Title of Invention

ABSORPTION CHILLER-HEATER

Abstract An absorption chiller-heater is disclosed wherein an absorbing solution and a refrigerant are circulated through a high-temperature regenerator (1), a condenser (4), an evaporator (5) and an absorber (6), interconnected by pipes and a heat operation medium cooled or heated as a result of having passed through a heat transfer pipe disposed in the interior of said evaporator (6) is supplied to an air conditioning load to effect cooling or heating, said absorption chiller-heater comprising: a level detector; an absorbing solution pump; and a control unit, characterized in that when said level detector detects a predetermined lower-limit level of the absorbing solution, said absorbing solution pump is operated for a predetermined time at high speed to increase the amount of the absorbing solution to be fed into said high-temperature regenerator (1), then when said predetermined time has been reached or elapsed, it is determined whether said level detector detects said predetermined lower-limit level of the absorbing solution, and if the level detector detects again the predetermined lower-limit level of the absorbing solution, both or one issuance of sounding of a warning and stop of operation of the absorption chiller-heater are/is performed so as to warn that the predetermined lower-limit level re-detected depends on a continuous drop in normal state not temporary drop.
Full Text

BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to an absorption type cold/hot water machine, in
other words, an absorption chiller-heater. Particularly, the present invention is concerned
with a technique wherein the operation of an absorbing solution pump for feeding a dilute
absorbing solution from an absorber to a high-temperature regenerator is controlled in
accordance with the level of the absorbing solution present in the high-temperature
regenerator.
Description of the Related Art
As a conventional method for coping with an abrupt change of load,
particularly for remedying a lowering in the coefficient of performance of a
cooling load there is known a method wherein an absorbing solution pump
for feeding as a dilute absorbing solution from an absorber into a high-
temperature regenerator is inverter-controlled in accordance with an
absorbing solution level detector signal indicative of the level of the
absorbing solution in the high-temperature regenerator, thereby matching
the flow rate of the absorbing solution with the cooling load to avoid
frequent ON-OFF of the absorbing solution pump caused by an abrupt
change of the liquid level in the high-temperature regenerator and stabilize
the operation of an absorption refrigerating machine (see, for example,
Patent Document: Japanese Patent Laid-Open Publication No. Hei 3(1991)-
28674).
An absorption type cold/hot water machine sometimes has a case
where an absorbing solution level detector detects a lower-limit value or less
of the absorbing solution level due to such an unusual state as a temporary
marked change of the absorbing solution level in a high-temperature

regenerator caused for example by a boiling state of the high-temperature
regenerator resulting from for example an abrupt change of a cooling load at
the time of start-up or during operation of the machine. Even in case of
having detected such a temporary drop of the absorbing solution level, an
absorbing solution pump is inverter-controlled as described above without
issuing an immediate warning of a state of boil-dry or stopping the
operation of the machine, and when the cooling load decreases, the level of
the absorbing solution rises rapidly, but the absorbing solution pump is
operated at a low frequency to avoid a marked rise of the absorbing solution
level and cause the level to drop to a predetermined level. When the
cooling load increases, the level of the absorbing solution drops rapidly, but
the absorbing solution pump is operated at a high frequency to avoid a
marked drop of the absorbing solution level and cause the level to rise up to
a predetermined level.
In the event there occurs an abrupt change of the absorbing solution
level due to such an unusual state, a considerable time of about 5 to 10
minutes is taken until the absorbing solution level reaches the
predetermined level by inverter-control of the absorbing solution pump, so
there is a fear that the high-temperature regenerator may assume a state of
boil-dry. Therefore, it is necessary to check as soon as possible whether the
abrupt drop of the absorbing solution level is caused by the unusual state
mentioned above or the absorbing solution level has dropped to the lower
limit or less as a result of an increase of the cooling load in normal operation.
SUMMARY OF THE INVENTION
According to the present invention, in view of the above-mentioned
point, it is detected quickly whether the drop of the absorbing solution level
in the high-temperature regenerator to the lower limit or less is temporary





or a drop in normal state, then if the drop is detected to be a temporary drop,
the operation of the absorption type cold/hot water machine is continued,
while if the drop is detected to be a continuous drop, there issues a warning
that the machine is in a state of boil-dry, and at the same time the operation
of the machine is stopped, thus making an appropriate boil-dry safety
control.
In a first aspect of the present invention there is provided an
absorption type cold/hot water machine wherein an absorbing solution and a
refrigerant are circulated through a high-temperature regenerator, a
condenser, an evaporator, an absorber, and so on, interconnected by pipes
and a heat operation medium cooled or heated as a result of having passed
through a heat transfer pipe disposed in the interior of the evaporator is
supplied to an air conditioning load to effect cooling or heating, the
absorption type cold/hot water machine comprising a level detector for
detecting the level of the absorbing solution in the high-temperature
regenerator, an absorbing solution pump for feeding a dilute absorbing
solution from the absorber into the high-temperature regenerator, and a
control unit for controlling the operation of the absorbing solution pump on
the basis of the detection made by the level detector, characterized in that
when the level detector detects a predetermined lower-limit level of the
absorbing solution, the absorbing solution pump is operated at high speed
for a predetermined time to increase the amount of the absorbing solution to
be fed into the high-temperature regenerator, then when the predetermined
time has been reached or elapsed, it is determined whether the level
detector detects the predetermined lower-limit level of the absorbing
solution, and if the level detector detects the predetermined lower-limit level
of the predetermined lower-limit, both or one issuance of sounding of a
warning and stop of operation of the absorption type cold/hot water machine


are (is) performed.
In a second aspect of the present invention there is provided an
absorption type cold/hot water machine wherein an absorbing solution and a
refrigerant are circulated through a high-temperature regenerator, a
condenser, an evaporator, an absorber, and so on, interconnected by pipes
and a heat operation medium cooled or heated as a result of having passed
through a heat transfer pipe disposed in the interior of the evaporator is
supplied to an air conditioning load to effect cooling or heating, the
absorption type cold/hot water machine comprising a level detector for
detecting the level of the absorbing solution in the high-temperature
regenerator, an absorbing solution pump for feeding a dilute absorbing
solution from the absorber into the high-temperature refrigerator, a
temperature detector for detecting the temperature of the high-temperature
refrigerator, and a control unit of an inverter control type adapted to change
the frequency in the range from a low frequency to a high frequency on the
basis of the detection made by the temperature detector and change the
number of revolutions of the absorbing solution pump, characterized in that
when the level detector detects a predetermined lower-limit level of the
absorbing solution, the absorbing solution pump is operated at a
predetermined high frequency for a predetermined time, then when the
predetermined time has been reached or elapsed, it is determined whether
the level detector detects the predetermined lower-limit level of the
absorbing solution, and if the level detector detects the predetermined
lower-limit level, both or one issuance of sounding of a warning or stop of
operation of the absorption type cold/hot water machine are (is) performed.
In a third aspect of the present invention there is provided an
absorption type cold/hot water machine wherein an absorbing solution and a
refrigerant are circulated through a high-temperature regenerator, a


