Title of Invention

A METHOD AND APPARATUS FOR MEASURING OIL EFFLUENT FLOW RATES

Abstract The invention relates to a flow rate measurement method adapted to oil effluents made up of multiphase fluid mixtures comprising water. oil, and gas. The effluent is passed through a Venturi in which the effluent is subjected to a pressure drop (&#916;P), a mean value (<&#916;P>) of the pressure drop is determined over a period tl corresponding to a frequency t that is low relative to the frequency at which gas and liquid alternate in a slug flow regime, a mean value (&#961;<sub>m</sub>) is determined for the density of the fluid mixture at the constriction of the Venturi over said period t<sub>1</sub>, and a total mass flow rate value < Q > is deduced for the period t<sub>1</sub> under consideration from the mean values of pressure drop and of density .
Full Text

A METHOD AND APPARATUS FOR MEASURING OIL EFFLUENT FLOW RATES
The invention relates in general to measurements intended to determine at least one characteristic of oil well effluents made up of multiphase fluids, typically comprising three phases: two liquid phases - crude oil and water - and one gas phase based on hydrocarbons. The characteristics in question are specifically the proportions of the component phases, including the water content of the liquid phase, and the flow rate values - total flow rate and the flow rates of the various phases. The ability of the oil industry to optimize production of a reservoir relies on the possibility of evaluating the well effluent at regular intervals, in terms of quantity (flow rate) and of composition (the proportions of the various phases). This makes it possible to determine what corrective action may need to be taken. However, measuring the flow rate of oil well effluent is a problem that is complex because of the way effluents are usually made up of three phases, and because of the changes in flow conditions to which they are subject (pressure, temperature, shape of pipes). These factors give rise to a wide variety of flow regimes being observed, including some regimes of highly non-uniform and unstable character, with the proportions of the phases in the fluid mixture being capable of varying very considerably both in the flow direction (i.e. over time) and across the flow direction, in the form of phase stratification across the flow section. One extreme, but very common, case is slug flow i.e. that of a high gas content with the flow being made up of an alternation of portions that are essentially gas, known as "pockets", and portions that are constituted essentially by liquid, known as "plugs".
In the oil industry, the traditional practice is to separate the effluent into its component phases and to perform measurements on the phases separated in this way. However that technique requires separators to be installed on site, where separators are bulky and expensive items of equipment, and while wells are being tested, it also requires additional pipes to be put into place.
Numerous proposals have been put forward for developing techniques that would make it possible to avoid using such separators. A description of these developments is

to be found in SPE publication 28515 (SPE Annual Technical Conference, New
Orleans, September 25-28, 1994) by J, Williams, "Status of multiphase flow
measurement research".
Most of the propositions suggest firstly a total flow rate sensor and secondly sensors
for measuring the proportions of the phases in the mixture.
Amongst those proposals, US patent 4,788,852 describes apparatus comprising a
Venturi and a device for measuring gamma ray attenuation at three different energy
levels, the device being situated at the constriction of the Venturi.
British patent application 2 128 756 explains that it is necessary to determine two of
the following three magnitudes: total mass flow rate, total volume flow rate, and mean
density of the fluid. In order to compensate for non-uniformities in the flow, which
give rise in particular to differences of speed between the gas and the liquid phase,
thereby making any flow rate measurement difficult, and also making density
measurements inaccurate, it proposes homogenizing the fluid upstream from the
sensors by means of an appropriate device. In addition to improving the quality of
mean density measurement, homogenization has the effect of equalizing the speeds of
the gas and liquid phases, and thus of enabling the gas flow rate to be measured.
An application of that principle is described in document WO 90/13859 which
provides firstly a Venturi and a gamma ray density meter placed at the constriction of
the Venturi, and secondly a mixer upstream from the Venturi for the purpose of
homogenizing the multiphase fluid entering the Venturi, Nevertheless, the cost and
the size of such apparatus may limit its commercial applications.
The invention seeks to characterize three-phase oil effluents by means that are simple
and cheap, and that are applicable to a wide variety of flow regimes, and in particular
to slug flow.
In one aspect, the invention provides a flow rate measurement method adapted to oil
effluents made up of multiphase fluid mixtures comprising water, oil, and gas, the
method comprising the following steps: the effluent is passed through a Venturi in
which the effluent is subjected to a pressure drop; a mean value of the pressure drop is
determined over a period t1 corresponding to a frequency f1 that is low relative to the
frequency at which gas and liquid alternate in a slug flow regime; a mean value is

