Title of Invention

COMPOSITE MATERIAL OF THIN PLY LAMINATES

Abstract Fiber composite materials using thin plies with a thickness of less than 0.08 mm provide improved delamination resistance and thinner minimum gauge for laminates. Thin plies may be hybridized with conventional plies, interlaced for strength, and used with adhesives as reinforcement in bonding.
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capability of a multi-directional laminate. As composites are being utilized for more and more primary structures, tike the Boeing 78? and Airbus 350 and 380 aircraft, composite components can be hundreds of plies thick, Delamination is a serious threat to the acceptance of composites for many applications.
[0041 One popular solution is to form a laminate as a 3~dimemionaf woven fabric. There are many versions of this weaving technique. There are at least two drawbacks; the cost can be an order of magnitude higher, and the in-plane properties are reduced to make room for the out-of-plane fibers. An alternative to this solution is to use transverse stitching. This approach is not only costly but also has dubious value. Stitching causes additional damage to the composite laminate,
SUMMARY
[005] Briefly, an embodiment of the present invention includes a laminate constructed using thin piies of thickness of 0,08 mm or less. An alternate embodiment includes a combination of thin plies of thickness less than 0*08 mm and thicker conventional plies of at least 0,12 mm thickness. These combinations provide an improved resistance to micro-cracking and delamination, thinner minimum gauge for laminates, opportunities of hybridization of thick and thin plies, reinforcement of bonded joints, interlaced product with performance higher than conventional woven fabrics, improved online consolidation for piping and vessels, and chopped fibers to form stranger sheet molding compounds. Multiple ply-orientation sublaminates (referred to below as "sublaminate modules'1) can be formed as a baste building block for composite laminates, reducing assembly cost while maintaining high resistance to delamination. With or without automation, products from thin ply sublaminates and laminates can be competitive in cost with those constructed from conventional thick ply laminates.
[006] Using a known tow spreading process, conventional 12k tows of carbon* glass or Kevlar fibers {approx, 0.12 mm thick) can be spread to form a ribbon as thin as 0.02 mm thick. With such thin plies, for example, a 3 ply orientation symmetric sublaminate according to the present invention can have the same 0.12 mm thickness as a conventional 0J2 mm ply. Minimum gauge is reduced to as low as one-sixth (1/6) of the thickness of conventional ply. In a symmetrical 4-ply laminate, the minimum gauge would be 0.16 mm. Such thin gauge modules provide design options not available with conventional thick plies*

and have tiiiich higher resistance to del ami nation, In fact, many designs of conventional composite structures are dictated by this delamination criterion. Thus higher performance or lighter weight structures can be effectively designed using thin ply laminates.
BRIEF DESCRIPTION OF THE DRAWING
J007] Fig, 1 illustrates the thin ply laminate of the present invention;
[008] Fig, 2 illustrates the thicker ply of the prior art;
[009] Fig, 3 is a graph of normal stress as a function of ply thickness;
[0010] Fig, 4 is a graph of sheer stress as a function of ply thickness;
[0011] Fig. 5 is a graph of delamination onset stress as a function of ply thickness,
[00121 Fig, 6A illustrates use of thick and thin plies;
[0013] Fig. 6B illustrates a sublaminate;
[0014] Fig. 7A is a perspective view of a composite material using sublaminates;
[0015] Fig. 7B is a side view of a composite material using sublaminates to stow joints;
[0014] Fig, 8A is a graph of stiffness as a function of ply thickness;
(0017] Fig. SB is a graph of max stress as a function of ply thickness;
[0018] Fig. 9 illustrates dry thin ply;
(00191 Fig. 10 shows a resin impregnated thin ply sheet;
f0020] Fig 11 shows a three-layer laminate;
(0021] Fig, 12 illustrates ply weaving and angle in a crimp exchange area;
10022] Fig, 13A is a graph of load deformation versus ply thickness for various temperatures
for a brittle adhesive;
[0023] Fig, 13B is a graph of load deformation versos ply thickness for various temperatures
for a ductile adhesive;
[0024] Fig 14 illustrates using thin ply to join two layers;
10025) Fig. 15 is a table illustrating the effectiveness of the joint of Fig. 14;
[0026] Fig. 16 shows use of a metal foil on one side of a laminate;
[0027] Fig. 17 shows metal foil on both sides of a laminate;
[0028] Fig 18A shows metal foil on both sides and the center of a laminate;
[0029] Fig, 18B is an enlarged section from Fig, I8A; and
[0030] Fig. 19 shows layer construction in the center of the laminate without a foil.

