Title of Invention	"PROCESS TO RECOVER MEDIUM PURITY CARBON DIOXIDE"
Abstract	The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover CO<sub>2</sub> having a purity of approximately ≥80 mole% from streams containing at least CO<sub>2</sub> and H<sub>2</sub> (e.g., syngas). The feed to the CO<sub>2</sub> VPSA can be at super ambient pressure. The CO<sub>2</sub> VPSA unit produces two streams, a H<sub>2</sub>-enriched stream and a CO<sub>2</sub> product stream. The process cycle steps are selected such that there is minimal or no H<sub>2 </sub>losses from the process. The recovered CO<sub>2</sub> can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).

Title of Invention

"PROCESS TO RECOVER MEDIUM PURITY CARBON DIOXIDE"

Abstract

The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover CO2 having a purity of approximately ≥80 mole% from streams containing at least CO2 and H2 (e.g., syngas). The feed to the CO2 VPSA can be at super ambient pressure. The CO2 VPSA unit produces two streams, a H2-enriched stream and a CO2 product stream. The process cycle steps are selected such that there is minimal or no H2 losses from the process. The recovered CO2 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).

Full Text	PROCESS TO RECOVER MEDIUM PURITY CARBON DIOXIDE TECHNICAL FIELD [0001] The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover carbon dioxide (CO2) having a purity of approximately ≥80 mole% from streams containing at least C02 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2-enriched stream and a C02 product stream. The process cycle steps are selected such that there is minimal or no H2 losses from the process and without requiring additional processing equipment. The recovered C02 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR). BACKGROUND OF THE INVENTION [0002] Steam methane reforming (SMR) is the primary process to produce hydrogen (H2) in bulk quantities. After catalytic conversion of natural gas, CO and H2 is produced as follows in equation (1): (Equation Removed) The gas mixture is shifted (by a water-gas shift reaction) to further produce H2 according to equation (2) : (Equation Removed) After the water-gas shift reaction, typical product gas has a pressure of between about 100-500 psia, a temperature of between about 60-150°F, and a composition of 60-80 mole% H2, 15-25 mole% C02, 0.1-5 mole% CO, 3-7 mole% CH4, 0-5 mole% N2 and is saturated with water. This gas mixture can then be fed to a pressure swing adsorption (PSA) unit to produce high purity H2 (e.g., H2 at a purity of at least 99%). [0003] In some current H2 production plants, an amine unit is placed between the shift reactor and the H2 PSA unit to extract C02 from the stream produced by the shift reactor. This process, however, is energy intensive. In addition, amine units can be difficult to operate and are known to have operational problems, such as corrosion, loss of fluid and the like. [0004] U.S. Patent No. 4,171,206 relates to production of high purity C02 (99.99+%) and high purity H2 (99.99+%) at high C02 (99.9+%) recovery from SMR off-gas. This patent discloses two trains of adsorption beds, which are in communication with each other during the feed and re-pressurization steps. Beds in the C02 train employ a rinse step by high purity C02 at high pressure. Depressurization and evacuation of the same bed follow this step. Depressurized gas is re-compressed and used for high-pressure rinse. The effluent from the high pressure, high purity rinse step is recycled to the feed. [0005] U.S. Patent No. 4,299,596 relates to production of two products at high purity by employing two trains of beds, which are integrated during the feed and co-current depressurization steps. The train producing the more strongly adsorbed species is purged by the co-current depressurized gas after it has been recompressed. Part of the co-current depressurized gas may be recycled for re-pressurization. Evacuation and blowdown steps produce part of the more strongly adsorbed species and part of the purge gas. [0006] U.S. Patent No. 4,770,676 relates to the production of methane and C02 from landfill gas. It is an integrated thermal (TSA) and pressure swing adsorption (PSA) process. The waste produced from the PSA regenerates the TSA. [0007] U.S. Patent No. 4,840,647 relates to production of ≥95% C02 from a feed stream containing 10-30% C02 at ambient pressure. The process steps are feed, co-current evacuation, countercurrent evacuation to produce product and a repressurization step. Co-current evacuated gas is used for pressure equalizations/repressurization and mixed with the feed. [0008] U.S. Patent No. 4,857,083 considers production of CO2 from a gas mixture. At the end of the feed step, the discharge end of the feed column is connected with the inlet end of the evacuated bed to reduce the pressure in this bed. Carbon dioxide is then produced by evacuation. This is followed by pressure build up steps. [0009] U.S. Patent No. 4,913,709 relates to the production of two products at high purity. The reference suggests the use of two trains of beds, which are integrated during the feed and re-pressurization steps. The train producing the more strongly adsorbed species is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step is recompressed and recycled as feed. - 4 - [0010] U.S. Patent No. 4,915,711 discloses production of two products at high purity using a single train of beds. The bed is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step and depressurization step is recompressed and recycled as feed. [0011] U.S. Patent No. 5,026,406 discloses the production of two products at high purity by employing a single train of beds. The bed is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step and depressurization step is recompressed and recycled as feed. [0012] U.S. Patent No. 5,051,115 produces a more strongly adsorbed species from a gas mixture at high purity. A co-current purge step is employed by the high purity strongly adsorbed species. This purge stream and product are obtained during the evacuation step. Effluent from the purge step is recycled for repressurization. [0013] U.S. Patent No. 5,248,322 relates to a process with four steps: adsorption, depressurization, evacuation and pressure equalization by part of the depressurized gas and repressurization. The first part (higher pressure) of the depressurized gas is recycled whereas the second part (lower pressure) is used for pressure equalization. [0014] U.S. Patent No. 5,354,346 relates to a process with five steps: adsorption, depressurization, low pressure co-current purge, evacuation and pressure equalization by part of the depressurized and low pressure purge effluent gas and repressurization. The first part (higher pressure) of the depressurized gas is recycled whereas the second part (lower pressure) and part of the low pressure purge effluent gas is used for pressure equalization. [0015] U.S. Patent No. 6,245,127 discusses production of CO2 from a low-pressure gas mixture at constant purity. It employs simultaneous purge and evacuation steps. The countercurrent purge is carried out by the less strongly adsorbed species. [0016] It would be desirable to provide economically beneficial processes and apparatus for C02 recovery. It would further be desirable for such processes and apparatus to be more efficient and easier to use relative to the prior art. SUMMARY OF THE INVENTION [0017] The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover C02 having a purity of approximately ≥80 mole% from streams containing at least C02 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2-enriched stream and a CO2 product stream. The process cycle steps are selected such that there is minimal or no H2 losses from the process and without requiring additional processing equipment. [0018] Carbon dioxide produced in accordance with the present invention may be used for any desired purpose. For example and while not to be construed as limiting, C02 produced as described herein can be used for liquefaction to produce food-grade quality-product (s), supercritical C02 for enhanced oil recovery or simply C02 for sequestration to avoid addition of green house gases in the atmosphere to meet regulatory requirements. [0019] The present invention utilizes depressurizations of an adsorbent from high pressure to low pressure to increase C02 concentration in the bed(s). After C02 concentration is increased, C02 product is produced by further pressure reduction. This can be accomplished because of the recognition that for some adsorbents, depressurization from high to low pressure increases C02 concentration in the adsorbent bed(s). Consequently, the need for rinse, purge and/or recycle steps as used in the prior art can be eliminated. This in turn allows for the elimination of certain pieces of rotating machines (e.g., rinse compressor, purge compressor, recycle compressor) and associated power requirements, thereby providing a process and apparatus which is simpler to operate and more economical than prior art systems. The proposed processes do not require steam and thus are expected to reduce the cost of C02 separation. [0020] To increase C02 recovery and minimize or eliminate H2 losses, the present invention uses the depressurized gas to build up or increase the pressure in low-pressure beds. The bed depressurization therefore increases C02 concentration in the product and by equalizing with other beds in the unit, at the same time, increases C02 recovery and minimizes or eliminates H2 loss. [0021] Another significant feature of the process is that the final depressurized gas (step number 5 (DPf) of Figures 2, 6, or 7 or step 4 (DPf) of Figures 5, 10, 11 or 12) is not wasted. Rather, this gas stream, which is now C02 rich, can be used in either of the two ways or in combination thereof. First, the final depressurized gas stream can be mixed with CO2 produced during the evacuation step. In this embodiment, the mixed gas constitutes the C02 product. In the alternative or in addition, part or the entire final depressurized gas stream can be passed through the bed which is under evacuation. In this embodiment, the evacuated gas constitutes the C02 product. In this manner, H2 loss from C02 VPSA is expected to be minimized or entirely eliminated. [0022] Another feature of the present invention is that by reducing C02 in the feed stream to the H2 PSA unit, H2 recovery from the H2 PSA unit is expected to increase. [0023] In preferred embodiments in which the C02 VPSA apparatus is installed between a steam methane reformer (SMR)/shift reactor and a H2 PSA unit, the amount of C02 in the feed stream to the H2 PSA unit is reduced, thereby allowing for increased recovery of H2 from the H2 PSA unit. In other embodiments of the present invention, a feed stream can be provided by a partial oxidation reactor or the like. In any of these embodiments, the feed stream to the C02 VPSA unit will be a stream containing at least H2 and C02 at high pressure (for example, 100-500 psia). By eliminating the hardware (i.e. rotating machinery) as mentioned hereinabove, and corresponding power requirements, the present invention is expected to more efficiently produce C02 from syngas or other streams containing at least C02 and H2 relative to the prior art. BRIEF DESCRIPTION OF THE DRAWINGS [0024] For a more complete understanding of the present invention and the advantages thereof, reference should be made to the following Detailed Description taken in conjunction with the accompanying drawings in which: [0025] Figure 1 illustrates an embodiment in accordance with the present invention in which a CO2 VPSA unit is positioned upstream of a H2 PSA unit; [0026] Figure 2 illustrates a cycle step chart for C02 VPSA unit having six beds, three pressure equalization steps and flow through the evacuating bed in accordance with one embodiment of the present invention; [0027] Figure 3 shows a schematic drawing for CO2 VPSA unit of Figure 2; [0028] Figure 4 shows the valve sequence for operation of the C02 VPSA unit shown in Figures 2 and 3; [0029] Figure 5 illustrates an alternative cycle step chart for a C02 VPSA unit having five beds, two pressure equalization steps and flow through the evacuating bed in accordance with the present invention; [0030] Figure 6 illustrates another alternative cycle step chart for a C02 VPSA unit having seven beds, three pressure equalization steps and flow through the evacuating bed in accordance with the present invention; [0031] Figure 7 illustrates a further cycle step for a C02 VPSA unit having six beds, three pressure equalization steps and direct mixing in accordance with another embodiment of the present invention; [0032] Figure 8 shows a schematic drawing for CO2 VPSA unit of Figure 7; [0033] Figure 9 shows the valve sequence for operation of the CO2 VPSA unit shown in Figures 7 and 8; [0034] Figure 10 illustrates yet another cycle step chart for a CO2 VPSA unit having five beds, two pressure equalization steps and direct mixing according to the present invention; [0035] Figure 11 illustrates yet another cycle step chart for a CO2 VPSA unit having eight beds, two pressure equalization steps and direct mixing in which two beds are continuously on feed and at least two beds are continuously under evacuation according to the present invention; and [0036] Figure 12 illustrates a further cycle step chart for a C02 VPSA unit having eleven beds, two pressure equalization steps and direct mixing in which three beds are continuously on feed and two beds are continuously under evacuation according to the present invention. DETAILED DESCRIPTION [0037] As discussed hereinabove, the present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover CO2 having a purity of approximately ≥80 mole% from streams containing at least CO2 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2~enriched stream and a C02 product stream. [0038] Carbon dioxide produced in accordance with the present invention may be used for any desired purpose. For example and while not to be construed as limiting, C02 produced as described herein can be used for liquefaction to produce food-grade quality product(s), supercritical C02 for enhanced oil recovery or simply C02 for sequestration to avoid additional green house gases in the atmosphere in order to satisfy regulatory requirements. [0039] As discussed in more detail herein, a significant feature of the processes is that the final depressurized gas (step number 5 (DPf) of Figures 2, 6, or 7 or step 4 (DPf) of Figures 5, 10, 11 or 12) is not wasted. Rather, this gas stream (which is now C02-rich) can be used in either of two ways or in combination thereof. First, the final depressurized gas stream can be mixed with C02 produced by another bed under evacuation. In this embodiment, the mixed gas constitutes the C02 product. In the alternative or in addition, part or the entire final depressurized gas stream can be passed through the bed which is under evacuation. In this embodiment, the evacuated gas constitutes at least a part of the C02 product. In this manner, H2 loss from C02 VPSA is expected to be minimized or entirely eliminated. [0040] In a preferred embodiment of the present invention and as illustrated in Figure 1, system 10 includes C02 VPSA unit 30 positioned upstream of H2 PSA unit 28. As discussed above, natural gas 12 and steam 14 can be reformed in steam methane reformer 16 to produce stream 18, as outlined in equation (1) hereinabove. Stream 18 is then fed to shift reactor 20 to produce stream 22 as outlined in equation (2), as also set forth above. [0041] Stream 22 can be fed to C02 VPSA unit 30 via stream 24. Valve 26 will therefore typically be in the closed position and is in the open position when the C02 VPSA unit is not being used. Those skilled in the art will appreciate that valve 26 may alternatively be in the partially open position depending on the desired process capacity (i.e., C02 recovery). [0042] When the arrangement shown in Figure 1 is used with processes and apparatus in accordance with the present invention, C02-rich stream 36 (e.g. M-1 mole%) can be produced, together with H2-rich feed 32 that is expected to result in higher H2 recovery 38 from H2 PSA unit 28. Hydrogen PSA unit 28 can also produce fuel 40 for use in plant 10. [0043] The present invention recognizes that depressurizations of a C02-selective adsorbent layer increases the C02 concentration in the adsorbent bed(s). More specifically, the present invention recognizes and utilizes depressurizations of an adsorbent from high pressure (e.g., 100-500 psia) to low pressure(s) (i.e., close to ambient and/or subambient pressures) to increase C02 