condenser, an evaporator, an absorber, and so on, interconnected by pipes
and a heat operation medium cooled or heated as a result of having passed
through a heat transfer pipe disposed in the interior of the evaporator is
supplied to an air conditioning load to effect cooling or heating, the
absorption type cold/hot water machine comprising a level detector for
detecting the level of the absorbing solution in the high-temperature
regenerator, an absorption solution pump for feeding a dilute absorbing
solution from the absorber into the high-temperature regenerator, a
temperature detector for detecting the temperature of the high-temperature
regenerator, and a control unit of an inverter control type adapted to change
the frequency in the range from a low frequency to a high frequency on the
basis of the detection made by the temperature detector and change the
number of revolutions of the absorbing solution pump, characterized in that
when the level detector detects a predetermined lower-limit level of the
absorbing solution, the absorbing solution pump is operated at a
predetermined high frequency for the predetermined time and a rise of
temperature detected by the temperature detector is measured, then when
the predetermined time has been reached or elapsed and when the
temperature rise is a predetermined value or more and the level detector
detects the predetermined lower-limit level of the absorbing solution, both
or one issuance of sounding of a warning and stop of operation of the
absorption type cold/hot water machine are (is) performed.
In a fourth aspect of the present invention there is provided an
absorption type cold/hot water machine comprising an absorbing solution
pump for circulating an absorbing solution and a refrigerant through a high-
temperature regenerator, a condenser, an evaporator, an absorber, and so on,
interconnected by pipes and for feeding a dilute absorbing solution from the
absorber into the high-temperature regenerator and a control unit of an


inverter control type adapted to change the frequency in the range from a
low frequency to a high frequency on the basis of detection of the
temperature of the absorbing solution in the high-temperature regenerator
and change the number of revolutions of the absorbing solution pump, a
heat operation medium being supplied to an air conditioning load to effect
cooling or heating, the heat operation medium being in a cooled or heated
state as a result of having passed through a heat transfer pipe disposed in
the interior of the evaporator, characterized in that a level detector for
detecting the level of the absorbing solution in the high-temperature
regenerator and a temperature detector for detecting the temperature of
exhaust gas discharged from the high-temperature regenerator are provided,
and when the level detector detects a predetermined lower-limit level of the
absorbing solution, the absorbing solution pump is operated at a
predetermined high frequency for the predetermined time and a rise of the
exhaust gas temperature detected by the temperature detector is measured,
then when the predetermined time has been reached or elapsed and when
the temperature rise is a predetermined value or more and the level
detector detects the predetermined lower-limit level of the absorbing
solution, both or one issuance of sounding of a warning and stop of operation
of the absorption type cold/hot water machine are (is) performed.
According to the first aspect of the present invention described above,
when the absorbing level detector detects the predetermined lower-limit
level of the absorbing solution due to a temporary marked change of the
absorbing solution level in the high-temperature regenerator caused for
example by a boiling state of the high-temperature regenerator resulting
from for example a change of a cooling load at the time of start-up or during
operation of the absorption type cold/hot water machine, the liquid level can
be returned to its normal level quickly by a high-speed operation of the


absorbing solution pump. Thus, it is possible to make a quick and accurate
determination without need of waiting for a long time for a natural recovery
from the temporarily dropped liquid level. Therefore, it is possible to
prevent malfunctions caused by a temporary drop of the liquid level, such as
sounding of a warning and/or stop of operation of the absorption type
cold/hot water machine. In the event the level of the absorbing solution
drops to the lower-limit value or less in normal operation, a control is made
for issuing a warning and/or stop of operation of the machine, whereby it is
possible to make the boil-dry protection of the high-temperature regenerator.
According to the second aspect of the present invention mentioned
above there is made an inverter control such that the number of revolutions
of the absorbing solution pump can be changed in the range from a low
frequency to a high frequency, so when the level detector detects the
predetermined lower-limit level of the absorbing solution, the absorbing
solution pump is fully operated at a predetermined high frequency for a
predetermined time, whereby it is possible to effect recovery up to the
normal liquid level quickly. Thus, it is possible to make a quick and
accurate determination without need of waiting for a long time for the
natural recovery from such a temporary drop of the liquid level. Therefore,
it is possible to prevent malfunctions caused by a temporary drop of the
liquid level, such as sounding of a warning and stop of operation of the
absorption type cold/hot water machine. At the same time, when the level
of the absorbing solution drops the lower-limit level or less, a control is
made to issue a warning and/or stop of the operation of the machine,
whereby it is possible to make the boil-dry protection of the high-
temperature regenerator.
According to the third aspect of the present invention mentioned
above, in addition to the second aspect, a rise in temperature of the


absorbing solution in the high-temperature regenerator is measured, and
when it is the predetermined value or more, it indicates an abnormal state.
Therefore, when the temperature rise is equal to or above the
predetermined value and the level detector detects the predetermined lower-
limit level of the absorbing solution, the high-temperature regenerator is in
a state of boil-dry due to a solution level drop. At this time, there issues a
boil-dry warning and/or the operation of the absorption type cold/hot watrer
machine is stopped, thereby informing a worker that the warning is of the
state of boil-dry and hence permitting the worker to make appropriate
inspection and protection.
According to the fourth aspect of the present invention mentioned
above, in addition to the second aspect, a rise in temperature of the high-
temperature regenerator is measured, when a rise in temperature of
exhaust gas discharged from the high-temperature regenerator is the
predetermined value or more, it indicates an abnormal state. Therefore,
when this temperature rise is equal to or above the predetermined value
and the level detector detects the predetermined lower-limit level of the
absorbing solution, the high-temperature regenerator is in a state of boil-dry
due to a solution level drop. At this time, there issues a boil-dry warning
and/or the operation of the absorption type cold/hot water machine is
stopped, thereby informing a worker that the warning is of the state of boil-
dry and permitting the worker to make and
protection.
BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS
Fig. 1 is a schematic configuration diagram of an absorption type
cold/hot water machine according to the present invention (the first
embodiment);