determined for the density of the fluid mixture at the constriction of the Venturi over
said period ti; and a total mass flow rate value is deduced for the period ti under
consideration from the mean values of pressure drop and of density.
Appropriately, the density of the fluid mixture is measured by gamma ray attenuation
at a first energy level at a frequency f2 that is high relative to said frequency of
gas/liquid alternation in a slug flow regime, and the mean of the measurements
obtained in this way over each period t1 corresponding to the frequency fi is formed to
obtain said mean density value.
Appropriately, the frequency f1 is 0.1 Hz or less than 0.1 Hz, e.g. 0.01 Hz.
Appropriately, the frequency f2 is greater than 20 Hz, and preferably greater than
40Hz, e.g. being equal to 45 Hz.
The invention will be well understood on reading the following description made with
reference to the accompanying drawings, in which:
Figure 1 is a diagram of flow measuring apparatus suitable for oil well effluents; and
Figure 2 is a block diagram illustrating the data processing operations performed by
the apparatus of Figure 1, in two embodiments.
Oil effluents are usually made up of a multiphase mixture of liquid oil, of gas
(hydrocarbons), and of water. Below we use the following notations: the symbols Q
and q designate mass flow rates and volume flow rates respectively; the symbol p
designates density; the symbols a and y designate the static and dynamic proportions
of the various phases; and the indices o, w, g, and 1 refer respectively to the oil, water,
gas, and liquid phases (where the liquid phase is the oil and the water taken together),
while the index m designates the fluid mixture.
The device comprises a pipe section 10 comprising a convergent Venturi 11 whose
narrowest portion 12 is referred to as the throat. In the example shown, the section of
the pipe 10 is disposed vertically and the effluent flows upwards, as symbolized by
arrow F.
The constriction of the flow section in the Venturi induces a pressure drop Ap between
level 13, situated upstream from the Venturi at the inlet to the measurement section,
and the throat 12. This pressure drop is associated with the total mass flow rate Q and
with the density pm by the following equation:


In a preferred embodiment, the ratio p is 0.5. With a pipe having a diameter of 10 cm, the diameter of the throat is 5 cm. The discharge coefficient C is about 1. This coefficient depends to a small extent and in predictable manner on the properties of the fluid. Traditionally, this corrective effect is taken into account by the Reynolds number.
The pressure drop Ap is measured by means of a differential pressure sensor 15 connected to two pressure takeoffs 16 and 17 opening out into the measurement section respectively at the upstream level 13 and in the throat 12 of the Venturi. In a variant, the measurement may also be performed by means of two absolute pressure sensors connected to the pressure takeoffs 16 and 17, respectively. The density pm of the fluid mixture is determined by means of a sensor which measures the attenuation of gamma rays, by using a source 20 and a detector 21 placed on opposite sides of the Venturi throat 12. The throat is provided with "windows" of a material that shows low absorption of photons at the energies under consideration. The source 20 produces gamma rays at two different energy levels, referred to below as the "high energy" level and as the "low energy" level. The detector 21 which comprises in conventional manner a scintillator crystal such as Nal and a photomultiplier produces two series of signals Whi and Wio referred to as count rates,

