Title of Invention	USING OVEREXPRESSION OF LAMININ ALPHA 4 SUBUNIT AS A DIAGNOSTIC AND PROGNOSTIC INDICATOR OF MALIGNANT TUMORS
Abstract	Improved stabilized spinel battery cathode material and methods of treating particles of spinel battery cathode material to produce a protective coating of battery-inactive lithium metal oxide on the particles are provided. The methods comprise mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide and then heating the resultant particulate mixture for a time and temperature to react the paniculate reactant with the spinel particles whereby a protective coating of lithium metal oxide is formed on the spinel particles and the lithium content of the spinel adjacent to the coating is increased a limited amount.

Title of Invention

USING OVEREXPRESSION OF LAMININ ALPHA 4 SUBUNIT AS A DIAGNOSTIC AND PROGNOSTIC INDICATOR OF MALIGNANT TUMORS

Abstract

Improved stabilized spinel battery cathode material and methods of treating particles of spinel battery cathode material to produce a protective coating of battery-inactive lithium metal oxide on the particles are provided. The methods comprise mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide and then heating the resultant particulate mixture for a time and temperature to react the paniculate reactant with the spinel particles whereby a protective coating of lithium metal oxide is formed on the spinel particles and the lithium content of the spinel adjacent to the coating is increased a limited amount.

