Indian Patents. 278320:"APPARATUS AND METHOD FOR THE CONTINUOUS PICKLING OF STEEL STRIP"

Title of Invention	"APPARATUS AND METHOD FOR THE CONTINUOUS PICKLING OF STEEL STRIP"
Abstract	Apparatus and method for the continuous pickling of steel strip The invention relates to the pickling of continuously running steel strip and more particularly to a pickling method, which includes centralized control of all of the pickling operations, and to the apparatus (1) for implementing it.

Full Text	Apparatus and method for the continuous pickling of steel strip The invention relates in general to the pickling of steel strip running continuously through a pickling apparatus,, and more specifically a pickling method which includes centralized control of all of the pickling operations and the apparatus for implementing said pickling. In their production processes, the steel strips are hot rolled at temperatures that can reach nearly 1200°C at the end of rolling, and then cold rolled. After hot rolling, .the steel strips are cooled by spraying water onto the faces of the rolled strips, and they are wound at temperatures of up to 800°C onto coils. During hot rolling, an oxidizing reaction with the water spray forms an iron-oxide layer known as "scale", such that following hot rolling, the steel strips are covered by a relatively thick and hard layer of scale. Oxidation continues as the coils are air cooled. The different temperatures and sources' of oxidation result in the presence of three iron oxides in the scale. This scale must be removed before final cold rolling, as otherwise it would encrust onto the metal and significantly alter its surface condition and its suitability for deep drawing. Furthermore, as the scale layer is extremely hard, its presence on the steel strips could cause very rapid wear of the cold-rolling rollers. Systems comprising specialized lines that subject strips running continuously through tanks containing acid pickling solutions to chemical pickling are classically used for pickling hot-rolled strips. In the oldest systems, the pickling solutions are solutions of sulfuric acid. However, hydrochloric acid-based pickling solutions are used nowadays for environmental and', productivity reasons. An example of a classical continuous pickling line apparatus 1 is shown in Figure 1. It is a pickling apparatus 1, comprising: - a fragmentation system 11 for the oxides that have formed on the surface of the steel strip 2 during hot rolling of that strip 2, to accelerate the subsequent pickling process, - an actual pickling system 12 comprising a plurality of pickling tanks (not shown in Figure 1) for the acid to corrode these oxides, and - a rinsing unit 15 to remove the acid (in particular hydrochloric acid) and iron chlorides present on the surface of the strip 2, the fragmentation system 11, the pickling system 12 and the, rinsing unit being arranged in series such that the strip 2 being pickled passes them successively as it runs continuously through the pickling apparatus 1. The apparatus 1 shown in Figure 1 also includes: - a set of strip uncoilers 21 operating alternately, a welder 23 and a first accumulation system 4, which are arranged in series upstream of the fragmentation system 11, and - a drier 25, a second accumulation system 26, an edge shear 27, an oiler 28, a shear 29 and.a set of coilers 30, which are also arranged in series but downstream of the pickling system 12. In operation, the strip 2 being pickled is uncoiled by the strip uncoilers 21 and passes the shear 22 which crops the head of the strip.2. The strip 2, passing the welder 23, is then welded to the tail of the strip previously cropped by the shear 22. The accumulation system 24 then enables the strip 2 to be accumulated, and then returned downstream, i.e. immediately upstream of the fragmentation system 11, when the tail of the previous strip and the strip 2 being pickled are welded. The strip'. 2 then passes the oxide fragmentation system 11, commonly known as an oxide breaker. This fragmentation system 11 in particular enables the mechanical fragmentation of the scale formed on the strip 2 during the hot-rolling phase, which facilitates and speeds up the acid pickling of the strip 2 which immediately follows this mechanical fragmentation. Then, having passed the fragmentation system 11, the strip 2 being pickled runs continuously through the pickling tanks of the pickling system 12, which are each filled with a churning pickling solution. The acid pickling of the strip 2 is then realized by dipping, and a pickled strip 2 is obtained. Then, having run through the tanks of the pickling system 12, the strip 2 is then rinsed in the. rinsing unit 15, then dried in the drier 25. The second accumulation device 2 6 enables the strip 2 to run continuously through the pickling apparatus 1 during the cropping and coiler 30 loading operations. The edge shear 27 is used to remove the edges of the strip to ensure there are no "edge" defects, such as cracks, and to guarantee a continuous strip width. The oiler 28 is used to protect the pickled sheet against oxidation. The shear 29 crops the strip 2 at the end of the coil, and the coilers 30, which operate alternately, coil the pickled strip 2. The oxide fragmentation operation, which is intended to speed up the overall strip pickling operation, is typically realized in an oxide fragmentation system 11, such as the one shown schematically in Figure 1 and in greater detail in Figure 2. This system 11 enables the fragmentation of. the scale layer using a technique known as "tension levelrng", which involves alternately bending the strip 2 on work rolls 111, which are held by supporting rollers 112, the strip 2 being subjected to elongation by the input 113 and output 114 tensioners. Elongation may reach 2%. The example fragmentation system 12 shown in Figure 3 is one of the most commonly used systems', on continuous pickling lines. Such a system 11 also helps to improve the flatness of the strip 2 being pickled. The actual pickling operation involves causing the iron oxides ("scale") to react with the acid pickling solution. Different chemical reactions occur in this pickling solution depending on the chemical characteristics of the scale layer. In fact, when the strip is hot, between the output of the final finishing stand of the hot mill and the coiler, the scale has a structure made up of layers of protoxide FeO, magnetite Fe304 and a little hematite Fe2O3. When the coils are cooling in ambient air, the strip heads and tails and the edges cool rapidlyT and the scale develops into an Fe3O4 and Fe2O3 structure. As the rest of the strip cools more slowly, the scale forming on it is essentially an Fe3O4-Fe eutectic composition potentially with a little residual FeO. Thus, during pickling in a pickling solution based on hydrochloric acid, the following chemical reactions occur: (Equation Removed) These reactions demonstrate that during pickling the pickling solution has an overall tendency to become less acidic and to become charged correspondingly with iron chlorides. As a continuous pickling process requires the characteristics of the pickling solution to be kept as constant as possible, it must necessarily be regenerated in "regeneration" tanks, which are arranged in line with the pickling installation and which work by injection into a furnace or reactor. Moreover, inhibitors are used to limit the acid corrosion on the bare steel, in particular if the strip stops in the bath. The loss of acidity in the pickling solution, the flow of pickling solution drawn by the strip down through the pickling apparatus, the need to renew and to ensure the best possible concentration balance between successive tanks in the pickling system have led to the adoption of a pickling system such as the one shown in Figure 3. This comprises a plurality of pickling tanks 121, 122, 123 (usually at least 3), which are each filled with pickling solution 1211, 1221, 1231 made up notably of sulfuric acid or hydrochloric acid. These tanks 121, 122, 123 are arranged in series one behind the other following the longitudinal running direction of the strip 2, such that the strip runs successively from one to the other (in this case from tank 123 to tank 121 via tank 122). The control means for movement of the strip 2 (not shown in Figure 3), for example a coiler, are classically arranged at the output of the pickling apparatus 1. These control means enable the strip 2 to be driven in the running direction so that it passes successively through the different pickling tanks 121, 122, 123 forming inside each of them a concave curve oriented upwards (known as a "catenary" curve) which is immersed in the pickling solution 1211, 1221, 1231 contained in each of the tanks 121, 122, 123. In addition to the pickling tanks 121, 122, 123, the pickling apparatus shown in Figure 1 includes a recirculation circuit 13 and a regeneration circuit 14 for the pickling solution 1211, 1221, 1231. The recirculation circuit 13 includes a plurality of storage tanks 131, 132, 133 that are each linked to a pickling tank 121, 122, 123 by means of units for pumping and heating using exchangers 1311, 1321, 1331. The storage tanks .131, 132, 133 are also connected by ducts 1312, 1323, such as to arrange them in the pickling apparatus in the direction opposite the running direction 3 of the strip 2 in the pickling apparatus 1. The regeneration circuit 14 includes a pyrohydrolysis unit 141 to transform the iron chlorides formed during acid corrosion into iron oxides, and a recovery tank 142 to collect oxides in tanks. The pyrohydrolysis unit 141 is connected to the first storage tank 133 and to the last storage tank 131 encountered in the running direction 3 of the strip 2 in the apparatus 1. Moreover, the recovery tank of the tanks 142 is only connected to the pyrohydrolysis unit 141, such that the iron chloride-rich pickling solution is captured in the first circulation tank 133, then regenerated in the pyrohydrolysis unit 141 by means of reactions 6, 7, where the iron chlorides are transformed into oxides: (Equation Removed) The pickling solution thus regenerated is then returned to the last circulation tank 131. The acid concentration balances between the different tanks 121, 122, 123 are defined in a known manner by the flow of pickling solution 1211, 1221, 1231 moved by the strip 2 running from tank to tank (i.e. from tank 123 to tank 121 via tank 122), and by the rate of reverse cascade between the storage tanks 131, 132, 133 (i.e. from tank 131 to tank 133 via tank 132). Extra regenerated acid and, if necessary, new acid 135 is added to the circulation tank 131. The free-acid concentration is therefore highest in the last pickling tank 121 where it can reach 200 g/1 and drops in the upstream tanks 122, 123, where it only reaches a few tens of g/1 in the first tank 123. Correspondingly, the pumping and reheating unit 1331 makes it possible to maintain a heating power that is greater in the first tank 123 in order to reheat the strip 2 and to ensure it is pickled despite the low acid concentration. Once the scale has been eliminated by fragmentation of the scale by acid corrosion, the acid solution may start to corrode the bare strip 2, in particular if the strip 2 stops running and remains for- an extended period in the pickling tanks 121, 122, 123. This unwanted corrosion, commonly known as "over pickling" has the following effects: - Loss of weight, -Variation in surface roughness, - Change of coloration, - Creation of surface marks, - Excessive generation of hydrogen, which may accumulate locally and create an explosion risk. To avoid this, an inhibitor is usually added to the pickling solution 1211, 1221, 1231. Although a correct initial titration of this inhibitor does prevent all risk of over-pickling during normal operation of the apparatus 1, it may be inadequate if the strip stops running and remains for an extended period in the pickling tanks . Following acid pickling, the strip 2 must be rinsed to remove the acid and the iron chlorides present on the surfaces of the strip 2. Rinsing is generally performed in a rinsing unit 15, such as the one shown in Figure 4. This is a rinsing unit classically used in continuous pickling lines. This rinsing unit 15 includes: - batteries of spray bars 151, 152, 153, 154, 155, that are arranged such that they can spray both faces of the strip 2 being pickled as it is running through the rinsing unit 15, - a plurality, of flow tanks 1511, 1521, 1531, 1541, 1551, each of which is arranged beneath a spray bar 151, 152, 153, 154, 155 respectively to recover the water sprayed by the bars 151, 152, 153, 154, 155, each of the flow tanks 1521, 1531, 1541, 1551 overflowing into its neighboring tank forming a cascade flowing in the direction opposite to the running direction 3 of the strip 2, and - Roller drier devices 1501, 1502 placed at the entrance and exit of the rinsing unit 15, as well as roller drier devices 1512, 1523, 1534, 1545 placed between each battery of bars 151, 152, 153, 154, 155. Rinsing is usually performed by a counter-current cascade operating as follows: the strip -2. passes through the rinsing unit 15, where it is sprayed, on both faces, with water, preferably demineralized, by batteries of spray bars 151, 152, 153, 154, 155. The roller drier devices prevent the strip 2 from drawing acid diluted in the water. The water flowing beneath each battery 151, 152, 153, 154, 155 is recovered in its corresponding flow tank 1511, 1521, 1531, 1541, 1551, the overflow of each tank 15,11, 1521, 1531, 1541, 1551 flowing into its neighboring tank in the direction opposite to the running direction 3 of the strip 2. Each flow tank 1511, 1521, 1531, 1541, 1551 is also fitted with a recirculation circuit 1510, 1520, 1530, 1540,. 1501, 1502 each of which includes a pump 15101, 15201, 15301, 15401, 15501. The now acid-rich rinsing water 15510 is recovered in the first flow tank 1511 encountered in the running direction 3 of. the strip 2, then discharged. Extra demineralized water 15510 is situated in line with the final flow tank 1551 encountered. Generally, following the acid pickling and rinsing stages, the surface characteristics of a pickled and rinsed strip are analyzed. This makes it possible to make an'.initial assessment of the quality of the operations performed and, depending on these results, to correct or optimize certain parameters such as the strip running speed V and parameters related to the oxide fragmentation, acid pickling and rinsing processes. In general, these surface characteristics are defined in accordance with the following characteristics: - a well pickled strip has a visibly uniform appearance with minor variations in roughness over the width and length of the strip, - an "under pickled" strip has brown or grey marks that are quite easy to detect and located across the width of the strip, there being major variations -in surface condition between the correctly, and inadequately pickled zones, - an "over pickled" strip has a grey appearance, for example following a prolonged stoppage in the pickling tanks. This grey appearance is easy to detect on visual inspection. However, more subtle visual defects due to inadequate settings for running speed, inhibitor concentration, temperature or acid concentration may not be visible to the naked eye and require high-performance image capture and analysis means. Roughness variation analyses may also be used in addition to appearance analysis. Consequently, a continuous pickling operation for steel strip in an acid medium on a continuous pickling line, such as the one shown in Figure 1, requires the management of a significant number of adjustable parameters relating to the running speed of the strip in the apparatus 1, the performance of oxide fragmentation in the fragmentation system 11, the performance of actual' pickling in the pickling system 12, and the* performance of rinsing in the rinsing unit 15. Japanese patent application JP 56-136982 proposes a control system limited to measuring only the density of the pickling solution which controls the opening and closing of a valve for adding new acid. The acid concentration is calculated solely using this measurement of the density of the pickling solution, applying empirical formulas. Other