Title of Invention

Δ1- PYRROLINES

Abstract

1-Pyrrolines of the formula (I) (I) in which R1 represents halogen or methyl, R2 represents hydrogen or halogen, R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents arylene or 5-membered heteroaiylene having 1 to 3 heteroatoms, containing 0 to 3 nitrogen atoms, 0 to 1 oxygen atom and/or 0 to 1 sulphur atom, or 6-membered heteioarylene having 3 nitrogen atoms or 6-membered heteioaiylene having 1 nitrogen atom and 1 to 2 further heteroatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms, each arylene or heteioarylene being optionally substituted from one to four times by identical or different substitueots R5, and Y represents O (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) orNR8, or

Full Text

FORM 2 THE PATENTS ACT 1970 [39 OF 1970] COMPLETE SPECIFICATION [See Section 10] "∆1-PYRROLINES" BAYER AKTIENGESELLSCHAFT, a body corporate organised under the laws of Germany, of D-51368 Leverkusen, Germany, GRANTED 26-5-2008 The following specification particularly describes the nature of the invention and the manner in which it is to be performed:- Le A 35 188-Foreign Countries being optionally substituted from one to four times by identical or different substituents R5, and Y represents O (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) or NR8, or b) A represents pyridinylene, pyrimidinylene, pyrazinylene or 10 pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and Y represents O (oxygen) or S (sulphur), and 15 X represents S (sulphur) or NRS, or c) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical 20 or different substituents R5, and Y represents S (sulphur), and X represents O (oxygen), 25 or d) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and 30 Y represents O (oxygen), and Le A 35 188-Foreign Countries X represents O (oxygen), and R4 and R5 independently of one another represent halogen, alkyl, alkoxy, alkylthio, 5 haloalkyl, haloalkoxy or haloalkylthio, m represents 0,1, 2, 3 or 4, R6 represents hydrogen or alkyl, 10 R7 and R8 independently of one another represent hydrogen or represent alkyl or alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkylcarbonyl, alkylcarbonyloxy, alkylamino, dialkylamino, alkoxy, alkylthio, alkoxyalkoxy, 15 haloalkoxy, haloalkylthio and halogenalkoxyalkoxy; or represent cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, saturated or unsaturated 5- to 10-membered heterocyclyl or heterocyclylalkyl each of which is optionally substituted one or more times by identical or different 20 substitutents selected from the group consisting of halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylcarbonyl and alkoxy carbonyl, R6 and R7 further together represent alkylene optionally substituted one or more 25 times by alkyl, or R7 and R8 further, together with the nitrogen atom to which they are attached, represent a saturated or unsaturated 5- to 10-membered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- 30 and -NR9- and which may optionally be substituted one or more times by Le A 35 188-Foreign Countries 4- identical or different substituents selected from the group consisting of halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy and haloalkylthio, and R9 represents hydrogen, alkyl or alkenyl. 5 Where appropriate, depending on the nature and number of the substituents, the compounds of the formula (I) may be in the form of geometrical and/or optical isomers, regioisomers or configurational isomers, or isomer mixtures thereof in varying compositions. The pure isomers and the isomer mixtures are claimed in 10 accordance with the invention. It has also been found that Al-pyrrolines of the formula (I) may be prepared by A) reacting Al -pyrrolines of the formula (II) (II) 15 N' in which R1, R2, R4 and m have the meanings given above and 20 Z1 represents chlorine, bromine, iodine, -OS02CF3 or -OS02(CF2)3CF3, in a tandem reaction with (hetero)cycles of the formula (III) (III) 25 in which Le A 35 188-Foreign Countries -5- A, R6 and R7 have the meanings given above, Y1 represents 0 (oxygen), 5 X1 represents O (oxygen) or NR8, E represents chlorine, bromine, iodine, -OS02CF3 or -OS02(CF2)3CF3, in the presence of a catalyst, in the presence of a diboronic ester and, where 10 appropriate, in the presence of an acid binder and, where appropriate, in the presence of a diluent, or B) reacting ∆1-pyrrolines of the formula (IV) \i\) 15 in which R1, R2, R4 and m have the meanings given above, 20 Z2 represents -B(OH)2, (4,4,5,5-tetrarnethyl-l,3,2-dioxaborolan)-2-yl, (5J-d{meihy}-1,3,2'dioKabodcian)-2-yl (4,4,6-trimethyl- 1,3,2-dioxa-borinan)-2-yl or l,3,2-benzodioxaborol-2-yl, with (hetero)cycles of the formula (III) Y1 25 in which Le A 35 188-Foreign Countries E, A, Y1, X1, R6 and R7 have the meanings given above, in the presence of a catalyst, where appropriate in the presence of an acid binder and, where appropriate, in the presence of a diluent, or C) reacting ∆1-pyrrolines of the formula (II) R1 (H) in which 10 R1, R2, R4, m and Z1 have the meanings given above with boronic acid derivatives of the formula (V) Y1 R° (V) 15 in which Z2, A, Y1, X1, R6 and R7 have the meanings given above in the presence of a catalyst, where appropriate in the presence of an acid binder and, where appropriate, in the presence of a diluent, 20 or D) reacting ∆1pyrrolines of the formula (Il-a) R1 (II-a) Le A 35 188-Foreign Countries in which R1, R2, R4 and m have the meanings given above, 5 Z3 represents bromine or iodine with organometallic compounds of the formula (VI) (VI) in which 10 A, Y1, X1, R6 and R7 have the meanings given above, M represents ZnCl, Sn(Me)3 or Sn(n-Bu)3, in the presence of a catalyst, where appropriate in the presence of an acid 15 binder and, where appropriate, in the presence of a diluent, or E) reacting ∆1-pyrrolines of the formula (VII) i (VII) 20 in which R1, R2, A, R4 and m have the meanings given above either with an iso(thio)cyanate of the formula (VIII) 25 Le A 35 188-Foreign Countries R7— N=C=Y (VIII) in which / Y and R7 have the meanings given above \ [ 5 ! or with a (thio)carbonate of the formula (IX) in which 10 Y and R7 have the meanings given above, X2 represents O (oxygen) or S (sulphur), in each case where appropriate in the presence of a diluent and, where 15 appropriate, in the presence of an acid binder. Finally it has been found that the compounds of the formula (I) according to the invention possess very good insecticidal properties and may be used both in crop protection and in the protection of materials for the purpose of controlling unwanted 20 pests, such as insects. The formula (I) provides a general definition of the AJ-pyrroIines according to the invention. 25 Preferred compounds of the formula (I) are those in which R1 represents fluorine, chlorine, bromine or methyl, R2 represents hydrogen, fluorine, chlorine or bromine, Le A 35 188-Foreign Countries R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents arylene (especially phenylene) or 5-membered hetero- 5 arylene having 1 to 3 heteroatoms, containing 0 to 3 nitrogen atoms, 0 to 1 oxygen atom and/or 0 to 1 sulphur atom (in particular from the series pyrrolylene, furylene, thienylene, pyrazylene, imidazylene, tri- azylene, thiazylene or oxazylene), or 6-membered heteroarylene having 3 nitrogen atoms (especially triazinylene) or 6-membered hete- 10 roarylene having 1 nitrogen atom and 1 to 2 further heteroatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms (in particular from the series oxazinylene or thiazinylene), each being optionally substituted from one to three times by identical or different substituents R5, and 15 Y represents O (oxygen) or S (sulphur) and X represents 0 (oxygen), S (sulphur) or NR8, or 20 b) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazin-ylene each optionally substituted once or twice by identical or differ¬ent substituents R5, and 25 Y represents O (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or Le A 35 188-Foreign Countries -10- c) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazin-ylene each optionally substituted once or twice by identical of differ¬ent substituents R5, and 5 Y represents S (sulphur), and X represents O (oxygen), or 10 d) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazin- ylene each optionally substituted once or twice by identical or differ¬ent substituents R5, and 15 Y represents O (oxygen), and X represents O (oxygen), and R4 