Full Text	1 A METHOD OF TREATING PARTICLES OF SPINEL AND A PARTICULATE SPINEL BATTERY CATHODE HAVING SAID PARTICLES COATED THEREON This invention relates to a method of treating particles and spaniel and a participate spinel battery cathode having said particles coated thereon, and in particular to stabilized lithium manganese oxide spinel battery cathode material, and to improved methods of stabilizing the spinel against acid attack and the like. Recently, there has been increased interest in using lithium manganese oxide having the formula Li1+xMn2-x04 (0.02 A variety of solutions to the problem of the rapid loss in capacity of spinel above 45°C have been proposed by those skilled in the art. The solutions include the incorporation of additional lithium into the spinel lattice to form spinel of the formula Li1+XMn2XxO4 or substituting fluoride for some of the oxygen to yield spinel having the formula Li1+xMn2-XxO4-zFz (see Amatucci et al., U.S. Patent No. 5,674,645 and Sugiyama et al., U.S. Patent No. 6,087,042). Another solution involves replacing a fraction of the Mn with a stabilizing metal (M) such as Cr, Ni, Co, Al and the like to form Li1+xMyMn2-.x-y04 (Dahn et al., U.S. Patent No. 5,900,385) wherein x is greater than 0 but less than 1 and y is less than or equal to 1. Another proposed solution involves the formation of a protective coating on the particles of spinel to prevent corrosion or dissolution of the spinel. The formation of a protective coating on spinel is disclosed in U.S. Patent No. 5,443,929 issued to 2 Yamamoto et al. on August 22, 1995 wherein a lithium-deficient spinel (Li1+xMn2O4 encapsulated by lithium manganite (Li2 MnO3) is disclosed. In accordance with the teachings of the patent, LiOH powder is added to stoichimetric spinel at various ratios from 0.02:1 to 1.2:3 and the mixture is heated in air at 200°C to 1000°C, preferably at 375°C, for 20 hours. The final product is a dual phase material that has acid resistance and enhanced stability during high temperature battery operation, but it suffers from the disadvantage that the maximum capacity is substantially reduced. U.S. Patent No.5,733,685 issued to Wang on March 31,1998 and U.S. Patent No. 5,783,328 also issued to Wang on July 21, 1998 disclose that improved spinel cathode material stability is obtained by protecting the spinel particles with a thin layer of lithium carbonate (Li2CO3). The coating is accomplished by combining a solution of LiOH with spinel having the formula Li1+xMn2-xO4 wherein x is greater or equal to 0 and less than or equal to 0.1. After the mixture is dried, it is heated to a temperature of from 270°C to 300°C for 20 hours in the presence of carbon dioxide. While the resulting layer of Li2CO3 on the spinel makes it more robust than unprotected spinels at temperatures above 45°C, the coated spinel tends to out-gas during battery use which causes the battery case to swell or vent, etc. U.S. Patent No. 5,705,291 issued to Amatucci et al. on January 6, 1998 discloses that a glassy coating of LiOH mixed with B2O3 and other additives retards spinel capacity loss, and U.S. Patent No. 6,022,641 issued to Endo et al. on February 8, 2000 discloses the benefits of mixing Li2CO3 or Na2CO3 with spinel in an amount of from 0.5% to 20% by weight of the spinel to improve cycle performance. Further, Oesten et al. (WO 00/70694 - November 23, 2000) protect all lithium metal oxide cathode materials by coating the active particles with an organometallic species and then pyrolyzing to leave a metal oxide outer layer. It is also possible to coat lithium manganese oxide spinels with other battery-active cathode materials having the general formula LiMOx wherein M is a transition metal (Iguchi et al., Japanese Kokai HEI 8[1996] - 162114 and Hwang et al., U.S. Patent No. 5,928,622). In this approach, thermally decomposable Li and M salts (or oxides) in the appropriate Li:M ratio are blended with the spinel and reacted at temperatures up to 750°C. This results in particles of the original spinel having an acid resistant LiMOx-rich outer shell. 3 The surface treatments of spinel battery cathode material of the types described above inevitably result in a decrease of the maximum reversible discharge capacity of the spinel. In addition to lowered capacity caused by the added mass of electrochemically inert species, Gummow et al. in Solid State Ionics. 69, 59 (1994) showed that the inclusion of non-stoichiometric Li in Li1+xMn2-xO4 will decrease the discharge capacity of the resulting material by a factor of (l-3x). The advantage of such treatments is that they slow the loss of discharge capacity (referred to in the art as fade) during repeated charge/discharge cycles. The battery industry's measure of useful battery life dictates battery replacement when the battery has lost 20% of its initial discharge capacity. The protective coatings extend the number of useful cycles that the spinel cathode material can provide, but as mentioned, the maximum reversible discharge capacity of the spinel is significantly decreased. The prior art discloses providing spinel battery cathode material with a coating of an acid resistant or acid-scavenging compound. Mineral acids present as impurities in lithium ion batteries attack Li1+xMn2-xO4 spinel cathode material extracting lithium arid up to 25% of the manganese leaving the spinel unable to perform satisfactorily. The impurity acids are generated in lithium-ion batteries by the hydrolysis of LiPF6 electrolyte salt, by trace moisture or by the oxidation of organic carbonate electrolyte solvents at the high voltage end of the battery cycle. While the protection afforded by the above described prior art coatings prevent or reduce the problems associated with acid attack at temperatures below 45°C in batteries for mobile devices such as cell phones, laptop computers, photographic equipment and the like, the prior art coatings significantly reduce the maximum reversible discharge capacity of the spinel cathode material. The present invention provides improved stabilized particulate Li1+xMn2-xO4 spinel battery cathode material and methods of treating particles of Li1+xMn2-xO4 spinel to produce a protective coating of a battery inactive, ceramic-like lithium metal oxide on the particles. The coating resists acid attack, substantially improves the capacity fade of the material and reduces the maximum discharge capacity of the material only minimally. The methods of the invention are basically comprised of the following steps. The spinel particles are mixed with a particulate reactant selected from a lithium salt, 4 a lithium metal oxide or a mixture of a lithium salt and a metal oxide. Thereafter, the resulting paniculate mixture is heated for a time in the range of from IS minutes to 20 hours at a temperature in the range of from 350°C to 850°C. During the heating step, the participate lithium salt, lithium metal oxide or mixture of the lithium salt and a metal oxide reacts with the spinel particles whereby a protective coating of battery-inactive lithium metal oxide is formed on the spinel particles and the lithium content of the spinel particles adjacent to the coating is increased a limited amount as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2. The coated spinel particles are preferably cooled to a temperature below 200°C in a time period in the range of from 10 to 120 minutes. Thereafter, the spinel particles are cleaned and sized by removing agglomerates and metallic particles while passing the particles through a magnetic trap and 150 mesh or smaller screens. The untreated Li1+xMn2-xO4 spinel used in the method described above can be of any desired particle size and there are no restrictions on the lithium or manganese content or crystal lattice size. Preferably, the spinel particles have an average size less than 35 microns and substantially all of the particles pass through a 200 mesh screen. Examples of the lithium salts that can be utilized for forming the coating on the spinel include, but are not limited to, lithium carbonate, lithium hydroxide, lithium nitrate, lithium salts of organic acids such as lithium acetate, lithium formate and lithium oxalate, and mixtures of such lithium salts. Of these, lithium carbonate is preferred. Examples of lithium metal oxides that can be utilized include, but are not limited to, Li2MnO3, LIScO2, LiYO2, Li2ZrO3, Li2Hf03, LiAlO2, LiAl5O8, LiGaO2, LiLaO2, Li2Si03, LuSiO4 Li2GeO3 and mixtures thereof. Examples of metal oxides that can be utilized include, but are not limited to Sc2O3, Y2O3, ZrO2, HfO2, AI2O3, Ga2O3, La2O3, SiO2, GeO3 and mixtures thereof. The lithium salt utilized generally has an average particle size of less than 10 microns and substantially all of the lithium salt particles pass through a 150 mesh screen. The lithium metal oxides utilized generally have an average particle size less than 5 microns, and preferably less than 1 micron. The lithium salt, lithium metal oxide or mixture of lithium salt and metal oxide utilized is mixed with the spinel particles in an amount which is less than or equal to 2.5 mole percent of the spinel particles in the mixture. To guard against destructive out-gassing, residual carbonate 5 in the protective coating should be limited to at least less than 0.05% by weight of the spinel product. As will be understood by those skilled in the art, other species of lithium salts, lithium metal oxides and metal oxides can be utilized which have different atomic ratios from those set forth above. Also, two or more metal oxides or lithium metal oxides can be utilized. The spinel particles and the lithium salt, lithium metal oxide or mixture of lithium salt and metal oxide particulate reactant(s) utilized are preferably mixed in a high intensity, low shear mill