acid bath control parameters, such as temperature, are not taken into account. The control system described in JP 56-13-6982 is however inadequate: firstly, the reduction in acid concentration due to the chemical reactions 1 to 4 mentioned above is a slow process, and, secondly, the addition of fresh acid involves a significant time constant, resulting in very. significant fluctuations in the controlled variable. In this field, patent. US 6,396,280 is also known, which describes a control system for acid concentration, with which it is possible to continuously measure acid concentration in two consecutive tanks, which makes it possible to measure extra acid doses. Although similar in principle to patent JP 56-136982, the American patent US 6,396,280 claims to limit the fluctuations in acid concentration. However, only one parameter is monitored, and the result of the pickling operation is not taken into account as a control parameter. Patent application US 2002/0130666 describes a complete measurement system outside the pickling tank. This system, which is fitted with a temperature sensor and a conductivity meter, makes it possible to measure the density of the pickling solution by means of variations in the level of liquid in a column. This system effectively makes it possible to change the performance of continuous pickling, but it does not identify the relative impact of concentrations of acid and iron chlorides in the measurements. On the other hand, American patent US 5,175,502 describes a more precise system intended to identify the effects of the acid concentration and iron chloride concentrations by measuring, at a controlled temperature, the density of the undiluted pickling solution coming from a pickling' tank, and the conductivity of the same pickling solution, but diluted in a controlled manner with water. Conductivity varies little with the iron chloride concentration for low acid concentrations (for example around 25. g/1). Conductivity measured in this way is then considered to be independent of the iron chloride content, and therefore representative only of HC1 content. Knowing the dilution rate used for the measurement, it is then easy to extrapolate the acid concentration in the pickling tank and to calculate the iron-chloride concentration. However, the techniques implemented to measure this acid concentration do not allow this concentration to be controlled. There is nothing in the systems of the prior art described above that make it possible to optimize the pickling operation as a whole. To overcome this, the person skilled in the art knows a pickling method controlled by a global process that manages the pickling operation as a whole. Thus, patent US 6,419,756 describes a method for pickling a rolled metal strip running through a pickling apparatus, which includes: - Adjustment of the pickling parameters by an operator, for example the temperature of the pickling solution - Using an optical measuring instrument to measure defects in the. metal strip, which are sorted into different categories of defects and counted by a classifier to determine the frequency of occurrence of these types of faults; - Sending these defect category occurrence frequencies to an * evaluator, which may be a fuzzy evaluator, a neural network or a neural fuzzy evaluator; and finally - Evaluation by the evaluator of the result of pickling, which is a function of the pickling adjustment parameters, on the basis of which the evaluator determines instructions for at least one of • the pickling adjustment parameters. Such a system has the drawback of acting on any one of the adjustment parameters. In the embodiment described in patent US 6,419,756, this is preferably the temperature of the pickling solution. Such a modification has the major drawback of not having an immediate effect on account of the inertia inherent in a pickling apparatus. This invention therefore relates to a pickling method that overcomes the drawbacks of the prior art by implementing a global control process that acts directly on the strip running speed by reducing it in steps, and that does not change the adjustment parameters of. the pickling. This invention also relates to an apparatus for implementing the method according to the invention. More specifically, this invention relates to a pickling method for a metal strip running continuously through a continuous pickling line apparatus, which includes successively a fragmentation stage for oxides formed on the surface of said strip during hot rolling, an acid pickling stage, a strip rinsing stage, and. a drying stage, the strip being driven at a running speed V in said apparatus in a longitudinal running direction perpendicular to the width of the strip, the strip running speed V being controlled by an uncoiling and coiling unit, and each of the stages of pickling being controlled by actuators that can act on the adjustment parameters of the pickling line, the action or absence of action of an actuator on a given adjustment parameter being identified by a status datum. The pickling method according to the invention also includes a global process for controlling pickling, which implements: - the continuous measurement of at least some of the pickling adjustment parameters, said measurement being implemented during pickling; - a command phase which is implemented during pickling, during which the global control process defines and sends optimized command instructions to all of the actuators using a predictive control system; and - continuous inspection of the surface of the strip.. According to the invention, the global process for controlling the pickling method includes: - a prior preparation phase, which is implemented upstream or at the start of pickling, during which the global control process defines and sends pre-adjustment instructions to all of the actuators using an analytical model, which may be associated with a predictive control system; - the continuous calculation of at least some.of the pickling adjustment parameters, said calculation being implemented during pickling; and - the continuous inspection of the surface of the strip defines and sends, in the event of under-pickling, an alarm instruction to the command phase, which reduces stepwise the strip running speed V to a corrected running speed Vcor, the running speed V being reduced stepwise until this defect is no longer detected and no longer triggers an alarm instruction. In this invention, actuator status datum means a datum that contains the operating or not-operating adjustment status of the actuator. In this invention, analytical model means a model of the adjustment parameters, that is realized either using equations or predetermined pre-adjustment tables. The use of an analytical model and a predictive control system has the advantage of making it possible to determine pickling speeds as a function of the adjustment parameters and the measurements of these parameters more precisely than with neural or fuzzy or neural fuzzy models, as in patent US' 6,419,756, and without the need for learning. Advantageously, the predictive model of the global control process corrects the command instructions sent to all of the actuators apart from the strip running speed V, as a function of the correction made to the running speed Vcor, and such as to maintain the quality of the evaluation made during inspection of the surface of the strip. Advantageously, the continuous inspection of the surface of the strip also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until the defect is no longer detected. Advantageously, calculation makes it possible to determine the acid and iron concentrations in the pickling solution, that are, used during acid pickling. Advantageously, the preparation phase includes the following operations: - receiving status data from the actuators, operating data, and target values for the adjustment parameters established by the analytical model to optimize strip pickling; - establishing pre-adjustment instructions for each actuator; - sending each actuator these pre-adjustment instructions; - establishing the input data for the command phase; - sending this input data to the command phase. In this invention, operating data means the data on the strip to be pickled, the size of the strip, the steel grade of the strip, or even data on the scale formed during hot rolling (nature of oxides- formed, quantity, for example). According to one particularly advantageous embodiment of the preparation phase of the method according to the invention, the analytical model includes an analytical sub-model associated with each actuator to define said pre-adjustment instruction for the adjustment parameter on which the related actuator acts. Advantageously, the command phase- includes the following operations: - receiving continuously and in teal time status data from the actuators, information from the nieasurement and calculation means, and input data for the coriunand phase established during the preparation phase; - establishing command signals optimized for each actuator; and - sending said command signals to the actuators. According to one particularly advantageous embodiment of the command phase of the method according to the invention, the predictive control system iacludes a primary adjustment loop to check the optimum operation of each actuator on the command instruction sent to it. Advantageously, the strip inspection phase includes optical inspection of the appearance of the surface of the strip and measurement of the variation of at least one characteristic of the surface condition of the strip. Notable examples of characteristics of the surface condition of the strip include average roughness Ra, maximum roughness Rm (peak-to-peak value) and the number of peaks per cm. Preferably, optical inspection (5001) of the appearance of the surface of the strip (2) and the variation measurement of the surface condition (5002) of the Strip (2). include learning suspect zones with reference to a library of images and/or data enabling a distinction to be made between over-pickling defects, under-pickling defects, or the absence of defects. This invention also relates to a continuous line apparatus for pickling a hot-rolled metal strip running continuously in said apparatus, said apparatus including: - a fragmentation system for oxides formed on the surface of the strip, said oxide fragmentation system being adjustable by means of fragmentation adjustment parameters,' - a pickling system, which is adjustable using pickling adjustment parameters, and - a rinsing system, which is adjustable using rinsing adjustment parameters, - a drying system, and - a set of means for measuring and calculating the adjustment parameters of said apparatus, - a set of actuators, intended to act on the adjustment parameters of said apparatus. According to the invention, the continuous pickling line apparatus also includes: a centralized command system to optimize pickling of the metal strip, said command system including: * a preparation module intended to receive information from all of the measurement and calculation means and the actuators, and to define and send pre-adjustment instructions to all of the actuators, * a command module intended to receive information from all -of. the measurement and calculation means and the actuators, and to define and send optimized command instructions to all of the actuators, and - a strip inspection system arranged at the output of the rinsing system, said inspection system being able to define and send an alarm instruction to the command module to act on the strip running speed V. Advantageously, the inspection system is also able to define and send a command instruction to the command module to act on the rinsing adjustment parameters. Advantageously, the set of measurement and calculation means includes: - a set of measurement means including means for measuring the strip running speed V, means for measuring the adjustment parameters for oxide fragmentation, means for measuring at least some of the adjustment parameters for pickling, and means for measuring the adjustment parameters for rinsing, and - means for calculating at least some of the adjustment parameters for pickling. Advantageously, the calculation means are able to determine the concentrations of acid and ferrous ions in the pickling solution used in the pickling system. Advantageously, the set of actuators includes fragmentation actuators intended to act on the oxide fragmentation adjustment parameters, pickling actuators intended to act on the pickling adjustment parameters, and rinsing actuators intended to act on the rinsing adjustment parameters. The pickling apparatus according to the invention enables the method according to the invention to be implemented. Thus, if the method according to the invention is implemented in the apparatus according to the invention, the preparation phase of the method according to the invention is performed by the preparation module, which establishes, using the analytical model of the pre-adjustment instructions for the different actuators of the apparatus according to the invention, on the basis of the status data generated for the. different actuators, operating data concerning the strip being pickled, and target values for the adjustment parameters. In this invention, target values means the optimum values of the adjustment parameters that' the global control process is intended to achieve. Some of the pickling adjustment parameters are calculated using calculation means in the pickling apparatus according to the invention. These means may advantageously make it possible to determine, on the basis of density and conductivity measurements of the pickling solution in the storage tanks, the acid and iron concentrations of the pickling solution in these storage tanks. Some of the pickling adjustment parameters are measured, during pickling, by the set of different measurement means placed on the pickling line. The command phase is performed by the command module which, on the basis of status data from the actuators, information from the measurement and calculation means, and input data from the predictive control system established during the preparation phase, establishes command instructions that it sends to the different actuators on the pickling line, from which it receives status data in response, which are corrected on each iteration of the global control process. The inspection phase of the surface of the strip is performed by ' the surface inspection system of the apparatus according to the invention, which is independent of the centralized command system. This surface inspection system may advantageously include: - a system for inspecting the appearance of the surface of the strip, and which in particular makes it possible to determine the presence of marks on the surface of the strip, as well as their color, location and size, and - a system for measuring surface condition, which makes it possible in particular to measure variation in at least one characteristic of the surface condition of the strip such as mean roughness Ra, maximum roughness Rm or number of peaks per cm. According to one particularly advantageous embodiment of the present invention in the case of under-pickling, if only one of the surface appearance inspection system and the surface condition measurement system detects a defect and sends an alarm instruction to the command module which sends it* to the operator, which only acts on the strip running speed V if the other of the 4 surface condition measurement system and the surface appearance inspection system also detects said defect. The strip surface appearance inspection system, useable in the apparatus according to the invention, may principally comprise: - a system for lighting the running strip such as the one described in French patent application FR 2892191, - an image capture system, for example made up of a CCD camera such as the one described in French patent application FR 2893519, and - an image processing function (FTI) to eliminate disturbances such" as uneven lighting or light reflections, - a grey-threshold or contour detection function (FD), - a photometric and morphological characterization and extraction function for suspect zones (FE), - a