concentration in the bed. [0044] As used herein, a "feed stream" being fed to a CO2 unit in accordance with the present invention is a stream containing at least H2 and CO2 at a pressure between about 100-500 psia (e.g., 375 psia). After the C02 concentration is increased by multiple depressurizations, it can be used to produce the C02 product by further pressure reduction. For some adsorbents, depressurization from high to low pressure increases CO2 concentration in the adsorbent bed. This step in the process can be used to eliminate several process steps as described in the prior art. Consequently, several pieces of rotating machinery (e.g., rinse compressor, purge compressor, recycle compressor) and associated power requirements can be eliminated, thus providing a process and system that enhances operation and improves efficiency. [0045] As mentioned above, the C02 VPSA processes and apparatus of the present invention can be used to produce CO2 having a purity of about 80 mole% from a feed gas such as a syngas. In one embodiment of the present invention, the processes provide for flow through the evacuating bed (see for example, Figures 2-6). The flow through embodiments can be accomplished using a varying number of beds and pressure equalization steps. For example, flow through the evacuating bed can be accomplished with six beds and three pressure equalization steps (Figures 2-4). Alternatively, flow through the evacuating bed can be accomplished with five beds and two pressure equalization steps (Figure 5) or seven beds and three pressure equalization steps (Figure 6). At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization. In addition, a purge step can be included in the cycle for the embodiment shown in Figure 6. [0046] In other alternative embodiments of the present invention, the C02 VPSA processes and apparatus can be used to produce C02 having a purity of about 8 0 mole% from a feed gas such as a syngas by direct mixing. In such embodiments, the C02 product produced during the final depressurization step (DPf) is not passed through another bed under evacuation. Rather, this stream is mixed directly with the stream from the evacuating bed. In one preferred and exemplary embodiment, this can be accomplished with a C02 VPSA unit having six beds and three pressure equalization steps (Figures 7-9). In other embodiments, this can be accomplished by using a C02 VPSA unit having five beds and two pressure equalization steps (Figure 10). At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization. [0047] Combinations of flow through and direct mixing can also be used. In such embodiments, a portion of the stream produced during the depressurization step (DPf) flows through the bed under evacuation and the remainder is directly mixed with the stream exiting the bed under evacuation. [0048] In embodiments where increased plant capacity is desirable, the embodiments shown in Figures 11 and 12 can be utilized. More specifically, Figure 11 shows a cycle step chart for an embodiment of the present invention in which two pressure equalizations and eight beds are used with direct mixing. In this embodiment, two beds are continuously on feed and at least two beds are continuously under evacuation. This arrangement is expected to allow for an increase in the capacity of the plant. Figure 12 illustrates a cycle step chart for an embodiment of the present invention in which two pressure equalizations and eleven beds are used with direct mixing. In this embodiment, three beds are continuously on feed and two beds are continuously under evacuation. This arrangement is also expected to allow for an increase in the capacity of the plant. At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization. [0049] In any of the embodiments, each bed is preferably packed with at least two layers of adsorbents. The type and sizing of the adsorbent layer toward the feed end (i.e. a water-selective adsorbent layer) in the bed is selected to remove moisture in the feed stream such that any residual moisture does not deteriorate the performance of the main (i.e., CO2-selective) adsorbent layer. The water-selective adsorbent layer is also preferably capable of removing impurities (e.g., trace amounts of sulfur or heavy hydrocarbon compounds) from the feed stream, to the extent such impurities are present. The main, second adsorbent layer (i.e., the C02-selective adsorbent layer) is used for selectively adsorbing C02 from the feed stream after sufficient moisture has been removed. [0050] For the first adsorbent layer (i.e. the water-selective adsorbent layer), adsorbents such as activated alumina, silica gel or zeolite molecular sieve are preferred. These adsorbents are intended to be illustrative and other adsorbents capable of removing sufficient moisture are also suitable for use in accordance with the present invention. Preferred characteristics for such adsorbent(s) include: high crush strength capabilities, high attrition resistance, large bulk density, low inter-particle void, high heat capacity, large thermal conductivity, low-pressure drop and stable in liquid water. [0051] The main layer of adsorbent (i.e., the C02-selective adsorbent layer) following the water-selective adsorbent layer preferably has the following characteristics: high selectivity, high working capacity, fast kinetics and low heat of adsorption. Typical examples of such adsorbents include, but are not limited to: are NaY, HY, NaX, silica gel, and activated carbon. Other desired physical properties of the main layer adsorbent (i.e. the C02-selective layer) include: high crush strength, high attrition resistance, large bulk density, low inter-particle void, high heat capacity, large thermal conductivity and low-pressure drop during the feed and evacuation steps. [0052] Those skilled in the art will appreciate that a composite mixed layer containing both adsorbents could be used in the present invention so long as the characteristics of the adsorbents are satisfied. Referring now to Figures 2-4, a first embodiment of the present invention having six beds (A1-A6) and using ten steps with flow through the evacuating bed to produce enriched CO2 from syngas is illustrated. The process steps include: 1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least C02 and H2 gases at a high pressure between about 100-500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated. 2. Co-Current (CoC) Depressurization 1 (DPI). The C02 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow. 3. Co-Current (CoC) Depressurization 2 (DP2). The C02 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow. 4. Co-Current (CoC) Depressurization 3 (DP3). The CO2 VPSA bed, which is now at some medium pressure (e.g., 60-300 psia), is further depressurized to a lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow. 5. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (shown in Figure 2) and/or the opposite (not shown in Figure 2) the feed flow. As shown by the arrows in Figure 2 (i.e. arrows from DPf to bed under evacuation), the stream from this step (DPf) flows through the bed under evacuation (e.g. in Figure 2: bed 1 to bed 6, bed 2 to bed 1, bed 3 to bed 2, bed 4 to bed 3, bed 5 to bed 4 or bed 6 to bed 5 on the respective cycle steps). 6. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. As shown in Figure 2 and outlined in the description of step 5 (DPf) above, this bed is receiving gas from another bed in the DPf step. The gas from the bed under evacuation constitutes the C02 product stream. 7. Countercurrent (CcC) Pressure Equalization 3 (PE3). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 4 (DP3) (i.e., to about 50-200 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step increases CO2 recovery by keeping the C02 from step 4 within the VPSA system. This minimizes CO2 loss by eliminating the need to send the C02 to a waste stream. 8. Countercurrent (CcC) Pressure Equalization 2 (PE2). The bed pressure equalized in step 7 is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step increases C02 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 9. Countercurrent Pressure (CcC) Equalization 1 (PE1). The bed pressure equalized in step 8 is further pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step further increases C02 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the CO2 to a waste stream. 10. Repressurization (FeRP). The pressure- equalized bed is repressurized to a feed pressure (100- 500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. The ten-step process described is for one cycle for one bed in the C02 VPSA unit. The above ten steps for this flow through the evacuating bed embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 6) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Six adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0053] Exemplary corresponding hardware and a flow schematic of the C02 VPSA process corresponding to the cycle shown in Figure 2 is depicted in Figure 3. The various valves in Figure 3 can be operated in the manner illustrated in Figure 4 to carry out the ten steps in the six-bed process as described hereinabove. It should be appreciated that pressures and step durations shown are only for illustrative purposes. Those skilled in the art will appreciate that other combinations of pressures and step durations may be used. [0054] As can be appreciated from the above description, the present invention thus relies upon depressurizations of at least one C02-selective adsorbent from high pressure to low pressure to increase C02 concentration in the bed. After C02 concentration is increased, it produces the C02 product by further pressure reduction. This became possible based on the recognition that for some adsorbents, pressure reduction from high to low pressure increases C02 concentration on the adsorbent. [0055] In the embodiment shown in Figures 2-4 and as described, the gas produced during the final depressurization (step number 5, DPf) flows through the bed under evacuation as shown by the arrows in the cycle step chart in Figure 2. By utilizing the final depressurization gas stream (step number 5) in this manner, there is minimal or no H2 loss from the C02 VPSA unit. [0056] Alternative and additional exemplary embodiments that utilize the final depressurization gas stream (DPf) flow through the evacuating bed are illustrated in Figures 5 and 6. [0057] Referring now to Figure 5, a cycle step chart for an eight-step process that utilizes five beds and two pressure equalization steps is shown. These cycle steps are carried out in a similar manner to those steps described above with reference to Figure 2, except that steps DP3 and PE3 have been eliminated. More specifically, the cycle steps for Figure 5 include the following: 1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least CO2 and H2 gases at a high pressure between about 100-500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated. 2. Co-Current (CoC) Depressurization 1 (DPI). The CO2 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 5) or opposite (not shown in Figure 5) as the feed flow. 3. Co-Current (CoC) Depressurization 2 (DP2). The CO2 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 5) or opposite (not shown in Figure 5) as the feed flow. 4. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (shown in Figure 5) and/or the opposite (not shown in Figure 5) the feed flow. As shown by the arrows in Figure 5 (i.e. arrows from DPf to bed under evacuation), the stream from this step (DPf) flows through the bed under evacuation (e.g. as shown in Figure 5: bed 1 to bed 5, bed 2 to bed 1, bed 3 to bed 2, bed 4 to bed 3 or bed 5 to bed 4 on the respective cycle steps). 5. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 5) or opposite (shown in Figure 5) to the feed flow. As shown in Figure 5 and as outlined in the description of step 4 (DPf) above, this bed is receiving gas from another bed in the DPf step for the duration of the DPf step. The gas from the bed under evacuation constitutes the CO2 product stream. 6. Countercurrent (CcC) Pressure Equalization 2 (PE2). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 5) or opposite (shown in Figure 5) to the feed flow. This step increases CO2 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 7. Countercurrent Pressure (CcC) Equalization 1 (PE1). The bed pressure equalized in step 6 is further pressure equalized to a pressure range of the gas produced in step 1 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 5) or opposite (shown in Figure 5) to the feed flow. This step further increases C02 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the CO2 to a waste stream. 8. Repressurization (FeRP). The pressure- equalized bed is repressurized to a feed pressure (100- 500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. The eight-step process described is for one cycle for one bed in the C02 VPSA unit. The above eight steps for this flow through the evacuating bed embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 5) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Five adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0058] Referring now to Figure 6, a cycle step chart for an eleven-step process that utilizes seven beds and three pressure equalization steps is shown. These cycle steps are carried out in a similar manner to those steps described above with reference to Figure 2, except that an additional step (Rf) is included between the final depressurization step (DPf) and the evacuation step. More specifically, the cycle steps for Figure 6 include the following: 1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least C02 and H2 gases at a high pressure between about 100—500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high- pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated. 2. Co-Current (CoC) Depressurization 1 (DPI). The C02 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow. 3. Co-Current (CoC) Depressurization 2 (DP2). The C02 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow. 4. Co-Current (CoC) Depressurization 3 (DP3). The CO2 VPSA bed, which is now at some medium pressure (e.g., 60-300 psia), is further depressurized to a lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow. 5. Final Depressurization (DPf) . The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (shown in Figure 6) and/or the opposite (not shown in Figure 6) the feed flow. 6. Receive Purge (Rf). The stream produced by DPf (e.g., bed 1 in Figure 6) is fed to another bed having completed DPf, but not yet under evacuation (e.g., bed 7 in Figure 6). During this time (duration of the Rf step), the effluent (e.g., bed 7 in Figure 6) flows to tank 42 as C02 product. During the remaining time period of DPf of bed 1, the gas flows through the bed under evacuation (e.g., bed 7 in Figure 6). 7. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. As shown in Figure 6, this bed (bed 1) is receiving gas from another bed in the DPf step (bed 2). The gas from the bed under evacuation constitutes at least part of the C02 product stream. 8. Countercurrent (CcC) Pressure Equalization 3 (PE3). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 4 (DP3) (i.e., to about 50-200 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step increases C02 recovery by keeping the CO2 from step 4 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 9. Countercurrent (CcC) Pressure Equalization 2 (PE2). The bed pressure equalized in step 7 is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. This step increases C02 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 10. Countercurrent Pressure (CcC) Equalization 1 (PE1). The bed pressure equalized in step 9 is further pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. This step further increases CO2 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes CO2 loss by eliminating the need to send the C02 to a waste stream. 