Title of Invention	HOT-ROLLED STEEL STRIP INTENDED FOR THE PRODUCTION OF NON-GRAIN ORIENTED ELECTRICAL SHEET AND A METHOD FOR THE PRODUCTION THEREOF
Abstract	The present invention relates to a hot-rolled steel strip for further processing to form non-grain oriented electrical sheet with the following composition (in % by weight) C: < 0.02%, Mn: ≤ 1.2%, Si: 0.1 - 4.4%, Al 0.1 - 4.4%, wherein the sum formed from the Si content and twice the Al content is < 5%, P: < 0.15%, Sn: ≤ 0.20%, Sb: ≤ 0.20%, the remainder iron and unavoidable impurities, with a strip thickness which is at most 1.8 mm, and with a partially softened structure which is characterised by a high intensity for the α fibre (fibre representation of orientation distribution functions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from the intensity I112 of the position (112) <110> to the intensity I001 of the position (001) <110> is > 0.4 and the ratio I111/I001 formed from the intensity I111 of the position (111) <110> to the intensity I001 of the position (001) <110> is > 0.2.

Title of Invention

HOT-ROLLED STEEL STRIP INTENDED FOR THE PRODUCTION OF NON-GRAIN ORIENTED ELECTRICAL SHEET AND A METHOD FOR THE PRODUCTION THEREOF

Abstract

The present invention relates to a hot-rolled steel strip for further processing to form non-grain oriented electrical sheet with the following composition (in % by weight) C: < 0.02%, Mn: ≤ 1.2%, Si: 0.1 - 4.4%, Al 0.1 - 4.4%, wherein the sum formed from the Si content and twice the Al content is < 5%, P: < 0.15%, Sn: ≤ 0.20%, Sb: ≤ 0.20%, the remainder iron and unavoidable impurities, with a strip thickness which is at most 1.8 mm, and with a partially softened structure which is characterised by a high intensity for the α fibre (fibre representation of orientation distribution functions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from the intensity I112 of the position (112) <110> to the intensity I001 of the position (001) <110> is > 0.4 and the ratio I111/I001 formed from the intensity I111 of the position (111) <110> to the intensity I001 of the position (001) <110> is > 0.2.

