Title of Invention

RECOVERY OF AROMATIC DICARBOXYLIC ACIDS FROM WASTE POLYESTER RESIN IN THE PRESENCE OF A POLYAMIDE

Abstract

Abstract RECOVERY OF AROMATIC DICARBOXYLIC ACIDS FROM WASTE POLYESTER RESIN IN THE PRESENCE OF A POLY AMIDE The present invention relates to a process of recovering aromatic dicarboxylic acids with low metal contaminants from manufactured articles, such as beverage bottles, fibers and films, comprising aromatic polyesters, whether or not those articles are contaminated with PVC or chlorinated compounds, or from waste from processing of these polyesters. In particular, the invention relates, to the recovery of terephthalic acid, isophthalic acid and 2, 6 -naphthalene dicarboxylic acid from bottles for recycling which are made of PET, PEN or aromatic polyester copolymers.

Full Text

RECOVERY OF AROMATIC DICARBOXYLIC ACIDS FROM WASTE POLYESTER RESIN IN THE PRESENCE OF A POLYAMIDE Background Producers of polyethylene terephthalate and its copolymers, collectively known as PET, have already developed processes for recycling PET scrap from polyester film, fiber and bottle production. The methods for recovering terephthalic acid and ethylene glycol from PET are based on depolymerization, for example by hydrolysis under conditions of neutral pH or in the presence of acids or bases, by acetolysis, methanolysis or glycolysis. U.S. Patent No. 6,670,503 describes a method of recovering terephthalic acid from PET in the absence of water, with a reagent consisting of one or more metal salts of an acid weaker than terephthalic acid, until a water-soluble compound is obtained, then subsequently carrying out dissolution in water and acidification. According to United States Patent No. 6,239,310, PET is heated in an aqueous solution at temperatures from 150 °C to 1280C with a reagent substance chosen from the group comprising bicarbonates of ammonia and alkali metals, ammonitim carbamate and urea. In United States Patent No. 6,545,061, a process is disclosed for depolymerizing and purifying recyclable PET comprising. acetolysis to form terephthalic acid and ethylene glycol diacetate. United States Patent No. 6,562,877 claims a process for depolymerizing recycled colored and contaminated aromatic PET articles with acceptable color characteristics, by depolymerizing said recycled articles in acetic acid at high temperatures (160 - 250 °C) . United States Patent No. 6,723,873 discloses a process for recovering terephthalic acid from PET by aramoniolysis. In this process, PET is reacted with ammonium hydroxide to fonrm diammonium terephthalate which is then converted to terephthalic acid by heating at a temperature from about 225 °C to about 300 °C. Depolymerization of PET by hydrolysis at a high temperature and pressure in the absence of a base or acid, is known, see for example United States Patent No. 4,587,502, or United States Patent No. 4,605,762. Although various processes are available for hydrolyzing PET waste, the purification of recovered terephthalic acid typically requires several process steps to remove dyes, pigments and other impurities including inorganic compounds and salts. In addition, recrystallization and hydrogenation over noble metal catalysts are usually used to purify terephthalic acid. Starting materials for making terephthalic acid include such things as mixtures of polyester film, fiber and PET bottle waste. This raw material can also contain metals, labels, lighter plastics, glass, rock and other heavy impurities. These contaminants are removed by such pretreatment processes as skimming or decantation. Depending on the types of contaminants present, bulk solids can also be separated after the hydrolysis process. In a hydrolysis process, PET scrap ground into small particles is dfepolymerized at temperatures ranging from about 230 ^C to about 300 °C and usually at pressures sufficient to maintain a liquid phase. Recycled PET waste used as feed to the hydrolysis process often contains traces of corrosion product, e.g. PVC (50 - 2 00 ppm) , metal chlorides, or halogen containing compounds which at the temperature of PET hydrolysis decompose to very corrosive chlorine and/or halogen compounds which attack the reactor. Since the PVC contaminants of the recycled articles can not be absolutely excluded, the hydrolytic processes must use expensive titanivtm based equipment to avoid corrosion and high metal content and discoloring of the produced terephthalic acid. Summary of the invention This specification discloses a method of recovering aromatic dicarboxylic acids from aromatic polyester resins containing less than 2 500 ppm of halogen containing compounds, comprising the step of depolymerizing the aromatic polyester resin in the presence of water at temperatures in the range of 230 "C to 300 °C wherein the reaction occurs in the presence of 1.0 to 10 wt % of a polyamide wherein the polyamide is selected from the group consisting of the repeating unit of amino caproic acid and the reaction product of A and D, wherein A is a residue of a dicarboxylic acid comprising adipic acid, isophthalic acid, terephthalic acid, 1,4-cyclohexanedicarboxylic acid, or naphthalene dicarboxylic acid, and D is a residue of a diamine' comprising m-xylylene diamine, p-xylylene diamine, hexamethylene