Title of Invention

A LAMINAR MATERIAL SUITABLE FOR USE IN THE MANUFACTURE OF SHOES AND A METHOD OF MAKING THE SAME

Abstract A laminar material suitable for use in the manufacture of shoes comprising an extruded thermoplastic sheet core having laminated thereto on at least one side a fibre fabric layer, the thermoplastic sheet - core,•comprising a mixture of granulated scrap shoe stiffener material with virgin extrudable thermoplastics material, the core including at 'least 40% by weight of extrudable thermoplastics material.
Full Text FORM 2
THE PATENTS ACT 1970
[39 OF 1970]
&
THE PATENTS RULES, 2003
COMPLETE SPECIFICATION
[See Section 10; rule 13]
"A LAMINAR MATERIAL SUITABLE FOR USE IN THE MANUFACTURE OF -SHOES AND A METHOD OF MAKING THE; SAME"
TEXON MANAGEMENT LIMITED, of 16a Fir Tree Lane, Groby, Leicester
LE6 0FH, United Kingdom,

The following specification particularly describes the invention and the manner in which it is to be performed:

The present invention relates to a laminar material suitable for use in the manufacture of shoes and a method of making the. same.
Technical Field
This invention is concerned with laminar materials suitable for use in the manufacture of shoes, methods of making the same and shoe 10 components comprising said laminar materials, especially shoe toe and heel end stiffeners and shoe insoles.
The term "shoe" where used herein is intended to denote outer footwear generally whether ready for wear or in the course of 15 manufacture.
Background Art
In the manufacture of shoes it is common practice to include at the 20 toe or heel end portion of the shoe, shoe stiffeners commonly referred to as toe puffs or counters respectively. The purpose of the stiffeners is to provide adequate support to the material of the shoe upper to retain the shoe in shape, for example during wear. Toe puff and counter materials commonly have a degree of stiffness and resilience, the stiffness being 25 necessary to retain the uppers in a desired shape and the resilience being required to return the shoe to the desired shape should the upper be deformed for any reason.
It is well know to those skilled in the art that such shoe stiffeners 30 may be cut from sheet shoe stiffener materials in a suitable shape for

incorporation into a shoe upper. As a result of cutting the shoe stiffeners from the sheet material, scrap sheet material remains which has openings in it corresponding to the shape of the shoe stiffener. Such scrap material has, in the past, been disposed of as waste, eg in land fill sites because 5 there has been no convenient way to re-use this scrap material efficiently. This especially has been the case with impregnated fibre fabric shoe stiffener materials and with stiffener materials consisting of fibre fabrics laminated with extruded thermoplastics sheets (both of which have been extensively used in the manufacture of shoes). On the contrary, scrap 10 from shoe stiffener materials made solely from extruded plastics sheet can be relatively easily recycled, in comparison with those based on latex-impregnated fabrics and fabric film laminates which do not have suitable thermoplastic/melt characteristics.
15 Disclosure of the invention
One of the various objects of the present invention is to provide an improved laminar material suitable for use in the manufacture of shoes.
20 Another of the various objects of the present is to provide an
improved laminar material which can incorporate cutting scrap (which arises when shoe components are cut from laminar material) back into new product.
25 The applicant company has for many years produced a heel end
shoe stiffener material consisting of an extruded thermoplastic core laminated on each side to a non-woven fibre fabric impregnated with a polymeric thermoplastic stiffening material and coated on both sides with a suitable hot-melt adhesive, for example based on ethylene-vinyl acetate
30 copolymer. It has surprisingly been found that it is possible to granulate


and re-use cutting scrap from this type of material in the manufacture of a generally similar material, except that the thermoplastic core includes not only virgin polymeric thermoplastics material but also the granulated cutting scrap.
5
The invention may be considered to provide, in one aspect, a laminar material suitable for use in the manufacture of shoes comprising an extruded thermoplastic sheet core having laminated thereto on at least one side a fibre fabric layer, the thermoplastic sheet core comprising a 10 mixture of granulated scrap shoe stiffener material with virgin extrudable thermoplastics material, the core including at least 40% by weight of thermoplastics material.
Preferably in a laminar material in accordance with the invention 15 the (or each) fibre fabric layer is a non-woven fabric, preferably a needled non-woven fabric of a type well known to those skilled in the art. Any suitable fibres may be used but the preferred fibres are polyester of about 6-7 decitex. Preferably, the fibre fabric layer is impregnated with a polymeric thermoformable stiffening material; suitable materials are well 20 known to those skilled in the art and may include, for example, high styrene content styrene butadiene copolymers.
A laminar material in accordance with the invention suitable for use as a shoe heel or toe end stiffener preferably has a hot-melt adhesive 25 coating on the surface of the fabric layer remote from the thermoplastic core.
A preferred laminar material in accordance with the invention has a fibre fabric layer laminated to each side of the thermoplastic core.
30

