Title of Invention

AN INSTALLATION AND METHOD FOR STORING AND RETURNING ELECTRICAL ENERGY

Abstract The present invention relates to an installation for storing and recovering electric energy comprising two first and second enclosures (1,2) containing a gas and porous refractory materials (11) capable of transferring thermal calories by contact between the said porous refractory materials and a gas travelling through the said enclosures, and means (3b, 4b) for compressing and means (3c, 4c) for expanding the gas travelling in pipes between each of the ends of an enclosure connected to one end of the other enclosure. The present invention relates to methods for storing electric energy in the form of thermal energy in which use is made of an installation according to the invention and a method for recovering an electric energy (E R) from a thermal energy stored by a method according to the invention. The electric energy is stored in the form of heat inside masses of refractory products, and this stored thermal potential energy is recovered in the form of electric energy.
Full Text AN INSTALLATION AND METHOD FOR STORING AND RETURNING
ELECTRICAL ENERGY
The present invention relates to an installation for
storing and returning electrical energy that is suitable
for storing several tens, or even several thousands of
megawatt hours (MWh), and it also relates to methods of
storing electrical energy in the form of heat energy in
which use is made of an installation of the invention,
and a method of returning electrical energy from heat
energy stored by a method of the invention.
The present invention relates to storing energy at
high temperature and more particularly to storing
electrical energy in order to return it over the
electricity network during peaks of consumption.
Electricity is generally produced by power stations
using a variety of fuels for producing the energy, such
as gas, oil, coal, or lignite. Another means consists in
using nuclear fuel to produce the heat that is then
transformed into electrical energy in high pressure steam
turbines.
Renewable energies are also known that contribute to
a greatly varying extent to the production of electricity
in various countries. Mention can be made, amongst other
possibilities of: hydraulic energy from dams, wind
turbines, water turbines that take energy from sea
currents, and various devices that recover energy from
the swell of the sea, or indeed from solar energy.
Although installations that produce electricity from
fuel or from water retained by dams can operate
continuously at nominal or maximum power during very long
periods, renewable energies are characterized by
operation that is intermittent, and incorporating
renewable energy in a network generally serves to off-
load only a fraction of conventional power stations, some
of which can then be run at low power or even merely
stopped, while waiting for a power demand from the
network.
Various techniques are known that use turbines to
produce mechanical energy from fuels, such as gas or oil,
which consist in compressing an oxidizer, generally air,
then mixing it with a fuel and causing it to burn in a
combustion chamber, and finally directing it towards an
expansion turbine in order to recover the mechanical
energy that is produced, the compressor and the expansion
turbine generally being mounted in line on a common
shaft. In that type of rotary machine, maximum efficiency
is sought, where maximum efficiency is a function of the
inlet temperature to the expansion turbine. The limits on
operating temperature are due to the temperature behavior
of the blades in the expansion turbine, given the very
aggressive nature of combustion gas at very high
temperature, combustion gas generally being made up of
CO2, of NOx, and of other compounds that are aggressive
for the alloys used for making the blades of the turbine.
Steam turbines are also known that are used in
nuclear power stations for converting the energy of water
that has been taken to very high temperature in the form
of steam, firstly into mechanical energy, and then into
electrical energy within generators that are coupled to
the end of the steam turbine shaft. Such steam turbines
operate in a closed circuit for the heat-conveying fluid,
water in the steam phase upstream from the turbine and
liquid water downstream from said turbine.
Attempts have been made for a long time to store
energy so as to have energy available almost
instantaneously during consumption peaks. Numerous
techniques have been developed, and mention can be made,
amongst others, of electrical storage batteries,
generally lead-acid batteries, or pumping water up to a
dam at altitude, for the purpose of driving turbines
during peaks in energy demand.
Storing energy in lead-acid batteries is a valid
technique for small and medium capacities, but when it is
necessary to store the equivalent of a nuclear power
station unit, i.e. about 1200 megawatts (MW) over periods
of 24 hours (h) or 36 h, the installations required
become gigantic and completely unrealistic.
Although dams constitute an excellent means for
storing energy, suitable sites are unfortunately limited
in number, and in addition storing very large quantities
of energy requires enormous quantities of water to be
mobilized, which quantities then need to be taken from
the quantities that are available, and subsequently they
need to be released during periods when there is no need
for such quantities of water, e.g. for irrigation, in
which case the water is then more or less wasted.
Nevertheless, several sites comprise a high reservoir and
a low reservoir, generally large-capacity lakes, and when
storing energy, the content of the low lake is pumped up
to the high lake, to be available for driving a turbine
in the opposite direction when consumption peaks require
additional power to be delivered to the electricity
network.
Another technique consists in storing energy in the
form of compressed air, and then retransforming it into
mechanical energy by piston engines, vane motors, or
indeed turbines.
Patent WO 2005/108758 describes a technique of
storing energy in the form of heat in an underground
enclosure, the heat being generated by compressing air
that is initially at atmospheric pressure and at ambient
temperature, with the temperature within the underground
storage being about 700°C. In that application, the gas,
i.e. air, flows in an open circuit from the free
atmosphere into the cavern during the storage stage, and
then from the cavern to the free atmosphere during the
energy return stage.
In another technical field, regenerators are
commonly employed in industries that use fire, i.e. with
blast furnaces, in the ceramics and terra cotta
industries, in the glass-making and cement-making
industries, which regenerators consist in sending hot
burnt gas into large towers to heat refractory masses
contained therein so as to recover the heat from the gas,
before releasing said gas into the atmosphere. When the
maximum temperature is reached within the refractory
materials, the flow of hot gas is stopped and a reverse
flow of cool air is passed through, which air becomes
heated on making contact with the refractory materials
prior to being directed to the inlets of furnaces, or to
burners. Those arrangements enable heat losses within
industrial processes that consume large amounts of energy
to be reduced very significantly.
The problem posed is to store electrical energy from
conventional power stations, such as coal, gas, oil, or
indeed nuclear power stations, in order to be able to
return the energy very quickly in large quantities to the
electricity network during peak periods when energy
demand exceeds production capacity.
Likewise, with renewable energies, such as wind
turbines or sea water turbines, the problem is to be able
to store large quantities of energy during periods of
strong wind or current, said energy corresponding to
surplus production, in order to return said energy during
a stage in which production is insufficient, i.e. when
the wind or the current does not enable the energy
production level to be maintained at a minimum threshold.
To do this, the present invention consists
essentially in storing considerable quantities of
electrical energy in the form of heat within masses of
refractory materials, the fluid that enables energy to be
transferred being a gas, preferably an inert gas such as
argon, and then to return said stored thermal potential
energy in the form of electrical energy.
More precisely, the present invention provides an
installation for storing and returning electrical energy,
the installation being characterized in that it
comprises :
• first and second enclosures containing a gas and
first and second porous refractory materials suitable for
transferring heat by contact between said porous
refractory materials and a gas flowing through said
enclosures; and
• a closed circuit of pipes enabling a gas to pass
successively through each of the two enclosures from one
end to the other; and
• compressor means and expander means for
compressing and expanding the gas flowing in said pipes
between each of the ends of an enclosure connected to an
end of the other enclosure; and
• preferably, first gas heater means suitable for
heating the gas flowing in said second enclosure; and
• also preferably, cooler means for cooling the gas
flowing between one of the ends of the first enclosure
and said compressor means and expander means, suitable
for cooling the gas leaving said first enclosure at said
end prior to being expanded in said expander means, or
respectively the gas entering into said first enclosure
after being compressed by said compressor means.
It will be understood that the two said nth top (or
bottom) pipes may either be two parallel pipes providing
a junction between said turbine/compressor and a single
enclosure or one of the two includes a branch pipe from
the other ahead of said turbine/compressor.
More particularly, according to the invention, an
installation for storing and returning electrical energy
comprises:
A) a first lagged enclosure filled with a first
porous refractory material suitable for passing a gas
flowing through said first enclosure between top and
bottom ends of said first enclosure; and
B) a second lagged enclosure filled with a second
porous refractory material suitable for passing a gas
flowing through said second enclosure between top and
bottom ends of said second enclosure; and
C) lagged pipes enabling the gas to flow in a closed
circuit between the two enclosures, the pipes comprising
first and second top pipes between the top ends of the
two enclosures, and first and second bottom pipes between
the bottom ends of the two enclosures; and
D) preferably, first gas heater means suitable for
heating a gas inside said second enclosure; and
E) first gas compressor means comprising an electric
motor suitable for being fed with electrical energy for
storing to actuate a first compressor suitable for
compressincf a gas coming from said top end of the second
enclosure via a said second top pipe to deliver it to
said top end of the first enclosure via a said first top
pipe; and
F) first gas expander means comprising a first
turbine suitable for expanding the gas coming from said
bottom end of the first enclosure via a first bottom pipe
to deliver it to said bottom end of the second enclosure
via second bottom pipe; and
G) second gas compressor means suitable for
compressing the gas coming from said bottom end of the
second enclosure via another second bottom pipe to
deliver it to said bottom end of the first enclosure via
another first bottom pipe; and
H) second gas expander means comprising a second
turbine suitable for expanding the gas coming from said
top end of the first enclosure via another first top pipe
to deliver it to said top end of the second enclosure via
another second top pipe, said second expander means being
suitable for actuating an electricity generator suitable
for returning the electrical energy; and
I) gas cooler means, preferably a heat exchanger
suitable for cooling the gas flowing in said first bottom
pipe betw€;en firstly the bottom end of the first
enclosure and secondly the outlet and inlet of said
second compressor and said first turbine, respectively.
Preferably, the electrical energy storage and return
installation of the invention includes second gas heater
means suitable for heating the gas flowing in a said
second top pipe between the top end of said second
enclosure and said first compressor.
According to other advantageous characteristics of
the installation of the invention:
• said first turbine is suitable for being actuated
by said first compressor to which it is mechanically
coupled;
• said second turbine is coupled to an auxiliary
electric motor suitable for driving it; and
• said second compressor is actuated by said second
turbine to which it is mechanically coupled.
In a preferred embodiment, the installation of the
invention is filled with an inert gas, preferably argon.
As explained below, argon gas is advantageous since
it is a gas that is permanent and inert, i.e. it does not
corrode the pipework, and it is a monatomic gas that
presents the advantage of heating easily, and thus a
limited compression ratio, and it is of low cost given
its abundance.