Full Text	HOT-ROLLED STEEL STRIP INTENDED FOR THE PRODUCTION OF NON- GRAIN ORIENTED ELECTRICAL SHEET AND A METHOD FOR THE PRODUCTION THEREOF The invention relates to a hot-rolled steel strip intended for the production of electrical sheet and a method for the production thereof. In this context, the term "non-grain oriented electrical sheet" is taken to mean a steel sheet or a steel strip which regardless of its texture comes under the sheets mentioned in DIN 46 400 Part 1 or 4 and the loss anisotropy of which does not exceed the maximum values established in DIN 46 400 Part 1. The terms "sheet" and "strip" are used synonymously here. The production of non-grain oriented electrical sheet (NO electrical sheet) conventionally comprises the steps: melting the steel, casting the steel to form slabs, if necessary, reheating the slabs, using the slabs in a hot-rolling line, pre-rolling the slabs, finishing hot-rolling of the slabs to form a hot strip, of which the end thickness is between 1.8 mm and 5 mm, typically between 2 mm and 3 mm, annealing and pickling of the hot strip wherein these hot strip treatments can be carried out as combined annealing pickling, cold-rolling to an end thickness in the region of 0.75 mm to 0.35 mm or smaller or, if necessary, cold- rolling of the hot strip to end thickness taking place in multi-stages with interposed annealing, and final annealing of cold strips of this type in end thickness, which have been cold-rolled with a degree of total deformation of at least 65%, or annealing and subsequent rerolling with a degree of total deformation of at most 20%. Not until the cold-rolling process is softening of the structure achieved by a recrystallisation, degrees of total deformation of > 65% being required to achieve the conventional end thicknesses of the end product "cold- rolled NO electrical strip" (starting point hot strip > 1.8 mm, end thickness 0.35 to 0.75 mm). Characteristic of a softened structure is an intensity distribution of the a fibre texture such that an increased intensity of the component {112} occurs and the cold-rolling component {001} is largely removed. Therefore the cold-rolling with these high degrees of total deformation creates the prerequisite for the possibility of using a final annealing, which is conventional nowadays, in the form of a "short-time annealing" (through-type furnace - short times of high temperatures for the strip) with the aim of achieving a softened structure and an optimum grain size in the finished product "cold-rolled NO electrical strip". The large number of working steps to be carried out in a conventional procedure of this type leads to high expenditure in terms of apparatus and costs. Therefore recently increased efforts have been made to design the casting of the steel and subsequent rolling processes in the hot strip production such that a hot strip with a thickness of aim is a continuous sequence of the casting and rolling process dispensing with the reheating and the pre-rolling. For this purpose, so-called "casting/rolling plants" have been developed and set up. In these devices also known as "CSP plants", the steel is cast to form a continuously drawn billet (thin slab) which is then hot-rolled "in-line" to form hot strip. The experiences obtained in operating casting/rolling plants and the advantages of the casting/rolling carried out "in-line" have been documented, for example in W. Bald et al. "Innovative Technologie zur Banderzeugung", Stahl und Eisen 119 (1999) No. 3, pages 77 to 85, or C. Hendricks et al. "Inbetriebnahme und erste Ergebnisse der Gie?walzanlage der Thyssen Krupp Stahl AG", Stahl und Eisen 120 (2000) No. 2, pages 61 to 68. However, even in the framework of conventional plant engineering for hot-rolling, including the pre- and intermediate rolling, an attempt is made in the use of conventional slabs to achieve hot strip thicknesses of 1.5 mm, see for example JP 2001 123225 A2. The invention was based on the object of realising an economically producible hot strip with a partially softened structure with a thickness of at most 1.8 mm which, owing to these properties, is especially suitable for producing high-grade electrical sneets. This object is achieved starting from the above-described prior art by a hot-rolled steel strip, which has the following composition (in ÷ by weight): C: Mn: ? 1.2 % Si: 0.1-4.4% Al 0.1-4.4%, wherein the sum formed from the Si content and twice the Al content ([% Si] + 2 x [% Al]) is P: Sn: ? 0.20% Sb: ? 0.20%, the remainder iron and unavoidable impurities, the strip thickness of which steel strip is at most 1.8 mm, and which has a partially softened structure, which is characterised by a high intensity of the a fibre (fibre representation of orientation distribution functions) in the range to 60°. The invention proceeds from the recognition that with a choice of a suitable method of production, a hot strip can be provided which already in the hot-rolled state has a structure which can be produced only by cold-rolling with high degrees of deformation in a conventional manner of production. Thus, a hot strip composed and made up according to the invention with a strip thickness of at most 1.8 mm has a partially softened structure. This structure is distinguished by high intensities of the a fibre in the range of angles up to 60° for specific positions, in other words in an angle range in which, in the case of conventional hot strips of comparable composition, no noteworthy intensities would be generally able to be established for these positions. The high intensities of the specific positions (112) and (111) are characteristic, wherein for the ratios of the intensities I112 of the position (112) to the intensity I001 of the position (001) a value > 0.4 is produced and for the ratios of the intensity I111 of the position (111) to the intensity I001 of the position (001) a value > 0.2 is produced. Owing to this composition, hot strip according to the invention can be processed in an excellent manner to form cold-rolled NO electrical sheet, the end thickness of which is typically 0.35 mm to 0.75 mm, in particular 0.2 mm, 0.35 mm, 0.50 mm or 0.65 mm. Conventional hot strips differ from those according to the invention in that in the case of these noteworthy intensities only occur in the range of up to 25° (-30°), while for the components (112) and (111) no further higher intensities can be established. In the conventional hot strips, an intensity maximum of the a fibre structure is typically present at 0°, from which the intensity decreases with an increasing angle. This intensity distribution of the a fibre corresponds to a hardened structure. Only owing to the cold-rolling process is a softening of the structure achieved in the case of such steel strips by a recrystallisation in the subsequent annealing. For this purpose, degrees of total deformation of more than 65% are required which, on the one hand, assume a specific minimum thickness of the hot strip to be cold-rolled and, on the other hand, a considerable rolling power in the cold-deformation of the strip. Hot strip according to the invention is composed in comparison such that the intensities of the component (112) and the intensities of the position (111) are high. At the same time, hot strip according to the invention has a particularly small end thickness. The hot strip according to the invention thus creates far more favourable conditions for the subsequent