such as a vibratory ball mill, a vibratory rod mill or the equivalent which does not reduce the size of the spinel particles. It is undesirable to reduce the spinel particle size during the mixing step in the presence of the particulate reactant(s) used in that the size reduction which takes place cannot be controlled. Preferably, the mixing of the spinel particles and particulate reactant(s) is performed in a high intensity, low shear ball mill charged with cylindrical ceramic media. The spinel particles and particulate reactant(s) utilized are preferably mixed for a time period, including discharging the mixture, which does not exceed 75 minutes. The heating of the mixture of spinel particles and the particulate reactant(s) utilized can be carried out in a batch mode. That is, the particulate mixture can be placed in an inert container formed of stainless steel, densified ceramic or the like and heated in a box oven, a belt or pusher furnace of the like. Air is flowed through the reaction chamber to remove moisture, CO2 and other gases while maintaining an oxidizing atmosphere. Due to the insulating properties of the reactant powders, the particulate mixture should be heated to above 575°C as shown in the accompanying drawing showing a Table I. As will be understood, deeper reactant beds will require higher heating temperatures while shallower beds require lower temperatures. A preferred bed depth is less than 5 centimeters (2 inches). At depths above about 5 centimeters, there is a risk that the product will be over-reacted (little or no protective coating) at the top portion of the bed and under-reacted (residual lithium salt) at the bottom portion of the bed. Such a non-homogeneous product may be susceptible to excessive capacity fade and out-gassing during battery operation. Generally, the reaction time is in the range of from 15 minutes to 20 hours, preferably less than 2 hours. 6 Preferably, the heating of the mixture of spinel particles and the particulate reactant(s) utilized is carried out in a rotary calciner with a countercurrent air flow passing through the calciner during the heating to remove residual moisture, carbon dioxide gas and the like. As mentioned above, the particulate mixture is heated for a time in the range of from 15 minutes to 20 hours, preferably for a time of from 30 minutes to 45 minutes, at a temperature in the range of from 350°C to 850°C, preferably in the range of from 550°C to 650°C. During the time that the mixture is heated at the above-mentioned temperature, the particulate reactant(s) combine with each other and with the spinel particles whereby protective coatings of lithium metal oxide are formed on the spinel particles. Simultaneously, the lithium content of the surface layers of the spinel particles adjacent to the coatings are increased limited amounts as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2. The bulk of each particle has a lower lithium content, that is, a lithium content wherein x is less than 0.15. Lithium manganite (Li2MnO3) is the most thermodynamically stable lithium manganese oxide compound and will withstand being heated to a temperature of 1000°C without decomposition. However, lithium manganite will react with manganese (HI) compounds such as Mn2O3 and LiMn(III)Mn(IV)O4 at temperatures above 300°C. Reaction (1) below is an iterative step in the commercial preparation of spinel, while reaction (2) describes the fate of the coating of lithium manganite on spinel. The product of reaction (2) is equivalent to Li1+xMn204+5, or alternately, Li1+xMn2-xO4 if y is less than approximately 0.1. Otherwise, high Li content will lead to tetragonally distorted material that will have poor cycling characteristics. The above reaction shows that a lithium manganite (Li2MnO3) coating will at least partially react with spinel above a temperature of 300°C and produce a lithium-enriched spinel. The longer the treatment time and/or the higher the treatment temperature, the more lithium migration will take place to form particles of uniform composition, rather than particles with just a surface portion enriched in lithium. 7 The above is confirmed by an analysis of X-ray diffraction data which allows the quantification of the lithium manganite coating formed on spinel. That is, samples of mixtures of spinel particles with participate lithium carbonate were calcined at different temperatures and times. The calcining at or below 575°C for 45 minutes did not produce any detectable lithium manganite coating as shown in Table I below. Table I also shows the percent lithium manganite determined by X-ray diffraction Rietveld analysis at various higher temperatures and reaction times. As shown in Table I, when the coating treatment was performed at 600°C, approximately 0.75% lithium manganite was formed on the spinel independent of whether the spinel was heated for 45 minutes or 75 minutes. At 625°C, 1.2% lithium manganite was formed after heating for only 30 minutes. That percentage was reduced upon continued heating and the spinel diffraction pattern shifted to greater scattering angle (26), indicating a decrease in the lattice constant as a result of lithium manganite reacting to form a lithium-rich spinel. The spinel lattice constant of Li1.07Mn1.93O4 typically shrinks from approximately 8.227 Angstroms to 8.218-8.223 Angstroms during the treatment. The above described treatments were carried out in a static oven. Similar results from treatments carried out in a rotary kiln were obtained at temperatures 20°C to 50°C lower. Referring to FIG. 1, a graph is presented showing the decrease in lattice constant of the treated spinel as a function of reaction time and temperature. As the lithium manganite reacts with the spinel and lithium diffuses through the spinel particles, the lattice constant of the particles shrinks. The rate of lattice shrinkage is a function of the temperature since lithium will diffuse more rapidly as the temperature 8 increases. If lithium manganite and spinel were mixed at the molecular level, there would be no time factor in the lattice contraction. Further, the lithium diffusion kinetics allows a temperature and a, time period to be selected that will optimize the economics of the treatment As illustrated in FIG. 1, it is possible to perform the treatment at 300°C, but the preparation time required for a viable product would be very expensive. Alternately, if the temperature exceeds 625°C, lithium diffusion can proceed too rapidly to control and the product as a consequence can be less than optimum. The above discussion concerning lithium manganite protective coatings holds true for any other lithium metal oxide that is battery-inactive, that is, the metal cannot be further oxidized at a voltage below 4.5 volts. If a coating is placed on the spinel particles that is battery-active, lithium will be extracted and reinserted during normal battery operation and the resulting contraction and expansion will cause the coating to loosen and crack, thereby negating its effectiveness as an acid barrier. The battery-inactive lithium metal oxide coatings formed on the spinel particles in accordance with this invention are typically ceramic in character and resist dissolution by acid under normal conditions. Thus, the protective coatings of this invention remain on the spinel particles during battery operation and storage even at elevated temperatures. Thus, a potential drawback of the treatment method of this invention is that there can be a significant loss in maximum capacity when excessive lithium is added to the spinel, specifically when x in the formula Li1+xMn2-xO4 is greater than 0.2. Accordingly, it is of great importance in accordance with the present invention that an encapsulating protective layer of battery-inactive lithium metal oxide is added to the spinel particles. Too much lithium added to the spinel will cause excessive formation of ceramic-like lithium metal oxide resulting in poor lithium mobility and unacceptable battery performance. If the lithium metal oxide and spinel are allowed to react for an overly-long period of time, the spinel structure will distort and cathodic stability and performance will be diminished. Even when an appropriate amount of lithium is added to the spinel, the reaction period may be too lengthy or too hot, allowing lithium to diffuse into the interior of the spinel particles thereby losing the coating effect. Spinel treated in a manner where the coating effect is lost will have lattice constants reduced by 0.01 to 9 0.02 Angstroms, and will exhibit a reduction of 10 to 25 percent in reversible discharge capacity. While the capacity fade will be approximately 0.05% per cycle which is a very desirable value, the initial capacity will be less than optimum. Further, if the treatment temperature exceeds approximately 920°C, there will be an irreversible phase change to the unacceptable tetragonal structure which exhibits very poor cathode performance. Lastly, if the temperature reduction after heating is too abrupt, the spinel oxygen deficiency caused by the treatment will not be reversed. Oxygen-deficient spinel species are inferior cathode materials to spinels with correct oxygen stoichiometry. In addition to managing the heating of the particulate mixture of spinel and lithium salt, the cooling of the heated and reacted particulate mixture to a temperature below 200°C should be carried out in a time period in the range of from 10 to 60 minutes, preferably in less than 25 minutes. After the treated spinel particles are cooled, the particles are cleaned and sized. That is, because the lithium salt utilized may cause flaking (spalling) of the iron containing alloy that forms the calciner, iron-containing metallic particles will generally be present in the