In particular embodiments, the installation presents
the characteristics whereby:
• said first enclosure and the first porous
refractory material are capable of withstanding a
temperature Tl of at least 750°C, preferably lying in the
range 750°C to 2000°C, more preferably 1000°C to 1500°C;
• said second turbine is dimensioned to expand a gas
at said temperature Tl, while said first turbine, of
smaller capacity than the second turbine, is dimensioned
to expand the gas from ambient temperature TO to a
temperature T3 in the range -80°C to -20°C;
• said second enclosure and second porous refractory
material are capable of withstanding a temperature T2 of
at least 400°C, preferably lying in the range 400°C to
1000°C, more preferably 500°C to 700°C; and
• said first compressor is dimensioned to compress a
gas at said temperature T2, while said second compressor,
of smaller capacity than the first compressor, is
dimensioned to compress the gas at a temperature T3 in
the range -80°C to -20°C to ambient temperature.
Still more particularly, said first compressor is
suitable for delivering at a volume flow rate greater
than said first turbine, and said second turbine is
suitable for delivering a volume flow rate greater than
said second compressor, and said first compressor and
second turbine are made of carbon.
Preferably, said refractory materials present an
intrinsic heat capacity per unit volume of at least
2000 kilojoules per cubic meter per kelvin (kJ.m"'. K^M ,
and more preferably at least 2800 kJ.m"^.K-'.
Advantageously, said first and second porous
refractory materials present porosities lying in the
range 20% to 60%.
More particularly, said first and second porous
refractory materials are constituted by porous bricks
assembled one against another, preferably having
cylindrical perforations passing therethrough that are
disposed parallel in a common longitudinal direction that
is the longitudinal direction of the enclosure in which
they are assembled, said perforations more preferably
being of a diameter in the range 5 millimeters (mm) to
20 mm.
In particular embodiments, said first and second
porous refractory materials are constituted by fire clay
having high contents of compounds selected from magnesia,
alumina, and lime.
Refractory materials that may be mentioned are
chamotte, magnesia, dolomite, mullite, and also carbon.
More particularly, said first porous refractory
material is constituted by second-firing fire clay or
chamotte, and said second porous refractory material is
constituted by first firing fire clay.
In a particular embodiment, said first and second
enclosures have respective volumes of not less than 5000
cubic meters (m3), and preferably lying in the range
10,000 m3 to 45,000 m3.
The present invention also provides a method of
storing electrical energy in the form of heat energy, in
which an installation of the invention is used, the
method being characterized in that, after an initial step
of preheating the gas of said second enclosure that is
heated to a temperature Tj, said installation being filled
with a permanent gas that is initially at ambient
temperature T0, the following successive steps are
performed:
1) the gas leaving the top end of the second
enclosure at a temperature T2 is heated to a temperature
T1 higher than a temperature T2 by being compressed in a
said first compressor before being delivered to the top
end of said first enclosure, in which a pressure PI is
established higher than the pressure P2 of the second
enclosure, said first compressor being driven by a first
electric motor powered by the electrical energy that is
to be stored; and
2) the gas passes right through said first enclosure
between said top end and its said bottom end, and it
leaves said bottom end of the first enclosure at an
ambient temperature TO or a temperature T'l greater than
TO but less than T2; and
3) the gas is then cooled, where appropriate, to an
ambient temperature TO by said gas cooler means,
preferably of the heat exchanger type, located downstream
from the outlet of the bottom end of the first enclosure;
and
4) the gas is then expanded through a said first
turbine, preferably driven by said first compressor, to
said pressure P2 of the second enclosure that is lower
than the pressure PI, the gas thus being cooled to a
temperature T3 lower than TO prior to entering into said
second enclosure via its bottom end; and
5) the gas is caused to flow through said second
enclosure between said bottom and top ends of the second
enclosure, thereby having the effect of increasing the
volume of the refractory material in the bottom portion
of said second enclosure that is cooled to the
temperature T3, and of decreasing the volume of its top
portion that is at the temperature T2 or T'2 lower than
T2 but greater than TO and T'l, and if necessary, where
appropriate, the gas leaving the second enclosure at the
temperature T'2 is heated to the temperature T2 with the
help of second gas heater means; and
6) above steps 1) to 5) are repeated until the top
portion of the first enclosure heated to the temperature
Tl occupies at least 80% of the volume of said first
enclosure, and the bottom portion of the second enclosure
cools to a temperature T3 occupying at least 80% of the
volume of the second enclosure.
It will be understood that at each step 2) when the
gas reacheis the temperature Tl at the top end of the
first enclosure, which is initially entirely at the
temperature TO, and the gas moves down from the top end
towards the bottom end of the first enclosure, the gas
passing through said first porous refractory material has
the effect of the gas delivering heat to said first
refractory material in the top portion of the first
enclosure, which then becomes heated to the temperature
Tl, while its bottom portion that is not heated or that
is heated to a smaller extent is at a temperature T'l
lying in the range TO to Tl, and in practice in the range
TO to T2. As the gas that circulates in a closed loop
continues to pass through, the front, or rather the
thermal transition layer, between the hot top portion and
the cold bottom portion in the first enclosure moves
downwards, and the top portion at the temperature Tl
occupies an ever increasing volume. In parallel, in step
5), the gas penetrates into the bottom of the second
enclosure at a cold temperature T3, thereby having the
effect of extracting heat from said second porous
refractory material and thus cooling the bottom portion
of the second enclosure which passes from the temperature
T2 to the temperature T3. As the gas continues to pass,
the front, or rather the thermal transition layer,
between the hot top portion and the cold bottom portion
of the second enclosure progresses upwards and the bottom
portion at the temperature T3 occupies an ever increasing
volume.
The electrical energy El used to feed the first
compressor with energy is thus stored in the form of
(hot) thermal energy (calories) in the first enclosure
and in the form of (cold) thermal energy (frigories) in
the second enclosure, with this energy depending on the
gradient T1-T3.
Preferably, storage is interrupted so that the
bottom portion of the first enclosure at said temperature
T'l represents at least 10% of the volume of the first
enclosure, preferably 10% to 20% of the volume of the
first enclosure, and/or the top portion of the second
enclosure at the temperature T2 represents less than 20%,
preferably 10% to 20% of the volume of said second
enclosure.
According to other particular characteristics of the
present invention that are advantageous, said refractory
materials used have the following properties and masses:
• said temperatures Tl and T2 are such that
Tl/Tl = 1.5 to 3 and Tl/TO is greater than 2, preferably
greater than 3, and more preferably less than 6, and
P1/P2 lies in the range 2 to 4; and
• Tl is 750°C to 2000°C, preferably 1000°C to
1500°C, and T2 is 400°C to 1000°C, preferably 500°C to
700°C; and
• the pressure PI lies in the range 2 to 4 bars
absolute (2x10^ Pa to 4x10^ Pa), and the pressure P2 lies
in the range 0.5 to 1.5 bars absolute (0.5x10^ Pa to
1.5X105 Pa); and
• TO lies in the range 10°C to 50°C and T3 lies in
the range -80°C to -20°C, Tl' lying in the range 20°C to
150°C, where appropriate. Advantageously, a quantity of
electrical energy is stored which lies in the range
2 0 MWh to 10,00 0 MWh.
The present invention also provides a method of
returning electrical energy from heat energy stored by a
method of the invention as defined above, the method
being characterized in that, after an initial starting
stage in which said second compressor and said second
turbine are driven by the said auxiliary electric motor,
during which initial stage a pressure gradient is
established between the pressure P'l in the first
enclosure and a pressure P'2 less P'l in the second
enclosure, such that P'l is greater than P'2, P'l
preferably being greater than PI and P'2 preferably being
less than P2, the following successive steps are
performed:
1) the gas leaving via the top end of the first
enclosure at said temperature Tl is expanded and cooled
to the temperature T2 through the second turbine, and
said second turbine actuates a said electricity generator
enabling returned electrical energy to be delivered; and
2) the gas passes through said second enclosure from
its top end to its bottom end, a top portion of the
second enclosure being heated to said temperature T2, a
bottom portion of the second enclosure remaining at said
temperature T3; and
3) the gas leaving the bottom end of said second
enclosure at the temperature T3 is then compressed by
passing through said second compressor that is preferably
actuated by the energy released by the second turbine so
as to be heated to a temperature T4 greater than an
ambient temperature TO and where appropriate greater than
T'l, but less than T2, at the outlet from said second
compressor; and
4) preferably, the gas is then cooled to the ambient
temperature TO or T'l by said cooler means prior to being
introduced into said first enclosure by its bottom end
(12) to enter the bottom portion of said first enclosure
which is at said temperature T'l; and
5) the gas is caused to flow through said first
enclosure, thereby having the effect of increasing the
volume of refractory material in the bottom portion that
is at said temperature T'l and of decreasing the volume
of refractory material in the top portion that is at said
hot temperature Tl; and
6) above steps 1) to 5) are repeated until the
bottom portion of the first enclosure at said temperature
Tl represents at least 80% of the volume of the first
enclosure, and the top portion of said second enclosure
at said temperature T2 represents at least 80% of the
volume of said second enclosure.
It will be understood that in order to maintain in
the enclosures the same temperatures Tl and T2 as in the
energy storage method of the invention, it is necessary,
in the initial step, to establish a pressure gradient
between the two enclosures that is greater than the
pressure gradient between the enclosures during the
storage method of the invention.
It will be understood that at each step 2), when the
gas reaches the temperature T2 at the top end of the
second enclosure, which is initially not more than 20% at
the temperature T2 or T'2 less than T2, and the gas moves
down from the top end towards the bottom end of the
second enclosure, the passage of the gas through said
second porous refractory material has the effect of the
gas delivering heat to said second refractory material in
the top portion of the second enclosure, which thus
becomes heated to the temperature T2, while its non-
heated bottom portion remains at the temperature T3. As
the gas continues to pass through, the front, or rather
the thermal transition layer, between the hot top portion
and the cold bottom portion of the second enclosure moves
downwards and the bottom portion at the temperature T3
occupies an ever decreasing volume. In parallel, in step
5), the gas arrives at ambient temperature TO or at a
temperature T'l in the bottom of the first enclosure,
thereby cooling said first porous refractory material and
thus cooling the bottom portion of the first enclosure
which goes from the temperature Tl to the temperature
T'l. As the gas continues to pass through, the front, or
rather the thermal transition layer, between the hot top
portion and the cold bottom portion of the first
enclosure moves upwards and the top portion at the
temperature Tl occupies an ever decreasing volume.