and R5 independently of one another represents fluorine, chlorine, bromine, 20 CrC6-alkyl, C1-C6-alkoxy, C1C6-alkylthio, C1C6-haloalkyl, C1C6-haIo- alkoxy or C1-C6-haloalkylthio, m represents 0,1, 2 or 3, 25 R6 represents hydrogen or C1-C6-alkyl, R7 and R8 independently of one another represent hydrogen or represent C1-C20- alkyl or C2-C20-alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of 30 fluorine, chlorine, bromine, C1-C6-alkylcarbonyl, C1-C6-alkylcarbonyloxy, C1-C6-alkylamino, di-(C1-C6-alkyl)amino, C1-C10-alkoxy, C1-C10-alkylthio, Le A 35 188-Foreign Countries -11 - C1-C10-alkoxy-C1-C10-alkoxy, C1-C10-haloalkoxy, C1-C10-haloalkylthio and C1-C10-haloalkoxy-C1-C10-alkoxy; or represent C3-Ci2-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, aryl, aryl-C1- 5 C4-alkyl, saturated or unsaturated 5- to 10-membered heterocyclyl or hetero- cyclyl-C1-C4-alkyl having 1 to 4 heteroatoms, containing 0 to 4 nitrogen atoms, 0 to 2 non-adjacent oxygen atoms and/or 0 to 2 non-adjacent sulphur atoms (especially tetrazolyl, furyl, furfuryl, benzofuryl, tetrahydrofuryl, thienyl, thenyl, benzothienyl, thiolanyl, pyrrolyl, indolyl, pyrrolinyl, pyrro- 10 lidinyl, oxazolyl, benzoxazolyl, isoxazolyl, imidazolyl, pyrazolyl, thiazolyl, benzothiazolyl, thiazolidinyl, pyridinyl, pyrimidinyl, pyridazyl, pyrazinyl, piperidinyl, morpholinyl, thiomorpholinyl, triazinyl, triazolyl, quinolinyl or isoquinolinyl) each optionally substituted from one to four times by identical or different substituents selected from the group consisting of fluorine, 15 chlorine, bromine, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-halo- alkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-alkylcarbonyl and C1-C6-alkoxycarbonyl, R6 and R7 further together represent C2-C4-alkylene optionally substituted from one 20 to four times by C1 -C4-alkyl, or R7 and R8 further represent, together with the nitrogen atom to which they are attached, a saturated or unsaturated 5- to 10-membered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- or 25 -NR9- and which may optionally be substituted from one to four times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-haloalkyl, C1-C6-haloalkoxy and/or C1-C6-haloalkylthio, and 30 R9 represents hydrogen, C1-C6-alkyl or C2-C6-alkenyl. Le A 35 188-Foreign Countries -12- Particularly preferred compounds of the formula (I) are those in which/ R1 represents fluorine, chlorine or methyl, 5 " R2 represents hydrogen, fluorine or chlorine, R3 represents -N(R6)-C(=Y)-X-R7, and 10 a) A represents phenylene, pyrrolylene, furylene, thienylene, pyrazylene, imidazylene, triazylene, thiazylene or oxazylene each optionally substituted once or twice by identical or different substituents R5, and 15 Y represents O (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) or NR8, or b) A represents pyridinylene, pyrimidinylene, pyrazinylene or 20 pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and Y represents O (oxygen) or S (sulphur), and 25 X represents S (sulphur) or NR8, or c) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical 30 or different substituents R5, and Le A 35 188-Foreign Countries -13 Y represents S (sulphur), and X represents O (oxygen), or 5 d) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and 10 Y represents O (oxygen), and X represents O (oxygen), and 15 R4 and R5 independently of one another represent fluorine, chlorine, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio; C1-C4-haloalkyl, C1-C4-haloalkoxy or C1-C4-haloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, 20 m represents 0, 1 or 2, R6 represents hydrogen or C j -C4-alkyl, R7 and R8 independently of one another represent hydrogen or represent C1-C16- 25 alkyl or C2-C16-alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkylamino, di-(C1-C4-alkyl)amino, C1-C10-alkoxy, C1-C10-alkylthio, C1-C10-alkoxy-C1-C6-alkoxy, C1-C10-haloalkoxy, C1-C10-haloalkylthio and 30 C1-C10-haloalkoxy-C1-C6-alkoxy having in each case 1 to 21 fluorine, chlorine and/or bromine atoms; e A 35 188-Foreign Countries -14- or represent C3-Cio-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, phenyl, benzyl, phenylethyl, tetrazolyl, furyl, furfuryl, benzofuryl, tetrahydrofuryl, thienyl, thenyl, benzothienyl, thiolanyl, pyrrolyl, indolyl, pyrrolinyl, pyrrolidinyl, oxazolyl, benzoxazolyl, isoxazolyl, irriidazolyl, pyrazolyl, 5 thiazolyl, benzothiazolyl, thiazolidinyl, pyridinyl, pyrimidinyl, pyridazyl, pyrazinyl, piperidinyl, morpholinyl, thiomorpholinyl, 'triazinyl, triazolyl, quinolinyl or isoquinolinyl each optionally substituted from one to three times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, 10 C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, C1-C4-alkylcarbonyl and C1-C4-alkoxycarbonyl, R6 and R7 further together represent C2-C3-alkylene optionally substituted from one 15 to three times by C1-C4-alkyl, or R7 and R8 further represent, together with the nitrogen atom to which they are attached, a saturated or unsaturated 5- to 7-membered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- or 20 -NR9- (in particular from the series piperidino, morpholino, thiomorpholino, piperazino, pyrrolidino oxazolidino, thiazolidino, 4H-l-oxazinyl, 4H-1-thiazinyl) and which may optionally be substituted from one to four times by identical or different substituents selected from the group consisting of fluorine, chlorine, C1-C4-alkyl, Cj-C4-alkoxy, Cj-C4-alkylthio, C1-C4- 25 haloalkyl, C1-C4-haloalkoxy and/or C1-C4-haloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, and R9 represents hydrogen, C1-C4-alkyl or C2-C4-alkenyl. 30 Very particularly preferred compounds of the formula (I) are those in which Le A 35 188-Foreign Countries -15-R1 represents fluorine or chlorine, r R2 represents hydrogen or fluorine, 5 R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents 1,2-phenylene, 1,4-phenylene, 2,5-pyrrolylene, 2,5- furylene, 2,4-furylene, 2,5-thienylene, 2,4-thienylene, 2,5-thiazylene, 10 2,4-thiazylene, 2,5-oxazylene or 2,4-oxazylene each optionally substituted once by R5, and Y represents O (oxygen) or S (sulphur), and 15 X represents O (oxygen), S (sulphur) or NR8, or b) A represents 2,5-pyridinylene, 2,5-pyrimidinylene, 2,5-pyrazinylene or 3,6-pyridazinylene each optionally substituted once by R5, and 20 Y represents O (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or 25 30 c) A represents 2,5-pyridinylene, 2,5-pyrimidinylene, 2,5-pyrazinylene or 3,6-pyridazinylene each optionally substituted once by R5, and Y represents S (sulphur), and X represents O (oxygen), Le A 35 188-Foreign Countries -16- d) A represents 2,5-pyridinylene, 2,5-pyrimidinylene, 2,5-pyrazinylene or 3,6-pyridazinylene each optionally substituted once by R5, and 5 Y represents 0 (oxygen), and X represents O (oxygen), and 10 R4 and R5 independently of one another represent fluorine, chlorine, methyl, ethyl, n- propyl, i-propyl, n-butyl, i-butyl, s-butyl, t-butyl, methoxy, ethoxy, n- propoxy, i-propoxy, n-butoxy, i-butoxy, s-butoxy, t-butoxy, methylthio, ethylthio, n-propylthio, i-propylthio, n-butylthio, i-butylthio, s-butylthio, t- 15 butylthio, trifluoromethyl, trifluoroethyl, trifluoromethoxy, trifluoroethoxy, trifluoromethylthio or trifluoroethylthio, m represents 0 or 1, 20 R6 represents hydrogen, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s- butyl or t-butyl, R7 and R8 independently of one another represent hydrogen or represent C1-C10-alkyl or C2-C10-alkenyl (especially methyl, ethyl, n-propyl, i-propyl, n-butyl, 25 i-butyl, s-butyl, t-butyl, the isomeric pentyls, the isomeric hexyls) each optionally substituted one or more times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, CrC4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkylamino, di-(C1-C4-alkyl)amino, C1-C10-alkoxy, C1-C8-alkoxy-C1-C6-alkoxy, C1-C10-alkylthio, 30 C1-C10-haloalkoxy, C1-C10-haloalkylthio having in each case 1 to 21 Le A 35 188-Foreign Countries -17- fluorine, chlorine and/or bromine atoms, C1-C8-haloalkoxy-C1-C6-alkoxy having 1 to 17 fluorine, chlorine and/or bromine atoms; • or represent C3-C8-cycloalkyl, cyclopropylmethyl, cyclopentylmethyl, 5 cyclohexylmethyl, cyclopropylethyl, cyclopentylethyl, cyclohexylethyl, phenyl, benzyl, phenylethyl, tetrazolyl, furyl, furfuryl, benzofuryl, tetrahydro-furyl, thienyl, thenyl, benzothienyl, thiolanyl, pyrrolyl, indolyl, pyrroliriyl, pyrrolidinyl, oxazolyl, benzoxazolyl, isoxazolyl, imidazolyl, pyrazolyl, thiazolyl, benzothiazolyl, thiazolidinyl, pyridinyl, pyrimidinyl, pyridazyl, 