Title of Invention

"METHOD OF HOT PRESSING HIGH STRENGTH MEMBER USING STEEL SHEET AND SUCH HOT PRESSED PARTS"

Abstract A hot pressing method for a high strength automobile member wherein the member is produced by the use of, as a steel component, a steel sheet containing 0.05 to 0.5 mass % of C or a steel sheet plated with a metal material containing Al or Zn as a main component, and by the employment of a hot pressing method, characterized in that the heating temperature before pressing is Ac3 or higher and 1100°C or lower, and the atmosphere during heating has a hydrogen concentration of 6 vol % or less and exhibits a dew point of 10°C or lower; and a hot pressed member manufactured by the above method. The above hot pressing method or hot pressed member uses a hot-rolled or cold-rolled steel sheet or an Al-based metal plated steel sheet or a Zn-based metal plated steel sheet, and can provide a member having a strength of 1200 MPa or higher after a forming at a high temperature and also being almost free from the fear of hydrogen embrittleness. Figure 1
Full Text DESCRIPTION
OF HOT PRESSING HIGH STRENGTH MEMBER USING STEEL SHEET AND SUCH HOT PRESSED PARTS
TECHNICAL FIELD
The present invention relates to a method of hot pressing comprising using cold rolled or hot rolled steel sheet or Al-based or Zn-based plated steel sheet to hot press automobile pillars, door impact beams, bumper beams, or other strength parts and such hot pressed parts .
BACKGROUND ART
To lighten the weight of automobiles, an issue arising from the problem of global warming, it is necessary to make the steel sheet used for automobiles as high in strength as possible. In general, if making steel sheet high in strength, the elongation and r value decrease and the formability deteriorates. To solve this problem, technology for hot forming materials and using the heat at that time to raise the strength is disclosed in Japanese Patent Publication (A) No. 2000-234153. This technology aims at suitably controlling the steel compositions, heating the steel in the fe'rrite temperature region, and utilizing precipitation strengthening in this temperature region to raise the strength .
Further, Japanese Patent Publication (A) No. 2000-87183 proposes high strength steel sheet improved in press forming precision by reducing the yield strength at the formation temperature to much lower than the yield strength at ordinary temperature. However, these technologies may be limited in the obtained strength. On the other hand, technology for obtaining a higher strength by heating the material to the high temperature austenite single-phase region after formation and transforming it to a hard phase in the subsequent cooling
process is proposed in Japanese Patent Publication (A) No. 2000-38640.
However, if heating and rapidly cooling a sheet after forming, problems may arise in the shape precision. As technology for overcoming this defect, technology for heating steel sheet to the austenite single-phase region, then cooling in the press formation process by a cooling rate of at least the critical cooling rate of martensite transformation determined by the steel compositions is disclosed in the Document (SAE, 2001-01-0078) and Japanese Patent Publication (A) No. 2001-181833. The former document discloses to suppress scaling of the surface at the time of heating by using Al-plated steel sheet. This type of pressing process is called "hot pressing" in the present invention.
As prior technology relating to hot pressing using such plated steel sheet, the following may be mentioned. Japanese Patent Publication (A) No. 2003-147499 discloses an example of using steel sheet covered by a plating layer comprised of an Fe-Zn alloy for hot pressing, while Japanese Patent Publication (A) No. 2003-41343 discloses an example of using Al-based plated steel sheet covered by a plating layer comprised of an Fe-Al alloy for hot pressing.
Further, Japanese Patent Publication (A) No. 2002-282951 discloses the example of a method of using a die and punch to press a heated metal sheet wherein the die clearance is defined from the viewpoint of the formability and hardenability.
DISCLOSURE OF THE INVENTION
In this way, the higher the strength, the more high strength steel sheet used for automobiles etc. has the above-mentioned problem of formability and the inherent problem, in particular in high strength materials of over 1000 MPa, of hydrogen embrittlement (also called aging cracks and delayed fracture), as is known from the past. Therefore, when using steel sheet as sheet for hot
pressing, it is important to lower the amount of hydrogen of the material.
The present invention was made to solve this problem and provides a method of hot pressing using hot rolled or cold rolled steel sheet or an Al-based plated steel sheet or a Zn~based plated steel sheet able to give a strength of 1200 MPa or more after high temperature forming and with extremely little liability of hydrogen embrittlement arid such pressed parts.