The electrical energy E1 stored in the form of (hot)
thermal energy (calories) in the first enclosure and
(cold) thermal energy (frigories) in the second enclosure
is thus converted into electrical energy ER from the
mechanical energy released by said second turbine used
during expansion and cooling of the gas from the first
enclosure.
Preferably, in step 6), the energy return method is
interrupted so as to maintain a top portion of the first
enclosure at a said temperature Tl, said top portion
representing less than 20%, preferably 10% to 20% of the
volume of said first enclosure, and/or a bottom portion
of the second enclosure at said cold temperature T3
represents less than 20%, preferably 10% to 20%, of the
volume of the second enclosure.
Advantageously, the efficiency E^/E^ with which
electrical energy is returned by said electricity
generator is greater than 60%, and preferably lies in the
range 75% to 85%.
According to other characteristics that are
advantageous of the method of returning electrical energy
of the invention:
• the ratio P'l/P'2 lies in the range 3 to 5; and
• T4 lies in the range 150°C to 400°C; and
• the pressure P'l lies in the range 3 to 5 bars
absolute (2X105 Pa to 4x105 Pa) and P'2 lies in the range
1 to 1.5 bars absolute (1x105 Pa to LSx105 Pa).
Other advantages and characteristics of the present
invention appear in the light of the following detailed
description given with reference to the following
figures, in which:
• Figure 1 is a functional diagram of an
installation of the invention in an energy storage method
of the invention, i.e. in a stage of recharging the first
enclosure or hot source;
• Figure 2 is a functional diagram of the
installation of the invention while returning in the form
of electricity the thermal energy stored in the first
enclosure or hot source;
• Figure 3 is a section and side view of an
enclosure of an installation of the invention, including
an enlargement showing cylindrical perforations;
• Figures 3A and 3B are section views on a
horizontal plane showing two variant arrangements for
refractory material elements that are respectively square
and hexagonal in shape;
• Figure 4 shows a perfect-gas type thermodynamic
cycle, and also compression and expansion of a real gas;
• Figure 5 shows the thermodynamic cycle for
recharging the first enclosure from electrical energy
taken from the network; and
• Figure 6 shows the thermodynamic cycle for
returning energy from the first enclosure for the purpose
of being re-injected into the network;
• Figures 7, 7A, and 7B show how a thermal
transition layer of height h advances within a said first
enclosure (Figure 7) between the top and bottom ends
(Figures 7A and 7B respectively).
The device of the invention for storing electrical
energy and for returning electrical energy comprises:
• a first lagged enclosure 1 comprising a steel wall
that is 10 mm to 100 mm thick and that is filled with a
first porous refractory material capable of withstanding
high temperatures and pressures of an inert gas contained
therein, at a temperature Tl lying in the range 1000°C to
1600°C, and more particularly of 13Q0°C, and at a
pressure PI lying in the range 2 bars absolute (bara) to
5 bara (i.e. lying in the range 2x105 pascals (Pa) to
5X105 Pa); and
• a second lagged enclosure 2 having the same
volume, e.g. lying in the range 10,000 m3 to 15,000 m3,
having a steel wall of thickness lying in the range 10 mm
to 100 mm and filled with a second porous refractory
material capable of withstanding the temperature 72 and
the pressure P2 of the inert gas it contains, i.e. T2
lying in the range 500°C to 700°C, and more particularly
being about 6 00°C.
Said first and second enclosures 1 and 2 are
substantially entirely filled with a porous refractory
material 11 having high calorific volume as described
above.
The device includes ducts for closed-circuit
circulation between said first and second enclosures 1
and 2 so as to enable the gas contained in the
installation to pass through each of the enclosures
between two opposite ends 11-l2 and 22-22 thereof that are
preferably situated respectively at the top and bottom
ends of said enclosures.
The circulation ducts between the first and second
enclosures also include means for compressing/expanding
the gas between the two enclosures, as explained below.
More particularly, said first and second enclosures
are disposed vertically.
In Figures 1 and 2, the first enclosure 1 has a top
duct 1d at its top end 11, opening out into the top
portion la of the first enclosure, and at its bottom end
12 it has a first bottom duct Ic opening out into the
bottom portion lb of the first enclosure 1.
Similarly, the second enclosure 2 has a second top
duct 2d at its top end 21 opening out into the top portion
2a of the second enclosure 2, and a second bottom duct 2c
at its bottom end 22 opening out into the bottom portion
2b of the second enclosure 2.
Said first and second bottom ducts 1c, 2c and top
ducts 1d, 2d are likewise lagged.
Said second enclosure 2 is coupled to a first heater
5a, preferably a heater comprising an electrical
resistance 5a1 and a closed circuit of heater piping 5a3
between two ends of the second enclosure, the gas flowing
in the heater piping ba3 being heated by said first heater
5a.
A first compression/expansion group 3 is interposed
between said first and second enclosures 1 and 2. This
first compression/expansion group 3 comprises an electric
motor 3a powered by electricity E1 and serving to actuate
a first dynamic compressor 3d of the axial or centrifugal
type, and a first gas turbine 3c, itself coupled to said
first compressor 3b, their respective shafts being
coupled to one another, as explained below.
Said first compressor 3b is connected at its outlet
to the top end 11 of the first enclosure 1 via said first
top pipe 1d, and said first compressor 3b is connected at
its inlet to the top end 21 of said second enclosure 2 via
said second top pipe 2d. Said second top pipe 2d
constitutes the feed pipe of the first compressor 3b and
said first top pipe 1d constitutes the gas exhaust pipe
from the first compressor 3b after compression during a
storage cycle, as explained below.
A second heater 5b, preferably comprising a second
electrical resistance 5a2, co-operates with said second
top pipe 2d, said second heater 5b being interposed
between the top end 21 of the second enclosure 2 and the
inlet of the first compressor 3b.
Said first turbine 3c is connected to the top end 12
of said first enclosure 1 via said first bottom pipe 1c,
and said first turbine 3c is connected to the bottom end
22 of said second enclosure 2 via said second bottom pipe
2c. Said first bottom pipe 1c serves to feed said first
turbine 3c with gas exhausted from the bottom portion lb
of the first enclosure 1, and the gas exhausted from said
first turbine 3c reaches the bottom portion 2b of said
second enclosure 2 via said second bottom pipe 2c, when
the device is operating in a storage cycle, as explained
below.
A heat exchanger 6 co-operates with said first
bottom pipe 1c between the bottom end 12 of said first
enclosure 1 and said first turbine 3c.
As shown in Figure 2, a second group 4, referred to
as an electricity generator group, is interposed between
said first enclosure 1 and said second enclosure 2 as
follows. Said electricity generator second group 4
comprises a second electric motor 4d coupled to a second
gas turbine 4c and to a second compressor 4b. The second
electric motor 4d is a small motor serving essentially to
start the second turbine 4c when starting the energy
return/withdrawal cycle, as explained below.
The electricity generator second group 4 includes an
alternator 4a coupled to the outlet shaft of said second
gas turbine 4c and of said second compressor 4b, so as to
return electrical energy ER when said second turbine 4c
and said compressor 4b are activated, as explained below,
during an energy withdrawal cycle.
Said second turbine 4c is fed with gas by a duct 1d'
constituting a branch connection from said first top duct
1d (also referred to as the first top branch duct 1d'),
or a duct parallel to said first top duct, providing the
connection between the top end 11 of the first enclosure 1
and the second turbine 4c. When the device is operating
in a withdrawal cycle, the expanded gas leaving said
second turbine 4c is exhausted towards the top end 21 of
the second enclosure 2 via a branch duct 2d' on the
second top duct 2d (also referred to as the second top
branch duct 2d') or via a duct parallel with said second
top duct, thus providing the connection between the top
end 21 of the second enclosure and the second turbine 4c.
Said second compressor 4b is fed with gas by a
branch duct 2c' on said second bottom duct 2c (also
referred to as the second branch bottom duct 2c') or a
pipe parallel thereto thus providing a connection between
the bottom end 22 of the second enclosure and the second
compressor 4b. The gas is exhausted from said second
compressor 4b towards the bottom end 12 of said first
enclosure 1 via a branch duct 1c' on said first bottom
duct 1c (also referred to as the first branch bottom duct
1c') or a duct parallel to the first bottom duct 1c,
providing the connection between the bottom end 12 and
said second compressor 4b.
The second branch bottom duct 2c' provides the
connection between the second compressor 4b and the
second bottom pipe 2c before it reaches said first
turbine 3c. The first branch top duct Id' provides a
connection between the second turbine 4c and the first
top duct Id before it reaches said first compressor 3b.
The seconc. branch top duct 2d' provides a junction
between the; second turbine 4c and the second top duct 2d
between sa;.d second heater 5b and said first compressor
3b. The first branch bottom duct Ic' provides a
connection between the second compressor 4b and the first
bottom duct 1c between said heat exchange 6 and first
turbine 3c.
The enclosures 1 and 2 are filled with a porous
refractory material 11 enabling the gas to flow right
through said enclosures between their top ends 11-12 and
bottom ends 12-22. The porous refractory materials used
in the first and second enclosures may present porosity
(void percentage) lying in the range 20% to 60%, thus
constituting a good compromise between firstly sufficient
heat exchange between the gas and the refractory
materials, and secondly head loss that is sufficiently
low, while conserving a speed of flow that is
sufficiently high through said porous material. In
operation, the device of the invention is completely
filled with an inert gas, preferably argon, i.e. the
above-mentioned pipe circuits, turbines, compressors,
heaters, and said first and second enclosures are all
filled with inert gas.
Figure 3 is a section and side view of an enclosure
comprising a gasproof metal outer casing 13 and an
internal lagging system 12 disposed between the wall of
the metal outer casing 13 and a stack of blocks or bricks
of refractory material 11 presenting vertical channels 11^
in the form of perforations, preferably of circular
section with a diameter lying in the range 5 mm to 30 mm,
passing right through them and arranged in substantially
uniform rr,.anner in each plane over the entire horizontal
section of said first enclosure, as shown in detail in
Figures 3A and 3B.