learning-based identification and classification function (FCI) for suspect zones with reference to an image library, capable of distinguishing "under pickling" defects, "over pickling" defects, previously described intrinsic defects in the steel strip, or the absence of any defects. The surface appearance inspection system of the apparatus according to the invention makes it possible to detect pickling defects in the surface of the strip, such as over-pickling or under-pickling, or marks that remain after rinsing. The lighting system of the surface appearance inspection system may advantageously.include a strip light capable of lighting the entire width of the strip within at least one band of the visible spectrum and a color CCD camera capturing the light reflected by the strip. The processing function (FTI) of this surface condition inspection system is used to eliminate disturbances such as uneven lighting or. light reflections, from grey-threshold or contour detection functions and photometric and morphological characterization and extraction functions for suspect zones. Finally the learning-based identification and classification function of suspect zones with reference to an image library of this system is used to identify "under pickling" defects, "over pickling" defects, intrinsic defects in the steel strip, or the absence of any defects. The strip surface appearance inspection system according to the invention makes it possible to continuously examine the entire width of the running strip. The system described in international patent application WO2006/134259 can be used as the surface appearance inspection system. Furthermore, the surface condition measurement system useable in the apparatus according to the invention may principally comprise an optical device, which is provided with the following functions: - a signal processing function (FTS) making it possible to detect variations in at least one profile characteristic (case 1), scatters characteristic (case 2) or reflected light spectrum characteristic (case 3) in suspect zones, - a learning-based suspect-zone classification function (FC) with reference to a database, that is able to distinguish between defects and an absence of defects. This surface condition measurement system makes it possible to continuously examine at least one line situated in the middle of the width of the running strip, and preferably three lines, one of which being situated in the middle of the strip width and the other two in a zone situated between one third and one quarter of the strip width from each edge of the pickled strip. The optical system recommended for use in the strip surface condition measurement system according to the invention is a linear or spot laser triangulation scanner, using either profile measurement (case 1) or scatter (case 2), or, alternatively, an axial chromatic aberration optical device (case 3). If a. profile-measurement laser triangulation scanner device is used, it evaluates the surface condition of the pickled strip by measuring the profile of the illuminated surface by laser beam. The beam of the laser scanner device may be a line (known as a linear laser scanner) or a spot (known as a spot laser scanner). If a scatter-based laser triangulation scanner device is used, it evaluates the surface condition of the pickled strip by-emitting . at least two beams at different angles of incidence, the surface condition of the pickled strip is then evaluated by detecting the difference in the beam diffraction caused by the illuminated surface. If an optical axial chromatic aberration system is used, it evaluates the surface condition of the pickled strip by spectral analysis of the light focused on the surface lit with white light by the optical device. The optical device of the surface condition measurement system according to the invention is advantageously fixed above the center of the pickled strip. According to a first particularly advantageous embodiment of the invention, two axial chromatic aberration optical, scatter laser or laser scanner systems are used, which are preferably located above the running strip, at a distance from its edges of between one third and one quarter of the width of the strip. According to a second also particularly advantageous embodiment of the invention, two laser scanners are used, which are fixed above the pickled strip at a distance from its edges of between one quarter and one third of its width and that are connected to another device of the same type, which is attached to it above the center of the strip. Finally, the apparatus control system is advantageously, also able to send data to a general control system controlling management of the strip processing installations downstream and/or upstream of said pickling apparatus. Other advantageous characteristics of the invention are detailed in the following description of certain embodiments given as examples and shown on the attached drawings: - Figure 1 is a schematic drawing of a first example of the continuous pickling line apparatus known in the prior art, - Figure 2 is a schematic drawing of an example of an oxide fragmentation system known in the prior art and intended for use in a continuous pickling line apparatus, - Figure 3 is a schematic drawing of an example of a pickling system known in the prior art and intended for use in a continuous pickling line apparatus, - Figure 4 is a schematic drawing of an example of a rinsing unit 15 known in the prior art and intended for use in a continuous pickling 'line apparatus, - Figure 5 is a schematic drawing of an example of the continuous pickling line apparatus according to the invention, - Figure 6 is a diagram showing the different phases of the global control process of the method according to the invention. Identical elements shown in Figures 1 to 6 are identified by identical numerical references. The continuous pickling line apparatus 1 shown in Figure 1 has previously been described in the reference to the prior art above. Furthermore, the fragmentation system 12 shown in Figure 2, the pickling system 12 shown in Figure 3, as well as the rinsing unit 15 shown in Figure 4 have also been described previously in the reference to the prior art above. The pickling installation according to the invention shown in Figure 5 in particular includes: - a fragmentation system 11 for the oxide that has formed on the surface of the steel strip 2 during hot rolling, - a pickling system 12 for the acid corrosion of the oxides, and - a rinsing unit 15 to remove the acid (and in particular hydrochloric acid) and iron chlorides present on the surface of the strip. The fragmentation system 11, the pickling system 12 and the rinsing unit 15 are arranged in series in the pickling apparatus 1 according to the invention such that the strip 2 being pickled passes in turn, as it moves continuously through the pickling apparatus 1, the fragmentation system 11, then the pickling system 12 and the rinsing unit 15. The fragmentation system 11 useable in the apparatus according to the invention may in particular be the one shown in Figure 2, which comprises notably: - actuators 45111, 451112 controlling overlapping 1112 of the work rolls 111 via the height difference 1111 between the lowest work roll(s) and the highest work roll(s) between which the strip 2 is leveled, and - an actuator 451113 controlling the traction 451113 exercised between the input tensioners 113 and the output tensioners 114. The pickling system 12 recommended for use in the apparatus 1 according to the invention shown in Figure 5 is the one shown in Figure 3, to which is added: - an acid top-up system 135 at the last storage tank 134 encountered in the running direction 3 of the strip 2, and - a set of means for measuring the pickling adjustment parameters 431212, 431222, 431232, 431242, 431313, 431323, 431333, 431343, 431314, 431324, 431334, 431344 and - a set of actuators 451311, 451311a, 451311b, 431321, 451321a, 451321b, 451331, 451331a, 451331b, 431341, 451341a, 451341b acting on said pickling adjustment parameters. The measurement means 431212, 431222, 431232, 431242, 431313, 431333, 431343, 431314, 431324, 431334, 431344 of the pickling adjustment parameters include: - means for measuring the temperature 431212, 431222, 431232, 431242 of the pickling solution 1211, 1221, 1231, 1241 contained in the different pickling tanks 121, 122, 123, 124, - means for measuring the density 431313, 431323, 431333, 431343 of the pickling solution 1211, 1221, 1231, 1241 in said storage tanks 131, 132, 133, 134, and - means for measuring the conductivity 431314, 431324, 431334, 431344 of the pickling solution 1211, 1221, 1231, 1241 in said storage tanks 131, 132, 133, 134. In the pickling apparatus 1 according to the invention, the actuators 451311, 451311a, 451311b, 451321, 451321a, 451321b, 451331, 451331a, 451331b, 451341, 451341a, 451341b able to act on the pickling adjustment parameters include pumping and reheating units 451311, 451321, 451331, 451341 that are each connected to a pickling tank 121, 122, 123, 124 and that each include: - a heat exchanger 451311a, 451321a, 451331a, 451341a to control the temperature of the pickling solution 1211, 1221, 1231, 1241 in the recirculation circuit 132 of the pickling system 12, and - a pump 451311a, 451321b,.451331b, 451341b to control the flow of pickling solution 1211, 1221, 1231, 1241 in the recirculation circuit 13 of the pickling system 12, and - a pump 451351 to control the flow of extra acid 135 in the last storage tank 134 encountered in the running direction 3 of the strip 2. The rinsing system useable in the apparatus according to the invention shown in Figure 4 may be the one shown in Figure 4, which comprises: - a plurality of spray bars 151, 152, 153, 154, 155 supplied with demineralized water for rinsing, which are arranged such that they can spray both faces 21, 22 of the strip 2 with water, - a plurality of flow tanks 1511, 1521, 1531, 1541, 1551, each of which is arranged beneath the spray bars 151, 152, 153, 154, 155, the water overflowing into its neighboring, tank forming a cascade flowing in the direction opposite to the running direction 3 of the strip 2, - roller drier devices 1501, 1502 placed at the entrance and exit of the rinsing unit 15, as well as roller drier devices 1512, 1523, 1534, 1545 placed between each battery of bars 151, 152, 153, 154, 155. The rinsing system 15 shown in Figure 5 also includes (compared to the rinsing system 15 in the prior art shown in Figure 4): - a main demineralized-water top-up system 1504 to supply rinsing water to the spray bars 151, 152, 153, 154, 155 of the rinsing unit, - two supplementary demineralized-water top-up devices 1534, 1544 to supply, as required, the third 153 and fourth 154 spray bars encountered in the running direction 3 of the strip 2, - acid injection devices 1515, 1525, 1535 in the first flow tanks 1511, 1521, 1531 of the rinsing unit 15 encountered in the . running direction 3 of the strip 2, and - alkaline-product injection devices 1536, 1546 in the third 1531 and fourth 1541 flow tanks of the rinsing unit 15 encountered in the running direction 3 of the strip 2. Furthermore, the rinsing system 15 of the apparatus shown in Figure 5 includes measurement means 431512, 431522, 431532, 431542, 431552, 431553, 431554 of the rinsing adjustment parameters and actuators 4515151, 4515251, 4515351, 4515361, 4515461, 4515341, 4515441, 4515041, 4515042 able to act on these rinsing adjustment parameters. The measurement means 431512, 431522, 431532, 431542, 431552, 431553, 431554.of the rinsing adjustment parameters enabling the activation of the rinsing device 15 include: - pH measurement means 431512, 431522, 431532, 431542, 431552 for the rinsing water in the flow tanks 1511, 1521, 1531, 1541, 1551 of the rinsing units 15, - conductivity measurement means 431553 for the rinsing water contained in the last flow tank 1551 encountered in the running direction 3 of the strip 2, - temperature measurement means 431554 for the rinsing water contained in the last flow tank 1551 encountered in the running direction 3 of the strip 2.' The actuators 4515151, 4515251, 4515351, 4515361, 4515461, 4515341, 4515441, 4515041, 4515042 able to act on the rinsing parameters include: - pumps 4515151, 4515251, 4515351 to control the flow of acid from said acid-injection devices 1515, 1525, 1535, - pumps 4515361, 4515461 to control the flow of alkaline product from the alkaline-product-injection devices 1536, 1546, - pumps 4515341, 4515441 to control the flow of demineralized water from the supplementary demineralized-water top-up devices 1534, 1544, - a pump 4515041 to control the flow of demineralized water from the main demineralized-water top-up device 1504, - a heat exchanger 4515042 to control the temperature of the demineralized water from the main demineralized-water top-up device 1504. The apparatus 1 according to the invention also includes, at the output of rinsing and drying an inspection system 5 of the strip 2 that breaks down as follows: - a surface appearance inspection system 51, and - a surface condition measurement system 52'. The surface appearance inspection system 5 of the strip 2 includes advantageously: - a lighting device 511 for the running strip 2, which is attached to - an image capture device. 512, - an image processing function 513. - a grey-threshold or contour detection function 514, - a photometric and morphological characterization and extraction function 515 for suspect zones, and - an identification and classification function 516 for suspect zones with reference to an image library, this function 516 making it possible to distinguish between "under pickling" defects, "over pickling" defects or even intrinsic defects in the steel strip 2, and the absence of any defects. The surface condition measurement system 52 includes advantageously: - an optical device 521 for the continuous examination of at least one line of the running strip 2, - a signal processing function 522, and - a learning-based classification function 523 with reference to a database, for suspect zones, this function 523 making it possible to distinguish between defects and an absence of defects. The surface condition measurement system 52 makes it possible to continuously examine at least one line situated in the middle of the width of the running strip 2; and preferably three lines where one is situated in the middle of the strip width and the two others in a zone situated between one third and one quarter of the strip width from each edge of the pickled strip. All of the measurement means 43 of the apparatus 1 and all of the actuators 45 of the apparatus 1 are controlled by a centralized control system 4, which enables the control of pickling by means of a global process that includes: the continuous measurement 43101, 43102 of at least some of the pickling adjustment parameters, said measurement being implemented during pickling; the continuous calculation 43200 of at least some of the pickling adjustment parameters, said calculation being implemented during pickling; a prior preparation phase 4101, 4102 which is implemented upstream or at the start of pickling, during which the global control process'4000 defines 4101 and sends 4102 pre-adjustment instructions 411 to all of the actuators 45 using an analytical model, which may be associated with a predictive control system a command phase 4201, 4202 which is implemented' during pickling, during which the global control process 4000 defines 4201 and sends 4202 optimized command instructions to all of the actuators using a predictive control system; and the continuous inspection 5001, 5002 of the surface of the strip 2, which results in the definition 5001 and sending 5002, in the case of under-pickling, of an alarm instruction (500) to the command phase 4201, 4202, which reduces the running speed V of the strip 2 stepwise to a corrected running speed Vcor, the stepwise reduction in the running speed V being effected until the condition of the strip 2 is deemed to be satisfactory during the inspection 5001, 5002 of the surface of the strip 2. The preparation module 41 performs the preparation phase 4101, 41.02 of the method according to this invention, which includes 'advantageously the following operations: - receiving status data 450 from 4501 the actuators 45, operating data .413, and target values 412 for the adjustment parameters established by the analytical model to optimize pickling of the strip 2; - establishing 4101 pre-adjustment.instructions 411 for each actuator 45; - sending 4102 pre-adjustment instructions 421 to each actuator 45; - establishing 410.3 the input data 414 for the command phase 4201, 4202; - sending 4104 said input data 414 to the command phase 4401. A calculation module performs the calculation phase 43200 for the different concentrations of acid 4321 and iron 4322 in the pickling solution 1211, 1221, 1231, 1241 flowing in the pickling system 12. The command module 42 performs the command phase 4401, 4402, which includes the following operations: - receiving continuously and in real time status data 450 from 4502 the actuators 45, information from 4300 the measurement and calculation means 43, and input data 414 for the command phase 4201, 4202 established during the preparation phase 4101, 4102; - establishing 4201 command signals 425 optimized for each actuator 45; sending 4202 said command signals 421 to the actuators 45. The surface inspection system 5 performs the surface inspection phase of the strip 2 at the output of the pickling apparatus, by optical inspection 5001 of the appearance of the surface of the strip 2 firstly, and by measuring the variations in the condition of the surface of the strip 2. CLAIMS 1. A pickling method for a metal strip (2) running through a pickling line apparatus (1), which includes successively a fragmentation stage for oxides formed on the surface of said strip (2) during hot rolling, an acid pickling stage, a rinsing stage for the strip (2), and a drying stage, the strip (2) being driven at a running speed V in said apparatus (1) in a longitudinal running direction perpendicular to the width of the strip (2), the running speed V of the strip (2) .being controlied by an uncoiling (21) and coiling (30) unit, and each of the stages of pickling being controlled by actuators (45') that can act on the adjustment parameters of the pickling line (1), the action or absence of action of an actuator (45) on a given adjustment parameter being identified by a status datum (450) . said method including a global control process (4000) for pickling, which implements: - the continuous measurement (43101, 43102)'of at least some of the pickling adjustment parameters, said measurement being implemented during pickling; - a command phase (4201, 4202) which is implemented during pickling, during which the global control process (4000) defines (4201) and sends (4202) optimized command instructions (425) to all of the actuators (45) using a predictive control system; and - the continuous inspection (5001, 5002) of the surface of the strip (2); said method being characterized in that the global control process (4000) includes: - a prior preparation phase (4101, 4102) which is implemented upstream or at the start of pickling, during which the global control process (4000) defines (4101) and sends (4102) pre-adjustment instructions (411) to all of the actuators (45) using an analytical model, which may be associated with the predictive control system; - the continuous calculation (43200) of at least some of the pickling adjustment parameters, said calculation being implemented during pickling; and also characterized in that the continuous inspection (5001, 5002) of the surface of the strip (2) defines (5001) and sends (5002), in the event of under-pickling, an alarm instruction (500) to the command phase (4201, 4202), which reduces stepwise (5001) the running speed' V of the strip (2) to a corrected running speed (Vcor)',. the stepwise reduction of the running speed V being effected until the defect is no longer detected and no longer triggers the alarm instruction (500), characterized in that the continuous inspection (5001, 5002) of the surface of the strip (2) also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until the defect is no longer detected. 2. The method as claimed in claim 1, characterized in that said predictive model of the global control process (4000) corrects the command instructions (425) sent to all of the actuators (45) apart from the running speed V of the strip (2), as a function of the correction made to the running speed Vcor, and such as to. maintain the quality of the evaluation made during inspection (5001, 5002) of the surface of the strip (2). 3. The method as claimed in any one of the preceding claims, characterized in that the inspection (5001, 5002) of the strip (2) includes: - optical inspection (5001) of the appearance of the surface of the strip (2) - measurement of the variation of at least one characteristic of the surface condition (5002) of the strip (2). 4. The method as claimed in any one of the preceding claims, characterized in that optical inspection (5001) of the appearance of the surface of the strip (2) and the variation measurement of the surface condition (5002) of the strip (2) include learning suspect zones with reference to a library of images and/or data enabling a distinction to be made between over-pickling defects, under-pickling defects, or the absence of defects. . 5. The method as claimed in any one of the preceding claims, characterized in that the calculation (43200) defines the acid and iron concentrations in the pickling solution (1211, 1221, 1241) used during acid pickling. 6. The method as claimed in any one of the preceding claims, characterized in that the preparation phase (4101, 4102) includes the following operations - receiving status data (450) from (4501) the actuators (45), operating data (413), and target values (412) for the adjustment parameters established by the analytical model to optimize pickling of the strip (2) - Establishing (4101) pre-adjustment instructions (411) for each actuator (45) - sending (4102) said pre-adjustment instructions (421) to each actuator (45) - establishing (4103) input data (414) for the command phase (4201, 4202) - sending (4104) said input data (414) to the command phase (4401). 7. The method as claimed in claim 6, characterized in that the analytical model includes an analytical sub-model associated with each actuator (45) to define said pre-adjustment instruction (411) for the adjustment parameter on which the related actuator (45) acts. 8. The method as claimed in any one of the preceding claims, characterized in that the command phase (4201, 4202) includes the following operations - receiving 'continuously and in real time status data (450) from (45-92) the actuators (45), information from (4300) the measurement and calculation means (43), and input data (414) for the command phase (4201, 4202) established during the preparation phase (4101, 4102); - establishing (4201) command signals (425) optimized for each actuator (45) - sending (4202) said command signals (421) to the actuators (45) . 9. The method as claimed in claim 8, characterized in that the predictive control system includes a primary adjustment loop to check the optimum operation of each actuator (45) on the command instruction (425) sent to it. 10. A continuous line apparatus (1) for pickling a hot-rolled •metal strip (2) running continuously'in said apparatus (1), said apparatus (1) including: - a fragmentation system (11) for oxides formed on the surface of the strip (2), said oxide fragmentation system (11)- be-ing adjustable by means of fragmentation adjustment parameters (1111, 1112, 1113), - a pickling system (12), which is adjustable using pickling adjustment parameters, and - a rinsing system (15), which is adjustable using.rinsing adjustment parameters, - a set of means for measuring and calculating (43) the adjustment parameters of said.apparatus (1), - a set of actuators (45), intended to act on the adjustment parameters of said apparatus (1)'. said apparatus being characterized in that it also includes - a centralized command system (4) to optimize pickling of the metal strip (2), said command system (4) including: * a preparation module, (41') intended to receive (4100) information from all of the measurement and calculation means (43) and the actuators (45), and to define (4101) and send (4102) pre-adjustment instructions (411) to all of the actuators (45), * a command module (42) intended to receive (4200) information from all of the measurement and calculation means (43) and the actuators (45), and to define (4201) and send (4202) optimized command instructions (421) to all of the actuators' (45), and ' - an inspection system (5, 51, 52) for the strip (2) arranged at the output of the rinsing system (15), said inspection system (5) being able to define (5001) and send (5002) an alarm instruction (500) to the command module (42) to act on the running speed V of the strip (2), characterized in that the inspection (5001, 5002) of said continuous inspection system of the surface of the strip (2) also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until-the defect is no longer detected. 11. The apparatus (1) as claimed in claim 10, characterized in that said inspection system (55, .51, 52) is also able to define (5001) and send (5002) a command instruction (500) to the command module (42) to act on the rinsing adjustment parameters. 12. The apparatus (1) as claimed in claim 10 or 11, characterized in that the set of measurement and calculation means' (43) -includes: - a set of measurement means (431) including measurement. means (4312) for the running speed V of the strip (2), measurement means for the oxide fragmentation adjustment parameters (431111, 431112, 431113), measurement means for at least some of the pickling adjustment parameters (431212, . 431222, 431232, 431242, 431313, 431323, 431333, 431343, 431314, 431324, 431334, 341344), and measurement means for the rinsing adjustment parameters (431512, 431522, 431532, 431542, 431553, 431554)), and - calculation means (432) for at least some of the pickling adjustment parameters. 13. The apparatus (1) as claimed in any one of claims 10'to 12, characterized in that the set of actuators (45) includes fragmentation actuators (451111, 451112, 451113) intended to act on the oxide fragmentation adjustment parameters (1111, 1112, 1113), pickling actuators (451311, 451311a, 451311b 451321, 451321a, 451321b, 451331, 451331a, 451331b, 451341, 451341a, 451341b) intended to act on the pickling adjustment . parameters, and rinsing actuators (4515151, 4515251, 4515351, 4515361, 4-515461, 4515341, 4515441, 4515041, 4515042) intended to act on-the rinsing adjustment parameters. 14. The apparatus (1) as claimed in any one of claims 10 to 13, characterized in that- the calculation means are able to .determine the acid and ferrous-ion concentrations in the pickling solution (1211, 1221, 1241) used in the pickling system (12). 15. The apparatus (1) as claimed in any one of claims 10 to 14, characterized in that: - the rinsing unit (15) includes a plurality of spray bars (151, 152, 153, 154, 155) supplied with demineralized water for rinsing and arranged such that they can spray water onto the strip (2), and a plurality of flow tanks (1511, 1521, 1531, 1541, 1551), which are each arranged underneath said spray bars (151, 152, 153, 154, 155), and - the' measurement means for the rinsing adjustment paramete-rs (431512, 431522, 431532, 431542, 431553, 431554) include pH measurement'means .(431512, 431522, 431532, 431542, 431552) for the rinsing water in the flow tanks (1511, 1521, 1531, 1541, 1551) of the rinsing unit (15) , conductivity measurement means (431553), and temperature measurement means (431554) for the rinsing water contained in the last flow tank (1551) encountered in the running direction (3) of the strip (2) . 16. The apparatus (1) as claimed in claim 15, characterized in that: - the rinsing unit (15) includes a main demineralized- water top-up device (1504) to. supply the spray bars (151, 152, 153, 154, 155) of the rinsing unit (15), supplementary demineralized-water top-up devices (1534, 1544) to supply the third (153) and fourth (154) spray bars encountered in the running direction (3) of the strip (2), acid injection devices (1515, 1525, 1535) in the first flow tanks (1511, 1521, 1531) of the rinsing unit (15) encountered in the running direction (3) of the strip (2), and alkaline-product injection devices (1536, 1546) in the third (1531) and fourth (1541) flow tanks of the rinsing unit (15) encountered in the running direction (3) of the strip (2), and - the actuators (4515151, 4515251, 4515351, 4515361, 4515461, 4515341, 4515441, 4515041, 4515042) able to act on the rinsing parameters include a pump (4515041) to control the flow of demineralized water from the main demineralized-water top-up device (1504), a heat exchanger (4515042) to control the • temperature of the demineralized water from the main demineralized-water top-up device (1504), and pumps (4515341, 4515441) to control the flow of demineralized water from the supplementary demineralized-water top-up devices (1534, 1544), pumps (4515151, 4515251, 4515351) to control the- flow of acid from sai-d acid injection" devices (1515, 1525, 1535) , and pumps (4515361, 451.5461) to control the flow of alkaline-product from said alkaline-product injection devices (1536; 1546). 17. The apparatus (1) as claimed in any one of claims 10 to 16, characterized in that the surface inspection system (5) of the strip (2) includes: - a surface appearance inspection system (51) for the strip (2), and ' - a surface condition measurement system (52) for the strip (2). 18. The apparatus (1) as claimed in any one of claims 10 to 17, characterized in that in the event of under-pickling, only one of the surface appearance inspection system (51) and the surface condition measurement system (52) detects a defect and • sends (5002)- an alarm instruction (500) to the command module. (42) which sends it to the operator, .which only acts on the . running speed V of the strip (2) if the other of the surface condition measurement system (52) and the surface appearance inspection system (51) also detects said defect. 19. The apparatus (1) as claimed in claim 17 or 18, characterized in that the surface appearance inspection system (51) includes: - a lighting device (511) for the running strip (2), which is attached to - an image capture device- (512) -an image processing function (513), - a grey-threshold or contour detection function (514), - a photometric and morphological characterization and extraction function (515) for suspect zones, and - a—suspect-zone identification and classification function (51.6) . 20. The apparatus (1) as claimed in claim 17 or 18, characterized in that the surface condition measurement system (52) is able to measure variations in at least one characteristic of the surface condition of the strip (2). 21. The apparatus (1) as claimed in claim 20, characterized in that the surface condition measurement system (52) includes - at least one optical•device (521) for the continuous examination of at least one line of the strip (2), - a signal processing function (522), and - a suspect-zone classification function (523). 22. The apparatus (1) as claimed in claim 21, characterized in that the optical device (521) is a laser scanner device, a scatter laser device or an optical axial chromatic aberration device. The apparatus (1) as claimed in claim 21 or 22, characterized in that the surface condition measurement system (52) includes two optical devices. (521) , that are located above the running strip, at a distance from its edges of between one quarter and one third of the width of the strip. 23 The apparatus (1) as claimed in claim 21 or 22, characterized in that the surface condition measurement system (52) includes two optical devices (521), that are fixed above the pickled strip, at a distance from its edges of between one quarter and one third of its width and that are connected to another device of the same type, which is fixed above the center of the strip. 24. The apparatus (1) as claimed in any 'one of claims 10 to 24, characterized in that the control system (4) of the apparatus (1) is able to send data to a general control system controlling management of the processing installation for the strip (2) downstream and/or upstream of said pickling apparatus (1)