processing than the conventional hot strips can achieve. Thus, hot strip according to the invention starting from its small thickness of at most 1.8 mm with a minimised total deformation can be cold-formed into a non-grain oriented electrical sheet, the properties of which are at least equal to the properties of conventionally produced NO electrical sheets. In relation to the terms used a fibre, intensity and position, it should be remembered that the texture of a crystalline phase is described quantitatively by means of the orientation distribution function. The orientation distribution function describes the relative position of the crystal coordinate system and sample coordinate system. The orientation distribution function allocates each point in the space an orientation density or intensity. As representation of the orientation distribution function is very complicated and not very graphic, a simplified description is selected with the aid of fibres. The fibres relevant for steels are: a fibre, y fibre, ? fibre, ?, fibre, 5 fibre. In the a fibre observed here, the direction is parallel to the rolling direction; it extends between the positions (001) and (110) . Hot strip according to the invention has a particular favourable softening state for further processing when its strip thickness is at most 1.2 mm. With hot strip according to the invention which is as thin as this, the ratio I112/I001 formed from the intensity I112 of the position (112) to the intensity I001 of the position (001) of the a fibre is > 0.75 and the ratio I111/I001 formed from the intensity Iin of the position (111) to the intensity I001 of the position (001) of the a fibre is > 0.4. Hot strip softened in this way can be processed with particularly small degrees of deformation into NO electrical sheet. Hot strips according to the invention with hot strip thicknesses of ways; conventional hot strip lines with possibilities for producing the above thicknesses, continuous casting and rolling plants (casting of thin slabs with subsequent in- line hot-rolling), thin strip casting plants with subsequent single or multi-stage hot-rolling of the thin strip. According to an advantageous configuration of the method according to the invention, at least one pass of the hot- rolling is carried out at temperature, at which the hot strip has an austenitic structure, and a plurality of subsequent passes of the hot-rolling are carried out at temperatures in which the hot strip has a ferritic structure. Owing to rolling deliberately carried out in this way in the individual phase state regions, in particular in the case of converting alloys, hot strips can be produced which have optimised properties with respect to the demands placed on NO electrical sheets. It has been shown, for example, that owing to a suitable combination of the phase sequence in hot-rolling in conjunction with specific end rolling and coiler temperatures, a decisive raising of the magnetic polarisation can be achieved. To ensure that at least the last pass of the hot-rolling is carried out with a ferritic structure in the hot strip, the end rolling temperature during hot-rolling should be less than 850°C. During the hot-rolling, at least during one of the last deformation passes, rolling is carried out with lubrication. Owing to the hot-rolling with lubrication, on the one hand, smaller shear deformations occur, so that the rolled strip receives a more homogeneous structure over the cross-section as a result. On the other hand, owing to the lubrication, the rolling forces are reduced, so that a greater reduction in thickness is possible over the respective rolling pass. Therefore, according to the desired properties of the electrical sheet to be produced, it may be advantageous if all the forming passes taking place in the ferrite region are carried out with a rolling lubrication. Hot strips according to the invention, can be produced in particular with reliably reproducible working results in that initially a steel composed according to the invention is melted and then the steel is cast into thin slabs which are then continuously ("in-line") hot-rolled to form hot strip. The extent of total deformation achieved during the hot-rolling is preferably at least 90%, the hot-rolling generally being carried out in a plurality of passes. The continuous sequence particular to known continuous casting and rolling, of casting the steel to form thin slabs and hot-rolling the thin slabs to form a hot strip, also allows working steps to be dispensed with in the production of hot strips according to the invention, as for example the reheating of the slabs and pre-rolling. Moreover, it has been shown that dispensing with the according working steps influences the material state in the various production phases. This sometimes differs considerably from that achieved in the conventional production of hot strip in which at the beginning the cooled slab is reheated. In particular it is the macroliquations and the solution and precipitation state which differentiates hot strips produced according to the invention from those produced conventionally. In addition, the forming process during the hot-rolling takes place during continuous in-line casting and rolling in favourable thermal conditions. Thus, the rolling passes can. be applied with higher degrees of deformation and the deformation conditions can be used in a targeted manner to control the structure development. In the use of continuous casting and rolling in the hot strip according to the invention, the phosphorous content is preferably limited to less than 0.08 % by weight in order to achieve adequate casting properties. The invention will be described hereinafter with the aid of embodiments. In the graph, the curve of the orientation distribution function (orientation density) is plotted for three examples over the angle ?. "?" is one of the eulerian angles which describe the relative position of the crystal coordination and sample coordination system. Special positions are simultaneously plotted: (001) , (112) , (111) and others. To determine the properties of an example for a hot strip WbF, according to the invention and two comparison examples for hot strips Wbv1 and WbV2 not according to the invention, a steel with (in % by weight or ppm by weight) 0.050% P, 1.3% Si, 0.12% A1, 0.01% Si and as the remainder Fe and impurities was melted. In the case of the hot strip Wbv1 manufactured for comparison, the melted steel is cast to form a slab, which is then cooled in a conventional manner, reheated, pre- rolled and hot-rolled to an end thickness of 2.5 mm. The hot strip Wbv1 thus obtained, for an orientation angle ? of 0° to 20°, had an orientation thickness of the a fibre determined in the strip centre, of at least 4, while the orientation thickness for angles O of more than 20° was regularly less than 3. The value of the ratio I112/I001 of the intensity I112 of the position (112) to the intensity I110 of the position (001) of the a fibre was accordingly likewise below 0.1 like the value of the ratio I111/I001 of the intensity I111 of the component (111) to the intensity I110 of the component (001) . The curve of the orientation density over the angle ? is shown in the graph for the hot strip Wbv1 serving for comparison as a dotted line. The high density in the region of small angles and the low density in the region of large angles prove that the hot strip WbV1 was in a hardened