Title of Invention

"AN IMAGE FORMING APPARATUS"

Abstract An image forming apparatus comprising: a latent image carrier (1) that is rotatable and configured to carry a latent image; a cleaning blade (8a) that cleans toner remaining on a cleaning area on the latent image carrier; a lubricant (3b); a lubricant applying brush roller (3a) configured to scrape off the lubricant and applies scrapped lubricant to the latent image carrier (1); and a lubricant applying blade (3e) arranged on a downstream side of an applying apparatus of the cleaning blade (8a) with respect to direction of rotation of the latent image carrier (1), and that applies a lubricant on the latent image carrier (1), wherein a lubricant applying area overlaps the cleaning area of the cleaning blade, and wherein a width of the lubricant (3b) is less than a width of the brush roller (3a) and the width of the brush roller (3a) is less than a width of the lubricant applying blade (3e) in contact with the latent image carrier (1) in a longitudinal direction thereof in the image forming apparatus.
Full Text TECHNICAL FIELD
The present invention relates to an image forming
apparatus, and a lubricant applying device, a transfer
device, a process cartridge, and toner used for an image
carrier of the image forming apparatus.
BACKGROUND ART
Recently, there is an increasing requirement for
forming high quality images. To obtain such images, a
finer and highly spherical toner needs to be used. Polymer
toners can be suitably used as finer and highly spherical
toners.
In the image forming apparatuses, excess toner that
remains on the surface of a photoconductor after image
formation is commonly cleaned with a cleaning means.
However, as the toner becomes finer and more spherical, it
becomes difficult to clean it. For example, a cleaning
blade, which is a commonly used cleaning means, can not
properly clean the excess toner. One approach is to more
strongly press the cleaning blade against the surface of
the photoconductor, however, the photoconductor can get
damaged. Another approach is to apply a lubricant on the
surface of the photoconductor. However, if the lubricant
is not applied uniformly, the quality of the toner image
can degrade.
Somethimes both of the above approaches are employed.
In that case there can be two options: apply a lubricant
first and then clean excess toner, or clean excess toner

first and then apply a lubricant. In Japanese Patent
Application Laid-Open (JP-A) No. 2001-305907, the applicant
of this application has proposed a method of cleaning
excess toner first and then applying a lubricant. However,
this technique does not take into account a fine, spherical,
polymer toner.
Various lubricants have been known. One of them is
zinc stearate. It is common to use a solid rod made of
zinc stearate, and use a brush roller to scrap zinc
stearate from the rod and apply it to the photoconductor.
A powdery lubricant can be used instead of a solid bar.
However, a powdery lubricant has some disadvantageous. For
example, in general, powders are difficult to manufacture
and pack. Moreover, powdery lubricants can contaminate the
environment.
The amount of lubricant applied also plays an
important role. If the lubricant applied is too less, the
lubricant may not be applied uniformly, which leads to
improper cleaning and wear of the cleaning blade. On the
other hand, if the lubricant applied is too much, excess
lubricant can make dirty the surface of a charging roller,
or even can absorb moisture, which leads to flow of an
electrostatic latent image. JP-A No. H10-260614 and JP-A
No. 2003-57996 discloses a technique to determine the most
appropriate amount of the lubricant.
JP-A No. 2002-244485 describes a method of controlling
the application amount of a lubricant based on image data
information to improve cleaning capability of polymer toner.
This method is the "the application after the cleaning",
but it is different from the present invention in the way
to smooth the application amount of the lubricant.
JP-A No. 2000-330443 describes a method of uniformly
applying a lubricant to improve cleaning capability of

toner. This method is the "the application after the
cleaning", but it is also different from the present
invention in the way to smooth the application amount of
the lubricant.
JP-A No. 2000-172138 proposes an invention
characterized in that an area applied with a lubricant in
an axial direction of a photoconductor almost coincides
with an area where a cleaning blade contacts the
photoconductor. However, this invention is different from
the present invention in a point how to configure the
lubricant and the cleaning blade, and in another point
whether a lubricant smoothing blade is provided.
DISCLOSURE OF INVENTION
PROBLEM TO BE SOLVED BY THE INVENTION
According to an aspect of the present invention, an
image forming apparatus includes a latent image carrier
that is rotatable and configured to carry a latent image; a
cleaning blade that cleans toner remaining on a cleaning
area on the latent image carrier; and a lubricant applying
element that is arranged on downstream side of the cleaning
blade with respect to direction of rotation of the latent
image carrier, and that applies a lubricant to a lubricant
applying area on the latent image carrier, wherein the
cleaning area and the lubricant applying area overlap.
According to another aspect of the present invention,
an image forming apparatus includes a cleaning blade that
removes toner remaining on a surface of an image carrier
after a toner image is transferred; a lubricant applying
device including a lubricant; and a noncontact lubricant-
applying element that applies a component of the lubricant
to the image carrier in a noncontact manner; and a
lubricant smoothing blade that spreads the lubricant

applied to the image carrier, to form a thin layer, wherein
torque of the image carrier which is contacted only by the
cleaning blade is higher than torque of the image carrier,
with the lubricant applied, which is contacted by the
cleaning blade and the lubricant smoothing blade.
According to still another aspect of the present
invention, an image forming apparatus includes an image
carrier on which a toner image is formed; a cleaning blade
that cleans the image carrier after the toner image is
transferred to a transfer material; a blade holder that
holds the cleaning blade; and a lubricant applying device
that applies a lubricant to the image carrier. The
lubricant applying device includes a solid lubricant, a
lubricant applying element, a guide that guides the solid
lubricant so that the solid lubricant can move
substantially only in a direction of approaching or
separating from the lubricant applying element, and a
pressing unit that presses the solid lubricant against the
lubricant applying element. Positions of the pressing unit
and the cleaning blade are respectively set so that a
direction in which the pressing unit presses the solid
lubricant against the lubricant applying element and a
direction in which the cleaning blade is protruded toward
the surface of the image carrier are almost parallel to
each other, and the blade holder is fixed to the guide
directly or through another element.
According to still another aspect of the present
invention, a lubricant applying device includes a lubricant
that is accommodated in the lubricant applying device; an
applying roller that applies the lubricant to an image
carrier, being an applied surface; and a smoothing element
that spreads the lubricant applied to the image carrier to
form a thin layer. The lubricant is applied after

adherents on the applied surface are cleaned, and the
lubricant applied is further smoothed.
MEANS FOR SOLVING PROBLEM
According to still another aspect of the present
invention, a lubricant applying device includes a solid
lubricant that is accommodated in the lubricant applying
device; an applying roller that contacts the solid
lubricant to be adhered to the surface thereof with
lubricant as a component of the solid lubricant, and
applies the lubricant to an image carrier; a pressing
element that presses the solid lubricant against the
applying roller so that the solid lubricant contacts the
applying roller; and a smoothing element that spreads the
lubricant applied to the image carrier to form a thin layer.
The solid lubricant is disposed in the lower side with
respect to the applying roller in the direction of gravity,
the pressing element is disposed in the lower side with
respect to the solid lubricant in the direction of gravity,
the lubricant is applied after adherents on the applied
surface are cleaned, and the lubricant applied is further
smoothed.
According to still another aspect of the present
invention, a lubricant applying device includes a solid
lubricant that is accommodated in the lubricant applying
device; an applying roller that contacts the solid
lubricant to be adhered to the surface thereof with
lubricant as a component of the solid lubricant, and
applies the lubricant to an image carrier; a pressing
element that presses the solid lubricant against the
applying roller so that the solid lubricant contacts the
applying roller; and a smoothing element that spreads the
lubricant applied to the image carrier to form a thin layer.

The solid lubricant moves in a direction perpendicular to a
direction of rotation of the applying roller.
According to still another aspect of the present
invention, a lubricant applying device includes a solid
lubricant that is accommodated in the lubricant applying
device; an applying roller that contacts the solid
lubricant to be adhered to the surface thereof with
lubricant as a component of the solid lubricant, and
applies the lubricant to an image carrier; a pressing
element that presses the solid lubricant against the
applying roller so that the solid lubricant contacts the
applying roller; and a smoothing element that spreads the
lubricant applied to the image carrier to form a thin layer.
The applying roller moves in a direction perpendicular to a
direction of rotation of the applying roller.
According to still another aspect of the present
invention, a lubricant applying device includes a lubricant
that is accommodated in the lubricant applying device; an
applying roller that applies the lubricant to an image
carrier; and a smoothing element of which edge portion
formed with a sheet-like elastic body is pressed against
the surface of the image carrier in its trailing posture,
to press and spread the lubricant applied thereto. A
contact angle of the smoothing element with respect to the
image carrier is 10 degrees or more.
According to still another aspect of the present
invention, a lubricant applying device includes a
lubricant that is accommodated in the lubricant applying
device; an applying roller that applies the lubricant to an
image carrier; a smoothing element of which edge portion
formed with a sheet-like elastic body is pressed against
the surface of the image carrier in its trailing posture,
to press and spread the lubricant applied thereto; and a

cleaning element of which edge portion formed with a sheet-
like elastic body is pressed against the surface of the
image carrier in its counter posture, to remove a foreign
matter from the surface thereof. The cleaning element, the
applying roller, and the smoothing element are arranged in
this order from an upstream side in a direction of movement
of the image carrier, and a contact angle of the smoothing
element with respect to the image carrier is 10 degrees or
more.
According to still another aspect of the present
invention, a lubricant applying device includes a lubricant
that is accommodated in the lubricant applying device; an
applying roller that applies the lubricant to an image
carrier; a smoothing element of which edge portion formed
with a sheet-like elastic body is pressed against the
surface of the image carrier in its trailing posture, to
press and spread the lubricant applied thereto; and a
cleaning element of which edge portion formed with a sheet-
like elastic body is pressed against the surface of the
image carrier in its counter posture, to remove a foreign
matter from the surface thereof. The cleaning element, the
applying roller, and the smoothing element are arranged in
this order from an upstream side in a direction of movement
of the image carrier, and a contact linear pressure of the
smoothing element is 0.01 N/cm or more.
According to still another aspect of the present
invention, a transfer device includes a transfer element
that is an image carrier; and a lubricant applying device
according to the above aspects that is detachably provided
in the transfer device.
According to still another aspect of the present
invention, a process cartridge includes an image carrier on
which a latent image is formed; and a process unit that

includes at least one selected from a charging device that
uniformly charges the surface of the image carrier, a
developing device that supplies toner to the latent image
and visualizes the latent image, a cleaning device that
cleans the surface of the image carrier, and a lubricant
applying device that applies lubricant to an applied
surface. The process cartridge integrally supports the
image carrier and the process unit, and is detachable from
an image forming apparatus, and the lubricant applying
device is a lubricant applying device according to above
aspects of the present invention.
According to still another aspect of the present
invention, an image forming apparatus includes an image
carrier on which a latent image is formed; a charging
device that uniformly charges the surface of the image
carrier; an exposing device that exposes the surface of the
image carrier charged, with light to write a latent image
thereon based on image data; a developing device that
supplies toner to the latent image and visualizes the
latent image; a cleaning device that cleans the surface of
the image carrier; a transfer device that transfers an
image visualized as a toner image on the surface of the
image carrier directly to a recording medium or to the
recording medium after the image is transferred to an
intermediate transfer element; a fixing device that fixes
the toner image on the recording medium; and a lubricant
applying device according to above aspects of the present
invention.
According to still another aspect of the present
invention, in a toner, a volume-average particle size is 10
micrometers or less, and a ratio, being a degree of
dispersion, between the volume-average particle size and a
number-average particle size is in a range from 1.00 to

1.40.
EFFECT OF THE INVENTION
According to one aspect of the present invention, the
frictional coefficient of the surface of the photoconductor
can be reduced stably over the whole area where the
cleaning unit contacts the photoconductor. Therefore,
image formation with high-resolution can be performed by
maintaining satisfactory cleaning performance.
According to anther aspect of the present invention,
by applying the lubricant to the image carrier, the torque
of the image carrier can be reduced, thereby providing an
energy-saving machine. Moreover, the drive motor can be
minimized, thereby providing a space-saving and low-cost
machine.
According to still anther aspect of the present
invention, although the cleaning blade, the blade holder,
and the lubricant applying device are provided, the whole
configuration of the image forming apparatus can be
downsized.
According to still anther aspect of the present
invention, the lubricant can be efficiently applied to the
surface of the photoconductor over the long period of time.
Moreover, the consumption amount of lubricant required for
maintaining the frictional coefficient of the surface of
the photoconductor to a fixed low value, can be reduced.
Furthermore, the lubricant is set on the lower side of
the brush roller, and the solid lubricant or the brush
roller is caused to sway. Therefore, even if the contact
pressure of the solid lubricant against the brush roller is
increased to obtain a required application amount of the
lubricant, the surface of the solid lubricant, which
contacts the brush, does not become irregular caused by its

uneven contact with the brush. This allows suppression of
fluctuations in the application amount of the lubricant
from the initial time to elapsed time.
According to still anther aspect of the present
invention, the transfer device in which the blade is not
rolled-in at the initial stage can be provided. The
process cartridge and the image forming apparatus according
to the present invention can provide excellent images
without the abnormal images due to cleaning failure of the
photoconductor.

BRIEF DESCRIPTION OF ACCOMPANYING DRAWINGS
Fig. 1 is a schematic of an image forming apparatus
according to an embodiment of the present invention;
Fig. 2 is a schematic of a lubricant applying device
and a cleaning device according to a first embodiment of
the present invention;
Fig. 3 is a schematic of a side seal of the cleaning
device;
Fig. 4 is a diagram for explaining how to measure a
frictional coefficient of a photoconductor;
Fig. 5A is a schematic diagram of a toner shape (1)
for explaining a shape factor SF-1;
Fig. 5B is a schematic diagram of a toner shape (2)
for explaining a shape factor SF-2;
Fig. 6A is a schematic diagram of a toner shape
according to the present invention;
Fig. 6B is a schematic diagram of the toner shape
according to the present invention;
Fig. 6C is a schematic diagram of the toner shape
according to the present invention;
Fig. 7 is a diagram of a solid lubricant for the
lubricant applying device when viewed from its longitudinal

direction as the front;
Fig. 8A is a diagram of how a blade contacts the
photoconductor (in a counter manner);
Fig. 8B is another diagram of how a blade contacts the
photoconductor (in a trailing manner) and of a contact
angle;
Fig. 9 is a schematic diagram of a lubricant applying
device and a cleaning device according to a third
embodiment of the present invention;
Fig. 10 is a cross-section of one example of an image
forming apparatus;
Fig. 11 is an enlarged cross-section of one of process
cartridges of Fig. 10;
Fig. 12 is a diagram for explaining a relation in
arrangement among a brush roller, a solid lubricant, and a
compressed coil spring of Fig. 11;
Fig. 13 is a cross-section of a process cartridge
having another configuration different from that of Fig.
10;
Fig. 14A is a diagram for explaining a faulty example
(1) when a guide for the solid lubricant is not provided;
Fig. 14B is a diagram for explaining another faulty
example (2) when the guide for the solid lubricant is not
provided;
Fig. 15 is a diagram for explaining faulty when a
pressing direction of the compressed coil spring and a
protruding direction of the cleaning blade are not parallel
to each other;
Fig. 16 is a diagram of how to manufacture an image
carrier having a low frictional coefficient using the
lubricant applying device according to the present
invention;
Fig. 17 is a diagram of an angle between the lubricant

applying device according to the present invention and a
sheet-like smoothing element which is a main portion
thereof, and how the lubricant is pressed and spread; and
Fig. 18 is a diagram of a lubricant applying device
and a cleaning device.
EXPLANATIONS OF LETTERS OR NUMERALS
1 photoconductor
2 charging device
2a charging roller
2b charge cleaning element
3 lubricant applying device
3a brush roller
3b solid lubricant
3c pressing element
3d lubricant holding element
3e lubricant smoothing blade
3f housing
4 developing device
8 cleaning device
8a cleaning blade
8c support element
9 exposing device
11 side seal
51 primary transfer rollers
56 intermediate transfer belt
61 secondary transfer roller
102Y, 102C, 102M, 102BK image carrier
128 cleaning blade
129 blade holder

131 lubricant applying device
132 smoothing blade
134 solid lubricant

136 guide
C pressing direction
F,G rotation center
H,I line
BEST MODE(S) FOR CARRYING OUT THE INVENTION
Exemplary embodiments of the present invention are
explained in detail below with reference to the
accompanying drawings. It is noted that the present
invention is not limited by these embodiments.
Fig. 1 is a schematic diagram of an image forming
apparatus according to the present invention.
The image forming apparatus includes an intermediate
transfer belt 56 in an almost center thereof. The
intermediate transfer belt 56 is an endless belt, which is
made of a heat-resistant material such as polyimide and
polyamide and includes a base body of which resistance is
adjusted to medium resistance. The intermediate transfer
belt 56 is supported by four rollers 52, 53, 54, and 55 by
being wound around among these rollers, and is made to
rotate in the direction of the arrow A. Four imaging units
corresponding to colored toners of yellow (Y), magenta (M) ,
cyan (C), and black (K) are aligned under the intermediate
transfer belt 56 along the belt surface thereof.
Fig. 18 is an enlarged diagram of one of the four
imaging units, and of a conventional applying device, but
the configuration thereof is basically the same as that
according to present invention, and hence the schematic
configuration of Fig. 18 is explained below. Because both
the conventional imaging unit and the imaging unit
according to the present invention are configured in the
same manner, characters Y, M, C, and K indicating
discrimination of the colors are omitted in Fig. 18

although the imaging unit includes photoconductors 1Y, 1M,
1C, and 1K in Fig. 1. Arranged around the photoconductor 1
are a charging device 2 that charges the surface of the
photoconductor 1, a developing device 4 that develops a
latent image formed on the surface of a photoconductor
(image carrier) 1 with a colored toner to form a toner
image, a lubricant applying device 3 that applies a
lubricant to the surface of the photoconductor 1, and a
cleaning device 8 that cleans the surface of the
photoconductor 1 after the toner image is transferred.
Referring to Fig. 1, an exposing device 9 is provided
under the four imaging units. The exposing device 9
exposes the surface of the photoconductor 1 that is charged,
based on image data for each color and forms a latent image.
Primary transfer rollers 51 are arranged in positions
each facing each photoconductor 1 across the intermediate
transfer belt 56, and primarily transfer respective toner
images formed on the photoconductors 1 to the intermediate
transfer belt 56. The primary transfer roller 51 is
connected to a power supply (not shown) and is applied with
a predetermined voltage.
A secondary transfer roller 61 is provided outside the
portion of the intermediate transfer belt 56 supported by
the roller 52 so as to be pressed against the roller 52.
The secondary transfer roller 61 is connected to the power
supply (not shown) and is applied with a predetermined
voltage. A contact portion between the secondary transfer
roller 61 and the intermediate transfer belt 56 is a
secondary transfer portion, where the toner image on the
intermediate transfer belt 56 is transferred to a transfer
paper.
An intermediate-transfer-belt cleaning device 57 is
provided outside the portion of the intermediate transfer