In a laminar material in accordance with the invention the amount of virgin extrudable thermoplastics material included in the core is sufficient to provide satisfactory melt characteristics for extrusion of the mixture of granulated scrap shoe stiffener material and virgin 5 thermoplastics material to provide the thermoplastic core. The amount of virgin thermoplastics material required is dependent to some extent on the amount of extrudable thermoplastics material present in the scrap shoe stiffener material. At least 40% by weight extrudable thermoplastics material appears to be necessary for satisfactory performance. For many
10 materials 40% by weight of virgin thermoplastics material is necessary. Although as much virgin thermoplastics material as is necessary may be used in order to provide suitable properties it is desirable to use no more than 60% virgin thermoplastics material, otherwise it may prove to be impossible to re-use all of the scrap material, thus reducing the overall
15 efficiency of the process.
In the manufacture of a laminar material in accordance with the invention it is, of course, important that the thermoplastics components used in the adhesive and in the core material are compatible with one 20 another so that the performance of the finished product is consistent.
In one laminar material in accordance with the invention the shoe
stiffener material which is granulated to provide the scrap comprises a
core of extruded thermoplastics sheet material having laminated to both
25 sides a fibre fabric layer impregnated with a polymeric stiffening material
the fabric layers each having a heat-activatable adhesive coating.
In a preferred laminar material in accordance with the invention the material which is granulated to provide the scrap has the same general 30 construction and composition as the laminar material.


Preferably in a laminar material in accordance with the invention the virgin thermoplastics material is substantially the same as the extnidable thermoplastics material in the core of the scrap shoe stiffener 5 material. In a laminar material in accordance with the invention the core conveniently comprises from 30% to 50% by weight of the total weight of laminar material.
A laminar material in accordance with the invention may 10 conveniently be used to provide a shoe toe or heel end stiffener. Laminar materials in accordance with the invention may also be used in the manufacture of shoe insoles which are also relatively stiff components. Insole materials of appropriate composition may also be recycled and are included in the term "stiffener material" where,referring to the invention 15 in its broadest aspects.
In another aspect the invention may be considered to provide a method of making a laminar material comprising the steps of; -
20 (i) procuring scrap shoe stiffener material
(ii) granulating the scrap material
(iii) mixing the granulated scrap material with virgin extnidable
25 thermoplastics material sufficient to provide at least 40% by weight
of extnidable thermoplastics material
(iv) melting the virgin thermoplastics material and thermoplastics material in the scrap and extruding the molten mixture of virgin

thermoplastics material and scrap material to form a thermoplastic sheet core; and
(v) laminating a fibre fabric with the mixture as it is extruded to form
5 the sheet core whereby to provide a fibre fabric layer on at least
one surface of the core.
Preferably a method in accordance with the invention comprises the further steps of 10
(vi) impregnating the fibre fabric layer or layers of the laminate produced by step (v) with a polymeric thermoformable stiffening material in fluid form; and
15 (vii) drying, cooling or curing the fluid impregnant to provide a thermoplastics stiffening material impregnating the fibre fabric layers.
Preferred polymeric thermoformable stiffening materials are
20 aqueous dispersions of a high styrene content thermoformable polymeric
material, for example styrene-butadiene copolymer comprising 80% by
weight styrene. Such materials are well known to those skilled in the
manufacture of shoe stiffener materials. Alternatively, the polymeric
stiffening material may be applied in the form of a solution or by reacting
25 liquid components which themselves react to form a thermoformable
polymeric stiffening material. The liquid polymeric stiffening material
may conveniently be applied by passing the laminate through an
impregnating apparatus of known construction in which the laminate is fed
through an impregnant bath in which the liquid stiffening material is
30 absorbed by the fabric layers and then passed through the nip between a

pair of calendar rollers to control the amount of liquid material retained in the fabric layers.
A method in accordance with the invention also preferably 5 comprises the further step of (viii) applying a coating of hot-melt adhesive composition to the surface of the fibre fabric layer or layers. Any suitable hot-melt adhesive composition may be used, for example an ethylene-vinyl acetate copolymer hot-melt adhesive. Whereas, in a preferred method in accordance with the invention, the fabric layers are 10 impregnated with stiffener composition after they have been laminated to the thermoplastic core, the fabric layers may be impregnated with the stiffener material before lamination to the core, the fabric layers having been dried prior to lamination with the core.
15 There now follows a detailed description, to be read with reference
to the accompany drawing of a laminar material, a method of making the material and a shoe stiffener made of the material, embodying the invention. It will be realised mat this material, method and stiffener have been selected for description to illustrate the invention by way of example.
Brief Description of the Drawings
In me accompanying drawing Figure 1 is a partial view in section of a laminar material embodying the invention.
25
Modes of Carrying Out the Invention
Figure 1 shows a laminar material suitable for use in the
manufacture of shoes and, especially, suitable for use in the manufacture
30 of heel end shoe stiffeners. Properties of two illustrative materials are set