The channels llj^ in the various superposed blocks 11
are in alignment with one another so as to allow the gas
to circulate in the longitudinal direction ZZ of the
enclosure 1, 2 between the two opposite ends of the
enclosure without obstacle between the channels in the
various blocks that are superposed on one another in the
same longitudinal direction ZZ. A highly perforated
support structure 14 situated in the bottom portion of
said enclosure enables the gas entering or exiting via
the adjacent lagged bottom ducts Ic, 2c to be spread in
substantially uniform manner over the entire section of
said enclosure, thereby directing the gas in optimum
manner, i.e. with minimum head losses, to the channels 11;^
passing vertically through said blocks of refractory
material 11 when feeding takes place from the bottom.
similarly, empty spaces 15 are provided in the top
portions of the enclosures so as to enable the gas to be
spread out well when the enclosures are fed with gas from
the top. In Figure 3, the gas enters via the bottom and
leaves through the top portion of the enclosure, with
this corresponding to the storage stage for the second
enclosure and to the return stage for the first
enclosure, as explained below.
Figure 3A is a fragmentary horizontal section in
plan view on plane AA of Figure 3. The blocks 11 of
refractory material are square and they are perforated by
multiple parallel circularly cylindrical holes extending
in the vertical direction ZZ perpendicular to the plane
of the figure. The blocks are advantageously spaced
apart from one another, e.g. by a distance e = 5 mm, so
that the expansion of said blocks during changes of
temperature can take place without damage in the
thickness of the resulting interstitial space, and also
enabling said space to serve, where appropriate, as a
vertical channel for passing gas from the bottom of the
enclosure 2 to the top thereof. The refractory material
blocks 11 are advantageously in direct contact with the
wall of the enclosure via the lagging 12 of said
enclosure, so as to limit any direct and uncontrolled
passage of cold or hot gas in said zone. In a first
version of the invention, the blocks in the successive
planes of blocks of refractory material are
advantageously offset from one another by half a module,
i.e. the blocks are staggered by half a block, so as to
ensure that the assembly is stable within said enclosure,
as shown in Figure 3. In a preferred version of the
enclosure, the blocks are stacked vertically on one
another over the entire height of the enclosure so as to
make up mutually independent stacks that are spaced apart
from one another by 5 mm to 10 mm in all directions, thus
making expansion during storage-return cycles while
avoiding any risk of wear in the horizontal planes AA
during said storage-return cycles, as occurs when they
are mounted in a staggered configuration as shown in
Figure 3.
In Figure 3B, there can be seen refractory blocks
11a of hexagonal section, close to the insulating wall of
an enclosure that is of cylindrical shape. The
connection with the insulating walls takes place either
by direct contact with the edge of a block, or else in
the form of an insulating block 12a that is adapted to
the curvature, or indeed by packing with an insulating
material 12a, e.g. material of the same type as the
lagging 12 of said enclosure, or indeed by a refractory
block 12b of shape that matches the curvature.
Branch connection valves V^ to V^ are provided at the
junctions between:
• the first top duct Id and the first branch top
duct Id' : V^;
¦ the second top duct 2d and the second branch top
duct 2d: Vj,-
• the first bottom duct Ic and the first branch
bottom duct Ic': V3; and
• the second bottom duct 2c and the second branch
bottom duct 2c' : V4.
As explained below with reference to Figures 1 and
2, it is possible to operate said compressor first group
3 (first compressor 3b and first turbine 3c) on its own
by disconnecting said electricity generator second group
4 during an energy storage cycle, or conversely, it is
possible to disconnect said first compressor 3 and open
said branch ducts to cause said second compressor 4 to
operate during an energy withdrawal cycle.
The device of the invention can operate in two
different modes, namely:
• a first mode with storage or charging cycles; and
• a second mode with energy return or energy
withdrawal cycles.
The energy storage or charging mode operates as
follows. Initially, the inert gas, such as argon, is
loaded into the device, i.e. into both enclosures, the
turbines, the compressors, and the pipework. It is at
ambient temperature, e.g. T = 20°C.
Figure 1 shows the device during a stage of
recharging energy or storing energy in the first
enclosure 1.
Initially, the entire installation is at ambient
temperature TO lying in the range 10°C to 20°C, with the
gas contained in the enclosures and the pipework thus
being at said ambient temperature TO and both enclosures
are at the same initial pressure that is associated with
the loading pressure, e.g. 1 bara to 1.2 bara.
The mass of refractory material inside the second
enclosure 2 is then heated to a temperature T2 of 600°C.
To do this, the gas of the second enclosure is caused to
circulate in a closed loop between its top and bottom
ends 2^ and 22 and it is heated outside the enclosure
using the first heater 5a which heat the gas in the
heater pipe Saj that forms the loop between the bottom and
top ends 22 and 2^ of the second enclosure, on the outside
thereof. The gas is caused to circulate through the
heater pipework Saj by a fan Saj, and the first heater 5a
comprises a first resistance 5a^. A valve 5a4 serves to
isolate the first heater 5a when it is not in use at the
end of the initial preheating, thereby avoiding
undesirable transfers and recirculation of gas during a
normal cycle.
When the entire mass of refractory material in the
second enclosure 2 has been raised to the temperature T2
of 600°C, the valve Sa^ is closed and the gas is sent via
the second top duct 2d into the first compressor 3b so as
to heat it to a temperature Tl lying in the range 1200°C
to 1400°C, e.g. 1300°C at the outlet from said first
compressor. A pressure gradient is established between
the two enclosures, the first enclosure being raised to a
pressure PI of 2 bara to 4 bara (2x105 Pa to 4x10^ Pa),
and the pressure P2 in the second enclosure being reduced
to about 1 bara (1x10^ Pa).
In the first enclosure, the top portion la of the
refractory material thus rises towards the temperature Tl
of 1300°C, while the bottom portion lb becomes
established at a temperature T'l lying in the range 20°C
to 100°C.
At the outlet from the bottom end Ij of the first
enclosure, the gas needs to be expanded by the first
turbine 3c so as to reestablish it at the pressure P2 of
the second enclosure prior to being reintroduced into the
second enclosure via the bottom thereof, expanded and
cooled to a temperature T3. Insofar as the energy stored
by the system is associated with the temperature gradient
T1-T3, it is advantageous to keep the temperature T3 as
low as possible. For this purpose, it is advantageous to
cause gas to be introduced and to penetrate into the
first turbine 3b at a temperature that is as low as
possible. That is why the gas is cooled from the
temperature T'l to the temperature TO lying in the range
10°C to 20°C with the help of a heat exchanger 6 at the
outlet from the bottom end Ij of the first enclosure prior
to being introduced into the first turbine 3c.
As the various gas circulation cycles progress while
operating in storage mode, the top portion la of the
refractory material in the hot first enclosure at a
temperature Tl of 1300°C occupies an ever increasing
volume in the enclosure, i.e. the hot gas introduced via
the top end 1^ of the first enclosure 1 delivers heat to
said refractory materials and heats an ever increasing
volume of refractory material in the first enclosure. A
front le that corresponds to a temperature transition
zone is represented by a line in Figures 1 and 2 . The
hot top portion la at the temperature Tl and the cold
bottom portion lb at the temperature T' 1 lying in the
range 20°C to 100°C moves progressively downwards as the
gas circulation cycles continue during storage.
Conversely, the bottom portion 2b of the second enclosure
at the temperature T3 lying in the range at least -80°C
to -20°C occupies an ever increasing volume in the
enclosure 2. The front 2e represents a line of
separat;-on that is constituted by a transition zone
between the bottom portion 2b at the temperature T3 and a
top portion 2a that the temperature T2, and it moves
progressively upwards as the various gas circulation
cycles progress.
The first compressor 3b is actuated by an electric
motor 3a which consumes electrical energy E^^. The first
turbine 3c is coupled to the first compressor 3b via
their shafts, such that the first turbine 3c delivers
energy to the first compressor 3b in addition to the
energy delivered by the first motor 3a.
During successive gas circulation cycles in energy
storage mode, the temperature of the top portion 2a in
the second enclosure tends to decrease to a temperature
T'2 that is lower than T2, i.e. lower than 600°C, e.g.
lying in the range 300°C to 450°C.
To mitigate this drop in temperature of the top
portion 2a of the second enclosure, it is advantageous to
heat the gas leaving the top end 2^ of the second
enclosure by means of a second heater 5b comprising a
second resistance Saj that enables the gas flowing in the
top duct 2d to be heated so as to maintain it at a
temperature T2 of 600°C before it reaches the first
compressor 3b. Similarly, the motor 3a is adjusted in
such a manner as to maintain the outlet temperature from
the first compressor 3b at a constant temperature Tl of
about 1300°C.
Throughout the duration of the various energy
storage cycles, the temperature of the gas at the inlet
to the second heater 5b is measured and the quantity of
electrical energy Ej injected per second into the second
heater 5b is adjusted in real time to raise the gas to a
substantially constant temperature T2. The power
injected into the installation during energy storage
cycles thus corresponds to the electrical energy E^
feeding the first electric motor 3a plus the electrical
energy E2 feeding the second heater 5b.
As mentioned above, during energy storage cycles, it
is necessary to cool the gas leaving the bottom end Ij of
the first enclosure so as to reduce its temperature to
the temperature TO prior to expanding it in the first
turbine 3c. This is done using the heat exchanger 6.
The heat exchanger 6 is fed with a cooling fluid such as
cold water or air at a temperature in the range 10°C to
20°C as to cool the gas leaving the first enclosure at
the temperature T'l lying in the range 20°C to 100°C and
bring it to the temperature TO lying in the range 10°C to
20°C. T?ie cooling fluid from the heat exchanger 6 leaves
the heat exchanger 6 at 6d at a temperature lying in the
range 50°C to 100°C depending on the flow rate of cooling
air or water. The heat exchanger 6 thus releases heat
energy E3 in the form of water heated to a temperature in
the range 50°C to 100°C. This heat energy E3 is energy
that cannot be stored in the system, but it can be
recovered either in a heat pump or it can be used in
industrial processes, or even for urban heating. Thus,
during a complete storage cycle, E3 constitutes a loss
that affects the overall efficiency of the device.
In order to stabilize the system and optimize this
operation during the succession of different passages
from operating in storage mode to operating in energy
return mode, it is preferable to interrupt storage before
the entire first enclosure has been raised to the
temperature Tl or the entire second enclosure has been
lowered to the temperature T3.
In practice, a bottom portion lb constituting 10% to
20% of the total volume of the first enclosure is
maintained in said enclosure at the temperature T'l lying
in the range 20°C to 100°C. In parallel, a top portion
2a of the second enclosure is maintained at the
temperature T2 or close to the temperature T2, i.e.
storage is interrupted when the bottom portion 2b of the
second enclosure at the temperature lying in the range
-80°C to -20°C represents 80% to 90% of the volume of the
second enclosure.