state in which it firstly has to be subjected to an expensive cold-rolling and after- treatment in order to be able to be used as a NO electrical sheet. In order to produce the hot strip WbV2 also manufactured for comparison, the same steel is firstly cast in a continuous casting and rolling plant to form a thin slab which was then hot-rolled also "in-line" in a plurality of passes to a hot strip end thickness of 3 mm. The hot strip WbV2 thus obtained, for an orientation angle ? of 0° to 20°, like the hot strip WbV1, had an orientation density of the a fibre determined in the strip centre of at least 4, while the orientation density for angles ? of more than 20° was regularly significantly less than 3. The value of the ratio I112/I001 of the intensity I112 oE the position (112) to the intensity I110 of the position (001) of the a fibre was 0.2, while the value of the ratio I111/I001 of the intensity I111 of the position (111) to the intensity I110 of the position (001) only reached 0.06. The curve of the orientation density over the angle ? is shown in the graph as a dash-dot line for the hot strip WbV2 serving as a comparison. In the case of the hot strip WbV2 the high density in the region of smaller angles, and the low density in the region of large angles, also proves that the hot strip WbV2 was in a hardened state in which it firstly had to be subjected to an extensive cold-rollinc and after-treatment in order to be able to be used as NO electrical sheet. The hot strip WbE according to the invention is also produced from the same steel as the hot strip Wbyl manufactured for comparison. For this purpose, the relevant steel is also cast in a continuous casting and rolling plant to form a thin slab which is then also hot-rolled "in-line" in a plurality of passes. In contrast to the hot strip Wbv2, the end thickness of the hot strip was only 1.04 mm, however. The hot strip WbE thus obtained for all orientation angles ? in the range of 0° to 60°, had an orientation density of the a fibre determined in the strip centre of at least 4. The orientation density only dropped to below 3 in the angle range of more than 60°. The value of the ratio I112/I001 of the intensity I112 of the position (112) to the intensity I110 of the component (001) of the a fibre was at a high level, namely 0.81. In the same way, the value of the ratio T111/I001 of the intensity I111 of the position (111) to the intensity I110 of the position (001) reached a high level, namely 0.54. The curve of the orientation density over the angle ? is shown as a solid line in the graph for the hot strip WbE according to the invention. The high orientation densities up to an angle of 60° and the high intensities of the component (112) and (111) proves that the hot strip according to the invention is in a substantially partially softened state. WE CLAIM 1. Hot-rolled steel strip for further processing to form non-grain oriented electrical sheet - with the following composition (in % by weight) C: Mn: ? 1.2% Si: 0.1 - 4.4% Al: 0.1 - 4.4% Wherein the sum formed from the Si content and twice the Al content is P: Sn: ? 0.20% Sb: ? 0.20% the remainder iron and unavoidable impurities, - with a strip thickness which is at most 1.8 mm, and - with a partially softened structure which is characterized by a high intensity of the a fibre (fibre representation of orientation distribution fuctions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from the intensity I112 of the position (112) to the intensity I001 of the position (001) is > 0.4 and the ratio I111/I001 formed from the - intensity I111 of the position (111) to the intensity I001 of the position (001) is > 0.2. 2. Hot strip as claimed in claim in 1, wherein the strip thickness is at most 1.2 mm and the ratio I112/I001 formed from the intensity I112 of the position (112) of the intensity I110 of the position (001) of the a fibre is > 0.75 and the ratio I111/I001 formed from the intensity I111 of the position (111) to the intensity I001 of the a fibre is 0.4. 3. Hot strip as claimed in any one of the preceding claims, wherein at a first high temperature, it has a ferritic structure, at a second temperature lying below the first temperature, it has a ferritic/austenitic structure, at a third temperature lying below the second temperature, it has an austenitic structure, at a fourth temperature lying below the third temperature it has an austenitic/ferritic structure and at a fifth temperature lying below the fourth temperature it again has a ferritic structure. 4. Method for producing hot strip composed as claimed in any one of claims 1 to 3, comprising the following working steps: - melting the steel, - casting the steel to form thin slabs, - continuous fin-line") hot-rolling of the thin slabs following the thin slabs following the casting of the steel - 5. Method as claimed in claim 4, wherein the phosphorous content in the hot strip is 6. Method as claimed in claim 4 or 5, wherein the degree of total deformation achieved during the hot rolling is at least 90%. 7. Method for producing hot strip as claimed in claims 1 to 3, comprising the following working steps: - melting the steel, - casting the steel to form a thin strip, - continuous ("in-line") hot-rolling following the casting of the steel in one or more passes 8. Hot strip as claimed in claim 7, wherein its P content is weight. 9. Method as claimed in any one of claims 4 to 8, wherein the hot-rolling is carried out in a plurality of passed. 10. Method as claimed in claim 9 wherein at least one pass of the hot-rolling is carried out at temperatures at which the hot strip has as austenitic structure,and a plurality of subsequent passed of the hot -rolling are carried out at temperatures in which the hot strip has a ferritic structure. 8. 11. Method as claimed in any one of claims 4 to 10 wherein the end rolling temperature during hot-rolling is less than 850°. 12. Method as claimed in any one of the preceding claims wherein during the rolling in the ferrite area at least rolling pass is carried out with lubrication. 13.Method for producing non-grain oriented electrical sheet from a hot strip composed according to any one of claims 1 to 3 and produced according to any one of claims 4 to 10, comprising the following working steps: - picking or annealing and pickling of the hot strip, - cold rolling of the hot strip, - intermediate annealing of the cold strip, - final annealing or - annealing with subsequent deformation with a total degree of deformation of less than 20%. 14.Method according to claim 11, characterized in that the cold-rolling is carried out in at least two stages with an intermediate annealing. The present invention relates to a hot-rolled steel strip for further processing to form non-grain oriented electrical sheet with the following composition (in % by weight) C: 4.4%, wherein the sum formed from the Si content and twice the Al content is 0.20%, the remainder iron and unavoidable impurities, with a strip thickness which is at most 1.8 mm, and with a partially softened structure which is characterised by a high intensity for the α fibre (fibre representation of orientation distribution functions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from the intensity I112 of the position (112) to the intensity I001 of the position (001) is > 0.4 and the ratio I111/I001 formed from the intensity I111 of the position (111) to the intensity I001 of the position (001) is > 0.2.

