Title of Invention | A FUEL COMPOSITION |
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Abstract | A fuel composition with a sulphur content of less than or equal to 500 ppm, and comprising at least one additive, characterized in that the additive is composed of: from 5 to 25% by weight of at least one glycerol monoester of formulae (IA) and/or (IB) below: with R1 chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms, • from 35 to 75% by weight of at least one compound of formula (II) below: in which R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is chosen from (i) the groups ORo, Ro being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, • from 0.1 to 20% by weight of at least one glycerol diester of formula (IIIA) and/or (IIIB): in which R3 and R4 are identical or different and are chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms. |
Full Text | FUEL LUBRICITY ADDITIVE The present invention relates to a fuel contain- ing a lubricity additive for improving the lubrication properties of fuels, whether ground vehicle engine fuel (diesel) or jet fuel, and more particularly of diesel fuels with a low sulphur content. It is well known that diesel fuels and jet fuels must have lubricating capabilities, for the protection of pumps, injection systems and any moving part with which these products come into contact in an internal combustion engine. With the intention of employing products which are increasingly pure and non-polluting, in particular devoid of sulphur, the refining industry has been led increasingly to improve its treatment processes for the removal of sulphur compounds. However, it has been observed that on losing sulphur compounds, the aromatic and polar compounds often associated were also lost, which caused a loss in the lubricating power of these fuels. Thus, beyond certain contents, the elimination of sulphur compounds from the composition of these products very substantially promotes the phenomena of wear and of failure of moving components in pumps and in injection systems. As regulations in many countries have imposed a limitation on the acceptable upper content of sulphur compounds in fuels of 0.05% by weight, in order to lower the emissions of polluting combustion gases from cars, lorries or buses, especially in urban built-up areas, these lubricating compounds must be replaced by other compounds which are non-polluting with regard to the environment but exhibit a sufficient lubricating power to avoid the risks of wear. The literature also mentions that petrol fuels with a low sulphur content have a lubricating power which can prove to be insufficient to ensure good lubrication of the injection systems in new vehicles and can bring about a premature risk of wear. Several types of additives have already been provided in order to solve this problem. Thus, antiwear additives have been added to diesel fuels, some of these additives being known in the field of lubricants, of the type of unsaturated fatty acid dimers and fatty acid esters, aliphatic amines, esters of fatty acids and of diethanolamine, and long-chain aliphatic monocarboxylic acids, such as described in Patents US 2,527,889, US 4,185,594, US 4,204,481 and US 4,208,190. The majority of these additives exhibit a sufficient lubricating power but at concentrations which are much too high, which is very unfavourable economically for purchasing. In addi- tion, additives containing dimeric acids, like those containing trimeric acids, cannot be employed in fuels feeding vehicles in which the fuel can be in contact with the lubricating oil, because these acids form, by chemi- cal reaction with the detergents usually employed in lubricants, deposits which can accelerate the wear processes. Patent US 4,609,376 recommends the use of antiwear additives obtained from esters of mono- and polycarboxylic acids and of polyhydroxylated alcohols in fuels containing alcohols in their composition. In Patent GB 2,307,246, the product resulting from the reaction of carboxylic acid containing 10 to 60 carbon atoms, chosen from fatty acids or fatty acid dimers, with an alkanolamine, obtained by condensation of an amine or of a polyamine with an alkylene oxide, is preferred as lubricity additive. It is preferable, in Patent GB 2,307,247, to employ an acid derivative, substituted by a least one hydroxyl group or one ester of polyols, or