This volume of 10% to 20% corresponds to the volume
of the temperature transition zone of height a as
described below with reference to Figure 7.
Figure 2 shows the cycle for returning energy stored
within the first enclosure 1 in the form of electrical
energy Er.
Once charging of the first enclosure 1 is complete,
the first motor 3a is stopped and the various valves V^^ to
V4 are actuated so as to feed the second group 4 with said
first and second branch top ducts Id', 2d', and said
first and second branch bottom ducts Ic', 2c', the first
compressor 3b and the first turbine 3c no longer being
fed with gas.
Initially, at the end of the charging stage, when
the first motor 3a is switched off, the gas becomes
stationary and its pressure is brought into equilibrium
in the two enclosures 1 and 2 at an intermediate value of
1.5 bara to 2.5 bara (1.5x10^ Pa to 2.5X10^ Pa).
During a stage of starting the mode of operation in
energy return or withdrawal cycling, a small electric
motor 4d is activated that drives the second turbine 4c
and the second compressor 4b that is coupled thereto so
that a pressure gradient becomes established between the
two enclosures 1 and 2, respectively with a pressure P'l
higher than PI in the first enclosure 1 and a pressure
P'2 lower than P2 in the second enclosure 2.
During starting, the second compressor sucks gas
from the second enclosure and sends it to the first
enclosure, thereby increasing the pressure in said first
enclosure, and thus feeding the second turbine with gas
so as to return finally into the second enclosure and
continue its circulation cycle. As soon as the turbine
reaches its operating speed, the small electric motor 4d
is switched off.
Under steady conditions, the second turbine 4c sucks
gas from the top portion of the first enclosure and
delivers it to the second enclosure while cooling and
expanding the gas. In order to optimize the operation of
the installation, it is desirable for the gas leaving the
second turbine 4d to take on substantially the same
temperature T2 as the temperature of the gas in the top
portion of the enclosure 2 at the end of the storage
cycle. To achieve this, losses in the turbine and
compressor are such that P'l/P'2 > P1/P2. In practice,
P'l lies in the range 3 bara to 5 bara and P'2 in the
range 1 bara to 1.5 bara.
When the pressure gradient P'l/P'2 is established,
the motor 4d is switched off. The gas in the bottom
portion 2b of the second enclosure is at the temperature
T3 lying in the range -80°C to -20°C which was its
temperature at the end of the storage cycle. The gas is
taken to the second compressor 4b where it is
recompressed to the pressure P'l. It is simultaneously
heated to the temperature T4, which temperature T4 is
higher than the temperature TO because of the losses in
the second compressor. Typically, T4 lies in the range
100°C to 150°C.
The gas at the temperature T4 greater than TO at the
outlet fjrom the second compressor 4b therefore needs to
be cooled to the temperature T'l using the heat exchanger
6 prior to being delivered to the bottom end 1^ of the
first enclosure 1, in which the bottom portion lb is at
the temperature T'l lying in the range 20°C to 120°C.
The cooling of the gas at the outlet from the second
compressor 4b during the withdrawal cycle has the effect
of causing heat energy E4 to be lost by heating the
cooling liquid. However this cooling of the gas from the
temperature T4 to T'l makes it easier during energy
storage cycles to cool the gas at the outlet from the
bottom end 1^^ of the first enclosure from the temperature
T'l to the temperature TO downstream from the heat
exchanger so that the gas reaches ambient temperature TO
on entering the first turbine 3c during energy storage
cycles. Overall, the heat energy loss E4 during
withdrawal cycles is compensated by a heat energy loss E3
in the heat exchanger 6 that is smaller than during
storage cycles. The heat energies E3 + E4 correspond
overall to the losses from the installation associated
with the gradient T4-T0 and due to losses in the
compressors and the turbines.
The energy E^ returned by the system corresponds to
the energy released by the second turbine 4c that drives
an electrical generator-alternator 4a that enables the
energy to be returned in the form of electricity.
Overall, Ej^ corresponds more precisely to the energy
released by the second turbine 4c minus the energy
consumed by the second compressor 4b which is coupled
thereto. Furthermore, the overall efficiency of the
installation between the storage and withdrawal cycles
can be written as follows:
Er = El - E2 - (E3 + EJ - E5
where E5 represents the losses through the lagging of the
enclosures, the ducts, the turbines, the compressors, and
the various accessories.
The losses E3+E4+E5 represent 15% to 25% compared
with the energies E^+Ej supplied, so the overall
efficiency of the installation and the energy return
method thus lie in the range 75% to 85%.
In order to optimize the energy efficiency of the
installation, it is advantageous to avoid heating the
first enclosure completely to the temperature Tl at the
end of the storage cycle, so as to conserve a thermal
transition layer in the bottom portion lb at a
temperature TO or T'l, and to conserve a thermal
transition zone in the top portion 2b of the second
enclosure at the temperature T2. Similarly, during
energy return cycles at the end of a cycle, withdrawal is
stopped before the first enclosure has been cooled
completely and the second enclosure has been heated
completely so as to conserve a thermal transition layer
in the top portion la corresponding to 10% to 20% of the
volume of the enclosure that remains at the temperature
Tl, and corresponding a thermal transition zone in the
bottom portion 2b of the second enclosure that remains at
the temperature T3, this layer likewise representing 10%
to 20% of the volume of the second enclosure.
This thermal transition zone in the top portion 2b
of the second enclosure at the temperature T2 makes it
easier to reestablish the pressure gradient P'l/P'2
between the two enclosures at the beginning of the cycle
for returning energy corresponding to the same
temperatures T1/T2 in the first/second enclosures
respectively.
Keeping a thermal transition zone at one end of each
of the first and second enclosures at the end of a
storage cycle and at the end of a return cycle is also
advantageous in terms of the overall energy efficiency of
the installation. If the entire first enclosure were to
be heated at the end of the storage cycle, then the gas
leaving the bottom end 1^ of the first enclosure while
heating the volume corresponding to the thermal
transition layer at the bottom end of the first enclosure
would leave at a temperature higher than the temperature
T'l, which would require greater cooling energy E3 and
therefore higher energy losses.
In parallel, if at the end of the return cycle the
bottom end 22 of the entire second enclosure were to be
heated, the gas leaving the bottom end 22 of the second
enclosure would leave at a temperature higher than T3 and
would arrive downstream from the heat exchanger 6 at a
higher temperature T4, thereby leading to higher cooling
heat loss E4 and thus to energy losses that are likewise
greater.
In addition, maintaining a bottom portion lb at the
temperature T'l at the end of storage and a top portion
2a at tne temperature T2 in the second enclosure at the
end of storage makes it easier to start the return cycle,
which requires using the motor 4d during a shorter length
of time in order to establish stable operation with
temperature gradients Tl and T2 in the first and second
enclosures respectively at the pressures P'l and P'2
during return. Likewise, maintaining a hot top layer la
at the temperature Tl in the first enclosure at the end
of energy return and maintaining a cold bottom layer 2b
at the temperature T3 at the end of the return cycle
makes it easier to start the subsequent storage cycle by
reducing the amount of electrical energy E2 that is
needed to maintain the gas entering the first compressor
3b at the temperature T2.
The dimensioning of the first compressor 3b and of
the first turbine 3c used during storage cycles, is very
different from the dimensioning of the second compressor
4b and the second turbine 4c used during withdrawal
cycles given the different temperatures to which they are
subjected. The volume of a gas increases with
temperature, so the compressor and the turbine that
operate with gas inlet at a high temperature needs to be
larger in size. That is why during the storage stage,
the first compressor 3b is a large compressor since it
operates az a temperature Tl of 1300°C, while the first
turbine 3c is a small turbine since it operates at a
temperature T3 of about -50°C. Conversely, during
withdrawal cycles, the second compressor 4c which
operates a temperature T3 of -50°C is a small compressor,
while the second turbine 4c that operates at a
temperature Tl of about 1300°C is a large turbine. It
should be observed that implementing a first turbine 3c
that is small during the storage stage makes it easier
for it to be driven by the large first compressor 3b.
Similarly, implementing a second compressor 4b that is
small rgiduces energy losses and the energy Ej^ corresponds
to the energy released by the second turbine 4c minus the
energy consumed by the second compressor 4b. There is
therefore an additional advantage in having the
temperature T3 as low as possible at the inlet to the
second compressor 4b so as to likewise reduce the
consumption of energy that affects the overall energy
consumption of the system.
Making use of cooling both during energy storage
cycles and during energy withdrawal cycles downstream
from the: bottom end of the first enclosure during energy
storage and upstream from the bottom end of the first
enclosure during energy return, using the same heat
exchanger, enables the size of the heat exchanger to be
reduced compared with an embodiment in which, for
example, the gas is not cooled during energy return
cycles in a heat exchanger downstream from the bottom end
of the first enclosure.
As successive gas circulation cycles take place
during the energy return stage, the front le between the
cold bottom portion lb at T'l and the hot top portion la
at Tl in the first enclosure moves progressively upwards,
while the front 2e between the hot top portion 2a at
temperature T2 from the cold bottom portion 2b at
temperature T3 in the second enclosure moves
progressively downwards.
It should be observed that firstly operating the
heat exchanger 6 on the gas return circuit between the
second compressor 4b and the bottom portion of the first
enclosure 1, and secondly operating the second turbine 4c
are adjusted in such a manner as to maintain said
temperatures Tl and T2 at respective constant values,
e.g. of 1300°C and 500°C, throughout the energy return
cycle.
It should also be observed that, according to an
essential original characteristic of the present
invention, the temperatures Tl and T2 are constant and
identical during energy storage/charging cycles and
during energy return/discharging cycles.
Figure 4 is a graph corresponding to a thermodynamic
cycle in which the abscissa axis represents volumes and
the ordinate axis represents absolute pressures (bara).
Four isothermals are shown corresponding respectively to:
• TO (ambient temperature 20°C);
• Tl (first enclosure temperature: 1300°C);
• T2 (hot second enclosure temperature: 600°C); and
• T3 (cold second enclosure temperature: ~80°C to
-20°C).
Between points A and B, there is represented an
adiabatic compression/expansion cycle for a perfect gas
in application of the relationship: PV = constant,
between the temperatures Tl and T2. In a real machine,
the behavior is different, and for adiabatic compression
between T2 and Tl, the curve actually followed is ABl,
which shows that the temperature Tl is reached at a
pressure Pbl that is lower than Pb and at a volume Vbl
that is greater than Vb. Similarly, during adiabatic
expansion, the temperature T2 is reached for a pressure
Pal that is lower than Pa and a volume Val that is
greater than Va.