The inventors engaged in various studies to solve the above problem. As a result, they discovered that controlling the atmosphere and temperature at the time of heating to the austenite single-phase region before pressing is important for producing hot pressed parts superior in resistance to hydrogen embrittlement. That is, since the atmosphere at the time of heating includes hydrogen, this hydrogen invades the steel sheet. Even if moisture is included, similarly hydrogen may invade the steel sheet, so it is important to reduce hydrogen and moisture. Further, the inventors discovered that to prevent hydrogen embrittlement, it is important to suitably select the die clearance. The gist of the present invention based on this discovery is as follows:
A method of hot pressing a high strength
automobile parts comprising using steel sheet containing
as a steel compositions, by wt%, C:0.05 to 0.5% or steel
sheet plated mainly by Al or Zn to hot press an
automobile member during which making the heating
temperature before pressing at least the Acs and not more
than 1100°C, making the hydrogen concentration in the
heating atmosphere not more than 6 vol%, and making the
dew point not more than 10°C.
A method of hot pressing a high strength
automobile parts as set forth in (1), characterized in
that a hydrogen concentration in the heating atmosphere
is not more than 1 vol% and a dew point is not more than
10°C.
A method of hot pressing a high strength
automobile parts as set forth in (1) or (2),
characterized by introducing the steel sheet after
heating into a press machine and making a clearance
between a die and punch at the time of forming 1.0 to 1.8
times the thickness of the steel material used.
A hot pressed part characterized by using a
method of hot pressing as set forth in any one of (1) to
(3) .
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is an external view of a hat shaped die used for a processing test of the examples.
BEST MODE FOR WORKING THE INVENTION
Next, the reasons for limitation of the present invention will be explained.
As explained above, the present invention comprises heating hot rolled or cold rolled steel sheet or Al-based or Zn-based plated steel sheet to 700°C or more, then hot forming it and immediately cooling and hardening it in a die to obtain the desired strength. The present invention defines the steel sheet before heating and press forming. The steel sheet compositions have to be superior in hardenability. Therefore, the amount of C must be 0.05% or more, preferably 0.1% or more. As other steel elements, Si, Mn, Ti, B, Cr, Mo, Al, P, S, N, or other elements are sometimes added. Si has an effect on the fatigue characteristics, so when included, 0.05 to 1% is preferable. Mn, B, Cr, and Mo contribute to the improvement of the hardenability, so when included, Mn: 0.5 to 3%, B: 0.05% or less, Cr: 2% or less, and Mo: 0.5% or less are preferable. Ti and Al improve the oxidation resistance of Al-based plated steel sheet, so when included, Ti: 0.5% or less and Al: 0.1% or less are preferable.
As to the type of plating, steel sheet given Al-based or Zn-based plating may be considered. If using
these for hot. pressing, formation of iron oxide at the surface is suppressed and corrosion resistance can be imparted.
First,, the configuration of the Al-based plating layer will be explained. At the present time, Al-based plated steel sheets are being produced for various applications. The present invention may be used for these steel sheets. As the to configuration of the Al-based plating layer, there is steel sheet with plating mainly comprised of Al and, to suppress the formation of an alloy layer at the time of hot dip Al coating, preferably containing 3 to 15% of Si. In addition, as elements for improving more the corrosion resistance of the plating layer, there are Cr, Mg, Ti, Sn, etc. These may also be added. At this time, Cr: 0.1 to 1%, Mg: 0.5 to 10%, Ti: 0.1 to 1%, and Sn: 1 to 5% are desirably further included. Note that the Al-based plating layer contains Fe as an impurity. The amount is normally 0.05 to 0.5%.
Note that after heating, the surface may be formed with intermetallic compounds such as FeAl3, Fe2Al5, Fe3Al, and Fe2AlaSi. These phases tend typically to be composite layer structures of five layers, but no matter what these phase structures, the gist of the invention of the present invention is riot affected. Further, the composition is mainly Al and Fe. When adding Si to the Al plating bath, Si is also included in an amount of about 5 to 10%. These elements form at least 90% of the total. Further, there may be some slight amount of residual Al not alloyed, but if a small amount, it does not have any particular effect on the performance. After heating, an Al-based oxide or nitride covers the surface, but these amounts are not particularly defined.