belt 56 supported by the roller 55. The intermediate-
transfer-belt cleaning device 57 cleans the surface of the
intermediate transfer belt 56 after the secondary transfer
is performed.
A fixing device 70 is provided above the secondary
transfer portion, and fixes the toner image on the transfer
paper semipermanently. The fixing device 70 includes an
endless fixing belt 71 that is wound around between a
heating roller 72 and a fixing roller 73, and a pressing
roller 7 4 that is arranged so as to face the fixing roller
73 through the fixing belt 71 and to be pressed against the
fixing roller 73. The heating roller 72 includes a halogen
heater.
A paper feed device 20 storing sheets of transfer
paper is provided in the lower side of the image forming
apparatus, and feeds a sheet of transfer paper to the
secondary transfer portion.
The features of the image forming apparatus are
explained in detail below with reference to Fig. 18.
The photoconductor 1 is an organic photoconductor and
has a surface protective layer that is formed with
polycarbonate-base resin.
The charging device 2 includes a charging roller 2a,
being a charging element which is covered with an elastic
layer having medium resistance and is provided outside a
conductive core metal of the charging roller 2a. The
charging roller 2a is connected to the power supply (not
shown) and is applied with a predetermined voltage. The
charging roller 2a is provided on the photoconductor 1 with
a small space between the two. The small space can be set,
for example, by winding a spacer element having a fixed
thickness around both ends of the charging roller 2a which
are non-image forming areas, and by bringing each surface

of the spacer elements into contact with the surface of the
photoconductor 1. A charge cleaning element 2b is provided
in the charging roller 2a, and contacts the surface of the
charging roller 2a to clean the surface thereof.
The developing device 4 includes a developing sleeve
4a that is provided in a position facing the photoconductor
1 and has a magnetic field generator. Provided in the
lower side of the developing sleeve 4a are two screws 4b
used to mix toner supplied from a toner bottle (not shown)
with a developer and to suck it up to the developing sleeve
4a while mixing them. The developer consisting of the
toner and magnetic carrier sucked-up by the developing
sleeve 4a forms a developer layer, of which thickness is
restricted to a predetermined value by a doctor blade 4c,
and the developer is carried on the developing sleeve 4a.
The developing sleeve 4a carries and coveys the developer
while rotating in the same direction as the photoconductor
1 at a position opposite thereto, and supplies the toner to
the surface of the latent image on the photoconductor 1.
It is noted that the configuration of the developing
device 4 of a two-component developing system is shown in
Fig. 1, but the configuration is not limited thereto.
Therefore, the present invention may also be applicable to
even a developing device based on a one-component
developing system.
The lubricant applying device 3 includes a solid
lubricant 3b accommodated in a case that is fixed, and a
brush roller 3a that contacts the solid lubricant 3b,
scrapes lubricant off, and applies the lubricant scraped-
off to the photoconductor 1. The solid lubricant 3b is
formed into a rectangular solid and is biased toward the
side of the brush roller 3a by the pressing element 3c.
The pressing element 3c may be any one of a plate spring, a

compressed spring, and the like, and particularly, the
compressed spring can be preferably used as shown in Fig.
18. The solid lubricant 3b is scraped off by the brush
roller 3a and consumed, so that its thickness is reduced
over time, but since the solid lubricant 3b is pressed by
the pressing element 3c, the solid lubricant 3b is always
in contact with the brush roller 3a. The brush roller 3a
scrapes the lubricant while rotating, and applies it to the
surface of the photoconductor 1.
In the present invention, the lubricant applying
device 3 is provided at the outside on the downstream side
of the cleaning device 8 as explained below with reference
to Fig. 2.
The configuration of the cleaning device 8 according
to a first embodiment of the present invention is explained
below with reference to Fig. 2.
The cleaning device 8 includes a cleaning blade 8a and
a support element 8c. The cleaning blade 8a is formed with
plate-like rubber such as urethane rubber and silicone
rubber, and is provided so that the edge thereof contacts
the surface of the photoconductor 1, thereby removing toner
remaining on the photoconductor 1 after a toner image is
transferred. The cleaning blade 8a and a lubricant
smoothing blade 3e are bonded to and supported by the
support element 8c and a support element 3g, respectively,
which are made of metal, plastic, ceramic, or the like.
The cleaning blade 8a and the lubricant smoothing blade 3e
are arranged roughly at each angle as shown in Fig. 2 with
respect to the surface of the photoconductor 1, which is
explained in detail later.
The lubricant applying device 3 is provided at the
outside on the downstream side of the cleaning device 8,
and the cleaning blade 8a is arranged on the upstream side

in the direction of movement of the photoconductor 1 and
the lubricant smoothing blade 3e is arranged on the
downstream side in the same direction as above.
The remaining toner on the surface of the
photoconductor 1 is removed by the cleaning blade 8a, and
the surface thereof is cleaned. The lubricant applying
device 3 applies the lubricant to the surface of the
phdtoconductor 1 thus cleaned, and then the lubricant
smoothing blade 3e slides along the surface thereof to
spread the lubricant, thereby forming a thin layer of the
lubricant on the surface of the photoconductor 1.
Moreover, the lubricant applying device 3 not only
applies the lubricant to the surface of the photoconductor
1 but also can be used as a device that applies the
lubricant to the surface of the intermediate transfer belt
56 of Fig.. 1. In this case, the lubricant applying device
3 can be arranged next to the intermediate-transfer-belt
cleaning device 57, or can be included in the intermediate-
transfer-belt cleaning device 57. The lubricant applying
device 3 is provided on the upstream side of the
intermediate-transfer-belt cleaning device 57 in the
direction of movement of the intermediate transfer belt 56,
and applies the lubricant to the surface of the
intermediate transfer belt 56. The cleaning blade included
in the intermediate-transfer-belt cleaning device 57
spreads the lubricant applied, thereby forming a thin layer
of the lubricant. Consequently, adherents such as toner
can be cleaned satisfactorily. More specifically, the
toner remains on the surface of the intermediate transfer
belt 56 without being secondarily transferred at a nip
portion between the secondary transfer roller 61 and the
intermediate transfer belt 56.
Furthermore, a process cartridge integrally supports

the lubricant applying device 3, the photoconductor 1, and
any unit selected from the charging device 2, the
developing device 4, and the cleaning device 8. The
process cartridge is detachably mounted on the main unit of
the image forming apparatus. If the lubricant applying
device 3 is integrated with the cleaning device 8 in the
process cartridge, as already explained above, the
lubricant applying device 3 is installed on the downstream
side of the cleaning blade 8a in the movement direction of
the photoconductor 1. The process cartridge allows the
cleaning performance of the surface of the photoconductor 1
to be maintained over a long period of time and the
degradation of image quality to be prevented.
The lubricant applying device 3 is explained below
more specifically. Fig. 2 is a partially enlarged diagram
of neighborhood of the lubricant applying device 3
according to the first embodiment. The lubricant applying
device 3 is provided at outside on the downstream side of
the cleaning device 8 for the photoconductor, and includes
the solid lubricant 3b and the brush roller 3a being a
brush-like element for applying the solid lubricant 3b to
the photoconductor 1. The solid lubricant 3b is obtained
by dissolving a lubricating-oil additive that contains zinc
stearate as a main component, and then cooling and
solidifying it to be molded into a bar. The solid
lubricant 3b is held by a lubricant holding element 3d, and
is pressed against the brush roller 3a by a pressing spring
fixed to a housing 3f of the lubricant applying device 3,
through the lubricant holding element 3d. The brush roller
3a is provided so as to be in contact with the
photoconductor 1, and scrapes the solid lubricant 3b by
rotation of the brush roller 3a to be adhered to the brush
roller 3a. The lubricant adhered to the brush roller 3a is

applied to the surface of the photoconductor 1 from a
contact portion of the brush roller 3a with the
photoconductor 1. Then, the lubricant is smoothed by the
lubricant smoothing blade 3e.
As the solid lubricant 3b, a dry solid hydrophobic
lubricant can be used, and zinc stearate and other
components including a stearic acid group as follows can be
used, that is, barium stearate, lead stearate, iron
stearate, nickel stearate, cobalt stearate, copper stearate,
strontium stearate, calcium stearate, cadmium stearate, and
magnesium stearate. The dry solid hydrophobic lubricant
may also include zinc oleate, manganese oleate, iron oleate,
cobalt oleate, lead oleate, magnesium oleate, and copper
oleate, which are included in the same fatty acid group;
and zinc palmitate, cobalt palmitate, copper palmitate,
magnesium palmitate, aluminum palmitate, and calcium
palmitate. In addition to these, the dry solid hydrophobic
lubricant also includes fatty acids and metal salts of
fatty acids such as lead caprylate, lead caproate, zinc
linoleate, cobalt linoleate, calcium linoleate, and cadmium
ricolinoleate. Furthermore, waxes such as candelilla wax,
carnauba wax, rice wax, Japan tallow, jojoba oil, bees wax,
and lanoline can be used.
The features of the first embodiment are explained
below. In this embodiment, the cleaning blade 8a, being a
cleaning unit, is made to contact the surface of the
photoconductor 1 on the upstream side in the movement
direction of the photoconductor 1 with respect to the zone
where the lubricant is applied by the brush roller 3a. And
the lubricant smoothing blade 3e, being a lubricant
smoothing unit, is made to contact the surface of the
photoconductor 1 on the downstream side in the direction of
its movement with respect to the zone where the lubricant

is applied. Furthermore, in the first embodiment, as shown
in Fig. 2, the cleaning blade 8a is made to contact the
surface of the photoconductor 1 in the counter direction,
and the lubricant smoothing blade 3e is made to contact the
surface of the photoconductor 1 in the trailing direction.
These cleaning blade 8a and lubricant smoothing blade 3e
are made of rubber that is an elastic body.
The toner image carried on the surface of the
photoconductor 1 is transferred to a transfer material, and
then the toner remaining thereon is first removed by the
cleaning blade 8a. Thereby, the surface of the
photoconductor 1 becomes clean, and is contacted by the
brush roller 3a, so that the lubricant is applied to the
surface thereof. The surface of the lubricant applied is
smoothed to be uniformly spread when passing through the
zone where the lubricant contacts the lubricant smoothing
blade 3e that is provided on the downstream side in the
movement direction of the surface of the photoconductor 1,
thereby forming a layer of the lubricant having a uniform
thickness.
In the image forming apparatus according to the
present invention, an "area applied with the lubricant"
means an area where the lubricant is spread by the
lubricant smoothing blade 3e and a lubricant layer having
the uniform thickness is formed. The area applied with the
lubricant "covers" an "area cleaned by the cleaning blade"
or a contact portion of the cleaning blade 8a with the
photoconductor 1. Consequently, the frictional coefficient
of the photoconductor 1 can be reduced stably over the
whole area where the cleaning blade 8a contacts the
photoconductor 1. Even if toner such as polymer toner of
which circularity is high (0.95 or higher) and the toner is
difficult to be cleaned by the blade, cleaning performance

can be kept satisfactory.
In the image forming apparatus according to the
present invention, the "area applied with the lubricant",
that is, the area where the lubricant is spread by the
lubricant smoothing blade 3e and the lubricant layer having
the uniform thickness is formed, is substantially same as
the "area cleaned by the cleaning blade" or the contact
portion of the cleaning blade 8a with the photoconductor 1.
Consequently, the frictional coefficient of the
photoconductor 1 can be reduced stably over the whole area
where the cleaning blade 8a contacts the photoconductor 1,
and cleaning performance can be kept satisfactory.
In the image forming apparatus according to the
present invention, the cleaning blade 8a is provided on the
upstream side of the lubricant applying device 3 in the
direction of rotation of the photoconductor 1, and the
lubricant smoothing blade 3e is provided on the downstream
side in the same direction as above. Longitudinal widths
of these blades in contact with the photoconductor 1 have a
relation of "width of applying brush roller" lubricant smoothing blade". More specifically, when the
width of the lubricant smoothing blade 3e is equal to or
larger than the width of the brush roller 3a of Fig. 2, the
whole lubricant applied by the brush roller 3a along the
longitudinal direction of the photoconductor 1 can be
spread by the lubricant smoothing blade 3e, to form a layer
of the lubricant having the uniform thickness. Accordingly,
the charging device 2 can be prevented from contamination
due to the lubricant.
In the image forming apparatus according to the
present invention, longitudinal widths as follows in
contact with the photoconductor 1 have a relation of "width
of lubricant'^'width of applying brush roller". More

specifically, when the width of the brush roller 3a is
equal to or larger than the width of the solid lubricant 3b
of Fig. 2, the following effect can be obtained.
If the brush is shorter than the lubricant, the
lubricant is scraped in a U shape, and both edges of the
lubricant touch a brush shaft. Therefore, the lubricant
cannot be used to the last portion, and this causes the
amount of waste to be increased or causes the bristle
length of the brush to be restricted. In this case, if the
bristle length of the brush is shorter, then the lubricant
is more wasted.
Therefore, the present invention has such a
configuration as "width of lubricant" brush roller", thereby using the lubricant without waste,
and hence, there is no need to restrict the bristle length
of the brush.
The image forming apparatus according to the present
invention has a relation of "width of charged area" of applied lubricant" in the longitudinal direction of the
photoconductor 1. More specifically, when the width of the
lubricant smoothing blade 3e (Fig. 2) is equal to or larger
than the width of the charging roller 2a (Fig. 18), the
whole range of a contact area of the photoconductor 1 with
the charging roller 2a is uniformly applied with the
lubricant, and the frictional coefficient of the
photoconductor 1 can be reduced stably in all over the
contact area, thereby obtaining the following effect.
A very small amount of the lubricant that is supposed
to be applied to the photoconductor shifts to the surface
of the charging roller when the charging roller contacts
the photoconductor. Even if the charging roller does not
contact the photoconductor, it may also shift thereto by
the action of the electric field. If the adhesion amount

of the lubricant to the surface of the charging roller due
to the shift is not uniform on the surface of the charging
roller, a charge amount (potential) on the photoconductor
becomes also nonuniform. By employing the configuration
according to the present invention, the lubricant is
uniformly applied over the whole range of the contact area
of the photoconductor 1 with the charging roller 2a, and
the amount of lubricant shifted to the surface of the
charging roller does not become nonuniform in the axial
direction of the charging roller, which allows stable
charging.
In the first embodiment, the cleaning blade 8a is used
to clean the surface of the photoconductor 1, but instead
of the cleaning blade 8a, a cleaning brush may be used.
The cleaning brush is obtained by applying bias to a
conductive brush having a resistance between a medium
resistance and a low resistance.
However, the present invention is not limited by the
first embodiment, and is applicable to all devices using
the technological principle of the present invention. The
photoconductor or the intermediate transfer element may be
either the belt shape or the roller shape.
In the image forming apparatus according to the
present invention, the frictional coefficient U on the
image carrier 1 is set to 0.4 or less. If JJ. is greater
than 0.4, occurrence of the filming cannot be sufficiently
prevented.
The frictional coefficient of the photoconductor 1 was
measured by using an Euler belt method in the following
manner. Fig. 4 is a diagram for explaining how to measure
a frictional coefficient of the photoconductor 1. In this
case, good quality paper with a medium thickness is used as
a belt. This paper is suspended around 1/4 of a drum

circumference of the photoconductor 1 so that the paper is
set in its longitudinal direction, and a weight of, for
example, 0.98 N (100 gr) is suspended at one end of the
belt, and a force gauge (digital push-pull gauge) is
provided at the other end thereof. The force gauge is
pulled, and when the belt moves, the weight is read to
calculate a frictional coefficient by substituting the
weight read in an equation: frictional coefficient
u=2/7txln (F/0.98) (where \i: static frictional coefficient,
F: measured value). The frictional coefficient of the
photoconductor 1 is a value when the photoconductor 1
enters into a steady state after image formation. This is
because the frictional coefficient of the photoconductor 1
is affected by another device also provided in the image
forming apparatus, and hence the value, out of other values,
of the frictional coefficient immediately after image
formation changes first. However, after image formation of
about 1,000 sheets of A4 recording paper, the value of the
frictional coefficient becomes an almost fixed value.
Therefore, the frictional coefficient mentioned here is a
frictional coefficient when the frictional coefficient
becomes a fixed value in this steady state.
In the image forming apparatus according to the
present invention, the cleaning blade has a side seal for
preventing toner scattering, and the side seal allows
adjustment of an area applied with the lubricant. In Fig.
3, a side seal 11 is provided in both ends of the cleaning
blade 8a in its width direction to contact the
photoconductor 1, and the contact positions of the side
seals 11 are adjusted in the longitudinal direction of the
photoconductor 1, thereby adjusting the area applied with
the lubricant. Therefore, if the lubricant is applied
beyond the cleaning area, the area applied with the

lubricant can be adjusted only by adjusting the positions
of the side seals 11. This allows achievement of the
object of the present invention such that the frictional
coefficient of the photoconductor is reduced stably over
the whole area of the photoconductor which the cleaning
blade 8a contacts.
Even if the toner as follows is used, satisfactory
cleaning capability can be obtained. The toner has a small
particle size such that a volume-average particle size of
toner particles is 3 to 8 micrometers and a ratio (Dv/Dn)
between a volume-average particle size (Dv) and a number-
average particle size (Dn) is in a range from 1.00 to 1.40,
and has a narrow particle size distribution. By narrowing
the particle size distribution of toner particles, a charge
amount distribution becomes uniform, thereby obtaining a
high quality image with less background fogging, and
increasing a transfer rate. Such toner of a small particle
size is difficult to be cleaned by the conventional blade
method because the cleaning force does not exceed the
adhesion force of the toner to the photoconductor 1.
Furthermore, if toner particles are small sized, the
percentage of external-additive particles in the toner
particles tends to be relatively high, and hence, the
external-additive particles easily drop out from the toner
particles, which causes filming to occur on the
photoconductor 1. However, by using the cleaning device 8
of the present invention, the brush roller 3a applies the
lubricant to the surface of the photoconductor 1 to reduce
the frictional coefficient of the photoconductor 1, and the
cleaning blade 8a blocks the toner particles, to prevent
them from their slipping through the cleaning blade 8a,
thereby improving the cleaning performance.
Furthermore, the present invention is suitable for