10 pyrazinyl, piperidinyl, morpholinyl, thiomorpholinyl, triazinyl, triazolyl, quinolinyl or isoquinolinyl each optionally substituted from one to three times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio having in each case 15 1 to 9 fluorine, chlorine and/or bromine atoms, C1-C4-alkylcarbonyl and C1-C4-alkoxycarbonyl, R6 and R7 together further represent methylene or ethylene each optionally substituted once or twice by identical or different methyl, ethyl, n-propyl or 20 i-propyl substituents, or R7 and R8 further represent, together with the nitrogen atom to which they are attached, a 5- to 6-membered heterocycle from the series piperidino, morpho-lino, thiomorpholino, piperazino, pyrrolidino, oxazolidino, thiazolidino, 4H- 25 1-oxazinyl, 4H-l-thiazinyl which may optionally be substituted from one to four times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl, t-butyl, methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, i-butoxy, s-butoxy, t-butoxy, methylthio, ethylthio, n-propylthio, i- 30 propylthio, n-butylthio, i-butylthio, s-butylthio, t-butylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio having in each case 1 to 9 fluorine, Le A 35 188-Foreign Countries 18- chlorine and/or bromine atoms, the piperazino radical being substituted on the second nitrogen atom by R9, and R9 represents hydrogen, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, 5 s-butyl, t-butyl, vinyl or allyl. Further very particularly preferred compounds are those of the formulae (1-1) and (1-2) N-C-X-R7 10 (1-1) (1-2) in each of which 15 a) Y represents O (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) or NR8, and R1, R2, R4, R5, m, R6, R7, R8 have the meanings given above. In the formulae (1-1) and (1-2) the radicals R1, R2, R4, R5, m, R6, R7, R8 each 20 represent with preference, with particular preference or with very particular preference those definitions stated as being preferred, particularly preferred, etc. for these radicals in the context of the description of the substances of the formula (I) Le A 35 188-Foreign Countries 19 according to the invention. Y and X represent in each case with preference, with particular preference or with very particular preference those definitions described in each case ander the corresponding section "a)". Further very particularly preferred compounds are those of the formulae (1-3) to (1-8) 10 Le A 35 188-Foreign Countries 20 (1-7) (1-8) in each of which 5 p represents 0, 1 or 2, b) Y represents O (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, 10 or c) Y represents S (sulphur), and X represents O (oxygen), 15 or d) Y represents O (oxygen), and X represents O (oxygen), 20 and R1, R2, R4, R5, m, R6, R7 and R8 have the meanings given above. Le A 35 188-Foreign Countries -21 - In the formulae (1-3) to (1-8) the radicals R1, R2, R4, R5, m, RV R.7, R8. each represent with preference, with particular preference or with very particular preference those definitions stated as being preferred, particularly preferred, etc. for these radicals in the context of the description of the substances of the formula (I) 5 according to the invention. Y and X represent in each case with preference, with particular preference or with very particular preference those definitions described in each case ander the corresponding section "a)", "b)", "c)" and "d)". p represents preferably 0, 1 or 2, with particular preference 0 or 1, with very particular preference 0. 10 Further preferred compounds of the formula (I) are those in which A represents phenylene, preferably 1,4-phenylene. Further preferred compounds of the formula (I) are those in which A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene, preferably 2,5-pyri- 15 dinylene, 2,5-pyrimidinylene, 2,5-pyrazinylene or 3,6-pyridazinylene. Further preferred compounds of the formula (I) are those in which Y represents O (oxygen). 20 Further preferred compounds of the formula (I) are those in which X represents O (oxygen) or NR8, preferably O (oxygen). Further preferred compounds of the formula (I) are those in which Y and X each represent O (oxygen). 25 Further preferred compounds of the formula (I) are those in which Y represents O (oxygen) and X represents NR8. Further preferred compounds of the formula (I) are those in which A represents 30 phenylene, preferably 1,4-phenylene, Y represents O (oxygen) or S (sulphur), Le A 35 188-Foreign Countries 23 Compounds of the formula (I-a) are obtained by customary methods of optical resolution, such as, for example, by chromatographing the corresponding racemates on a chiral stationary phase. It is possible to separate either the racemic end products or racemic intermediates in this way into the two enantiomers. 5 Saturated hydrocarbon radicals such as alkyl, alone or in conjunction ,with heteroatoms, such as in alkoxy, for example, may where possible in each case be straight-chain or branched. 10 The radical definitions and elucidations set out above in general or in ranges of preference may, however, also be combined as desired with one another, i.e. are arbitrary combinations between the respective ranges and ranges of preference. They apply both to the end products and to the precursors and intermediates accordingly. 15 Using 5-(2,6-difluorophenyl)-2-(4-bromophenyl)-3,4-dihydro-2H-pyrrole, methyl 4-bromophenylcarbamate and 4,4,4',4',5,5,5',5'-octamethyl-2,2'-bis-l,3,2-dioxa-borolane as starting materials and a palladium catalyst, the course of the process (A) according to the invention can be illustrated by the following equation. Pd 20 OMe Using 5-(2,6-difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)- phenyl]-3,4-dihydro-2H-pyrrole and methyl 4-bromophenylcarbamate as starting materials and a palladium catalyst, the course of the process (B) according to the 25 invention can be illustrated by the following equation. Le A 35 188-Foreign Countries 24 Using 5-(2,6-difluorophenyl)-2-[4-(trifluoromethylsulfonyloxy)phenyl]-3,4-dihydro-2H-pyrrole and methyl 4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)phenyl-carbamate as starting materials and a palladium catalyst, the course of the process (C) according to the invention can be illustrated by the following equation. OS02CF3 OMe OMe Pd Using 5-(2,6-difluorophenyl)-2-(4-bromophenyl)-3,4-dihydro-2H-pyrrole and methyl 10 4-(tributylstannyl)phenylcarbamate as starting materials and a palladium catalyst, the course of the process (D) according to the invention can be illustrated by the following equation. OMe Pd 15 Le A 35 188-Foreign Countries -25- Using 4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H-pyrrol-2-yl]-l,r-biphenyl-4-amine and (methylimino)(thioxo)methane as starting material, the course of the process (E) according to the invention can be illustrated by the following equation. Elucidation of the processes and intermediates 10 Process (A) In a first reaction step, a compound of the formula (II) is coupled with a diboronic acid ester in the presence of a palladium catalyst, if appropriate in the presence of an acid binder and if appropriate in the presence of a solvent. Without any isolation of 15 the intermediate, a compound of the formula (III) is coupled in the same reaction vessel in a second reaction step in the presence of a catalyst, if appropriate in the presence of an acid binder and if appropriate in the presence of a solvent (cf, for example, Tetrahedron Lett. 1997, 38, 3841). 20 The process (A) according to the invention can be carried out in two variants. It is possible either to initially charge a compound of the formula (II) or to initially charge a compound of the formula (III). Process (A) is to be considered a tandem reaction of the processes (B) and (C) described below. 25 The formula (II) provides a general definition of the ∆1-pyrrolines required as starting materials for carrying out the process (A). In this formula, R], R2, R3 and m preferably, particularly preferably and very particularly preferably have those meanings which have already been mentioned in connection with the description of Le A 35 188-Foreign Countries -26- the substances of the formula (I) according to the invention as being preferred, particularly preferred, etc. for these radicals. Z preferably represent^Drdrnine*ipdine, -OS02CF3 or -OS02(CF2)3CF3, particularly preferably bromine, -OSC^CF^or -OS02(CF2)3CF3, very particularly preferably bromine or -OSO2CF3. * ', 5 Al-Pyrrolines of the fomula (II) can be prepared by known processes (cf. WO 98/22438). A'-Pyrrolines of the formula (II) can also be obtained by a process which is described below. 