Full Text

Apparatus and method for the continuous pickling of steel strip
The invention relates in general to the pickling of steel strip running continuously through a pickling apparatus,, and more specifically a pickling method which includes centralized control of all of the pickling operations and the apparatus for implementing said pickling.
In their production processes, the steel strips are hot rolled at temperatures that can reach nearly 1200°C at the end of rolling, and then cold rolled. After hot rolling, .the steel strips are cooled by spraying water onto the faces of the rolled strips, and they are wound at temperatures of up to 800°C onto coils. During hot rolling, an oxidizing reaction with the water spray forms an iron-oxide layer known as "scale", such that following hot rolling, the steel strips are covered by a relatively thick and hard layer of scale. Oxidation continues as the coils are air cooled. The different temperatures and sources' of oxidation result in the presence of three iron oxides in the scale. This scale must be removed before final cold rolling, as otherwise it would encrust onto the metal and significantly alter its surface condition and its suitability for deep drawing. Furthermore, as the scale layer is extremely hard, its presence on the steel strips could cause very rapid wear of the cold-rolling rollers. Systems comprising specialized lines that subject strips running continuously through tanks containing acid pickling solutions to chemical pickling are classically used for pickling hot-rolled strips.
In the oldest systems, the pickling solutions are solutions of sulfuric acid. However, hydrochloric acid-based pickling solutions are used nowadays for environmental and', productivity reasons.
An example of a classical continuous pickling line apparatus 1 is shown in Figure 1. It is a pickling apparatus 1, comprising:
- a fragmentation system 11 for the oxides that have formed on the surface of the steel strip 2 during hot rolling of that strip 2, to accelerate the subsequent pickling process,
- an actual pickling system 12 comprising a plurality of pickling tanks (not shown in Figure 1) for the acid to corrode these oxides, and
- a rinsing unit 15 to remove the acid (in particular hydrochloric acid) and iron chlorides present on the surface of the strip 2,
the fragmentation system 11, the pickling system 12 and the, rinsing unit being arranged in series such that the strip 2 being pickled passes them successively as it runs continuously through the pickling apparatus 1. The apparatus 1 shown in Figure 1 also includes:
- a set of strip uncoilers 21 operating alternately, a welder 23 and a first accumulation system 4, which are arranged in series upstream of the fragmentation system 11, and
- a drier 25, a second accumulation system 26, an edge shear 27, an oiler 28, a shear 29 and.a set of coilers 30, which are also arranged in series but downstream of the pickling system 12.
In operation, the strip 2 being pickled is uncoiled by the strip uncoilers 21 and passes the shear 22 which crops the head of the strip.2. The strip 2, passing the welder 23, is then welded to the tail of the strip previously cropped by the shear 22. The accumulation system 24 then enables the strip 2 to be accumulated, and then returned downstream, i.e. immediately upstream of the fragmentation system 11, when the tail of the previous strip and the strip 2 being pickled are welded. The strip'. 2 then passes the oxide fragmentation system 11, commonly known as an oxide breaker. This fragmentation system 11 in
particular enables the mechanical fragmentation of the scale formed on the strip 2 during the hot-rolling phase, which facilitates and speeds up the acid pickling of the strip 2 which immediately follows this mechanical fragmentation. Then, having passed the fragmentation system 11, the strip 2 being pickled runs continuously through the pickling tanks of the pickling system 12, which are each filled with a churning pickling solution. The acid pickling of the strip 2 is then realized by dipping, and a pickled strip 2 is obtained.
Then, having run through the tanks of the pickling system 12, the strip 2 is then rinsed in the. rinsing unit 15, then dried in the drier 25. The second accumulation device 2 6 enables the strip 2 to run continuously through the pickling apparatus 1 during the cropping and coiler 30 loading operations.
The edge shear 27 is used to remove the edges of the strip to ensure there are no "edge" defects, such as cracks, and to guarantee a continuous strip width. The oiler 28 is used to protect the pickled sheet against oxidation. The shear 29 crops the strip 2 at the end of the coil, and the coilers 30, which operate alternately, coil the pickled strip 2.
The oxide fragmentation operation, which is intended to speed up the overall strip pickling operation, is typically realized in an oxide fragmentation system 11, such as the one shown schematically in Figure 1 and in greater detail in Figure 2. This system 11 enables the fragmentation of. the scale layer using a technique known as "tension levelrng", which involves alternately bending the strip 2 on work rolls 111, which are held by supporting rollers 112, the strip 2 being subjected to elongation by the input 113 and output 114 tensioners. Elongation may reach 2%. The example fragmentation system 12 shown in Figure 3 is one of the most commonly used systems', on continuous pickling
lines. Such a system 11 also helps to improve the flatness of the strip 2 being pickled.
The actual pickling operation involves causing the iron oxides ("scale") to react with the acid pickling solution. Different chemical reactions occur in this pickling solution depending on the chemical characteristics of the scale layer. In fact, when the strip is hot, between the output of the final finishing stand of the hot mill and the coiler, the scale has a structure made up of layers of protoxide FeO, magnetite Fe304 and a little hematite Fe2O3. When the coils are cooling in ambient air, the strip heads and tails and the edges cool rapidlyT and the scale develops into an Fe3O4 and Fe2O3 structure. As the rest of the strip cools more slowly, the scale forming on it is essentially an Fe3O4-Fe eutectic composition potentially with a little residual FeO.
Thus, during pickling in a pickling solution based on hydrochloric acid, the following chemical reactions occur:
(Equation Removed)
These reactions demonstrate that during pickling the pickling solution has an overall tendency to become less acidic and to become charged correspondingly with iron chlorides. As a continuous pickling process requires the characteristics of the pickling solution to be kept as constant as possible, it must necessarily be regenerated in "regeneration" tanks, which are arranged in line with the pickling installation and which work by injection into a furnace or reactor. Moreover, inhibitors are used to limit the acid corrosion on the bare steel, in particular if the strip stops in the bath.
The loss of acidity in the pickling solution, the flow of pickling solution drawn by the strip down through the pickling apparatus, the need to renew and to ensure the best possible concentration balance between successive tanks in the pickling system have led to the adoption of a pickling system such as the one shown in Figure 3. This comprises a plurality of pickling tanks 121, 122, 123 (usually at least 3), which are each filled with pickling solution 1211, 1221, 1231 made up notably of sulfuric acid or hydrochloric acid. These tanks 121, 122, 123 are arranged in series one behind the other following the longitudinal running direction of the strip 2, such that the strip runs successively from one to the other (in this case from tank 123 to tank 121 via tank 122). The control means for movement of the strip 2 (not shown in Figure 3), for example a coiler, are classically arranged at the output of the pickling apparatus 1. These control means enable the strip 2 to be driven in the running direction so that it passes successively through the different pickling tanks 121, 122, 123 forming inside each of them a concave curve oriented upwards (known as a "catenary" curve) which is immersed in the pickling solution 1211, 1221, 1231 contained in each of the tanks
121, 122, 123.
In addition to the pickling tanks 121, 122, 123, the pickling apparatus shown in Figure 1 includes a recirculation circuit 13 and a regeneration circuit 14 for the pickling solution 1211, 1221, 1231.
The recirculation circuit 13 includes a plurality of storage tanks 131, 132, 133 that are each linked to a pickling tank 121,
122, 123 by means of units for pumping and heating using
exchangers 1311, 1321, 1331.
The storage tanks .131, 132, 133 are also connected by ducts 1312, 1323, such as to arrange them in the pickling apparatus in the
direction opposite the running direction 3 of the strip 2 in the pickling apparatus 1.
The regeneration circuit 14 includes a pyrohydrolysis unit 141 to transform the iron chlorides formed during acid corrosion into iron oxides, and a recovery tank 142 to collect oxides in tanks. The pyrohydrolysis unit 141 is connected to the first storage tank 133 and to the last storage tank 131 encountered in the running direction 3 of the strip 2 in the apparatus 1. Moreover, the recovery tank of the tanks 142 is only connected to the pyrohydrolysis unit 141, such that the iron chloride-rich pickling solution is captured in the first circulation tank 133, then regenerated in the pyrohydrolysis unit 141 by means of reactions 6, 7, where the iron chlorides are transformed into oxides:
(Equation Removed)
The pickling solution thus regenerated is then returned to the
last circulation tank 131.
The acid concentration balances between the different tanks 121,
122, 123 are defined in a known manner by the flow of pickling
solution 1211, 1221, 1231 moved by the strip 2 running from tank
to tank (i.e. from tank 123 to tank 121 via tank 122), and by the
rate of reverse cascade between the storage tanks 131, 132, 133
(i.e. from tank 131 to tank 133 via tank 132).
Extra regenerated acid and, if necessary, new acid 135 is added
to the circulation tank 131.
The free-acid concentration is therefore highest in the last
pickling tank 121 where it can reach 200 g/1 and drops in the
upstream tanks 122, 123, where it only reaches a few tens of g/1
in the first tank 123. Correspondingly, the pumping and reheating
unit 1331 makes it possible to maintain a heating power that is
greater in the first tank 123 in order to reheat the strip 2 and to ensure it is pickled despite the low acid concentration.
Once the scale has been eliminated by fragmentation of the scale by acid corrosion, the acid solution may start to corrode the bare strip 2, in particular if the strip 2 stops running and remains for- an extended period in the pickling tanks 121, 122, 123. This unwanted corrosion, commonly known as "over pickling" has the following effects:
- Loss of weight,
-Variation in surface roughness,
- Change of coloration,
- Creation of surface marks,
- Excessive generation of hydrogen, which may accumulate locally
and create an explosion risk.
To avoid this, an inhibitor is usually added to the pickling solution 1211, 1221, 1231. Although a correct initial titration of this inhibitor does prevent all risk of over-pickling during normal operation of the apparatus 1, it may be inadequate if the strip stops running and remains for an extended period in the pickling tanks .
Following acid pickling, the strip 2 must be rinsed to remove the acid and the iron chlorides present on the surfaces of the strip 2. Rinsing is generally performed in a rinsing unit 15, such as the one shown in Figure 4. This is a rinsing unit classically used in continuous pickling lines. This rinsing unit 15 includes:
- batteries of spray bars 151, 152, 153, 154, 155, that are
arranged such that they can spray both faces of the strip 2 being
pickled as it is running through the rinsing unit 15,
- a plurality, of flow tanks 1511, 1521, 1531, 1541, 1551, each of which is arranged beneath a spray bar 151, 152, 153, 154, 155
respectively to recover the water sprayed by the bars 151, 152, 153, 154, 155, each of the flow tanks 1521, 1531, 1541, 1551 overflowing into its neighboring tank forming a cascade flowing in the direction opposite to the running direction 3 of the strip 2, and
- Roller drier devices 1501, 1502 placed at the entrance and exit of the rinsing unit 15, as well as roller drier devices 1512, 1523, 1534, 1545 placed between each battery of bars 151, 152, 153, 154, 155.
Rinsing is usually performed by a counter-current cascade operating as follows: the strip -2. passes through the rinsing unit 15, where it is sprayed, on both faces, with water, preferably demineralized, by batteries of spray bars 151, 152, 153, 154, 155. The roller drier devices prevent the strip 2 from drawing acid diluted in the water.
The water flowing beneath each battery 151, 152, 153, 154, 155 is recovered in its corresponding flow tank 1511, 1521, 1531, 1541, 1551, the overflow of each tank 15,11, 1521, 1531, 1541, 1551 flowing into its neighboring tank in the direction opposite to the running direction 3 of the strip 2.
Each flow tank 1511, 1521, 1531, 1541, 1551 is also fitted with a recirculation circuit 1510, 1520, 1530, 1540,. 1501, 1502 each of which includes a pump 15101, 15201, 15301, 15401, 15501. The now acid-rich rinsing water 15510 is recovered in the first flow tank 1511 encountered in the running direction 3 of. the strip 2, then discharged. Extra demineralized water 15510 is situated in line with the final flow tank 1551 encountered.
Generally, following the acid pickling and rinsing stages, the surface characteristics of a pickled and rinsed strip are analyzed. This makes it possible to make an'.initial assessment of the quality of the operations performed and, depending on
these results, to correct or optimize certain parameters such as the strip running speed V and parameters related to the oxide fragmentation, acid pickling and rinsing processes. In general, these surface characteristics are defined in accordance with the following characteristics:
- a well pickled strip has a visibly uniform appearance with
minor variations in roughness over the width and length of the strip,
- an "under pickled" strip has brown or grey marks that are quite
easy to detect and located across the width of the strip, there
being major variations -in surface condition between the correctly,
and inadequately pickled zones,
- an "over pickled" strip has a grey appearance, for example
following a prolonged stoppage in the pickling tanks. This grey
appearance is easy to detect on visual inspection.
However, more subtle visual defects due to inadequate settings for running speed, inhibitor concentration, temperature or acid concentration may not be visible to the naked eye and require high-performance image capture and analysis means. Roughness variation analyses may also be used in addition to appearance analysis.
Consequently, a continuous pickling operation for steel strip in an acid medium on a continuous pickling line, such as the one shown in Figure 1, requires the management of a significant number of adjustable parameters relating to the running speed of the strip in the apparatus 1, the performance of oxide fragmentation in the fragmentation system 11, the performance of actual' pickling in the pickling system 12, and the* performance of rinsing in the rinsing unit 15.
Japanese patent application JP 56-136982 proposes a control system limited to measuring only the density of the pickling solution which controls the opening and closing of a valve for
adding new acid. The acid concentration is calculated solely using this measurement of the density of the pickling solution, applying empirical formulas. Other acid bath control parameters, such as temperature, are not taken into account. The control system described in JP 56-13-6982 is however inadequate: firstly, the reduction in acid concentration due to the chemical reactions 1 to 4 mentioned above is a slow process, and, secondly, the addition of fresh acid involves a significant time constant, resulting in very. significant fluctuations in the controlled variable.
In this field, patent. US 6,396,280 is also known, which describes a control system for acid concentration, with which it is possible to continuously measure acid concentration in two consecutive tanks, which makes it possible to measure extra acid doses. Although similar in principle to patent JP 56-136982, the American patent US 6,396,280 claims to limit the fluctuations in acid concentration. However, only one parameter is monitored, and the result of the pickling operation is not taken into account as a control parameter.
Patent application US 2002/0130666 describes a complete measurement system outside the pickling tank. This system, which is fitted with a temperature sensor and a conductivity meter, makes it possible to measure the density of the pickling solution by means of variations in the level of liquid in a column. This system effectively makes it possible to change the performance of continuous pickling, but it does not identify the relative impact of concentrations of acid and iron chlorides in the measurements. On the other hand, American patent US 5,175,502 describes a more precise system intended to identify the effects of the acid concentration and iron chloride concentrations by measuring, at a controlled temperature, the density of the undiluted pickling solution coming from a pickling' tank, and the conductivity of the
same pickling solution, but diluted in a controlled manner with water. Conductivity varies little with the iron chloride concentration for low acid concentrations (for example around 25. g/1). Conductivity measured in this way is then considered to be independent of the iron chloride content, and therefore representative only of HC1 content. Knowing the dilution rate used for the measurement, it is then easy to extrapolate the acid concentration in the pickling tank and to calculate the iron-chloride concentration. However, the techniques implemented to measure this acid concentration do not allow this concentration to be controlled.
There is nothing in the systems of the prior art described above that make it possible to optimize the pickling operation as a whole.
To overcome this, the person skilled in the art knows a pickling method controlled by a global process that manages the pickling operation as a whole. Thus, patent US 6,419,756 describes a method for pickling a rolled metal strip running through a pickling apparatus, which includes:
- Adjustment of the pickling parameters by an operator, for example the temperature of the pickling solution
- Using an optical measuring instrument to measure defects in the. metal strip, which are sorted into different categories of defects and counted by a classifier to determine the frequency of occurrence of these types of faults;
- Sending these defect category occurrence frequencies to an * evaluator, which may be a fuzzy evaluator, a neural network or a neural fuzzy evaluator; and finally
- Evaluation by the evaluator of the result of pickling, which is a function of the pickling adjustment parameters, on the basis of which the evaluator determines instructions for at least one of • the pickling adjustment parameters.