11. Repressurization (FeRP). The pressure-equalized bed is repressurized to a feed pressure (100-500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. The eleven-step process described is for one cycle for one bed in the C02 VPSA unit. [0059] The above eleven steps for this flow through the evacuating bed embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 7) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Seven adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0060] As mentioned above, by flowing the gas produced during the final depressurization step (DPf) through a bed under evacuation and/or prior to its going to the evacuation step, all or substantially all the H2 loss from the C02 VPSA unit can be eliminated (Figure 2-6). In other embodiments (Figures 7-12), little or no H2 loss may also be achieved by directly mixing the two streams (i.e. effluents from DPf and evacuation). Referring now to Figures 7-9, an embodiment of the present invention having six beds (A1-A6) and using ten steps with direct mixing of CO2 gas from the DPf step and the evacuation step to produce a final C02-enriched gas from syngas is illustrated. The process steps include: 1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least CO2 and H2 gases at a high pressure between about (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit(unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated. 2. Co-Current (CoC) Depressurization 1 (DPI) . The CO2 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow. 3. Co-Current (CoC) Depressurization 2 (DP2). The CO2 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow. 4. Co-Current (CoC) Depressurization 3 (DP3). The CO2 VPSA bed, which is now at some medium pressure (e.g., 60-300 psia), is further depressurized to a lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow. 5. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (not shown in Figure 7) and/or the opposite (shown in Figure 7) the feed flow to produce CO2 product 36b shown in Figure 8. This stream may constitute part of the C02 product (stream 36 in Figure 8). 6. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. The gas from the bed under evacuation (stream 36a in Figure 8) constitutes part of the C02 product stream (stream 36 in the Figures). Optionally, stream 36a can be further compressed using a blower (not shown) prior to passing to tank 42. 7. Countercurrent (CcC) Pressure Equalization 3 (PE3). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 4 (DP3) (i.e., to about 50-200 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. This step increases CO2 recovery by keeping the C02 from step 4 within the VPSA system. This minimizes C02 loss by eliminating the need to send the CO2 to a waste stream. 8. Countercurrent (CcC) Pressure Equalization 2 (PE2). The bed pressure equalized in step 7 is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. This step increases C02 recovery by keeping the C02 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 9. Countercurrent Pressure (CcC) Equalization 1 (PE1). The bed pressure equalized in step 8 is further pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. This step further increases C02 recovery by keeping the C02 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 10. Repressurization (FeRP). The pressure- equalized bed is repressurized to a feed pressure (100- 500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. As further shown in Figure 7, C02 product 3 6 is formed of C02 from streams 36b (step 6) and 36a (step 7) by product tank 42. Product 36 is expected to have a C02 purity level of approximately 80 mole% or greater. [0061] The ten-step process described is for one cycle for one bed in the C02 VPSA unit. The above ten steps for this direct mixing embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 6) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Six adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0062] Exemplary corresponding hardware and a flow schematic of the CO2 VPSA process corresponding to the cycle shown Figure 7 is depicted in Figure 8. The various valves in Figure 8 can be operated in the manner illustrated in Figure 9 to carry out the ten steps in the six-bed process as described hereinabove. [0063] It should be appreciated that pressures and step durations shown are only for illustrative purposes. Thos skilled in the art will appreciate that other combinations of pressures and steps may be used. In the embodiment shown in Figures 7-9 and as described, the gas produced during the final depressurization step (DPf) is mixed with the evacuated gas from step number 6. Consequently, there is minimal or no H2 loss from the C02 VPSA unit. [0064] Another exemplary embodiment that utilizes direct mixing of the final depressurization gas stream (DPf) with the gas produced by evacuation bed is illustrated in Figure 10. [0065] Referring now to Figure 10, a cycle step chart for an eight-step process that utilizes five beds and two pressure equalization steps is shown. These cycle steps are carried out in a similar manner to those steps described above with reference to Figure 7, except that steps DP3 and PE3have been eliminated. More specifically, the cycle steps for Figure 10 include the following: 1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least C02 and H2 gases at a high pressure between about 100-500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high- pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated. 2. Co-Current (CoC) Depressurization 1 (DPI). The C02 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 10) or opposite (not shown in Figure 10) as the feed flow. 3. Co-Current (CoC) Depressurization 2 (DP2). The C02 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 10) or opposite (not shown in Figure 10) as the feed flow. 4. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (not shown in Figure 10) and/or the opposite (shown in Figure 10) the feed flow to produce C02 product 36b. This stream may constitute part of the C02 product (stream 36). 5. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. The gas from the bed under evacuation (stream 36a in Figure 8) constitutes part of the CO2 product stream (stream 36 in the Figures). Optionally, stream 36a can be further compressed using a blower (not shown) prior to passing to tank 42. 6. Countercurrent (CcC) Pressure Equalization 2 (PE2). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. This step increases C02 recovery by keeping the C02 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 7. Countercurrent Pressure (CcC) Equalization 1 (PEl). The bed pressure equalized in step 6 is further pressure equalized to a pressure range of the gas produced in step 2 (DP1) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. This step further increases C02 recovery by keeping the C02 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream. 8. Repressurization (FeRP). The pressure-equalized bed is repressurized to a feed pressure (100-500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. Carbon dioxide product 36 is formed of C02 from streams 36b (step 4) and 36a (step 5) by product tank 42. Product 36 is expected to have a C02 purity level of approximately 80 mole% or greater. [0066] The eight-step process described is for one cycle for one bed in the C02 VPSA unit. The above eight steps for this direct mixing embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 5) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Five adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0067] It is also expected that the present invention can be modified to produce higher amounts of C02 and thus high plant capacity. For example, one may need or desire to process higher feed flow rates than may be handled by a single vacuum train or single vessel (due to fluidization or transportation limitations). In such situations, the process steps may be arranged such that at least two beds are on feed and at least two beds are under evacuation all the time. Such exemplary cycle step charts and arrangement are shown in Figures 11 and 12. Alternatively or in addition, multiple trains can be used. Example [0068] The direct mixing process cycle shown in Figure 7 was tested on a six-bed pilot unit and is expected to readily scale up. The inner diameter (ID) of the column was 2.17 inch and the packed bed height was 130 inches. The column was packed with 1.3 lb of commercially available activated alumina, 10.2 lb of commercially available 1/16" NaY pellets and the top void was filled with 3" of ceramic balls. The feed contained 2.8% CO, 15.7% C02, 6.3% CH4 and 0.2% N2 with balance being H2. The feed was at 375 psia. The process was run in a cyclic manner until it reached cyclic steady state. The final depressurization step (DPf) was from about 70 to about 20 psia. This was followed by evacuation to approximately 4 psia. Carbon dioxide recovery was approximately 8 6% at a purity of about 83%. [0069] The processes described above may be operated at feed pressures higher than 100 psia, and more preferably greater than 300 psia (for example, about 375 psia). Carbon dioxide in the feed gas should preferably be higher than 10 mole%, and most preferably greater than 15 mole% (e.g., 15-25 mole%). Feed temperature may be between about 40-200°F, more preferably between about 60-150°F, and most preferably about 100°F. [0070] In alternative embodiments of the present invention, storage tanks may be added in place of some of the adsorbent beds in the process cycle to store some of the intermediate gas streams such as the depressurized gas. The purpose of these storage tanks is to maintain flow into and out of the C02 VPSA unit as continuous. [0071] The present invention thus provides processes and apparatus for the recovery of medium purity (e.g., approximately M-1 mole%) C02 from syngas. In accordance with preferred embodiments of the present invention, there is constant feed, constant product being produced and rotating machinery is preferably run continuously so as to eliminate unnecessary tank(s). If, however, there are reasons for limiting the number of adsorbent beds (e.g. high cost of the adsorbent) storage tanks instead of the adsorbent vessels may be used as explained above. While every bed goes through the same cycle, the number of beds is to be minimized taking these factors into consideration. [0072] The feed to the C02 VPSA unit can be at super ambient pressure, and the C02 product can be produced as described above. When the C02 VPSA unit is installed upstream of a H2 PSA unit, H2 recovery is expected to increase by extracting the C02, thereby increasing H2 partial pressure in the H2 PSA feed stream. The recovered C02 can be used as produced or further upgraded such as shown in commonly owned U.S. Patent Application Serial No. 11/395,137, filed on even date herewith and entitled "Carbon Dioxide Production Method" by Shah et al., the entire contents of which are incorporated herein by reference. The recovered C02 can then be used, sequestered or used in applications such as enhanced oil recovery (EOR). [0073] It will be appreciated by those skilled in the art that the present invention is not limited to embodiments where the C02 VPSA unit is placed downstream of an SMR/shift reactor and upstream of a H2 PSA unit. The present invention can also be used, for example, with a partial oxidation reactor together with any feed stream as defined hereinabove. [0074] It will also be appreciated that in some cases, the pressure equalization steps could be eliminated. In such cases, the gas that was not pressure equalized can be fed to the product stream. Consequently, C02 purity may be reduced. This may reduce H2 and/or C02 recovery since more H2 and/or C02 could be present in stream 36. In such cases, the number of beds may be reduced. [0075] It should be appreciated by those skilled in the art that the specific embodiments disclosed above may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims. CLAIMS What is claimed is: 1. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising: feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream; depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a third depressurization step from the third pressure to a fourth pressure within a fourth pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a final depressurization step from the fourth pressure to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product; evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product and during the evacuating step, the at least one adsorption bed receiving at least a portion of the first portion of CO2 product; pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a third pressure equalization step in a direction opposite the feed flow; and repressurizing the at least one adsorption bed in a repressurization step to the first pressure range; wherein the process is repeated cyclically. 2. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising: feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream; depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a final depressurization step from the third pressure to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product; evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product and during the evacuating step, the at least one adsorption bed receiving at least a portion of the first portion of C02 product; pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; and repressurizing the at least one adsorption bed in a repressurization (RP) step to the first pressure range; wherein the process is repeated cyclically. 3. A vacuum pressure swing adsorption (VPSA) process for the recovery of C02 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising: feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream; depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a third depressurization step from the third pressure to a fourth pressure within a fourth pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a final depressurization step from the fourth pressure range to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of CO2 product; evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product; pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a third pressure equalization step in a direction opposite the feed flow; and repressurizing the at least one adsorption bed in a repressurization step to the first pressure range; wherein the process is repeated cyclically. 4. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one CO2-selective adsorbent, the process comprising: feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2~enriched stream; depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow; depressurizing the at least one adsorption bed in a final depressurization step from the third pressure to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product; evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product; pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow; further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; and repressurizing the at least one adsorption bed in a repressurization step to the first pressure range; wherein the process is repeated cyclically. 5. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least CO2 and H2 in a VPSA unit containing at least two adsorption beds, each bed containing at least one C02-selective adsorbent, the process comprising: a feed step, a depressurization step, an evacuation step, a pressure equalization step and a repressurization step; wherein the process is conducted in a cyclic manner and at steady state; wherein a H2-enriched stream is produced and a final C02 product is produced from at least one C02 product stream; and wherein the final CO2 product is at a purity of approximately ≥80 mole% CO2. 6. The process of claim 1, 3 or 5, wherein the number of adsorption beds comprises six beds. 7. The process of claim 2, 4 or 5, wherein the number of adsorption beds comprises five beds. 8. The process of claim 5, wherein the number of adsorption beds comprises seven beds. 9. The process of claim 5, wherein the number of adsorption beds comprises eight beds. 10. The process of claim 5, wherein the number of adsorption beds comprises eleven beds. 11. The process of claim 1, 2, 3, or 4 wherein the first pressure range is 100-500 psia. 12. The process of claim 1, 2, 3 or 4 wherein the second pressure range is 80-400 psia. 13. The process of claim 1, 2, 3 or 4 wherein the third pressure range is 60-300 psia. 14. The process of claim 1, 3 or 4 wherein the fourth pressure range is 50-200 psia. 15. The process of claim 1, 2, 3 or 4 wherein the pressure range for the pressure close to ambient is about 20 psia. 16. The process of claim 1, 2, 3 or 4 wherein the pressure range for the pressure below ambient is 1-12 psia. 17. The process of claim 1, 2, 3, 4 or 5 wherein the H2-enriched stream is fed to a H2 pressure swing adsorption (PSA) unit. 18. The process of claim 1, 2, 3, 4 or 5 wherein each at least one bed contains a water-selective adsorbent and a CO2-selective adsorbent. 19. The process of claim 18, wherein the water-selective adsorbent is selected from the group comprising: activated alumina, silica gel, zeolite molecular sieve and combinations thereof. 20. The process of claim 18, wherein the C02-selective adsorbent is selected from the group comprising: NaY, HY, NaX, silica gel, activated carbon and combinations thereof.