Full Text

HOT-ROLLED STEEL STRIP INTENDED FOR THE PRODUCTION OF NON-
GRAIN ORIENTED ELECTRICAL SHEET AND A METHOD FOR THE
PRODUCTION THEREOF
The invention relates to a hot-rolled steel strip intended
for the production of electrical sheet and a method for the
production thereof.
In this context, the term "non-grain oriented electrical
sheet" is taken to mean a steel sheet or a steel strip
which regardless of its texture comes under the sheets
mentioned in DIN 46 400 Part 1 or 4 and the loss anisotropy
of which does not exceed the maximum values established in
DIN 46 400 Part 1. The terms "sheet" and "strip" are used
synonymously here.
The production of non-grain oriented electrical sheet (NO
electrical sheet) conventionally comprises the steps:
melting the steel,
casting the steel to form slabs,
if necessary, reheating the slabs,
using the slabs in a hot-rolling line,
pre-rolling the slabs,
finishing hot-rolling of the slabs to form a hot
strip, of which the end thickness is between 1.8 mm
and 5 mm, typically between 2 mm and 3 mm,
annealing and pickling of the hot strip wherein these
hot strip treatments can be carried out as combined
annealing pickling,
cold-rolling to an end thickness in the region of 0.75
mm to 0.35 mm or smaller or, if necessary, cold-
rolling of the hot strip to end thickness taking place
in multi-stages with interposed annealing, and

final annealing of cold strips of this type in end
thickness, which have been cold-rolled with a degree
of total deformation of at least 65%, or
annealing and subsequent rerolling with a degree of
total deformation of at most 20%.
Not until the cold-rolling process is softening of the
structure achieved by a recrystallisation, degrees of total
deformation of > 65% being required to achieve the
conventional end thicknesses of the end product "cold-
rolled NO electrical strip" (starting point hot strip > 1.8
mm, end thickness 0.35 to 0.75 mm). Characteristic of a
softened structure is an intensity distribution of the a
fibre texture such that an increased intensity of the
component {112} occurs and the cold-rolling component
{001} is largely removed.
Therefore the cold-rolling with these high degrees of total
deformation creates the prerequisite for the possibility of
using a final annealing, which is conventional nowadays, in
the form of a "short-time annealing" (through-type furnace
- short times of high temperatures for the strip) with the
aim of achieving a softened structure and an optimum grain
size in the finished product "cold-rolled NO electrical
strip".
The large number of working steps to be carried out in a
conventional procedure of this type leads to high
expenditure in terms of apparatus and costs. Therefore
recently increased efforts have been made to design the
casting of the steel and subsequent rolling processes in
the hot strip production such that a hot strip with a
thickness of
aim is a continuous sequence of the casting and rolling
process dispensing with the reheating and the pre-rolling.
For this purpose, so-called "casting/rolling plants" have
been developed and set up. In these devices also known as
"CSP plants", the steel is cast to form a continuously
drawn billet (thin slab) which is then hot-rolled "in-line"
to form hot strip. The experiences obtained in operating
casting/rolling plants and the advantages of the
casting/rolling carried out "in-line" have been documented,
for example in W. Bald et al. "Innovative Technologie zur
Banderzeugung", Stahl und Eisen 119 (1999) No. 3, pages 77
to 85, or C. Hendricks et al. "Inbetriebnahme und erste
Ergebnisse der Gie?walzanlage der Thyssen Krupp Stahl AG",
Stahl und Eisen 120 (2000) No. 2, pages 61 to 68.
However, even in the framework of conventional plant
engineering for hot-rolling, including the pre- and
intermediate rolling, an attempt is made in the use of
conventional slabs to achieve hot strip thicknesses of 1.5 mm, see for example JP 2001 123225 A2.
The invention was based on the object of realising an
economically producible hot strip with a partially softened
structure with a thickness of at most 1.8 mm which, owing
to these properties, is especially suitable for producing
high-grade electrical sneets.
This object is achieved starting from the above-described
prior art by a hot-rolled steel strip, which has the
following composition (in ÷ by weight):
C: Mn: ? 1.2 %

Si: 0.1-4.4%
Al 0.1-4.4%,
wherein the sum formed from the Si content and twice the Al
content ([% Si] + 2 x [% Al]) is P: Sn: ? 0.20%
Sb: ? 0.20%,
the remainder iron and unavoidable impurities,
the strip thickness of which steel strip is at most
1.8 mm, and
which has a partially softened structure, which is
characterised by a high intensity of the a fibre
(fibre representation of orientation distribution
functions) in the range to 60°.
The invention proceeds from the recognition that with a
choice of a suitable method of production, a hot strip can
be provided which already in the hot-rolled state has a
structure which can be produced only by cold-rolling with
high degrees of deformation in a conventional manner of
production. Thus, a hot strip composed and made up
according to the invention with a strip thickness of at
most 1.8 mm has a partially softened structure. This
structure is distinguished by high intensities of the a
fibre in the range of angles up to 60° for specific
positions, in other words in an angle range in which, in
the case of conventional hot strips of comparable
composition, no noteworthy intensities would be generally