10 The formula (III) provides a general definition of the (hetero)cycles required as starting materials for carrying out the process (A) according to the invention. In this formula, Y1 preferably represents O (oxygen). X1 preferably represents O (oxygen) or NR8. E preferably represents bromine, chlorine, iodine or -OS02CF3, with particular preference bromine, chlorine or iodine, with very particular preference 15 bromine or chlorine. A, R6, R7 and R8 represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the formula (I) according to the invention. 20 The (hetero)cycles of the formula (III) are known in some cases. (Hetero)cycles of the formula (Ill-a) 25 in which E, A, Y1, X1 and R7 have the meanings given above, R6_a represents hydrogen, Le A 35 188-Foreign Countries 27- may be prepared, for example, by a) reacting isocyanates of the formula (X) 5 E-A-N=C=0 (X) in which E and A have the meanings given above, 10 with alcohols and/or amines of the formula (XI) H-X1-R7 (XI) in which X1 and R7 have the meanings given above, 15 or with compounds of the formula (XII) * 20 in which X1 has the meanings given above, L represents alkylene optionally substituted one or more times by alkyl 25 optionally in the presence of a diluent (e.g. toluene, dioxane, dimethyl sulphoxide). Le A 35 188-Foreign Countries -29 Alcohols and amines of the formula (XI) are known. The formula (XII) provides a general definition of the compounds additionally required as starting materials for carrying out the process (a). In this formula, X1 5 represents preferably, with particular preference or with very particular preference, those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the formula-(III) according to the invention. L represents preferably C2-C4-alkylene optionally substituted from one to four times by C1-C4-alkyl, particularly preferably C2-C3- 10 alkylene optionally substituted from one to three times by Ci-C4-alkyl, with very particular preference methylene or ethylene each optionally substituted once or twice by identical or different methyl, ethyl, n-propyl or i-propyl substituents. Compounds of the formula (XII) are known. 15 (Hetero)cycles of the formula (Ill-b) in which 20 E, A, Y1 and R7 have the meanings given above, 25 X3 represents O (oxygen), R6-b represents alkyl, may be prepared, for example, by b) reacting amines of the formula (XIII) Le A 35 188-Foreign Countries 10 -30- (XIII) in which E, A and R6_b have the meanings given above, with a chloroformate of the formula (XIV) (XIV) in which R7 has the meanings given above, in the presence of N,0-bis(trimethylsilyl)acetamide and, where appropriate, in the presence of a diluent (e.g. dichloromethane) (cf. Syn. Commun. 1985, 15, 1025-1031). 15 The formula (Ill-b) provides a general definition of the (hetero)cycles which can be prepared by the process (b). In this formula, A represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the 20 description of the substances of formula (I) according to the invention. E represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of formula (III) according to the invention. R6-b represents preferably C1-C6-alkyl, with particular 25 preference C1-C4-alkyl, with very particular preference methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl or t-butyl. The formula (XIII) provides a general definition of the amines required as starting materials for carrying out the process (d). In this formula, E and A represent Le A 35 188-Foreign Countries -31- preferably, with particular preference or with very particular preference those I definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of formula (I) according to the invention. R6_b represents preferably Cj^-alkyl, with particular preference 5 Cj-C4-alkyl, with very particular preference methyl, ethyl, n-propyl, i-propyl, n- butyl, i-butyl, s-butyl or t-butyl. Amines of the formula (XIII) are known. 10 The formula (XIV) provides a general definition of the chloroformates required as starting materials for carrying out the process (b). In this formula, R7 represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of formula (I) according 15 to the invention. Chloroformates of the formula (XIV) are known. (Hetero)cycles of the formula (III-c) 20 (III-c) in which E, A and Y1 have the meanings given above, 25 X3 represents O (oxygen), R6_c and R7"c together represent alkylene optionally substituted one or more times by alkyl, Le A 35 188-Foreign Countries -32- may be prepared, for example, by c) reacting isocyanates of the formula (X) 5 E-A-N=C=0 (X) in which E and A have the meanings given above, 10 with a dioxolane of the formula (XV) (XV) 15 R6_c and R7"c have the meanings given above, where appropriate in the presence of an acid binder (e.g. caesium fluoride) and, where appropriate, in the presence of a diluent (e.g. dimethyl sulphoxide) (cf. JP 2000-2902635). 20 The formula (III-c) provides a general definition of the (hetero)cycles which can be prepared by process (c). In this formula, A represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the 25 description of the substances of formula (I) according to the invention. E represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of formula (III) according to the invention. R6-c and R7-c together represent preferably C2-C4- Le A 35 188-Foreign Countries -33- alkylene optionally substituted from one to four times by C1-C4-alkyl, with particular preference C2-C3-alkylene optionally substituted from one to three times by C1-:C4- alkyl, with very particular preference methylene or ethylene substituted once or twice by methyl, ethyl, n-propyl or i-propyl. 5 . The isocyanates of the formula (X) required as starting materials for earrying out the process (c) have already been described in connection with the elucidation of the process (a). 10 The formula (XV) provides a general definition of the dioxolanes required as starting materials for carrying out the process (c). In this formula, R6-c and R7-c preferably, with particular preference and with very particular preference represent those definitions already stated as being preferred, particularly preferred, for these radicals in connection with the description of the substances of formula (III-c). 15 Dioxolanes of the formula (XV) are known. Suitable diboronic esters for carrying out process (A) according to the invention are 4,4',4',5,5,5',5'-octamethyl-2,2,-bis-l,352-dioxaborolane, 5,5,5',5'-tetramethyl-2,2'-bis- 20 1,3,2-dioxaborinane, 4,4,4',4',6,6'-hexamethyl-2,2'-bis-1,3,2-dioxaborinane or 2,2'- bis-l,3,2-benzodioxaborole. Preference is given to using 4,4,4',4',5,5,5',5'-octamethyl-2,2'-bis-l,3,2-dioxaborolane, 5,5,5',5'-tetramethyl-2,2'-bis-l,3,2-dioxa-borinane or 4,4,4',4',6,6'-hexamethyl-2,2'-bis-1,3,2-dioxaborinane, particularly preferably 4,4,4',4',5,5,5',5,-octamethyl-2,2,-bis-l,3,2-dioxaborolane or 5,5,5',5'- 25 tetramethyl-2,2'-bis- 1,3,2-dioxaborinane, very particularly preferably 4,4,4',4',5,5,5',5'-octamethyl-2,2,-bis-l,3,2-dioxaborolane. When carrying out the process (A) according to the invention, in general 1 mol or a slight excess of a diboronic ester and 1 mol or a slight excess of a compound of the 30 formula (III), and 3% of a palladium catalyst, are employed per mole of the compound of the formula (II). However, it is also possible to employ the reaction Le A 35 188-Foreign Countries 34 components in other ratios. It is possible to initially charge the compound of the formula (II) or, alternatively, the compound of the formula (III). Work-up is carried out by customary methods. In general, the reaction mixture is diluted with water and extracted with ethyl acetate. The organic phase is washed, dried filtered arid ft 5 concentrated. The residue is, if appropriate, freed from any impurities that may still be present using customary methods, such as chromatography or recrystallization. Process (B) 10 The formula (IV) provides a general definition of the A'-pyrrolines required as starting materials for carrying out the process (B) according to the invention. In this formula, R1, R2, R4 and m preferably, particularly preferably and very particularly preferably have those meanings which have already been mentioned in connection with the description of the substances of the formula (I) according to the invention as 15 being preferred, particularly preferred, etc. for these radicals. Z2 preferably represents (4,4,5,5-tetramethyl-l,3,2-dioxaborolan)-2-yl, (5,5-dimethyl-1,3,2-dioxaborinan)-2-yl, (4,4,6-trimethyl-l,3,2-dioxaborinan)-2-yl or l,3,2-benzodioxaborol-2-yl, particularly preferably (4,4,5,5-tetramethyl-l,3,2-dioxaborolan)-2-yl, (5,5-dimethyI-l,3,2-dioxaborinan)-2-yl or (4,4,6-trimethyl-l,3,2-dioxaborinan)-2-yl, very 20 particularly preferably (4,4,5,5-tetramethyl-l,3,2-dioxaborolan)-2-yl or (5,5- dimethyl-l,3,2-dioxaborinan)-2-yl. ∆1-Pyrrolines of the formula (IV) can be prepared by 25 d) reacting compounds of the formula (II) (II) in which Le A 35 188-Foreign Countries -35- R1, R2, R4, m and Z1 have the meanings given above, ■« ' * ■-. i- t "■■ ■ '■ with a diboronic ester in the presence of a catalyst,;if appropriate in'the presence of an acid binder and if appropriate in the presence of a diluent (ef. 5 J. Org. Chem. 1995, 60, 7508; Tetrahedron Lett. 1997, 38, 3447). Diboronic esters suitable for carrying out the process (d) have already been mentioned in the description of the process (A) according to the invention. 