cleaning of spherical toner. The spherical toner particle
can be defined by values of the shape factor SF-1 and the
shape factor SF-2 as follows. The toner particles used in
the image forming apparatus of the present invention are
such that the shape factor SF-1 is from 100 to 180 and the
shape factor SF-2 is from 100 to 180.
Fig. 5A and Fig. 5B are schematic diagrams of toner
shapes for explaining the shape factor SF-1 and the shape
factor SF-2. The shape factor SF-1 represents the degree
of sphericity of a toner shape, and is expressed by the
following expression (1). The shape factor SF-1 is a value
obtained by dividing the square of a maximum length MXLNG
of a shape, which is obtained by projecting a toner
particle onto a two-dimensional plane, by its graphics area
AREA, and by multiplying the quotient by 100 π/4.
SF-1={ (MXLNG) 2/AREA}x (100 π/4) (1)
If the value of SF-1 is 100, the shape of toner
becomes perfect sphericity, and the shape becomes more and
more irregular as the value of SF-1 rises.
The shape factor SF-2 represents the degree of
irregularities of a toner shape, and is expressed by the
following expression (2). The shape factor SF-2 is a value
obtained by dividing the square of a peripheral length PERI
of a shape, which is obtained by projecting a toner
particle onto a two-dimensional plane, by its graphics area
AREA, and by multiplying the quotient by 100 π/4.
SF-2={ (PERI) 2/AREA}x (100 π/4) (2)
If the value of SF-2 is 100, the surface of toner has
no irregularities, and the surface becomes more and more
irregular as the value of SF-2 rises.
The shape factor was measured specifically by
photographing a toner particle with a scanning electron

microscope (S-800: manufactured by Hitachi Ltd.),
introducing the photograph into an image analyzer (LUZEX3:
manufactured by Nireco Corp.), and analyzing and
calculating it.
If the toner has a high sphericity, a contact between
a toner particle and a toner particle or between a toner
particle and the photoconductor 1 becomes a point contact,
which causes an attracting force between the toner
particles to get weak. Therefore, fluidity becomes higher
as the attracting force gets weaker. The attracting force
between a toner particle and the photoconductor 1 also gets
weak, and as a result, a transfer ratio becomes high. As
explained above, the spherical toner is easy to cause
cleaning failure in the cleaning using the blade method,
but by using the cleaning device 8 according to the present
invention, satisfactory cleaning can be performed. If the
SF-1 and the SF-2 are too large, toner scatters over an
image, and image quality is thereby degraded, and hence, it
is preferable that the SF-1 and the SF-2 do not exceed 180.
The shape of the toner according to the present
invention is substantially spherical, and can be expressed
by the following shape definition.
Fig. 6A, Fig. 6B, and Fig. 6C are schematic diagrams
of the shape of the toner according to the present
invention. As shown in Fig. 6A to Fig. 6C, assume that a
substantially spherical toner is defined by a major axis rl,
a minor axis r2, and a thickness r3 (where rl > r2 > r3) .
The toner particle according to the present invention
preferably ranges as follows: a ratio between the minor
axis and the major axis (r2/rl) (see Fig. 6B) ranges from
0.5 to 1.0, and a ratio between the thickness and the minor
axis (r3/r2) (see Fig. 6C) ranges from 0.7 to 1.0. If the
ratio between the minor axis and the major axis (r2/rl) is

less than 0.5, the toner shape is not close to the perfect
sphericity, and hence, dot reproducibility and transfer
efficiency are degraded, and a high quality image cannot be
obtained. If the ratio between the thickness and the minor
axis (r3/r2) is less than 0.7, the toner shape is close to
a flat shape, and hence, a high transfer rate as that of
the spherical toner cannot be obtained. Particularly, if
the ratio between the thickness and the minor axis (r3/r2)
is 1.0, the toner becomes a "rotating body" with its major
axis as a rotational axis, thereby improving the fluidity
of toner.
The rl, r2, and r3 were measured by observing and
photographing a toner particle with a scanning electron
microscope (SEM) while changing an angle of a visual field.
The toner adequately used in the image forming
apparatus according to the present invention is obtained by
allowing a toner material solution to undergo crosslinking
reaction and/or elongation reaction in an aqueous medium.
More specifically, the toner material solution is obtained
by dissolving or dispersing at least a polyester prepolymer
having a functional group that contains nitrogen atoms, a
polyester, a colorant, and a release agent, in an organic
solvent. Materials of and a method of manufacturing toner
are explained below.
Modified Polyester:
The toner of the present invention contains modified
polyester (i) as a binder resin. The modified polyester
(i) means a bond group other than ester bonds exists in
polyester resin, or in which resin components of which
structure is different are bonded by covalent bond or ionic
bond in polyester resin. More specifically, the modified
polyester (i) is a functional group such as an isocyanate

group that reacts with a carboxylic acid group and a
hydroxyl group is introduced to polyester end, and is made
to react with an active-hydrogen-containing compound to
modify the polyester end.
Examples of the modified polyester (i) include a urea-
. modified polyester obtained by reaction between an
isocyanate group-containing polyester prepolymer (A) and an
amine group (B), and the like. Examples of the isocyanate
group-containing polyester prepolymer (A) include reaction
products of a polyester with a polyisocyanate compound
(PIC), and the like. More specifically, the polyester is a
polycondensation product between a polyhydric alcohol (PO)
and a polycarboxylic acid (PC), and has an active hydrogen
group. Examples of the active hydrogen group of the
polyester are hydroxyl groups such as an alcoholic hydroxyl
group and a phenolic hydroxyl group, an amino group, a
carboxyl group, a mercapto group, and the like. Among them,
the alcoholic hydroxyl group is preferred.
The urea-modified polyester is produced in the
following manner.
Examples of polyhydric alcohol compounds (PO) include
dihydric alcohol (DIO) and trihydric or more alcohols (TO) ;
and dihydric alcohol (DIO) alone or a mixture of dihydric
alcohol (DIO) with a small amount of trihydric alcohol (TO)
is preferable. Examples of dihydric alcohol (DIO) include
alkylene glycol (e.g. ethylene glycol, 1,2-propylene glycol,
1,3-propylene glycol, 1,4-butanediol, and 1,6-hexanediol) ;
alkylene ether glycols (e.g. diethylene glycol, triethylene
glycol, dipropylene glycol, polyethylene glycol,
polypropylene glycol, and polytetramethylene ether glycol);
alicyclic diols (e.g. 1,4-cyclohexane dimethanol, and
hydrogenated bisphenol A); bisphenols (e.g. bisphenol A,
bisphenol F, and bisphenol S); adducts of alkylene Oxide Of

the alicyclic diols (e.g. ethylene oxide, propylene oxide,
and butylene oxide); and adducts of alkylene oxide of the
bisphenols (e.g. ethylene oxide, propylene oxide, and
butylene oxide). Among these, alkylene glycol having a
carbon number from 2 to 12 and the adducts of alkylene
oxides of the bisphenols are preferable. Particularly
preferable are the adducts of alkylene oxides of the
bisphenols, and a combination of the adducts of alkylene
oxides of the bisphenols and alkylene glycol having a
carbon number from 2 to 12. Trihydric or more alcohols
(TO) include trihydric to octahydric alcohols and more
aliphatic alcohols (e.g. glycerol, trimethylolethane,
trimethylolpropane, pentaerythritol, and sorbitol);
trivalent or more phenols (e.g. trisphenol PA, phenol
novolak, and cresol novolak); and adducts of alkylene
oxides of the trivalent or more polyphenols.
Examples of a polyvalent carboxylic acid (PC) include
a divalent carboxylic acid (DIC) and a trivalent or more
carboxylic acid (TC). The divalent carboxylic acid (DIC)
alone and a mixture of the divalent carboxylic acid (DIC)
and a small amount of the trivalent or more carboxylic acid
(TC) are preferable. Examples of divalent carboxylic acids
(DIC) include alkylene dicarboxylic acids (e.g. succinic
acid, adipic acid, and sebacic acid); alkenylene
dicarboxylic acids (e.g. maleic acid and fumaric acid); and
aromatic dicarboxylic acids (e.g. phthalic acid,
isophthalic acid, terephthalic acid, and naphthalene
dicarboxylic acid). Among these, the alkenylene
dicarboxylic acids having a carbon number from 4 to 20 and
the aromatic dicarboxylic acids having a carbon number from
8 to 20 are preferred. Examples of trivalent or more
carboxylic acids (TC) include aromatic polyvalent
carboxylic acids having a carbon number from 9 to 20 (e.g.

trimellitic acid and pyromellitic acid). The polyvalent
carboxylic acid (PC) may be reacted with polyhydric alcohol
(PO) using acid anhydrides of these or lower alkyl esters
(e.g. methyl ester, ethyl ester, and isopropyl ester).
A ratio between the polyhydric alcohol (PO) and the
polyvalent carboxylic acid (PC) is usually from 2/1 to 1/1,
preferably from 1.5/1 to 1/1, more preferably from 1.3/1 to
1.02/1, as an equivalent ratio of [OH]/[COOH] between a
hydroxy1 group [OH] and a carboxyl group [COOH].
Examples of polyvalent isocyanate compounds (PIC) are
aliphatic polyvalent isocyanates (e.g. tetramethylene
diisocyanate, hexamethylene diisocyanate, and 2,6-
diisocyanate methyl caproate); alicyclic polyisocyanates
(e.g. isophorone diisocyanate and cyclohexylmethane
diisocyanate); aromatic diisocyanates (e.g. tolylene
diisocyanate and diphenylmethane diisocyanate); aromatic
aliphatic diisocyanates (e.g. a,a,cc',a'-
tetramethylxylylene diisocyanate); isocyanates; compounds
formed by blocking these polyisocyanates by a phenol
derivative, an oxime, and a caprolactam; and a combination
of at least two of these.
A ratio of the polyvalent isocyanate compounds (PIC)
is usually from 5/1 to 1/1, preferably from 4/1 to 1.2/1,
and more preferably from 2.5/1 to 1.5/1, as an equivalent
ratio of [NCO]/[OH] between an isocyanate group [NCO] and a
hydroxyl group [OH] of a hydroxy1 group-containing
polyester. When [NCO]/[OH] exceeds 5, the low-temperature
fixing property gets worse. In a case of using urea-
modified polyester, the urea content in the ester becomes
low when a molar ratio of [NCO] is less than 1, and hot
offset resistance deteriorates.
The content of the polyvalent isocyanate compound
(PIC) in the isocyanate group-containing polyester

prepolymer (A) ranges usually from 0.5 wt.% to 40 wt.%,
preferably from 1 wt.% to 30 wt.%, and more preferably from
2 wt.% to 20 wt.%. If the content of the polyvalent
isocyanate compound is less than 0.5 wt.%, the hot offset
resistance deteriorates, and it is unfavorable from the
viewpoint of compatibility of heat resistant preservability
and low-temperature fixing property. On the other hand, if
the content of the polyvalent isocyanate compound exceeds
40 wt.%, the low-temperature fixing property gets worse.
The number of isocyanate groups contained in one
molecule of the isocyanate group-containing polyester
prepolymer (A) is usually at least 1, preferably, an
average of 1.5 to 3, and more preferably, an average of 1.8
to 2.5. If the isocyanate group per molecule is less than
1, then the molecular weight of the urea-modified polyester
becomes low and the hot offset resistance deteriorates.
Further, amines (B) that are reacted with the
polyester prepolymer (A) include divalent amine compounds
(Bl), trivalent or more amine compounds (B2), amino
alcohols (B3), amino mercaptans (B4), amino acids (B5), and
the compounds (B6) of Bl to B5 in which their amino groups
are blocked.
Examples of the divalent amine compounds (Bl) include
aromatic diamines (e.g. phenylene diamine, diethyl toluene
diamine, and 4,4'-diaminodiphenyl methane); alicyclic
diamines (e.g. 4,4'-diamino-3,3'-
dimethyldicyclohexylmethane, diamine cyclohexane, and
isophorone diamine); and aliphatic diamines (e.g. ethylene
diamine, tetramethylene diamine, and hexamethylene diamine).
Examples of the trivalent or more amine compounds (B2)
include diethylene triamine and triethylene tetramine.
Examples of the amino alcohols (B3) include ethanolamine
and hydroxyethylaniline. Examples of the amino mercaptans

(B4) include aminoethyl mercaptan and aminopropyl mercaptan.
Examples of the amino acids (B5) include aminopropionic
acid and aminocaproic acid. Examples of the compounds (B6),
in which the amino groups of Bl to B5 are blocked, include
ketimine compounds obtained from the amines of Bl to B5 and
ketones (e.g. acetone, methyl ethyl ketone, and methyl
isobutyl ketone), and oxazolidine compounds. The
preferable amines among the amines (B) are Bl and a mixture
of Bl with a small amount of B2.
A ratio of amines (B) is usually 1/2 to 2/1,
preferably 1.5/1 to 1/1.5, and more preferably 1.2/1 to
1/1.2 as an equivalent ratio of [NCO]/[NHx] between an
isocyanate group [NCO] in the isocyanate group-containing
polyester prepolymer (A) and an amine group [NHx] in the
amines (B). When [NCO]/[NHx] exceeds 2 or is less than 1/2,
the molecular weight of the urea-modified polyester becomes
smaller, resulting in deterioration in hot offset
resistance.
Moreover, an urethane bond may be contained together
with an urea bond in the urea-modified polyester. A molar
ratio of the urea bond content and the urethane bond
content ranges usually from 100/0 to 10/90, preferably from
80/20 to 20/80, and more preferably from 60/40 to 30/70.
If the molar ratio of the urea bond is less than 10%, the
hot offset resistance deteriorates.
The modified polyester (i) used in the present
invention is manufactured by a one shot method and a
prepolymer method. The weight-average molecular weight of
the modified polyester (i) is usually not less than 10,000,
preferably 20,000 to 10,000,000, and more preferably 30,000
to 1,000,000. The peak molecular weight at this time is
preferably 1,000 to 10,000, and when it is less than 1,000,
the modified polyester (i) is not easily elongated and the

elasticity of toner is low, resulting in deterioration in
the hot offset resistance. When it exceeds 10,000, tasks
in manufacturing such as reduction of fixing property,
smaller particle, and pulverization are more difficult to
achieve. A number-average molecular weight of the modified
polyester (i) is not particularly limited when a native
polyester (ii) explained later is used, and the number-
average molecular weight should be one which is easily
obtained to get a weight-average molecular weight. When
the modified polyester (i) is used alone, the number-
average molecular weight is usually 20,000 or less,
preferably 1,000 to 10,000, and more preferably 2,000 to
8,000. When the number-average molecular weight exceeds
20,000, the low-temperature fixing property deteriorates
and the glossiness also deteriorates when used for full-
color apparatus.
A reaction inhibitor is used as required for
crosslinking reaction between a polyester prepolymer (A)
and amines (B) to obtain the modified polyester (i) and/or
elongation reaction, thereby adjusting the molecular weight
of the urea-modified polyester obtained. Examples of the
reaction inhibitor include monoamines (e.g., diethylamine,
dibutylamine, butylamine, and laurylamine), and compounds
(ketimine compounds) in which the monoamines are blocked.
Native Polyester:
In the present invention, the modified polyester (i)
can be used alone, and also a native polyester (ii) can be
contained together with (i) as a binder resin component.
By using (i) in combination with the native polyester (ii) ,
the low-temperature fixing property is improved and the
glossiness is also improved when used for full-color
apparatus, which is more preferable than a single use of

(i). Examples of the native polyester (ii) include
polycondensation of polyhydric alcohol (PO) and polyvalent
carboxylic acid (PC), similarly to the polyester component
of (i), and preferred compounds are also the same as (i).
The native polyester (ii) may be not only a native
polyester but also modified one through a chemical bond
other than an urea bond, for example, (ii) may be modified
with an urethane bond. It is preferable that at least
parts of (i) and (ii) are compatible with each other, from
viewpoint of low-temperature fixing property and hot offset
resistance. Therefore, polyester components of (i) and
(ii) have preferably similar compositions. A weight ratio
between (i) and (ii) when (ii) is contained is usually 5/95
to 80/20, preferably 5/95 to 30/70, more preferably 5/95 to
25/75, and particularly preferably 7/93 to 20/80. When the
weight ratio of (i) to (ii) is less than 5%, the hot offset
resistance deteriorates, and this becomes disadvantageous
in respect of compatibility between heat resistant
preservability and low-temperature fixing property.
The peak molecular weight of (ii) is usually 1,000 to
10,000, preferably 2,000 to 8,000, and more preferably
2,000 to 5,000. When it is less than 1,000, heat resistant
preservability deteriorates, and when it exceeds 10,000,
low-temperature fixing property deteriorates. A hydroxyl
value of (ii) is preferably 5 or more, more preferably 10
to 120, and particularly preferably 20 to 80. When it is
less than 5, it becomes disadvantageous in respect of
compatibility between the heat resistant preservability and
the low-temperature fixing property. An acid value of (ii)
is preferably 1 to 5, and more preferably 2 to 4. Since a
wax having a high acid value is used, the binder is a low
acid value binder that leads to charging and high volume
resistance. Therefore, the binder is suitable for the

toner used in a two-component developer.
A glass transition point (Tg) of binder resin is
usually set to be 35° C. to 70° C, and preferably 55° C. to
65° C. If Tg is less than 35° C. , the heat resistant
preservability of toner deteriorates. On the other hand,
if Tg exceeds 70° C, the low temperature fixing property
becomes insufficient. An urea-modified polyester is likely
to be on the surfaces of obtained toner base particles.
Therefore, the toner according to the present invention
tends to show better heat resistant preservability as
compared with known polyester toner, even if the glass
transition point is low.
Colorant:
All known dyes and pigments are available for a
colorant, and the followings and mixtures thereof can be
used: for example, carbon black, nigrosine dye, iron black,
naphthol yellow S, Hansa yellow (10G, 5G, G), cadmium
yellow, yellow iron oxide, yellow ocher, chrome yellow,
titanium yellow, polyazo yellow, oil yellow, Hansa yellow
(GR, A, RN, R), pigment yellow L, benzidine yellow (G, GR),
permanent yellow (NCG), vulcan fast yellow (5G, R) ,
tartrazine lake, quinoline yellow lake, anthrazane yellow
BGL, isoindolinone yellow, red iron oxide, minium, red lead,
cadmium red, cadmium mercury red, antimony vermilion,
permanent red 4R, para red, fire red, parachloro-ortho-
nitroaniline red, lithol fast scarlet G, brilliant fast
scarlet, brilliant carmine BS, permanent red (F2R, F4R, FRL,
FRLL, F4RH), fast scarlet VD, vulcan fast rubin B,
brilliant scarlet G, lithol rubin GX, permanent red F5R,
brilliant carmine 6B, pigment scarlet 3B, bordeaux 5B,
toluidine maroon, permanent bordeaux F2K, helio bordeaux BL,

bordeaux 10B, BON maroon light, BON maroon medium, eosin
lake, rhodamine lake B, rhodamine lake Y, alizarin lake,
thioindigo red B, thioindigo maroon, oil red, quinacridone
red, pyrazolone red, polyazo red, chrome vermilion,
benzidine orange, perinone orange, oil orange, cobalt blue,
cerulean blue, alkali blue lake, peacock blue lake,
Victoria blue lake, metal-free phthalocyanine blue,
phthalocyanine blue, fast sky blue, indanthrene blue (RS,
BC), indigo, ultramarine blue, Prussian blue, anthraquinone
blue, fast violet B, methyl violet lake, cobalt violet,
manganese violet, dioxane violet, anthraquinone violet,
chrome green, zinc green, chrome oxide, pyridian, emerald
green, pigment green B, naphthol green B, green gold, acid
green lake, malachite green lake, phthalocyanine green,
anthraquinone green, titanium oxide, zinc white, and
lithopone. The content of the colorant is usually 1 wt.%
to 15 wt.%, and preferably 3 wt.% to 10 wt.% in toner
particles.
The colorant can also be used as a master batch mixed
with resin. Examples of binder resin used to manufacture
such a master batch or to be kneaded with the master batch
include styrenes such as polystyrene, poly-p-chlorostyrene,
polyvinyltoluene, and substituted polymer thereof, or
copolymer of these compounds and vinyl compounds,
polymethyl methacrylate, polybutyl methacrylate, polyvinyl
chloride, polyvinyl acetate, polyethylene, polypropylene,
polyester, epoxy resin, epoxy polyol resin, polyurethane,
polyamide, polyvinyl butyral, polyacrylate resin, rosin,
modified rosin, terpene resin, aliphatic or alicyclic
hydrocarbon resin, aromatic petroleum resin, chlorinated
paraffin, and paraffin wax. These materials can be used
alone or as a mixture thereof.