It should be observed that for effective management
of heat in both of the enclosures, it is important for
the high portion of each of the gas enclosures to be at
respective temperatures that are substantially identical
during the storage stage and during the return stage. To
explain this point, consider for example the top portion
of the first enclosure. During the storage stage, the
hot gas penetrates from the top into the supply of
refractories. The temperature of the solids cannot
exceed that of the gas but can merely come as close as
possible thereto. During the return stage, the
temperature of the gas leaving the top portion of the
supply of refractory material in the first enclosure can
at best be equal to the temperature of said refractory
material. Identical remarks can be made for the second
enclosure. In order to obtain the highest possible
efficiency, it is important in the first enclosure for
all of the heat of the gas that is injected during the
storage stage to be used as well as possible during the
return stage, and in the second enclosure for all of the
heat recovered from the gas during the storage stage to
be reused as well as possible during the return stage.
In other words, it is advantageous to seek to have
temperatures Tl and T2 that are as close together as
possible (ideally identical) during the storage and
return stages.
As mentioned above with reference to Figure 4, if
the same temperatures Tl and T2 are used during expansion
or compression with real machines, then the pressure
ratios are different. This means that the pressure
ratios of the turbine-and-compressor assemblies used
during tne storage and return stages need to be
different. For example, from Figure 4, during storage
the high pressure is P^^^ and the low pressure P^, whereas
during the return stage the high pressure is P^^ and the
low pressure P^j^.
Figures 5 and 6 show thermodynamic cycles
corresponding respectively to the energy storage and
return cycles that take place in the installations and
methods as described with reference to Figures 1 and 2.
These thermodynamic cycles correspond to a unit volume of
gas, e.g. 1 m3, performing one complete cycle during which
it acquires energy in one of the enclosures or in a
compressor, and then returns it in a turbine or in the
other enclosure. Said unit volume performs this
thermodynamic cycle in a length of time that is very
short compared with the complete duration of a storage or
return cycle, and it thus carries out hundreds or
thousands or even tens of thousands of thermodynamic
cycles, i.e. it passes that many times through the
compressor, the turbine, the ducts, and each of the
enclosures.
Figure 5 shows the storage stage as described with
reference to Figure 1 . The gas coming from the top
portion of the second enclosure enters the first
compressor 3b at the temperature T2 at point A. It is
compressed and leaves at the temperature Tl at point B.
It penetrates the refractory mass 11 of the first
enclosure 1, passes through the refractory mass
delivering heat thereto, thereby causing the temperature
front to move progressively downwards. The gas leaves
the bot'iom portion of the first enclosure at 6a at a
temperature of about 20°C to 100°C, and then passes
through the heat exchanger 6 where it delivers energy E3
to the outside so as to leave said heat exchanger at a
substantially constant temperature TO corresponding to an
ambient temperature of 20°C, corresponding to point C of
the diagram. It then passes through the turbine at 3c
where it gives off its energy to the compressor 3b, and
it leaves the turbine in the pipe 2c at the temperature
T3 (-5C°C) corresponding to point D of the diagram.
Finally, it enters the low portion of the second
enclosure, where it recovers heat from the refractory
mass through which it flows upwards, thereby causing the
temperature front E2 to rise progressively upwards.
Finally,, the gas leaves the second enclosure from the top
thereof and is taken to the compressor 3b, which it
enters at the temperature T2, possibly after passing
through the heater 5b where, if necessary, it receives
sufficient energy E2 to readjust said gas temperature to
a value T2. The gas is then returned to point A on the
diagram and then undertakes a new cycle.
The thermodynamic cycle for returning energy as
shown in detail on Figure 6 takes place as follows. The
gas at high temperature Tl leaves the first enclosure 1
from the top, corresponding to point B on the diagram.
The gas is then passed through the turbine 4c to where it
delivers energy to the generator (ER) and reaches point A
on the diagram at temperature T2. Thereafter it enters
the top of the second enclosure and delivers its heat to
the refractory mass 11, thereby causing the temperature
front 2e to move progressively downwards, and it leaves
said enclosure from the bottom at a temperature T3
corresponding to point D on the diagram. The gas then
passes through the second compressor 4b which it leaves
at a temperature T4 higher than the desired temperature
TO: it then passes through a heat exchanger 6 where it
delivers the quantity of energy E4 to the outside, so as
to return to the temperature TO, and thus to point C of
said diagram. Finally, it penetrates into the first
enclosure from the bottom where it recovers energy and
heats up to reach point B of the diagram, thereby causing
the temperature front le to rise progressively upwards,
in other words cooling said first enclosure down overall.
Figure 7 shows on the left, in section in side view,
the first enclosure and the rising front le between the
bottom zone where the temperature is about 20 °C and the
top portion where the temperature is about 1300°C. This
rising front corresponds to a transition zone of height h
as shown in greater detail by the graph on the right of
Figure 7. During the energy storage stage, the
transition zone moves downwards (Figure 7B), and during
the return stage it moves upwards (Figure 7A) . In order
to remain within the operating ranges of the turbine
machines that corresponds to best efficiency, the first
enclosure is advantageously neither fully charged nor
fully discharged, which corresponds, as shown in detail
in Figure 7B, to limiting the charge/discharge cycle to a
maximum he;ight dE-^, e.g. corresponding to 80%-90% to the
total height, and thus of the total peak capacity of said
first enclosure. In like manner, a similar transition
zone exists in the second enclosure, however it
corresponds to different temperatures, e.g. -50°C in the
bottom portion and 500°C in the top portion. The
percentage of the calorific mass that is used then
corresponds to a height SHj, said used percentage
preferably being substantially identical to that to of
said first enclosure, i.e. 80%-90%.
By means of this configuration having two enclosures
at different temperatures, with masses of refractory
material that are used to only 80%-90% of their heat
capacity, it is possible to obtain efficiency that is
very good, of the order of 75% to 85%.
This is due firstly to the fact that the energy is
alternately pumped and recovered between two temperature
levels T2 to Tl that are both well above ambient
temperature. It is known from Carnot's theorem that the
efficiency of a heat engine increases with increasing
temperature of its hot source.
A second reason lies in the temperatures Tl and T2
being equal during both the storage and the return
stages, with this being obtained by using different
turbine and compressor assemblies operating with
different pressure ratios (P1/P2 and P'l/P'2).
A third reason for the good overall efficiency lies
in the fact that during the storage stage, losses from
the hot compressor 3b are extracted in the form of heat
in the gas. This energy is stored in the refractory of
the first enclosure 1 just like the heat pumped from the
second enclosure. This loss of energy from the hot
compressor is thus recovered for the most part in the
form of useful work during the return stage.
The fourth reason results from using regenerators
for exchanging heat with a gas. It is possible to
arrange sets of refractory parts that can operate at very
high temp)erature and that present a very large heat
exchange area between the gas and the solids. This makes
it possible to approach as close as possible to equality
between the temperatures Tl and T2 in both stages. The
storage capacity is associated with the mass of
refractory material. The disposition of the invention
presents the advantage that nearly all of the refractory
mass is used to perform two roles: storing heat and
exchanging heat with the gas.
The final reason for good overall efficiency results
from the fact that the cold produced by expansion in the
turbine 3c during the storage stage is likewise stored in
the enclosure 2. During the return stage this enables
the gas to be cooled prior to it being compressed by the
compressor 4b, thereby decreasing the amount of energy
absorbed by the compressor 4b, which energy is taken from
the energy that is returned Ej^.
The power of a turbomachine is given by the formula:
W = m.Cp.(T2- Tl)
where: m is the mass flow rate of the gas in kilograms
per second (kg/s), Cp is the heat capacity of the gas in
joules pei: kilogram per kelvin (J/kg/K) , Tl is the gas
inlet temperature and T2 is the gas outlet temperature.
For a turbine, T2 is extracted from the gas). For a compressor, W is
positive (power is delivered to the gas).
The density of the gas is proportional to its molar
mass. It is easier to compress or expand a heavy gas
than a light gas. The necessary machines are smaller and
less expensive for a heavy gas than for a light gas.
The molar mass of argon is 40, of CO2 is 44, of
krypton is 84, of xenon is 131, and of radon is 222.
Thus, a turbomachine using krypton or xenon as its
gas is much more compact than one using a gas such as
helium that has a molar mass of 4, or nitrogen that has a
molar mass of 28. In addition, in the thermodynamic
formula:
PV'' = constant
Y = 1.66 for a monatomic gas;
Y = 1.4 for a diatomic gas; and
Y = 1.33 for a triatomic gas.
The temperature ratios Tl, T2 depends on the
pressure ratio PI, P2 or P'l, P'2, in application of the
formula::
It can be seen that for a given temperature ratio,
the pressure ratio is smaller for a monatomic gas (y =
1.56) than for a diatomic gas (Y = 1.4), or a triatomic
gas (Y == 1.33). This is of practical advantage in the
design of the enclosures. The wall thickness of the
enclosures is associated with the maximum pressure of the
gas. In addition, since the method has the capacity to
store very large quantities of energy it would use
enclosures of very large dimensions. It is therefore
economically advantageous to seek to minimize the
internal pressure level of the gas. One simple way of
achieving this result is to limit the compression ratio
of the gas, for which it is preferable to select a gas
that is monatomic.
Thus, the best cycle is obtained with a monatomic
gas, such as helium, neon, argon, or other noble gases of
high molecular mass.
Diatomic gases such as nitrogen and triatomic gases
such as air or COj are very abundant and inexpensive, but
at high temperature they are aggressive to metals
constitut:-ng the casing of enclosures, the pipes, or the
blades of turbines and compressors, that is why it is
advantageous for the gas within the device to be an inert
gas that is completely inert relative to the metal
elements of the device, such as helium, neon, argon or
other noble gases of higher molar mass. Helium, neon,
and argon are present at significant percentages in
ambient air and they are available in large quantities at
acceptable costs. Of these three gases, argon is the gas
that gives the best performance for use in the device of
the invention since it is monatomic, inert at high and
very high temperatures relative to metal elements
constituting the device of the invention, and it presents
a molecular mass that is high together with an
acquisition cost that is low.
Said first refractory material of the first
enclosure is for example chamotte, also known as second-
firing fire clay that withstands 1200°C, or indeed a
composition having a high content of alumina and/or
magnesia. The second refractory material in the second
enclosure may be first-firing fire clay.