Next, the configuration of the Zn-plating layer will be explained. Zn-based plated steel sheets are currently being produced in various compositions. The present invention can be applied to these steel sheets. As typical configurations of Zn-based plating layers, the
folLowinq may be mentioned: Zn-0.2%Al, Zn-5%Al-0.l%Mg, Zn-5'fiAl-0.l%Mg-mische metal, Zn-7%Al-3%Mg, Zn-ll%Al-3%Mg-0.1%Si, Zn-55%Al-l.6%Si, etc. In addition, by plating in a Zn-O.l'fiAl bath, then heating, this may be changed to Zn-10%Fe. In addition, as elements for improving more the corrosion resistance of the plating layer, there are Cr, Mg, T.i, Sn, etc. These may also be added. At this time, Cr: 0.1 to 1%, Mg: 0.5 to 10%, Ti: 0.1 to 1%, and Sn: 1 to 5% are preferably contained.
Note that after heating, the surface may be formed with £,, 61, F, Fl phases or other intermetallic compounds or a ferrite phase containing Zn in solid solution. These phases may be distributed in layers or distributed in the form of particles, but no matter what these phase structures, the gist of the invention of the present application is not affected. Further, if plating comprised including Al, formation of the above-mentioned Fe-Al-based compound is also possible. In the case of Zn— based plating, after the heating, a Zn-based or Al-based oxide film is formed, but even if these are formed, the gist of the present invention is not affected.
The amount of deposition of the Al-based or Zn-based plating, the treatment before plating, and the treatment after it are not particularly limited, but the plating deposition is preferably at least 50 g/m2 on one side. This is because the greater the amount of plating deposition, the more improved the effect of suppression of oxidation at the time of heating and the corrosion resistance of the part after heating and forming. As such treatment after plating, chromate treatment, resin coating, etc. for primary rust prevention and lubrication are possible, but an organic resin is consumed upon heating, so is not preferred. For the chromate treatment as well, considering the recent restrictions on hexavalent chrome, electrolytic chromate or other trivalent coatings are preferred. Even not imparting a chromate coating and just coating with oil is possible in
the case of Al-based plated steel sheet superior in corrosion resistance.
In the present invention, the temperature and atmosphere at the time of heating are defined. The temperature is made at least Ac3 and not more than 1100°C. This is because for the steel sheet to completely transform to the austenite single-phase region, the Acs temperature or more is necessary. On the other hand, if the heating temperature is too high, the surface oxidizes and hydrogen more actively invades the steel. If using a Zn-based plating, in addition to this, since the boiling point of Zn is about 910°C and, at a high temperature, Zn will completely evaporate away and the steel sheet will become seriously oxidized, 1000°C is preferably made the upper limit. More preferably, the upper limit temperature is 920°C. The lower limit temperature is preferably made 800°C. This is because even if heating to the Aca temperature or more, in the interval after heating when the steel sheet is taken out from the furnace and transported to the press machine, the temperature drops and ferrite ends up being formed in some cases.
The heating atmosphere is made one with a hydrogen concentration of 6 vol% or less. This is because, as explained above, the invasion of hydrogen into the steel will increase the liability of hydrogen embrittlement. No lower limit is particularly set, but the lower the better. More preferably, the amount of hydrogen is 1% or less. Similarly, the inventors discovered in the present invention that the moisture in the atmosphere may also easily invade the steel as hydrogen. Therefore, the moisture in the atmosphere is also preferably low. In practice, the dew point is measured to measure the moisture content. The upper limit of the dew point is made 10°C. Note that the following equation is known for conversion of the dew point and moisture content. The moisture content at this time is 1.2 vol%. In particular,
when using a Zn-based plated steel sheet, having the atmosphere contain oxygen causes the steel sheet surface to be formed with a Zn oxide and suppress the evaporation of Zn. Therefore, when using a Zn-based plated steel sheet, the atmosphere preferably contains oxygen in an amount of I to 21%. Further, not only plated steel sheet, but also not plated steel sheet (bare material) is invaded by hydrogen during heating, so the hydrogen concentration and moisture content of the heating atmosphere must be controlled. Equation 1
44016-118.774 *Tdp
= ex —
8.314*Tdp
f ;
hydrogen concentration (vol%) Tdp: dew point (absolute temperature)
The heating method is not particularly prescribed. It may be radiant heating by radiant tubes etc., induction heating, conduction heating, etc. The heating rate at this time is not limited. This naturally depends largely on the sheet thickness and the shape.