Such a system has the drawback of acting on any one of the adjustment parameters. In the embodiment described in patent US 6,419,756, this is preferably the temperature of the pickling solution. Such a modification has the major drawback of not having an immediate effect on account of the inertia inherent in a pickling apparatus.
This invention therefore relates to a pickling method that overcomes the drawbacks of the prior art by implementing a global control process that acts directly on the strip running speed by reducing it in steps, and that does not change the adjustment parameters of. the pickling. This invention also relates to an apparatus for implementing the method according to the invention. More specifically, this invention relates to a pickling method for a metal strip running continuously through a continuous pickling line apparatus, which includes successively a fragmentation stage for oxides formed on the surface of said strip during hot rolling, an acid pickling stage, a strip rinsing stage, and. a drying stage, the strip being driven at a running speed V in said apparatus in a longitudinal running direction perpendicular to the width of the strip, the strip running speed V being controlled by an uncoiling and coiling unit, and each of the stages of pickling being controlled by actuators that can act on the adjustment parameters of the pickling line, the action or absence of action of an actuator on a given adjustment parameter being identified by a status datum.
The pickling method according to the invention also includes a global process for controlling pickling, which implements:
- the continuous measurement of at least some of the pickling adjustment parameters, said measurement being implemented during pickling;
- a command phase which is implemented during pickling, during which the global control process defines and sends optimized

command instructions to all of the actuators using a predictive control system; and
- continuous inspection of the surface of the strip.. According to the invention, the global process for controlling the pickling method includes:
- a prior preparation phase, which is implemented upstream or at the start of pickling, during which the global control process defines and sends pre-adjustment instructions to all of the actuators using an analytical model, which may be associated with a predictive control system;
- the continuous calculation of at least some.of the pickling adjustment parameters, said calculation being implemented during pickling; and
- the continuous inspection of the surface of the strip defines and sends, in the event of under-pickling, an alarm instruction to the command phase, which reduces stepwise the strip running speed V to a corrected running speed Vcor, the running speed V being reduced stepwise until this defect is no longer detected and no longer triggers an alarm instruction.
In this invention, actuator status datum means a datum that contains the operating or not-operating adjustment status of the actuator.
In this invention, analytical model means a model of the adjustment parameters, that is realized either using equations or predetermined pre-adjustment tables.
The use of an analytical model and a predictive control system has the advantage of making it possible to determine pickling speeds as a function of the adjustment parameters and the measurements of these parameters more precisely than with neural or fuzzy or neural fuzzy models, as in patent US' 6,419,756, and without the need for learning.

Advantageously, the predictive model of the global control process corrects the command instructions sent to all of the actuators apart from the strip running speed V, as a function of the correction made to the running speed Vcor, and such as to maintain the quality of the evaluation made during inspection of the surface of the strip.
Advantageously, the continuous inspection of the surface of the strip also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until the defect is no longer detected.
Advantageously, calculation makes it possible to determine the acid and iron concentrations in the pickling solution, that are, used during acid pickling.
Advantageously, the preparation phase includes the following operations:
- receiving status data from the actuators, operating data, and target values for the adjustment parameters established by the analytical model to optimize strip pickling;
- establishing pre-adjustment instructions for each actuator;
- sending each actuator these pre-adjustment instructions;
- establishing the input data for the command phase;
- sending this input data to the command phase.
In this invention, operating data means the data on the strip to be pickled, the size of the strip, the steel grade of the strip, or even data on the scale formed during hot rolling (nature of oxides- formed, quantity, for example).
According to one particularly advantageous embodiment of the preparation phase of the method according to the invention, the analytical model includes an analytical sub-model associated with each actuator to define said pre-adjustment instruction for the adjustment parameter on which the related actuator acts.

Advantageously, the command phase- includes the following operations:
- receiving continuously and in teal time status data from the actuators, information from the nieasurement and calculation means, and input data for the coriunand phase established during the preparation phase;
- establishing command signals optimized for each actuator; and
- sending said command signals to the actuators. According to one particularly advantageous embodiment of the command phase of the method according to the invention, the predictive control system iacludes a primary adjustment loop to check the optimum operation of each actuator on the command instruction sent to it.
Advantageously, the strip inspection phase includes optical inspection of the appearance of the surface of the strip and measurement of the variation of at least one characteristic of the surface condition of the strip.
Notable examples of characteristics of the surface condition of the strip include average roughness Ra, maximum roughness Rm (peak-to-peak value) and the number of peaks per cm. Preferably, optical inspection (5001) of the appearance of the surface of the strip (2) and the variation measurement of the surface condition (5002) of the Strip (2). include learning suspect zones with reference to a library of images and/or data enabling a distinction to be made between over-pickling defects, under-pickling defects, or the absence of defects. This invention also relates to a continuous line apparatus for pickling a hot-rolled metal strip running continuously in said apparatus, said apparatus including:
- a fragmentation system for oxides formed on the surface of the
strip, said oxide fragmentation system being adjustable by means
of fragmentation adjustment parameters,'

- a pickling system, which is adjustable using pickling adjustment parameters, and
- a rinsing system, which is adjustable using rinsing adjustment parameters,
- a drying system, and
- a set of means for measuring and calculating the adjustment parameters of said apparatus,
- a set of actuators, intended to act on the adjustment parameters of said apparatus.
According to the invention, the continuous pickling line apparatus also includes:
a centralized command system to optimize pickling of the metal strip, said command system including:
* a preparation module intended to receive information from all of the measurement and calculation means and the actuators, and to define and send pre-adjustment instructions to all of the actuators,
* a command module intended to receive information from all -of. the measurement and calculation means and the actuators, and to define and send optimized command instructions to all of the actuators, and
- a strip inspection system arranged at the output of the rinsing
system, said inspection system being able to define and send an
alarm instruction to the command module to act on the strip
running speed V.
Advantageously, the inspection system is also able to define and
send a command instruction to the command module to act on the
rinsing adjustment parameters.
Advantageously, the set of measurement and calculation means
includes:
- a set of measurement means including means for measuring the
strip running speed V, means for measuring the adjustment

parameters for oxide fragmentation, means for measuring at least some of the adjustment parameters for pickling, and means for measuring the adjustment parameters for rinsing, and - means for calculating at least some of the adjustment parameters for pickling.
Advantageously, the calculation means are able to determine the concentrations of acid and ferrous ions in the pickling solution used in the pickling system.
Advantageously, the set of actuators includes fragmentation actuators intended to act on the oxide fragmentation adjustment parameters, pickling actuators intended to act on the pickling adjustment parameters, and rinsing actuators intended to act on the rinsing adjustment parameters.
The pickling apparatus according to the invention enables the method according to the invention to be implemented. Thus, if the method according to the invention is implemented in the apparatus according to the invention, the preparation phase of the method according to the invention is performed by the preparation module, which establishes, using the analytical model of the pre-adjustment instructions for the different actuators of the apparatus according to the invention, on the basis of the status data generated for the. different actuators, operating data concerning the strip being pickled, and target values for the adjustment parameters.
In this invention, target values means the optimum values of the adjustment parameters that' the global control process is intended to achieve.
Some of the pickling adjustment parameters are calculated using calculation means in the pickling apparatus according to the invention. These means may advantageously make it possible to determine, on the basis of density and conductivity measurements

of the pickling solution in the storage tanks, the acid and iron concentrations of the pickling solution in these storage tanks. Some of the pickling adjustment parameters are measured, during pickling, by the set of different measurement means placed on the pickling line.
The command phase is performed by the command module which, on the basis of status data from the actuators, information from the measurement and calculation means, and input data from the predictive control system established during the preparation phase, establishes command instructions that it sends to the different actuators on the pickling line, from which it receives status data in response, which are corrected on each iteration of the global control process.
The inspection phase of the surface of the strip is performed by ' the surface inspection system of the apparatus according to the invention, which is independent of the centralized command system. This surface inspection system may advantageously include:
- a system for inspecting the appearance of the surface of the strip, and which in particular makes it possible to determine the presence of marks on the surface of the strip, as well as their color, location and size, and
- a system for measuring surface condition, which makes it possible in particular to measure variation in at least one characteristic of the surface condition of the strip such as mean roughness Ra, maximum roughness Rm or number of peaks per cm. According to one particularly advantageous embodiment of the present invention in the case of under-pickling, if only one of the surface appearance inspection system and the surface condition measurement system detects a defect and sends an alarm instruction to the command module which sends it* to the operator, which only acts on the strip running speed V if the other of the
4

surface condition measurement system and the surface appearance inspection system also detects said defect.
The strip surface appearance inspection system, useable in the apparatus according to the invention, may principally comprise:
- a system for lighting the running strip such as the one described in French patent application FR 2892191,
- an image capture system, for example made up of a CCD camera such as the one described in French patent application FR 2893519, and
- an image processing function (FTI) to eliminate disturbances such" as uneven lighting or light reflections,
- a grey-threshold or contour detection function (FD),
- a photometric and morphological characterization and extraction function for suspect zones (FE),
- a learning-based identification and classification function (FCI) for suspect zones with reference to an image library, capable of distinguishing "under pickling" defects, "over pickling" defects, previously described intrinsic defects in the steel strip, or the absence of any defects.
The surface appearance inspection system of the apparatus according to the invention makes it possible to detect pickling defects in the surface of the strip, such as over-pickling or under-pickling, or marks that remain after rinsing. The lighting system of the surface appearance inspection system may advantageously.include a strip light capable of lighting the entire width of the strip within at least one band of the visible spectrum and a color CCD camera capturing the light reflected by the strip.
The processing function (FTI) of this surface condition inspection system is used to eliminate disturbances such as uneven lighting or. light reflections, from grey-threshold or

contour detection functions and photometric and morphological characterization and extraction functions for suspect zones. Finally the learning-based identification and classification function of suspect zones with reference to an image library of this system is used to identify "under pickling" defects, "over pickling" defects, intrinsic defects in the steel strip, or the absence of any defects.
The strip surface appearance inspection system according to the invention makes it possible to continuously examine the entire width of the running strip. The system described in international patent application WO2006/134259 can be used as the surface appearance inspection system.
Furthermore, the surface condition measurement system useable in the apparatus according to the invention may principally comprise an optical device, which is provided with the following functions:
- a signal processing function (FTS) making it possible to detect variations in at least one profile characteristic (case 1), scatters characteristic (case 2) or reflected light spectrum characteristic (case 3) in suspect zones,
- a learning-based suspect-zone classification function (FC) with reference to a database, that is able to distinguish between defects and an absence of defects.
This surface condition measurement system makes it possible to continuously examine at least one line situated in the middle of the width of the running strip, and preferably three lines, one of which being situated in the middle of the strip width and the other two in a zone situated between one third and one quarter of the strip width from each edge of the pickled strip. The optical system recommended for use in the strip surface condition measurement system according to the invention is a linear or spot laser triangulation scanner, using either profile

measurement (case 1) or scatter (case 2), or, alternatively, an axial chromatic aberration optical device (case 3). If a. profile-measurement laser triangulation scanner device is used, it evaluates the surface condition of the pickled strip by measuring the profile of the illuminated surface by laser beam. The beam of the laser scanner device may be a line (known as a linear laser scanner) or a spot (known as a spot laser scanner). If a scatter-based laser triangulation scanner device is used, it evaluates the surface condition of the pickled strip by-emitting . at least two beams at different angles of incidence, the surface condition of the pickled strip is then evaluated by detecting the difference in the beam diffraction caused by the illuminated surface.
If an optical axial chromatic aberration system is used, it evaluates the surface condition of the pickled strip by spectral analysis of the light focused on the surface lit with white light by the optical device.
The optical device of the surface condition measurement system according to the invention is advantageously fixed above the center of the pickled strip.
According to a first particularly advantageous embodiment of the invention, two axial chromatic aberration optical, scatter laser or laser scanner systems are used, which are preferably located above the running strip, at a distance from its edges of between one third and one quarter of the width of the strip. According to a second also particularly advantageous embodiment of the invention, two laser scanners are used, which are fixed above the pickled strip at a distance from its edges of between one quarter and one third of its width and that are connected to another device of the same type, which is attached to it above the center of the strip.