alternatively an amide of this acid. Another route chosen is to introduce vegetable oils or their esters into the fuels, in order to improve their lubricating power or their lubricity. These include rapeseed, linseed, soybean and sunflower oils or their esters (see Patents EP 635,558 and EP 605,857). However, one of the major disadvantages of these esters is their low lubricating power at a concentration of less than 0.5% by weight in the fuels. The present invention aims to solve the problems encountered with the additives provided by the prior art, that is to say to improve the lubricating power of the desulphurized and partially dearomatized fuels, while remaining compatible with the other additives, in par- ticular detergents, and the lubricating oils, in par- ticular in not forming deposits, and while reducing the cost price, in particular by a lower additive content of markedly less than 0.5%. The subject of the present invention is the use as lubricity additive for improving the lubricating power of diesel and aviation fuels with a low sulphur content, that is to say with a sulphur content of less than or equal to 500 ppm, characterized in that the additive is composed of: 1) from 5 to 25% by weight of at least one glycerol monoester of following formula (IA) or (IB): with Rx chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms, 2) from 3 5 to 75% by weight of a compound of formula (II) below: in which R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms or a cyclic or polycyclic group comprising from 8 to 60 carbon atoms and X is chosen from (i) the groups OR0, R0 being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, 3) and from 5 to 20% by weight of at least one glycerol diester of formulae (IIIA) and/or (IIIB) : in which R3 and R4, which are identical or different, are chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms, and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms. Preference is given, among the glycerol mono- esters of formula (I) and the diesters of formula (III) with, respectively, Rx or R3 and R4 consisting of an alkyl chain, to the monoesters and diesters obtained from the oils of the group composed of lauryl oils originating from copra or palm, which are rich in saturated alkyl chains containing 12 to 14 carbon atoms, palmitic oils resulting from palm, lard or tallow, containing a major amount of saturated alkyl chains containing 16 carbon atoms, linoleic oils resulting from sunflower, maize or rape, containing a high content of linoleic acid, linolenic oils from linseed, comprising significant contents of triunsaturated alkyl chains containing from 1 to 18 carbon atoms, and ricinoleic oils resulting from the castor oil plant. Among the glycerol monoesters and diesters obtained from polycyclic acids, the preferred monoesters and diesters comprise an Rx or R3 and/or R4 composed of at least two rings, each formed of 5 to 6 atoms, at most one of which is optionally a heteroatom, such as nitrogen or oxygen, and the others are carbon atoms, these two rings additionally having two carbon atoms in common, preferably vicinal, these said rings being saturated or unsaturated. These are preferably glycerol monoesters of natural resin acids obtained from the residues from the distillation of natural oils extracted from resinous trees, in particular resinous conifers. Among these esters of resin acids according to the invention, preference is given to esters of abietic acid, of dihydroabietic acid, of tetrahydroabietic acid, of dehydroabietic acid, of neoabietic acid, of pimaric acid, of laevopimaric acid and of parastrinic acid. By adjusting the operating conditions for partial hydrolysis of these oils, it is possible directly to obtain the mixture of glycerol monoalkyl esters/dialkyl esters. According to another form of the invention, it is possible to prepare glycerol alkyl esters by an esterification reaction between the carboxylic acids described above and glycerol. The esters and the amides of formula (II) can be easily obtained by reaction of an alcohol, amine and/or alkanolamine compound with an organic acid, such as oleic acid, or a simple ester, such as methyl oleate, the reaction being carried out under the conditions known per se by a person skilled in the art for esterification and amidation processes. In a first embodiment, the alcohols used to obtain the compound (II) are chosen from the group composed of methanol, ethanol, propanol, isopropanol, butanol, isobutanol, pentanol or 2-ethylhexanol, and/or oxyalkylated alcohols of formula R(0-CH2-CHR')n-0H, in which R is an alkyl group containing 1 to 6 carbon atoms, R' is hydrogen or an alkyl group containing 1 to 4 carbon atoms and n an integer varying from 1 to 5, such as methyl cellosolve, butyl cellosolve, butyl digol and 1- butoxypropanol. In a second embodiment, the primary or secondary amines used to obtain the compound (II) are chosen from the group composed of methylamine, ethylamine, propyl- amine, butylamine, isobutylamine, 2-ethylhexylamine, decylamine, dodecylamine, stearylamine and oleylamine, N,N-diethylamine, N,N-dipropylamine, N,N-dibutylamine, N,N-di(2-ethylhexyl)amine, methyldecylamine, N-methyl- dodecylamine and N-methyloleylamine. In a third embodiment, for the compound (II), use is made of alkanolamines chosen from amines containing 1 to 18 carbon atoms substituted by at least one hydroxy- lated, hydroxymethylated, hydroxyethylated or hydroxy- propylated group, such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, N-methylethanolamine, tris(hydroxy- methyl)aminomethane, (N-hydroxyethyl)methylimidazoline or (N-hydroxyethyl)heptadecenylimidazoline. The additives obtained by physical mixing according to the invention are used to improve the lubricating power of diesel fuels for ground vehicle engines, optionally as a mixture with at least one oxygen-containing compound chosen from the group formed by alcohols, ethers and esters, as well as with any additive used to improve the quality of fuel, such as detergent, dispersing, antioxidizing and antifoaming additives or -even biofuel. A second subject of the invention corresponds to the fuels containing between 25 and 2500 ppm and pre- ferably from 100 to 1000 ppm by weight of at least one additive used according to the invention dispersed in a diesel fuel which are defined by ASTM standard D-975. The examples below are given by way of illustration of the invention but do not limit the scope thereof. EXAMPLE I: The object of the present example is to compare the lubricating power of the lubricity additives according to the invention with that of the known lubricity additives with regard to wear under the HFRR (High Frequency Reciprocating Rig) test conditions, as is described by the standardized procedure CEC-F06-A96 in the SAE 932692 article by J. W. Hadley of the University of Liverpool. The additives according to the invention will be referenced Xi, while the comparative additives will be referenced TA. A first additive T1 is the product of the reaction of oleic acid with diethanolamine. This reaction is carried out in a 500 ml four-necked round-bottomed flask into which are introduced first 84.6 g of oleic acid and 105.3 g of xylene and then 31.5 g of diethanol- amine over a period of 10 minutes. The entire mixture is subsequently maintained under reflux in xylene for 6 hours in order to remove 6.4 ml of water. The final product obtained contains 50% of active material with an orangey-yellow colour. Analysis by infrared spectroscopy exhibits absorption bands at 3500 cm"1, at 1730 cm"1 and at 1650 cm"1, corresponding respectively to the hydroxyl, ester and amide functional groups. The second additive T2 is the product of the reaction of a tall-oil acid and of diethanolamine. The tall-oil acid used is a combination of 70% of a mixture of fatty acids (55% oleic acid, 38% linoleic acid, 5% palmitic acid and 2% of linolenic acid) and of 30% of resin acids exhibiting an acid number of 185 mg of KOH per gram. The reaction is carried out as for T1 by introducing 80 g of tall-oil acid, 28.2 g of diethanol- amine and 98.6 g of xylene successively into the round- bottomed flask and by maintaining reflux in xylene for 6 hours. The final reaction product is a clear, viscous, orangey-yellow liquid having a residual acid number of 0.21 mg of KOH per gram. The third additive T3 is a mixture of glycerol alkyl esters, mono-, di- and trialkyl esters, mainly comprising glycerol monooleate. The first additive according to the invention X1 is a physical mixture of 2 g of the additive T2 and 1 g of the additive T3. The second additive according to the invention X2 is a physical mixture of 2 g of the additive T1 and 1 g of the additive T3. The additive T4 is the glycerol trioleate