product. In addition, the lithium salts may cause minor agglomeration of the paniculate product In order to remove the particles containing iron and oversized particles from the treated product, the treated product particles are subjected to magnetic separation such as by causing the product particles to flow through a column containing multiple magnets which remove the particles containing iron from the paniculate product. In addition, the paniculate product is caused to pass through a 150 mesh or smaller screen. A preferred method of this invention of treating particles of spinel having the formula Li1+xMn2-xO4(0.02 inactive lithium metal oxide on the particles is comprised of the following steps: (a) mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide; and (b) heating the resulting paniculate mixture for a time in the range of from 15 minutes to 20 hours at a temperature in the range of from 35O°C to 850°C to thereby react the spinel particles with the reactant whereby protective coatings of battery-inactive lithium metal oxide are formed on the spinel particles and the lithium 10 contents of the spinel particles adjacent to the coatings are increased limited amounts as represented by the formula Li1+xMn2.xO4 wherein x is less than 0.2. Another preferred method of this invention of treating particles of spinel having the formula Li1+xMn2.xO4 (0.02 (a) mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide in a high intensity, low shear mixer; (b) heating the resulting particulate mixture for a time in the range of from 15 minutes to 20 hours at a temperature in the range of from 350°C to 850°C to thereby react the spinel particles with the reactant whereby protective coatings of battery-inactive lithium metal oxide am formed on the spinel particles and the lithium contents of the spinel particles adjacent to the coatings are increased limited amounts as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2; (c) cooling the resulting heated and reacted particulate mixture to a temperature below 200°C in a time period in the range of from 10 to 120 minutes; and (d) cleaning and sizing the resulting reacted and cooled particulate mixture by removing metallic particles from said mixture and removing oversize particles by passing said mixture through a 150 mesh or smaller screen. In order to further illustrate the stabilized spinel battery cathode material and methods of this invention, the following examples are given. Example 1 Electrolytic manganese dioxide (EMD) of two different particle sizes were converted to lithium manganite Li2nMnO3) by reacting equimolar amounts of lithium carbonate and the EMD at 650°C. The two resultant lithium manganite lots had 0.9 micron and 3.8 microns mean particle sizes, respectively, designated as fine and super-fine Li2MnO3, respectively. Each lot was separately mixed with spine! having the formula Li1-07Mn1.93O4 from a commercial lot at two addition levels of 1.5% by weight of the mixture and 2.37% by weight of the mixture, respectively. The mixtures were each incorporated into a battery cathode and cycle tested in a laboratory coin cell battery. The results of these tests are set forth in Table II below 11 as Tests Nos. 3 and 4. As shown, no improvement over the starting spinel material (Test No. 1 in Table II) was noted. Example 2 Test portions of the mixtures from Example 1 were heated to 575°C for 30 minutes. X-ray diffraction analysis of the spinel products revealed a modest decrease in the spinel crystal lattice constant, indicating a migration of lithium from the lithium manganite into the spinel. The resulting products comprised of spinel particles coated with lithium manganite are listed in Tests Nos. 5 - 8 set forth in Table II below. The lithium manganite content was determined by Rietveld analysis of XRD diffraction scans. The electrochemical test results given in Table II above were obtained by incorporating the test materials given in Table U into battery cathodes and cycle testing the cathodes in laboratory coin cell batteries at 55°C. The maximum discharge capacities of the cathodes and fade rates during charge/discharge cycling are given in Table II. As shown in Table II, when lithium manganite (LizMnO3) having an average particle size of 0.9 microns was the lithium source (Tests Nos. 5 and 6), the maximum discharge capacity was 8% to 10% less than that of the precursor spinel having the formula Li1.07Mn1.93O4 (Test No. 1), while fade rates improved 15% to 40%. When the lithium manganite having a particle size of 3.8 microns was used (Tests Nos. 7 and 8), approximately 5% capacity loss and 15% fade rate improvement were observed. This particle size effect is consistent with the poor mobility of lithium manganite, even at elevated temperatures. The physical mixtures of spinel and 12 lithium manganite (Tests Nos. 3 and 4) showed no measurable improvement over the precursor spinel alone (Test No. 1). Example 3 27.52 grams of Li2CO3, 100 grams of Mn2O3 and 7.04 grams of AI2O3 were mixed together and calcined at 750°C for 16.7 hours. The resulting calcined mixture was cooled, re-mixed in a blender and re-calcined at 750°C for 16.7 hours. X-ray diffraction analysis revealed a LiMn2O4 spinel pattern with a lattice constant of 8.207 A and with small peaks from LiAl5O8 spinel. The produced cathode material calculated as Li1.046Alo.195Mn1.75O4 was cycle tested in a laboratory coin cell battery at 55 °C. The maximum discharge capacity of the cathode material was 109 mAh/g and the fade rate was 0.058% per cycle. It is believed that the immobile LiAl5O8 is a surface species on the LMO spinel particles. Similarly prepared LiAlo.2Mn1.8O4 cathode material exhibited a lattice constant of 8.227 A and an unacceptable capacity of only 55 mAh/g. Extensive AI2O3 was detected in the sample. 13 WE CLAIM : 1. A method of treating particles of spinel having the formula Li1+xMn2.xO4 (0.02 (a) mixing said spinel particles with a particulate reactant selected from the group consisting of a lithium salt, a lithium metal oxide and a mixture of a lithium salt and a metal oxide ; and (b) heating the resulting particulate mixture for a time in the range of from 15 minutes to 20 hours at a temperature in the range of from 350°C to 850°C to thereby react said spinel particles with said reactant whereby protective coatings of battery- inactive lithium metal oxide are formed on said spinel particles and the lithium contents of said spinel particles adjacent to said coatings are increased limited amounts as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2. 2. The method as claimed in claim 1 wherein a particulate lithium salt reactant is selected from the group consisting of lithium carbonate, lithium hydroxide, lithium nitrate, lithium salts of organic acids and mixtures thereof. 3. The method as claimed in claim 1 wherein a particulate lithium metal oxide reactant is selected from the group consisting of Li2MnO3, LiScO2, LiYO2, LiZrO3, Li2HfO3, LiAIO2l LiAI5O8, LiGaO2, LiLaO2, Li2SiO3, LUSiO4, Li2Ge03 and mixtures thereof. 14 4. The method as claimed in claim 1 wherein, a particulate metal oxide reactant is selected from the group consisting of Sc2O3, Y2O3\| ZrO2, HfO2, AI2O3, Ga2O3, La2O3i SiO2, GeO3 and mixtures thereof. 5. The method as claimed in any one of claim's 1 to 4, wherein said particulate reactant is mixed with said spinel particles in an amount which is less than or equal to 2.5 mole percent of said spinel particles in said mixture. 6. The method as claimed in claim 2 wherein said particulate lithium salt reactant has an average particle size less than 10 microns and substantially all of the particles pass through a 150 mesh screen. 7. The method as claimed in claim 3 or 4 wherein said lithium metal oxide or said metal oxide reactant, respectively, have an average particle size of less than 5 microns. 8. The method as claimed in any one of claims 1 to 7 wherein said spinel particles have an average size of less than 35 microns and substantially all of said particles pass through a 200 mesh screen. 9. The method as claimed in any one of claims 1 to 8, wherein said spinel particles and said particulate reactant are mixed in accordance with step (a) in a high intensity, low shear vibratory ball mill or the equivalent which does not reduce the size of said spinel particles. 15 10. The method as claimed in claim 9 wherein said spinel particles and participate reactant are mixed for a time period including discharging the mixture which does not exceed 75 minutes. 11. The method as claimed in any one claims 1 to 10 comprising the step of cooling said heated and reacted particulate mixture to a temperature below 200°C in a time period in the range of from 10 to 120 minutes. 12. The method as claimed in claim 11 comprising the steps of cleaning and sizing said reacted and cooled particulate mixture by removing metallic particles from said mixture and removing oversize particles by passing said mixture through a 150 mesh or smaller screen. 13. A particulate stabilized spinel battery cathode material having a protective coating of lithium metal oxide thereon produced by the method as claimed in any one of claims 1 to 12. Improved stabilized spinel battery cathode material and methods of treating particles of spinel battery cathode material to produce a protective coating of battery-inactive lithium metal oxide on the particles are provided. The methods comprise mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide and then heating the resultant particulate mixture for a time and temperature to react the paniculate reactant with the spinel particles whereby a protective coating of lithium metal oxide is formed on the spinel particles and the lithium content of the spinel adjacent to the coating is increased a limited amount.