Charge Control Agent:
Known charge control agents can be used as a charge
control agent, and include, for example, nigrosine dyes,
triphenylmethane dyes, chromium-containing metal complex
dyes, chelate molybdate pigment, rhodamine dyes, alkoxy
amine, quaternary ammonium salt (including fluorine
modified quaternary ammonium salt), alkylamide, phosphorus
alone or compounds thereof, tungsten alone or compounds
thereof, fluorine-based active agents, salicylic acid metal
salts, and metal salts of salicylic acid derivatives. More
specific examples of the charge control agents are Bontron
03 as nigrosine dyes, Bontron P-51 as quaternary ammonium
salts, Bontron S-34 as metal-containing azo dyes, E-82 as
oxynaphthoic acid type metal complex, E-84 as salicylic
acid metal complex, E-89 as phenol type condensate (these
are manufactured by Orient Chemical Industries, Ltd.), TP-
302 and TP-415 as quaternary ammonium salt molybdenum
complexes (manufactured by Hodogaya Chemical Industries,
Ltd.), Copy Charge PSY VP2038 as quaternary ammonium salt
and Copy Charge NX VP434 as quaternary ammonium salt (these
are manufactured by Hoechst Co., Ltd.), LRA-901 and LR-147
as boron complex (manufactured by Japan Carlit Co., Ltd.),
copper phthalocyanine, perylene, quinacridone, azo type
pigments, and polymer compounds having a functional group
such as a sulfonic acid group, a carboxyl group, and a
quaternary ammonium salt group. Among these, a material
that controls the toner to have negative polarity is
preferably used.
The use amount of the charge control agent is
determined depending on the type of binder resins, presence
or absence of additives to be used as required, and a
method of manufacturing toner including a dispersion method,
and hence, it is not uniquely limited. However, the charge

control agent is used preferably in a range from 0.1 to 10
parts by weight (wt. parts), and more preferably from 0.2
to 5 wt. parts, per 100 wt. parts of the binder resin. If
it exceeds 10 wt. parts, the toner is charged too highly,
which causes effects of the charge control agent to be
decreased, electrostatic attracting force with a developing
roller to be increased, fluidity of the developer to be
lowered, and image density to be reduced.
Release Agent:
A wax having a low melting point in a range from 50° C.
to 120° C. effectively functions as a release agent between
a fixing roller and a toner boundary in dispersion with
binder resin. Due to this effective functioning of the wax,
there is no need to apply a release agent as oil to the
fixing roller and the high temperature offset is improved.
Such wax components include the followings. Examples of
waxes include waxes from plants such as carnauba wax,
cotton wax, wood wax, and rice wax; waxes from animals such
as beeswax and lanolin; waxes from mineral substances such
as ozokerite and cercine; and petroleum waxes such as
paraffin, microcrystalline, and petrolatum. Examples of
waxes apart from these natural waxes include synthetic
hydrocarbon waxes such as Fischer-Tropsch wax and
polyethylene wax; and synthetic waxes such as ester, ketone,
and ether. In addition to these, a crystalline polymer of
which side chain has long alkyl group can be also used.
The crystalline polymer includes homo polymer or copolymer
of polyacrylate such as poly-n-stearyl methacrylate and
poly-n-lauryl methacrylate (for example, n-stearyl
acrylate-ethyl methacrylate copolymer), which are aliphatic
amide such as 12-hydroxy stearamide, stearic acid amide,
phthalic anhydride imide, and chlorinated hydrocarbon; and

crystalline polymer resin having low molecular weight.
The charge control agent and the release agent can be
fused and mixed with the master batch and the binder resin,
and may be added to organic solvent at a time of
dissolution and dispersion.
External Additive:
Inorganic fine particles are preferably used as an
external additive to facilitate fluidity, developing
performance, and chargeability of toner particles. Such an
inorganic fine particle has preferably a primary particle
diameter of 5xl0"3 to 2 micrometers. In particular, the
primary particle diameter is preferably 5xl0-3 to 0.5
micrometer. A specific surface area by the BET method is
preferably 20 to 500 m2/g. The use ratio of the inorganic
fine particles is preferably 0.01 wt.% to 5 wt.% in toner
particles, and more preferably 0.01 wt.% to 2.0 wt.%.
Specific examples of the inorganic particles include
silica, alumina, titanium oxide, barium titanate, magnesium
titanate, calcium titanate, strontium titanate, zinc oxide,
tin oxide, silica sand, clay, mica, wollastonite, diatomite,
chromium oxide, cerium oxide, red iron oxide, antimony
trioxide, magnesium oxide, zirconium oxide, barium sulfate,
barium carbonate, calcium carbonate, silicon carbide, and
silicon nitride. Among these materials, hydrophobic silica
particles and hydrophobic titanium oxide particles are
preferably used in combination as a fluidizing agent. In
particular, when both particles having an average diameter
of 5xl0~2 micrometers or less are mixed, electrostatic
force and Van der Waals force with toner particles are
significantly improved. As a result, even if such external
additives are mixed with toner particles in a developing

device to achieve a desired charge level, "firefly"(spot)-
free desirable image quality can be obtained without
desorption of the fluidizing agent from toner particles,
and further an amount of remaining toner after a toner
image is transferred can be reduced.
While titanium oxide fine particles are excellent in
environmental stability and image density stability, the
titanium oxide fine particles tend to exhibit degradation
in charge rising property. As a result, if an addition
amount of titanium oxide fine particles is more than that
of silica fine particles, this adverse effect becomes more
influential. However, if hydrophobic silica particles and
hydrophobic titanium oxide particles are added within 0.3
wt.% to 1.5 wt.%, desired charge rising property is
obtained without significant damage to the charge rising
property. In other words, even if an image is repeatedly
copied, stable image quality can be obtained.
A toner manufacturing method is explained below. Here,
exemplary embodiments of the toner manufacturing method are
explained below, but the present invention is not limited
to these embodiments.
Toner Manufacturing Method:
1) Toner material solution is produced by dispersing a
colorant, a native polyester, an isocyanate group-
containing polyester prepolymer, and a release agent in
organic solvent.
From the viewpoint of easy removal after formation of
toner base particles, it is preferable that the organic
solvent be volatile and have a boiling point of less than
100° C. More specifically, the followings can be used
solely or in combination with two or more types thereof,
such as toluene, xylene, benzene, carbon tetrachloride.

methylene chloride, 1,2-dichloroethane, 1,1,2-
trichloroethane, trichloroethylene, chloroform,
monochlorobenzene, dichloroethylidene,. methyl acetate,
ethyl acetate, methyl ethyl ketone, and methyl isobutyl
ketone. In particular, aromatic solvent such as toluene
and xylene, and halogenated hydrocarbon such as methylene
chloride, 1,2-dichloroethane, chloroform, and carbon
tetrachloride are preferred. The use amount of organic
solvent is usually 0 to 300 wt. parts for 100 wt. parts of
polyester prepolymer, preferably 0 to 100 wt. parts, and
further preferably 25 to 70 wt. parts.
2) The toner material solution is emulsified in
aqueous medium in the presence of a surfactant and resin
fine particles.
Such aqueous medium may be water alone or contain
organic 'solvent such" as alcohol {e.g. methanol, isopropyl
alcohol, and ethylene, glycol) , dimethyl formamide,
tetrahydrofuran, cellosolves (e.g. methyl cellosolve), and
lower ketones (e.g. acetone, methyl ethyl ketone).
The use amount of the aqueous medium for 100 wt. parts
of the toner material solution is usually 50 to 2,000 wt.
parts, and preferably 100 to 1,000 wt. parts. If the
amount is less than 50 wt. parts, the toner material
solution is poorly dispersed, and it is thereby impossible
to obtain toner particles having a predetermined particle
size. On the other hand, if the amount exceeds 20,000 wt.
parts, this is economically inefficient.
Further, to improve the dispersion in the aqueous
medium, a dispersing agent such as a surfactant and resin
fine particles are added as required.
Examples of the surfactant are anionic surfactants
such as alkyl benzene sulfonate, α-olefin sulfonate, and
ester phosphate; amine salts such as alkyl amine salts,

aminoalcohol fatty acid derivatives, polyamine fatty acid
derivatives, and imidazoline; cationic surfactants of
quaternary ammonium salt types such as alkyl trimethyl
ammonium salts, dialkyl dimethyl ammonium salts, alkyl
dimethyl benzyl ammonium salts, pyridinium salts, alkyl
isoquinolinium salts, and benzethonium chloride; nonionic
surfactants such as fatty acid amide derivatives and
polyhydric alcohol derivatives; and ampholytic surfactants
such as alanine, dodecyl di(aminoethyl) glycine,
di(octylaminoethyl) glycine, N-alkyl-N, and N-dimethyl
ammonium betaine.
Furthermore, a surfactant having a fluoroalkyl group
is used to achieve a desired effect with a very small
amount thereof. Preferable examples of anionic surfactants
having a fluoroalkyl group are fluoroalkyl carboxylic acids
having a carbon number from 2 to 10 and their metal salts;
disodium perfluorooctane sulfonyl glutamate, sodium 3-[co-
fluoroalkyl (C6 to Cll) oxy]-l-alkyl (C3 to C4) sulfonate,
sodium 3-[co-fluoroalkanoyl (C6 to C8) -N-ethylamino] -1-
propane sulfonate, fluoroalkyl (Cll to C20) carboxylic acid
and its metal salts; perfluoroalkyl carboxylic acid (C7 to
C13) and its metal salts; perfluoroalkyl (C4 to C12)
sulfonic acid and its metal salts, perfluorooctane sulfonic
acid diethanolamide, N-propyl-N-(2-hydroxyethyl)
perfluorooctane sulfonamide, perfluoroalkyl (C6 to CIO)
sulfonamide propyl trimethyl ammonium salts, perfluoroalkyl
(C6 to CIO)-N-ethylsulfonyl glycine salts,
monoperfluoroalkyl (C6 to C16) ethyl phosphoric acid esters.
Examples of trade names are SURFLON S-lll, S-112, and
S113 (manufactured by Asahi Glass Co., Ltd.), FLUORAD FC-93,
FC-95, FC-98, and FC-129 (manufactured by Sumitomo 3M Co.,
Ltd.), UNIDINE DS-101 and DS-102 (manufactured by Daikin
Industries, Ltd.), MEGAFACE F-110, F-120, F-113, F-191, F-

812, and F-833 (manufactured by Dainippon Ink & Chemicals,
Inc.), EKTOP EF-102, 103, 104, 105, 112, 123A, 123B, 306A,
501, 201, and 204 (manufactured by Tochem Products Co.,
Ltd.), and FTERGENT F-100 and F150 (manufactured by Neos
Co., Ltd.).
Examples of cationic surfactants are aliphatic primary,
secondary, or tertiary amine containing a fluoroalkyl group,
aliphatic quaternary ammonium salt such as ammonium salt of
perfluoroalkyl (C6-C10) sulfonamide propyl trimethyl;
benzalkonium salts, benzethonium chloride, pyridinium salts,
and imidazolinium salts. Trade names thereof are SURFLON
S-121 (manufactured by Asahi Glass Co., Ltd.), FLUORAD FC-
135 (manufactured by Sumitomo 3M Co., Ltd.), UNIDYNE DS-202
(manufactured by Daikin Industries, Ltd.), MEGAFACE F-150
and F-824 (manufactured by Dainippon Ink & Chemicals, Inc.),
EKTOP EF-132 (manufactured by Tochem Products Co., Ltd.),
and FTERGENT F-300 (manufactured by Neos Co., Ltd.), or the
like.
The resin fine particles may be of any resin selected
from thermoplastic resins and thermosetting resins, if an
aqueous dispersion may be formed from the resin fine
particles. Examples of the resins include vinyl resins,
polyurethane resins, epoxy resins, polyester resins,
polyamide resins, polyimide resins, silicon resins, phenol
resins, melamine resins, urea resins, aniline resins,
ionomer resins, and polycarbonate resins. Two or more
types of these resins in combination may be used for the
resin fine particles.
Among these, vinyl resin, polyurethane resin, epoxy
resin, polyester resin, or combination thereof are
preferable, since aqueous dispersions of resin spherical
fine particles can be easily obtained. Examples of the
vinyl resins include resin of polymer in which vinyl

monomer is solely polymerized or co-polymerized, such as
styrene-methacrylic ester copolymers, styrene-butadiene
copolymers, methacrylic acid-acrylic ester copolymers,
styrene-acrylonitrile copolymers, styrene-maleic acid
anhydride copolymers, and styrene-methacrylic acid
copolymers. An average particle size of the resin fine .
particles is 5 to 200 nanometers, preferably 200 to 300
nanometers.
Moreover, inorganic dispersing agents such as calcium
phosphate tribasic, calcium carbonate, titanium oxide,
colloidal silica, and hydroxyapatite can also be used.
Dispersion droplets may be stabilized by a high
polymer protective colloid as a dispersing agent usable in
combination with the resin fine particles and the inorganic
dispersing agent. Examples are acids such as acrylic acid,
methacrylic acid, a-cyanoacrylic acid, a-cyanomethacrylic
acid, itaconic acid, crotonic acid, fumaric acid, maleic
acid, or maleic anhydride; or methacrylic monomers
containing a hydroxyl group such as p-hydroxyethyl acrylate,
p-hydroxyethyl methacrylate, p-hydroxypropyl acrylate, |3-
hydroxypropyl methacrylate, y-hydroxypropyl acrylate, y-
hydroxypropyl methacrylate, 3-chloro 2-hydroxypropyl
acrylate, 3-chloro 2-hydroxypropyl methacrylate, diethylene
glycol monoacrylic ester, diethylene glycol monomethacrylic
ester, glycerol monoacrylic ester, glycerol monomethacrylic
ester, N-methylol acrylamide, N-methylol methacrylamide;
vinyl alcohol or ethers with vinyl alcohol such as vinyl
methyl ether, vinyl ethyl ether, vinyl propyl ether; or
esters of compounds that contains a vinyl alcohol and a
carboxyl group such as vinyl acetate, vinyl propionate,
vinyl butyrate; acrylamide, methacrylamide, diacetone
acrylamide or their methylol compounds; acid chlorides such

as chloride acrylate and chloride methacrylate;
homopolymers or copolymers of nitrogen-containing compounds
such as vinylpyridine, vinylpyrrolidone, vinylimidazole,
and ethyleneimine or of heterocyclic ring thereof;
polyoxyethylene compounds such as polyoxyethylene,
polyoxypropylene, polyoxyethylene alkyl amine,
polyoxypropylene alkyl amine, polyoxyethylene alkyl amide,
polyoxypropylene alkyl amide, polyoxyethylene nonyl phenyl
ether, polyoxyethylene lauryl phenyl ether, polyoxyethylene
stearyl phenyl ester, and polyoxyethylene nonyl phenyl
ester; and a cellulose group such as methyl cellulose,
hydroxyethyl cellulose, and hydroxypropyl cellulose.
A dispersion method is not particularly limited, and
it is possible to use known facilities of a low-speed
shearing type, a high-speed shearing type, a friction type,
a high-pressure jet type, and an ultrasonic type. Among
these, the high-speed shearing type is preferred to obtain
dispersed particles having a particle size ranging from 2
to 20 micrometers. When a high-speed shearing type
dispersing machine is used, the number of revolutions is
not particularly limited, and is usually from 1,000
revolutions per minute (rpm) to 30,000 rpm, preferably from
5,000 rpm to 20,000 rpm. The dispersion time is not
particularly limited and is usually from 0.1 to 5 minutes
in a batch system. The dispersing temperature is usually
from 0° C. to 150° C. (under a pressure) , preferably from
40° C. to 98° C.
3) During preparation of an emulsified liquid, amines
(B) are added and are allowed to react with polyester
prepolymer (A) having an isocyanate group.
This reaction is followed by crosslinking and/or
elongation of a molecular chain. The reaction time is
selected according to the reactivity between an isocyanate

group structure of the polyester prepolymer (A) and amines
(B), and is usually 10 minutes to 40 hours, preferably 2
hours to 24 hours. The reaction temperature ranges usually
from 0° C. to 150° C, preferably from 40° C. to 98° C.
Moreover, a known catalyst can be used if necessary.
Specific examples of the catalyst are dibutyl tin laurate
and dioctyl tin laurate.
4) After completion of the reaction, the organic
solvent is removed from emulsified dispersion (reaction
compound), is washed, and dried to obtain the toner base
particles.
To remove the organic solvent therefrom, the whole
system is gradually heated up while laminar flow is stirred,
and is stirred vigorously at a fixed temperature range.
The solvent is removed from the dispersion, and then
spindle-shaped toner base particles are prepared. Further,
if a compound like calcium phosphate salt that can dissolve
in an acid or an alkali is used as a dispersion stabilizer,
after the calcium phosphate salt is dissolved in an acid
like hydrochloric acid, the calcium phosphate salt is
removed from the toner base particles by a method of
washing. In addition, the calcium phosphate salt can be
removed through decomposition by an enzyme.
5) A charge control agent is implanted into the toner
base particles thus obtained, and inorganic fine particles
such as those of silica and titanium oxide are added
externally to obtain the toner.
The implantation of the charge control agent and the
external addition of the inorganic fine particles are
carried out by a known method using a mixer and so on.
Accordingly, the toner having a small particle size
and a sharp particle-size distribution can be obtained
easily. Moreover, by vigorously stirring the toner in the

process of removing the organic solvent, the shape of
particles can be controlled in a range from a perfectly
spherical shape to a spindle shape. Furthermore, the
morphology of the surface can also be controlled in a range
from a smooth shape to a rough shape.
The configurations of the image forming apparatus, the
imaging unit, and the cleaning device according to a second
embodiment of the present invention are the same as these
in Fig. 1, Fig. 2, and Fig. 18, and hence, explanation
thereof is omitted.
In the present invention, the lubricant applying
device 3 is disposed inside the cleaning device 8 as explained with reference to Fig. 2. Pressing forces are
produced when the solid lubricant 3b is pressed against and
contacted with the brush roller 3a upwardly (from the lower
side of the brush) as shown in Fig. 2, when it is pressed
against and contacted withthe brush roller 3a sidewardly
(from the side of the brush), or when it is pressed against
and contacted with the brush roller 3a downwardly (from the
upper side of the brush) (not shown). Each of the pressing
forces and the deviations of pressing forces between the
initial time and the elapsed time (life) (initial pressing
force-elapsed time pressing force) are obtained.


