Title of Invention	ANTI-BLOCKING COMPOSITIONS COMPRISING INTERPOLYMERS OF ETHYLENE/ALPHA-OLEFINS
Abstract	Anti-blocking polymer compositions comprise at least one ethylene/α-olefin interpolymer and at least one anti-blocking agent comprising an amide. The ethylene/α-olefin interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block. The anti-blocking agent can be erucamide or other amides. The antiblocking polymer composition has a pellet blocking strength of equal to or less than 100 lbs/ft2 (4800 Pa). When the anti-blocking polymer composition is made into a film, the film has a blocking force of less than about 100 grams, measured according to ASTM method D-3354.

Title of Invention

ANTI-BLOCKING COMPOSITIONS COMPRISING INTERPOLYMERS OF ETHYLENE/ALPHA-OLEFINS

Abstract

Anti-blocking polymer compositions comprise at least one ethylene/α-olefin interpolymer and at least one anti-blocking agent comprising an amide. The ethylene/α-olefin interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block. The anti-blocking agent can be erucamide or other amides. The antiblocking polymer composition has a pellet blocking strength of equal to or less than 100 lbs/ft2 (4800 Pa). When the anti-blocking polymer composition is made into a film, the film has a blocking force of less than about 100 grams, measured according to ASTM method D-3354.

Full Text	ABSTRACT OF THE DISCLOSURE Anti-blocking polymer compositions comprise at least one ethylene/a-olefin interpolymer and at least one anti-blocking agent comprising an amide. The ethylene/a-olefin interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block. The anti-blocking agent can be erucamide or other amides. The antiblocking polymer composition has a pellet blocking strength of equal to or less than 100 lbs/ft2 (4800 Pa). When the anti-blocking polymer composition is made into a film, the film has a blocking force of less than about 100 grams, measured according to ASTM method D-3354. CLAIMS What is claimed is: 1. A polymer composition comprising: (i) at least one ethylene/α-olefin interpolymer, wherein the ethylene/α-olefin interpolymer is a block interpolymer and: (a) has a MJMn from about 1.7 to about 3.5, at least one melting point, Tjn, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm ^2002.9 + 4538.5(d) - 2422.2(d)2; or (b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a heat of fusion, AH in J/g, and a delta quantity, AT, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of AT and AH have the following relationships: AT > -0.1299(AH) + 62.81 for AH greater than zero and up to 130 J/g, AT > 48 °C for AH greater than 130 J/g, wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30 °C; or (c) is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylcnc/os-olefin interpolymer is substantially free of a cross-linked phase: Re>l48M629(d);or (d) has a molecular fraction which elutes between 40 °C and 130 °C when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin interpolymer; or (e) is characterized by a storage modulus at 25 DC, GJ(25 °C), and a storage modulus at 100 °C, G'(100°C), wherein the ratio of G'(25 °C) to G(100 °C) is from about 1:1 to about 10:1; and (ii) at least one anti-blocking agent comprising an amide, wherein the amide has a melting point of at least about 70 °C. 2. The polymer composition of claim 1, wherein the ethylene/α-olefin interpolymer has a Mv/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tro ^858.91 - 1825.3(d) + 1112.8(d)2. 3. The polymer composition of claim 1, wherein the ethylene/α-olefin interpolymer has a MvMn from about 1.7 to about 3.5 and is characterized by a heat of fusion, AH in J/g, and a delta quantity, AT, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, herein the numerical values of AT and AH have the following relationships; AT > -0.1299(AH) + 62.81 for AH greater than zero and up to 130 J/g, AT > 48 °C for AH greater than 130 J/g , wherein the CRYSTAF peak is detennined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30 °C. 4. The polymer composition of claim 1, wherein the ethyiene/α-olefin interpolymer is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase: Re>1481-1629(d). 5. The polymer composition of claim 4, wherein the numerical values of Re and d satisfy the following relationship: Re>1491-1629(d). 6. The polymer composition of claim 4, wherein the numerical values of Re and d satisfy the following relationship: Re>1501-I629(d). 7. The polymer composition of claim 4, wherein the numerical values of Re and d satisfy the following relationship: Re>1511-1629(d). 8. A polymer composition comprising: (i) at least one ethylene/α-olefin interpolymer, wherein (he ethylene/α-olefin interpolymer is a block interpolymer and has: (a) at least one molecular fraction which elutes between 40 °C and 130 °C when fractionated using TREF, characterized in that the fraction has a block index of at least 0.5 and up to about 1 and a molecular weight distribution, Mw/Ma, greater than about 1.3; or (b) an average block index greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3; and (ii) at least one anti-blocking agent comprising an amide, wherein the amide has a melting point of at least about 70 °C. 9. The polymer composition of claim 1 or 8, wherein the ethylene/α-olefin interpolymer has a molecular fraction which elutes between 40 °C and 130 °C when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin interpolymer. 10. The polymer composition of claim 1 or 8, wherein the ethylene/α-olefin interpolymer is characterized by a storage modulus at 25 °C, G'(25 °C), and a storage modulus at 100 °C, G'(100 °C), wherein the ratio of G'(25 °C) to G(100 °C) is from about