Full Text

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A METHOD OF TREATING PARTICLES OF SPINEL AND A PARTICULATE SPINEL BATTERY CATHODE HAVING SAID PARTICLES COATED THEREON
This invention relates to a method of treating particles and spaniel and a participate spinel battery cathode having said particles coated thereon, and in particular to stabilized lithium manganese oxide spinel battery cathode material, and to improved methods of stabilizing the spinel against acid attack and the like.
Recently, there has been increased interest in using lithium manganese oxide having the formula Li1+xMn2-x04 (0.02 A variety of solutions to the problem of the rapid loss in capacity of spinel above 45°C have been proposed by those skilled in the art. The solutions include the incorporation of additional lithium into the spinel lattice to form spinel of the formula Li1+XMn2XxO4 or substituting fluoride for some of the oxygen to yield spinel having the formula Li1+xMn2-XxO4-zFz (see Amatucci et al., U.S. Patent No. 5,674,645 and Sugiyama et al., U.S. Patent No. 6,087,042). Another solution involves replacing a fraction of the Mn with a stabilizing metal (M) such as Cr, Ni, Co, Al and the like to form Li1+xMyMn2-.x-y04 (Dahn et al., U.S. Patent No. 5,900,385) wherein x is greater than 0 but less than 1 and y is less than or equal to 1.
Another proposed solution involves the formation of a protective coating on the particles of spinel to prevent corrosion or dissolution of the spinel. The formation of a protective coating on spinel is disclosed in U.S. Patent No. 5,443,929 issued to

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Yamamoto et al. on August 22, 1995 wherein a lithium-deficient spinel (Li1+xMn2O4 encapsulated by lithium manganite (Li2 MnO3) is disclosed. In accordance with the teachings of the patent, LiOH powder is added to stoichimetric spinel at various ratios from 0.02:1 to 1.2:3 and the mixture is heated in air at 200°C to 1000°C, preferably at 375°C, for 20 hours. The final product is a dual phase material that has acid resistance and enhanced stability during high temperature battery operation, but it suffers from the disadvantage that the maximum capacity is substantially reduced.
U.S. Patent No.5,733,685 issued to Wang on March 31,1998 and U.S. Patent No. 5,783,328 also issued to Wang on July 21, 1998 disclose that improved spinel cathode material stability is obtained by protecting the spinel particles with a thin layer of lithium carbonate (Li2CO3). The coating is accomplished by combining a solution of LiOH with spinel having the formula Li1+xMn2-xO4 wherein x is greater or equal to 0 and less than or equal to 0.1. After the mixture is dried, it is heated to a temperature of from 270°C to 300°C for 20 hours in the presence of carbon dioxide. While the resulting layer of Li2CO3 on the spinel makes it more robust than unprotected spinels at temperatures above 45°C, the coated spinel tends to out-gas during battery use which causes the battery case to swell or vent, etc.
U.S. Patent No. 5,705,291 issued to Amatucci et al. on January 6, 1998 discloses that a glassy coating of LiOH mixed with B2O3 and other additives retards spinel capacity loss, and U.S. Patent No. 6,022,641 issued to Endo et al. on February 8, 2000 discloses the benefits of mixing Li2CO3 or Na2CO3 with spinel in an amount of from 0.5% to 20% by weight of the spinel to improve cycle performance. Further, Oesten et al. (WO 00/70694 - November 23, 2000) protect all lithium metal oxide cathode materials by coating the active particles with an organometallic species and then pyrolyzing to leave a metal oxide outer layer.
It is also possible to coat lithium manganese oxide spinels with other battery-active cathode materials having the general formula LiMOx wherein M is a transition metal (Iguchi et al., Japanese Kokai HEI 8[1996] - 162114 and Hwang et al., U.S. Patent No. 5,928,622). In this approach, thermally decomposable Li and M salts (or oxides) in the appropriate Li:M ratio are blended with the spinel and reacted at temperatures up to 750°C. This results in particles of the original spinel having an acid resistant LiMOx-rich outer shell.

3
The surface treatments of spinel battery cathode material of the types described above inevitably result in a decrease of the maximum reversible discharge capacity of the spinel. In addition to lowered capacity caused by the added mass of electrochemically inert species, Gummow et al. in Solid State Ionics. 69, 59 (1994) showed that the inclusion of non-stoichiometric Li in Li1+xMn2-xO4 will decrease the discharge capacity of the resulting material by a factor of (l-3x). The advantage of such treatments is that they slow the loss of discharge capacity (referred to in the art as fade) during repeated charge/discharge cycles. The battery industry's measure of useful battery life dictates battery replacement when the battery has lost 20% of its initial discharge capacity. The protective coatings extend the number of useful cycles that the spinel cathode material can provide, but as mentioned, the maximum reversible discharge capacity of the spinel is significantly decreased.
The prior art discloses providing spinel battery cathode material with a coating of an acid resistant or acid-scavenging compound. Mineral acids present as impurities in lithium ion batteries attack Li1+xMn2-xO4 spinel cathode material extracting lithium arid up to 25% of the manganese leaving the spinel unable to perform satisfactorily. The impurity acids are generated in lithium-ion batteries by the hydrolysis of LiPF6 electrolyte salt, by trace moisture or by the oxidation of organic carbonate electrolyte solvents at the high voltage end of the battery cycle. While the protection afforded by the above described prior art coatings prevent or reduce the problems associated with acid attack at temperatures below 45°C in batteries for mobile devices such as cell phones, laptop computers, photographic equipment and the like, the prior art coatings significantly reduce the maximum reversible discharge capacity of the spinel cathode material.
The present invention provides improved stabilized particulate Li1+xMn2-xO4 spinel battery cathode material and methods of treating particles of Li1+xMn2-xO4 spinel to produce a protective coating of a battery inactive, ceramic-like lithium metal oxide on the particles. The coating resists acid attack, substantially improves the capacity fade of the material and reduces the maximum discharge capacity of the material only minimally.
The methods of the invention are basically comprised of the following steps. The spinel particles are mixed with a particulate reactant selected from a lithium salt,