It is understood from the table 1 that the pressing
force applied to the brush roller 3a and the deviation of
the pressing forces are different depending on the .
direction of pressing the solid lubricant 3b.
The pressing force and the deviation of the pressing
forces in an actual lubricant applying device are explained
below. The following two types of machines are used for
comparisons. When the solid lubricant 3b is pressed

downwardly, the deviation of the pressing forces increases
by 42% in model G and by 22% in model J as compared with
the case where the solid lubricant 3b is pressed upwardly.

It is understood from the table 2 that the application
amount of the lubricant largely fluctuates when the
deviation of the pressing force is large because the
required application amount of the lubricant is different
depending on the models and a multiplier of a pressure
spring to be used is different due to restriction to layout,
although the magnitudes of the deviation cannot be compared
between the models in a simple manner. Therefore, the

large fluctuations may lead to an excessive application in
the initial stage or to a shortage of application when time
is elapsed. Consequently, a smaller deviation of the
pressing force allows more stable application.
Accordingly, the arrangement, as shown in Fig. 2, in
which the solid lubricant 3b is pressed from the lower side
of the brush roller 3a, allows more stable application of
the lubricant as compared with the arrangements in which it
is pressed from the side and from the upper side of the
brush roller 3a.
Fig. 7 is a diagram of the solid lubricant 3b for the
lubricant applying device 3, when viewed from its
longitudinal direction as the front side.
The solid lubricant 3b molded into a rectangular solid
is fixed to the lubricant holding element 3d. A plurality
of pressing elements 3c-l and 3c-2 are provided in the
lubricant holding element 3d so as to be aligned in the
longitudinal direction thereof. The pressing elements 3c-l
and 3c-2 bias the solid lubricant 3b toward the side of the
brush roller 3a. The pressing force of the pressing
element 3c is adjusted so as to decrease the pressing force
of the pressing elements 3c-2 provided at a central area as
compared with that of the pressing elements 3c-l provided
at end areas in the longitudinal direction. When a
compressed spring is used as the pressing element 3c as
shown in Fig. 7, a spring pressure is changed between the
pressing element 3c-l and the pressing element 3c-2.
The reason that the pressing element 3c is provided in
plurality and the pressing force is made different between
the pressing element 3c-l and the pressing element 3c-2 in
the above manner is as follows. At first, if there is only
one pressing element 3c, the lubricant cannot be uniformly
applied in the longitudinal direction. If the pressing

forces of the pressing elements 3c are the same as one
another, then the pressing force of the pressing elements
3c-l positioned at the end areas in the longitudinal
direction easily escapes to the outside. Therefore, the
solid lubricant 3b undergoes larger pressure at its central
area in the longitudinal direction, which causes nonuniform
application of the lubricant. Consequently, the pressing
force of the pressing elements 3c-2 is controlled to be
lower than that of the pressing elements 3c-l, to balance
the pressures in the longitudinal direction of the solid
lubricant 3b, and the solid lubricant 3b is in contact with
the brush roller 3a at uniform pressure, thereby achieving
uniform application of the lubricant to the surface of the
photoconductor 1.
The example of Fig. 7 shows four pressing elements 3c,
but two or more, preferably three or more of pressing
elements 3c may be provided in the present invention. If
two pressing elements 3c are provided, the two are arranged
at both ends in the longitudinal direction, and hence, no
pressing element 3c is provided at the central area. This
loses the pressure balance in the longitudinal direction,
which causes nonuniform application to occur in the central
area in the longitudinal direction of the photoconductor 1.
Thus, three or more pressing elements 3c are aligned in a
row in the longitudinal direction, to take balance over the
whole area in the longitudinal direction, thereby enabling
further uniform application of the lubricant.
The pressing force of the solid lubricant 3b against
the brush roller 3a is controlled so that the total
pressure of the pressing forces of the pressing elements 3c
(3c-l and 3c-2 in Fig. 7) ranges from 200 to 1,000 mN. If
the total pressure is less than 200 mN, the brush roller 3a
cannot sufficiently scrape the solid lubricant 3b off,

which results in unsatisfactory application amount of the
lubricant for the surface of the photoconductor 1. This
promotes the wear of the cleaning blade 8a and the surface
of the photoconductor 1, and cleaning failure such that
toner remains after a toner image is transferred easily
occurs. If the total pressure exceeds 1,000 mN, the
application amount of the lubricant for the surface of the
photoconductor 1 becomes too much. This causes consumption
of the solid lubricant 3b to be quicker, and causes the
surface of the photoconductor 1 to be excessively applied
with the lubricant that contains hygroscopic fatty acid
metal salt, thereby being affected by humidity. This
causes an electrostatic latent image to be flowed, which
leads to such a failure as occurrence of the image blur.
Therefore, the solid lubricant 3b is pressed preferably at
the total pressure of 200 to 1,000 mN with respect to the
brush roller 3a.
The thickness of each brush fiber of the brush roller
3a is preferably 3 to 8 denials, and the density of brush
fibers is preferably 20,000 to 100,000/inch2. If the
thickness of the brush fiber is too thin, the bristles
become easily bent when the brush roller 3a contacts the
surface of the photoconductor 1. Conversely, if the brush
fiber is too thick, the density of the brush fibers cannot
be increased. If the density of the brush fibers is low,
the number of brush fibers contacting the surface thereof
is small, and hence, the lubricant cannot be uniformly
applied to the surface of the photoconductor 1. Conversely,
if the density of brush fibers is too high, a gap between a
fiber and a fiber becomes narrower, and an adhesion amount
of the powder of the lubricant scraped off is reduced,
which causes a shortage of the application amount.
The brush roller 3a is produced in the range set SUCh

that the thickness of the brush fiber is provided so as not
to be bent and the density of the brush fibers is provided
so as to efficiently perform uniform application of the
lubricant.
As shown in Fig. 2, the rotation direction of the
brush roller 3a is preferably in the forward direction with
respect to the movement direction of the photoconductor 1.
If the rotation direction of the brush roller 3a is in the
opposite direction to the movement direction of the
photoconductor 1, the powder of the lubricant adhered to
the brush fiber of the brush roller 3a is scattered by the
impact when the brush roller 3a contacts the surface of the
photoconductor 1, so that the uniform and efficient
application cannot be performed. As a result, the rotation
direction of the brush roller 3a is preferably in the
forward direction with respect to the movement direction of
the photoconductor 1.
The solid lubricant 3b is used in the same manner as
that explained in the first embodiment.
Features of the second embodiment are explained below.
The cleaning blade 8a, being a cleaning unit, is made to
contact the surface of the photoconductor 1 on the upstream
side in the movement direction of the photoconductor 1 with
respect to the zone where the lubricant is applied by the
brush roller 3a. Then a lubricant smoothing blade 8b,
being a lubricant smoothing unit, is made to contact the
surface of the photoconductor 1 on the downstream side in
the movement direction of the photoconductor 1 with respect
to the zone where the lubricant is applied. In the second
embodiment, as shown in Fig. 8A and Fig. 8B, the cleaning
blade 8a is made to contact the surface of the
photoconductor 1 from the counter direction, and the
lubricant smoothing blade 8b is made to contact the surface

thereof from the trailing direction. The cleaning blade 8a
and the lubricant smoothing blade 8b are made of rubber
which is an elastic body.
Based on the configuration above, a toner image
carried on the surface of the photoconductor 1 is
transferred to a transfer material, and the toner remaining
on the surface thereof after the toner image is transferred
is first removed by the cleaning blade 8a. The surface of
the photoconductor 1 becomes clean through the toner
removal, and the brush roller 3a contacts the surface
cleaned and applies the lubricant thereto. The surface of
the lubricant applied is uniformly spread when it is
passing through the zone, where the lubricant smoothing
blade 8b contacts the lubricant, which is on the downstream
side in the movement direction of the photoconductor 1, to
form a layer of the lubricant having a uniform thickness.
The lubricant applying device 3 and the cleaning
device 8 thus configured are provided in the image forming
apparatus, and an appropriate amount of lubricant is
applied to the surface of the photoconductor 1, which
allows formation of a uniform thin film of the lubricant
without nonuniform application.
After the remaining toner is cleaned in the above
manner, the lubricant is applied, and the lubricant applied
is smoothed to form a uniform layer, thereby preventing
both failures occurring in the cases of the "the cleaning
after the application" and the "the application after the
cleaning". More specifically, the deviation of the
application amount of lubricant and the deviation of the
static frictional coefficient of the surface due to the
"the cleaning after the application" are prevented to occur.
The abnormal images due to a nonuniform lubricant layer
caused by "the application after the cleaning" are also

prevented to occur. The abnormal images include the worm
hole, the image blur, and the rough image. At the same
time, the application function of the brush roller 3a can
also be maintained over the long period of time. Since the
rubber is used for the lubricant smoothing blade 8b, even
if the lubricant smoothing blade 8b moves along the
photoconductor 1 in its contact state, the surface of the
photoconductor 1 is not possibly damaged.
In the present invention, the wear of the cleaning
blade 8a and the surface of the photoconductor 1 can be
prevented, and the toner remaining on the surface thereof
after the toner image is transferred can be satisfactorily-
cleaned even if the spherical and small-sized toner
particles are used. Moreover, the image blur can be
prevented. The image blur may occur when the surface of
the photoconductor 1 is affected by humidity due to
excessive application of the lubricant.
In the second embodiment, the surface of the
photoconductor 1 is cleaned by the cleaning blade 8a, but a
cleaning brush may be used instead of the cleaning blade 8a.
The cleaning brush is obtained by applying bias to a
conductive brush having a resistance between a medium
resistance and a low resistance.
The present invention is not limited by the
embodiments, and is applicable to any device that uses the
technological principles of the present invention. The
photoconductor or the intermediate transfer element may be
either one of a belt shape and a roller shape.
A relation between the torque and the cleaning
performance according to the present invention is shown in
table 3 .
When only the cleaning blade is made to contact the
surface of the photoconductor, the torque is 10, but when

the lubricant is applied, the torque decreases to 8 even
when the lubricant smoothing blade 8b contacts the surface
thereof. The cleaning performance is not sufficient enough
to perform cleaning without the lubricant, but it is
improved with the lubricant, and then, the efficient
cleaning becomes possible.

The decrease in the torque allows energy saving, and a
motor can be minimized to allow low cost and space saving.
Fig. 9 is a schematic diagram for explaining a third
embodiment of the present invention. A lubricant applying
device according to the third embodiment is different from
that in Fig. 2. More specifically, in the lubricant
applying device of Fig. 2, the applying brush, being a
contact type, is used as an applying element. However, in
the third embodiment, an applying brush 3a1 being
noncontact with the surface of the photoconductor 1 is used.
In this device, a solid lubricant is not used but a powdery
lubricant 3b' is used. The rotation of the applying brush
3a allows compositions of the lubricant to float, and the
compositions are adhered to the surface of the
photoconductor 1.
Since the lubricant applying device thus configured
applies the lubricant in a noncontact manner, the torque
can decrease more than the second embodiment while the

cleaning performance the same as that of the second
embodiment is maintained. Therefore, further energy saving
is achieved, and the motor can be minimized to allow low
cost and space saving.
In the third embodiment, tests were conducted by
comparing a method according to the present invention with
the conventional method. The method according to the
present invention was such that the lubricant smoothing
blade 8b was made to contact the surface of the
photoconductor 1 in the trailing manner and the lubricant
applied was smoothed. As the result of the testing, the
effect of the present invention can be verified.
Effect Verification Test on Present Invention:
Present Invention:
First blade (Cleaning blade) (Upstream side: Counter
manner, Blade type: T7240, Thickness: 1.3 mm)
Applying device (Brush type: Insulation polyethylene
terephthalate (PET), Pressure to lubricant: 1250 mNx4)
Second blade (Lubricant smoothing blade) (Downstream
side: Trailing manner, Blade type: T7240, Thickness: 1.3
mm)
Conventional Method:
First blade (Upstream side: not provided)
Applying device (Brush type: Insulation PET, Pressure
to lubricant: 1250 mNx4)
Second blade (Cleaning blade) (Downstream side:
Counter manner, Blade type: T7240, Thickness: 1.3 mm)
The lubricant was applied under the conditions as
explained above, and comparisons were made on the
application amounts of the lubricant required to keep a
frictional coefficient of the surface of photoconductor:

µ=0.2 under the conditions of image formation in which a
rate of an image area of polymer toner is 50%.
Results are as follows:
Present Invention 0.04 g/km
Conventional Method 0.35 g/km
It is verified from the results that the present invention
employing the method of '"the application after the
cleaning" + smoothing blade is further highly effective in
reduction of the frictional coefficient of the surface of
the photoconductor, as compared with the conventional
method of "the cleaning after the application".
The following tests were conducted to obtain optimal
values of a contact angle and a contact pressure of the
second blade, being the lubricant smoothing blade according
to the present invention, with respect to the surface of
the photoconductor. As the result of the tests, the
following conditions which are suitable for implementation
of the present invention are obtained.
Test Conditions:
Second blade (Lubricant smoothing blade) (Blade
type: T7050, Thickness: 1.3 mm)
Fur brush (Brush type: SA7, No Brush flicker)
Charging roller (No roller, No cleaner)
Pressure to lubricant (Own weight: 36 g)
Contact angle and contact pressure of second blade
Contact angle: 9 degrees (Contact pressure 1400 mN,
2800 mN)
Contact angle: 19.7 degrees (Contact pressure 2200 mN)
Contact angle: 22.7 degrees (Contact pressure 1400 mN,
2800 mN)
The photoconductor unit was made to run idle under the
above conditions, and µ on the surface of the
photoconductor was measured at a predetermined time

interval. As the result, when the contact angle is 22.7
degrees and the contact pressure is 2800 mN, the frictional
coefficient is the minimum (minimum value 0.12, maximum
value 0.21), and the vibration of the unit is smaller than
other conditions, so that these conditions become the most
favorable. From the results, to efficiently reduce the
frictional coefficient of the surface of the photoconductor,
a larger angle of the blade is better, and a higher contact
pressure is better according to the range of the tests.
In the image forming apparatus according to the
present invention, the toner used in the developing device
4 preferably has a volume-average particle size ranging
from 3 to 8 micrometers, and has a ratio (Dv/Dn) between
the volume-average particle size (Dv) and the number-
average particle size (Dn) ranging from 1.00 to 1.40.
By using toner particles having a small particle size,
the toner particles can be densely adhered to a latent
image. However, if the volume-average particle size is
smaller than the range of the present invention, and if a
two-component developer is used, the toner particles are
fused onto the surfaces of magnetic carriers during
stirring of the developer for a long time in the developing
device, to reduce the charging capability of the magnetic
carriers. And if a one-component developer is used,
filming of the toner particles to the developing roller
easily occurs, and the toner particles are easily fused to
an element such as a blade for making the toner thinner.
Conversely, if the volume-average particle size is larger
than the range of the present invention, it becomes
difficult to obtain a high-resolution and high-quality
image. When toner particles in the developer are consumed,
the balance of toner particle sizes may sometimes largely
fluctuate.

By narrowing the particle size distribution, a charge
amount distribution of toner becomes uniform, thereby
obtaining a high quality image with less background fogging,
and increasing a transfer rate. However, when Dv/Dn
exceeds 1.40, the charge amount distribution is widened and
resolution decreases, which is not preferable.
An average particle size and a particle size
distribution of toner particles can be measured using
Coulter Counter TA-II and Coulter Multisizer II (both
manufactured by Coulter Electronics Limited). In the
present invention, the Coulter Counter TA-II was used to
measure the average particle size and the size distribution
by being connected to an interface (manufactured by Nikkaki
Bios Co.) which outputs a number (of particles)
distribution and a volume distribution, as well as to a
personal computer (PC9801: manufactured by NEC Corp.).
In such toner, a proportion of wax and inorganic fine
particles occupied in toner particles is increased as
compared with that of conventional toner particles by
reducing the toner particle size. The wax is internally or
externally added to toner particles to improve the release
property, and the inorganic fine particles are used to
improve the fluidity. These additives become a factor of
adhesion substances (adherents) produced on the
photoconductor 1. The lubricant applying device 3
according to the present invention is therefore installed
to form a thin film with uniform lubricant over the whole
area on the surface of the photoconductor 1, thereby
reducing an adhesion force of the adhesion substances to
the surface of the photoconductor 1. Furthermore, the
frictional force between the surface of the photoconductor
1 and the cleaning blade 8a of the cleaning device 8 or the
lubricant smoothing blade 8b is reduced to enable

satisfactory cleaning.
When toner particles used in the developing device 4
have high circularity such as an average circularity of
0.93 or higher, the effect of providing the cleaning device
8 of the present invention in an image forming apparatus is
significant. The toner particles having high circularity
easily enter the space between the photoconductor 1 and the
cleaning blade during cleaning using the blade system, and
easily slip through the space. If the contact pressure of
the cleaning blade to the photoconductor 1 is increased,
the photoconductor 1 is largely damaged. Furthermore, even
in a method of applying a bias having opposite polarity to
charge polarity of toner, to the brush roller, and
electrostatically collecting toner, it is difficult to
remove the toner from the brush roller. Therefore,
electrostatic toner removal capability tends to decrease
gradually.
However, the cleaning device 8 of the present
invention allows efficient cleaning of the surface of the
photoconductor 1 in the following manner even if the toner
particles have high average circularity. More specifically,
the toner remaining on the photoconductor 1 is
electrostatically collected by an electrostatic cleaning
element, and then, the remaining toner is finally scraped
off by the cleaning blade 8a and removed. Thus, efficient
cleaning can be performed without damage to the surface of
the photoconductor 1.
The average circularity of toner is a value obtained
by optically detecting a particle, projecting the particle
onto a plane to obtain an area of the particle projected,
and dividing the area by a circumferential length of a
circle having an area equivalent to the area of the
particle projected. The average circularity is measured