10 The heterocycles of the formula (III) required as starting materials for carrying out the process (B) according to the invention have already been described above in the description of process (A). When carrying out the process (B) according to the invention, in general 1 mol or a slight excess of a compound of the formula (III) is employed per mole of the 15 compound of the formula (V). However, it is also possible to employ the reaction components in other ratios. Work-up is carried out by customary methods. In general, the reaction mixture is taken up in ethyl acetate and the organic phase is washed with water, dried over sodium sulphate, filtered and concentrated. The residue is, if appropriate, freed from any impurities that may still be present using customary 20 methods, such as chromatography or recrystallization. Process (C) The ∆1-pyrrolines of the formula (II) required as starting materials for carrying out 25 the process (C) according to the invention have already been described in the description of process (A). The formula (V) provides a general definition of the boronic acid derivatives required as starting materials for carrying out the process (C) according to the invention. In 30 this formula, Y1 represents preferably O (oxygen). X1 represents preferably O (oxygen) or NR8. Z2 represents preferably (4,4,5,5-tetramethyl-l,3,2-dioxaborolan)- Le A 35 188-Foreign Countries -36- 2-yl, (5,5-dimethyl-l,3,2-dioxaborinan)-2-yl, (4,4,6-trimethyl-l,3,2-dioxaborinan)2- yl or l,3,2-benzodioxaborol-2-yl, particularly preferably (4,4,5,5-tetramethyl-l,3,2- dioxaborolan)-2-yl, (5,5-dimethyl-l,3,2-dioxaborinan)-2-yl or (4,4,6-trimethyl-1,3,2- dioxaborinan)-2-yl, very particularly preferably (4,4,5,5-tetramethyl-1,3,2- 5 dioxaborolan)-2-yl or (5,5-dimethyl-l,3,2-dioxaborinan)-2-yl. A, R6, R7 and R8 represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the formula (I) according to the invention. 10 The compounds of the formula (V) are known or can be prepared by known processes. When carrying out the process (C) according to the invention, in general 1 mol or a 15 slight excess of a compound of the formula (V) is employed per mole of the compound of the formula (II). However, it is also possible to employ the reaction components in other ratios. Work-up is carried out by customary methods. In general, the reaction mixture is taken up in ethyl acetate and the organic phase is washed with water, dried over sodium sulphate, filtered and concentrated. The residue is, if 20 appropriate, freed from any impurities that may still be present using customary methods, such as chromatography or recrystallization. Process(D) 25 The formula (Il-a) provides a general definition of the A'-pyrrolines required as starting materials for carrying out the process (D) according to the invention. In this formula, R1, R2, R4 and m preferably, particularly preferably and very particularly preferably have those meanings which have already been mentioned in connection with the description of the substances of the formula (I) according to the invention as 30 being preferred, particularly preferred, etc., for these radicals. Z3 preferably represents bromine or iodine. Le A 35 188-Foreign Countries -37- ∆1-Pyrrolines of the formula (Il-a) can be prepared by known processes (cf. WO98/22438). The formula (VI) provides a general definition of the organornetallic compounds 5 required as starting materials for carrying out the process (D) according to the invention. In this formula, Y1 represents preferably 0 (oxygen). X1 represents preferably O (oxygen) or NR8. M represents preferably ZnCl, Sn(Me)3 or Sn(n-Bu)3- A, R6, R7 and R8 represents preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly 10 preferred, etc. for these radicals in connecton with the description of the substances of formula (I) according to the invention. Organometallic compounds of the formula (VI) are known in some cases or can be prepared by known methods. It is possible, for example, to prepare compounds of the 15 formula (VI) in situ from the corresponding compounds of the formula (III) in which X represents -OS02CF3 (cf. Tetrahedron Lett. 1995, 36, 9085). When carrying out the process (D) according to the invention, in general 1 mol or a slight excess of a compound of the formula (VI) is employed per mole of the 20 compound of the formula (Il-a). However, it is also possible to employ the reaction components in other ratios. Work-up is carried out by customary methods. In general, the reaction mixture is taken up in ethyl acetate and the organic phase is washed with water, dried over sodium sulphate, filtered and concentrated. The residue is, if appropriate, freed from any impurities that may still be present using customary 25 methods, such as chromatography or recrystallization. Le A 35 188-Foreign Countries 38 Preparation of starting materials for processes (A), (B), (C) and (D) The ∆1-pyrrolines of the formulae (II), (IV) and (II-a) required as starting materials for carrying out the processes (A), (B), (C) and (D) according to the invention may 5 also be prepared by e) reacting amides of the formula (XVI) (XVI) o 10 in which Q represents Z1, Z2 or Z3, RlO represents alkyl, haloalkyl, phenyl or benzyl, 15 R1, R2, R4, m, Z1, Z2 and Z3 have the meanings given above, with an N-deacylating agent in the presence of a diluent. The formula (XVI) provides a general definition of the amides required as starting 20 materials for carrying out the process (e). In this formula, R1, R2, R4 and m represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the formula (I) according to the invention. Q represents Z1, Z2 or Z3 or represents the preferred, 25 particularly preferred and very particularly preferred definitions of these radicals which have already been described above. R10 represents preferably C1-C4-alkyl, C1- Le A 35 188-Foreign Countries -39 C4-haloalkyl, phenyl or benzyl, with particular preference methyl, ethyl, phenyl or benzyl, with very particular preference methyl, phenyl or benzyl. The amides of the formula (XVI) required as starting materials for carrying out the process (e) may be prepared by f) reacting cyclopropanes of the formula (XVII) R1 O (XVII) 10 in which R1, R2, R4, m and Q have the meanings given above, with nitriles of the formula (XVIII) 15 R10-—CN (XVIII) in which R10 has the meanings given above and a protic acid or trimethylsilyl tetrafluoroborate. The formula (XVII) provides a general definition of the cyclopropanes required as 20 starting materials for carrying out the process (f). In this formula, R1, R2, R4 and m represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred or very particularly preferred for these radicals in connection with the description of the substances of the formula (I) according to the invention. Q represents Z1, Z2 or Z3 or 25 represents the preferred, particularly preferred and very particularly preferred definitions of these radicals which have already been described above. Le A 35 188-Foreign Countries -40 The formula (XVIII) provides a general definition of the nitriles required as starting materials for carrying out the process (f). In this formula, R10 represents preferably C1-C4-alkyl, C1-C4-haloalkyl, phenyl or benzyl, with particular preference methyl, ethyl, phenyl or benzyl, with very particular preference methyl, phenyl or benzyl. 