Full Text

PROCESS TO RECOVER MEDIUM PURITY CARBON DIOXIDE
TECHNICAL FIELD
[0001] The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover carbon dioxide (CO2) having a purity of approximately ≥80 mole% from streams containing at least C02 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2-enriched stream and a C02 product stream. The process cycle steps are selected such that there is minimal or no H2 losses from the process and without requiring additional processing equipment. The recovered C02 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).
BACKGROUND OF THE INVENTION
[0002] Steam methane reforming (SMR) is the primary process to produce hydrogen (H2) in bulk quantities. After catalytic conversion of natural gas, CO and H2 is produced as follows in equation (1):
(Equation Removed)

The gas mixture is shifted (by a water-gas shift reaction) to further produce H2 according to equation (2) :
(Equation Removed)

After the water-gas shift reaction, typical product gas has a pressure of between about 100-500 psia, a temperature of between about 60-150°F, and a composition of 60-80 mole% H2, 15-25 mole% C02, 0.1-5

mole% CO, 3-7 mole% CH4, 0-5 mole% N2 and is saturated with water. This gas mixture can then be fed to a pressure swing adsorption (PSA) unit to produce high purity H2 (e.g., H2 at a purity of at least 99%). [0003] In some current H2 production plants, an amine unit is placed between the shift reactor and the H2 PSA unit to extract C02 from the stream produced by the shift reactor. This process, however, is energy intensive. In addition, amine units can be difficult to operate and are known to have operational problems, such as corrosion, loss of fluid and the like. [0004] U.S. Patent No. 4,171,206 relates to production of high purity C02 (99.99+%) and high purity H2 (99.99+%) at high C02 (99.9+%) recovery from SMR off-gas. This patent discloses two trains of adsorption beds, which are in communication with each other during the feed and re-pressurization steps. Beds in the C02 train employ a rinse step by high purity C02 at high pressure. Depressurization and evacuation of the same bed follow this step. Depressurized gas is re-compressed and used for high-pressure rinse. The effluent from the high pressure, high purity rinse step is recycled to the feed.
[0005] U.S. Patent No. 4,299,596 relates to production of two products at high purity by employing two trains of beds, which are integrated during the feed and co-current depressurization steps. The train producing the more strongly adsorbed species is purged by the co-current depressurized gas after it has been recompressed. Part of the co-current depressurized gas may be recycled for re-pressurization. Evacuation and
blowdown steps produce part of the more strongly adsorbed species and part of the purge gas. [0006] U.S. Patent No. 4,770,676 relates to the production of methane and C02 from landfill gas. It is an integrated thermal (TSA) and pressure swing adsorption (PSA) process. The waste produced from the PSA regenerates the TSA.
[0007] U.S. Patent No. 4,840,647 relates to production of ≥95% C02 from a feed stream containing 10-30% C02 at ambient pressure. The process steps are feed, co-current evacuation, countercurrent evacuation to produce product and a repressurization step. Co-current evacuated gas is used for pressure equalizations/repressurization and mixed with the feed. [0008] U.S. Patent No. 4,857,083 considers production of CO2 from a gas mixture. At the end of the feed step, the discharge end of the feed column is connected with the inlet end of the evacuated bed to reduce the pressure in this bed. Carbon dioxide is then produced by evacuation. This is followed by pressure build up steps.
[0009] U.S. Patent No. 4,913,709 relates to the production of two products at high purity. The reference suggests the use of two trains of beds, which are integrated during the feed and re-pressurization steps. The train producing the more strongly adsorbed species is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step is recompressed and recycled as feed.