sold by the company Fluka. The third additive according to the invention X3 is the product of the reaction of gylcerol trioleate T4 with diethanolamine. The reaction is carried out in a four-necked round-bottomed flask, as for Tx, by mixing 80 g of glycerol trioleate and 18.5 g of diethanolamine and by then heating the entire mixture at 150°C for 4 hours. The additive T5 is a soybean triglyceride oil with an average molecular mass of approximately 870, composed of 28% of oleic acid, 50% of linoleic acid, 8% of linolenic acid, 3% of stearic acid, 10% of palmitic acid and 1% of arachidic acid. The fourth additive according to the invention X4 is the product of the reaction of 87 g of T4 with 21 g of diethanolamine, the mixture being kept stirred at 150°C for 6 hours. The additive X4 is a fluid, orangey-yellow liquid exhibiting, by infrared spectrometry, the absorption bands characteristic of the alcohol, ester and amide functional groups. The fifth additive according to the invention X5 is obtained under the same conditions as the additive X4 but by using 87 g of T4 and 15.75 g of diethanolamine. The sixth additive according to the invention X6 is obtained under the same conditions as the additive X4 but by using 27 g of the additive Ts and 26 g of diethanolamine. The seventh additive according to the invention X7 is obtained under the same conditions as the additive X4 but by replacing diethanolamine by 24 g of tris- (hydroxymethyl)aminomethane. The eighth additive according to the invention X8 is obtained under the same conditions as the additive X4 but by using, as triglyceride, castor oil with an average molecular mass of approximately 927 composed of 87% of ricinoleic acid, 7% of oleic acid and 3% of stearic acid. Each of the additives described above is introduced into three different diesel oils A, B and C, the characteristics of which are given in Table I below, at a content of 100 ppm of active material. The diesel oils A, B and C, thus treated with additives, were subjected to the HFRR test, which consists in jointly applying, to a steel ball in contact with a motionless metal plate, a pressure corresponding to a weight of 2 00 g and an alternating movement of 1 mm at a frequency of 50 Hz. The moving ball is lubricated by the test composition. The temperature is maintained at 6 0°C throughout the duration of the test, that is to say 75 min. The lubricating power is expressed by the mean value of the diameters of the wear imprint of the ball on the plate. A small wear diameter indicates a good lubricating power; conversely, a large wear diameter expresses a power which becomes increasingly insufficient as the wear diameter increases. It is found, from this Table II, that the physical mixtures according to the invention, such as X1 and X2, have wear characteristics which are smaller and thus clearly better than those of T1, T2 and T3, which expresses the synergistic effect obtained by combination of the predominant components of the lubricity additive according to the invention. X3 corresponds to the reaction product obtained according to the process of the invention from diethanolamine with glycerol trioleate. As above, the advantage of the additive thus obtained with regard to the wear characteristics obtained with T4 is perceived. The performances of the additives X4, X5, X6 and X7 are to be compared with those of the starting oil T5. As above, the combination of the reaction products limits the wear phenomena observed in the case of the oil alone. CLAIMS 1. Use as lubricity additive for diesel and aviation engine fuels, with a sulphur content of less than or equal to 500 ppm, characterized in that the additive is composed of: ¦ from 5 to 25% by weight of at least one glycerol monoester of formulae (IA) and/or (IB) below: with Rx chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms, ¦ from 35 to 75% by weight of at least one compound of formula (II) below; in which R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is chosen from (i) the groups OR0, R0 being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, ¦ from 0.1 to 20% by weight of at least one glycerol diester of formula (IIIA) and/or (IIIB) : in which R3 and R4 are identical or different and are chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 6 0 carbon atoms. 