diamine, ethylene diamine, or 1,4 cyclohexanedimethylamine. It is further disclosed that the depolymerization reaction proceed in the presence of 1 to 8 wt % of -activated charcoal calculated to the amount of polyester resin. It is also disclosed that the depolymerized material may be subsequently passed through a fixed-bed adsorber filled with activated charcoal at a temperature in the range of 50 "C below the depolymerization temperature to the depolymerization temperature. It is further disclosed that the ratio of the amount of water at the end of depolymerization to the amount of aromatic polyester resin present in the reaction mixture is between 4 : 1 to 10 : 1 and that the amount the water at the beginning of the reaction may optionally contain ethylene glycol at an amount less than or equal to 10 weight percent with respect to the water plus ethylene glycol mixture. It is further disclosed that the aromatic dicarboxylic acid can be separated from the reaction mixture cooled to the temperature in the range from 180 to 90 °C. Detailed description It has been found that it is possible to produce terephthalic acid with metal contents below 10 ppm using a) the neutral hydrolytic depolymerization of PET waste containing less than 2,500 ppm of halogen containing compounds, b) a stainless steel reactor, c) the presence of 1.0 to 10 wt % of polyamide calculated to PET(in particular aliphatic based polyamides such as PA 6, PA 66, and polyamides based on MXDA as amine components, most notably MXD6 and PET/MXD6 blends or polyester polyamides) . The hydrolytic depolymerization of PET waste proceeds usually in one step at temperatures between 230 "C and 300 °C, preferably at 260 - 275 °C and at a pressure sufficient to maintain a liquid phase. To avoid the purification of recovered terephthalic acid, the hydrolytic depolymerization of PET is performed in the presence of activated charcoal (1 - 7 wt % to PET) or the reaction mixture is passed through a fixed-bed adsorber filled with granulated activated charcoal after the depolymerization reaction. The disclosed process is for recovering terephthalic acid from waste polyester film, fiber, bottles, manufacturing residues and other manufactured articles, which contain less than 2,500 ppm of corrosion compoiuids, e.g. PVC, metal chlorides, halogenated compounds. In the preferred embodiment, material waste such as PET is broken into chips or fragments that may be produced from mixtures of articles of different colors and different origin including articles made of or containing polyester resin mixed with polyamides such as poly (m-xylylene adipamide) or other polymers. Of particular interest are those articles in the form of multi-layer films or multi-layer bottles in.which at least one layer is made of co(polyalkylene terephthalate) and one layer is made of poly (m-xylylene adipamide), or mixtures thereof with polyalkylene terephthalate. The polyamides suitable for this invention can be described as comprising the repeating unit of amino caproic acid or A-D, wherein A is the residue of a dicarboxylic acid comprising adipic acid, isophthalic acid, terephthalic acid, 1,4-cyclohexanedicarboxylic acid, or naphthalene dicarboxylic acid, and D is a residue of a diamine comprising m-xylylene diamine, p-xylylene diamine, hexamethylene diamine, ethylene diamine, or 1,4 cyclohexanedimethylamine. These polyamides can also be described as the comprising at least one reaction product selected from the group consisting of the reaction product of amino caproic acid with itself and/or the reaction product of a residue of a dicarboxylic acid comprising adipic acid, isophthalic acid, terephthalic acid, 1,4-cyclohexanedicarboxylic acid, or naphthalene dicarboxylic acid with a residue of a diamine comprising m-xylylene diamine, p-xylylene diamine, hexamethylene diamine, ethylene diamine, or 1,4 eyelohexanedimethylamine. Those skilled in the art will recognize many of the combinations as well known commercially available polyamides. The reaction product of the residue of sebacic acid with hexamethylene diamine is nylon 6.10 and the reaction product of the residue of adipic acid and hexamethylene diamine is nylon 6.6. Nylon 6.12 is another nylon which benefits from the invention. Nylon 6 is a special type of polyamide having the formula of H2N-(CH2) 5-COOH and is made by the opening of caprolactam ring and then reacting' or polymerizing the resulting amino caproic acid with itself. Although nylon 6 is a preferred polyamide polymer, the most preferred polyamide polymer is the reaction product of the residues of adipic acid and m-xylylene diamine, known as poly-m-xylylene adipamide. This product is commercially known as MXD6 or nylon MXD6. The reaction is preferably carried out in a stainless steel reactor for 30 - 120 minutes and can be performed continuously or discontinuously. The hydrolytic depolymerization may be conducted in water, mixtures of ethylene glycol and water (up to 10 wt %), or steam which is purged into the reaction system. The weight ratio of PET/water is from 1 : 4 to 1 : 10, preferably 1 : 5 to 1 : 7. The depolymerization process can be carried out in air or more preferably inert gas, which is most preferred. The produced terephthalic acid is separated from the liquid phase by