Full Text

ABSTRACT OF THE DISCLOSURE
Anti-blocking polymer compositions comprise at least one ethylene/a-olefin interpolymer and at least one anti-blocking agent comprising an amide. The ethylene/a-olefin interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block. The anti-blocking agent can be erucamide or other amides. The antiblocking polymer composition has a pellet blocking strength of equal to or less than 100 lbs/ft2 (4800 Pa). When the anti-blocking polymer composition is made into a film, the film has a blocking force of less than about 100 grams, measured according to ASTM method D-3354.

CLAIMS
What is claimed is:
1. A polymer composition comprising:
(i) at least one ethylene/α-olefin interpolymer, wherein the ethylene/α-olefin interpolymer is a block interpolymer and:
(a) has a MJMn from about 1.7 to about 3.5, at least one melting point,
Tjn, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical
values of Tm and d correspond to the relationship:
Tm ^2002.9 + 4538.5(d) - 2422.2(d)2; or
(b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a
heat of fusion, AH in J/g, and a delta quantity, AT, in degrees Celsius defined as the
temperature difference between the tallest DSC peak and the tallest CRYSTAF peak,
wherein the numerical values of AT and AH have the following relationships:
AT > -0.1299(AH) + 62.81 for AH greater than zero and up to 130 J/g,
AT > 48 °C for AH greater than 130 J/g,
wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30 °C; or
(c) is characterized by an elastic recovery, Re, in percent at 300 percent
strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin
interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values
of Re and d satisfy the following relationship when the ethylcnc/os-olefin interpolymer is
substantially free of a cross-linked phase:
Re>l48M629(d);or
(d) has a molecular fraction which elutes between 40 °C and 130 °C when
fractionated using TREF, characterized in that the fraction has a molar comonomer content of
at least 5 percent higher than that of a comparable random ethylene interpolymer fraction
eluting between the same temperatures, wherein said comparable random ethylene
interpolymer has the same comonomer(s) and a melt index, density, and molar comonomer

content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin interpolymer; or
(e) is characterized by a storage modulus at 25 DC, GJ(25 °C), and a storage modulus at 100 °C, G'(100°C), wherein the ratio of G'(25 °C) to G*(100 °C) is from about 1:1 to about 10:1; and
(ii) at least one anti-blocking agent comprising an amide, wherein the amide has a melting point of at least about 70 °C.
2. The polymer composition of claim 1, wherein the ethylene/α-olefin
interpolymer has a Mv/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in
degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of
Tm and d correspond to the relationship:
Tro ^858.91 - 1825.3(d) + 1112.8(d)2.
3. The polymer composition of claim 1, wherein the ethylene/α-olefin
interpolymer has a MvMn from about 1.7 to about 3.5 and is characterized by a heat of
fusion, AH in J/g, and a delta quantity, AT, in degrees Celsius defined as the temperature
difference between the tallest DSC peak and the tallest CRYSTAF peak, herein the
numerical values of AT and AH have the following relationships;
AT > -0.1299(AH) + 62.81 for AH greater than zero and up to 130 J/g,
AT > 48 °C for AH greater than 130 J/g ,
wherein the CRYSTAF peak is detennined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30 °C.
4. The polymer composition of claim 1, wherein the ethyiene/α-olefin
interpolymer is characterized by an elastic recovery, Re, in percent at 300 percent strain and
1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase:
Re>1481-1629(d).