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[0010] U.S. Patent No. 4,915,711 discloses production of two products at high purity using a single train of beds. The bed is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step and depressurization step is recompressed and recycled as feed. [0011] U.S. Patent No. 5,026,406 discloses the production of two products at high purity by employing a single train of beds. The bed is purged by the more strongly adsorbed species obtained during the evacuation step. This purge is at low pressure and is carried out after the bed has been depressurized. Effluent during the purge step and depressurization step is recompressed and recycled as feed. [0012] U.S. Patent No. 5,051,115 produces a more strongly adsorbed species from a gas mixture at high purity. A co-current purge step is employed by the high purity strongly adsorbed species. This purge stream and product are obtained during the evacuation step. Effluent from the purge step is recycled for repressurization.
[0013] U.S. Patent No. 5,248,322 relates to a process with four steps: adsorption, depressurization, evacuation and pressure equalization by part of the depressurized gas and repressurization. The first part (higher pressure) of the depressurized gas is recycled whereas the second part (lower pressure) is used for pressure equalization.
[0014] U.S. Patent No. 5,354,346 relates to a process with five steps: adsorption, depressurization,

low pressure co-current purge, evacuation and pressure equalization by part of the depressurized and low pressure purge effluent gas and repressurization. The first part (higher pressure) of the depressurized gas is recycled whereas the second part (lower pressure) and part of the low pressure purge effluent gas is used for pressure equalization.
[0015] U.S. Patent No. 6,245,127 discusses production of CO2 from a low-pressure gas mixture at constant purity. It employs simultaneous purge and evacuation steps. The countercurrent purge is carried out by the less strongly adsorbed species. [0016] It would be desirable to provide economically beneficial processes and apparatus for C02 recovery. It would further be desirable for such processes and apparatus to be more efficient and easier to use relative to the prior art.
SUMMARY OF THE INVENTION
[0017] The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover C02 having a purity of approximately ≥80 mole% from streams containing at least C02 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2-enriched stream and a CO2 product stream. The process cycle steps are selected such that there is minimal or no H2 losses from the process and without requiring additional processing equipment.
[0018] Carbon dioxide produced in accordance with the present invention may be used for any desired
purpose. For example and while not to be construed as limiting, C02 produced as described herein can be used for liquefaction to produce food-grade quality-product (s), supercritical C02 for enhanced oil recovery or simply C02 for sequestration to avoid addition of green house gases in the atmosphere to meet regulatory requirements.
[0019] The present invention utilizes
depressurizations of an adsorbent from high pressure to low pressure to increase C02 concentration in the bed(s). After C02 concentration is increased, C02 product is produced by further pressure reduction. This can be accomplished because of the recognition that for some adsorbents, depressurization from high to low pressure increases C02 concentration in the adsorbent bed(s). Consequently, the need for rinse, purge and/or recycle steps as used in the prior art can be eliminated. This in turn allows for the elimination of certain pieces of rotating machines (e.g., rinse compressor, purge compressor, recycle compressor) and associated power requirements, thereby providing a process and apparatus which is simpler to operate and more economical than prior art systems. The proposed processes do not require steam and thus are expected to reduce the cost of C02 separation.
[0020] To increase C02 recovery and minimize or eliminate H2 losses, the present invention uses the depressurized gas to build up or increase the pressure in low-pressure beds. The bed depressurization therefore increases C02 concentration in the product and by equalizing with other beds in the unit, at the
same time, increases C02 recovery and minimizes or eliminates H2 loss.
[0021] Another significant feature of the process is that the final depressurized gas (step number 5 (DPf) of Figures 2, 6, or 7 or step 4 (DPf) of Figures 5, 10, 11 or 12) is not wasted. Rather, this gas stream, which is now C02 rich, can be used in either of the two ways or in combination thereof. First, the final depressurized gas stream can be mixed with CO2 produced during the evacuation step. In this embodiment, the mixed gas constitutes the C02 product. In the alternative or in addition, part or the entire final depressurized gas stream can be passed through the bed which is under evacuation. In this embodiment, the evacuated gas constitutes the C02 product. In this manner, H2 loss from C02 VPSA is expected to be minimized or entirely eliminated.
[0022] Another feature of the present invention is that by reducing C02 in the feed stream to the H2 PSA unit, H2 recovery from the H2 PSA unit is expected to increase.
[0023] In preferred embodiments in which the C02 VPSA apparatus is installed between a steam methane reformer (SMR)/shift reactor and a H2 PSA unit, the amount of C02 in the feed stream to the H2 PSA unit is reduced, thereby allowing for increased recovery of H2 from the H2 PSA unit. In other embodiments of the present invention, a feed stream can be provided by a partial oxidation reactor or the like. In any of these embodiments, the feed stream to the C02 VPSA unit will be a stream containing at least H2 and C02 at high pressure (for example, 100-500 psia).
By eliminating the hardware (i.e. rotating machinery) as mentioned hereinabove, and corresponding power requirements, the present invention is expected to more efficiently produce C02 from syngas or other streams containing at least C02 and H2 relative to the prior art.
BRIEF DESCRIPTION OF THE DRAWINGS
[0024] For a more complete understanding of the present invention and the advantages thereof, reference should be made to the following Detailed Description taken in conjunction with the accompanying drawings in which:
[0025] Figure 1 illustrates an embodiment in accordance with the present invention in which a CO2 VPSA unit is positioned upstream of a H2 PSA unit; [0026] Figure 2 illustrates a cycle step chart for C02 VPSA unit having six beds, three pressure equalization steps and flow through the evacuating bed in accordance with one embodiment of the present invention;
[0027] Figure 3 shows a schematic drawing for CO2 VPSA unit of Figure 2;
[0028] Figure 4 shows the valve sequence for operation of the C02 VPSA unit shown in Figures 2 and 3;
[0029] Figure 5 illustrates an alternative cycle step chart for a C02 VPSA unit having five beds, two pressure equalization steps and flow through the evacuating bed in accordance with the present invention;
[0030] Figure 6 illustrates another alternative
cycle step chart for a C02 VPSA unit having seven beds,
three pressure equalization steps and flow through the
evacuating bed in accordance with the present
invention;
[0031] Figure 7 illustrates a further cycle step for
a C02 VPSA unit having six beds, three pressure
equalization steps and direct mixing in accordance with
another embodiment of the present invention;
[0032] Figure 8 shows a schematic drawing for CO2
VPSA unit of Figure 7;
[0033] Figure 9 shows the valve sequence for
operation of the CO2 VPSA unit shown in Figures 7 and
8;
[0034] Figure 10 illustrates yet another cycle step
chart for a CO2 VPSA unit having five beds, two
pressure equalization steps and direct mixing according
to the present invention;
[0035] Figure 11 illustrates yet another cycle step
chart for a CO2 VPSA unit having eight beds, two
pressure equalization steps and direct mixing in which
two beds are continuously on feed and at least two beds
are continuously under evacuation according to the
present invention; and
[0036] Figure 12 illustrates a further cycle step
chart for a C02 VPSA unit having eleven beds, two
pressure equalization steps and direct mixing in which
three beds are continuously on feed and two beds are
continuously under evacuation according to the present
invention.