actually by using a flow particle image analyzer (FPIA-
2000: manufactured by Sysmex Corp.). Water of 100 to 150
milliliters from which impurity solid is previously removed
is put into a predetermined container, 0. 1 to 0. 5
milliliter of surfactant being a dispersing agent is added
to the water, and sample to be measured is further added
thereto by about 0.1 to 9.5 grams. A suspension with the
sample dispersed therein is dispersed for about 1 to 3
minutes by an ultrasonic disperser, and concentration of a
dispersing solution is controlled to 3,000 to 10,000
pieces/uL, and the shape and the distribution of toner
particles are measured.
The toner used in the image forming apparatus
according to the present invention has the shape factor SF-
1 ranging preferably from 100 to 180 and the shape factor
SF-2 ranging also preferably from 100 to 180. The shape
factor SF-1 and the shape factor SF-2 are the same as those
explained with reference to Fig. 5.
Further, the constitutional materials and
manufacturing method of toner are the same as those
explained in the first embodiment, and explanation thereof
is omitted.
The molecular weight of a polymer produced with a
modified polyester can be measured, using Gel Permeation
Chromatography (GPC), with tetrahydrofuran (THF) as a
solvent. A glass transition point (Tg) of a native
polyester can be measured by a Differential Scanning
Calorimeter (DSC).
In the toner manufacturing method, resin fine
particles are added to stabilize toner base particles that
are formed in the aqueous medium. Therefore, it is
preferable that the resin fine particles are added to make
10% to 90% covering over the surface of the toner base

particles. Examples of the resin fine particles are fine
particles of poly methyl methacrylate having a particle
size of 1 micrometer and 3 micrometers; fine particles of
polystyrene having a particle size of 0.5 micrometer and 2
micrometers; and fine particles of poly (styrene-
acrylonitrile) having a particle size of 1 micrometer.
Examples of trade names are PB-200H (manufactured by Kao
Corp.), SGP (manufactured by Soken Co., Ltd.),
TECHNOPOLYMER-SB (manufactured by Sekisui Plastics Co.,
Ltd.), SGP-3G (manufactured by Soken Co., Ltd.), and
MICROPEARL (manufactured by Sekisui Fine Chemical Co. Ltd.).
The shape of the toner according to the third
embodiment is almost spherical as that in the first
embodiment. The toner manufactured can be used as magnetic
toner, for a one-component developer that does not use
magnetic carrier, or as non-magnetic toner.
When the toner is used for a two-component developer,
the toner may be mixed with magnetic carrier. The magnetic
carrier is ferrite that contains divalent metal such as
iron, magnetite, Mn, Zn, and Cu, and its volume-average
particle size is preferably 20 to 100 micrometers. If the
average particle size is less than 20 micrometers, then the
carrier is easily adhered to the photoconductor 1 upon
development. If it exceeds 100 micrometers, then carrier
is not easily mixed with toner, and the charge amount of
toner is not sufficient. Therefore, charging failure
easily occurs during continuous use. Zn-containing Cu
ferrite is preferred because its saturated magnetization is
high, but it can be selected as required according to the
process of the image forming apparatus. Resin covering the
magnetic carrier is not particularly limited, but includes,
for example, the resin includes silicone resin, styrene-
acrylic resin, fluororesin, and olefin resin. The

manufacturing method of the resin may be either one of
methods as follows: a method of dissolving coating resin in
a solvent and spraying the solvent into a fluidized bed to
coat a carrier core, and another method of
electrostatically adhering resin particles to core
particles and thermally fusing the resin particles to cover
the core particles. The thickness of the core particle
covered with resin is 0.05 to 10 micrometers, preferably
0.3 to 4 micrometers.
Fig. 10 is a vertical cross-section of one example of
an image forming apparatus that can form a full-color image.
The image forming apparatus includes an endless
intermediate transfer belt 103 that is wound around among a
plurality of support rollers 104, 105, and 106 and is made
to rotate in the direction of arrow A, and first to fourth
process cartridges 107Y, 107C, 107M, and 107BK, which are
arranged opposite to the intermediate transfer belt 103.
The process cartridges 107Y, 107C, 107M, and 107BK include
image carriers 102Y, 102C, 102M, and 102BK, respectively,
which are configured as drum-shaped photoconductors that
form respective toner images of different colors. The
toner images of different colors are formed on the
respective image carriers, and are superposedly transferred
to the intermediate transfer belt 3. The intermediate
transfer belt 103 is one example of a transfer material to
which the toner images on the respective image carriers are
transferred. Reference numeral 100 in Fig. 10 is the main
unit of the image forming apparatus.
How to form toner images on the image carriers 102Y,
102C, 102M, and 102BK of the first to fourth process
cartridges 107Y, 107C, 107M, and 107BK and to transfer the
toner images to the intermediate transfer belt 103 is
substantially the same as one another in the respective

configurations, although the toner images are formed with different colors. Therefore, only the configuration, in
which a toner image is formed on the image carrier 102Y of
the first process cartridge 107Y and the toner image formed
is transferred to the intermediate transfer belt 103, is
explained below.
Fig. 11 is an enlarged cross-section of the first
process cartridge 107Y. The image carrier 102Y of the
process cartridge 107Y is rotatably supported by a unit
case 108, and is made to rotate in the clockwise direction
by a drive unit (not shown). When it is rotated, a
charging voltage is applied to a charging roller 109
rotatably supported by the unit case 108, so that the
surface of the image carrier 102Y is charged to
predetermined polarity. Laser light L, which is emitted
from an optical writing unit 110 shown in Fig. 10 and
optically modulated, is radiated to the image carrier 102Y
after being charged, thereby forming an electrostatic
latent image on the image carrier 102Y. The electrostatic
latent image is visualized as a yellow toner image by a
developing device 111.
The developing device 111 includes a developing case
112 that is formed with a part of the unit case 108, and
the developing case 112 accommodates a two-component dry-
type developer D containing toner and carrier. Disposed in
the developing case 112 are two screws 113 and 114 that
stir the developer D, and a developing roller 123 that is
made to rotate in the counterclockwise direction in Fig. 11.
The developer D sucked to the circumferential surface of
the developing roller 123 is carried on the circumferential
surface thereof and is conveyed in the direction of
rotation of the developing roller 123. Then the developer
D passing through a doctor blade 124 is conveyed to a

developing region between the developing roller 123 and the
image carrier 102Y. At this time, the toner in the
developer is electrostatically moved to the electrostatic
latent image formed on the image carrier 102Y and the
latent image is visualized as a toner image. The developer
D having passed through the developing region is separated
from the developing roller 123 and stirred by the screws
113 and 114. The toner image is formed on the image
carrier 102Y in the above manner. A developing device
using one-component developer without carrier can also be
employed.
On the other hand, a primary transfer roller 125 is
arranged on the opposite side to the process cartridge 107Y
across the intermediate transfer belt 103. A transfer
voltage is applied to the primary transfer roller 125, and
the toner image on the image carrier 102Y is thereby
primarily transferred to the intermediate transfer belt 103
that is made to rotate in the direction of arrow A.
Remaining toner adhered to the image carrier 102Y after the
toner image is transferred is removed by a cleaning device
126. The cleaning device 126 according to the third
embodiment includes a cleaning case 127 formed with a part
of the unit case 108, a cleaning blade 128 of which front
edge is pressed against the surface of the image carrier
102Y, a blade holder 129 that holds the cleaning blade 128,
and a toner conveying screw 130 disposed in the cleaning
case 127. The cleaning blade 128 is arranged in the
counter direction with respect to the movement direction of
the surface of the image carrier 102Y. Such a cleaning
blade 128 is made of an elastic body such as rubber, and
the base side of the cleaning blade 128 is fixed to the
blade holder 129 with, for example, an adhesive. By
pressing the front edge of the cleaning blade 128 against

the surface of the image carrier 102Y, the remaining toner
on the image carrier 102Y is scraped off and removed. The
toner removed is conveyed to the outside of the cleaning
case 127 by the toner conveying screw 130 that is made to
rotate. The cleaning blade 128 cleans the image carrier
after the toner image is transferred to a transfer material
(which corresponds to the intermediate transfer belt 103 of
Fig. 10).
The process cartridge 107Y also includes a lubricant
applying device 131 that applies a lubricant to the image
carrier 102Y, and a smoothing blade 132 that is one example
of a lubricant smoothing unit for smoothing the lubricant
applied to the image carrier 102Y. These devices are
explained in detail later.
In the same manner as explained above, a cyan toner
image, a magenta toner image, and a black toner image are
formed on the second to fourth image carriers 102C, 102M,
and 102BK of Fig. 10, respectively. These toner images are
primarily transferred, in a sequential superposing manner,
to the intermediate transfer belt 103 with the yellow toner
image having been transferred thereon, to form a composite
toner image on the intermediate transfer belt 103. How to
remove the remaining toner on the image carriers 102C, 102M,
and 102BK after the respective toner images are transferred
is also the same as that of the first image carrier 102Y.
As shown in Fig. 10, a paper feed device 116 is
provided in the main unit 100 of the image forming
apparatus at the lower side thereof. The paper feed device
116 includes a paper feed cassette 114 for storing
recording mediums P such as transfer paper, and a paper
feed roller 115. The top-most recording medium P is sent
out in the direction of arrow B by rotation of the paper
feed roller 115. The recording medium sent-out is fed, at

a predetermined time, into a space between a portion of the
intermediate transfer belt 103, which is wound around the
support roller 104, and a secondary transfer roller 118
which faces the support roller 104 by a registration roller
pair 117. At this time, a predetermined transfer voltage
is applied to the secondary transfer roller 118, and the
composite toner image on the intermediate transfer belt 103
is thereby secondarily transferred to the recording medium
P.
The recording medium P with the composite toner image
secondarily transferred thereon is further conveyed
upwardly to pass through a fixing device 119, where the
toner image on the recording medium P is fixed thereon by
the action of heat and pressure. The recording medium P
having passed through the fixing device 119 is ejected to a
paper ejection portion 122 provided on the upper side of
the main unit 100 of the image forming apparatus. The
remaining toner adhered to the intermediate transfer belt
103 after the toner image is transferred is removed by the
cleaning device 120.
The image forming apparatus according to the third
embodiment includes the lubricant applying device 131 so
that the wear of the cleaning blade 128 and the image
carrier 102Y in Fig. 11 is suppressed, and that high
cleaning performance by the cleaning blade 128 can be
maintained even if the spherical toner having a small
particle size is used. The lubricant applying device 131
is also provided in the second to fourth process cartridges
107C, 107M, and 107BK, respectively, and its configuration
and performance are perfectly the same as those of the
process cartridge 107Y. Therefore, only the lubricant
applying device 131 of the process cartridge 107Y shown in
Fig. 11 is explained below.

The lubricant applying device 131 of Fig. 11 includes
a brush roller 133 that contacts the surface of the image
carrier 102Y, a solid lubricant 134 that faces the brush
roller 133, a lubricant holder 135 that firmly supports the
solid lubricant 134, a guide 136 that guides the solid
lubricant 134 through the lubricant holder 135, and a
compressed coil spring 137 as one example of the pressing
unit.
The brush roller 133 includes a core shaft 138 and a
large number of brush fibers 139 whose base portion is
fixed to the core shaft 138. The brush roller 133 thus
configured extends in almost parallel to and longitudinally
along the image carrier 102Y, and both ends of the core
shaft 138 in the longitudinal direction are rotatably
supported with respect to the unit case 108 via bearings
(not shown). During image formation, the brush roller 133
is made to rotate in the counterclockwise direction in Fig.
11.
The solid lubricant 134 is formed into a rectangular
solid longitudinally extending in parallel to the brush
roller 133. The top surface of the solid lubricant 134 on
the side facing the brush roller 133 contacts the brush
fibers 139 of the brush roller 133, and the base side of
the solid lubricant 134 that is opposite to the top surface
is fixed to the lubricant holder 135. The guide 136
according to the third embodiment includes a pair of guide
plates 140 and 141 which are spaced in parallel to each
other so as to face each other, and the pair of guide
plates 140 and 141 is integrated into one unit by a
connection plate 142. The pair of guide plates 140 and 141
and the connection plate 142 are formed with a part of the
unit case 108.
The lubricant holder 135 is disposed between the pair

of guide plates 140 and 141, and slidably contacts the
mutually facing sides of the guide plates 140 and 141.
The compressed coil spring 137 is arranged in
plurality between the connection plate 142 and the
lubricant holder 135 as shown in Fig. 12. The compressed
coil springs 137 press the solid lubricant 134 against the
brush roller 133 through the lubricant holder 135. The
pressing direction is indicated by arrow C in Fig. 11.
Instead of the compressed coil spring, a pressing unit such
as a twisted coil spring and a plate spring can be used.
The solid lubricant 134 is pressed against the brush
fibers 139 of the brush roller 133 in the above manner, and
the brush fibers 139 are pressed against the surface of the
image carrier 102Y. At this time, the brush roller 133 is
rotated, and the lubricant of the solid lubricant 134 is
scraped off by the brush fibers 139 to become powdery
lubricant, and the powdery lubricant scraped-off is applied
to the surface of the image carrier 102Y. As explained
above, the brush roller 133 is one example of a lubricant
applying element that applies the powdery lubricant
scraped-off from the solid lubricant 134 to the surface of
the image carrier.
The solid lubricant 134 is scraped by the brush roller
133 and consumed, so that its thickness is reduced over
time, but since the solid lubricant 134 is pressed by the
compressed coil spring 137, the solid lubricant 134 can be
always in contact with the brush fibers 139 of the brush
roller 133.
Since the surface of the image carrier 102Y is applied
with the lubricant in the above manner, the frictional
coefficient of the surface thereof can be suppressed to low.
The wear of the image carrier 102Y and the cleaning blade
128 can thereby be minimized, and their lives can be

prolonged. Moreover, even if the spherical toner having a
small particle size is used, large reduction in cleaning
performance of the image carrier 102Y by the cleaning blade
128 can be prevented.
Furthermore, the guide 136 is provided in the
lubricant applying device 131 according to the third
embodiment. The guide 136 guides the lubricant holder 135
and the solid lubricant 134 so that these two can move
substantially only in a direction of approaching or
separating from the brush roller 133, namely, in a pressing
direction C of the compressed coil spring 137 and in the
opposite direction thereto. Therefore, the solid lubricant
134 does not largely sway in a direction E, which is
perpendicular to the pressing direction C. Consequently,
the solid lubricant 134 is capable of contacting the brush
roller 133 along almost the same area at any time, and an
almost fixed amount of lubricant can be fed to the surface
of the image carrier through the brush roller 133, thereby
preventing nonuniform application of the lubricant to the
surface of the image carrier.
If the guide 136 is not provided, as shown in Fig. 14A
and Fig. 14B, the solid lubricant 134 largely sways in the
direction E perpendicular to the pressing direction C of
the compressed coil spring. Therefore, only a portion 143
or a portion 144 of the surface of the solid lubricant 134
that faces the brush roller 133 contacts the brush roller
133, or the whole of the surface contacts the brush roller
133. Thus, the lubricant is not uniformly applied to the
image carrier 102Y, which may lead to degradation of the
toner image transferred to the intermediate transfer belt
103 and of the image quality of a final image formed on the
recording medium P. The image forming apparatus according
to the third embodiment allows prevention of such failure.

In the image forming apparatus shown in Fig. 10, the
lubricant holder 135 contacts the pair of guide plates 140
and 141, and the solid lubricant 134 is guided by the guide
136 through the lubricant holder 135. However, the solid
lubricant 134 can be also configured to be guided directly
by the guide 136. The solid lubricant 134 is guided by the
guide 136 so that the solid lubricant 134 can move
substantially only in the direction C in which the solid
lubricant 134 approaches or separates from the brush roller
133. This indicates, however, that the solid lubricant 134
may sway along the direction E, which is perpendicular to
the direction C, by a slight amount of allowance.
As explained above, the lubricant applying device 131
according to the third embodiment includes a lubricant
applying element that is the brush roller 133 which
contacts the image carrier 102Y while rotating, the solid
lubricant 134 disposed in a location facing the lubricant
applying element, the guide 136 that guides the solid
lubricant 134 so that the solid lubricant 134 can move
substantially only in the direction of approaching or
separating from the brush roller 133, and the pressing unit
that includes the compressed coil spring 137 for pressing
the solid lubricant 134 against the lubricant applying
element.
Moreover, as shown in Fig. ll, the positions of the
compressed coil spring 137 and the cleaning blade 12 8 are
respectively set so that the direction C in which the
compressed coil spring 137 presses the solid lubricant 134
against the brush roller 133 is almost parallel to the
direction in which the cleaning blade 128 is protruded
toward the surface of the image carrier 102Y. Therefore,
the space occupied by the cleaning blade 128, the blade
holder 129, and the lubricant applying device 131 in the

main unit of the image forming apparatus can be reduced,
thereby downsizing the image forming apparatus. As shown
in Fig. 15, if the pressing direction C is not parallel to
the direction in which the cleaning blade 128 is protruded
toward the surface of the image carrier 102Y, the whole of
the cleaning blade 128, the blade holder 129, and the
lubricant applying device 131 occupies a large space around
the image carrier 102Y, and this large space inevitably
causes upsizing of the image forming apparatus. The image
forming apparatus according to the third embodiment can
avoid this disadvantage with simple configuration.
.Furthermore, as shown in Fig. 11, in the image forming
apparatus according to the third embodiment, the blade
holder 129 is directly fixed to the guide plate 140 of the
guide 136 with, for example, a screw (not shown). In other
words, the blade holder 129 is fixed to the guide 136 that
guides the solid lubricant 134. Consequently, the
parallelism between the direction in which the cleaning
blade 128 is protruded toward the surface of the image
carrier 102Y and the pressing direction C can be easily and
surely enhanced. The blade holder 129 may be fixed to the
guide 136 through some other intermediate element.
In this manner, the positions of the pressing unit and
the cleaning blade are respectively set so that the
direction in which the pressing unit presses the solid
lubricant against the lubricant applying element is almost
parallel to the direction in which the cleaning blade is
protruded toward the surface of the image carrier. And the
blade holder is fixed to the guide, which guides the solid
lubricant, directly or through another element, thereby
downsizing the image forming apparatus.
In the image forming apparatus as shown in Fig. 13,
positions of the image carrier 102Y, the lubricant applying

element, and the pressing unit are respectively set so that
a line H and the pressing direction C are on the
substantially same line I. More specifically, the line H
connects between a rotation center F of the image carrier
102Y and a rotation center G of the lubricant applying
element such as the brush roller 133, and the pressing
direction C is a pressing direction of the compressed coil
spring 137 toward the solid lubricant 134. As shown in the
image forming apparatus of Fig. 11, if the line H and the
pressing direction C are not on the same line, the center
portion of the brush roller 133 in the longitudinal
direction pressed by the compressed coil spring 137 may
possibly be deformed as indicated by the chain line of Fig.
12, where the deformation is slightly exaggerated. If the
brush roller 133 is thus deformed, the amount of the
lubricant applied to the image carrier 102Y becomes
nonuniform, which may cause degradation of the toner image
transferred to the intermediate transfer belt 103 and of
the image quality of the image on the recording medium.
On the other hand, in the process cartridge 107Y as
shown in Fig. 13, since the line H and the pressing
direction C are on almost the same line I, the center
portion of the brush roller 133 in the longitudinal
direction which contacts the image carrier is surely caught
on the surface of the image carrier 102Y. Therefore, the
brush roller 133 is not possibly deformed unlike the
deformation indicated by the chain line of Fig. 12. This
allows uniform application of the lubricant to the image
carrier 102Y and an increase in image quality of the toner
image formed on the recording medium P. The other
components of the image forming apparatus of Fig. 13 are
the same as those of Fig. 10 to Fig. 12, and the same
reference numerals of Fig. 11 are assigned to the

components the same as or corresponding to the components
of Fig. 11.
The image forming apparatus of Fig. 11 includes a
lubricant smoothing unit that serves as the smoothing blade
132. The smoothing blade 132 is made of an elastic body-
such as rubber. The front edge of the smoothing blade 132
contacts the surface of the image carrier 102Y, and the
base side thereof is fixed to a holder 145. The smoothing
blade 132 is arranged in the trailing direction with
respect to the movement direction of the surface of the
image carrier. As is clear from Fig. 11, the lubricant
applying element including the brush roller 133 is arranged
on the downstream side of the cleaning blade 128 in the
movement direction of the surface of the image carrier.
In the configuration, the remaining toner adhered to
the surface of the image carrier after the toner image is
transferred is removed by the cleaning blade 128, and the
surface of the image carrier 102Y thus cleaned is applied
with the lubricant. The lubricant applied is uniformly
spread and smoothed over the surface of the image carrier
102Y while passing through the smoothing blade 132 in
contact with the surface of the image carrier 102Y. This
allows formation of a lubricant layer having a uniform
thickness on the image carrier 102Y. In this manner, the
lubricant is applied immediately after the image carrier
102Y is cleaned, and the lubricant applied is smoothed,
thereby preventing deviation of the application amount of
the lubricant to the surface of the image carrier 102Y and
deviation of the frictional coefficient of the surface
thereof, and increasing the quality of image formed on the
recording medium. Moreover, because the smoothing blade
132 is arranged in the trailing direction with respect to
the movement direction of the surface of the image carrier