out in Table 1, together with properties of a previously known product for comparison. These illustrative materials each comprise an extruded thermoplastic sheet core 10 having laminated thereto on each side a fibre ( fabric layer 12. An ethylene-vinyl acetate hot-melt adhesive layer 14 is 5 applied onto the outer surfaces of both fibre fabric layers 12. Other hot-melt adhesive materials may be used if desired.
In the illustrative laminar materials the mermoplastic sheet core 10 comprises a mixture of granulated scrap shoe stiffener material with virgin 10 extrudable termoplastics material, the core including at least 40% by weight of extrudable uiermoplastics material. The granulated scrap shoe stiffener material is cutting scrap produced from a material which is of generally similar construction to the illustrative laminar material except mat the central thermoplastics core does not comprise any scrap material 15 but is of virgin polymeric thermoplastics material. In this scrap material, the polymeric material of the core comprises 70% by weight ethylene-vinyl acetate copolymer and 30% by weight polypropylene. In order to vary the stiffness of die thermoplastic core me proportion of ethylene-vinyl acetate copolymer to polypropylene may be varied - higher relative 20 amounts of polypropylene produce a stiffer core material. A balance must be struck between stiffness, mpldability in a shoe, shape retention and general wear characteristics. Other uiermoplastics materials may be used in shoe stiffener materials which may be used to provide me scrap, (for example the ionomeric resin supplied under me trade name Surlyn) 25 provided that the thermoplastics polymeric material which provides the core has appropriate melt and stiffness characteristics.
In order to produce the illustrative materials in carrying out a
method in accordance with the invention, the cutting scrap remaining from
30 a sheet of shoe stiffener material, following cutting out of shoe stiffeners,


is chopped up in a suitable apparatus, namely an Erema thermoplastic recycling machine which comprises a chopping arrangement in conjunction with an extruder. The scrap is first chopped up without causing the material to overheat (which might cause the adhesive coating 5 on the material to be activated and stick the particles of chopped material together to form a block), commonly referred to as "blocking". Prevention of blocking may be achieved by any convenient means, for example by controlling cutter power and feed rate of raw material and/or by the addition of another material, e.g. mineral filler that militates 10 against blocking and allows more vigorous cutting.
The chopped material is fed directly to a pelletising extruder which supplies the scrap material as a granulate or pellet of a size suitable for use in a plastics sheet extruding apparatus. The scrap granules are then
15 mixed with granules of virgin polymeric thermoplastics material of the same composition as the thermoplastics material in the core of the scrap material, namely ethylene-vinyl acetate copolymer blended with polypropylene. The mixed granules (or pellets) are then supplied to the sheet extruder in which they are melted and the melt fully blended and
20 thereafter extruded. The fibre fabric layers are laminated to the extruded thermoplastic sheet core as it leaves the extruder in a manner well known to those skilled in the art.
Although the thermoplastic sheet core of die illustrative laminar 25 materials comprises mainly granulated scrap shoe stiffener material and virgin polymeric thermoplastics material, other components may be included if desired, for example material commonly included in plastics compounds for extrusion purposes, including fillers, plasticizers and antioxidents and pigments if desired.
30


In the illustrative laminar materials, the thermoplastic sheet core
includes particles 16 of fibrous material arising from the granulated scrap
stiffener material. The particle size of the fibrous particles 16 varies over
a wide range but, in the first illustrative material typical particles 16 are
5 about 2-3mm in lengthwise and transverse dimension and about 0.5mm in
thickness; in the second illustrative material particle sizes are about 0.5
mm or less. Neverthieless the lengthwise and transverse dimensions of the
particles 16 in materials otherwise similar to me illustrative materials may
vary over a wide range and some may be as much 8mm by 5mm in some
10 final products.
The fibre fabric layers 12 of the illustrative laminar materials are needled non-woven fibre fabric layers in which the fibre is a polyester textile fibre of about 6.7 decitex and is produced by needling techniques in 15 a manner well known to those skilled in the art. The impregnant is a high styrene (including about 80% by weight styrene), styrene-butadiene copolymer latex, also well known to those skilled in the shoe stiffener art.
The granules or pellets of scrap material produced by the Erema 20 apparatus are typically between 3mm and 7mm in dimension but as discussed above the granule size is influenced by the operating conditions of the apparatus. Clearly where a relatively thin laminar material is to be made, the apparatus needs to be operated to produce relatively small granules - although part of the granules are thermoplastic material which 25 will melt and mix with the virgin thermoplastics material, the remainder may include clumps of fibre and, possibly, filler which will not melt and will remain as particulate material in the illustrative material.
The production of the granules of scrap material generates fibrous 30 particles 16 which may be considered to act as a filler in the extruded core