5 Suitable protic acids when carrying out process (f) include all acids which can commonly be used for this purpose. A preferred possibility for use is sulphuric acid. As trimethylsilyltetrafluoroborate for carrying out process (f), the compound of the 10 formula (XIX) Me3Si-N=C-CH3 BF4 (XIX) is suitable. The reagent of the formula (XIX) is known (cf. Tetrahedron Lett. 1984, 25, 577-578). 15 The reaction temperatures for carrying out process (f) may be varied within a relatively wide range. It is normal to operate at temperatures between -20°C and +60°C, preferably between -10°C and 30°C. The cyclopropanes of the formula (XVII) required as starting materials for carrying 20 out the process (f) may be prepared by g) reacting chalcones of the formula (XX) R1 O ^ ^ (XX) 25 R1, R2, R4, m and Q have the meanings given above, Le A 35 188-Foreign Countries -41 - with a trialkylsulphoxonium ylide in the presence of a base and, where appropriate, in the presence of a diluent. The formula (XX) provides a general definition of the chalcones required as starting 5 materials when carrying out the process (g). In this formula, R1, R2, R4 and m, represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred or very particularly preferred for these radicals in connection with the description of the substances of the formula (I) according to the invention. Q represents Z1, Z2 or Z3 or 10 represents a preferred, particularly preferred and very particularly preferred definition of these radicals which have already been described above. As a trialkylsulphoxonium ylide for carrying out the process (g) it is preferred to use trimethylsulphoxonium ylide. 15 As bases when carrying out process (g) it is possible to use alkali metal hydrides, alkoxides and hydroxides. Preference is given to using sodium hydride, potassium 2-methyl-2-propoxide, sodium methoxide or potassium hydroxide, with particular preference sodium hydride. 20 Suitable diluents when carrying out process (g) include dimethyl sulphoxide, tetrahydrofuran, acetonitrile, toluene or diethylene glycol, and mixtures thereof. It is preferred to use dimethyl sulphoxide (cf. Tetrahedron Asymmetry 1998, 9, 1035). The reaction temperatures for carrying out process (g) according to the invention may 25 be varied within a relatively wide range. It is normal to operate at temperatures between -20°C and +120°C, preferably between 0°C and 60°C, with particular preference between 20°C and 40°C. The chalcones of the formula (XX) required as starting materials for carrying out 30 process (g) are known. Le A 35 188-Foreign Countries 42- When carrying out process (e), the amides of the formula (XVI) are N-deacylated in the reaction to give pyrrolines of the formulae (II), (IV), and (Il-a) rising protic acids (cf. J. Org. Chem. 1978, 43, 4593), inorganic bases (cf. J. Chem. Soc.; 1964, 4142), hydrazines (cf. J. Org. Chem. 1978,43, 3711) or biotransformation with enzymes (cf 5 Appl. Microbiol. Biotechnol. 1997, 47, 650). Other customary methods of deacylating amides are described in T. W. Greene, P. G. M. Wuts, Protective Groups in Organic Synthesis (Ed. 3, New York, Wiley 1999, pp. 553-555). As N-deacylating agents it is preferred to use protic acids or organic acids, with 10 particular preference aqueous hydrochloric acid, aqueous hydrobromic acid or trifluoroacetic acid, with very particular preference aqueous hydrochloric acid; preferably inorganic bases, with particular preference barium hydroxide [Ba(OH)2] and sodium hydroxide (NaOH) and preferably biotransformations, with particular preference using acylases. 15 In the case of N-deacylation by means of biotransformations, the compounds of the formulae (II), (IV), and (Il-a) are obtained with one of the two enantiomers in excess. Suitable diluents when carrying out process (e) include water or alcohols and mixtures of these. Preference is given to using water, methanol or ethanol or mixtures 20 of two or three of these three diluents. The reaction temperatures when carrying out process (e) may be varied within a relatively wide range. It is normal to operate at temperatures between 20°C and 200°C, preferably between 60°C and 140°C, with particular preference between 80°C 25 and 120°C. Where the N-deacylation is carried out enzymatically using acylases, it is normal to operate between 20°C and 60°C, preferably between 20°C and 40°C. When carrying out process (e) it is normal to use 2 parts by volume of a protic acid per part by volume of a 10% strength (w/v) alcoholic solution of amide of the 30 formula (XVI). However, other ratios of the reaction components may also be Le A 35 188-Foreign Countries 43- chosen. Work-up is carried out by customary methods. In general, the reaction mixture is neutralized with sodium hydroxide solution and then extracted witfi thyl acetate and the organic phase is dried, filtered and concentrated. . Process(E) | 10 The formula (VII) provides a general definition of the ∆1-pyrrolines required as starting materials when carrying out the process (E) according to the invention. In this formula, R1, R2, A, R4 and m represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of formula (I) according to the invention. ∆1-Pyrrolines of the formula (VII) are novel. They may be prepared by 15 h) reacting ∆1-pyrrolines of the formula (I-b) (I-b) in which 20 R1, R2, A, R4, m and R7 have the meanings given above, 25 with a mineral acid (e.g. hydrochloric acid, sulphuric acid) or a base (e.g. sodium hydroxide, potassium hydroxide) where appropriate in the presence of a diluent (e.g. alcohols such as methanol, ethanol or water or mixtures of these). Le A 35 188-Foreign Countries -44- The ∆1-pyrrolines of the formula (I-b) required as starting materials when carrying out the process (h) are a subgroup of the compounds of the formula (I) according to the invention. In the formula (I-b), R1, R2, A, R4, m and R7 represent preferably, with particular preference or with very particular preference those definitions already 5 stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the formula (I) according to the invention. ∆1-Pyrrolines of the formula (I-b) may be prepared by one of the processes (A), (B), (C) or (D) according to the invention. 10 The formula (VIII) provides a general definition of the iso(thio)cyanates required as starting materials when carrying out the process (E) of the invention. In this formula, Y and R7 represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the 15 formula (I) according to the invention. Iso(thio)cyanates of the formula (VIII) are known and/or may be prepared by known processes. 20 The formula (IX) provides a general definition of the (thio)carbonates required as starting materials when carrying out the process (E) of the invention. In this formula, Y and R7 represent preferably, with particular preference or with very particular preference those definitions already stated as being preferred, particularly preferred, etc. for these radicals in connection with the description of the substances of the 25 formula (I) according to the invention. X2 represents preferably O (oxygen) or S (sulphur). (Thio)carbonates of the formula (IX) are known and/or may be prepared by known processes. 30 Le A 35 188-Foreign Countries -45 When carrying out the process (E) according to the invention, in general 1 mol or a slight excess of a compound of the formula (VIII) and/or 1 mol or a slight excess of a compound of the formula (IX) are employed per mole of compound of the formula (VII). However, it is also possible to employ the reaction components in other proportions. Work-up is carried out by customary methods. In general, the reaction mixture is taken up in ethyl acetate and the organic phase is washed with water, dried over sodium sulphate, filtered and concentrated. The residue is, if appropriate, freed from any impurities that may still be present using customary methods, such as chromatography or recrystallization. 