representative of the numbers of photons detected per sampling period in the energy
ranges bracketing the above-mentioned levels respectively.
These energy levels are such that the high energy count rate WM is essentially sensitive
to the density pm of the fluid mixture, while the low energy count rate Wio is also
sensitive to the composition thereof, thus making it possible to determine the water
content of the liquid phase.
Preferably the high energy level lies in a range 85 keV to 150 keV. For characterizing
oil effluent, this energy range presents the remarkable property that the mass
attenuation coefficient of gamma rays therein is substantially the same for water, for
sodium chloride, and for oil, being about 0.17 cm2/g. This means that based on the
high energy attenuation, it is possible to determine the density pm of the fluid mixture
without the need to perform auxiliary measurements to determine the properties of the
individual phases of the fluid mixture (attenuation coefficients and densities).
The attenuation measured by the detector 21 is expressed by the following equation:
A = Dv.Vm.|3m (3)
where Dy is the distance travelled through the fluid, i.e. in this case the diameter of the Venturi throat, and Vm is the mass attenuation coefficient of the fluid mixture. Since the mass attenuation coefficients of water and oil in the above-indicated energy range are substantially identical, and since the contribution of the gas is negligible because of its very low density, the mass attenuation coefficient Vm, and thus the product Dv.Vm that appears in equation (3) can be considered as being substantially constant and independent of the densities po and pw of the oil and water phases. Under such conditions, the high energy attenuation AM is a very advantageous indicator of the density pm of the mixture.
A material that is suitable for producing high energy gamma rays in the energy range under consideration, and low energy rays is gadolinium 153. This radioisotope has an emission line at an energy that is approximately 100 keV (in fact there are two lines around 100 keV, but they are so close together they can be treated as a single line), and that is entirely suitable for use as the high energy source. Gadolinium 153 also has an emission line at about 40 keV, which is suitable for the low energy level that is used to determine water content. This level provides good contrast between water and oil.

since the attenuation coefficients at this level are significantly different, typical values being 0.228 cmVg for oil and 0.291 cm2/g for sea water.
Figure 1 also shows a pressure sensor 22 connected to a pressure takeoff 23 opening out into the throat 12 of the Venturi, which sensor produces signals representative of the pressure pv in the throat of the Venturi, and a temperature sensor 24 producing signals T representative of the temperature of the fluid mixture. The data pv and T is used in particular for determining gas density pg under the flow rate conditions and gas flow rate qg under normal conditions of pressure and temperature on the basis of the value for the flow rate under the flow rate conditions, determined in a manner described below. In this respect, it is preferable for the pressure to be measured at the throat of the Venturi. In contrast, it does not matter where temperature is measured. The information coming from the above-mentioned sensors is applied to a data processing unit 30 constituted by a computer running a program for delivering the looked-for results by performing various treatments based on the principle explained below. In the explanation, reference is made to the block diagram of Figure 2.
1 - Determining total mass flow rate
The need is to determine the total mass flow rate Q in a manner that is adapted to the particularly difficult case of the effluent flow regime being of the pocket-and-plug type, also called slug flow i.e. when the flow is in the form of alternating portions made up essentially of gas, known as "pockets", and portions made up essentially of liquid.
A mass flow rate value , referred to below as the mean mass flow rate, is determined (block 35) by applying above equation (2) to values defined as means and of the pressure drop Ap and of the density of the mixture pm over a time interval t1 which is long relative to the gas/liquid alternation period of a pocket-and-plug flow:
= k(

)'/2 (4)
It has been found that this method gives results that are robust and of satisfactory accuracy, contrary to what might have been expected, given that equation (2) is nonlinear and equation (4) is a priori only applicable to a single-phase liquid since the

values both of pressure drop Ap and of density pm are subject to extremely sudden variations in a slug flow made up of pockets and plugs. Such a method of determining mass flow rate transforms a multiphase flow, even a flow that is extremely nonuniform such as slug flow, into a virtual single-phase flow, in that it makes equation (4) above, that applies to single-phase flows, applicable to multiphase flows. The method can thus be depicted as performing a "virtual homogenization". The period of gas/liquid alternations in a slug flow can vary widely, depending on circumstances: typically it lies in the range 0.1 to 10 seconds. The duration ti over which the above-mentioned mean values are defined must be long relative to said alternation period. It is appropriate to set it at a value that is not less than the upper limit of the above-mentioned range, i,e. 10 s, which corresponds to a frequency, written fi, of 0.1 Hz.
In the preferred implementation of the invention, these mean values are obtained as follows.
As explained above, the density is determined from the high energy attenuation WM at a frequency fa which is high relative to the gas/liquid alternation frequency in a slug flow (block 40). Starting from values pm(i) respectively obtained for intervals t1 corresponding to the frequency f2, a mean density value is calculated over a duration corresponding to above-mentioned frequency f1 (block 41). Such a method is adapted to the non-linear character of the equation relating the count rate Whi to the density pm of the fluid mixture. It is appropriate for the frequency fz to be at least 20 Hz, preferably at least 40 Hz, and for example 45 Hz.
Measurements are acquired at such a sampling frequency by means of a specialized electronic circuit associated with the detector 21 but not shown in Figure 1. The circuit is implemented in accordance with the teaching of US patent 5,349,195, and it need not be described in detail herein. Such a circuit provides fast and reliable processing of the pulses sensed in each energy window.
The inherent response time of the differential pressure sensor 15 is considerably slower than the time corresponding to the frequency fa, for example it is about 0.5Hz. However, to simplify implementation, differential pressure measurement samples are