conventional methods, for example after cooling by filtration. Terephthalic acid prepared according to the present invention contain no polyamides or amino compounds in detectable amounts. The iron content is below 10 ppm. The L* color parameters of recovered terephthalic acid samples prepared, even those prepared from the mixture of green, blue and brown colored PET waste, are above 82 - 84. The following examples illustrate but do not limit the scope of the present invention. Example 1 270 g of colored PET bottle scrap, 3.25 wt % of poly(m-xylylene adipamide) , 350 ppm of iron compounds and inorganic salts, and 1,700 g deionized water were weighed into a 3 1 stainless steel rocking autoclave. Inside the reactor, a basket was filled with 20 g of granulated (0.6 - 0.7 mm) activated charcoal. The reactor was twice purged with nitrogen and heated at 270 ^C for 90 minutes. After cooling to approximately 90 "C, the resultant terephthalic acid was separated by filtration and then filter washed (3 x 300 ml) with warm (approximately 75 'C) deionized water. The product was dried in an oven overnight at 95 ^C. Terephthalic acid was obtained in 89.8 % mol yield and contained 4.6 ppm of iron. Comparative experiment 1 The procedure of Example 1 was repeated, except that 270 g of recycled clear PET without the polyamide was used. The resultant terephthalic acid contained 31.7 ppm of iron. Comparative experiment 2 27 g of other sources PET scrap and 150 g deionized water was weighed into a 250 ml stainless steel rocking autoclave. Inside the reactor a basket was filled with 0.5 g of granulated (0.6 - 0.7 mm) activated charcoal. The reactor was twice purged with nitrogen and heated at 270 "C for 50 minutes. Terephthalic acid isolated by filtration, washed with ca. 75 »C deionized water ( 3 x 50 ml) and dried at 95 °C overnight contained 35.3 ppm of iron. Example 2 The procedure of comparative experiment 2 was repeated except that 0.70 g PVC (2590 ppm) and 1.35 g polyamide MXD6 was added. The recycled terephthalic acid contained 9.5 ppm of iron. Example 3 The procedure of example 2 was repeated except that no PVC was added. The isolated terephthalic acid contained 8.34 ppm of iron. The results of Experiments 2 and 3 clearly demonstrate the positive effects of polyamide on the content of iron in the recovered terephthalic acid, even in the presence of huge concentrations of PVC in the depolymerization process. Example 4 The procedure of Example 1 was repeated 22 times. The average yield of recovered terephthalic acid was 89.3 mol %. All samples were homogenized and the resulting mixture analyzed for metal and nitrogen content. The resultant terephthalic acid contained 7.1 ppm of iron. The content of nitrogen is below 0.1 ppm and the color parameters are L* = 82.68, a* = -1.46 and b* = 4.96. Example 5 The procedure of Comparative Experiment 2 was repeated except that 27 g of PET as in Comparative Experiment 1 and 150 g of water containing 3.6 wt % of ethylene glycol was used. The recovered terephthalic acid contained 46.4 ppm of iron. Example 6 The procedure of Example 5 was repeated except that 0.20 g of PVG (740 ppm) and 1.25 g of polyamide MXD6 was used. The resultant terephthalic acid contained 9.7 ppm of iron. CLAIMS We claim 1. A method of recovering aromatic dicarboxylic acids from aromatic polyester resins containing less than 2 500 ppra of halogen containing compounds, comprising the step of depolymerizing the aromatic polyester resin with water at temperatures in the range of 230 "C to 300 °C wherein the depolymerization reaction occurs in the presence of a polyamide wherein the polyamide is selected from the group consisting of the repeating unit of amino caproic acid and the reaction product of A and D, wherein A is a residue of a dicarboxylic acid comprising adipic acid, isophthalic acid, terephthalic acid, 1,4-cyclohexanedicarbpxylic acid, or naphthalene dicarboxylic acid, and D is a residue of a diamine comprising iti-xyXylene diamine, p-xylylene diamine, hexamethylene diamine, ethylene diamine, or 1,4 cyclohexanedimethylamine. 2. A method according to claim 1, wherein the polyamide is present in the range of 0,1 to 10 weight percent. 3. A method according to claims 1 or 2, in which the depolymerization proceeds in the presence of 1 to 8 wt % of activated charcoal calculated to the amount of polyester resin. 4. A method according to claims 1 or 2, in which the reaction mixture is passed through a fixed-bed adsorber filled with activated charcoal at a temperature in the range of 50 "C below the depolymerization temperature of the polyester with water and the depolymerization temperature of the polyester with water. 5. A method according to claims 1 or 2, in which the ratio of the amount of water at the end of the depolymerization to the amount of aromatic polyester resin present in the reaction mixture is between 4 : 1 to 10 : 1. 6. A method according to claim 4, in which the water at the beginning of the reaction contains ethylene glycol at an amount less than or equal to 10 weight percent with respect to the water plus ethylene glycol mixture. 7. A method according to claim 5, wherein the aromatic dicarboxylic acid is separated from the reaction mixture cooled to the temperature in the range from 180 to 90 °C.