Hot pressing is characterized by cooling from an austenite phase to obtain a hardened microstructure. Naturally, the effect of the cooling rate after heating is great. In the present invention, it is necessary to cool by at least the critical cooling rate for obtaining a martensite structure as determined by the steel compositions, but as a general measure, the average cooling temperature from 700°C to 350°C is preferably at least 15°C/sec. This cooling rate depends on the steel ingredients. In a steel with a good hardenability, even with a cooling rate of about 20°C/sec, a desired structure mainly comprised of martensite can be obtained. Depending on the type of the steel, a cooling rate of about 30°C/sec
may become necessary.
At the time of pressing, the clearance between the die arid punch is an important factor. In the present invention, this clearance is preferably 1.0 to 1.8 times the sheet thickness. If the clearance is small, the sheet will have difficulty flowing resulting in ironing, so the surface of the steel sheet will suffer from galling which may form the starting point for hydrogen embrittlement. Further, if large, hardening tends to become difficult, the part will become uneven in strength, residual stress will remain in the part, and the possibility of hydrogen embrittlement will rise.
EXAMPLES
Next, examples will be used to explain the present invention in further detail.
(Example 1)
Cold rolled steel sheets having the steel compositions shown in Table 1 and having thicknesses of 1.4 mm were heated under various conditions, then formed by a hat shaped die as shown in FIG. 1. The clearance was made 1.1 times the sheet thickness. After this, in the flange of each part, 5 nrnwj) holes were punched at 10 points with a clearance of 0.5 mm (two sides). After the elapse of seven days, a 20X power loupe was used to examine the punched out parts and judge the presence of microcracks. The samples were heated by insertion in an electric furnace controlled in atmosphere. The time for raising the temperature to 900°C was about 4 minutes, the time from the furnace to the press was about 10 seconds, and the press start temperature was about 750°C. The cooling was performed in the die. The average cooling rate from 700°C to 350°C was 40°C/sec. The heating conditions and the presence of any microcracks are shown in Table 2. Note that after forming, part was cut out and measured for Vicker's hardness at a load of 10 kgf, whereupon the Hv was in the range of 410 to 510 and a martensite
microstructure was exhibited at all levels. Further, after hot pressing, the surfaces of these steel sheets were formed with iron oxide.
No. 8 of Example 1 was high in dew point, so five or more microcracks occurred. No. I and No. 3 had amounts of hydrogen of over 1%, so small amounts of microcracks occurred.
Table I (Table Remove)
Scoring of occurrence of microcracks:
Total number of microcracks at 10 points: VG (very good):
0, G (good): I, F (fair): less than 5, P (poor): 5 or
more
(Example 2)
Cold rolled steel sheets of the steel compositions shown in Table 3 after the ordinary hot rolling and cold rolling processes (sheet thickness 1.4 mm) were used as materials for hot dip Al coating. The hot dip Al coating was performed using a nonoxidizing furnace-reduction furnace type line. After plating, the gas wiping method was used to adjust the plating deposition to 80 g/m2 per side, then the sheets were cooled. The plating appearance
was good with no nonplated areas. The type of plating and the bath temperature are shown in Table 9. The plating bath composition at this time was Al-10%Si-2%Fe and the bath temperature was 660°C. The Fe in the bath was unavoidable Fe from the plating equipment or strip. The plating appearance was good with no nonplated areas. The thus hot dip Al coated steel sheets were heated under various conditions, then formed by a hat shaped die shown in FIG. 1. The clearance was made 1.1 times the sheet thickness. After this, in the flange of each part, 5 mm*}) holes were punched at 10 points with a clearance of 0.5 mm (two sides). After the elapse of seven days, a 20X power loupe was used to examine the punched out parts and judge the presence of microcracks. The samples were heated by insertion in an electric furnace controlled in atmosphere. The time for raising the temperature to 900°C was about 4 minutes, the time from the furnace to the press was about 10 seconds, and the press start temperature was about 750°C. The cooling was performed in the die. The average cooling rate from 700°C to 350°C was 40°C/sec. The heating conditions and the presence of any microcracks are shown in Table 4. Note that after forming into the hats, parts were cut out and measured for Vicker's hardness at a load of 10 kgf, whereupon the Hv's were in the range of 410 to 510 and a martensite structure was exhibited at all levels. Further, after hot pressing, the surfaces of these steel sheets were not formed with iron oxide.