similarly acquired at the frequency f2 (45Hz in the example described) and the desired mean value is obtained by averaging the measured samples Ap(i). The mean value used in determining the total mass flow in application of above equation (4) is obtained from the mean values and .
2 - Determining water content
The detector 21 measures attenuation of gamma rays by the fluid mixture at the two
above-mentioned energy levels:

where A stands for attenuation and Whi,o and Wio.o are the high and low count rates in the absence of attenuation, as obtained by calibration.
As already mentioned above, the attenuation of the gamma rays by the fluid mixture is as follows:

where Dy is the diameter of the throat of the Venturi and Vm is the mass attenuation
coefficient of the fluid mixture.
Given that the density of the gas phase is very low, it is possible to make the following
approximations:
Vm^Vi and pm^oti-pi where Vi is the mass attenuation coefficient of the liquid (oil and water together) and ai is the volume fraction of the liquid, and hence:
Am = Dv.Vi.pi.ai The mass attenuation coefficient of the liquid Vi is a function of the attenuation coefficients of oil and water Vo and Vw, and of the water/liquid mass ratio (WLR):

The water/liquid mass ratio WLR can be determined from the high and low energy attenuations in the mixture, given the attenuations in oil and in water as determined by calibration, by using the following expression:
(5)

where Xm, Xo, and A^ are the ratios of high energy attenuation over low energy attenuation for the fluid mixture, for oil, and for water, respectively:

The values of the water/liquid mass ratio WLR(i) are thus calculated for each of the sampling intervals t2(i) corresponding to the frequency f2 which is equal to 45 Hz in the example described, on the basis of the measurements Whi(i) and Wjo(i) acquired over the interval under consideration (block 50). Thereafter (block 51) a mean value is calculated over the interval t1 corresponding to the frequency f1 at which the mass flow rate Q is determined, with the values WLR(i) being weighted by respective confidence coefficients C(i).
The water ratio WLR is relative to the quantity of liquid in the fluid mixture. The measurement of WLR therefore applies to this quantity of liquid. When the gas content is high, the liquid content is small. Also attenuation is low because the density of the fluid mixture is low. Under such circumstances, the measurements relating to the proportions of water and oil in the liquid cannot be of good quality. The confidence coefficient should therefore decrease with increasing gas content. Since the density pm of the fluid mixture is a sensitive indicator of its gas content, the confidence coefficient C(i) is advantageously determined as a function of the density pm. (This choice is justified by the assumption that there is no systematic correlation between the composition of the liquid as expressed by the water fraction WLR, and the gas content as given by the density p™ of the mixture.) Such a function can have several different forms. By way of example, the confidence coefficient may merely be equal to the density pm. Naturally, other types of function can be envisaged. Also, the parameter used could be the variation in the density pm rather than the density proper, or a combination of these factors could be used.
To sum up, each value of WLR(i) is associated with a confidence coefficient C(i) determined as a function of the density pm(i) obtained as described above, and the mean value is a weighted mean of the values WLR(i):

= (1 C(i).WLR(i))/Σ C(i) where Σ symbolizes the sum of the values lying in the interval ti under consideration. From the mean value obtained for the mass fraction of water, it is possible to determine the density of the liquid phase p1 and the mean value of the volume fraction of water , knowing the densities Pw and po of water and oil respectively in the effluent. The density values pw and po and the density of gas pg (under the flow conditions) can be obtained in various ways by auxiliary measurements that are known per se. By way of example, for the liquid phases, mention can be made of the sampling device described in French patent application 96 14292 filed on November 22, 1996. The density of the liquid phase is obtained (block 52) from the following equation:
1/p, = /pw + (1 - )/po and the mean volume fraction of water (block 53) is given by:
= pw/pi. It should be observed that the water content of the liquid phase is a characteristic of the effluent which is stable (or at any rate which varies slowly), unlike the gas content of the mixture. It is therefore appropriate to determine pi at the frequency fi, as a function of the mean value ,
In addition, starting from the density of the liquid phase pi determined as described above, and from the density of the gas phase Pg under flow conditions, it is possible (block 54) to determine the proportions of liquid ai and of gas ag at the frequency fa using the following equations:
ai(i) = (pm(i) - pg)/(pi - Pg)
ai + ttg = 1
3 - Determining the oil and the water flow rates
The gas mass flow rate Qg is negligible relative to the liquid mass flow rate because of the low density of the gas. It can therefore be assumed that the liquid mass flow rate Qi is approximately equal to the total mass flow rate Q:
Qi-Q