able to be established for these positions. The high
intensities of the specific positions (112) and (111)
are characteristic, wherein for the ratios of the
intensities I112 of the position (112) to the
intensity I001 of the position (001) a value > 0.4 is
produced and for the ratios of the intensity I111 of the
position (111) to the intensity I001 of the position
(001) a value > 0.2 is produced. Owing to this
composition, hot strip according to the invention can be
processed in an excellent manner to form cold-rolled NO
electrical sheet, the end thickness of which is typically
0.35 mm to 0.75 mm, in particular 0.2 mm, 0.35 mm, 0.50 mm
or 0.65 mm.
Conventional hot strips differ from those according to the
invention in that in the case of these noteworthy
intensities only occur in the range of up to 25° (-30°),
while for the components (112) and (111) no
further higher intensities can be established. In the
conventional hot strips, an intensity maximum of the a
fibre structure is typically present at 0°, from which the
intensity decreases with an increasing angle. This
intensity distribution of the a fibre corresponds to a
hardened structure. Only owing to the cold-rolling process
is a softening of the structure achieved in the case of
such steel strips by a recrystallisation in the subsequent
annealing. For this purpose, degrees of total deformation
of more than 65% are required which, on the one hand,
assume a specific minimum thickness of the hot strip to be
cold-rolled and, on the other hand, a considerable rolling
power in the cold-deformation of the strip.
Hot strip according to the invention is composed in
comparison such that the intensities of the component (112)

and the intensities of the position (111) are
high. At the same time, hot strip according to the
invention has a particularly small end thickness. The hot
strip according to the invention thus creates far more
favourable conditions for the subsequent processing than
the conventional hot strips can achieve. Thus, hot strip
according to the invention starting from its small
thickness of at most 1.8 mm with a minimised total
deformation can be cold-formed into a non-grain oriented
electrical sheet, the properties of which are at least
equal to the properties of conventionally produced NO
electrical sheets.
In relation to the terms used a fibre, intensity and
position, it should be remembered that the texture of a
crystalline phase is described quantitatively by means of
the orientation distribution function.
The orientation distribution function describes the
relative position of the crystal coordinate system and
sample coordinate system. The orientation distribution
function allocates each point in the space an orientation
density or intensity. As representation of the orientation
distribution function is very complicated and not very
graphic, a simplified description is selected with the aid
of fibres. The fibres relevant for steels are:
a fibre, y fibre, ? fibre, ?, fibre, 5 fibre.
In the a fibre observed here, the direction is
parallel to the rolling direction; it extends between the
positions (001) and (110) .

Hot strip according to the invention has a particular
favourable softening state for further processing when its
strip thickness is at most 1.2 mm. With hot strip according
to the invention which is as thin as this, the ratio
I112/I001 formed from the intensity I112 of the position (112)
to the intensity I001 of the position (001) of
the a fibre is > 0.75 and the ratio I111/I001 formed from the
intensity Iin of the position (111) to the intensity
I001 of the position (001) of the a fibre is > 0.4.
Hot strip softened in this way can be processed with
particularly small degrees of deformation into NO
electrical sheet.
Hot strips according to the invention with hot strip
thicknesses of ways; conventional hot strip lines with possibilities for
producing the above thicknesses, continuous casting and
rolling plants (casting of thin slabs with subsequent in-
line hot-rolling), thin strip casting plants with
subsequent single or multi-stage hot-rolling of the thin
strip.
According to an advantageous configuration of the method
according to the invention, at least one pass of the hot-
rolling is carried out at temperature, at which the hot
strip has an austenitic structure, and a plurality of
subsequent passes of the hot-rolling are carried out at
temperatures in which the hot strip has a ferritic
structure. Owing to rolling deliberately carried out in
this way in the individual phase state regions, in
particular in the case of converting alloys, hot strips can
be produced which have optimised properties with respect to
the demands placed on NO electrical sheets. It has been

shown, for example, that owing to a suitable combination of
the phase sequence in hot-rolling in conjunction with
specific end rolling and coiler temperatures, a decisive
raising of the magnetic polarisation can be achieved. To
ensure that at least the last pass of the hot-rolling is
carried out with a ferritic structure in the hot strip, the
end rolling temperature during hot-rolling should be less
than 850°C.
During the hot-rolling, at least during one of the last
deformation passes, rolling is carried out with
lubrication. Owing to the hot-rolling with lubrication, on
the one hand, smaller shear deformations occur, so that the
rolled strip receives a more homogeneous structure over the
cross-section as a result. On the other hand, owing to the
lubrication, the rolling forces are reduced, so that a
greater reduction in thickness is possible over the
respective rolling pass. Therefore, according to the
desired properties of the electrical sheet to be produced,
it may be advantageous if all the forming passes taking
place in the ferrite region are carried out with a rolling
lubrication.
Hot strips according to the invention, can be produced in
particular with reliably reproducible working results in
that initially a steel composed according to the invention
is melted and then the steel is cast into thin slabs which
are then continuously ("in-line") hot-rolled to form hot
strip. The extent of total deformation achieved during the
hot-rolling is preferably at least 90%, the hot-rolling
generally being carried out in a plurality of passes.
The continuous sequence particular to known continuous
casting and rolling, of casting the steel to form thin