DETAILED DESCRIPTION OF THE EMBODIMENTS
(0031) A cross section of a composite material 10 according to the present invention is shown in Fig. L The composite material 10 has a plurality of layers (plies) including first plies 12 indicated with dots, oriented in a first direction. The first plies 12 are separated by second plies 14 oriented in a second direction, different from the first direction. The second plies 14 are indicated without any marks for the purpose of distinguishing them in Pig. 1 from the first plies 12* According to the present invention, the plies 12* 14 are of a thickness T* less than 0.08 mm, and preferably of thickness from 0,02 mm to 0.06 mm, Fig 2 is used to simply indicate that a conventional/prior art laminate is constructed of alternating plies such as 16, 18 that are thicker than the thickness of the present invention, each having a thickness *T* of generally 0.12 mm or more.
[0032] According to the present invention, thin ply laminates provide improved del animation resistance. They require no out-of-plane fibers and thereby maintain the superior in-plane properties. As an example, the calculated normal and shear stresses present at a free edge of a laminate are shown in Figs, 3 and 4, as functions of ply thickness. The conventional/prior ait ply thickness of at least 0.12 mm is shown on the right of each figure, with decreasing ply thicknesses to the left down to 0.02 mm, These measurements show a dramatic decrease in the normal and shear stresses as ply thickness decreases to 1/3 and 1/6 of the 0.12 mm prior ait thick ply laminate. This is an unexpected result in view of the prior art- Thus, the thin ply laminates provide improved solutions for deiamination resistance*
(0033] Another example of the effect of thin plies on the onset of deiamination is illustrated in Fig, 5 which shows the stress required for deiamination as a function of effective ply thickness. As ply thickness decreases, the deiamination stress again dramatically increases. [0034] As an alternate embodiment, hybrid combinations of thick and thin plies can provide a balance between performance and cost, and this combination is included in the present invention. Thin plies not only increase toughness, they also increase flexibility on ply drop. This is achieved by use of a sublaminate module, in which a module with thin plies having different orientations or a combination of thin and thick plies with different orientations are pre-formed as building blocks for laminates. Instead of dropping individual plies, sublaminate modules are dropped,
{0035} Example 1: An example according to the present invention includes a combination of thick ply with 0.12 mm thickness and thin ply with 0.02 mm thickness. This is illustrated in Fig. 6A with thin plies 21 and thick plies 23. Further* a sublaminate 25 as in Fig, 6B can be a

thick-thin hybrid having one thick [0] ply 27 and one thin [90] ply 29. The total thickness of this sabiaminate module could be 0.12 mm + 0,02 mm = 0.14 mm and the percentage of [0] in this case would be 0.12/0,14 « 86 percent Using this sublaminate to build a mast or boom provides a highly anisotropic structure having a toughness not possible with conventional laminates using only thick plies. For the latter case* the repeating module of thick plies would have to be 9 plies of [0] and one ply of [90]. The total sublaminate thickness would be 1.2Dmm with the percentage of [0] equal to 90 percent This design has 9 plies of [0] stacked together, which is a poor design from the standpoint of toughness, This practice makes masts unstable and susceptible to failure by snapping.
IW36J ExampkL2: If a higher percentage of |0] is desired, it is possible to have two thick plies [0] following by one thin ply [90], In this case the percentage of [0] would be 0.24/0,26 « 92 percent. A tri-directional sublaminate module having two [0] amd one 1+/-45] would have a percentage of [0] of 0.24/0.28 » 86 percent. Both these examples will give the mast or boom much tougher laminates. This hybrid structure is also useful for drive shafts, leaf springs, and sporting goods (e.g. pole vault shafts, hockey sticks, golf clubs, etc.). [W37J Example 3; Another example of a thick-thin piy laminate is a tri-directional sublaminate having one thick 0,12 mm ply fOJ and two thin 0,02 mm* angled-plies [+A30] or [+/-4SJ» such as a [+30W/-3O] or [+45/0M5] module. The total sublaminate thickness is 0,16 mm, which can be accomplished as one step in a ply drop. Tri-directional modules of any combination of thick and thin plies can be produced* This design flexibility allows products with significantly improved laminate performance and significant cost savings in manufacturing.
(00381 Example 4: The same concept of multidirectional subliminates can be designed for spars and ribs as substructures of a composite structure. In this case, shear modulus in the web is most important. A thick-thin hybrid may have thick [+M5] combined with thin 10]. In all these applications, the lay-up process of sublaminates can be in one direction, ejj. along the axis of the spar. In the case of a skin for wings, the lay-up can be along the wing axis. In the case of a fuselage, the lay-up may be in two directions, one along the hoop direction and the other along the axial direction, or along two helical angles. Very significant savings in lay-up machine capability and lay-up time and labor can be realized. [0039] A composite material according to the present invention can be constructed with a plurality of sublaminate modules. Fig. 7A illustrates a composite materia] 31 including sublaminate modules 33. Fig. 7B is a planar side view of a composite material 35 with sublaminates 37, similar to Fig. 7A for illustrating sublaminate joints 39. Sublaminate sheets