The oil and water mass flow rates can then be determined (block 60) approximately from the following equations:
Qw = . and Qo = - Qw The water and oil volume flow rates qw and qo are deduced from the mass flow rates Qw and Qo (block 61) given the respective densities pw and po of water and oil in the effluent:
qw = Qw/rw and qo = QJpo The volume flow rate of the liquid qi can then be determined as the sum of the oil and water flow rates:
q1 = qo+qw or equivalently:
q, = Q,/p, = Q/p,
The values obtained in this way are approximate since they assume that the gas flow rate is negligible. For more accurate determination, account is taken of the presence of gas, expressed by the volume fraction of the gas. Since the speed of gas is higher than that of the liquid (a phenomenon known as "slip"), it is necessary to make use not of the liquid and gas proportions at and ag as deduced in the manner given above from the gamma ray attenuation measurements since those proportions are static proportions, but instead to make use of dynamic proportions Y1 and Yg (with YI + Yg = 1) which take the slip phenomenon into account, which proportions are respectively lower than and greater than the static proportions ai and ttg. This is expressed by the equation:
Yg = ttg + 5g(ag) where 8g(ag) is the slip term and represents a positive correction. When dealing with values at the throat of the Venturi, it has been found that the dynamic proportions can be determined as a function solely of the gas proportion ag and are therefore essentially independent of flow rate. A suitable example of the empirical equation making such determination possible is of the form:
Yg(i) = ag(i)-+(Yl(i))"(l-Yi(i)r where the coefficient A and the exponents m and n are determined empirically, A
suitable example corresponds to the following values; A = 1, m = 1, n = 6. This

equation makes it possible by iterative computation to determine the dynamic
proportion y1 from the static proportion a1 (block 55).
Using the values of Yi(i) as determined at the high frequency f2 (45 Hz in this example),
a mean value is calculated (block 56) over each interval ti (i.e. 10 s in the
example described) corresponding to the frequency f1.
The liquid volume flow rate q1 can then be obtained at frequency f1 from the total mass
flow rate . The total volume flow rate, taking account of slip, is given (block 70)
by the following equation:
q = Q/pH where the magnitude pH is a value for the density of the mixture, known as the "homogeneous density", that takes account of the slip phenomenon, and that is obtained (block 57) from the equation:
pH = P1 + Pg and the liquid flow rate q1 is given (block 71) by:
q1=qy1
From which the water and oil flow rates are deduced (block 72): qw = qi qo = (l -)qi
4 - Determining gas flow rate
To determine the gas flow rate, a suitable method, different from that described above, relies on an "instantaneous" value for the total mass flow rate Q(i) calculated (block 80) for each sample corresponding to the high frequency fz (45 Hz in the example described) in application of the following equation:
Q(i) = k[( - pm(i).g.hv).p™(i)]'/2 with the notation being the same as above. An "instantaneous" value for the total volume flow rate is then deduced (block 81):
q(i) = Q(i)/pH(i) where pH(i) is the "homogeneous density" as defined above, determined for each sample at the high frequency f2 (block 58) as follows:

pH(i) = Yi(i)pi + Yg(i)pg Based on this value for the total volume flow rate, an "instantaneous" value for the gas flow rate qg(i) is determined (block 82) for each sample at the high frequency f2:
g(i) = yg(i)q(i)
and finally the gas flow rate qg is calculated by averaging the values qg(i) over each interval ti (10 seconds in the example described) corresponding to the low frequency fi (block 83),