2. Use according to Claim 1, characterized in that the glycerol monoesters of formula (I) and the diesters of formula (III) with, respectively, Rx or R3 and R4 consisting of an alkyl chain are chosen from the monoesters and diesters obtained from the oils of the group composed of lauryl oils originating from copra or palm, which are rich in saturated alkyl chains containing 12 to 14 carbon atoms, palmitic oils resulting from palm, lard or tallow, containing a major amount of saturated alkyl chains containing 16 carbon atoms, linoleic oils resulting from sunflower, maize or rape, containing a high content of linoleic acid, linolenic oils from linseed, comprising significant contents of triun- saturated alkyl chains containing 1 to 18 carbon atoms, and ricinoleic oils resulting from the castor oil plant. 3. Use according to either of Claims 1 and 2, characterized in that the gylcerol monoesters of formula (I) and the glycerol diesters of formula (III) comprise an Ri or R3 and/or R4 composed of at least two rings, each formed of 5 to 6 atoms, at most one of which is optionally a heteroatom, such as nitrogen or oxygen, and the others are carbon atoms, these two rings additionally having two carbon atoms in common, preferably vicinal, these said rings being saturated or unsaturated. 4. Use according to Claim 3, characterized in that the glycerol monoesters and diesters of formulae (I) and (III) are obtained from natural resin acids contained in the residues from the distillation of natural oils extracted from resinous trees, in particular from resinous conifers. WE CLAIM: 1. A fuel composition with a sulphur content of less than or equal to 500 ppm, and comprising at least one additive, characterized in that the additive is composed of: from 5 to 25% by weight of at least one glycerol monoester of formulae (Ia) and/or (Ib) below: with R1 chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms, • from 35 to 75% by weight of at least one compound of formula (II) below: in which R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is chosen from (i) the groups OR0, R0 being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, • from 0.1 to 20% by weight of at least one glycerol diester of formula (IIA) and/or (IIIB): in which R3 and R4 are identical or different and are chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms. 2. Fuel composition as claimed in claim 1, wherein the glycerol monoesters of formula (I) and the diesters of formula (III) with, respectively, R1 or R3 and R4 consisting of an alkyl chain are chosen from the monoesters and diesters obtained from the oils of the group composed of lauryl oils originating from copra or palm, which are rich in saturated alkyl chains containing 12 to 14 carbon atoms, palmitic oils resulting from palm, lard or tallow, containing a major amount of saturated alkyl chains containing 16 carbon atoms, linoleic oils resulting from sunflower, maize or rape, containing a high content of linoleic acid, linolenic oils from linseed, comprising significant contents of triunsaturated alkyl chains containing 1 to 18 carbon atoms, and ricinoleic oils resulting from the castor oil plant. 3. Fuel composition as claimed in claims 1 and 2, wherein the glycerol monoesters of formula (I) and the glycerol diesters of formula (III) comprise an R1 or R3 and/or R4 composed of at least two rings, each formed of 5 to 6 atoms, at most one of which is optionally a heteroatom, such as nitrogen or oxygen, and the others are carbon atoms, these two rings additionally having two carbon atoms in common, preferably vicinal these said rings being saturated or unsaturated. 4. Fuel composition as claimed in claim 3, wherein the glycerol monoesters and diesters of formulae (I) and (III) are obtained from natural resin acids contained in the residues from the distillation of natural oils extracted from resinous trees, in particular from resinous conifers. 5. Fuel composition as claimed in claim 4, wherein the esters of resin acids are chosen from the group composed of esters of abietic acid, of dihydroabietic acid, of tetrahydroabietic acid, of dehydroabietic acid, of neoabietic acid, of pimaric acid, of laevopimaric acid and of parastrinic acid. 6. Fuel composition as claimed in one of claims 1 to 5, wherein the esters and the amides of formula (II) are obtained by reaction of an alcohol, amine and/or alkanolamine compound with a carboxylic acid, such as oleic acid, or alternatively methyl oleate. 