DETAILED DESCRIPTION
[0037] As discussed hereinabove, the present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover CO2 having a purity of approximately ≥80 mole% from streams containing at least CO2 and H2 (e.g., syngas). The feed to the C02 VPSA can be at super ambient pressure. The C02 VPSA unit produces two streams, a H2~enriched stream and a C02 product stream. [0038] Carbon dioxide produced in accordance with the present invention may be used for any desired purpose. For example and while not to be construed as limiting, C02 produced as described herein can be used for liquefaction to produce food-grade quality product(s), supercritical C02 for enhanced oil recovery or simply C02 for sequestration to avoid additional green house gases in the atmosphere in order to satisfy regulatory requirements.
[0039] As discussed in more detail herein, a significant feature of the processes is that the final depressurized gas (step number 5 (DPf) of Figures 2, 6, or 7 or step 4 (DPf) of Figures 5, 10, 11 or 12) is not wasted. Rather, this gas stream (which is now C02-rich) can be used in either of two ways or in combination thereof. First, the final depressurized gas stream can be mixed with C02 produced by another bed under evacuation. In this embodiment, the mixed gas constitutes the C02 product. In the alternative or in addition, part or the entire final depressurized gas stream can be passed through the bed which is under evacuation. In this embodiment, the evacuated gas constitutes at least a part of the C02 product. In
this manner, H2 loss from C02 VPSA is expected to be minimized or entirely eliminated.
[0040] In a preferred embodiment of the present invention and as illustrated in Figure 1, system 10 includes C02 VPSA unit 30 positioned upstream of H2 PSA unit 28. As discussed above, natural gas 12 and steam 14 can be reformed in steam methane reformer 16 to produce stream 18, as outlined in equation (1) hereinabove. Stream 18 is then fed to shift reactor 20 to produce stream 22 as outlined in equation (2), as also set forth above.
[0041] Stream 22 can be fed to C02 VPSA unit 30 via stream 24. Valve 26 will therefore typically be in the closed position and is in the open position when the C02 VPSA unit is not being used. Those skilled in the art will appreciate that valve 26 may alternatively be in the partially open position depending on the desired process capacity (i.e., C02 recovery). [0042] When the arrangement shown in Figure 1 is used with processes and apparatus in accordance with the present invention, C02-rich stream 36 (e.g. M-1 mole%) can be produced, together with H2-rich feed 32 that is expected to result in higher H2 recovery 38 from H2 PSA unit 28. Hydrogen PSA unit 28 can also produce fuel 40 for use in plant 10. [0043] The present invention recognizes that depressurizations of a C02-selective adsorbent layer increases the C02 concentration in the adsorbent bed(s). More specifically, the present invention recognizes and utilizes depressurizations of an adsorbent from high pressure (e.g., 100-500 psia) to low pressure(s) (i.e., close to ambient and/or
subambient pressures) to increase C02 concentration in the bed.
[0044] As used herein, a "feed stream" being fed to a CO2 unit in accordance with the present invention is a stream containing at least H2 and CO2 at a pressure between about 100-500 psia (e.g., 375 psia). After the C02 concentration is increased by multiple depressurizations, it can be used to produce the C02 product by further pressure reduction. For some adsorbents, depressurization from high to low pressure increases CO2 concentration in the adsorbent bed. This step in the process can be used to eliminate several process steps as described in the prior art. Consequently, several pieces of rotating machinery (e.g., rinse compressor, purge compressor, recycle compressor) and associated power requirements can be eliminated, thus providing a process and system that enhances operation and improves efficiency. [0045] As mentioned above, the C02 VPSA processes and apparatus of the present invention can be used to produce CO2 having a purity of about 80 mole% from a feed gas such as a syngas. In one embodiment of the present invention, the processes provide for flow through the evacuating bed (see for example, Figures 2-6). The flow through embodiments can be accomplished using a varying number of beds and pressure equalization steps. For example, flow through the evacuating bed can be accomplished with six beds and three pressure equalization steps (Figures 2-4). Alternatively, flow through the evacuating bed can be accomplished with five beds and two pressure equalization steps (Figure 5) or seven beds and three
pressure equalization steps (Figure 6). At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization. In addition, a purge step can be included in the cycle for the embodiment shown in Figure 6.
[0046] In other alternative embodiments of the present invention, the C02 VPSA processes and apparatus can be used to produce C02 having a purity of about 8 0 mole% from a feed gas such as a syngas by direct mixing. In such embodiments, the C02 product produced during the final depressurization step (DPf) is not passed through another bed under evacuation. Rather, this stream is mixed directly with the stream from the evacuating bed. In one preferred and exemplary embodiment, this can be accomplished with a C02 VPSA unit having six beds and three pressure equalization steps (Figures 7-9). In other embodiments, this can be accomplished by using a C02 VPSA unit having five beds and two pressure equalization steps (Figure 10). At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization.
[0047] Combinations of flow through and direct mixing can also be used. In such embodiments, a portion of the stream produced during the depressurization step (DPf) flows through the bed under evacuation and the remainder is directly mixed with the stream exiting the bed under evacuation.
[0048] In embodiments where increased plant capacity is desirable, the embodiments shown in Figures 11 and 12 can be utilized. More specifically, Figure 11 shows a cycle step chart for an embodiment of the present invention in which two pressure equalizations and eight beds are used with direct mixing. In this embodiment, two beds are continuously on feed and at least two beds are continuously under evacuation. This arrangement is expected to allow for an increase in the capacity of the plant. Figure 12 illustrates a cycle step chart for an embodiment of the present invention in which two pressure equalizations and eleven beds are used with direct mixing. In this embodiment, three beds are continuously on feed and two beds are continuously under evacuation. This arrangement is also expected to allow for an increase in the capacity of the plant. At any time during any of these processes, the beds will be in one of the following categories of steps: feed, depressurizations, evacuation, pressure equalizations, and repressurization.
[0049] In any of the embodiments, each bed is preferably packed with at least two layers of adsorbents. The type and sizing of the adsorbent layer toward the feed end (i.e. a water-selective adsorbent layer) in the bed is selected to remove moisture in the feed stream such that any residual moisture does not deteriorate the performance of the main (i.e., CO2-selective) adsorbent layer. The water-selective adsorbent layer is also preferably capable of removing impurities (e.g., trace amounts of sulfur or heavy hydrocarbon compounds) from the feed stream, to the extent such impurities are present. The main, second
adsorbent layer (i.e., the C02-selective adsorbent layer) is used for selectively adsorbing C02 from the feed stream after sufficient moisture has been removed. [0050] For the first adsorbent layer (i.e. the water-selective adsorbent layer), adsorbents such as activated alumina, silica gel or zeolite molecular sieve are preferred. These adsorbents are intended to be illustrative and other adsorbents capable of removing sufficient moisture are also suitable for use in accordance with the present invention. Preferred characteristics for such adsorbent(s) include: high crush strength capabilities, high attrition resistance, large bulk density, low inter-particle void, high heat capacity, large thermal conductivity, low-pressure drop and stable in liquid water.
[0051] The main layer of adsorbent (i.e., the C02-selective adsorbent layer) following the water-selective adsorbent layer preferably has the following characteristics: high selectivity, high working capacity, fast kinetics and low heat of adsorption. Typical examples of such adsorbents include, but are not limited to: are NaY, HY, NaX, silica gel, and activated carbon. Other desired physical properties of the main layer adsorbent (i.e. the C02-selective layer) include: high crush strength, high attrition resistance, large bulk density, low inter-particle void, high heat capacity, large thermal conductivity and low-pressure drop during the feed and evacuation steps.
[0052] Those skilled in the art will appreciate that a composite mixed layer containing both adsorbents
could be used in the present invention so long as the characteristics of the adsorbents are satisfied. Referring now to Figures 2-4, a first embodiment of the present invention having six beds (A1-A6) and using ten steps with flow through the evacuating bed to produce enriched CO2 from syngas is illustrated. The process steps include:
1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least C02 and H2 gases at a high pressure between about 100-500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated.
2. Co-Current (CoC) Depressurization 1 (DPI). The C02 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow.
3. Co-Current (CoC) Depressurization 2 (DP2). The C02 VPSA bed, which is now at some medium pressure (e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow.
4. Co-Current (CoC) Depressurization 3 (DP3). The CO2 VPSA bed, which is now at some medium pressure (e.g., 60-300 psia), is further depressurized to a lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 2) or opposite (not shown in Figure 2) as the feed flow.
5. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (shown in Figure 2) and/or the opposite (not shown in Figure 2) the feed flow.
As shown by the arrows in Figure 2 (i.e. arrows from DPf to bed under evacuation), the stream from this step (DPf) flows through the bed under evacuation (e.g. in Figure 2: bed 1 to bed 6, bed 2 to bed 1, bed 3 to bed 2, bed 4 to bed 3, bed 5 to bed 4 or bed 6 to bed 5 on the respective cycle steps).
6. Evacuation. The C02 VPSA bed, which is now
close to ambient pressure (about 20 psia), is evacuated
to a predetermined low pressure, a subambient pressure
(about 1-12 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. As shown in Figure 2 and outlined in the description of step 5 (DPf) above, this bed is receiving gas from another bed in the DPf step. The gas from the bed under evacuation constitutes the C02 product stream.
7. Countercurrent (CcC) Pressure Equalization 3
(PE3). The evacuated bed is now pressure equalized to
a pressure range of the gas produced in step 4 (DP3)
(i.e., to about 50-200 psia) in a direction the same as
(not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step increases CO2 recovery by keeping the C02 from step 4 within the VPSA system. This minimizes CO2 loss by eliminating the need to send the C02 to a waste stream.
8. Countercurrent (CcC) Pressure Equalization 2
(PE2). The bed pressure equalized in step 7 is now
pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step increases C02 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
9. Countercurrent Pressure (CcC) Equalization 1
(PE1). The bed pressure equalized in step 8 is further
pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 2) or opposite (shown in Figure 2) to the feed flow. This step further increases C02 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the CO2 to a waste stream.
10. Repressurization (FeRP). The pressure-
equalized bed is repressurized to a feed pressure (100-
500 psia) either by the feed gas or by part of the
effluent generated from another bed in step 1 (i.e.
feed effluent). Following repressurization to feed
pressure, this bed is now ready to go back to step 1.
The ten-step process described is for one cycle for one bed in the C02 VPSA unit. The above ten steps for this flow through the evacuating bed embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 6) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Six adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps.
[0053] Exemplary corresponding hardware and a flow schematic of the C02 VPSA process corresponding to the cycle shown in Figure 2 is depicted in Figure 3. The various valves in Figure 3 can be operated in the manner illustrated in Figure 4 to carry out the ten steps in the six-bed process as described hereinabove. It should be appreciated that pressures and step durations shown are only for illustrative purposes. Those skilled in the art will appreciate that other combinations of pressures and step durations may be used.
[0054] As can be appreciated from the above description, the present invention thus relies upon depressurizations of at least one C02-selective adsorbent from high pressure to low pressure to increase C02 concentration in the bed. After C02 concentration is increased, it produces the C02 product by further pressure reduction. This became possible based on the recognition that for some adsorbents,
pressure reduction from high to low pressure increases C02 concentration on the adsorbent.
[0055] In the embodiment shown in Figures 2-4 and as described, the gas produced during the final depressurization (step number 5, DPf) flows through the bed under evacuation as shown by the arrows in the cycle step chart in Figure 2. By utilizing the final depressurization gas stream (step number 5) in this manner, there is minimal or no H2 loss from the C02 VPSA unit.
[0056] Alternative and additional exemplary embodiments that utilize the final depressurization gas stream (DPf) flow through the evacuating bed are illustrated in Figures 5 and 6.
[0057] Referring now to Figure 5, a cycle step chart for an eight-step process that utilizes five beds and two pressure equalization steps is shown. These cycle steps are carried out in a similar manner to those steps described above with reference to Figure 2, except that steps DP3 and PE3 have been eliminated. More specifically, the cycle steps for Figure 5 include the following:
1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least CO2 and H2 gases at a high pressure between about 100-500 psia (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit (unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02
breakthrough from the bed on the feed 24, the feed step is terminated.
2. Co-Current (CoC) Depressurization 1 (DPI). The CO2 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 5) or opposite (not shown in Figure 5) as the feed flow.
3. Co-Current (CoC) Depressurization 2 (DP2). The CO2 VPSA bed, which is now at some medium pressure
(e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 5) or opposite (not shown in Figure 5) as the feed flow.
4. Final Depressurization (DPf). The C02 VPSA
bed, which is now at a pressure lower than at the start
of step 4 (about 50-200 psia) is further depressurized
to a pressure close to ambient (about 20 psia) in a
direction the same as (shown in Figure 5) and/or the
opposite (not shown in Figure 5) the feed flow.
As shown by the arrows in Figure 5 (i.e. arrows from DPf to bed under evacuation), the stream from this step (DPf) flows through the bed under evacuation (e.g. as shown in Figure 5: bed 1 to bed 5, bed 2 to bed 1, bed 3 to bed 2, bed 4 to bed 3 or bed 5 to bed 4 on the respective cycle steps).
5. Evacuation. The C02 VPSA bed, which is now
close to ambient pressure (about 20 psia), is evacuated
to a predetermined low pressure, a subambient pressure
(about 1-12 psia) in a direction the same as (not shown
in Figure 5) or opposite (shown in Figure 5) to the
feed flow. As shown in Figure 5 and as outlined in the
description of step 4 (DPf) above, this bed is receiving gas from another bed in the DPf step for the duration of the DPf step. The gas from the bed under evacuation constitutes the CO2 product stream.
6. Countercurrent (CcC) Pressure Equalization 2 (PE2). The evacuated bed is now pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 5) or opposite (shown in Figure 5) to the feed flow. This step increases CO2 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
7. Countercurrent Pressure (CcC) Equalization 1 (PE1). The bed pressure equalized in step 6 is further
pressure equalized to a pressure range of the gas produced in step 1 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 5) or opposite (shown in Figure 5) to the feed flow. This step further increases C02 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the CO2 to a waste stream.
8. Repressurization (FeRP). The pressure-
equalized bed is repressurized to a feed pressure (100-
500 psia) either by the feed gas or by part of the
effluent generated from another bed in step 1 (i.e.
feed effluent). Following repressurization to feed
pressure, this bed is now ready to go back to step 1.
The eight-step process described is for one cycle for
one bed in the C02 VPSA unit. The above eight steps
for this flow through the evacuating bed embodiment are
carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 5) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Five adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0058] Referring now to Figure 6, a cycle step chart for an eleven-step process that utilizes seven beds and three pressure equalization steps is shown. These cycle steps are carried out in a similar manner to those steps described above with reference to Figure 2, except that an additional step (Rf) is included between the final depressurization step (DPf) and the evacuation step. More specifically, the cycle steps for Figure 6 include the following:
1. Feed Step. A feed stream 24 (shown in Figure
1) containing at least C02 and H2 gases at a high
pressure between about 100—500 psia (for example, about
375 psia) and produced by the shift reactor 20 is
diverted to the C02 VPSA unit of the present invention.
High-pressure effluent 32 (i.e., a H2-enriched stream)
from the C02 VPSA unit (unit 30 in Figure 1) is sent to
the H2 PSA unit 28, which in turn produces high-
pressure, high purity H2 product (stream 38 in Figure
1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated.
2. Co-Current (CoC) Depressurization 1 (DPI).
The C02 VPSA bed, which has finished the feed step is
now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow.
3. Co-Current (CoC) Depressurization 2 (DP2). The
C02 VPSA bed, which is now at some medium pressure
(e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow.
4. Co-Current (CoC) Depressurization 3 (DP3). The CO2 VPSA bed, which is now at some medium pressure (e.g., 60-300 psia), is further depressurized to a lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 6) or opposite (not shown in Figure 6) as the feed flow.
5. Final Depressurization (DPf) . The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (shown in Figure 6) and/or the opposite (not shown in Figure 6) the feed flow.
6. Receive Purge (Rf). The stream produced by
DPf (e.g., bed 1 in Figure 6) is fed to another bed
having completed DPf, but not yet under evacuation
(e.g., bed 7 in Figure 6). During this time (duration
of the Rf step), the effluent (e.g., bed 7 in Figure 6)
flows to tank 42 as C02 product. During the remaining
time period of DPf of bed 1, the gas flows through the
bed under evacuation (e.g., bed 7 in Figure 6).
7. Evacuation. The C02 VPSA bed, which is now
close to ambient pressure (about 20 psia), is evacuated
to a predetermined low pressure, a subambient pressure (about 1-12 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. As shown in Figure 6, this bed (bed 1) is receiving gas from another bed in the DPf step (bed 2). The gas from the bed under evacuation constitutes at least part of the C02 product stream.
8. Countercurrent (CcC) Pressure Equalization 3
(PE3). The evacuated bed is now pressure equalized to
a pressure range of the gas produced in step 4 (DP3)
(i.e., to about 50-200 psia) in a direction the same as
(not shown in Figure 2) or opposite (shown in Figure 2)
to the feed flow. This step increases C02 recovery by keeping the CO2 from step 4 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
9. Countercurrent (CcC) Pressure Equalization 2
(PE2). The bed pressure equalized in step 7 is now
pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. This step increases C02 recovery by keeping the CO2 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
10. Countercurrent Pressure (CcC) Equalization 1
(PE1). The bed pressure equalized in step 9 is further
pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 6) or opposite (shown in Figure 6) to the feed flow. This
step further increases CO2 recovery by keeping the CO2 from step 2 within the VPSA system. This minimizes CO2 loss by eliminating the need to send the C02 to a waste stream.
11. Repressurization (FeRP). The pressure-equalized bed is repressurized to a feed pressure (100-500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. The eleven-step process described is for one cycle for one bed in the C02 VPSA unit.
[0059] The above eleven steps for this flow through the evacuating bed embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 7) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Seven adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps.
[0060] As mentioned above, by flowing the gas produced during the final depressurization step (DPf) through a bed under evacuation and/or prior to its going to the evacuation step, all or substantially all the H2 loss from the C02 VPSA unit can be eliminated (Figure 2-6). In other embodiments (Figures 7-12), little or no H2 loss may also be achieved by directly mixing the two streams (i.e. effluents from DPf and evacuation).