Fig. 2 is a control flow chart according to the first and second aspects
of the present invention (the first embodiment);
Fig. 3 is a diagram showing a temperature - frequency relation for
inverter-controlling an absorbing solution pump according to the present
invention (the first embodiment);
Fig. 4 is a control flow chart according to the third and fourth
aspects of the present invention (the second and the third embodiments);
and
Fig. 5 is a diagram showing a temperature rise detected by a
temperature detector according to the third and fourth aspects of the
present invention (the second and the third embodiments).
DESCRIPTION OF THE PREFERRED EMBODIMENT
In the absorption type cold/hot water machine according to the
present invention, an absorbing solution and a refrigerant are circulated
through a high-temperature regenerator, a condenser, an evaporator, an
absorber, and so on, interconnected by pipes and a heat operation medium
cooled or heated as a result of having passed through a heat transfer pipe
disposed in the interior of the evaporator is supplied to an air conditioning
load to effect cooling or heating. The absorption type cold/hot water
machine includes a level detector for detecting the level of the absorbing
solution in the high-temperature regenerator, an absorbing solution pump
for feeding a dilute absorbing solution from the absorber into the high-
temperature regenerator, and a control unit for controlling the operation of
the absorbing solution pump on the basis of the detection made by the level
detector. According to the absorption type cold/hot water machine, when
the level detector detects a predetermined lower-limit level of the absorbing
solution, the absorbing solution pump is operated at high speed for a


predetermined time to increase the amount of the absorbing solution to be
fed into the high-temperature regenerator, then when the predetermined
time has been reached or elapsed, it is determined whether the level
detector detects the predetermined lower-limit level of the absorbing
solution, and if the level detector detects the predetermined lower-limit level
of the absorbing solution, both or one issuance of sounding of a warning and
stop of operation of the absorption type cold/hot water machine are (is)
performed. Embodiments of the present invention will be described
hereunder.
An absorption type cold/hot water machine according to an
embodiment of the present invention will be described below. Fig. 1 is a
schematic configuration diagram of the absorption type cold/hot water
machine, Fig. 2 is a control flow chart related to the first and the second
aspects of the present invention, and Fig. 3 illustrates a temperature
frequency relation for inverter-controlling an absorbing solution pump.
An embodiment of the present invention will now be described. Fig.
1 schematically illustrates the configuration of an absorption type cold/hot
water machine P using water as a refrigerant and lithium bromide (LiBr) as
an absorbing solution. A high-temperature regenerator 1 is configured so
as to heat a dilute solution containing both absorbing solution and
refrigerant with heat of a gas burner 2 which uses, for example, city gas as
fuel, allowing the refrigerant to evaporate and thereby causing the
absorbing solution and the refrigerant to become separated from each other.
Numeral 3 denotes a low-temperature regenerator, numeral 4 denotes a
condenser, 5 an evaporator, 6 an absorber, 7 a low-temperature heat
exchanger, 8 a high-temperature heat exchanger, numerals 9 to 11 denote
absorbing solution pipes, numeral 12 denotes an absorbing solution pump
having a mechanism such that its pump section is rotated by an electric


motor, numerals 13 to 15 denote refrigerant pipes, 16 a refrigerant pump, 17
a cold/hot water pipe, 18 a cooling water pipe, 19 a gas supply pipe for the
supply of gas to the gas burner 2, numeral 20 denotes a fuel valve for
controlling the amount of gas to be supplied to the gas burner 2, numeral 21
denotes a temperature detector attached to an output pipe 17B of the
cold/hot water pipe 17 for detecting the temperature of cold or hot water
flowing out from the outlet pipe 17B, and numeral 22 denotes a burner
controller for controlling the degree of opening of the fuel valve 20 in
accordance with the result of temperature detection made by the
temperature detector 21. Numeral 23 denotes a blower for feeding air into
the gas burner 2 and numeral 24 denotes an igniter for igniting the gas in
the gas burner 2.
Numeral 25 denotes a second absorbing solution pump, numerals 26,
27 and 28 denote opening/closing valves, numeral 29 denotes a temperature
detector for detecting the temperature of the absorbing solution in the high-
temperature regenerator 1, numeral 30 denotes a level detector for detecting
the level of the absorbing solution in the high-temperature regenerator 1,
numeral 31 denotes a temperature detector for detecting the temperature of
exhaust gas of the high-temperature regenerator, numeral 32 denotes an
inverter controller for inverter-controlling the absorbing solution pump 12,
and numeral 33 denotes a control unit including both burner controller 22
and inverter controller 32 to control the operation of the absorption type
cold/hot water machine P. The control unit 33 further includes an MPU
(microprocessor unit), a ROM for the storage of programs, a RAM for the
storage of data such as temperature data, and an input/output interface
serving as communication means, to control the operation of the absorption
type cold/hot water machine P.
The absorption type cold/hot water machine P is operated


switchingly between a cooling operation of taking out cold water from the
outlet pipe 17B of the cold/hot water pipe 17 and a heating operation of
taking out hot water from the outlet pipe 17B. In the cooling operation, the
opening/closing valves 26, 27 and 28 are closed, allowing cooling water to
flow through the cooling water pipe 18, and the gas burner 2 is ignited by
the igniter 24 to heat the absorbing solution in the high-temperature
regenerator 1, whereby there are obtained refrigerant vapor separated by
evaporation from the absorbing solution and an intermediate absorbing
solution increased in condensation after separation of the refrigerant vapor.
The refrigerant vapor of a high temperature produced in the high-
temperature regenerator 1 passes through the refrigerant pipe 13 and
enters the low-temperature regenerator 3 to heat the intermediate
absorbing solution having been produced in the high-temperature
regenerator 1 and entered the low-temperature regenerator 2 through the
high-temperature heat exchanger 8 by the absorbing solution pipe 10, thus
radiates heat, condenses and enters the condenser 4. On the other hand,
the refrigerant having been heated in the low-temperature regenerator 3
and evaporated off from the intermediate absorbing solution gets into the
condenser 4, heat-exchanges with water flowing through the interior of the
heat transfer pipe ISA from the cooling water pipe 18, thereby condenses
into liquid, then passes through the refrigerant pipe 14 together with the
condensed refrigerant supplied from the refrigerant pipe 13, and enters the
evaporator 5.
The refrigerant liquid having entered the evaporator 5 and
accumulated in a refrigerant sump formed in the bottom of the evaporator is
sprinkled by the refrigerant pump 16 over a heat transfer pipe 17A
connected to the cold/hot water pipe 17, then heat-exchanges with water
which is supplied through the cold/hot water pipe 17, thereby evaporates