As mentioned above, the refractory materials 11 are
in the form of bricks that are perforated by parallel
channels having a diameter of 5 mm to 20 mm and that pass
right through the bricks, being disposed in such a manner
as to encible gas to circulate and pass along the channels
in the longitudinal direction of the enclosure.
Various types of very high temperature refractory
material that are available under economically acceptable
conditions are listed in the table below.
Chamorte remains the least expensive of all these
materials, but its maximum temperature remains well below
that of th€i others.
Furthermore, the energy stored in a cubic meter of
refractory is given by the formula:
E = V.Cp(T - TO)
where E is expressed in joules, V is the volume of hot
refractory, Cp is the heat capacity in joules per cubic
meter per kelvin (J/m3/K) , T is the hot temperature, and
TO is the initial temperature before heating.
It can thus be seen that the higher the storage
temperature T the greater the amount of energy that is
stored per unit volume of refractory.
Thus, for magnesia the limit temperature of 1800°C
presents better performance in terms of heat capacity per
unit volume with a value:
Cp = 3600 kJ*m-^*K-'
By way of example, for a device having a capacity of
3000 MWh, capable of storing and returning power at
100 MW, corresponding to charging over 40 hours and
return over 30 hours is constituted:
• by a first enclosure that is cylindrical having a
diameter of 41 meters (m) and a height of 20 m,
containing 16,500 m3 of magnesia, presenting 25% porosity,
i.e., 37,000 metric tonnes (t) of refractory material;
and
• a second enclosure having a diameter of 48 m, a
height of 20 m, and containing 22,500 m3 of chamotte,
presenting 35% porosity, i.e. 29,500 t of refractory
material, a storage group comprising a 100 MW electric
motor 3a, a 117 MW compressor 3b, a 17 MW turbine 3c, and
a return group comprising a 100 MW generator 4a, a 156 MW
turbine 4c, and a 56 MW compressor 4b. The internal
volume of the complete installation, including the
connection ducts, but excluding the volume corresponding
to the effective mass of refractory, comes to about
35,000 m3. A fraction of the gas is confined within the
insulating materials that lag the walls of the hot
refractory enclosures (about 12,000 m3) and only an
available volume of 23,000 m3 can participate in gas
circulation. The installation is filled with argon prior
to starting a pressure of 1 bar, i.e. 2 bara, which
corresponds to a volume of 70,000 normalized cubic meters
(Nm3), of which 46,000 Nm3 is free to circulate. During
the storage stage, the pressure PI is 3 bara in the first
enclosure and the pressure P2 is 0.9 bara in the second
enclosure, whereas during discharging, these pressures
are respectively 3.3 bara (P'l) and 0.6 bara (P'2). The
temperature Tl becomes established at 1256°C while the
temperature T2 is about 600°C. During the storage stage,
the flow rate of gas to the turbine 3c or the compressor
3b is 193 normalized cubic meters per second (Nm3/s),
giving a thermodynamic cycle time as shown in Figure 5 of
238 seconds, which corresponds to 600 cycles of gas
circulation for the duration of a full charge. Similar
values a2:e obtained for the discharge cycle.
Centrifugal or axial compressors and turbines are
generally limited in temperature because of the
aggressivity of the gas that results from combustion,
however :-n the device of the invention, said turbines and
said compressors are used in a closed circuit with an
inert gas such as argon, thereby enabling such machines
to present operating points at much higher temperature
than in the prior art.
The energy stored in the first and second enclosures
is not lost unless the device is left inactive for a long
time in terms of charging-discharging, and losses then
take place to the surrounding medium, principally through
the lagging 12 of said enclosures.
Since the method is essentially of advantage in
storing Large quantities of energy, the enclosures are
relatively voluminous, which means that their surface
over volume ratio is small. Heat losses for large
enclosures represent only a small fraction of the energy
stored. Thermal insulation is achieved with materials
presenting high porosity, such as ceramic fiber felts or
ceramic foams. Calculation shows that in the above-cited
example, lagging presenting a thickness of 2 m using
conventional fiber materials enables energy losses to be
limited to less than 1% per day.
since the gas is inert, the large compressor 3b and
the large turbine 4c that operate at high temperature can
advantageously be made with carbon-based materials. Such
materials are capable mechanically of withstanding very
high temperatures, up to more than 2000°C. They are not
usually used for constructing turbomachines since they
oxidize rapidly in oxidizing gases such as air or
combust:.on products. This limitation does not apply
here, so the use of carbon-based materials can be
envisaged. Carbon turbines have already been made
experime^ntally, or for rocket engines having a lifetime
of no more than a few minutes. In this application of
the invention, such turbines or compressors would have no
lifetime limitation. In current machines made using
metals, it is necessary to cool the blades by an internal
flow of cold gas, and this is achieved to the detriment
of efficiency. In spite of that, the moving blades
present a lifetime that is limited because of the
phenomenon of creep.
Figure 1 shows two separate heaters 5a and 5b,
however it is possible to use a single heater, providing
the configuration of the ducts is adapted appropriately.
CLAIMS
1, An installation for storing and returning electrical
energy, the installation being characterized in that it
comprises:
• first and second enclosures (1, 2) containing a
gas and first and second porous refractory materials (11)
suitable for transferring heat by contact between said
porous refractory materials and a gas flowing through
said enclosures; and
• a closed circuit of pipes (Ic, Ic', 2c, 2c', Id,
Id', 2d, 2d') enabling a gas to pass successively through
each of the two enclosures from one end to the other; and
• compressor means (3b, 4b) and expander means (3c,
4c) for compressing and expanding the gas flowing in said
pipes between each of the ends of an enclosure connected
to an end of the other enclosure; and
• preferably, first gas heater means suitable for
heating the gas flowing in said second enclosure (5a) ;
and
• also preferably, cooler means (6) for cooling the
gas flowing between one of the ends of the first
enclosure and said compressor means (4b) and expander
means (3c), suitable for cooling the gas leaving said
first enclosure at said end prior to being expanded in
said expander means (3c), or respectively the gas
entering into said first enclosure after being compressed
by said compressor means (4b).
2. An installation for storing and returning energy
according to claim 1, characterized in that it comprises:
A) a first lagged enclosure (1) filled with a first
porous refractory material suitable for passing a gas
flowing through said first enclosure between top and
bottom ends (1,^, Ij) of said first enclosure; and
B) a second lagged enclosure (2) filled with a
second porous refractory material suitable for passing a
gas flowing through said second enclosure between top and
bottom ends of said second enclosure (2^, 22); and
C) lagged pipes (Ic, Ic', 2c, 2c', Id, Id', 2d, 2d')
enabling the gas to flow in a closed circuit between the
two enclosures, the pipes comprising first and second top
pipes (Id- Id', 2d-2d') between the top ends (1^^, 2^) of
the two enclosures, and first and second bottom pipes
(Ic-lc', 2c-2c') between the bottom ends (Ij, 22) of the
two enclosures; and
D) preferably, first gas heater means (5a) suitable
for heating a gas inside said second enclosure; and
E) first gas compressor means (3) comprising an
electric motor (3a) suitable for being fed with
electrical energy (El) for storing to actuate a first
compressor (3b) suitable for compressing a gas coming
from said top end (2^) of the second enclosure via a said
second top pipe (2d) to deliver it to said top end (1^) of
the first enclosure via a said first top pipe (Id); and
F) first gas expander means (3c) comprising a first
turbine (3c) suitable for expanding the gas coming from
said bottom end (I2) of the first enclosure via a first
bottom pipe (Ic) to deliver it to said bottom end (22) of
the second enclosure via second bottom pipe (2c); and
G) second gas compressor means (4b) suitable for
compressing the gas coming from said bottom end (22) of
the second enclosure via another second bottom pipe (2c,
2c') to deliver it to said bottom end (I2) of the first
enclosure via another first bottom pipe (Ic, Ic'); and
H) second gas expander means comprising a second
turbine (4c) suitable for expanding the gas coming from
said top end (1^^) of the first enclosure via another first
top pipe (Id, Id') to deliver it to said top end (2^) of
the second enclosure via another second top pipe (2d,
2d'), said second expander means being suitable for
actuating an electricity generator (4a) suitable for
returning the electrical energy (Ej^) ; and
I) gas cooler means, preferably a heat exchanger (6)
suitable for cooling the gas flowing in said first bottom
pipe (Ic, Ic') between firstly the bottom end (Ij) of the
first enclosure and secondly the outlet and inlet of said
second compressor (4b) and said first turbine (3c),
respectively.
3. An installation for storing and returning energy
according to claim 2, characterized in that it includes
second gas heater means (5b) suitable for heating the gas
flowing in a said second top pipe (2d) between the top
end of said second enclosure and said first compressor
(3b) .
4. An installation for storing and returning energy
according to claim 2 or claim 3, characterized in that
said first turbine (3c) is suitable for being actuated by
said first compressor (3b) to which it is mechanically
coupled.
5. An installation for storing and returning energy
according to any one of claims 2 to 4, characterized in
that said second turbine (4c) is coupled to an auxiliary
electric motor (4d) suitable for driving it.
6. An installation for storing and returning energy
according to any one of claims 2 to 5, characterized in
that said second compressor (4b) is actuated by said
second turbine (4c) to which it is mechanically coupled.
7. An installation for storing and returning energy
according to any one of claims 1 to 6, characterized in
that it is filled with an inert gas, preferably argon.
8. An installation for storing and returning energy
according to any one of claims 2 to 7, characterized in
that said first enclosure and the first porous refractory
material are capable of withstanding a temperature Tl of
at least 750°C, preferably lying in the range 750°C to
2000°C, m.ore preferably 1000°C to 1500°C, and said second
turbine is dimensioned to expand a gas at said
temperature Tl, while said first turbine, of smaller
capacity than the second turbine, is dimensioned to
expand the gas from ambient temperature TO to a
temperature T3 in the range -80°C to -20°C.
9. An installation for storing and returning energy
according to any one of claims 2 to 8, characterized in
that said second enclosure and second porous refractory
material are capable of withstanding a temperature T2 of
at least 400°C, preferably lying in the range 400°C to
1000°C, more preferably 500°C to 700°C, and said first
compressor is dimensioned to compress a gas at said
temperature T2, while said second compressor, of smaller
capacity than the first compressor, is dimensioned to
compress the gas at a temperature T3 in the range -80°C
to -20°C to ambient temperature.