Finally, the apparatus control system is advantageously, also able to send data to a general control system controlling management of the strip processing installations downstream and/or upstream of said pickling apparatus.
Other advantageous characteristics of the invention are detailed in the following description of certain embodiments given as examples and shown on the attached drawings:
- Figure 1 is a schematic drawing of a first example of the continuous pickling line apparatus known in the prior art,
- Figure 2 is a schematic drawing of an example of an oxide fragmentation system known in the prior art and intended for use in a continuous pickling line apparatus,
- Figure 3 is a schematic drawing of an example of a pickling system known in the prior art and intended for use in a continuous pickling line apparatus,
- Figure 4 is a schematic drawing of an example of a rinsing unit 15 known in the prior art and intended for use in a continuous pickling 'line apparatus,
- Figure 5 is a schematic drawing of an example of the continuous pickling line apparatus according to the invention,
- Figure 6 is a diagram showing the different phases of the global control process of the method according to the invention. Identical elements shown in Figures 1 to 6 are identified by identical numerical references.
The continuous pickling line apparatus 1 shown in Figure 1 has
previously been described in the reference to the prior art
above.
Furthermore, the fragmentation system 12 shown in Figure 2, the
pickling system 12 shown in Figure 3, as well as the rinsing unit
15 shown in Figure 4 have also been described previously in the
reference to the prior art above.

The pickling installation according to the invention shown in Figure 5 in particular includes:
- a fragmentation system 11 for the oxide that has formed on the surface of the steel strip 2 during hot rolling,
- a pickling system 12 for the acid corrosion of the oxides, and
- a rinsing unit 15 to remove the acid (and in particular hydrochloric acid) and iron chlorides present on the surface of the strip.
The fragmentation system 11, the pickling system 12 and the rinsing unit 15 are arranged in series in the pickling apparatus
1 according to the invention such that the strip 2 being pickled
passes in turn, as it moves continuously through the pickling
apparatus 1, the fragmentation system 11, then the pickling
system 12 and the rinsing unit 15.
The fragmentation system 11 useable in the apparatus according to the invention may in particular be the one shown in Figure 2, which comprises notably:
- actuators 45111, 451112 controlling overlapping 1112 of the
work rolls 111 via the height difference 1111 between the lowest
work roll(s) and the highest work roll(s) between which the strip
2 is leveled, and
- an actuator 451113 controlling the traction 451113 exercised between the input tensioners 113 and the output tensioners 114. The pickling system 12 recommended for use in the apparatus 1 according to the invention shown in Figure 5 is the one shown in Figure 3, to which is added:
- an acid top-up system 135 at the last storage tank 134 encountered in the running direction 3 of the strip 2, and
- a set of means for measuring the pickling adjustment parameters 431212, 431222, 431232, 431242, 431313, 431323, 431333, 431343, 431314, 431324, 431334, 431344 and

- a set of actuators 451311, 451311a, 451311b, 431321, 451321a,
451321b, 451331, 451331a, 451331b, 431341, 451341a, 451341b
acting on said pickling adjustment parameters.
The measurement means 431212, 431222, 431232, 431242, 431313, 431333, 431343, 431314, 431324, 431334, 431344 of the pickling adjustment parameters include:
- means for measuring the temperature 431212, 431222, 431232,
431242 of the pickling solution 1211, 1221, 1231, 1241 contained
in the different pickling tanks 121, 122, 123, 124,
- means for measuring the density 431313, 431323, 431333, 431343
of the pickling solution 1211, 1221, 1231, 1241 in said storage
tanks 131, 132, 133, 134, and
- means for measuring the conductivity 431314, 431324, 431334,
431344 of the pickling solution 1211, 1221, 1231, 1241 in said
storage tanks 131, 132, 133, 134.
In the pickling apparatus 1 according to the invention, the actuators 451311, 451311a, 451311b, 451321, 451321a, 451321b, 451331, 451331a, 451331b, 451341, 451341a, 451341b able to act on the pickling adjustment parameters include pumping and reheating units 451311, 451321, 451331, 451341 that are each connected to a pickling tank 121, 122, 123, 124 and that each include:
- a heat exchanger 451311a, 451321a, 451331a, 451341a to control the temperature of the pickling solution 1211, 1221, 1231, 1241 in the recirculation circuit 132 of the pickling system 12, and
- a pump 451311a, 451321b,.451331b, 451341b to control the flow of pickling solution 1211, 1221, 1231, 1241 in the recirculation circuit 13 of the pickling system 12, and
- a pump 451351 to control the flow of extra acid 135 in the last storage tank 134 encountered in the running direction 3 of the strip 2.

The rinsing system useable in the apparatus according to the invention shown in Figure 4 may be the one shown in Figure 4, which comprises:
- a plurality of spray bars 151, 152, 153, 154, 155 supplied with demineralized water for rinsing, which are arranged such that they can spray both faces 21, 22 of the strip 2 with water,
- a plurality of flow tanks 1511, 1521, 1531, 1541, 1551, each of which is arranged beneath the spray bars 151, 152, 153, 154, 155, the water overflowing into its neighboring, tank forming a cascade flowing in the direction opposite to the running direction 3 of the strip 2,
- roller drier devices 1501, 1502 placed at the entrance and exit of the rinsing unit 15, as well as roller drier devices 1512, 1523, 1534, 1545 placed between each battery of bars 151, 152, 153, 154, 155.
The rinsing system 15 shown in Figure 5 also includes (compared to the rinsing system 15 in the prior art shown in Figure 4):
- a main demineralized-water top-up system 1504 to supply rinsing water to the spray bars 151, 152, 153, 154, 155 of the rinsing unit,
- two supplementary demineralized-water top-up devices 1534, 1544 to supply, as required, the third 153 and fourth 154 spray bars encountered in the running direction 3 of the strip 2,
- acid injection devices 1515, 1525, 1535 in the first flow tanks 1511, 1521, 1531 of the rinsing unit 15 encountered in the . running direction 3 of the strip 2, and
- alkaline-product injection devices 1536, 1546 in the third 1531 and fourth 1541 flow tanks of the rinsing unit 15 encountered in the running direction 3 of the strip 2.
Furthermore, the rinsing system 15 of the apparatus shown in Figure 5 includes measurement means 431512, 431522, 431532, 431542, 431552, 431553, 431554 of the rinsing adjustment

parameters and actuators 4515151, 4515251, 4515351, 4515361, 4515461, 4515341, 4515441, 4515041, 4515042 able to act on these rinsing adjustment parameters.
The measurement means 431512, 431522, 431532, 431542, 431552, 431553, 431554.of the rinsing adjustment parameters enabling the activation of the rinsing device 15 include:
- pH measurement means 431512, 431522, 431532, 431542, 431552 for the rinsing water in the flow tanks 1511, 1521, 1531, 1541, 1551 of the rinsing units 15,
- conductivity measurement means 431553 for the rinsing water contained in the last flow tank 1551 encountered in the running direction 3 of the strip 2,
- temperature measurement means 431554 for the rinsing water contained in the last flow tank 1551 encountered in the running direction 3 of the strip 2.'
The actuators 4515151, 4515251, 4515351, 4515361, 4515461, 4515341, 4515441, 4515041, 4515042 able to act on the rinsing parameters include:
- pumps 4515151, 4515251, 4515351 to control the flow of acid from said acid-injection devices 1515, 1525, 1535,
- pumps 4515361, 4515461 to control the flow of alkaline product from the alkaline-product-injection devices 1536, 1546,
- pumps 4515341, 4515441 to control the flow of demineralized water from the supplementary demineralized-water top-up devices 1534, 1544,
- a pump 4515041 to control the flow of demineralized water from the main demineralized-water top-up device 1504,
- a heat exchanger 4515042 to control the temperature of the demineralized water from the main demineralized-water top-up device 1504.

The apparatus 1 according to the invention also includes, at the output of rinsing and drying an inspection system 5 of the strip 2 that breaks down as follows:
- a surface appearance inspection system 51, and
- a surface condition measurement system 52'.
The surface appearance inspection system 5 of the strip 2 includes advantageously:
- a lighting device 511 for the running strip 2, which is attached to
- an image capture device. 512,
- an image processing function 513.
- a grey-threshold or contour detection function 514,
- a photometric and morphological characterization and extraction function 515 for suspect zones, and
- an identification and classification function 516 for suspect zones with reference to an image library, this function 516 making it possible to distinguish between "under pickling" defects, "over pickling" defects or even intrinsic defects in the steel strip 2, and the absence of any defects.
The surface condition measurement system 52 includes advantageously:
- an optical device 521 for the continuous examination of at least one line of the running strip 2,
- a signal processing function 522, and
- a learning-based classification function 523 with reference to a database, for suspect zones, this function 523 making it possible to distinguish between defects and an absence of defects.
The surface condition measurement system 52 makes it possible to continuously examine at least one line situated in the middle of the width of the running strip 2; and preferably three lines where one is situated in the middle of the strip width and the

two others in a zone situated between one third and one quarter of the strip width from each edge of the pickled strip. All of the measurement means 43 of the apparatus 1 and all of the actuators 45 of the apparatus 1 are controlled by a centralized control system 4, which enables the control of pickling by means of a global process that includes:
the continuous measurement 43101, 43102 of at least some of the pickling adjustment parameters, said measurement being implemented during pickling;
the continuous calculation 43200 of at least some of the pickling adjustment parameters, said calculation being implemented during pickling;
a prior preparation phase 4101, 4102 which is implemented upstream or at the start of pickling, during which the global control process'4000 defines 4101 and sends 4102 pre-adjustment instructions 411 to all of the actuators 45 using an analytical model, which may be associated with a predictive control system
a command phase 4201, 4202 which is implemented' during pickling, during which the global control process 4000 defines 4201 and sends 4202 optimized command instructions to all of the actuators using a predictive control system; and
the continuous inspection 5001, 5002 of the surface of the strip 2, which results in the definition 5001 and sending 5002, in the case of under-pickling, of an alarm instruction (500) to the command phase 4201, 4202, which reduces the running speed V
of the strip 2 stepwise to a corrected running speed Vcor, the stepwise reduction in the running speed V being effected until the condition of the strip 2 is deemed to be satisfactory during the inspection 5001, 5002 of the surface of the strip 2. The preparation module 41 performs the preparation phase 4101, 41.02 of the method according to this invention, which includes 'advantageously the following operations:

- receiving status data 450 from 4501 the actuators 45, operating data .413, and target values 412 for the adjustment parameters established by the analytical model to optimize pickling of the strip 2;
- establishing 4101 pre-adjustment.instructions 411 for each actuator 45;
- sending 4102 pre-adjustment instructions 421 to each actuator 45;
- establishing 410.3 the input data 414 for the command phase 4201, 4202;
- sending 4104 said input data 414 to the command phase 4401.
A calculation module performs the calculation phase 43200 for the different concentrations of acid 4321 and iron 4322 in the pickling solution 1211, 1221, 1231, 1241 flowing in the pickling system 12.
The command module 42 performs the command phase 4401, 4402, which includes the following operations:
- receiving continuously and in real time status data 450 from 4502 the actuators 45, information from 4300 the measurement and calculation means 43, and input data 414 for the command phase 4201, 4202 established during the preparation phase 4101, 4102;
- establishing 4201 command signals 425 optimized for each actuator 45;
sending 4202 said command signals 421 to the actuators 45. The surface inspection system 5 performs the surface inspection phase of the strip 2 at the output of the pickling apparatus, by optical inspection 5001 of the appearance of the surface of the strip 2 firstly, and by measuring the variations in the condition of the surface of the strip 2.