and cools water flowing through the interior of the heat transfer pipe 17A.
The refrigerant evaporated in the evaporator 5 enters the absorber 6 and is
absorbed by the absorbing solution whose condensation has been further
increased by being heated in the low-temperature regenerator 3 to
evaporate off the refrigerant, i.e., the condensed absorbing solution which is
supplied from the absorbing solution pipe 11 through the low-temperature
heat exchanger 7 by the pump 25 and sprinkled from above. The absorbing
solution whose condensation has been decreased by absorbing the
refrigerant in the absorber 6, i.e., a dilute absorbing solution, is fed from the
absorbing solution pipe 9 to the high-temperature regenerator 1 through the
low-temperature heat exchanger 7 and the high-temperature heat
exchanger 8 by the operation of the absorbing solution pump 12.
With the operation of the absorption type cold/hot water machine
performed in the above-mentioned manner, if cold water which has been
cooled by the heat of vaporization of the refrigerant in the heat transfer pipe
17A disposed in the interior of the evaporator 5 is supplied circulatively to
an indoor unit (not shown) through the outlet pipe 17B of the cold/hot water
pipe 17, it is possible to perform a cooling operation.
On the other hand, for a heating operation, the opening/closing
valves 26, 27 and 28 are opened, then the gas burner 2 is ignited by the
igniter 24 without flowing cooling water into the cooling water pipe 18, and
the dilute absorbing solution is heated in the high-temperature regenerator
1. As a result, the refrigerant evaporated from the dilute absorbing
solution in the high-temperature regenerator 1 passes mainly through a
refrigerant pipe 13A of a low channel resistance from an intermediate
position of the refrigerant pipe 13, enters the absorber 6 and the evaporator
5, then heat-exchanges through the heat transfer pipe 17A with water
supplied from the cold/hot water pipe 17 and condenses thereby. Mainly


with the resulting condensation heat, the water flowing through the interior
of the heat transfer pipe 17A is heated.
The refrigerant condensed after heating in the evaporator 5 is fed
from the refrigerant sump formed in the bottom of the evaporator 5 into the
absorber 6 through the opening/closing valve 28 by means of the refrigerant
pump 16, then is mixed with the absorbing solution which flows into the
absorber 6 through the opening/closing valve 27 after evaporation and
separation of the refrigerant in the high-temperature regenerator 1, then by
operation of the absorbing solution pump 12 the resulting mixture is fed
from the absorbing solution pipe 9 into the high-temperature regenerator 1
through the low-temperature heat exchanger 7 and the high-temperature
heat exchanger 8.
Hot water heated by the heat transfer pipe 17A in the interior of the
evaporator 5 is supplied circulatively to the indoor unit (not shown) through
the outlet pipe 17B of the cold/hot water pipe 17, whereby a heating
operation is performed.
The control unit 33 controls the operation of the absorbing solution
pump 12 in accordance with the result of detection made by the level
detector 30. When the level detector 30 detects the lower-limit level or less
of the absorbing solution, the absorbing solution pump 12 is operated at
high speed for a predetermined time to increase the amount of the absorbing
solution fed into the high-temperature regenerator 1. Then, upon arrival
at or lapse of the predetermined time, the control unit 33 determines
whether the detector 30 is detecting the lower-limit level or less of the level
absorbing solution, When the detector 30 is detecting the lower-limit level
or less of the level of the absorbing solution, the control unit 33 makes
control so as to perform both or one issuance of sounding of a warning and
stop of operation of the absorption type cold/hot water machine P.


A more concrete configuration will now be described. A detection
output of the temperature detector 29 which detects the temperature of the
absorbing solution in the high-temperature regenerator 1 and a detection
output of a temperature detector 34 which detects an inlet temperature of
cooling water flowing into the cooling water pipe 18 are inputted to the
control unit 33. In the cooling operation as shown in Fig.3, when on the
basis of the detection outputs of the temperature detectors 29 and 34 the
temperature of the absorbing solution in the high-temperature regenerator
1 is found to change for example in the range of 90° C to 160°C
correspondingly to each range of the cooling water inlet temperature defined
in increments of 2°C for example from 22°C to 32°C, there is made an
adjustment so that the frequency changes continuously or stepwise for
example in the range of 28 to 60 Hz, whereby the higher the temperature of
the absorbing solution in the high-temperature regenerator 1, the higher the
frequency signal which the control unit 33 outputs on the basis of the input
provided from the temperature detector 29. Consequently, the frequency of
electric power outputted from the inverter controller 32 to the electric motor
of the absorbing solution pump 12 becomes high and the absorbing solution
pump 12 assumes a state of high-speed operation, resulting in that the
delivery of the absorbing solution pump 12 increases. Besides, the lower
the temperature of the absorbing solution in the high-temperature
regenerator 1, the lower the frequency signal which the control unit 33
outputs on the basis of the input provided from the temperature detector 29.
Consequently, the frequency of electric power outputted from the inverter
controller 32 to the electric motor of the absorbing solution pump 21
becomes low and the absorbing solution pump 12 assumes a state of low-
speed operation, resulting in that the delivery of the absorbing solution
pump 12 decreases.