Referring now to Figures 7-9, an embodiment of the present invention having six beds (A1-A6) and using ten steps with direct mixing of CO2 gas from the DPf step and the evacuation step to produce a final C02-enriched gas from syngas is illustrated. The process steps include:
1. Feed Step. A feed stream 24 (shown in Figure 1) containing at least CO2 and H2 gases at a high pressure between about (for example, about 375 psia) and produced by the shift reactor 20 is diverted to the C02 VPSA unit of the present invention. High-pressure effluent 32 (i.e., a H2-enriched stream) from the C02 VPSA unit(unit 30 in Figure 1) is sent to the H2 PSA unit 28, which in turn produces high-pressure, high purity H2 product (stream 38 in Figure 1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated.
2. Co-Current (CoC) Depressurization 1 (DPI) . The CO2 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow.
3. Co-Current (CoC) Depressurization 2 (DP2). The CO2 VPSA bed, which is now at some medium pressure
(e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow.
4. Co-Current (CoC) Depressurization 3 (DP3). The
CO2 VPSA bed, which is now at some medium pressure
(e.g., 60-300 psia), is further depressurized to a
lower pressure (e.g., 50-200 psia) in a direction the same as (shown in Figure 7) or opposite (not shown in Figure 7) as the feed flow.
5. Final Depressurization (DPf). The C02 VPSA bed, which is now at a pressure lower than at the start of step 4 (about 50-200 psia) is further depressurized to a pressure close to ambient (about 20 psia) in a direction the same as (not shown in Figure 7) and/or the opposite (shown in Figure 7) the feed flow to produce CO2 product 36b shown in Figure 8. This stream may constitute part of the C02 product (stream 36 in Figure 8).
6. Evacuation. The C02 VPSA bed, which is now close to ambient pressure (about 20 psia), is evacuated to a predetermined low pressure, a subambient pressure
(about 1-12 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. The gas from the bed under evacuation
(stream 36a in Figure 8) constitutes part of the C02
product stream (stream 36 in the Figures). Optionally, stream 36a can be further compressed using a blower (not shown) prior to passing to tank 42.
7. Countercurrent (CcC) Pressure Equalization 3
(PE3). The evacuated bed is now pressure equalized to
a pressure range of the gas produced in step 4 (DP3) (i.e., to about 50-200 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7)
to the feed flow. This step increases CO2 recovery by
keeping the C02 from step 4 within the VPSA system.
This minimizes C02 loss by eliminating the need to send
the CO2 to a waste stream.

8. Countercurrent (CcC) Pressure Equalization 2
(PE2). The bed pressure equalized in step 7 is now
pressure equalized to a pressure range of the gas produced in step 3 (DP2) (i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. This step increases C02 recovery by keeping the C02 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
9. Countercurrent Pressure (CcC) Equalization 1
(PE1). The bed pressure equalized in step 8 is further
pressure equalized to a pressure range of the gas produced in step 2 (DPI) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 7) or opposite (shown in Figure 7) to the feed flow. This step further increases C02 recovery by keeping the C02 from step 2 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
10. Repressurization (FeRP). The pressure-
equalized bed is repressurized to a feed pressure (100-
500 psia) either by the feed gas or by part of the
effluent generated from another bed in step 1 (i.e.
feed effluent). Following repressurization to feed
pressure, this bed is now ready to go back to step 1.
As further shown in Figure 7, C02 product 3 6 is formed
of C02 from streams 36b (step 6) and 36a (step 7) by
product tank 42. Product 36 is expected to have a C02
purity level of approximately 80 mole% or greater.
[0061] The ten-step process described is for one
cycle for one bed in the C02 VPSA unit. The above ten
steps for this direct mixing embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 6) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Six adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps.
[0062] Exemplary corresponding hardware and a flow schematic of the CO2 VPSA process corresponding to the cycle shown Figure 7 is depicted in Figure 8. The various valves in Figure 8 can be operated in the manner illustrated in Figure 9 to carry out the ten steps in the six-bed process as described hereinabove. [0063] It should be appreciated that pressures and step durations shown are only for illustrative purposes. Thos skilled in the art will appreciate that other combinations of pressures and steps may be used. In the embodiment shown in Figures 7-9 and as described, the gas produced during the final depressurization step (DPf) is mixed with the evacuated gas from step number 6. Consequently, there is minimal or no H2 loss from the C02 VPSA unit.
[0064] Another exemplary embodiment that utilizes direct mixing of the final depressurization gas stream (DPf) with the gas produced by evacuation bed is illustrated in Figure 10.
[0065] Referring now to Figure 10, a cycle step chart for an eight-step process that utilizes five beds and two pressure equalization steps is shown. These
cycle steps are carried out in a similar manner to those steps described above with reference to Figure 7, except that steps DP3 and PE3have been eliminated. More specifically, the cycle steps for Figure 10 include the following:
1. Feed Step. A feed stream 24 (shown in Figure
1) containing at least C02 and H2 gases at a high
pressure between about 100-500 psia (for example, about
375 psia) and produced by the shift reactor 20 is
diverted to the C02 VPSA unit of the present invention.
High-pressure effluent 32 (i.e., a H2-enriched stream)
from the C02 VPSA unit (unit 30 in Figure 1) is sent to
the H2 PSA unit 28, which in turn produces high-
pressure, high purity H2 product (stream 38 in Figure
1). After a predetermined time or after C02 breakthrough from the bed on the feed 24, the feed step is terminated.
2. Co-Current (CoC) Depressurization 1 (DPI). The C02 VPSA bed, which has finished the feed step is now at high feed pressure (e.g., 100-500 psia), is depressurized to a medium pressure (e.g., 80-400 psia) in a direction the same (shown in Figure 10) or opposite (not shown in Figure 10) as the feed flow.
3. Co-Current (CoC) Depressurization 2 (DP2). The C02 VPSA bed, which is now at some medium pressure
(e.g., 80-400 psia), is further depressurized to a lower pressure (e.g., 60-300 psia) in a direction the same as (shown in Figure 10) or opposite (not shown in Figure 10) as the feed flow.
4. Final Depressurization (DPf). The C02 VPSA
bed, which is now at a pressure lower than at the start
of step 4 (about 50-200 psia) is further depressurized
to a pressure close to ambient (about 20 psia) in a direction the same as (not shown in Figure 10) and/or the opposite (shown in Figure 10) the feed flow to produce C02 product 36b. This stream may constitute part of the C02 product (stream 36).
5. Evacuation. The C02 VPSA bed, which is now
close to ambient pressure (about 20 psia), is evacuated
to a predetermined low pressure, a subambient pressure
(about 1-12 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. The gas from the bed under evacuation
(stream 36a in Figure 8) constitutes part of the CO2
product stream (stream 36 in the Figures). Optionally, stream 36a can be further compressed using a blower (not shown) prior to passing to tank 42.
6. Countercurrent (CcC) Pressure Equalization 2
(PE2). The evacuated bed is now pressure equalized to
a pressure range of the gas produced in step 3 (DP2)
(i.e., to about 60-300 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. This step increases C02 recovery by keeping the C02 from step 3 within the VPSA system. This minimizes C02 loss by eliminating the need to send the C02 to a waste stream.
7. Countercurrent Pressure (CcC) Equalization 1
(PEl). The bed pressure equalized in step 6 is further
pressure equalized to a pressure range of the gas produced in step 2 (DP1) (i.e., to about 80-400 psia) in a direction the same as (not shown in Figure 10) or opposite (shown in Figure 10) to the feed flow. This step further increases C02 recovery by keeping the C02 from step 2 within the VPSA system. This minimizes C02