4
a lithium metal oxide or a mixture of a lithium salt and a metal oxide. Thereafter, the resulting paniculate mixture is heated for a time in the range of from IS minutes to 20 hours at a temperature in the range of from 350°C to 850°C. During the heating step, the participate lithium salt, lithium metal oxide or mixture of the lithium salt and a metal oxide reacts with the spinel particles whereby a protective coating of battery-inactive lithium metal oxide is formed on the spinel particles and the lithium content of the spinel particles adjacent to the coating is increased a limited amount as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2.
The coated spinel particles are preferably cooled to a temperature below 200°C in a time period in the range of from 10 to 120 minutes. Thereafter, the spinel particles are cleaned and sized by removing agglomerates and metallic particles while passing the particles through a magnetic trap and 150 mesh or smaller screens.
The untreated Li1+xMn2-xO4 spinel used in the method described above can be of any desired particle size and there are no restrictions on the lithium or manganese content or crystal lattice size. Preferably, the spinel particles have an average size less than 35 microns and substantially all of the particles pass through a 200 mesh screen.
Examples of the lithium salts that can be utilized for forming the coating on the spinel include, but are not limited to, lithium carbonate, lithium hydroxide, lithium nitrate, lithium salts of organic acids such as lithium acetate, lithium formate and lithium oxalate, and mixtures of such lithium salts. Of these, lithium carbonate is preferred. Examples of lithium metal oxides that can be utilized include, but are not limited to, Li2MnO3, LIScO2, LiYO2, Li2ZrO3, Li2Hf03, LiAlO2, LiAl5O8, LiGaO2, LiLaO2, Li2Si03, LuSiO4 Li2GeO3 and mixtures thereof. Examples of metal oxides that can be utilized include, but are not limited to Sc2O3, Y2O3, ZrO2, HfO2, AI2O3, Ga2O3, La2O3, SiO2, GeO3 and mixtures thereof.
The lithium salt utilized generally has an average particle size of less than 10 microns and substantially all of the lithium salt particles pass through a 150 mesh screen. The lithium metal oxides utilized generally have an average particle size less than 5 microns, and preferably less than 1 micron. The lithium salt, lithium metal oxide or mixture of lithium salt and metal oxide utilized is mixed with the spinel particles in an amount which is less than or equal to 2.5 mole percent of the spinel particles in the mixture. To guard against destructive out-gassing, residual carbonate

5
in the protective coating should be limited to at least less than 0.05% by weight of the spinel product.
As will be understood by those skilled in the art, other species of lithium salts, lithium metal oxides and metal oxides can be utilized which have different atomic ratios from those set forth above. Also, two or more metal oxides or lithium metal oxides can be utilized.
The spinel particles and the lithium salt, lithium metal oxide or mixture of lithium salt and metal oxide particulate reactant(s) utilized are preferably mixed in a high intensity, low shear mill such as a vibratory ball mill, a vibratory rod mill or the equivalent which does not reduce the size of the spinel particles. It is undesirable to reduce the spinel particle size during the mixing step in the presence of the particulate reactant(s) used in that the size reduction which takes place cannot be controlled. Preferably, the mixing of the spinel particles and particulate reactant(s) is performed in a high intensity, low shear ball mill charged with cylindrical ceramic media. The spinel particles and particulate reactant(s) utilized are preferably mixed for a time period, including discharging the mixture, which does not exceed 75 minutes.
The heating of the mixture of spinel particles and the particulate reactant(s) utilized can be carried out in a batch mode. That is, the particulate mixture can be placed in an inert container formed of stainless steel, densified ceramic or the like and heated in a box oven, a belt or pusher furnace of the like. Air is flowed through the reaction chamber to remove moisture, CO2 and other gases while maintaining an oxidizing atmosphere. Due to the insulating properties of the reactant powders, the particulate mixture should be heated to above 575°C as shown in the accompanying drawing showing a Table I. As will be understood, deeper reactant beds will require higher heating temperatures while shallower beds require lower temperatures. A preferred bed depth is less than 5 centimeters (2 inches). At depths above about 5 centimeters, there is a risk that the product will be over-reacted (little or no protective coating) at the top portion of the bed and under-reacted (residual lithium salt) at the bottom portion of the bed. Such a non-homogeneous product may be susceptible to excessive capacity fade and out-gassing during battery operation. Generally, the reaction time is in the range of from 15 minutes to 20 hours, preferably less than 2 hours.

6
Preferably, the heating of the mixture of spinel particles and the particulate reactant(s) utilized is carried out in a rotary calciner with a countercurrent air flow passing through the calciner during the heating to remove residual moisture, carbon dioxide gas and the like. As mentioned above, the particulate mixture is heated for a time in the range of from 15 minutes to 20 hours, preferably for a time of from 30 minutes to 45 minutes, at a temperature in the range of from 350°C to 850°C, preferably in the range of from 550°C to 650°C. During the time that the mixture is heated at the above-mentioned temperature, the particulate reactant(s) combine with each other and with the spinel particles whereby protective coatings of lithium metal oxide are formed on the spinel particles. Simultaneously, the lithium content of the surface layers of the spinel particles adjacent to the coatings are increased limited amounts as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2. The bulk of each particle has a lower lithium content, that is, a lithium content wherein x is less than 0.15.
Lithium manganite (Li2MnO3) is the most thermodynamically stable lithium manganese oxide compound and will withstand being heated to a temperature of 1000°C without decomposition. However, lithium manganite will react with manganese (HI) compounds such as Mn2O3 and LiMn(III)Mn(IV)O4 at temperatures above 300°C. Reaction (1) below is an iterative step in the commercial preparation of spinel, while reaction (2) describes the fate of the coating of lithium manganite on spinel.

The product of reaction (2) is equivalent to Li1+xMn204+5, or alternately, Li1+xMn2-xO4 if y is less than approximately 0.1. Otherwise, high Li content will lead to tetragonally distorted material that will have poor cycling characteristics. The above reaction shows that a lithium manganite (Li2MnO3) coating will at least partially react with spinel above a temperature of 300°C and produce a lithium-enriched spinel. The longer the treatment time and/or the higher the treatment temperature, the more lithium migration will take place to form particles of uniform composition, rather than particles with just a surface portion enriched in lithium.

7
The above is confirmed by an analysis of X-ray diffraction data which allows the quantification of the lithium manganite coating formed on spinel. That is, samples of mixtures of spinel particles with participate lithium carbonate were calcined at different temperatures and times. The calcining at or below 575°C for 45 minutes did not produce any detectable lithium manganite coating as shown in Table I below. Table I also shows the percent lithium manganite determined by X-ray diffraction Rietveld analysis at various higher temperatures and reaction times.