are jointed in the direction of width and the steers are stacked up without repeating the joint part in the direction of the thickness. The sublamiaates of Figs. 7A* 7B can- ail be the same, or they can be different. A sublaminaie can have ali thin plies, or a combination of thin and thick plies, and/or the sublaminate can have plies of interlaced fabric as illustrated in Fig. 12. Use of thin ply permits sublaminate thickness of approximately the same as a conventional ply thickness. Using this method, large-scale composite molding of products with superior mechanical properties is obtained,
[0040] One method,of forming thin ply tows is by spreading conventional tows. The cross-section of the spread tows is rectangular with thickness of 0.04 mm or less and width on the order of 20 mm. These spread tows can be easily interlaced to form a woven fabric, A cross section of interlacing tows is shown in Fig. 12. Interlaced fabric offers high performance laminates which easily conform to complex tooling geometries. The total thickness of such an interlaced fabric will be twice that of the thin ply thickness; i.e. 0,04 mm thick if 0.02 mm thin ply is used. The structural performance of an interlaced fabric with thick and thin plies is shown in Figs. 8A and 8B, with increasing mechanical properties shown as ply thickness decreases finom right to left. There is a 35% increase in stiffness and a 20% reduction in maximum stress when 0.02 mm plies are used instead of 0.12 mm plies. [0041] Thin ply 24 may be (a) dry fibers 26 (L& without resin impregnation) as shown in Fig. 9 with a thickness of less than 0.08 mmt and preferably less than 0.06 mm, or (b) fibers 26 in a resin impregnated (pieprcg) sheet 28 of less than QM mmt and preferably less than 0.06 mm (Fig. 10).
[0042] As an example* laminate 28 is shown in Fig. 11, with three layers 30, 32, 34 formed with a plurality of plies 36, Plies can be located close to ends 38 and along a side as at 40, and where layers meet 42. Them may be gaps in between. These gaps only slightly affect the mechanical properties of the laminate because the ply thickness is very small. [0043] Fig. 12 is a cross section of interlaced plies 4J. Thin ply laminates have improved properties because the size of the crimp interchange area 42 and resulting angle A shown in Fig> 12 becomes smaller as ply thickness decreases. The affected area of the crimp when the spread tows weave their way up and down as they meet the orthogonally oriented tows is smaller with thinner tows. The interchanging tows must accommodate one another's thickness^ The thinner the tows, the less accommodation is required at the tow interchange. Thus, the macroscopic stiffness of the interlaced tows and the resulting stress at the interchange are affected by this thickness. The thinner the tows, the higher will be the stiffness and lower local stress.