loss by eliminating the need to send the C02 to a waste stream.
8. Repressurization (FeRP). The pressure-equalized bed is repressurized to a feed pressure (100-500 psia) either by the feed gas or by part of the effluent generated from another bed in step 1 (i.e. feed effluent). Following repressurization to feed pressure, this bed is now ready to go back to step 1. Carbon dioxide product 36 is formed of C02 from streams 36b (step 4) and 36a (step 5) by product tank 42. Product 36 is expected to have a C02 purity level of approximately 80 mole% or greater.
[0066] The eight-step process described is for one cycle for one bed in the C02 VPSA unit. The above eight steps for this direct mixing embodiment are carried out in a cyclic manner with the other beds in the unit such that feed-into and feed-effluent from step 1 are continuous. In addition, the evacuation step (number 5) is designed to be continuous. This ensures that the vacuum pump operates continuously, and that there is no break in feed-into the C02 VPSA unit or to the H2 PSA unit. Five adsorption beds are utilized in the embodiment described above to maintain the continuity of the key process steps. [0067] It is also expected that the present invention can be modified to produce higher amounts of C02 and thus high plant capacity. For example, one may need or desire to process higher feed flow rates than may be handled by a single vacuum train or single vessel (due to fluidization or transportation limitations). In such situations, the process steps may be arranged such that at least two beds are on feed
and at least two beds are under evacuation all the time. Such exemplary cycle step charts and arrangement are shown in Figures 11 and 12. Alternatively or in addition, multiple trains can be used.
Example [0068] The direct mixing process cycle shown in Figure 7 was tested on a six-bed pilot unit and is expected to readily scale up. The inner diameter (ID) of the column was 2.17 inch and the packed bed height was 130 inches. The column was packed with 1.3 lb of commercially available activated alumina, 10.2 lb of commercially available 1/16" NaY pellets and the top void was filled with 3" of ceramic balls. The feed contained 2.8% CO, 15.7% C02, 6.3% CH4 and 0.2% N2 with balance being H2. The feed was at 375 psia. The process was run in a cyclic manner until it reached cyclic steady state. The final depressurization step (DPf) was from about 70 to about 20 psia. This was followed by evacuation to approximately 4 psia. Carbon dioxide recovery was approximately 8 6% at a purity of about 83%.
[0069] The processes described above may be operated at feed pressures higher than 100 psia, and more preferably greater than 300 psia (for example, about 375 psia). Carbon dioxide in the feed gas should preferably be higher than 10 mole%, and most preferably greater than 15 mole% (e.g., 15-25 mole%). Feed temperature may be between about 40-200°F, more preferably between about 60-150°F, and most preferably about 100°F.
[0070] In alternative embodiments of the present invention, storage tanks may be added in place of some of the adsorbent beds in the process cycle to store some of the intermediate gas streams such as the depressurized gas. The purpose of these storage tanks is to maintain flow into and out of the C02 VPSA unit as continuous.
[0071] The present invention thus provides processes and apparatus for the recovery of medium purity (e.g., approximately M-1 mole%) C02 from syngas. In accordance with preferred embodiments of the present invention, there is constant feed, constant product being produced and rotating machinery is preferably run continuously so as to eliminate unnecessary tank(s). If, however, there are reasons for limiting the number of adsorbent beds (e.g. high cost of the adsorbent) storage tanks instead of the adsorbent vessels may be used as explained above. While every bed goes through the same cycle, the number of beds is to be minimized taking these factors into consideration. [0072] The feed to the C02 VPSA unit can be at super ambient pressure, and the C02 product can be produced as described above. When the C02 VPSA unit is installed upstream of a H2 PSA unit, H2 recovery is expected to increase by extracting the C02, thereby increasing H2 partial pressure in the H2 PSA feed stream. The recovered C02 can be used as produced or further upgraded such as shown in commonly owned U.S. Patent Application Serial No. 11/395,137, filed on even date herewith and entitled "Carbon Dioxide Production Method" by Shah et al., the entire contents of which are incorporated herein by reference. The recovered
C02 can then be used, sequestered or used in applications such as enhanced oil recovery (EOR). [0073] It will be appreciated by those skilled in the art that the present invention is not limited to embodiments where the C02 VPSA unit is placed downstream of an SMR/shift reactor and upstream of a H2 PSA unit. The present invention can also be used, for example, with a partial oxidation reactor together with any feed stream as defined hereinabove. [0074] It will also be appreciated that in some cases, the pressure equalization steps could be eliminated. In such cases, the gas that was not pressure equalized can be fed to the product stream. Consequently, C02 purity may be reduced. This may reduce H2 and/or C02 recovery since more H2 and/or C02 could be present in stream 36. In such cases, the number of beds may be reduced.
[0075] It should be appreciated by those skilled in the art that the specific embodiments disclosed above may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims.

CLAIMS
What is claimed is:
1. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising:
feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream;
depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a third depressurization step from the third pressure to a fourth pressure within a fourth pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a final depressurization step from the fourth pressure to a pressure range close to ambient in a
same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product;
evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product and during the evacuating step, the at least one adsorption bed receiving at least a portion of the first portion of CO2 product;
pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a third pressure equalization step in a direction opposite the feed flow; and
repressurizing the at least one adsorption bed in a repressurization step to the first pressure range;
wherein the process is repeated cyclically.
2. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising:
feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least
one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream;
depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a final depressurization step from the third pressure to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product;
evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product and during the evacuating step, the at least one adsorption bed receiving at least a portion of the first portion of C02 product;
pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; and
repressurizing the at least one adsorption bed in a repressurization (RP) step to the first pressure range;
wherein the process is repeated cyclically.
3. A vacuum pressure swing adsorption (VPSA) process for the recovery of C02 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one C02-selective adsorbent, the process comprising:
feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2-enriched stream;
depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a third depressurization step from the third pressure to a fourth pressure within a fourth pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a final depressurization step from the fourth pressure range to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of CO2 product;
evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product;
pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a third pressure equalization step in a direction opposite the feed flow; and
repressurizing the at least one adsorption bed in a repressurization step to the first pressure range;
wherein the process is repeated cyclically.
4. A vacuum pressure swing adsorption (VPSA) process for the recovery of CO2 from a multi-component gas mixture containing at least C02 and H2 in a VPSA unit containing at least one adsorption bed containing at least one CO2-selective adsorbent, the process comprising:
feeding the multi-component gas mixture containing the at least C02 and the H2 to the at least
one adsorption bed at a first pressure within a first pressure range for a predetermined time to produce a H2~enriched stream;
depressurizing the at least one adsorption bed in a first depressurization step from the first pressure to a second pressure within a second pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a second depressurization step from the second pressure to a third pressure within a third pressure range in a same direction as or an opposite direction as the feed flow;
depressurizing the at least one adsorption bed in a final depressurization step from the third pressure to a pressure range close to ambient in a same direction as the feed flow or in a direction opposite the feed flow to produce at least a first portion of C02 product;
evacuating the at least one adsorption bed from the pressure close to ambient to a pressure at or below ambient in a direction opposite the feed flow to produce at least a second portion of CO2 product;
pressure equalizing the at least one adsorption bed in a first pressure equalization step in a direction opposite the feed flow;
further pressure equalizing the at least one adsorption bed in a second pressure equalization step in a direction opposite the feed flow; and
repressurizing the at least one adsorption bed in a repressurization step to the first pressure range;
wherein the process is repeated cyclically.
5. A vacuum pressure swing adsorption (VPSA)
process for the recovery of CO2 from a multi-component
gas mixture containing at least CO2 and H2 in a VPSA
unit containing at least two adsorption beds, each bed
containing at least one C02-selective adsorbent, the
process comprising:
a feed step, a depressurization step, an evacuation step, a pressure equalization step and a repressurization step;
wherein the process is conducted in a cyclic manner and at steady state;
wherein a H2-enriched stream is produced and a final C02 product is produced from at least one C02 product stream; and
wherein the final CO2 product is at a purity of approximately ≥80 mole% CO2.
6. The process of claim 1, 3 or 5, wherein the number of adsorption beds comprises six beds.
7. The process of claim 2, 4 or 5, wherein the number of adsorption beds comprises five beds.
8. The process of claim 5, wherein the number of adsorption beds comprises seven beds.
9. The process of claim 5, wherein the number of adsorption beds comprises eight beds.
10. The process of claim 5, wherein the number of adsorption beds comprises eleven beds.
11. The process of claim 1, 2, 3, or 4 wherein the first pressure range is 100-500 psia.
12. The process of claim 1, 2, 3 or 4 wherein the second pressure range is 80-400 psia.
13. The process of claim 1, 2, 3 or 4 wherein the third pressure range is 60-300 psia.
14. The process of claim 1, 3 or 4 wherein the fourth pressure range is 50-200 psia.
15. The process of claim 1, 2, 3 or 4 wherein the pressure range for the pressure close to ambient is about 20 psia.
16. The process of claim 1, 2, 3 or 4 wherein the pressure range for the pressure below ambient is 1-12 psia.
17. The process of claim 1, 2, 3, 4 or 5 wherein the H2-enriched stream is fed to a H2 pressure swing adsorption (PSA) unit.
18. The process of claim 1, 2, 3, 4 or 5 wherein each at least one bed contains a water-selective adsorbent and a CO2-selective adsorbent.
19. The process of claim 18, wherein the water-selective adsorbent is selected from the group comprising: activated alumina, silica gel, zeolite molecular sieve and combinations thereof.
20. The process of claim 18, wherein the C02-selective adsorbent is selected from the group comprising: NaY, HY, NaX, silica gel, activated carbon and combinations thereof.

Documents:

8156-delnp-2008-Abstract-(24-12-2013).pdf

8156-delnp-2008-abstract.pdf

8156-delnp-2008-Claims-(24-12-2013).pdf

8156-delnp-2008-claims.pdf

8156-delnp-2008-Correspondence Others-(24-12-2013).pdf

8156-delnp-2008-correspondence-others.pdf

8156-delnp-2008-description (complete).pdf

8156-delnp-2008-Drawings-(24-12-2013).pdf

8156-delnp-2008-drawings.pdf

8156-delnp-2008-form-1.pdf

8156-delnp-2008-form-2.pdf

8156-delnp-2008-Form-3-(24-12-2013).pdf

8156-delnp-2008-form-3.pdf

8156-delnp-2008-form-5.pdf

8156-delnp-2008-GPA-(24-12-2013).pdf

8156-delnp-2008-pct-101.pdf

8156-delnp-2008-pct-210.pdf

8156-delnp-2008-pct-304.pdf

8156-delnp-2008-Petition-137-(24-12-2013)-1.pdf

8156-delnp-2008-Petition-137-(24-12-2013).pdf

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Patent Number

259741

Indian Patent Application Number

8156/DELNP/2008

PG Journal Number

13/2014

Publication Date

28-Mar-2014

Grant Date

26-Mar-2014

Date of Filing

29-Sep-2008

Name of Patentee

PRAXAIR TECHNOLOGY, INC.,

Applicant Address

39 OLD RIDGEBURY ROAD, DANBURY, STATE OF CONNECTICUT 06810-5113, U.S.A

Inventors:

#	Inventor's Name	Inventor's Address
1	RAVI KUMAR	153 WEDGEWOOD DRIVE, WILLIAMSVILLE, NY 14221, U.S.A

PCT International Classification Number

B01D 53/047

PCT International Application Number

PCT/US2007/007758

PCT International Filing date

2007-03-28

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	11/395,139	2006-04-03	U.S.A.