Table 3(Table Remove)
Scoring of occurrence of microcracks:
Total number of microcracks at 10 points: VG (very good):
0, G (good): 1, F (fair): less than 5, P (poor): 5 or
more
As shown in Table 4, the amount of hydrogen invading the steel changes and the sensitivity to microcracks changes depending on the heating atmosphere and temperature. No. 5 with a hydrogen concentration of 10 vol% and No. 8 with a dew point of 15°C exhibited five or more cracks. As the hydrogen concentration and dew point are lowered, the formation of cracks is suppressed, but in the case of Nos. 6, 11, and 16, some cracks were formed.
(Example 3)
Cold rolled steel sheets having the steel compositions shown in Table 5 and having thicknesses of 1.4 mm were used for various types of Zn-based plating. The type of plating, bath compositions, and bath temperature at this time are shown in Table 6. These Zn-based plated steel sheets were used to form hats in the same way as in Example 1. The presence of any microcracks after punching was examined. The relationship between the
heating conditions and the state of formation of cracks at this time is shown in Table 7. The cooling was performed in the die. The average cooling rate from 700°C to 350°C was 20°C/sec. The samples were measured for cross-sectional, hardness after formation in the same way as in Example 1, whereupon all the samples had Hv's in the range of 410 to 510 and the structures were martensite microstructures. Further, after hot pressing, the surfaces of these steel sheets were not formed with iron oxide.
Table 5(Table Remove)
Scoring of occurrence of microcracks:
Total number of microcracks at 10 points: VG
0, G (good): 1, F (fair): less than 5, P (poor): 5 or
mo r e
In the same way as in Examples 1 and 2, No. 8 of Table 7 had a high dew point, so microcracks occurred. Nos. 1. and 3 had amounts of hydrogen larger than 1%, so some microcracks occurred. Further, Nos. 1 to 3 had low oxygen concentrations, so the furnace became dirty along with evaporation of the Zn in the furnace and deterioration of the surfaces of the steel sheets were observed.
(Example 4)
Cold rolled steel sheets of the steel compositions shown in Table 8 after the ordinary hot rolling and cold rolling processes (sheet thickness 1.4 mm) were used as materials. Parts were coated with Al by hot dipping or coated with Zn by hot dipping. The hot dipping was performed using a nonoxidizing furnace-reduction furnace type line. After plating, the gas wiping method was used to adjust the plating deposition, then the sheets were cooled. The plating appearance was good with no nonplated areas. The type of plating and the bath temperature are shown in Table 9. (Table Remove)
The thus produced steel sheets were heated under various conditions and then formed by the hat shaped die shown in FIG. 1. The clearance at the time of hot pressing is shown in Table 10. After this, in the flange
of each part, 5 rnrnij) holes were punched at 10 points with a clearance of 0.5 mm (two sides). After the elapse of seven day;s, a 20X power loupe was used to examine the punched out parts arid judge the presence of microcracks. The samples were heated by insertion in an electric furnace controlled in atmosphere. The time for raising the temperature to 900°C was about 4 minutes, the time from the furnace to the press was about 10 seconds, and the press start temperature was about 750°C. The cooling was performed in the die. The average cooling rate from 700°C to 350°C was 40°C/sec. The heating conditions and the presence of any microcracks are shown in Table 10. Note that after forming into the hat, part was cut out and measured for Vicker's hardness at a load of 10 kgf, whereupon the Hv was in the range of 410 to 510 and a martensite microstructure was exhibited at all levels.
Table 10(Table Remove)
Scoring of occurrence of microcracks:
Total number, of microcracks at 10 points: VG (very good) : 0, G (good): 1, F (fair): less than 5, P (poor): 5 or more
Nos. 1, '/, and 13 of Table 10 had clearances of the die at the Lime of hot pressing of less than the limit, so five or more microcracks were observed. Nos. 6, 12, and 18 of Table 10 had die clearances at the time of hot pressing of over the limit, so were uneven in strength and had residual stress remaining in the parts, so five or more microcracks were observed. Nos. 5, 11, and 17 had somewhat larger die clearances at the time of hot pressing, so were uneven in strength and tended to have residual stress remaining in the parts, so some microcracks occurred.
INDUSTRIAL APPLICABILITY
According to the present invention, it is possible to use hot rolled or cold rolled steel sheet or Al-based plated steel sheet or Zn-based plated steel sheet to produce high strength members by the hot pressing method and possible to use them without hydrogen embrittlement.