As shown in Table I, when the coating treatment was performed at 600°C, approximately 0.75% lithium manganite was formed on the spinel independent of whether the spinel was heated for 45 minutes or 75 minutes. At 625°C, 1.2% lithium manganite was formed after heating for only 30 minutes. That percentage was reduced upon continued heating and the spinel diffraction pattern shifted to greater scattering angle (26), indicating a decrease in the lattice constant as a result of lithium manganite reacting to form a lithium-rich spinel. The spinel lattice constant of Li1.07Mn1.93O4 typically shrinks from approximately 8.227 Angstroms to 8.218-8.223 Angstroms during the treatment. The above described treatments were carried out in a static oven. Similar results from treatments carried out in a rotary kiln were obtained at temperatures 20°C to 50°C lower.
Referring to FIG. 1, a graph is presented showing the decrease in lattice constant of the treated spinel as a function of reaction time and temperature. As the lithium manganite reacts with the spinel and lithium diffuses through the spinel particles, the lattice constant of the particles shrinks. The rate of lattice shrinkage is a function of the temperature since lithium will diffuse more rapidly as the temperature

8
increases. If lithium manganite and spinel were mixed at the molecular level, there would be no time factor in the lattice contraction. Further, the lithium diffusion kinetics allows a temperature and a, time period to be selected that will optimize the economics of the treatment As illustrated in FIG. 1, it is possible to perform the treatment at 300°C, but the preparation time required for a viable product would be very expensive. Alternately, if the temperature exceeds 625°C, lithium diffusion can proceed too rapidly to control and the product as a consequence can be less than optimum.
The above discussion concerning lithium manganite protective coatings holds true for any other lithium metal oxide that is battery-inactive, that is, the metal cannot be further oxidized at a voltage below 4.5 volts. If a coating is placed on the spinel particles that is battery-active, lithium will be extracted and reinserted during normal battery operation and the resulting contraction and expansion will cause the coating to loosen and crack, thereby negating its effectiveness as an acid barrier. The battery-inactive lithium metal oxide coatings formed on the spinel particles in accordance with this invention are typically ceramic in character and resist dissolution by acid under normal conditions. Thus, the protective coatings of this invention remain on the spinel particles during battery operation and storage even at elevated temperatures. Thus, a potential drawback of the treatment method of this invention is that there can be a significant loss in maximum capacity when excessive lithium is added to the spinel, specifically when x in the formula Li1+xMn2-xO4 is greater than 0.2. Accordingly, it is of great importance in accordance with the present invention that an encapsulating protective layer of battery-inactive lithium metal oxide is added to the spinel particles. Too much lithium added to the spinel will cause excessive formation of ceramic-like lithium metal oxide resulting in poor lithium mobility and unacceptable battery performance. If the lithium metal oxide and spinel are allowed to react for an overly-long period of time, the spinel structure will distort and cathodic stability and performance will be diminished.
Even when an appropriate amount of lithium is added to the spinel, the reaction period may be too lengthy or too hot, allowing lithium to diffuse into the interior of the spinel particles thereby losing the coating effect. Spinel treated in a manner where the coating effect is lost will have lattice constants reduced by 0.01 to

9
0.02 Angstroms, and will exhibit a reduction of 10 to 25 percent in reversible discharge capacity. While the capacity fade will be approximately 0.05% per cycle which is a very desirable value, the initial capacity will be less than optimum. Further, if the treatment temperature exceeds approximately 920°C, there will be an irreversible phase change to the unacceptable tetragonal structure which exhibits very poor cathode performance. Lastly, if the temperature reduction after heating is too abrupt, the spinel oxygen deficiency caused by the treatment will not be reversed. Oxygen-deficient spinel species are inferior cathode materials to spinels with correct oxygen stoichiometry. In addition to managing the heating of the particulate mixture of spinel and lithium salt, the cooling of the heated and reacted particulate mixture to a temperature below 200°C should be carried out in a time period in the range of from 10 to 60 minutes, preferably in less than 25 minutes.
After the treated spinel particles are cooled, the particles are cleaned and sized. That is, because the lithium salt utilized may cause flaking (spalling) of the iron containing alloy that forms the calciner, iron-containing metallic particles will generally be present in the product. In addition, the lithium salts may cause minor agglomeration of the paniculate product In order to remove the particles containing iron and oversized particles from the treated product, the treated product particles are subjected to magnetic separation such as by causing the product particles to flow through a column containing multiple magnets which remove the particles containing iron from the paniculate product. In addition, the paniculate product is caused to pass through a 150 mesh or smaller screen.
A preferred method of this invention of treating particles of spinel having the
formula Li1+xMn2-xO4(0.02 inactive lithium metal oxide on the particles is comprised of the following steps:
(a) mixing the spinel particles with a paniculate reactant selected from
a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide; and
(b) heating the resulting paniculate mixture for a time in the range of from 15 minutes to 20 hours at a temperature in the range of from 35O°C to 850°C to thereby react the spinel particles with the reactant whereby protective coatings of battery-inactive lithium metal oxide are formed on the spinel particles and the lithium

10
contents of the spinel particles adjacent to the coatings are increased limited amounts as represented by the formula Li1+xMn2.xO4 wherein x is less than 0.2.
Another preferred method of this invention of treating particles of spinel having the formula Li1+xMn2.xO4 (0.02 (a) mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide in a high intensity, low shear mixer;
(b) heating the resulting particulate mixture for a time in the range of
from 15 minutes to 20 hours at a temperature in the range of from 350°C to 850°C to
thereby react the spinel particles with the reactant whereby protective coatings of
battery-inactive lithium metal oxide am formed on the spinel particles and the lithium
contents of the spinel particles adjacent to the coatings are increased limited amounts
as represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2;
(c) cooling the resulting heated and reacted particulate mixture to a
temperature below 200°C in a time period in the range of from 10 to 120 minutes; and
(d) cleaning and sizing the resulting reacted and cooled particulate
mixture by removing metallic particles from said mixture and removing oversize
particles by passing said mixture through a 150 mesh or smaller screen.
In order to further illustrate the stabilized spinel battery cathode material and methods of this invention, the following examples are given.
Example 1
Electrolytic manganese dioxide (EMD) of two different particle sizes were converted to lithium manganite Li2nMnO3) by reacting equimolar amounts of lithium carbonate and the EMD at 650°C. The two resultant lithium manganite lots had 0.9 micron and 3.8 microns mean particle sizes, respectively, designated as fine and super-fine Li2MnO3, respectively. Each lot was separately mixed with spine! having the formula Li1-07Mn1.93O4 from a commercial lot at two addition levels of 1.5% by weight of the mixture and 2.37% by weight of the mixture, respectively. The mixtures were each incorporated into a battery cathode and cycle tested in a laboratory coin cell battery. The results of these tests are set forth in Table II below

11
as Tests Nos. 3 and 4. As shown, no improvement over the starting spinel material (Test No. 1 in Table II) was noted.
Example 2
Test portions of the mixtures from Example 1 were heated to 575°C for 30 minutes. X-ray diffraction analysis of the spinel products revealed a modest decrease in the spinel crystal lattice constant, indicating a migration of lithium from the lithium manganite into the spinel. The resulting products comprised of spinel particles coated with lithium manganite are listed in Tests Nos. 5 - 8 set forth in Table II below. The lithium manganite content was determined by Rietveld analysis of XRD diffraction scans.