slabs and hot-rolling the thin slabs to form a hot strip,
also allows working steps to be dispensed with in the
production of hot strips according to the invention, as for
example the reheating of the slabs and pre-rolling.
Moreover, it has been shown that dispensing with the
according working steps influences the material state in
the various production phases. This sometimes differs
considerably from that achieved in the conventional
production of hot strip in which at the beginning the
cooled slab is reheated. In particular it is the
macroliquations and the solution and precipitation state
which differentiates hot strips produced according to the
invention from those produced conventionally. In addition,
the forming process during the hot-rolling takes place
during continuous in-line casting and rolling in favourable
thermal conditions. Thus, the rolling passes can. be applied
with higher degrees of deformation and the deformation
conditions can be used in a targeted manner to control the
structure development.
In the use of continuous casting and rolling in the hot
strip according to the invention, the phosphorous content
is preferably limited to less than 0.08 % by weight in
order to achieve adequate casting properties.
The invention will be described hereinafter with the aid of
embodiments. In the graph, the curve of the orientation
distribution function (orientation density) is plotted for
three examples over the angle ?. "?" is one of the
eulerian angles which describe the relative position of
the crystal coordination and sample coordination system.
Special positions are simultaneously plotted: (001) ,
(112) , (111) and others. To determine the
properties of an example for a hot strip WbF, according to

the invention and two comparison examples for hot strips
Wbv1 and WbV2 not according to the invention, a steel with
(in % by weight or ppm by weight) 0.050% P, 1.3% Si, 0.12% A1, 0.01% Si and as the remainder
Fe and impurities was melted.
In the case of the hot strip Wbv1 manufactured for
comparison, the melted steel is cast to form a slab, which
is then cooled in a conventional manner, reheated, pre-
rolled and hot-rolled to an end thickness of 2.5 mm. The
hot strip Wbv1 thus obtained, for an orientation angle ? of
0° to 20°, had an orientation thickness of the a fibre
determined in the strip centre, of at least 4, while the
orientation thickness for angles O of more than 20° was
regularly less than 3. The value of the ratio I112/I001 of
the intensity I112 of the position (112) to the
intensity I110 of the position (001) of the a fibre
was accordingly likewise below 0.1 like the value of the
ratio I111/I001 of the intensity I111 of the component (111)
to the intensity I110 of the component (001) .
The curve of the orientation density over the angle ? is
shown in the graph for the hot strip Wbv1 serving for
comparison as a dotted line.
The high density in the region of small angles and the low
density in the region of large angles prove that the hot
strip WbV1 was in a hardened state in which it firstly has
to be subjected to an expensive cold-rolling and after-
treatment in order to be able to be used as a NO electrical
sheet.

In order to produce the hot strip WbV2 also manufactured
for comparison, the same steel is firstly cast in a
continuous casting and rolling plant to form a thin slab
which was then hot-rolled also "in-line" in a plurality of
passes to a hot strip end thickness of 3 mm.
The hot strip WbV2 thus obtained, for an orientation angle
? of 0° to 20°, like the hot strip WbV1, had an orientation
density of the a fibre determined in the strip centre of at
least 4, while the orientation density for angles ? of
more than 20° was regularly significantly less than 3. The
value of the ratio I112/I001 of the intensity I112 oE the
position (112) to the intensity I110 of the position
(001) of the a fibre was 0.2, while the value of the
ratio I111/I001 of the intensity I111 of the position (111)
to the intensity I110 of the position (001) only
reached 0.06.
The curve of the orientation density over the angle ? is
shown in the graph as a dash-dot line for the hot strip
WbV2 serving as a comparison.
In the case of the hot strip WbV2 the high density in the
region of smaller angles, and the low density in the region
of large angles, also proves that the hot strip WbV2 was in
a hardened state in which it firstly had to be subjected to
an extensive cold-rollinc and after-treatment in order to
be able to be used as NO electrical sheet.
The hot strip WbE according to the invention is also
produced from the same steel as the hot strip Wbyl
manufactured for comparison. For this purpose, the relevant
steel is also cast in a continuous casting and rolling

plant to form a thin slab which is then also hot-rolled
"in-line" in a plurality of passes. In contrast to the hot
strip Wbv2, the end thickness of the hot strip was only
1.04 mm, however.
The hot strip WbE thus obtained for all orientation angles
? in the range of 0° to 60°, had an orientation density of
the a fibre determined in the strip centre of at least 4.
The orientation density only dropped to below 3 in the
angle range of more than 60°. The value of the ratio
I112/I001 of the intensity I112 of the position (112) to
the intensity I110 of the component (001) of the a
fibre was at a high level, namely 0.81. In the same way,
the value of the ratio T111/I001 of the intensity I111 of the
position (111) to the intensity I110 of the position
(001) reached a high level, namely 0.54.
The curve of the orientation density over the angle ? is
shown as a solid line in the graph for the hot strip WbE
according to the invention.
The high orientation densities up to an angle of 60° and
the high intensities of the component (112) and (111)
proves that the hot strip according to the invention
is in a substantially partially softened state.

WE CLAIM
1. Hot-rolled steel strip for further processing to form non-grain oriented
electrical sheet
- with the following composition (in % by weight)
C: Mn: ? 1.2%
Si: 0.1 - 4.4%
Al: 0.1 - 4.4%
Wherein the sum formed from the Si content and twice the Al content is P: Sn: ? 0.20%
Sb: ? 0.20%
the remainder iron and unavoidable impurities,
- with a strip thickness which is at most 1.8 mm, and
- with a partially softened structure which is characterized by a high
intensity of the a fibre (fibre representation of orientation distribution
fuctions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from
the intensity I112 of the position (112) to the intensity I001 of the
position (001) is > 0.4 and the ratio I111/I001 formed from the
-