10 Chiral compounds of the formula (I-a) To prepare chiral compounds of the formula (I-a), it is possible, for example, to 15 subject A'-pyrrolines of the formula (Il-b) (Il-b) 20 in which R1, R2, R4 and m have the meanings given above, Z4 represents chlorine, bromine or iodine to an optical resolution. To this end, for example, methods of preparative chromatography, preferably the high performance liquid chromatography (HPLC) 25 method, are employed. Here, a chiral stationary silica gel phase is used. A tris(3,5- dimethylphenylcarbamate)-cellulose-modified silica gel has been found to be particularly suitable for separating the compounds of the formula (Il-b) into the two enantiomers. This separating material is commercially available. However, it is also Le A 35 188-Foreign Countries -46- possible to use other stationary phases. Suitable mobile phases are all customary inert organic solvents, and mixtures of these. Preference is given to using optionally halogenated aliphatic, alicyclic or aromatic hydrocarbons, such as petroleum ether, hexane, heptane, cyclohexane; dichloromethane, chloroform; alcohols, such as 5 methanol, ethanol, propanol; nitriles, such as acetonitrile; esters, such as methyl acetate or ethyl acetate. Particular preference is given to using aliphatic hydro¬ carbons, such as hexane or heptane, and alcohols, such as methanol or propanol, very particularly preferably n-heptane and isopropanol or mixtures of these. In general, the separation is carried out at temperatures between 10°C and 60°C, preferably between 10 10°C and 40°C, particularly preferably at room temperature. The (Reconfigured enantiomers obtained in this manner are then used as starting materials for the processes (A), (C) or (D). When carrying out the processes (A), (B), (C) and (D) according to the invention, in 15 each case a palladium catalyst is employed, which for its part can be used with or without addition of further ligands. The catalyst used is preferably PdCl2(dppf) [dppf = l,l'-bis(diphenylphosphino)ferrocene], Pd(PPh3)4, PdCl2(PPh3)2, PdCl2(CH3CN)2, Pd2(dba)3 [dba = dibenzylideneacetone] or Pd(OAc)2, particularly preferably PdCl2(dppf), Pd(PPh3)4, PdCl2(PPh3)2 or Pd(OAc)2, very particularly 20 preferably PdCl2(dppf) or PdCl2(PPh3)2. Suitable ligands are triarylphosphines, trialkylphosphines or arsines. Preference is given to using dppf, PPh3, P(t-Bu)3, Pcy3 or AsPh3, particularly preferably dppf. 25 Suitable diluents for carrying out the processes (A), (B) and (C) according to the invention are in each case all customary inert organic solvents. Preference is given to using optionally halogenated aliphatic, alicyclic or aromatic hydrocarbons, such as petroleum ether, hexane, heptane, cyclohexane, methylcyclohexane, benzene, toluene, xylene or decalin; chlorobenzene, dichlorobenzene, dichloromethane, 30 chloroform, tetrachloromethane, dichlorethane or trichloroethane; ethers, such as diethyl ether, diisopropyl ether, methyl tert-butyl ether, methyl tert-amyl ether, Le A 35 188-Foreign Countries -47- dioxane, tetrahydrofuran, 1,2-dimethoxyethane, 1,2-diethoxyethane or anisole; nitriles, such as acetonitrile, propionitrile, n- or isobutyronitrile or benzonitrile; amides, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methylform- anilide, N-methylpyrrolidone or hexamethylphosphoric triamide; esters, such as 5 methyl acetate or ethyl acetate, sulphoxides, such as dimethyl sulphoxide, or sulphones, such as sulpholane. Particular preference is given to using acetone, di-methoxyethane, dioxane, tetrahydrofuran, dimethylformamide, dimethylacetamide, dimethyl sulphoxide, ethanol, toluene or, if appropriate, mixtures of the diluents mentioned with water. 10 Suitable diluents for carrying out the processes (D) and (E) according to the invention are in each case all customary inert organic solvents. Preference is given to using optionally halogenated aliphatic, alicyclic or aromatic hydrocarbons, such as petroleum ether, hexane, heptane, cyclohexane, methylcyclohexane, benzene, 15 toluene, xylene or decaline; chlorobenzene, dichlorobenzene, dichloromethane, chloroform, carbon tetrachloride, dichlorethane or trichloroethane; ethers, such as diethyl ether, diisopropyl ether, methyl tert-butyl ether, methyl tert-amyl ether, dioxane, tetrahydrofuran, 1,2-dimethoxyethane, 1,2-diethoxyethane or anisole. Particular preference when carrying out process (D) according to the invention is 20 given to using dioxane, tetrahydrofuran or toluene. Suitable acid binders for carrying out the processes (A), (B), (C) and (D) according to the invention are in each case all inorganic and organic bases which are customary for such reactions. Preference is given to using alkaline earth metal or alkali metal 25 hydroxides, such as sodium hydroxide, calcium hydroxide, potassium hydroxide, or else ammonium hydroxide, alkali metal carbonates, such as sodium carbonate, potassium carbonate, potassium bicarbonate, sodium bicarbonate, alkali metal or alkaline earth metal acetates, such as sodium acetate, potassium acetate, calcium acetate, alkali metal fluorides, and also tertiary amines, such as trimethylamine, 30 triethylamine, tributylamine, N,N-dimethylaniline, pyridine, N-methylpiperidine, N,N-dimethylaminopyridine, diazabicyclooctane (DABCO), diazabicyclononene Le A 35 188-Foreign Countries -48- (DBN) or diazabicycloundecene (DBU). However, it is also possible to operate without additional acid binder, or to employ an excess of the amine component so that it simultaneously acts as acid binder. Barium hydroxide, sodium hydroxide potassium hydroxide, tripotassium phosphate, caesium carbonate, potassium 5 carbonate, sodium carbonate, potassium acetate, triethylamine, potassium tert- butoxide, caesium fluoride or potassium fluoride are used with particular preference. Suitable acid binders for carrying out the process (E) according to the invention are in each case all inorganic and organic bases which are customary for such reactions. 10 Preference is given to using alkali metal carbonates, such as sodium carbonate, potassium carbonate, potassium bicarbonate, sodium bicarbonate, and also tertiary amines, such as trimethylamine, triethylamine, tributylamine, N,N-dimethylaniline, pyridine, N-methylpiperidine, N,N-dimethylaminopyridine, diazabicyclooctane (DABCO), diazabicyclononene (DBN) or diazabicycloundecene (DBU). However, it 15 is also possible to operate without additional acid binder. When carrying out the processes (A), (B) and (C) according to the invention, the reaction temperatures can in each case be varied within a relatively wide range. In general, the reactions are carried out at temperatures between 0oC and 140°C, 20 preferably between 20°C and 120°C, particularly preferably between 60°C and 100°C. When carrying out the process (D) according to the invention, the reaction temperatures can in each case be varied within a relatively wide range. In general, the 25 reaction is carried out at temperatures between 0°C and 140°C, preferably between 20°C and 120°C. When carrying out the process (E) according to the invention, the reaction temperatures can in each case be varied within a relatively wide range. In general, the 30 reaction is carried out at temperatures between 0°C and 100°C, preferably between 20°C and 50°C. Le A 35 188-Foreign Countries -49- All process according to the invention are genrerally carried out under atmospheric *■ *. pressure. However, in each case it is also possible to operate under elevated or reduced pressure. 5 The active compounds according to the invention are suitable for controlling animal pests, in particular insects, arachnids and nematodes, which are encountered in agriculture, in forestry, in the protection of stored products and of materials, and in the hygiene sector, and have good plant tolerance and favourable toxicity to warm-blooded animals. They may be preferably employed as plant protection agents. They are active 10 against normally sensitive and resistant species and against all or some stages of development. The abovementioned pests include: From the order of the Isopoda, for example, Oniscus asellus, Armadillidium vulgare and Porcellio scaber. 15 From the order of the Diplopoda, for example, Blaniulus guttulatus. From the order of the Chilopoda, for example, Geophilus carpophagus and Scutigera spp. From the order of the Symphyla, for example, Scutigerella immaculata. From the order of the Thysanura, for example, Lepisma saccharina. 20 From the order of the Collembola, for example, Onychiurus armatus. From the order of the Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp. and Schistocerca gregaria. From the order of the Blattaria, for example, Blatta orientalis, Periplaneta americana, Leucophaea maderae and Blattella germanica. 