In the heating operation, cooling water is not allowed to flow into the
cooling water pipe 18 as noted above, so that the higher the temperature of
the absorbing solution in the high-temperature regenerator 1 on the basis of
the detection output of the temperature detector 29 as a detector for
detecting the temperature of the absorbing solution in the high-temperature
regenerator 1, which is inputted to the control unit 33, the higher the
frequency signal which the control unit 33 outputs on the basis of the input
provided from the temperature detector 29 as mentioned above.
Consequently, the frequency of electric power outputted from the inverter
controller 32 to the electric motor of the absorbing solution pump 12
becomes high and the absorbing solution pump 12 assumes a state of high-
speed operation, with the result that the delivery of the absorbing solution
pump 12 increases. Moreover, the lower the temperature of the absorbing
solution in the high-temperature regenerator 1, the lower the frequency
signal which the control unit 33 outputs on the basis of the input provided
from the temperature detector 29. Consequently, the frequency of electric
power outputted from the inverter controller 32 to the electric motor of the
absorbing solution pump 12 becomes low and the absorbing solution pump
12 assumes a state of low-speed operation, with consequent decrease of the
delivery of the absorbing solution pump 12.
Thus, the frequency of electric power outputted from the inverter
controller 32 in the control unit 33 to the absorbing solution pump 12 varies
at least in accordance with the temperature of the absorbing solution in the
high-temperature regenerator 1. Thus, the absorbing solution pump 12 is
inverter-controlled so that the number of revolutions thereof changes,
whereby the level of the absorbing solution in the high-temperature
regenerator 1 is maintained at an appropriate level.
Although in the above configuration the temperature of the high-


temperature regenerator is detected by the temperature detector 29 which
detects the temperature of the absorbing solution in the high-temperature
regenerator 1, there may be adopted a configuration using the temperature
detector 31 which detects the temperature of exhaust gas discharged from
the high-temperature regenerator 1.
The level detector 30 has three electrodes A, B and C for detecting
the level of the absorbing solution in the high-temperature regenerator 1, of
which the electrode B is a common electrode. When the level of the
absorbing solution rises and reaches the electrode A, the electrodes A and B
become conductive and the control unit 33 operates so as to detect a high
level (upper-limit level). When the level of the absorbing solution drops
lower than the electrode C and the electrodes B and C become non-
conductive, the state of detection becomes a low level (lower-limit level)
detecting state and the control unit 33 operates accordingly. Thus, an
absorbing solution level range from the electrode C to the electrode A
represents a normal state of the amount of the absorbing solution. This is
determined by the control unit 33 and the absorbing solution pump 12 is
inverter-controlled in the manner described above.
Thus, the absorbing solution level range from the electrode C to the
electrode A corresponds to a normal state of the amount of the absorbing
solution. In this state, as noted above and as shown in Fig. 3, the
absorbing solution pump 12 is inverter-controlled in the range of 28 to 60 Hz.
If in this state of operation there occurs a rise of the absorbing solution level
frequently in a short time by some causes, the electric power frequency
supplied to the absorbing solution pump 12 is lowered. For example, when
the electric power frequency supplied to the absorbing solution pump 12
which is in operation under inverter control is 40 Hz, the number of times
the level of the absorbing solution reaches the electrode A within a


has dropped to the lower-limit level or less, the processing flow advances to
step S3. In step S3, the absorbing solution pump 12 is operated in a state
of highest speed within its operation range or at a high speed close thereto.
In this embodiment the absorbing solution pump 12 is operated for a
predetermined time at the maximum frequency of 60 Hz under inverter
control. In this embodiment the predetermined time is 60 seconds, but
may be any time in the range of 30 to 60 seconds.
In step S4, if during the aforesaid period of 60 seconds the level of
the absorbing solution rises and the electrodes B and C become conductive
and so do the electrodes A and C, then at this instant the processing flow
advances to step S6. However, if during this 60 sec. period the solution
level does not rise so as to bring the electrodes A and C into conduction, the
processing flow advances to step S5 in 60 seconds (upon arrival at 60
seconds or after the lapse of 60 seconds). In step S5 it is determined
whether the electrodes B and C are conductive, i.e., whether the level of the
absorbing solution in the high-temperature regenerator 1 is the lower-limit
level or more. If the answer is affirmative, the processing flow advances to
step S6. In step S6, the absorption type cold/hot water machine P is in
normal operation and the frequency of electric power outputted from the
inverter controller 32 in the control unit 33 to the absorbing solution pump
12 changes in accordance with the temperature of the absorbing solution in
the high-temperature regenerator 1, whereby the absorbing solution pump
12 is inverter-controlled so that the number of revolutions thereof changes
and the level of the absorbing solution in the high-temperature regenerator
1 is maintained at an appropriate absorbing solution level.
If in step S5 the electrodes B and C are non-conductive, i.e., the
lower-limit level has not been reached, it is determined that the level of the
absorbing solution in the high-temperature regenerator 1 is in an abnormal


deficient state, and the processing flow advances to step S7, in which a
warning indicative of the abnormal state is issued. This "abnormal"
warning is issued, for example, by sounding of a buzzer or lighting of a lamp.
In step S7 the operation of the absorption type cold/hot water machine P
may be stopped. The control unit 33 may make a control so that both or
one of such issuance of the warning and stop of operation of the machine P
are (is) performed.
After arrival at step S6 in the operation, the processing flow
advances to step S1, followed by the same determinations as above and each
determination is made. In this way the operations of steps S1 to S6 are
repeated.
According to the present invention, when the level of the absorbing
solution drops to the predetermined lower-limit level, that is, when the
electrodes B and C cease to conduct and become non-conductive, this state
indicates the deficiency of the absorbing solution, but it is determined by the
control unit 33 whether this state is attributable to a temporary change of
the absorbing solution level or not. Further, another means for this
determining operation will be described with reference to Figs. 4 and 5.
The configuration and operation of the absorption type cold/hot water
machine P are the same as in Figs. 1 and 3. In this case, the detection
output of the temperature detector 29 for detecting the temperature of the
absorbing solution in the high-temperature regenerator 1 is inputted to the
control unit 33. The absorbing solution pump 12 is in a state of being
inverter-controlled in the range of 28 to 60 Hz, as shown in Fig. 3. Fig. 4 is
a control flow chart and Fig. 5 is a diagram showing a temperature rise
detected by a temperature detector, both in connection with the present
invention.
In Fig. 4, the level of the absorbing solution in the high-temperature