intensity I111 of the position (111) to the intensity I001 of the
position (001) is > 0.2.
2. Hot strip as claimed in claim in 1, wherein the strip thickness is at most
1.2 mm and the ratio I112/I001 formed from the intensity I112 of the
position (112) of the intensity I110 of the position (001) of
the a fibre is > 0.75 and the ratio I111/I001 formed from the intensity I111
of the position (111) to the intensity I001 of the a fibre is 0.4.
3. Hot strip as claimed in any one of the preceding claims, wherein at a first
high temperature, it has a ferritic structure, at a second temperature lying
below the first temperature, it has a ferritic/austenitic structure, at a third
temperature lying below the second temperature, it has an austenitic
structure, at a fourth temperature lying below the third temperature it has
an austenitic/ferritic structure and at a fifth temperature lying below the
fourth temperature it again has a ferritic structure.
4. Method for producing hot strip composed as claimed in any one of claims
1 to 3, comprising the following working steps:

- melting the steel,
- casting the steel to form thin slabs,
- continuous fin-line") hot-rolling of the thin slabs following the thin slabs
following the casting of the steel
-

5. Method as claimed in claim 4, wherein the phosphorous content in the hot
strip is 6. Method as claimed in claim 4 or 5, wherein the degree of total
deformation achieved during the hot rolling is at least 90%.
7. Method for producing hot strip as claimed in claims 1 to 3, comprising the
following working steps:

- melting the steel,
- casting the steel to form a thin strip,
- continuous ("in-line") hot-rolling following the casting of the steel in one
or more passes

8. Hot strip as claimed in claim 7, wherein its P content is weight.
9. Method as claimed in any one of claims 4 to 8, wherein the hot-rolling is
carried out in a plurality of passed.
10. Method as claimed in claim 9 wherein at least one pass of the hot-rolling
is carried out at temperatures at which the hot strip has as austenitic
structure,and a plurality of subsequent passed of the hot -rolling are
carried out at temperatures in which the hot strip has a ferritic structure.
8.

11. Method as claimed in any one of claims 4 to 10 wherein the end rolling
temperature during hot-rolling is less than 850°.
12. Method as claimed in any one of the preceding claims wherein during the
rolling in the ferrite area at least rolling pass is carried out with
lubrication.
13.Method for producing non-grain oriented electrical sheet from a hot strip
composed according to any one of claims 1 to 3 and produced according
to any one of claims 4 to 10, comprising the following working steps:
- picking or annealing and pickling of the hot strip,
- cold rolling of the hot strip,
- intermediate annealing of the cold strip,
- final annealing or
- annealing with subsequent deformation with a total degree of
deformation of less than 20%.
14.Method according to claim 11, characterized in that the cold-rolling is
carried out in at least two stages with an intermediate annealing.
The present invention relates to a hot-rolled steel strip
for further processing to form non-grain oriented
electrical sheet with the following composition (in % by
weight) C: 4.4%, wherein the sum formed from the Si content and twice
the Al content is 0.20%, the remainder iron and unavoidable impurities, with
a strip thickness which is at most 1.8 mm, and with a
partially softened structure which is characterised by a
high intensity for the α fibre (fibre representation of
orientation distribution functions) in the region of 0° to
60°, wherein the ratio I112/I001 formed from the intensity
I112 of the position (112) to the intensity I001 of the
position (001) is > 0.4 and the ratio I111/I001 formed
from the intensity I111 of the position (111) to the
intensity I001 of the position (001) is > 0.2.

Documents:

555-kolnp-2004-granted-abstract.pdf

555-kolnp-2004-granted-claims.pdf

555-kolnp-2004-granted-correspondence.pdf

555-kolnp-2004-granted-description (complete).pdf

555-kolnp-2004-granted-drawings.pdf

555-kolnp-2004-granted-examination report.pdf

555-kolnp-2004-granted-form 1.pdf

555-kolnp-2004-granted-form 18.pdf

555-kolnp-2004-granted-form 2.pdf

555-kolnp-2004-granted-form 26.pdf

555-kolnp-2004-granted-form 3.pdf

555-kolnp-2004-granted-form 5.pdf

555-kolnp-2004-granted-reply to examination report.pdf

555-kolnp-2004-granted-specification.pdf

555-kolnp-2004-granted-translated copy of priority document.pdf

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Patent Number

226776

Indian Patent Application Number

555/KOLNP/2004

PG Journal Number

52/2008

Publication Date

26-Dec-2008

Grant Date

24-Dec-2008

Date of Filing

27-Apr-2004

Name of Patentee

THYSSENKRUPP STAHL AG.

Applicant Address

KAISER-WILHELM-STRASSE 100, 47161 DUISBURG

Inventors:

#	Inventor's Name	Inventor's Address
1	KARL ERNST FIEDRICH	EHRENMALSTRAβE 32 47447 MOERS
2	JURGEN SCHNEIDER	EDERSTRAβE 26 44807 BOCHUM
3	RUDOLF KAWALLA	PFARRGASSE 3C 09627 BOBRITZSCH
4	CARL-DIETER WUPPERMANN	DEUSSTRAβE 26C 47803 KREFELD
5	WOLFGANG RASIM	ZUR BAHN 2A 46509 XANTEN

PCT International Classification Number

C21D 8/12,C22C 38/02

PCT International Application Number

PCT/EP02/11822

PCT International Filing date

2002-10-23

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	10153234.2	2001-10-31	Germany