Documents:

5952-CHENP-2008 CORRESPONDENCE OTHERS 05-06-2013.pdf

5952-CHENP-2008 AMENDED CLAIMS 07-02-2014.pdf

5952-CHENP-2008 AMENDED PAGE OF SPECIFICATION 07-02-2014.pdf

5952-CHENP-2008 FORM-1 07-02-2014.pdf

5952-CHENP-2008 FORM-3 07-02-2014.pdf

5952-CHENP-2008 OTHER PATENT DOCUMENT 07-02-2014.pdf

5952-CHENP-2008 OTHER PATENT DOCUMENT-1 07-02-2014.pdf

5952-CHENP-2008 OTHERS 07-02-2014.pdf

5952-CHENP-2008 POWER OF ATTORNEY 07-02-2014.pdf

5952-chenp-2008 abstract.pdf

5952-chenp-2008 claims.pdf

5952-chenp-2008 correspondance others.pdf

5952-chenp-2008 correspondence others.pdf

5952-chenp-2008 description (complete).pdf

5952-CHENP-2008 EXAMINATION REPORT REPLY RECEIVED 07-02-2014.pdf

5952-chenp-2008 form-1.pdf

5952-chenp-2008 form-18.pdf

5952-chenp-2008 form-3.pdf

5952-chenp-2008 form-5.pdf

5952-chenp-2008 pct.pdf