7. Fuel composition as claimed in claim 6, wherein the alcohols are chosen from alkanols of the group composed of methanol, ethanol, propanol, isopropanol, butanol, isobutanol, pentanol or 2-ethylhexanol and/or oxyalkylated alcohols of formula R(0-CH2-CHR')n-OH, in which R is an alkyl group containing 1 to 6 carbon atoms, R' is hydrogen or an alkyl group containing 1 to 4 carbon atoms and n an integer varying from 1 to 5, such as methyl cellosolve, butyl cello solve, butyl digol and I- butoxypropanol. 8. Fuel composition as claimed in claim 6, wherein the amines are primary and secondary amines chosen from the group composed of methylamine, ethylamine, propylamine, butylamine, isobutylamine, 2-ethylhexylamine, decylamine, dodecylamine, stearylamine and oleylamine, N,N- diethylamine, N,N-dipropylamine, N,N-dibutylamine, N,N-di(2- ethylhexyl)amine, N-methyldecylamine, N-methyldodecylamine or N- methyloleylamine. 9. Fuel composition as claimed in claim 6, wherein the alkanolamines are chosen from amines comprising from 1 to 18 carbons atoms substituted by at least one hydroxylated, hydroxymethylated, hydroxyethylated or hydroxypropylated group, such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, N-methylethanolamine, tris (hydroxymethyl)aminomethane, (N-hydroxyethyl )methylimidazoline or (N -hydroxyethyljheptadecenylimidazo line. 10. Fuel composition for ground vehicle engines as claimed in any one of claims 1 to 9, wherein the fuel composition comprises 25 to 2500 ppm and preferably from 100 to 1000 ppm by weight of at least one of said additive, the said additive being introduced into a diesel fuel. A fuel composition with a sulphur content of less than or equal to 500 ppm, and comprising at least one additive, characterized in that the additive is composed of: from 5 to 25% by weight of at least one glycerol monoester of formulae (IA) and/or (IB) below: with R1 chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms, • from 35 to 75% by weight of at least one compound of formula (II) below: in which R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is chosen from (i) the groups ORo, Ro being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, • from 0.1 to 20% by weight of at least one glycerol diester of formula (IIIA) and/or (IIIB): in which R3 and R4 are identical or different and are chosen from saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms. |
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in-pct-1999-22-kol-abstract.pdf
in-pct-1999-22-kol-correspondence 1.1.pdf
in-pct-1999-22-kol-correspondence.pdf
in-pct-1999-22-kol-description (complete).pdf
in-pct-1999-22-kol-examination report 1.1.pdf
in-pct-1999-22-kol-examination report.pdf
in-pct-1999-22-kol-form 13.1.pdf
in-pct-1999-22-kol-form 13.pdf
in-pct-1999-22-kol-form 18.1.pdf
in-pct-1999-22-kol-form 18.pdf
in-pct-1999-22-kol-form 2.1.pdf
in-pct-1999-22-kol-form 3.1.pdf
in-pct-1999-22-kol-form 5.1.pdf
in-pct-1999-22-kol-granted-abstract 1.1.pdf
in-pct-1999-22-kol-granted-claims 1.1.pdf
in-pct-1999-22-kol-granted-description (complete) 1.1.pdf
in-pct-1999-22-kol-granted-form 1.1.pdf
in-pct-1999-22-kol-granted-form 2.1.pdf
in-pct-1999-22-kol-granted-specification 1.1.pdf
in-pct-1999-22-kol-priority document.pdf
in-pct-1999-22-kol-reply to examination report 1.1.pdf
in-pct-1999-22-kol-reply to examination report.pdf
in-pct-1999-22-kol-specification.pdf
in-pct-1999-22-kol-specification1.1.pdf
in-pct-1999-22-kol-translated copy of priority document 1.1.pdf
in-pct-1999-22-kol-translated copy of priority document.pdf
Patent Number | 244070 | ||||||||||||
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Indian Patent Application Number | IN/PCT/1999/22/KOL | ||||||||||||
PG Journal Number | 47/2010 | ||||||||||||
Publication Date | 19-Nov-2010 | ||||||||||||
Grant Date | 16-Nov-2010 | ||||||||||||
Date of Filing | 30-Aug-1999 | ||||||||||||
Name of Patentee | ELF ANTAR FRANCE | ||||||||||||
Applicant Address | TOUR ELF-2 PLACE DE KA COUPOLE, LA DEFENSE 6, F-92400 COURBEVOIE | ||||||||||||
Inventors:
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PCT International Classification Number | C10L 1/18 | ||||||||||||
PCT International Application Number | PCT/FR1998/02823 | ||||||||||||
PCT International Filing date | 1998-12-22 | ||||||||||||
PCT Conventions:
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