10. An installation for storing and returning energy
according to any one of claims 2 to 9, characterized in
that said first compressor is suitable for delivering at
a volume flow rate greater than said first turbine, and
said second turbine is suitable for delivering a volume
flow rate greater than said second compressor, and said
first compressor and second turbine are made of carbon.
11. An installation for storing and returning energy
according to any one of claims 1 to 10, characterized in
that said first and second porous refractory materials
present porosities lying in the range 20% to 60%.
12. An installation for storing and returning energy
according to claim 11, characterized in that said first
and second porous refractory materials are constituted by
porous bricks (11) assembled one against another,
preferably having cylindrical perforations (ll^) passing
therethrough that are disposed parallel in a common
longitudinal direction that is the longitudinal direction
of the enclosure in which they are assembled, said
perforations more preferably being of a diameter in the
range 5 mm to 20 mm.
13. An installation for storing and returning energy
according to any one of claims 1 to 12, characterized in
that said first and second porous refractory materials
are constituted by fire clay having high contents of
compounds selected from magnesia, alumina, and lime.
14. An installation for storing and returning energy
according to any one of claims 1 to 13, characterized in
that said first porous refractory material is constituted
by second-firing fire clay or chamotte.
15. An installation for storing and returning energy
according to any one of claims 1 to 14, characterized in
that said second porous refractory material is
constituted by first-firing fire clay.
16. An installation for storing and returning energy
according to any one of claims 1 to 15, characterized in
that said first and second enclosures have respective
volumes cf not less than 5000 m3, and preferably lying in
the range 10,000 m3 to 45,000 m3.
17. A method of storing electrical energy (El) in the
form of heat energy, in which an installation according
to any one of claims 1 to 16 is used, the method being
characterized in that, after an initial step of
preheating the gas of said second enclosure that is
heated to a temperature T2, said installation being filled
with a permanent gas that is initially at ambient
temperature Tq, the following successive steps are
performed:
1) the gas leaving the top end (2^) of the second
enclosure (2) at a temperature T-, is heated to a
temperature T^^ higher than a temperature Tj by being
compressed in a said first compressor {3b) before being
delivered to the top end (1^) of said first enclosure, in
which a pressure PI is established higher than the
pressure P2 of the second enclosure, said first
compressor (3b) being driven by a first electric motor
(3a) powered by the electrical energy (El) that is to be
stored; and
2) the gas passes right through said first enclosure
between said top end (1^) and its said bottom end (I2),
and it leaves said bottom end (Ij) of the first enclosure
at an ambient temperature TO or a temperature T'l greater
than TO but less than T2; and
3) the gas is then cooled, where appropriate, to an
ambient temperature TO by said gas cooler means (5),
preferably of the heat exchanger type, located downstream
from the outlet of the bottom end (Ij) of the first
enclosure; and
4) the gas is then expanded through a said first
turbine (3c), preferably driven by said first compressor
(3b) , to said pressure P2 of the second enclosure that is
lower than the pressure PI, the gas thus being cooled to
a temperature T3 lower than TO prior to entering into
said second enclosure via its bottom end (22) ; and
5) the gas is caused to flow through said second
enclosure between said bottom and top ends (2^, 2^) of the
second enclosure, thereby having the effect of increasing
the volume of the refractory material in the bottom
portion (2b) of said second enclosure that is cooled to
the temperaiture T3, and of decreasing the volume of its
top portion (2a) that is at the temperature T2 or T'2
lower than T2 but greater than TO and T'l, and if
necessary, where appropriate, the gas leaving the second
enclosure at the temperature T'2 is heated to the
temperature T2 with the help of second gas heater means
(5b); and
6) above steps 1) to 5) are repeated until the top
portion (la) of the first enclosure heated to the
temperature Tl occupies at least 80% of the volume of
said first enclosure, and the bottom portion (2b) of the
second enclosure cools to a temperature T3 occupying at
least 80% of the volume of the second enclosure.
18. A method according to claim 17, characterized in
that, in step 6), storage is interrupted so that the
bottom portion (lb) of the first enclosure at said
temperature T'l represents at least 10% of the volume of
the first enclosure, preferably 10% to 20% of the volume
of the first enclosure, and/or the cop portion (2a) of
the second enclosure at the temperature (T2) represents
less than 20%, preferably 10% to 20% of the volume of
said second enclosure.
19. A method according to claim 17 or claim 18,
characterized in that said temperatures Tl and T2 are
such that T1/T2 = 1.5 to 3 and Tl/TO is greater than 2,
preferably greater than 3, and more preferably less than
6, and P1/P2 lies in the range 2 to 4.
20. A method according to any one of claims 17 to 19,
characterized in that Tl is 750°C to 2000°C, preferably
1000°C to 1500°C, and 12 is 400°C to 1000°C, preferably
500°C to 700°C.
21. A method according to claim 19 or claim 20,
characterized in that the pressure PI lies in the range
2 to 4 bars absolute (2X10^ Pa to 4x10^ Pa), and the
pressure P2 lies in the range 0.5 to 1.5 bars absolute
(0.5X105 Pa to 1.5X105 Pa).
22. A method according to any one of claims 17 to 21,
characterized in that TO lies in the range 10°C to 50°C
and T3 lies in the range -80°C to -20°C, Tl' lying in the
range 20°C to 150°C, where appropriate.
23. A nethod according to any of claims 17 to 21,
charact€;rized in that the quantity of electrical energy
stored lies in the range 20 MWh to 10,000 MWh.
24. A method of returning electrical energy (Ej^) from heat
energy stored by a method according to any one of claims
17 to 23, the method being characterized in that, after
an initial starting stage in which said second compressor
(4b) and said second turbine (4c) are driven by the said
auxiliary electric motor (4d), during which initial stage
a pressure gradient is established between the pressure
P'l in the first enclosure and a pressure P'2 less P'l in
the second enclosure, such that P'l is greater than P'2,
P'l preferably being greater than PI and P'2 preferably
being less than P2, the following successive steps are
performed:
1) the gas leaving via the top end (l^) of the first
enclosure (1) at said temperature Tl is expanded and
cooled to the temperature T2 through the second turbine
(4c), and said second turbine (4c) actuates a said
electricity generator (4a) enabling returned electrical
energy (Ef^) to be delivered; and
2) the gas passes through said second enclosure from
its top end (2^^) to its bottom end (2^), a top portion
(2a) of the second enclosure being heated to said
temperature T2, a bottom portion (2b) of the second
enclosure remaining at said temperature T3; and
3) the gas leaving the bottom end (22) of said second
enclosure at the temperature T3 is then compressed by
passing through said second compressor (4b) that is
preferably actuated by the energy released by the second
turbine (4c) so as to be heated to a temperature T4
greater than an ambient temperature TO and where
appropriate greater than T'l, but less than T2, at the
outlet from said second compressor {4b); and
4) preferably, the gas is then cooled to the ambient
temperature TO or T'l by said cooler means (6) prior to
being introduced into said first enclosure (1) by its
bottom end (Ij) to enter the bottom portion (lb) of said
first enclosure which is at said temperature T'l; and
5) the gas is caused to flow through said first
enclosure, thereby having the effect of increasing the
volume of refractory material in the bottom portion (lb)
that is at said temperature T'l and of decreasing the
volume of refractory material in the top portion (la)
that is at said hot temperature Tl; and
6) above steps 1) to 5) are repeated until the
bottom portion (lb) of the first enclosure at said
temperature (Tl) represents at least 80% of the volume of
the first enclosure, and the top portion (2a) of said
second enclosure at said temperature (T2) represents at
least 80% of the volume of said second enclosure.
25. A me~hod according to claim 24, characterized in
that, in step 6), the energy return method is interrupted
so as to maintain a top portion (la) of the first
enclosure at a said temperature Tl, said top portion (la)
represent:.ng less than 20%, preferably 10% to 20% of the
volume of said first enclosure, and/or a bottom portion
(2b) of the second enclosure at said cold temperature T3
represents less than 20%, preferably 10% to 20%, of the
volume of the second enclosure.
26. A method according to claim 24 or claim 25,
characterized in that the efficiency Ej^/E^^ with which
electrical energy is returned by said electricity
generator (4a) is greater than 60%, and preferably lies
in the range 75% to 85%.
27. A method according to any one of claims 24 to 26,
characterized in that the ratio P'l/P'2 lies in the range
3 to 5.
28. A method according to any one of claims 24 to 27,
characterized in that T4 lies in the range 150°C to
400°C.
29. A m€;thod according to any one of claims 24 to 28,
characterized in that the pressure P'l lies in the range
3 to 5 bars absolute (2x10^ Pa to 4x105 Pa) and P'2 lies
in the range 1 to 1.5 bars absolute (1x105 Pa to
1.5X105 Pa).


The present invention relates to an installation for storing and recovering electric energy comprising two first and
second enclosures (1,2) containing a gas and porous refractory materials (11) capable of transferring thermal calories by contact
between the said porous refractory materials and a gas travelling through the said enclosures, and means (3b, 4b) for compressing
and means (3c, 4c) for expanding the gas travelling in pipes between each of the ends of an enclosure connected to one end of the
other enclosure. The present invention relates to methods for storing electric energy in the form of thermal energy in which use is
made of an installation according to the invention and a method for recovering an electric energy (E R) from a thermal energy stored
by a method according to the invention. The electric energy is stored in the form of heat inside masses of refractory products, and
this stored thermal potential energy is recovered in the form of electric energy.

Documents:

http://ipindiaonline.gov.in/patentsearch/GrantedSearch/viewdoc.aspx?id=pdCJr5JceLXvWawvzKivFQ==&loc=wDBSZCsAt7zoiVrqcFJsRw==


Patent Number 279171
Indian Patent Application Number 3829/KOLNP/2009
PG Journal Number 02/2017
Publication Date 13-Jan-2017
Grant Date 13-Jan-2017
Date of Filing 04-Nov-2009
Name of Patentee SAIPEM S.A.
Applicant Address 1/7 AVENUE SAN FERNANDO, F-78180 MONTIGNY LE BRETONEUX FRANCE
Inventors:
# Inventor's Name Inventor's Address
1 RUER, JACQUES 44, AVENUE DE LA RÉPUBLIQUE, F-78230 LE PECQ FRANCE
PCT International Classification Number F01K3/12; F01K25/00; F02C6/14
PCT International Application Number PCT/FR2008/050712
PCT International Filing date 2008-04-21
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 07 55010 2007-05-11 France