102Y, the drive torque of the image carrier 102Y can be
prevented from being too high.
The thickness of the brush fibers of the brush roller
133 in the lubricant applying device 131 is preferably 3 to
8 deniers, and the density of the brush fibers 139 is
preferably 20,000 to 100,000 lines/inch2. If the thickness
of the brush fiber is too thin, the bristles become easily
bent when the brush roller 3a contacts the surface of the
image carrier 102Y. Conversely, if the brush fiber is too
thick, the density of the fibers cannot be increased. If
the density of the brush fibers is low, the lubricant
cannot be uniformly applied to the surface of the image
carrier 102Y because the number of brush fibers contacting
the surface thereof is small. Conversely, if the density
of brush fibers is too high, a gap between a fiber and a
fiber becomes narrower, and an adhesion amount of the
powdery lubricant scraped-off is reduced, which causes a
shortage of the application amount.
The same solid lubricant as the solid lubricant 134 of
the first embodiment is used in the third embodiment.
It is preferred that the toner used in the developing
device 111 is such that a volume-average particle size is
10 micrometers or less and a ratio (Dv/Dn) between the
volume-average particle size (Dv) and a number-average
particle size (Dn) is in a range from 1.00 to 1.40, and the
volume-average particle size in particular desirably ranges
from 3 to 8 micrometers.
By using toner particles having a small particle size,
the toner particles can be densely adhered to an
electrostatic latent image. However, if the volume-average
particle size of toner is too small, the toner particles in
the two-component developer are fused onto the surfaces of
magnetic carriers during stirring of the developer for a

long time in the developing device, to reduce the charging
capability of the magnetic carriers. If a one-component
developer is used as the developer, filming of the toner
particles to the developing roller easily occurs, and the
toner particles are easily fused onto an element such as a
blade for making the toner thinner. Conversely, if the
volume-average particle size is too large, it becomes
difficult to obtain a high-resolution and high-quality
image. When the toner particles in the developer are
consumed, the balance of toner particle sizes may sometimes
largely fluctuate.
Furthermore, by narrowing the particle size
distribution, a charge amount distribution of toner becomes
uniform, thereby obtaining a high quality image with less
background fogging, and increasing a transfer rate.
However, when Dv/Dn exceeds 1.40, the charge amount
distribution is widened and resolution decreases, which is
not preferable.
An average particle size and a particle size
distribution of toner particles can be measured using
Coulter Counter TA-II and Coulter Multisizer II (both
manufactured by Coulter Electronics Limited). In the
present invention, the Coulter Counter TA-II was used to
measure the average particle size and the size distribution
by being connected to the interface (manufactured by
Nikkaki Bios Co.) which outputs a number (of particles)
distribution and a volume distribution, as well as to a
personal computer (PC9801: manufactured by NEC Corp.).
In such toner, a proportion of wax and inorganic fine
particles occupied in toner particles is increased by
reducing a toner particle size. The wax is internally or
externally added to toner particles to improve the release
property, and the inorganic fine particles are used to

improve the fluidity. These additives become a factor of
adhesion substances produced on the image carrier. However,
the lubricant applying device 131 is installed to form a
thin film with uniform lubricant over the whole area on the
surface of the image carrier, thereby reducing adhesion
force of the adhesion substances to the surface of the
image carrier 102Y. Furthermore, the installation of the
lubricant applying device 131 allows reduction in the
frictional force between the surface of the image carrier
and the cleaning blade 128 of the cleaning device 126 or
the lubricant smoothing blade 132, and performance of
satisfactory cleaning.
When toner used in the developing device 111 has an
average circularity of 0.93 to 1.00, significant effect can
be obtained as the result of applying the lubricant to the
image carrier. By applying the lubricant to the image
carrier, even if the toner having high circularity is used,
such defect that the toner scrapes through under the
cleaning blade 128 can be efficiently suppressed.
The average circularity of toner is a value obtained
by optically detecting a particle, projecting the particle
onto a plane to obtain an area of the particle projected,
and dividing the area by a circumferential length of a
circle having an area eguivalent to the area of the
particle projected. The average circularity is measured
actually by using the flow particle image analyzer (FPIA-
2000: manufactured by Sysmex Corp.). Water of 100 to 150
milliliters from which impurity solid is previously removed
is put into a predetermined container, 0. 1 to 0. 5
milliliter of surfactant being a dispersing agent is added
to the water, and sample to be measured is further added
thereto by about 0.1 to 9.5 grams. A suspension with the
sample dispersed therein is dispersed for about 1 to 3

minutes by an ultrasonic disperser, and concentration of a
dispersing solution is controlled to 3,000 to 10,000
pieces/uL, and the shape and the distribution of toner
particles are measured.
The toner used in the developing device 111 has the
shape factor SF-1 ranging preferably from 100 to 180 and
the shape factor SF-2 ranging also preferably from 100 to
180. The shape factor SF-1 indicates the degree of
sphericity of toner shape. When the value of SF-1 is 100,
the shape of the toner becomes perfect sphericity, and when
the value of the SF-1 is larger, the toner shape becomes
more irregular. The shape factor SF-2 indicates the degree
of irregularities in the shape of toner. When the value of
SF-2 is 100, no irregularities are found on the surface of
the toner, and when the value of the SF-2 is larger, the
irregularities on the surface of the toner become more
significant. See JP-A No. 2002-244485 for details of these.
If the shape of the toner is close to sphericity, a
contact between a toner particle and a toner particle or
between a toner particle and the image carrier is closer to
a point contact. Therefore, fluidity becomes higher as the
attracting force between toner particles gets weaker. The
attracting force between the toner particle and the image
carrier also gets weak, and as a result, a transfer rate
becomes high. Since the spherical toner easily enters the
space between the cleaning blade 128 and the image carrier
102Y, the shape factor SF-1 or the shape factor SF-2 of
toner should be large to some extent. However, if the SF-1
and the SF-2 become too large, toner particles scatter over
an image, and image quality is thereby degraded. Therefore,
it is preferable that the SF-1 and the SF-2 do not exceed
180. The shape factor was measured specifically by
photographing toner with the scanning electron microscope

(S-800: manufactured by Hitachi Ltd.), introducing the
photograph into the image analyzer (LUZEX3: manufactured by
Nireco Corp.), and analyzing and calculating it.
The toner adequately used in the image forming
apparatus according to the third embodiment is obtained by
allowing a toner material solution to undergo crosslinking
reaction and/or elongation reaction in an aqueous medium in
the presence of resin fine particles. The toner material
solution is a toner composition obtained by dispersing at
least a polyester prepolymer having a functional group that
contains nitrogen atoms, a polyester, a colorant, and a
release agent in an organic solvent. The constitutional
materials of the toner and the method of manufacturing the
toner are the same as these in the first embodiment, and
hence explanation thereof is omitted.
A glass transition point (Tg) of a native polyester
can be measured by the Differential Scanning Calorimeter
(DSC). By using the toner manufacturing method, toner
having a small particle size and a sharp particle-size
distribution can be easily obtained. Furthermore, by
strongly stirring the organic solvent in the process of
removing it, the shape can be controlled in a range from a
perfectly spherical shape to a "rugby ball" shape, and
further, the morphology of the surface can also be
controlled in a range from a smooth shape to a rough shape.
The external toner shape is preferably almost
spherical, and this is the same as that of the embodiments.
In the image forming apparatus as explained above, the
image carrier is formed into a drum shape, and the
intermediate transfer element is formed with ah
intermediate transfer belt, but the configuration according
to the present invention can be employed even when the
image carrier is formed with an endless belt and the

intermediate transfer element is formed into a drum shape.
The configurations according to the present invention can
be used even when an image carrier that carries a toner
image thereon is formed with an intermediate transfer
element and a transfer material to which the toner image on
the image carrier is transferred is a recording medium. In
this case, the image forming apparatus is provided with the
cleaning blade that removes the remaining toner adhered to
the intermediate transfer element after the toner image is
transferred, and the lubricant applying device for applying
the lubricant to the intermediate transfer element, and the
configurations are employed for these components.
Furthermore, the present invention is also applicable
without any trouble to an image forming apparatus in which
a toner image formed on one image carrier, being a
photoconductor, is directly transferred to a transfer
material, being a recording medium.
The configurations of an image forming apparatus,
imaging units, and a cleaning device according to a fourth
embodiment of the present invention are the same as these
of Fig. 1, Fig. 2, and Fig. 18, and hence, explanation
thereof is omitted.
A pressing force is produced when the solid lubricant
3b is pressed against and contacted with the brush roller
3a upwardly as shown in Fig. 2, when it is pressed against
and contacted with the brush roller 3a sidewardly as shown
in Fig. 18, or when it is pressed against and contacted
with the brush roller 3a downwardly (not shown). The
results of obtaining the pressing force and the deviation
of pressing forces between an initial time and an elapsed
time (life) (initial pressing force-elapsed time pressing
force) are shown in table 4.


It is understood from the table 4 that the pressing
force applied to the brush roller 3a and the deviation of
the pressing forces are different depending on the pressing
direction toward the solid lubricant 3b.
The pressing force and the deviation of the pressing
forces in an actual lubricant applying device are explained
below. Two models, model G and model J, were used for the
following comparisons, and the results of the comparisons
are shown in table 5. The deviation of the pressing forces.

when the solid lubricant 3b is pressed downwardly,
increases by 42% in model G and by 22% in model J as
compared with the case where the solid lubricant 3b is
pressed upwardly.

It is understood that the application amount of the
lubricant largely fluctuates when the deviation of the
pressing forces is large because the required application
amount of the lubricant is different depending on the
models and a multiplier of a pressure spring to be used is
different due to restriction to layout, although the

magnitude of the deviation cannot be compared between the
models in a simple manner. The large fluctuations may lead
to an excessive application in the initial stage or to a
shortage of application when time is elapsed. Consequently,
when the deviation of the pressing forces is smaller, more
stable application can be achieved.
Accordingly, the arrangement, as shown in Fig. 2, in
which the solid lubricant 3b is pressed upwardly, that is,
from the lower side of the brush roller 3a, allows more
stable application of the lubricant as compared with the
sideward application and the downward application.
The configuration of the solid lubricant 3b of the
lubricant applying device 3 is the same as that of Fig. 7.
By providing the solid lubricant 3b and the cleaning
device 8, which are configured in the above manner, in the
image forming apparatus, an appropriate amount of the
lubricant can be applied to the surface of the
photoconductor 1, thereby forming a thin film with the
smoothed lubricant without nonuniform application.
The solid lubricant 3b or the brush roller 3a moves in
the longitudinal direction which is perpendicular to the
rotation direction of the brush roller 3a, thereby
preventing nonuniform application caused When the brush
roller 3a unevenly contacts the solid lubricant 3b.
The lubricant is applied after the remaining toner is
cleaned in the above manner, and further, the lubricant
applied is smoothed to form a thin film, thereby preventing
both the defects occurring in "the cleaning after the
application" such that the photoconductor is cleaned only
after the lubricant is applied and in "the application
after the cleaning" such that the lubricant is applied
after the photoconductor is cleaned. More specifically,
the deviation of the application amount of the lubricant

and the deviation of the static frictional coefficient of
the surface due to the "the cleaning after the application"
can be prevented, and the abnormal images such as the worm
hole, the image blur, and the rough image due to nonuniform
lubricant layer caused by "the application after the
cleaning" without smoothing it can also be prevented. At
the same time, the application function of the brush roller
3a can be maintained over the long period of time. Since
the rubber is used for the lubricant smoothing blade 8b,
even if the photoconductor 1 is moved being in contact with
the lubricant smoothing blade 8b, the surface of the
photoconductor 1 is not possibly damaged.
In the present invention, the wear of the cleaning
blade 8a and the surface of the photoconductor 1 can be
prevented, and even if the toner having a small particle
size is used, the toner remaining on the surface thereof
after the toner image is transferred can be satisfactorily
cleaned. Moreover, the image blur can be prevented. The
image blur may occur when the surface of the photoconductor
1 is affected by humidity due to excessive application of
the lubricant.
In the fourth embodiment, the cleaning blade 8a is
used to clean the surface of the photoconductor 1, but a
cleaning brush may also be used instead of the cleaning
blade 8a. The cleaning brush is obtained by applying bias
to a conductive brush having a resistance.between a medium
resistance and a low resistance.
The present invention is not limited by the
embodiments, but is applicable to any device that uses the
technological principles of the present invention. The
photoconductor or the intermediate transfer element may be
either one of a belt shape and a roller shape.
In the fourth embodiment, tests were conducted by

comparing a method according to the present invention with
the conventional method. The method according to the
present invention was such that the lubricant smoothing
blade 8b was made to contact the surface of the
photoconductor 1 in the trailing manner to smooth the
lubricant applied. The effect of the present invention as
the results of the tests is verified in the same manner as
that of the second embodiment.
Working examples of the present invention are
explained below.
Fig. 16 is a diagram of how to manufacture an image
carrier having a low frictional coefficient using the
lubricant applying device according to the present
invention. Fig. 17 is a diagram of an image on an "angle
0" between the lubricant applying device according to the
present invention and a sheet-like smoothing element being
its main portion, and on how the lubricant is pressed and
spread.
First Working Example:
A lubricant applying device was prepared in the
following manner. As a sheet-like smoothing element, an
urethane rubber sheet having a thickness of 2 millimeters,
manufactured by Bando Chemical Industries, Ltd., was used
and set in a trailing posture so that a contact pressure
can be changed in a range of 25±10 (g/cm) and a contact
angle in a range of 0 to 90 degrees upon setting of a
photoconductor. And, as an applying brush, a conductive
nylon brush having a bristle length of 3 millimeters,
manufactured by Toeisangyo Co., Ltd., was used and set so
that the applying brush was pressed into the photoconductor
by an amount of 1 millimeter. The lubricant applying
device thus prepared was used to run idle (approximately 5
to 10 minutes) until the lubricant was sufficiently applied

to the photoconductor, and the photoconductor with the
sufficient lubricant was used to prepare a process
cartridge.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation, under the
environment of 35° C., 80%. The results are as follows.
When the contact angle was less than 10 degrees, a cleaning
sheet was rolled in (indicated by "cross:x" in table 6),
but in the other cases, no sheet roll-in occurred
(indicated by "circle:o" in table 6).

Second Working Example:
A lubricant applying device was prepared in the
following manner. As a sheet-like smoothing element, an
urethane rubber sheet having a thickness of 1.6 millimeters,
manufactured by Hokushin Corp., was used and set in a
trailing posture so that a contact pressure can be changed
in a range of 55+10 (g/cm) and a contact angle in a range
of 0 to 90 degrees upon setting of a photoconductor. And,
as an applying brush, a conductive nylon brush having a
bristle length of 2.5 millimeters, manufactured by Tsuchiya
Co., Ltd., was used and set so that the applying brush was
pressed into a photoconductor by an amount of 0.5
millimeter. The lubricant applying device thus prepared
was used to run idle (approximately 5 to 10 minutes) until

the lubricant was sufficiently applied to the
photoconductor, and the photoconductor with the sufficient
lubricant was used to prepare a process cartridge.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation, under the
environment of 35° C, 80%. The results are as follows.
When the contact angle was less than 10 degrees, a cleaning
sheet was rolled in (indicated by "cross:x" in table 7),
but in the other cases, no sheet roll-in occurred
(indicated by "circle:o" in table 7).

Third Working Example:
A lubricant applying device was prepared in the
following manner. As a sheet-like smoothing element, an
urethane rubber sheet having a thickness of 1.5 millimeters,
manufactured by Toyo Tire and Rubber Co., Ltd., was used
and set in a trailing posture so that a contact pressure
can be changed in a range of 20±10 (g/cm) and a contact
angle in a range of 0 to 90 degrees upon setting of a
photoconductor. And, as an applying brush, a conductive
nylon brush having a bristle length of 3 millimeters,
manufactured by Tsuchiya Co., Ltd., was used and set so
that the applying brush was pressed into the photoconductor
by an amount of 1 millimeter. The lubricant applying
device thus prepared was used to run idle (approximately 5

to 10 minutes) until the lubricant was sufficiently applied
to the photoconductor, and the photoconductor with the
sufficient lubricant was used to prepare a process
cartridge.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation, under the
environment of 35° C, 80%. The results are as follows.
When the contact angle was less than 10 degrees, a cleaning
sheet was rolled in (indicated by "cross:x" in table 8),
but in the other cases, no sheet roll-in occurred
(indicated by "circle:o" in table 8).

Fourth Working Example:
A process cartridge was prepared in the following
manner. As a cleaning sheet, an urethane rubber sheet
having a thickness'of 2 millimeters, manufactured by Bando
Chemical Industries, Ltd., was used and set so that a
contact pressure was in a range of 20±10 (g/cm) and a
contact angle in a range of 75±10 degrees with respect to a
photoconductor. As an applying brush, a conductive nylon
brush having a bristle length of 3 millimeters,
manufactured by Toeisangyo Co., Ltd., was used and set so
that the applying brush was pressed into the photoconductor
by an amount of 1 millimeter. As a sheet-like smoothing
element, an urethane rubber sheet having a thickness of 1.5

millimeters, manufactured by Toyo Tire and Rubber Co., Ltd.,
was used and set so that a contact angle was in a range of
15±5 degrees and a contact linear pressure was variously
changed.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation under laboratory
environment, to check whether the inside of the machine was
contaminated. The results are as follows. When the
contact linear pressure was less than 0.01 (N/cm), the
contamination inside the machine was verified (indicated by
"cross:x" in table 9), but in the other cases, no such
problem occurred (indicated by "circle: O" in table 9).