CLAIMS
1. A pickling method for a metal strip (2) running through a pickling line apparatus (1), which includes successively a fragmentation stage for oxides formed on the surface of said strip (2) during hot rolling, an acid pickling stage, a rinsing stage for the strip (2), and a drying stage, the strip (2) being driven at a running speed V in said apparatus (1) in a longitudinal running direction perpendicular to the width of the strip (2), the running speed V of the strip (2) .being controlied by an uncoiling (21) and coiling (30) unit, and each of the stages of pickling being controlled by actuators (45') that can act on the adjustment parameters of the pickling line (1), the action or absence of action of an actuator (45) on a given adjustment parameter being identified by a status datum (450) .
said method including a global control process (4000) for pickling, which implements:
- the continuous measurement (43101, 43102)'of at least some of the pickling adjustment parameters, said measurement being implemented during pickling;
- a command phase (4201, 4202) which is implemented during pickling, during which the global control process (4000) defines (4201) and sends (4202) optimized command instructions (425) to all of the actuators (45) using a predictive control system; and
- the continuous inspection (5001, 5002) of the surface of the strip (2);
said method being characterized in that the global control process (4000) includes:
- a prior preparation phase (4101, 4102) which is
implemented upstream or at the start of pickling, during
which the global control process (4000) defines (4101) and
sends (4102) pre-adjustment instructions (411) to all of
the actuators (45) using an analytical model, which may be associated with the predictive control system;
- the continuous calculation (43200) of at least some of
the pickling adjustment parameters, said calculation being
implemented during pickling;
and also characterized in that the continuous inspection (5001, 5002) of the surface of the strip (2) defines (5001) and sends (5002), in the event of under-pickling, an alarm instruction (500) to the command phase (4201, 4202), which reduces stepwise (5001) the running speed' V of the strip (2) to a corrected running speed (Vcor)',. the stepwise reduction of the running speed V being effected until the defect is no longer detected and no longer triggers the alarm instruction (500), characterized in that the continuous inspection (5001, 5002) of the surface of the strip (2) also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until the defect is no longer detected.
2. The method as claimed in claim 1, characterized in that said predictive model of the global control process (4000) corrects the command instructions (425) sent to all of the actuators (45) apart from the running speed V of the strip (2), as a function of the correction made to the running speed Vcor, and such as to. maintain the quality of the evaluation made during inspection (5001, 5002) of the surface of the strip (2).
3. The method as claimed in any one of the preceding claims, characterized in that the inspection (5001, 5002) of the strip (2) includes:
- optical inspection (5001) of the appearance of the
surface of the strip (2)
- measurement of the variation of at least one
characteristic of the surface condition (5002) of the
strip (2).
4. The method as claimed in any one of the preceding claims, characterized in that optical inspection (5001) of the appearance of the surface of the strip (2) and the variation measurement of the surface condition (5002) of the strip (2) include learning suspect zones with reference to a library of images and/or data enabling a distinction to be made between over-pickling defects, under-pickling defects, or the absence of defects. .
5. The method as claimed in any one of the preceding claims, characterized in that the calculation (43200) defines the acid and iron concentrations in the pickling solution (1211, 1221, 1241) used during acid pickling.
6. The method as claimed in any one of the preceding claims, characterized in that the preparation phase (4101, 4102) includes the following operations

- receiving status data (450) from (4501) the actuators (45), operating data (413), and target values (412) for the adjustment parameters established by the analytical model to optimize pickling of the strip (2)
- Establishing (4101) pre-adjustment instructions (411) for each actuator (45)

- sending (4102) said pre-adjustment instructions (421) to each actuator (45)
- establishing (4103) input data (414) for the command phase (4201, 4202)
- sending (4104) said input data (414) to the command phase (4401).
7. The method as claimed in claim 6, characterized in that the analytical model includes an analytical sub-model associated with each actuator (45) to define said pre-adjustment instruction (411) for the adjustment parameter on which the related actuator (45) acts.
8. The method as claimed in any one of the preceding claims, characterized in that the command phase (4201, 4202) includes the following operations

- receiving 'continuously and in real time status data (450) from (45-92) the actuators (45), information from (4300) the measurement and calculation means (43), and input data (414) for the command phase (4201, 4202) established during the preparation phase (4101, 4102);
- establishing (4201) command signals (425) optimized for each actuator (45)
- sending (4202) said command signals (421) to the actuators (45) .
9. The method as claimed in claim 8, characterized in that the
predictive control system includes a primary adjustment loop to
check the optimum operation of each actuator (45) on the
command instruction (425) sent to it.
10. A continuous line apparatus (1) for pickling a hot-rolled
•metal strip (2) running continuously'in said apparatus (1),
said apparatus (1) including:
- a fragmentation system (11) for oxides formed on the
surface of the strip (2), said oxide fragmentation system
(11)- be-ing adjustable by means of fragmentation adjustment
parameters (1111, 1112, 1113),
- a pickling system (12), which is adjustable using
pickling adjustment parameters, and
- a rinsing system (15), which is adjustable using.rinsing adjustment parameters,
- a set of means for measuring and calculating (43) the adjustment parameters of said.apparatus (1),
- a set of actuators (45), intended to act on the adjustment parameters of said apparatus (1)'.
said apparatus being characterized in that it also includes
- a centralized command system (4) to optimize pickling of the
metal strip (2), said command system (4) including:
* a preparation module, (41') intended to receive (4100)
information from all of the measurement and calculation
means (43) and the actuators (45), and to define (4101)
and send (4102) pre-adjustment instructions (411) to all
of the actuators (45),
* a command module (42) intended to receive (4200)
information from all of the measurement and calculation
means (43) and the actuators (45), and to define (4201)
and send (4202) optimized command instructions (421) to
all of the actuators' (45), and '
- an inspection system (5, 51, 52) for the strip (2) arranged
at the output of the rinsing system (15), said inspection
system (5) being able to define (5001) and send (5002) an alarm
instruction (500) to the command module (42) to act on the
running speed V of the strip (2),
characterized in that the inspection (5001, 5002) of said continuous inspection system of the surface of the strip (2) also results in the event of detection of defective rinsing, in a stepwise pH adjustment of the rinsing water, until-the defect is no longer detected.
11. The apparatus (1) as claimed in claim 10, characterized in that said inspection system (55, .51, 52) is also able to define (5001) and send (5002) a command instruction (500) to the
command module (42) to act on the rinsing adjustment parameters.
12. The apparatus (1) as claimed in claim 10 or 11,
characterized in that the set of measurement and calculation
means' (43) -includes:
- a set of measurement means (431) including measurement.
means (4312) for the running speed V of the strip (2),
measurement means for the oxide fragmentation adjustment
parameters (431111, 431112, 431113), measurement means for at
least some of the pickling adjustment parameters (431212,
. 431222, 431232, 431242, 431313, 431323, 431333, 431343, 431314, 431324, 431334, 341344), and measurement means for the rinsing adjustment parameters (431512, 431522, 431532, 431542, 431553, 431554)), and
- calculation means (432) for at least some of the
pickling adjustment parameters.
13. The apparatus (1) as claimed in any one of claims 10'to 12, characterized in that the set of actuators (45) includes fragmentation actuators (451111, 451112, 451113) intended to act on the oxide fragmentation adjustment parameters (1111, 1112, 1113), pickling actuators (451311, 451311a, 451311b 451321, 451321a, 451321b, 451331, 451331a, 451331b, 451341, 451341a, 451341b) intended to act on the pickling adjustment . parameters, and rinsing actuators (4515151, 4515251, 4515351, 4515361, 4-515461, 4515341, 4515441, 4515041, 4515042) intended to act on-the rinsing adjustment parameters.
14. The apparatus (1) as claimed in any one of claims 10 to 13, characterized in that- the calculation means are able to
.determine the acid and ferrous-ion concentrations in the pickling solution (1211, 1221, 1241) used in the pickling system (12).
15. The apparatus (1) as claimed in any one of claims 10 to 14,
characterized in that:
- the rinsing unit (15) includes a plurality of spray bars (151, 152, 153, 154, 155) supplied with demineralized water for rinsing and arranged such that they can spray water onto the strip (2), and a plurality of flow tanks (1511, 1521, 1531, 1541, 1551), which are each arranged underneath said spray bars (151, 152, 153, 154, 155), and
- the' measurement means for the rinsing adjustment paramete-rs (431512, 431522, 431532, 431542, 431553, 431554) include pH measurement'means .(431512, 431522, 431532, 431542, 431552) for the rinsing water in the flow tanks (1511, 1521, 1531, 1541, 1551) of the rinsing unit (15) , conductivity measurement means (431553), and temperature measurement means
(431554) for the rinsing water contained in the last flow tank (1551) encountered in the running direction (3) of the strip
(2) .
16. The apparatus (1) as claimed in claim 15, characterized in
that:
- the rinsing unit (15) includes a main demineralized-
water top-up device (1504) to. supply the spray bars (151, 152,
153, 154, 155) of the rinsing unit (15), supplementary
demineralized-water top-up devices (1534, 1544) to supply the
third (153) and fourth (154) spray bars encountered in the
running direction (3) of the strip (2), acid injection devices
(1515, 1525, 1535) in the first flow tanks (1511, 1521, 1531)
of the rinsing unit (15) encountered in the running direction
(3) of the strip (2), and alkaline-product injection devices
(1536, 1546) in the third (1531) and fourth (1541) flow tanks
of the rinsing unit (15) encountered in the running direction
(3) of the strip (2), and
- the actuators (4515151, 4515251, 4515351, 4515361,
4515461, 4515341, 4515441, 4515041, 4515042) able to act on the
rinsing parameters include a pump (4515041) to control the flow
of demineralized water from the main demineralized-water top-up
device (1504), a heat exchanger (4515042) to control the
• temperature of the demineralized water from the main demineralized-water top-up device (1504), and pumps (4515341, 4515441) to control the flow of demineralized water from the supplementary demineralized-water top-up devices (1534, 1544), pumps (4515151, 4515251, 4515351) to control the- flow of acid from sai-d acid injection" devices (1515, 1525, 1535) , and pumps (4515361, 451.5461) to control the flow of alkaline-product from said alkaline-product injection devices (1536; 1546).
17. The apparatus (1) as claimed in any one of claims 10 to 16,
characterized in that the surface inspection system (5) of the
strip (2) includes:
- a surface appearance inspection system (51) for the strip (2), and '
- a surface condition measurement system (52) for the strip (2).
18. The apparatus (1) as claimed in any one of claims 10 to 17,
characterized in that in the event of under-pickling, only one
of the surface appearance inspection system (51) and the
surface condition measurement system (52) detects a defect and
• sends (5002)- an alarm instruction (500) to the command module. (42) which sends it to the operator, .which only acts on the . running speed V of the strip (2) if the other of the surface condition measurement system (52) and the surface appearance inspection system (51) also detects said defect.
19. The apparatus (1) as claimed in claim 17 or 18,
characterized in that the surface appearance inspection system
(51) includes:
- a lighting device (511) for the running strip (2), which is attached to
- an image capture device- (512)
-an image processing function (513),
- a grey-threshold or contour detection function (514),
- a photometric and morphological characterization and extraction function (515) for suspect zones, and
- a—suspect-zone identification and classification function (51.6) .
20. The apparatus (1) as claimed in claim 17 or 18,
characterized in that the surface condition measurement system
(52) is able to measure variations in at least one
characteristic of the surface condition of the strip (2).
21. The apparatus (1) as claimed in claim 20, characterized in that the surface condition measurement system (52) includes
- at least one optical•device (521) for the continuous examination of at least one line of the strip (2),
- a signal processing function (522), and
- a suspect-zone classification function (523).
22. The apparatus (1) as claimed in claim 21, characterized in that the optical device (521) is a laser scanner device, a scatter laser device or an optical axial chromatic aberration device.
The apparatus (1) as claimed in claim 21 or 22, characterized in that the surface condition measurement system (52) includes two optical devices. (521) , that are located above the running strip, at a distance from its edges of between one quarter and one third of the width of the strip.
23 The apparatus (1) as claimed in claim 21 or 22,
characterized in that the surface condition measurement system (52) includes two optical devices (521), that are fixed above the pickled strip, at a distance from its edges of between one quarter and one third of its width and that are connected to another device of the same type, which is fixed above the center of the strip.
24. The apparatus (1) as claimed in any 'one of claims 10 to 24, characterized in that the control system (4) of the apparatus (1) is able to send data to a general control system controlling management of the processing installation for the strip (2) downstream and/or upstream of said pickling apparatus (1)

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Patent Number

278320

Indian Patent Application Number

4442/DELNP/2010

PG Journal Number

53/2016

Publication Date

23-Dec-2016

Grant Date

20-Dec-2016

Date of Filing

21-Jun-2010

Name of Patentee

PRIMETALS TECHNOLOGIES FRANCE SAS

Applicant Address

51, RUE SIBERT, F-42403 SAINT-CHAMOND

Inventors:

#	Inventor's Name	Inventor's Address
1	JEAN-FRANCOIS CLAVEL	46, RUE LOUIS MARCHAND, F-42800 GENILAC, FRANCE
2	SANDRA CROWTHER	42, RUE DE LA BANNIERE, F-69003 LYON, FRANCE
3	PHILIPPE BARBIERI	18, RUE DUNOIR, F-69003 LYON, FRANCE
4	JACQUES LEROYER	12, MONTEE BEAUMUR, F-38200 VIENNE, FRANCE

PCT International Classification Number

C23G 1/02

PCT International Application Number

PCT/FR2008/001655

PCT International Filing date

2008-11-28

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	0760222	2007-12-21	France