CLAIMS
1. A flow rate measurement method adapted to oil effluents made up of multiphase fluid mixtures comprising water, oil, and gas, comprising the following steps: the effluent is passed through a Venturi in which the effluent is subjected to a pressure drop (Ap); a mean value () of the pressure drop is determined over a period ti corresponding to a frequency f1 that is low relative to the frequency at which gas and liquid alternate in a slug flow regime; a mean value () is determined for the density of the fluid mixture at the constriction of the Venturi over said period t1; and a total mass flow rate value is deduced for the period t1 under consideration from the mean values of pressure drop and of density.
2. A method according to claim 1, in which the density of the fluid mixture (pm) is measured by gamma ray attenuation at a first energy level at a frequency fz that is high relative to said frequency of gas/liquid alternation in a slug flow regime, and the mean () of the measurements pm(i) obtained in this way over each period t1 corresponding to the frequency f1 is formed to obtain said mean density value.
3. A method according to claim 1 or 2, in which the frequency f1 is not greater than 0.1 Hz.
4. A method according to claim 2 or 3, in which the frequency fz is not less than 20 Hz.
5. A method according to any one of claims 2 to 4, in which the attenuation of gamma rays by the fluid mixture is measured at the frequency f2 at a second energy level lower than the first energy level, this measurement being performed at the constriction of the Venturi, and a value WLR(i) is deduced therefrom for the mass ratio of water relative to the liquid component of the fluid mixture.

6. A method according to claim 5, in which each of the measurements at said second energy level is associated with a confidence coefficient relating to the corresponding value pm(i) of the density of the fluid mixture, said coefficient being small when the density is low and higher at densities corresponding to a low proportion of gas.
7. A method according to claim 5 or 6, in which approximate values for the mass flow rate Qo and Qw and for the volume flow rates qo and qw of the oil and of the water are deduced from said total flow rate value and the water ratio WLR.
8. A method according to claim 5 or 6, in which the static proportions of liquid ai(i) and of gas ag(i) at the frequency f2 are deduced from the measurements of the fluid mixture density pm(i) and of the water mass ratio WLR(i) at said frequency.
9. A method according to claim 8, in which the dynamic proportions of liquid Yi(i) and of gas Yg(i) at the frequency f1 are deduced from the corresponding static proportions using a determined relationship.

10. A method according to claim 9, in which, from said dynamic proportions, mean values and are determined over each interval t1 corresponding to said frequency f1.
11. A method according to claim 10, in which the total volume flow rate is deduced from the total mass flow rate , from said mean values and > and from the liquid and gas densities, and the volume flow rates of oil and of water are deduced therefrom.
12. A method according to claim 9, in which total mass flow rate values Q(i) are determined at the frequency f1 as a function of the corresponding density values pm(i), gas flow rate values qg(i) are deduced from said values Q(i), from the dynamic proportions of liquid Yi(i) and of gas Yg(i), and from the liquid and gas densities, and

the mean of the values qg(i) is calculated to obtain a value for the gas flow rate over each interval t1.
13. A flow rate measurement method adapted to oil effluents made up of multiphase fluid mixtures, substantially as herein described with reference to the accompanying drawings-


Documents:

1922-mas-1998-abstract.pdf

1922-mas-1998-claims filed.pdf

1922-mas-1998-claims granted.pdf

1922-mas-1998-correspondnece-others.pdf

1922-mas-1998-correspondnece-po.pdf

1922-mas-1998-description(complete)filed.pdf

1922-mas-1998-description(complete)granted.pdf

1922-mas-1998-drawings.pdf

1922-mas-1998-form 1.pdf

1922-mas-1998-form 26.pdf

1922-mas-1998-form 3.pdf

1922-mas-1998-form 5.pdf

1922-mas-1998-other documents.pdf

1922-mas-1998-pct.pdf


Patent Number 212434
Indian Patent Application Number 1922/MAS/1998
PG Journal Number 07/2008
Publication Date 15-Feb-2008
Grant Date 03-Dec-2007
Date of Filing 25-Aug-1998
Name of Patentee SCHLUMBERGER HOLDINGS LIMITED
Applicant Address P O BOX 71, CRAIGMUIR CHAMBERS, ROAD TOWN -TORTOLA,
Inventors:
# Inventor's Name Inventor's Address
1 MICHEL BERARD 176, RUE DE PARIS, 91120 PALAISEAU,
2 GERARD SEGERAL 56 , AVENUE CENTRALE , 91190 GIF SUR YVETTE ,
PCT International Classification Number G 01 F 1/04
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 97 10648 08 1997-08-29 France