Fifth Working Example:
A process cartridge was prepared in the following
manner. As a cleaning sheet, an urethane rubber sheet
having a thickness of 2 millimeters, manufactured by
Hokushin Corp., was used and set so that a contact pressure
was in a range of 25±10 (g/cm) and a contact angle in a
range of 70+10 degrees with respect to a photoconductor.
As an applying brush, an insulation polyester brush having
a bristle length of 3 millimeters, manufactured by Tsuchiya
Co., Ltd., was used and set so that the applying brush was
pressed into the photoconductor by an amount of 1
millimeter. As a sheet-like smoothing element, an urethane

rubber sheet having a thickness of 1 millimeter,
manufactured by Toyo Tire and Rubber Co., Ltd., was used
and set so that a contact angle was in a range of 25±5
degrees and a contact linear pressure was variously changed.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation under laboratory
environment, to check whether the inside of the machine was
contaminated. The results are as follows. When the
contact linear pressure was less than 0.01 (N/cm), the
contamination inside the machine was verified (indicated by
"cross:x" in table 10), but in the other cases, no such
problem occurred (indicated by "circle:o" in table 10).

Sixth Working Example:
A process cartridge was prepared in the following
manner. As a cleaning sheet, an urethane rubber sheet
having a thickness of 1.6 millimeters, manufactured by Toyo
Tire and Rubber Co., Ltd., was used and set so that a
contact pressure was in a range of 55±10 (g/cm) and a
contact angle in a range of 70±10 degrees with respect to a
photoconductor. As an applying brush, an insulation
polyester brush having a bristle length of 2.5 millimeters,
manufactured by Tsuchiya Co., Ltd., was used and set so
that the applying brush was pressed into the photoconductor
by an amount of 0.5 millimeter. As a sheet-like smoothing

element, an urethane rubber sheet having a thickness of 1.3
millimeters, manufactured by Bando Chemical Industries,
Ltd., was used and set so that a contact angle was in a
4
range of 22±5 degrees and a contact linear pressure was
variously changed.
The process cartridge was set in imagio NeoC325
manufactured by Ricoh Co., Ltd., and 1,000 sheets of paper
were continuously passed through the cartridge on the
condition of the image formed on A4-size white paper passed
therethrough in horizontal orientation under laboratory
environment, to check whether the inside of the machine was
contaminated. The results are as follows. When the
contact linear pressure was less than 0.01 (N/cm), the
contamination inside the machine was verified (indicated by
"cross:x" in table 11), but in the other cases, no such
problem occurred (indicated by "circle:0" in table 11).

In the image forming apparatus according to the
present invention, toner used in the developing device 4
preferably has the volume-average particle size ranging
from 3 to 8 micrometers, and has a ratio (Dv/Dn) between
the volume-average particle size (Dv) and the number-
average particle size (Dn) ranging from 1.00 to 1.40.
By using toner particles having a small particle size,
the toner particles can be densely adhered to a latent
image.. However, if the volume-average particle size is
smaller than the range of the present invention, toner
particles in a two-component developer are fused onto the

surfaces of magnetic carriers during its stirring for a
long period of time in the developing device, to reduce the
charging capability of the magnetic carriers. If a one-
component developer is used as the developer, filming of
the toner particles to the developing roller easily occurs,
and the toner particles are easily fused to an element such
as a blade for making the toner thinner. Conversely, if
the volume-average particle size is larger than the range
of the present invention, it becomes difficult to obtain a
high-resolution and high-quality image. When toner
particles in the developer are consumed, the balance of
toner particle sizes may sometimes largely fluctuate.
Furthermore, by narrowing the particle size
distribution, a charge amount distribution of toner becomes
uniform, thereby obtaining a high quality image with less
background fogging, and increasing a transfer rate.
However, when Dv/Dn exceeds 1.40, the charge amount
distribution is widened and resolution decreases, which is
not preferable.
An average particle size and a particle size
distribution of toner particles can be measured using
Coulter Counter TA-II and Coulter Multisizer II (both
manufactured by Coulter Electronics Limited). In the
present invention, the Coulter Counter TA-II was used to
measure the average particle size and the size distribution
by being connected to an interface (manufactured by Nikkaki
Bios Co.) which outputs a number (of particles)
distribution and a volume distribution, as well as to a
personal computer (PC9801: manufactured by NEC Corp.) .
In such toner, a proportion of wax and inorganic fine
particles occupied in toner particles is increased by
reducing toner particle size as compared with that of
conventional toner particles. The wax is internally or

externally added to toner particles to improve the release
property, and the inorganic fine particles are used to
improve the fluidity. These additives become a factor of
adhesion substances produced on the photoconductor 1. The
lubricant applying device 3 according to the present
invention is therefore installed to form a thin film with
uniform lubricant over the whole area on the surface of the
photoconductor 1, thereby reducing adhesion force of the
adhesion substances to the surface of the photoconductor 1.
Furthermore, the frictional force between the surface of
the photoconductor 1 and the cleaning blade 8a of the
cleaning device 8 or the lubricant smoothing blade 8b is
reduced to enable satisfactory cleaning.
When toner particles used in the developing device 4
have high circularity such as an average circularity of
0.93 or higher, the effect of providing the cleaning device
8 of the present invention in an image forming apparatus is
significant. The toner particles having high circularity
easily enter the space between the photoconductor 1 and the
cleaning blade during cleaning using the blade system, and
easily slip through the space. If the contact pressure of
the cleaning blade to the photoconductor 1 is increased,
the photoconductor 1 is largely damaged. Further, in the
method of applying a bias having opposite polarity to
charge polarity of toner, to the brush roller, and
electrostatically collecting toner, it is difficult to
remove the toner from the brush roller. Therefore,
electrostatic toner removal capability tends to decrease
gradually.
However, the cleaning device 8 of the present
invention allows efficient cleaning of the surface of the
photoconductor 1 in the following manner even if the toner
particles have high average circularity. More specifically,

at first, the toner particles remaining on the
photoconductor 1 are electrostatically collected by the
electrostatic cleaning element, and then, the remaining
toner particles are finally scraped off by the cleaning
blade 8a and removed. Thus, efficient cleaning can be
performed without damage to the surface of the
photoconductor 1.
The average circularity of toner is a value obtained
by optically detecting a particle, projecting the particle
onto a plane to obtain an area of the particle projected,
and dividing the area by a circumferential length of a
circle having an area equivalent to the area of the
particle projected. Actually, the average circularity is
measured by using a flow particle image analyzer (FPIA-
2000: manufactured by Sysmex Corp.). Water of 100 to 150
milliliters from which impurity solid is previously removed
is put into a predetermined container, 0. 1 to 0. 5
milliliter of surfactant being a dispersing agent is added
to the water, and sample to be measured is further added
thereto by about 0.1 to 9.5 grams. A suspension with the
sample dispersed therein is dispersed for about 1 to 3
minutes by an ultrasonic disperser, and concentration of a
dispersing solution is controlled to 3,000 to 10,000
pieces/jj.L, and the shape and the distribution of toner
particles are measured.
The toner used in the image forming apparatus
according to the present invention has the shape factor SF-
1 ranging preferably from 100 to 180 and the shape factor
SF-2 ranging also preferably from 100 to 180.
The toner adequately used in the image forming
apparatus according to the present invention is obtained by
allowing toner material solution to undergo crosslinking
reaction and/or elongation reaction in an aqueous medium.

The toner material solution is obtained by dispersing at
least a polyester prepolymer having a functional group that
contains nitrogen atoms, a polyester, a colorant, and a
release agent in an organic solvent.
The constitutional materials of toner and the method
of manufacturing toner are also the same as these of the
first embodiment, and explanation thereof is omitted.
The molecular weight of polymer produced with modified
polyester can be measured, using Gel Permeation
Chromatography (GPC), with THF as a solvent.
The shape of the toner according to the fourth
embodiment is almost spherical, and this is as explained
above.
More specifically, the toner manufactured can be used
as one-component magnetic toner that does not use magnetic
carrier or as non-magnetic toner.
When the toner is used for the two-component developer,
the toner may be mixed with magnetic carrier. The magnetic
carrier is ferrite that contains divalent metal such as
iron, magnetite, Mn, Zn, and Cu, and its volume-average
particle size is preferably 20 to 100 micrometers. If the
average particle size is less than 20 micrometers, then the
carrier is easily adhered to the photoconductor 1 upon
development. If it exceeds 100 micrometers, then carrier
is not easily mixed with toner, and the charge amount of
toner is not sufficient. Therefore, charging failure
easily occurs during continuous use. Zn-containing Cu
ferrite is preferred because its saturated magnetization is
high, but it can be selected as required according to the
process of the image forming apparatus 100. Resin covering
the magnetic carrier is not particularly limited, but
includes, for example, the resin includes silicone resin,
styrene-acrylic resin, fluororesin, and olefin resin. The

manufacturing method of the resin may be either one of
methods as follows: a method of dissolving coating resin in
a solvent and spraying the solvent into a fluidized bed to
coat carrier cores, and another method of electrostatically
adhering resin particles to core particles and thermally
fusing the resin particles to cover the core particles.
The thickness of the core particle covered with resin is
0.05 to 10 micrometers, preferably 0.3 to 4 micrometers.
INDUSTRIAL APPLICABILITY
As described above, an image forming apparatus, a
lubricant applying device, a transfer device, a process
cartridge, and toner used for an image carrier of the image
forming apparatus according to the present invention are
usuful for image forming apparatuses such as a copying
machine, a printing machine, a facsimile and so on, using
an electronic photographic process, especially, these are
useful for maintaining an apropriate frictional coefficient
of the surface of a photoconductor and a transfer device
and usuful for obtaining stable image quality.

We Claim:
1. An image forming apparatus comprising:
a latent image carrier (1) that is rotatable and configured to carry a latent image;
a cleaning blade (8a) that cleans toner remaining on a cleaning area on the latent
image carrier;
a lubricant (3b);
a lubricant applying brush roller (3a) configured to scrape off the lubricant and
applies scrapped lubricant to the latent image carrier (1); and
a lubricant applying blade (3e) arranged on a downstream side of an applying
apparatus of the cleaning blade (8a) with respect to direction of rotation of the latent image
carrier (1), and that applies a lubricant on the latent image carrier (1),
wherein a lubricant applying area overlaps the cleaning area of the cleaning blade,
and
wherein a width of the lubricant (3b) is less than a width of the brush roller (3a) and
the width of the brush roller (3a) is less than a width of the lubricant applying blade (3e) in
contact with the latent image carrier (1) in a longitudinal direction thereof in the image
forming apparatus.
2. The image forming apparatus as claimed in claim 1, wherein the cleaning area and
the lubricant applying area are substantially equal size on the latent image carrier.
3. The image forming apparatus as claimed in claim 1, wherein
widths of a charged portion and a lubricant applied on the latent image carrier in a
longitudinal direction have a relation:
charge width 4. The image forming apparatus as claimed in claim 1, wherein the latent image carrier
has a frictional coefficient of 0.4 or less.
5. The image forming apparatus as claimed in claim 1, wherein the cleaning blade
includes a side seal that prevents toner scattering, and the lubricant applying area can be
adjusted based on position of the side seal.
6. The image forming apparatus as claimed in claim 1, wherein the toner is such that a
shape factor indicating a degree of sphericity of a toner shape is in a range from 100 to 180,
and a shape factor indicating a degree of irregularities of the toner shape is in a range from
100 to 180.

7. The image forming apparatus as claimed in claim 1, wherein a volume-average
particle size (Dv) of toner is in a range from 3 to 8 micrometers, and a degree of dispersion
defined by a ratio (Dv/Dn) between the volume-average particle size (Dv) and a number-
average particle size (Dn) is in a range from 1.00 to 1.40.
8. The image forming apparatus as claimed in claim 1, wherein a ratio (r2/r1) between
a minor axis (r2) and a major axis of the toner (r1) is in a range from 0.5 to 1.0, a ratio
(r3/r2) between a thickness of the toner (r3) and the minor axis of the toner (r2) is in a range
from 0.7 to 1.0, and r1> r2 >r3.
9. The image forming apparatus as claimed in claim 1, wherein the toner is obtained by
allowing a toner material solution to undergo either one of or both of crosslinking reaction
and elongation reaction in an aqueous medium, the toner material solution being obtained by
dissolving or dispersing at least a polymer having a portion enabling reaction with a
compound that contains an active hydrogen group, and a release agent in an organic
solvent.
10. The image forming apparatus as claimed in claim 1, optionally comprising:
a process cartridge that integrally supports the latent image carrier and at least one a
lubricant applying device which applies the lubricant to the latent image carrier, a charging
device, a developing device, and a cleaning device, the process cartridge being mounted
detachably from the image forming apparatus.
11. The image forming apparatus as claimed in claim 1, wherein the lubricant applying
blade applies the lubricant to a surface of an intermediate transfer belt.
12. The image forming apparatus as claimed in claim 1, wherein the lubricant includes
zinc stearate.


ABSTRACT

AN IMAGE FORMING APPARATUS
An image forming apparatus comprising: a latent image carrier (1) that is rotatable and
configured to carry a latent image; a cleaning blade (8a) that cleans toner remaining on a
cleaning area on the latent image carrier; a lubricant (3b); a lubricant applying brush roller
(3a) configured to scrape off the lubricant and applies scrapped lubricant to the latent image
carrier (1); and a lubricant applying blade (3e) arranged on a downstream side of an applying
apparatus of the cleaning blade (8a) with respect to direction of rotation of the latent image
carrier (1), and that applies a lubricant on the latent image carrier (1), wherein a lubricant
applying area overlaps the cleaning area of the cleaning blade, and wherein a width of the
lubricant (3b) is less than a width of the brush roller (3a) and the width of the brush roller (3a)
is less than a width of the lubricant applying blade (3e) in contact with the latent image
carrier (1) in a longitudinal direction thereof in the image forming apparatus.

Documents:

02208-kolnp-2006 abstract.pdf

02208-kolnp-2006 assignment.pdf

02208-kolnp-2006 claims.pdf

02208-kolnp-2006 correspondence others.pdf

02208-kolnp-2006 description (complete).pdf

02208-kolnp-2006 drawings.pdf

02208-kolnp-2006 form-1.pdf

02208-kolnp-2006 form-3.pdf

02208-kolnp-2006 form-5.pdf

02208-kolnp-2006 international search report.pdf

02208-kolnp-2006 pct form.pdf

02208-kolnp-2006 priority document.pdf

02208-kolnp-2006-correspondence-1.1.pdf

02208-kolnp-2006-form-18.pdf

2208-KOLNP-2006-(03-05-2012)-CORRESPONDENCE.pdf

2208-KOLNP-2006-(03-05-2012)-DRAWINGS.pdf

2208-KOLNP-2006-(03-05-2012)-FORM-2.pdf

2208-KOLNP-2006-(12-03-2012)-CORRESPONDENCE.pdf

2208-KOLNP-2006-ABSTRACT 1.1.pdf

2208-KOLNP-2006-AMANDED CLAIMS.pdf

2208-KOLNP-2006-ASSIGNMENT.pdf

2208-KOLNP-2006-CORRESPONDENCE.pdf

2208-kolnp-2006-description (complete) 1.1.pdf

2208-kolnp-2006-drawings 1.1.pdf

2208-KOLNP-2006-EXAMINATION REPORT REPLY RECIEVED.pdf

2208-KOLNP-2006-EXAMINATION REPORT.pdf

2208-KOLNP-2006-FORM 1-1.1.pdf

2208-KOLNP-2006-FORM 13 1.1.pdf

2208-KOLNP-2006-FORM 13.pdf

2208-KOLNP-2006-FORM 18 1.1.pdf

2208-KOLNP-2006-FORM 18.pdf

2208-KOLNP-2006-FORM 2.pdf

2208-KOLNP-2006-FORM 3 1.2.pdf

2208-KOLNP-2006-FORM 3-1.1.pdf

2208-KOLNP-2006-FORM 5 1.2.pdf

2208-KOLNP-2006-FORM 5-1.1.pdf

2208-KOLNP-2006-GPA.pdf

2208-KOLNP-2006-GRANTED-ABSTRACT.pdf

2208-KOLNP-2006-GRANTED-CLAIMS.pdf

2208-KOLNP-2006-GRANTED-DESCRIPTION (COMPLETE).pdf

2208-KOLNP-2006-GRANTED-DRAWINGS.pdf

2208-KOLNP-2006-GRANTED-FORM 1.pdf

2208-KOLNP-2006-GRANTED-FORM 2.pdf

2208-KOLNP-2006-GRANTED-SPECIFICATION.pdf

2208-KOLNP-2006-OTHERS 1.1.pdf

2208-KOLNP-2006-OTHERS 1.2.pdf

2208-KOLNP-2006-OTHERS.pdf

2208-KOLNP-2006-PETITION UNDER RULE 137.pdf

2208-KOLNP-2006-REPLY TO EXAMINATION REPORT.pdf


Patent Number 253811
Indian Patent Application Number 2208/KOLNP/2006
PG Journal Number 35/2012
Publication Date 31-Aug-2012
Grant Date 27-Aug-2012
Date of Filing 04-Aug-2006
Name of Patentee RICOH COMPANY, LIMITED
Applicant Address 3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
Inventors:
# Inventor's Name Inventor's Address
1 SUDA, TAKEO C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
2 KAWAHARA, SHINICHI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
3 FUJISHIRO, TAKATSUGU C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
4 OJIMI, TOKUYA C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
5 TABUCHI, TAKESHI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
6 YANAGIDA, MASATO C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
7 MIZUISHI, HARUJI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
8 KASUGA, TERUYUKI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
9 HARADA, HIROOMI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
10 TANAKA, SHUJI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
11 TAWADA, TAKAAKI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
12 ONO, HIROSHI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
13 AMEMIYA, KEN C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
14 KOIKE, TOSHIO C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
15 ARAI, YUJI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
16 KAWASUMI, MASANORI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
17 YONEDA, TAKUZI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
18 TOMITA, MASAMI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
19 TAKAHASHI, YUTAKA C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
20 HATTORI, YOSHIO C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
21 YOSHIDA, KEIICHI C/O. RICHO COMPANY, LTD.3-6, NAKAMAGOME, 1-CHOME,OHTA-KU, TOKYO, 143-8555
PCT International Classification Number G03G21/00 ,G03G15/16
PCT International Application Number PCT/JP2005/022731
PCT International Filing date 2005-12-06
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2004-358884 2004-12-10 Japan
2 2005-033312 2005-02-09 Japan
3 2005-198570 2005-07-07 Japan
4 2005-012739 2005-01-20 Japan
5 2005-047225 2005-02-23 Japan