The electrochemical test results given in Table II above were obtained by
incorporating the test materials given in Table U into battery cathodes and cycle
testing the cathodes in laboratory coin cell batteries at 55°C. The maximum discharge
capacities of the cathodes and fade rates during charge/discharge cycling are given in
Table II. As shown in Table II, when lithium manganite (LizMnO3) having an
average particle size of 0.9 microns was the lithium source (Tests Nos. 5 and 6), the
maximum discharge capacity was 8% to 10% less than that of the precursor spinel
having the formula Li1.07Mn1.93O4 (Test No. 1), while fade rates improved 15% to
40%. When the lithium manganite having a particle size of 3.8 microns was used
(Tests Nos. 7 and 8), approximately 5% capacity loss and 15% fade rate improvement
were observed. This particle size effect is consistent with the poor mobility of lithium
manganite, even at elevated temperatures. The physical mixtures of spinel and

12
lithium manganite (Tests Nos. 3 and 4) showed no measurable improvement over the precursor spinel alone (Test No. 1).
Example 3
27.52 grams of Li2CO3, 100 grams of Mn2O3 and 7.04 grams of AI2O3 were mixed together and calcined at 750°C for 16.7 hours. The resulting calcined mixture was cooled, re-mixed in a blender and re-calcined at 750°C for 16.7 hours. X-ray diffraction analysis revealed a LiMn2O4 spinel pattern with a lattice constant of 8.207 A and with small peaks from LiAl5O8 spinel. The produced cathode material calculated as Li1.046Alo.195Mn1.75O4 was cycle tested in a laboratory coin cell battery at 55 °C. The maximum discharge capacity of the cathode material was 109 mAh/g and the fade rate was 0.058% per cycle. It is believed that the immobile LiAl5O8 is a surface species on the LMO spinel particles. Similarly prepared LiAlo.2Mn1.8O4 cathode material exhibited a lattice constant of 8.227 A and an unacceptable capacity of only 55 mAh/g. Extensive AI2O3 was detected in the sample.

13 WE CLAIM :
1. A method of treating particles of spinel having the formula Li1+xMn2.xO4 (0.02
(a) mixing said spinel particles with a particulate reactant selected from the
group consisting of a lithium salt, a lithium metal oxide and a mixture of a lithium salt
and a metal oxide ; and
(b) heating the resulting particulate mixture for a time in the range of from
15 minutes to 20 hours at a temperature in the range of from 350°C to 850°C to thereby
react said spinel particles with said reactant whereby protective coatings of battery-
inactive lithium metal oxide are formed on said spinel particles and the lithium contents
of said spinel particles adjacent to said coatings are increased limited amounts as
represented by the formula Li1+xMn2-xO4 wherein x is less than 0.2.

2. The method as claimed in claim 1 wherein a particulate lithium salt reactant
is selected from the group consisting of lithium carbonate, lithium hydroxide, lithium
nitrate, lithium salts of organic acids and mixtures thereof.
3. The method as claimed in claim 1 wherein a particulate lithium metal oxide
reactant is selected from the group consisting of Li2MnO3, LiScO2, LiYO2, LiZrO3,
Li2HfO3, LiAIO2l LiAI5O8, LiGaO2, LiLaO2, Li2SiO3, LUSiO4, Li2Ge03 and mixtures thereof.

14
4. The method as claimed in claim 1 wherein, a particulate metal oxide reactant
is selected from the group consisting of Sc2O3, Y2O3| ZrO2, HfO2, AI2O3, Ga2O3, La2O3i
SiO2, GeO3 and mixtures thereof.
5. The method as claimed in any one of claim's 1 to 4, wherein said particulate
reactant is mixed with said spinel particles in an amount which is less than or equal to
2.5 mole percent of said spinel particles in said mixture.
6. The method as claimed in claim 2 wherein said particulate lithium salt
reactant has an average particle size less than 10 microns and substantially all of the
particles pass through a 150 mesh screen.
7. The method as claimed in claim 3 or 4 wherein said lithium metal oxide or
said metal oxide reactant, respectively, have an average particle size of less than 5
microns.
8. The method as claimed in any one of claims 1 to 7 wherein said spinel
particles have an average size of less than 35 microns and substantially all of said
particles pass through a 200 mesh screen.
9. The method as claimed in any one of claims 1 to 8, wherein said spinel
particles and said particulate reactant are mixed in accordance with step (a) in a high
intensity, low shear vibratory ball mill or the equivalent which does not reduce the size of
said spinel particles.

15
10. The method as claimed in claim 9 wherein said spinel particles and
participate reactant are mixed for a time period including discharging the mixture which
does not exceed 75 minutes.
11. The method as claimed in any one claims 1 to 10 comprising the step of
cooling said heated and reacted particulate mixture to a temperature below 200°C in a
time period in the range of from 10 to 120 minutes.
12. The method as claimed in claim 11 comprising the steps of cleaning and
sizing said reacted and cooled particulate mixture by removing metallic particles from
said mixture and removing oversize particles by passing said mixture through a 150
mesh or smaller screen.
13. A particulate stabilized spinel battery cathode material having a protective
coating of lithium metal oxide thereon produced by the method as claimed in any one of
claims 1 to 12.
Improved stabilized spinel battery cathode material and methods of treating particles of spinel battery cathode material to produce a protective coating of battery-inactive lithium metal oxide on the particles are provided. The methods comprise mixing the spinel particles with a paniculate reactant selected from a lithium salt, a lithium metal oxide or a mixture of a lithium salt and a metal oxide and then heating the resultant particulate mixture for a time and temperature to react the paniculate reactant with the spinel particles whereby a protective coating of lithium metal oxide is formed on the spinel particles and the lithium content of the spinel adjacent to the coating is increased a limited amount.

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Patent Number

201215

Indian Patent Application Number

00926/KOLNP/2003

PG Journal Number

12/2007

Publication Date

23-Mar-2007

Grant Date

23-Mar-2007

Date of Filing

18-Jul-2003

Name of Patentee

KERR-MCGEE CHEMICAL .LLC

Applicant Address

123 ROBERT S. KERR, OKALHOMA CITY, OK 73102

Inventors:

#	Inventor's Name	Inventor's Address
1	PETERSON ROBERT L	30TH NORTH 2ND EAST, SODA SPRINGS, ID 83276,
2	HOWARD WILMONT F JR	648 WILDMEADOW DRIVE, EDMOND, OK 73003
3	SHEARGOLD STEPHEN W	2513 PAWNEE CROSSING EDMOND, OK 73034
4	STORY PHILIP M	13225 W.MEMORIAL ROAD, YUKON ,OK 73099

PCT International Classification Number

M 01M 4/50,4/02

PCT International Application Number

PCT/US01/50292

PCT International Filing date

2002-01-18

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	09/741.550	2000-12-19	U.S.A.