10. The dimensions of the fibrous particles have a bearing on the thickness of the extruded thermoplastic sheet core: particle sizes referred to above are used in the manufacture of a core having a weight of about 800 grams per square metre. For lighter weight cores more severe 5 chopping of the scrap shoe stiffener material before producing the scrap granules or pellets would be required (to reduce the average size of the fibrous particles 16). The core of 800 grams per centimetre is rather greater in thickness than the core of the scrap material which does not include any scrap in the manufacture of the core.
Adhesive coating weights are about the same in all cases.
Depending upon the properties required in the final product the weight of the felt non-woven fibre fabric layers and the impregnant
15 content may be varied. In the illustrative laminar materials each non-woven fibre fabric layer may have a weight of about 100 grams per square metre, the weight of impregnant in each of the fibre fabric layers is about 185 grams per square metre and the adhesive layers are each about 130 grams per square metre in weight with an extruded core of about 800
20 grams per square metre giving a total weight for the first illustrative laminar material of about 1630 grams per square metre. The second illustrative laminar material is similar but has a core of slightly lower weight per square metre.
25 The scrap sheet stiffener material used in the manufacture of the
illustrative lammar material has an extruded thermoplastic core of virgin polymeric thermoplastics material having a weight of about 580 grams per square metre, each of the non-woven fibre fabric layers has a weight of about 125 grams per square metre, the weight of the impregnated
30 polymeric stiffening material in each of the fabric layers is about 205

grams per square metre and the adhesive layers have the same weight, namely 130 grams per square metre giving a total weight of about 1500 grams per square metre. In the scrap material, the amount of available thermoplastics material is the sum of the core film and the adhesive and is 5 about 55% by weight. The impregnant is thermoformable but is not included as thermoplastics material for this purpose because although it is affected by heat and softened, making it more readily malleable it is not rendered molten in me extrusion process.
10 The illustrative laminar material is found to be satisfactory for use
in the production of shoe heel end stiffeners and has a performance which is generally comparable with the previously known material where the core is of virgin polymeric material and does not include any scrap stiffener material with any fibre content. The accompanying Table 1
15 gives an indication of a comparison of the illustrative laminar material as outlined above and a previously known heel end shoe stiffening product of the composition and construction noted above.

TABLE 1

Previously
known
product First
Illustrative Laminar Material Second Illustrative Laminar Material

Weight GSM (grams per square metre) 1446 1618 1507
Gauge mm 1.71 2.05 1.71
DLC 1st lbf (N) 46.7 42.5 45(204.7)
DLC 10th lbf(N) 21.1 21.1 24.7(112.3)
Resilience % 45 50 54.9
Tensile Tests Stress at Yield MPa AL
AX 7.9 6.6 11.7

7.1 4.9 6.8
Strain at Yield % AL
AX 2.4 2.3 2.7

2 2.3 2.1
Modulus at 5% MPa AL Extension AX 217 195 312

195 145 201
Karl Frank Stiffness (KF units) 2400 2320 2000
Flexural Modulus MPa 945 530 779
5
Whereas the compared products have roughly similar weights and
performances, there are naturally some minor variations.

WE CLAIM:
1. A laminar material suitable for use in the manufacture of shoes
comprising an extruded thermoplastic sheet core having laminated
thereto on at least one side a fibre fabric layer, the thermoplastic sheet
- core,•comprising a mixture of granulated scrap shoe stiffener material
with virgin extrudable thermoplastics material, the core including at
'least 40% by weight of extrudable thermoplastics material.
A laminar material as claimed in Claim 1 wherein the fibre fabric layer is non-woven fabric.
3. A laminar material as claimed in either one of Claims 1 and 2 wherein the fibre fabric layer is impregnated with a polymeric thermoformable stiffening material.
4. A laminar material as claimed in any one of the preceding claims wherein said at. least one fabric layer has a coating of hot melt adhesive on its surface remote from the thermoplastic core.
,5 A laminar material as claimed in any one the preceding claims having a fibre fabric layer laminated to both sides of the thermoplastic core.
6. A laminar material as claimed in any one the preceding claims comprising at least 40% by weight of virgin thermoplastics material.
7. A laminar material as claimed in any one A the preceding claims wherein the shoe stiffener material which is granulated to provide the scrap comprises a core of extruded thermoplastics sheet material having laminated to both sides a fibre fabric layer impregnated with a
'polymeric stiffening material the fabric layers each having a heat-activatable adhesive coating.

