25 mm or 15 to 40 crimps/25 mm.
5. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 1, wherein at least a portion of the peripheral surface of each staple fiber is formed from at least one member selected from the group consisting of polyester resins, polyamide resins, polypropylene resins, high pessure low density poethylene resins, linear low density poethylene resins and elastomer resins.
6. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 1, wherein at least one functional agent is adhered in an amount of 0.01 to 10% by mass on the basis of the mass of the staple fibers, to the surfaces of the staple fibers.
7. The synthetic staple fibers for an air-laid nonwoven fabric as claimed in claim 6, wherein the functional agent is sleeted from the group consisting of deodorant functional agents, antibacterial functional agents, flame retardant functional agents and vermin repellent functional agents.


Documents:

2053-DELNP-2006-Abstract-(31-03-2009).pdf

2053-delnp-2006-abstract.pdf

2053-DELNP-2006-Claims-(31-03-2009).pdf

2053-delnp-2006-claims.pdf

2053-DELNP-2006-Correspondence-Others-(31-03-2009).pdf

2053-delnp-2006-correspondence-others-1.pdf

2053-delnp-2006-correspondence-others.pdf

2053-delnp-2006-description (complete).pdf

2053-DELNP-2006-Drawings-(31-03-2009).pdf

2053-DELNP-2006-Form-1-(31-03-2009).pdf

2053-delnp-2006-form-1.pdf

2053-delnp-2006-form-13-(30-06-2006).pdf

2053-delnp-2006-form-13.pdf

2053-delnp-2006-form-18.pdf

2053-DELNP-2006-Form-2-(31-03-2009).pdf

2053-delnp-2006-form-2.pdf

2053-delnp-2006-form-26.pdf

2053-DELNP-2006-Form-3-(31-03-2009).pdf

2053-delnp-2006-form-3.pdf

2053-DELNP-2006-Form-5-(31-03-2009).pdf

2053-delnp-2006-form-5.pdf

2053-delnp-2006-pct-210.pdf

2053-delnp-2006-pct-304.pdf

2053-delnp-2006-pct-311.pdf


Patent Number 233820
Indian Patent Application Number 2053/DELNP/2006
PG Journal Number 18/2009
Publication Date 01-May-2009
Grant Date 13-Apr-2009
Date of Filing 17-Apr-2006
Name of Patentee TEIJIN FIBERS LIMITED
Applicant Address 6-7, Minamihommachi 1-chome, Chuo-ku, Osaka-shi, Osaka 541-0054, JAPAN
Inventors:
# Inventor's Name Inventor's Address
1 GODA, HIRONORI c/o Teijin Fibers Limited, Matsuyama Factory, 77, Kitayoshidacho, Matsuyama-shi, Ehime, 7918041, Japan
2 YAMAMOTO, NOBUYUKI c/o Teijin Fibers Limited, Matsuyama Factory, 77, Kitayoshidacho, Matsuyama-shi, Ehime, 7918041, Japan
PCT International Classification Number D04H 1/42
PCT International Application Number PCT/JP2005/003541
PCT International Filing date 2005-02-23
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2004-045804 2004-02-23 Japan