5. The polymer composition of claim 4, wherein the numerical values of Re and
d satisfy the following relationship:
Re>1491-1629(d).
6. The polymer composition of claim 4, wherein the numerical values of Re and
d satisfy the following relationship:
Re>1501-I629(d).
7. The polymer composition of claim 4, wherein the numerical values of Re and
d satisfy the following relationship:
Re>1511-1629(d).
8. A polymer composition comprising:
(i) at least one ethylene/α-olefin interpolymer, wherein (he ethylene/α-olefin interpolymer is a block interpolymer and has:
(a) at least one molecular fraction which elutes between 40 °C and 130 °C
when fractionated using TREF, characterized in that the fraction has a block index of at least
0.5 and up to about 1 and a molecular weight distribution, Mw/Ma, greater than about 1.3; or
(b) an average block index greater than zero and up to about 1.0 and a
molecular weight distribution, Mw/Mn, greater than about 1.3; and
(ii) at least one anti-blocking agent comprising an amide, wherein the amide has a melting point of at least about 70 °C.
9. The polymer composition of claim 1 or 8, wherein the ethylene/α-olefin
interpolymer has a molecular fraction which elutes between 40 °C and 130 °C when
fractionated using TREF, characterized in that the fraction has a molar comonomer content of
at least 5 percent higher than that of a comparable random ethylene interpolymer fraction
eluting between the same temperatures, wherein said comparable random ethylene
interpolymer has the same comonomer(s) and a melt index, density, and molar comonomer
content (based on the whole polymer) within 10 percent of that of the ethylene/α-olefin
interpolymer.
10. The polymer composition of claim 1 or 8, wherein the ethylene/α-olefin
interpolymer is characterized by a storage modulus at 25 °C, G'(25 °C), and a storage
modulus at 100 °C, G'(100 °C), wherein the ratio of G'(25 °C) to G*(100 °C) is from about

Documents:

4031-CHENP-2007 AMENDED PAGES OF SPECIFICATION 20-01-2015.pdf

4031-CHENP-2007 AMENDED CLAIMS 20-01-2015.pdf

4031-CHENP-2007 ASSIGNMENT 20-01-2015.pdf

4031-chenp-2007 form-13 02-05-2011.pdf

4031-chenp-2007 other document 02-05-2011.pdf

4031-chenp-2007 correspondence others 02-05-2011.pdf

4031-CHENP-2007 POWER OF ATTORNEY 20-01-2015.pdf

4031-CHENP-2007 CORRESPONDENCE OTHERS 16-06-2014.pdf

4031-CHENP-2007 FORM-1 20-01-2015.pdf

4031-CHENP-2007 EXAMINATION REPORT REPLY RECEIVED 20-01-2015.pdf

4031-chenp-2007(form18).pdf

4031-chenp-2007-abstract.pdf

4031-chenp-2007-claims.pdf

4031-chenp-2007-correspondnece-others.pdf

4031-chenp-2007-description(complete).pdf

4031-chenp-2007-drawings.pdf

4031-chenp-2007-form 1.pdf

4031-chenp-2007-form 3.pdf

4031-chenp-2007-form 5.pdf

4031-chenp-2007-pct.pdf

FORM 3.pdf

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Patent Number

265343

Indian Patent Application Number

4031/CHENP/2007

PG Journal Number

08/2015

Publication Date

20-Feb-2015

Grant Date

19-Feb-2015

Date of Filing

14-Sep-2007

Name of Patentee

DOW GLOBAL TECHNOLOGIES LLC

Applicant Address

2040 DOW CENTER, MIDLAND, MICHIGAN 48674,

Inventors:

#	Inventor's Name	Inventor's Address
1	HOENIG, STEPHEN, MARK	113 ARROWHEAD DRIVE, LAKE JACKSON, TX 77566
2	CHEUNG, YUNWA., W	104 ROSEMARY LANE, LAKE JACKSON, TX 77566, USA
3	MOLDOVAN, DAN	2407 COUNTRY ROAD 209, DANBURY, TX 77534, USA.

PCT International Classification Number

C08K 5/20

PCT International Application Number

PCT/US2006/009378

PCT International Filing date

2006-03-15

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	60/717,588	2005-09-16	U.S.A.
2	PCT/US05/08917	2005-03-17	U.S.A.