We Claim:
1. A method of hot pressing a high strength automobile parts comprising using steel sheet that comprises a plating layer that is at least about 50g/m on one side of the sheet, containing as a steel compositions, by wt%, C: 0.05 to 0.5% or steel sheet plated mainly by Al or Zn to form an automobile member by hot pressing during which making the heating temperature before pressing at least Ac3 and not more than 1100°C, controlling the hydrogen concentration in the heating atmosphere of not more than 1 vol%, the dew point of not more than 10 °C, introducing the steel sheet into a press machine after heating and providing a clearance between a die and punch of the said press machine at the time of shaping in the range of 1.0 to 1.8 times the thickness of the steel sheet.
2. A hot pressed high strength automobile part produced using a method of hot pressing as claimed in claim 1.
3. A method of hot pressing a high strength automobile part substantially as herein described with reference to accompanying drawings and foregoing examples.

Documents:

50-DELNP-2007-Abstract-(30-07-2010).pdf

50-delnp-2007-abstract.pdf

50-DELNP-2007-Claims-(01-12-2010).pdf

50-DELNP-2007-Claims-(30-07-2010).pdf

50-delnp-2007-claims.pdf

50-DELNP-2007-Correspondence-Others-(01-12-2010).pdf

50-DELNP-2007-Correspondence-Others-(23-06-2010).pdf

50-DELNP-2007-Correspondence-Others-(29-07-2010).pdf

50-DELNP-2007-Correspondence-Others-(30-07-2010).pdf

50-DELNP-2007-Correspondence-Others.pdf

50-delnp-2007-description (complete).pdf

50-DELNP-2007-Drawings-(30-07-2010).pdf

50-delnp-2007-drawings.pdf

50-DELNP-2007-Form-1-(30-07-2010).pdf

50-delnp-2007-form-1.pdf

50-delnp-2007-form-18.pdf

50-DELNP-2007-Form-2-(30-07-2010).pdf

50-delnp-2007-form-2.pdf

50-delnp-2007-form-26.pdf

50-DELNP-2007-Form-3-(29-07-2010).pdf

50-DELNP-2007-Form-3.pdf

50-delnp-2007-form-5.pdf

50-DELNP-2007-GPA-(29-07-2010).pdf

50-delnp-2007-pct-304.pdf

50-delnp-2007-pct-308.pdf

50-delnp-2007-pct-311.pdf

50-delnp-2007-pct-search report.pdf


Patent Number 245294
Indian Patent Application Number 50/DELNP/2007
PG Journal Number 02/2011
Publication Date 14-Jan-2011
Grant Date 12-Jan-2011
Date of Filing 02-Jan-2007
Name of Patentee NIPPON STEEL CORPORATION
Applicant Address 6-1, MARUNOUCHI 2-CHOME, CHIYODU-KU, TOKYO 100-8071, JAPAN
Inventors:
# Inventor's Name Inventor's Address
1 NORIHIRO FUJITA (5) C/O NIPPON STEEL CORPORATON NAGOYA WORKS, 5-3, TOKAIMACHI, TOKAI-SHI, AICHI 476-8686, JAPAN
2 KAZUHISA KUSUMI (1)-(4)(6): C/O NIPPON STEEL CORPORATION YAWATA WORKS, 1-1 TOBIHATACHO, TOBATA-KU, KITAKYUSHU-FUKUOKA 804-8501 JAPAN
3 JUN MAKI (1)-(4)(6): C/O NIPPON STEEL CORPORATION YAWATA WORKS, 1-1, TOBIHATACHO, TOBATA-KU, KITAKYUSHU-SHI, FUKUOKA 804-8501, JAPAN
4 MASAYUKI ABE (5) C/O NIPPON STEEL CORPORATON NAGOYA WORKS, 5-3, TOKAIMACHI, TOKAI-SHI, AICHI 476-8686, JAPAN
5 MASAHIRO OHGAMI (5) C/O NIPPON STEEL CORPORATON NAGOYA WORKS, 5-3, TOKAIMACHI, TOKAI-SHI, AICHI 476-8686, JAPAN
6 SHINYA NAKAJIMA (5) C/O NIPPON STEEL CORPORATON NAGOYA WORKS, 5-3, TOKAIMACHI, TOKAI-SHI, AICHI 476-8686, JAPAN
PCT International Classification Number B21D 22/20
PCT International Application Number PCT/JP2005/013518
PCT International Filing date 2005-07-15
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2004-208326 2004-07-15 Japan
2 2005-203748 2005-07-13 Japan