regenerator 1 is detected by the level detector 30 in step S1. In step S2, it
is determined whether the absorbing solution level has dropped to the
lower-limit value or less, i.e., whether the electrodes B and C are non-
conductive or not, and if the electrodes B and C are conductive, the
processing flow advances to step S7, while if the electrodes B and C are non-
conductive and the lower-limit level or less is detected, the processing flow
advances to step S3. In step S3, the absorbing solution pump 12 is
operated at high speed. In the embodiment, the operation is performed for
a predetermined time at the maximum frequency of 60 Hz which is inverter-
controlled. In the embodiment the predetermined time is 60 seconds, but
may be any other time falling under the range of 30 to 60 seconds.
In step S4, if during the 60 sec. period the solution level rises and
the electrodes B and C become conductive and so do the electrodes A and C,
the processing flow advances to step S7 on the moment. However, if during
the 60 sec. period the solution level does not rise so as to bring the
electrodes A and C into conduction, the processing flow advances to step S5
in 60 seconds (upon arrival at 60 seconds or after the lapse of 60 seconds).
In step S5, it is determined whether the electrodes B and C are conductive
or not, i.e., whether the level of the absorbing solution in the high-
temperature regenerator 1 is the lower-limit level or more. If the answer is
affirmative, the processing flow advances to step S6, but if the electrodes B
and C are non-conductive, i.e., if the lower-limit level has not been reached,
it is determined that the level of the absorbing solution in the high-
temperature regenerator 1 is in an abnormal deficient state, then the
processing flow advances to step S8, in which a warning indicative of the
abnormal state is issued. This "abnormal" warning is issued, for example,
by sounding of a buzzer or lighting of a lamp. In step S8, the operation of
the absorption type cold/hot water machine P may be stopped. The control


unit 33 may make a control so that both or one of such issuance of the
warning and stop of operation of the machine P are (is) performed.
If in step S5 the electrodes B and C are conductive, i.e., if the lower-
limit level has been reached, the processing flow advances to step S6. In
step S6, as shown in Fig. 5, on the basis of the detection output of the
temperature detector 29 which is inputted to the control unit 33, it is
determined whether the temperature rise of the absorbing solution in the
high-temperature regenerator 1 is within a prescribed range or not. In the
embodiment, it is determined whether the temperature rise of the absorbing
solution in the high-temperature regenerator 1 is a predetermined value
(5°C) or more in a predetermined time (15 seconds). The temperatures
shown on the left side of Fig. 5 do not constitute any limitation.
In step S6, if the temperature rise of the absorbing solution in the
high-temperature regenerator 1 is within the prescribed range, i.e., if it does
not reach the predetermined value (5°C) in the predetermined time (15
seconds), this means that the high-temperature regenerator 1 is within a
safe range, therefore, the processing flow advances to step S6. If the
temperature rise of the absorbing solution in the high-temperature
regenerator 1 exceeds the predetermined range, i.e., if it is the
predetermined value (5°C) or more in the predetermined time (15 seconds),
this means that the high-temperature regenerator 1 is in a dangerous range,
therefore, the processing flow advances to step S8, in which a warning
indicative of this abnormal state is issued. This "abnormal" warning is
issued, for example, by sounding of a buzzer or lighting of a lamp. In step
S8, the operation of the absorption type cold/hot water machine P may be
stopped. The control unit 33 may make a control so that both or one of
such issuance of the warning and stop of operation of the machine P are (is)
performed.


In step S7, the absorption type cold/hot water machine P is in
normal operation, and as noted above, the frequency of electric power
outputted from the inverter controller 32 in the control unit 33 to the
absorbing solution pump 12 changes in accordance with the temperature of
the absorbing solution in the high-temperature regenerator 1, whereby the
absorbing solution pump 12 is inverter-controlled so that the number of
revolutions thereof changes. In this way the lever of the absorbing solution
in the high-temperature regenerator 1 is maintained at an appropriate level.
Thus, when the level detector 30 detects a drop of the absorbing
solution level to the lower-limit value or less, the control unit 33 makes
control so that the absorbing solution pump 12 operates at a predetermined
high frequency for a predetermined time. At the same time, a temperature
rise of the absorbing solution in the high-temperature regenerator 1 is
measured. Then, when the temperature rise is the predetermined value or
more and the level detector 30 detects the lower-limit level or less of the
absorbing solution upon arrival at or lapse of the predetermined time, the
issuance of a warning and/or the stop of operation of the absorption type
cold/hot water machine are (is) performed. After arrival at step S7, the
processing flow advances to step S1, followed by each determination in the
same steps as mentioned above. In this way the operations from step SI to
step S7 are repeated.
According to the present invention, when the level of the absorbing
solution drops to the predetermined lower-limit level, that is, when the
electrodes B and C cease to conduct and become non-conductive, this state
indicates the deficiency of the absorbing solution, but it is determined by the
control unit 33 whether this state is attributable to a temporary change of
the absorbing solution level or not. Further, still another means for this
determining operation will be described with reference to Figs. 4 and 5.


The configuration and operation of the absorption type cold/hot water
machine P are the same as in Figs. 1 and 3. In this case, the detection
output of the temperature detector 31 for detecting the temperature of
exhaust gas discharged from the high-temperature regenerator 1 is inputted
to the control unit 33. The absorbing solution pump 12 is in a state of
being inverter-controlled in the range of 28 to 60 Hz, as shown in Fig. 3.
Fig. 4 is a control flow chart and Fig. 5 is a diagram showing a temperature
rise detected by a temperature detector, both in connection with the
invention.
In Fig. 4, the level of the absorbing solution in the high-temperature
regenerator 1 is detected by the level detector 30 in step S1. In step S2, it
is determined whether the absorbing solution level has dropped to the
lower-limit value or less, i.e., whether the electrodes B a and C are non-
conductive or not, and if the electrodes B and C are conductive, the
processing flow advances to step S7, while if the electrodes B and C are non-
conductive and the lower-limit level or less is detected, the processing flow
advances to step S3. In step S3, the absorbing solution pump 12 is
operated at high speed. In the embodiment the operation is performed for
a predetermined time at the maximum frequency of 60 Hz which is inverter-
controlled. In the embodiment the predetermined time is 60 seconds, but
may be any other time falling under the range of 30 to 60 seconds.
In step S4, if during the 60 sec. period the solution level rises and
the electrodes B and C become conductive and so do the electrodes A and C,
the processing flow advances to step S7 on the moment. However, if during
the 60 sec. period the solution level does not rise so as to bring the
electrodes A and C into conduction, the processing flow advances to step S5
in 60 seconds (upon arrival at 60 seconds or after the lapse of 60 seconds).
In step S5, it is determined whether the electrodes B and C are conductive