[0044] Bonded joints provide the best method of joining two composite components. Bonded joints are easier to produce and induce minimum stress concentrations at joints. Broadly speaking, there aft two types of bonded joint adhesive: brittle and ductile adhesives. Figs. 13A and I3B show load-deformation curves of a brittle adhesive and a ductile adhesive at various temperatures, respectively. The sliffest adhesive load-deformation curve is the room temperature behavior. As temperature increases, the adhesive will behave more and more like a ductile material. The brittle adhesive in Fig. 13A is a glass powder reinforced epoxy; the ductile adhesive is PMMA.
[0045] A new bonded joint 43 can be produced using thin ply as a reinforcement, as shown in Fig. 14. The effectiveness of such a joint is shown in the table of Fig. 15, which shows predictions from a finite element analysis. Note the stress reduction to 56% and 30% of the stress far unenforced adhesive. In addition, this joint design achieves a balance between the peel and shear stresses, not having one dominate the other as is the case of unreinforeed adhesive. For thin ply reinforced adhesive, the (0J orientation is aligned with the axial force applied to the bonded joint;
(0046] Sheet molding compounds and mats can be produced using chopped thin ply fibers. These products have higher performance because the loss of stiffness and strength due to crimp interchange is reduced. In addition, thinner plies reduce bending stiffness by a cubic relation; Le> 1/6 of thick ply thickness will have 1/216 the original stiffness. Thus a sheet molding compound made of chopped thin ply tows will more easily conform to the abrupt changes in curvature and shape in a molded part. This processing advantage is in addition to the improved stiffness and strength.
[0047] Online consolidation of carbon reinforced thermoplastic tope also benefits from thin plies in quality and process speed. The usual boardiness (high stiffness) of thick ply tapes can be significantly reduced to more pliable or compliant tape when the tape thickness is smaller. The same cubic relation discussed above also applies to tape flexural rigidity. In online processing using thin tapes, preheating for the sole purpose of making the tape more pliable is not necessary. This process can be used to make pressure vessels by filament winding followed by curing.
[0048] Figs, 16-18 illustrate other embodiments of the laminate of the present invention including metal and thin ply laminate. Fig. 16 shows metal 44 applied to one side of thin ply laminate 46. Fig- 17 shows metal 48, 50 on both sides of thin ply laminate 52. Figures 16 and 17 illustrate products on which a metal matrix composite is bonded to one or both sides

of a thin ply laminate. The metal layer can be created in a number of ways known in the an, including metal foil, vapor deposition (CVD), metal embedded in polymers, plating, etc. The metal protects the laminate* In an uncoated thin ply laminate, the surface ply is very thin. When an outside fiber in the laminate is damaged (e^ by impact or scratch), fiber destruction in the surface ply can easily occur, which can lead to failure of the laminate. The products shown in Figs. 16 mid 17 help prevent such fiber destruction and failure. Fig. 18A shows metal on both sides 54, 56 and in the center 58 of thin ply laminate 60, 62. Fig. 18B is a section from Fig. ISA for illustrating the orientation (90°, -45°) of the fibers in the laminate layers of Fig* 18A, When metal matrix composite is inserted in the center of thin ply laminates as shown in Figures ISA and 18BS double thickness in the laminate is prevented. This is helpful in symmetrical lamination, where double thickness at the center of the laminate can lead to matrix cracking and delaminalion. Fig. 19 illustrates double thickness of the center ply layers if no metal is present, which can create cracking and delamination susceptibility for the laminate,
[0049] A new family of metal matrix composites using metallic and thin ply composites that can be manufactured at reasonably low cost, For example, high temperature composite materials using thin carbon fiber reinforced plastics (CFRP) in conjunction with titanium (Tign Titanium-graphite) or copper (Cugr: Copper-graphite) can be formed. Such metal matrix composites have both high temperature and unique corrosion resistance for many applications, including che mica] piping and vessels.
[0050] For mats and interlaced fabrics, including resin transfer molding (RTM) and vacuum-assisted resin transfer molding (VARTM) processes, the use of thin ply materials makes material flow easier, and enhances conformation to complex surfaces while maintaining superior physical properties.
[0051] The embodiments described above are given as examples of the present invention. Those skilled in the art wilt be aware of variations to these examples. These variations are to be included in the spirit of the present invention. [0052] What is claimed is:









WE CLAIM:
1. A composite material comprising thin plies having a thickness of less than 0,08 mm.
2- The material of claim 1, wherein the material includes a combination of conventional plies having a thickness of at least 0.12 mm, and thin plies having a thickness of less than 008 mm.
3. The material of claim I, wherein the material includes a combination of sublaminate modules of thin plies.
4. The material of claim 2* wherein the material includes sublaminate modules of thin plies and sublaminate modules of conventional plies.
5. The material of claim 2, wherein the material includes sublaminate modules having thin plies and conventional plies.
6. The material of claim I, claim % claim 3, claim 4, or claim 5, wherein the thin plies are interlaced or woven,
7. The material of claim 1, claim 2, claim 3t claim 4, or claim 5, wherein the material is formed using resin transfer molding.
8. The material of claim 1, claim 2, claim 3, claim 4, or claim 5, wherein the thin plies are combined with an adhesive to provide a reinforced bonding material for joining composites and/or metallic components with bonded joints.
9. The material of claim 1, claim 2, claim 3, claim 4f or claim 5* wherein the thin plies are combined with an adhesive to provide a reinforced bonding material for composite components having honeycomb or sandwich construction,
10. The material of claim 1, claim 2, claim 3, claim 4, or claim 5, wherein the thin plies air chopped and reconstituted into a molding compound.

IL A product including the material of claim I, claim 2t claim 3, claim 4, or claim 5, wherein the thin plies or sublimate modules are incorporated into a thermosetting or thermoplastic tape, the product is formed by a tape placement method or a tape winding method* and the tape is cured.
12. A fiber-metal composite material comprising the material of claim 1, claim 2, claim 3, claim 4, or claim 5, and a metal sheet.
13. The composite material of claim 12, wherein the metal sheet is laid only as a surface layer.
14. The composite material of claim 12, wherein the metal sheet is laid
between thin plies having the same fiber direction,
15. The matrix composite material of claim 12, claim 13, or claim 14, wherein
the thin plies include graphite plies,
16. The matrix composite material of claim 15, wherein the metal is selected
from the group consisting of titanium and copper.
Dated this 15th day of March 2007

Documents:

1101-CHENP-2007 AMENDED PAGES OF SPECIFICATION 21-02-2011.pdf

1101-CHENP-2007 AMENDED CLAIMS 21-02-2011.pdf

1101-chenp-2007 form-3 21-02-2011.pdf

1101-chenp-2007 form-5 21-02-2011.pdf

1101-CHENP-2007 EXAMINATION REPORT REPLY RECIEVED 21-02-2011.pdf

1101-chenp-2007 others 14-08-2007.pdf

1101-chenp-2007 abstract 17-05-2007.pdf

1101-chenp-2007 correspondence others 11-08-2008.pdf

1101-chenp-2007 correspondence others 14-08-2007.pdf

1101-chenp-2007 correspondence others 17-05-2007.pdf

1101-CHENP-2007 CORRESPONDENCE-OTHERS 03-11-2009.pdf

1101-chenp-2007 form-1 11-08-2008.pdf

1101-chenp-2007 form-3 17-05-2007.pdf

1101-CHENP-2007 POWER OF ATTORNEY 05-11-2009.pdf

1101-chenp-2007-claims.pdf

1101-chenp-2007-correspondnece-others.pdf

1101-chenp-2007-description(complete).pdf

1101-chenp-2007-drawings.pdf

1101-chenp-2007-form 1.pdf

1101-chenp-2007-form 3.pdf

1101-chenp-2007-form 5.pdf

1101-chenp-2007-pct.pdf


Patent Number 246658
Indian Patent Application Number 1101/CHENP/2007
PG Journal Number 10/2011
Publication Date 11-Mar-2011
Grant Date 09-Mar-2011
Date of Filing 15-Mar-2007
Name of Patentee ITOCHU CORPORATION
Applicant Address 2-5-1 KITTA -AOYAMA MINATO-KU, TOKYO 107-8077, JAPAN
Inventors:
# Inventor's Name Inventor's Address
1 TSAI, STEPHEN W. 101 ALMA STREET #703,PALO ALTO, CALIFORNIA 94301,USA
2 KAWABE KAZUMASA 61 KAWAIWASHIZUKA-CHO, FUKI CITY ,FUKUI PREFECTURE 910-0102, JAPAN
PCT International Classification Number B32B7/02
PCT International Application Number PCT/US2005/034961
PCT International Filing date 2005-09-23
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/668,341 2005-04-04 U.S.A.
2 60/612,740 2004-09-24 U.S.A.