A laminar material as claimed in any one of Claims 1 to 6 wherein the material which is granulated to provide the scrap has the same general construction and composition as the laminar material.
A laminar material as claimed in any one of Claims 7 and 8 wherein the.: virgin thermoplastics polymeric material is substantially the same .. as the extrudable thermoplastics material in the core of the scrap shoe stiffener material.
A laminar material as claimed in any one of Claims 1 to 9 wherein the core comprises from 30 to 50% by weight of the total weight of the laminar material.
A method of making a laminar material as claimed in claim 1 comprising the steps of :
procuring a scrap shoe stiffener material;
granulating the scrap material;
mixing the granulated scrap material with virgin thermoplastics material sufficient to provide at least 40% by weight of extruded thermoplastics material;
melting the virgin thermoplastics material and thermoplastics material in the scrap and extruding the molten mixture of virgin thermoplastics material and scrap material to form a thermoplastic sheet core;
laminating a fibre fabric with the mixture as it is extruded to form the sheet core whereby to provide a fibre fabric layer on at least one surface of the core;

impregnating the fibre fabric layer or layers of the laminate produced by step (v) with a polymeric thermoformable stiffening material in fluid form;
drying, cooling or curing the fluid impregnant material to provide a thermoformable stiffening material impregnating the fibre fabric layers; and
applying a coating of a hot melt adhesive composition to the surface of the.fibre fabric layer or layers.
A laminar material as claimed in any one of Claims 1 to 10 made by a method as claimed in claim 11.
Dated this 6th day of September, 2001.
[RITUBHKA NEGI]
OF REMFRY & SAGAR
ATTORNEY FOR THE APPLICANTS.

Documents:

abstract1.jpg

in-pct-2001-01065-mum-assignment(10-06-2005).pdf

in-pct-2001-01065-mum-cancelled pages(10-06-2005).pdf

in-pct-2001-01065-mum-claims(granted)-(10-06-2005).doc

in-pct-2001-01065-mum-claims(granted)-(10-06-2005).pdf

in-pct-2001-01065-mum-correspondence(30-03-2006).pdf

in-pct-2001-01065-mum-correspondence(ipo)-(16-06-2004).pdf

in-pct-2001-01065-mum-drawing(10-06-2005).pdf

in-pct-2001-01065-mum-form 1(06-09-2001).pdf

in-pct-2001-01065-mum-form 13(10-06-2005).pdf

in-pct-2001-01065-mum-form 19(27-04-2004).pdf

in-pct-2001-01065-mum-form 1a(10-06-2005).pdf

in-pct-2001-01065-mum-form 2(granted)-(10-06-2005).doc

in-pct-2001-01065-mum-form 2(granted)-(10-06-2005).pdf

in-pct-2001-01065-mum-form 3(10-06-2005).pdf

in-pct-2001-01065-mum-form 6(10-06-2005).pdf

in-pct-2001-01065-mum-form-pct-ipea-409(16-06-2004).pdf

in-pct-2001-01065-mum-form-pct-isa-210(16-06-2004).pdf

in-pct-2001-01065-mum-petition under rule 137(10-06-2005).pdf

in-pct-2001-01065-mum-power of authority(10-06-2005).pdf


Patent Number 209311
Indian Patent Application Number IN/PCT/2001/01065/MUM
PG Journal Number 38/2007
Publication Date 21-Sep-2007
Grant Date 24-Aug-2007
Date of Filing 06-Sep-2001
Name of Patentee TEXON MANAGEMENT LIMITED
Applicant Address 16A FIR TREE LANE, GROBY, LEICESTER LE6 OFH, UNITED KINGDOM.
Inventors:
# Inventor's Name Inventor's Address
1 GARETH PARKER 67 SHANKLIN DRIVE, WEDDINGTON, NUNEATON, WARWICKSHIRE, CV 10 0BG, UNITED KINGDOM.
2 BRIAN ARNOLD 43 ORCHARD WAY, SYSTON, LEICESTER LE7 1AL, ENGLAND.
PCT International Classification Number B32B 27/12
PCT International Application Number PCT/GB00/00863
PCT International Filing date 2000-03-09
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 9905382.9 1999-03-10 U.K.