or not, i.e., whether the level of the absorbing solution in the high-
temperature regenerator 1 is the lower-limit level or more. If the answer is
affirmative, the processing flow advances to step S6, but if the electrodes B
and C are non-conductive, i.e., if the lower-limit level has not been reached,
it is determined that the level of the absorbing solution in the high-
temperature regenerator 1 is in an abnormal deficient state, then the
processing flow advances to step S8, in which a warning indicative of the
abnormal state is issued. This "abnormal" warning is issued, for example,
by sounding of a buzzer or lighting of a lamp. In step S8, the operation of
the absorption type cold/hot water machine P may be stopped. The control
unit 33 may make a control so that both or one of such issuance of the
warning and stop of operation of the machine P are (is) performed.
If in step S5 the electrodes B and C are conductive, i.e., if the lower-
limit level has been reached, the processing flow advances to step S6. In
step S6, as shown in Fig. 5, on the basis of the detection output of the
temperature detector 31 which is inputted to the control unit 33, it is
determined whether the temperature rise of exhaust gas discharged from
the high-temperature regenerator 1 is within a prescribed range or not. In
the embodiment, it is determined whether the temperature rise of exhaust
gas from the high-temperature regenerator 1 is a predetermined value (5°C)
or more in a predetermined time (15 seconds). The temperatures shown on
the left side of Fig. 5 do not constitute any limitation.
In step S6, if the temperature rise of the exhaust gas from the high-
temperature regenerator 1 is within the prescribed range, i.e., if it does not
reach the predetermined value (5°C) in the predetermined time (15 seconds),
this means that the high-temperature regenerator 1 is within a safe range,
therefore, the processing flow advances to step S6. If the temperature rise
of the exhaust gas from the high-temperature regenerator 1 exceeds the


prescribed range, i.e., if it is the predetermined value (5°C) or more in the
predetermined time (15 seconds), this means that the high-temperature
regenerator 1 is in a dangerous range, therefore, the processing flow
advances to step S8, in which a warning indicative of this abnormal state is
issued. This "abnormal" warning is issued, for example, by sounding of a
buzzer or lighting of a lamp. In step S8, the operation of the absorption
type cold/hot water machine P may be stopped. The control unit 33 may
make a control so that both or one of such issuance of the warning and stop
of operation of the machine P are (is) performed.
In step S7. the absorption type cold/hot water machine P is in
normal operation, and as noted above, the frequency of electric power
outputted from the inverter controller 32 in the control unit 33 to the
absorbing solution pump 12 changes in accordance with the temperature of
the absorbing solution in the high-temperature regenerator 1, whereby the
absorbing solution pump 12 is inverter-controlled so that the number of
revolutions thereof changes. In this way the level of the absorbing solution
in the high-temperature regenerator 1 is maintained at an appropriate level.
Thus, when the level detector 30 detects a drop of the absorbing
solution level to the predetermined lower-limit level, i.e., when it is detected
that the electrodes B and C in the level detector 30 have come into a non-
conductive state, the control unit 33 makes control so that the absorbing
solution pump 12 operates at a predetermined high frequency for a
predetermined time. At the same time, a temperature rise of the exhaust
gas from the high-temperature regenerator 1 is measured. Then, when the
temperature rise is the predetermined value or more and the level detector
30 detects the lower-limit level or less of the absorbing solution upon arrival
at or lapse of the predetermined time, the issuance of a warning and/or the
stop of operation of the absorption type cold/hot water machine are (is)


performed. After arrival at step S7, the processing flow advances to step
S1, followed by each determination in the same steps as mentioned above.
In this way the operations from step S1 to step S7 are repeated.
In the above second and third embodiments the order of steps S5
and S6 may be reversed so that step S6 is performed before step S5 is
performed.
Although in the above embodiments the upper- and lower-limit
levels of the absorbing solution are detected by the level detector 30 using
three electrodes A, B and C of different lengths, no limitation is made
thereto. For example, there may be adopted a configuration wherein the
level detector 30 is made up four electrodes D, E, F and G of different
lengths, the upper-limit level of the absorbing solution is detected by
conduction of the electrodes D and E, the lower-limit level thereof is
detected by conduction of the electrodes F and G, an intermediate solution
level is detected by the electrodes E and F, and the absorbing solution pump
12 is inverter-controlled in the same manner as mentioned above between
the upper- and the lower-limit level.
As to piping, control mechanism, and so on in the absorption type
cold/hot water machine according to the present invention, various changes
may be made and no limitation is made to the above embodiments. The
present invention is applicable to various forms insofar as they do not
depart from the technical scope of the invention.



WE CLAIM:
1. An absorption chiller-heater wherein an absorbing solution and a refrigerant
are circulated through a high-temperature regenerator, a condenser, an evaporator and an
absorber, interconnected by pipes and a heat operation medium cooled or heated as a result of
having passed through a heat transfer pipe disposed in the interior of said evaporator is
supplied to an air conditioning load to effect cooling or heating, said absorption chiller-heater
comprising:
a level detector for detecting the level of the absorbing solution in said high-
temperature regenerator;
an absorbing solution pump for feeding a dilute absorbing solution from said
absorber into said high-temperature regenerator; and
a control unit for controlling the operation of said absorbing solution pump on the
basis of the detection made by said level detector,
characterized in that when said level detector detects a predetermined lower-limit
level of the absorbing solution, said absorbing solution pump is operated for a predetermined
time at high speed to increase the amount of the absorbing solution to be fed into said high-
temperature regenerator, then when said predetermined time has been reached or elapsed, it is
determined whether said level detector detects said predetermined lower-limit level of the
absorbing solution, and if the level detector detects again the predetermined lower-limit level
of the absorbing solution, both or one issuance of sounding of a warning and stop of operation
of the absorption chiller-heater are/is performed so as to warn that the predetermined lower-
limit level re-detected depends on a continuous drop in normal state not temporary drop.
2. The absorption chiller-heater as claimed in claim 1, wherein said absorption



chiller-heater comprises:
a temperature detector for detecting a temperature of the absorbing solution in the
high-temperature regenerator;
the control unit is a control unit of an inverter control type adapted to change the
frequency in the range from a low frequency to a high frequency on the basis of the detection
made by said temperature detector and change the number of revolutions of said absorbing
solution pump,
when the level detector detects the predetermined lower-limit level of the absorbing
solution, the absorbing solution pump is operated for the predetermined time at the high
speed by a predetermined high frequency,
3. The absorption chiller-heater as claimed in claim 2, wherein when the level
detector detects the predetermined lower-limit level of the absorbing solution, a rise of the
temperature detected by the temperature detector is further measured, then when the
predetermined time has been reached or elapsed, and if a rise of the temperature of the
absorbing solution measured is a predetermined value or more and the level detector again
detects the predetermined lower-limit level of the absorbing solution, both or one issuance of
sounding of a warning and stop of operation of said absorption chiller-heater are/is performed.
4. The absorption chiller-heater as claimed in claim 2, wherein said absorption chiller-
heater comprises an exhaust gas temperature detector for detecting the temperature of exhaust
gas discharged from said high-temperature regenerator, and when said level detector detects a
predetermined lower-limit level of the absorbing solution, a rise of the exhaust gas
temperature detected by said exhaust gas temperature detector is further measured, then when


the predetermined time has been reached or elapsed, and if a rise of the exhaust gas
temperature measured is a predetermined value or more and the level detector again detects
the predetermined lower-limit level of the absorbing solution, both or one issuance of
sounding of a warning and stop of operation of said absorption chiller-heater are/is performed.


ABSTRACT

ABSORPTION CHILLER-HEATER
An absorption chiller-heater is disclosed wherein an absorbing solution and a
refrigerant are circulated through a high-temperature regenerator (1), a condenser (4), an
evaporator (5) and an absorber (6), interconnected by pipes and a heat operation medium
cooled or heated as a result of having passed through a heat transfer pipe disposed in the
interior of said evaporator (6) is supplied to an air conditioning load to effect cooling or
heating, said absorption chiller-heater comprising: a level detector; an absorbing solution
pump; and a control unit, characterized in that when said level detector detects a
predetermined lower-limit level of the absorbing solution, said absorbing solution pump is
operated for a predetermined time at high speed to increase the amount of the absorbing
solution to be fed into said high-temperature regenerator (1), then when said predetermined
time has been reached or elapsed, it is determined whether said level detector detects said
predetermined lower-limit level of the absorbing solution, and if the level detector detects
again the predetermined lower-limit level of the absorbing solution, both or one issuance of
sounding of a warning and stop of operation of the absorption chiller-heater are/is performed
so as to warn that the predetermined lower-limit level re-detected depends on a continuous
drop in normal state not temporary drop.

Documents:

01175-kol-2007-abstract.pdf

01175-kol-2007-claims.pdf

01175-kol-2007-correspondence others.pdf

01175-kol-2007-description complete.pdf

01175-kol-2007-drawings.pdf

01175-kol-2007-form 1.pdf

01175-kol-2007-form 2.pdf

01175-kol-2007-form 3.pdf

01175-kol-2007-form 5.pdf

01175-kol-2007-others.pdf

01175-kol-2007-priority document.pdf

1175-KOL-2007-(01-06-2012)-ABSTRACT.pdf

1175-KOL-2007-(01-06-2012)-AMANDED CLAIMS.pdf

1175-KOL-2007-(01-06-2012)-AMANDED PAGES OF SPECIFICATION.pdf

1175-KOL-2007-(01-06-2012)-CORRESPONDENCE.pdf

1175-KOL-2007-(01-06-2012)-DESCRIPTION (COMPLETE).pdf

1175-KOL-2007-(01-06-2012)-FORM-1.pdf

1175-KOL-2007-(01-06-2012)-FORM-2.pdf

1175-KOL-2007-(01-06-2012)-FORM-3.pdf

1175-KOL-2007-(01-06-2012)-FORM-5.pdf

1175-KOL-2007-(01-06-2012)-OTHERS.pdf

1175-KOL-2007-(01-06-2012)-PA.pdf

1175-KOL-2007-(01-06-2012)-PETITION UNDER RULE 137.pdf

1175-KOL-2007-(13-06-2012)-AMANDED PAGES OF SPECIFICATION.pdf

1175-KOL-2007-(15-06-2012)-EXAMINATION REPORT REPLY RECEIVED.pdf

1175-KOL-2007-(15-06-2012)-OTHERS.pdf

1175-KOL-2007-ASSIGNMENT.pdf

1175-KOL-2007-CORRESPONDENCE OTHERS 1.1.pdf

1175-KOL-2007-CORRESPONDENCE.pdf

1175-KOL-2007-EXAMINATION REPORT.pdf

1175-KOL-2007-FORM 18 1.1.pdf

1175-kol-2007-form 18.pdf

1175-KOL-2007-FORM 3.pdf

1175-KOL-2007-FORM 5.pdf

1175-KOL-2007-GPA 1.1.pdf

1175-KOL-2007-GPA.pdf

1175-KOL-2007-GRANTED-ABSTRACT.pdf

1175-KOL-2007-GRANTED-CLAIMS.pdf

1175-KOL-2007-GRANTED-DESCRIPTION (COMPLETE).pdf

1175-KOL-2007-GRANTED-DRAWINGS.pdf

1175-KOL-2007-GRANTED-FORM 1.pdf

1175-KOL-2007-GRANTED-FORM 2.pdf

1175-KOL-2007-GRANTED-SPECIFICATION.pdf

1175-KOL-2007-OTHERS.pdf

1175-KOL-2007-PRIORITY DOCUMENT.pdf

1175-KOL-2007-REPLY TO EXAMINATION REPORT.pdf

1175-KOL-2007-TRANSLATED COPY OF PRIORITY DOCUMENT.pdf

abstract-01175-kol-2007.jpg


Patent Number 255431
Indian Patent Application Number 1175/KOL/2007
PG Journal Number 08/2013
Publication Date 22-Feb-2013
Grant Date 21-Feb-2013
Date of Filing 27-Aug-2007
Name of Patentee SANYO ELECTRIC CO., LTD.
Applicant Address 5-5, KEIHANHONDORI 2-CHOME MORIGUCHI-SHI OSAKA-FU
Inventors:
# Inventor's Name Inventor's Address
1 ISHIZAKI SYUJI 3-13-21, ASAHI, OIZUMI-MACHI, OURA-GUN, GUNMA-KEN
2 OANA HIDEAKI 60-6, NITTAMIZUKICHO, OTA-SHI, GUNMA-KEN
3 KANUMA HITOSHI 3-26-403, GINZA, KUMAGAYA-SHI, SAITAMA-KEN
4 TOKUDA TETSUYA 3-25-1, SENGOKU, OIZUMI-MACHI, OURA-GUN, GUNMA-KEN
5 ISHIFUKU SOUICHI 505-3, OSHIMA-CHO, TATEBAYASHI-SHI, GUNMA-KEN
6 KOBAYASHI TAKAHIRO 4-1-7, KITAKOIZUMI, OIZUI-MACHI, OURA-GUN, GUNMA-KEN
PCT International Classification Number F25B
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2006-287743 2006-10-23 Japan