25 From the order of the Dermaptera, for example, Forficula auricularia. From the order of the Isoptera, for example, Reticulitermes spp. From the order of the Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp. and Damalinia spp. From the order of the Thysanoptera, for example, Hercinothrips femoralis, Thrips 30 tabaci, Thrips palmi and Frankliniella accidentalis. Le A 35 188-Foreign Countries -50- From the order of the Heteroptera, for example, Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus and Triatornaspp. From the order of the Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, ' Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae,Cryptomyzus ribiS, . 5 Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera. vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli; Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidielia aurantii, Aspidiotus hederae, Pseudococcus spp. and Psylla spp. 10 From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., 15 Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. 20 From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites 25 sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica and Lissorhoptrus oryzophilus. 30 From the order of the Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis and Vespa spp. Le A 35 188-Foreign Countries -51 - From the order of the Diptera, for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythropephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia sppi, Bibio hortulanus, 5 Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp. and Liriomyza spp. From the order of the Siphonaptera, for example, Xenopsylla cheopls and Ceratophyllus spp. From the class of the Arachnida, for example, Scorpio maurus, Latrodectus mactans, 10 Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp. 15 The phytoparasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp. 20 In particular, the compounds of the formula (I) according to the invention have excellent activity against caterpillars, beetle larvae, spider mites, aphids and leaf-mining flies. 25 If appropriate, the compounds according to the invention can, at certain concentrations or application rates, also be used as herbicides or microbicides, for example as fungicides, antimycotics and bactericides. If appropriate, they can also be employed as intermediates or precursors for the synthesis of other active compounds. 30 All plants and plant parts can be treated in accordance with the invention. Plants are to be understood as meaning in the present context all plants and plant populations Le A 35 188-Foreign Countries -52- such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can. be obtained fey conventional plant breeding and optimization methods or by biptechnological ,arld recombinant methods or by combinations of these methods, including the transgenic. 5 plants and including the plant cultivars protectable or not protectable by plant breeders' rights. Plant parts are to be understood as meaning all parts and organs of plants above and below the ground, such as shoot, leaf, flower arid root, examples which may be mentioned being leaves, needles, stalks, stems, flowers, fruit bodies, fruits, seeds, roots, tubers and rhizomes. The plant parts also include harvested 10 material, and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offsets and seeds. Treatment according to the invention of the plants and plant parts with the active compounds is carried out directly or by allowing the compounds to act on their 15 surroundings, environment or storage space by the customary treatment methods, for example by immersion, spraying, evaporation, fogging, scattering, painting on and, in the case of propagation material, in particular in the case of seeds, also by applying one or more coats. 20 The active compounds according to the invention can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with active compound and microencapsulations in polymeric substances. 25 These formulations are produced in a known manner, for example by mixing the active compounds according to the invention with extenders, that is liquid solvents and/or solid carriers, optionally with the use of surfactants, that is emulsifiers and/or dispersants and/or foam-formers. 30 Le A 35 188-Foreign Countries -53- If the extender used is water, it is also possible to employ for example organic .solvents as auxiliary solvents. Essentially, suitable liquid solvents are: aromatics-such as xyiene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphantiic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene, chloride, aliphatic 5 hydrocarbons such as cyclohexane or paraffins, for example petrojeum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and also their ethers' and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulphoxide, and also water. 10 Suitable solid carriers are: for example ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly disperse silica, alumina and silicates; suitable solid carriers for 15 granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, and also synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; 20 suitable emulsifiers and/or foam-formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates and also protein hydrolysates; 25 suitable dispersants are: for example lignosulphite waste liquors and methylcellulose. Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins, and 30 synthetic phospholipids, can be used in the formulations. Other additives can be mineral and vegetable oils. Le A 35 188-Foreign Countries -54- It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron manganese, boron, copper, cobalt, molybdenum and zinc. 5 The formulations generally comprise between 0.1 and 95% by -weight of active compound, preferably between 0.5 and 90%. The active compounds according to the invention can be used in customary commerical form or in their formulations as a mixture with other active compounds, such as 10 insecticides, attractants, sterilizing agents, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides. The insecticides include, for example, phosphoric acid esters, carbamates, carboxylates, chlorinated hydrocarbons, phenylureas and substances produced by microorganisms, inter alia. 15 Particularly advantageous co-components are, for example, the following: Fungicides: aldimorph, ampropylfos, ampropylfos-potassium, andoprim, anilazine, azaconazole, azoxystrobin, benalaxyl, benodanil, benomyl, benzamacril, benzamacryl-isobutyl, bialaphos, 20 binapacryl, biphenyl, bitertanol, blasticidin-S, bromuconazole, bupirimate, buthiobate, calcium polysulphide, capsimycin, captafol, captan, carbendazim, carboxin, carvon, quinomethionate, chlobenthiazone, chlorfenazole, chloroneb, chloropicrin, chlorothalonil, chlozolinate, clozylacon, cufraneb, cymoxanil, cyproconazole, cyprodinil, cyprofuram, 25 debacarb, dichlorophen, diclobutrazole, diclofluanid, diclomezine, dicloran, diethofencarb, difenoconazole, dimethirimol, dimethomorph, diniconazole, diniconazole-M, dinocap, diphenylamine, dipyrithione, ditalimfos, dithianon, dodemorph, dodine, drazoxolon, edifenphos, epoxiconazole, etaconazole, ethirimol, etridiazole, 30 famoxadon, fenapanil, fenarimol, fenbuconazole, fenfuram, fenitropan, fenpiclonil, fenpropidin, fenpropimorph, fentin acetate, fentin hydroxide, ferbam, ferimzone, Le A 35 188-Foreign Countries -55- fluazinam, flumetover, fluoromide, fluquinconazole, flurprimidol, flusilazole, flusulphamide, flutolanil, flutriafol, folpet, fosetyl-aluminium, fosetyl-sodium,fthalide, fuberidazole, furalaxyl, furametpyr, furcarbonil, furconazole, furconazole-cis, furmecyclox, guazatine, hexachlorobenzene, hexaconazole, hymexazole, • - 5 imazalil, imibenconazole, iminoctadine, iminoctadine albesilate, iminoctadine triacetate, iodocarb, ipconazole, iprobenfos (IBP), iprodione, irumamycin, isoprothiolane, isovaledione, kasugamycin, kresoxim-methyl, copper preparations, such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulphate, copper oxide, oxine-copper 10 and Bordeaux mixture, mancopper, mancozeb, maneb, meferimzone, mepanipyrim, mepronil, metalaxyl, metconazole, methasulfocarb, methfuroxam, metiram, metomeclam, metsulfovax, mildiomycin, myclobutanil, myclozolin, nickel dimethyldithiocarbamate, nitrothal-isopropyl, nuarimol, 15 ofurace, oxadixyl, oxamocarb, oxolinic acid, oxycarboxim, oxyfenthiin, paclobutrazole, pefurazoate, penconazole, pencycuron, phosdiphen, pimaricin, piperalin, polyoxin, polyoxorim, probenazole, prochloraz, procymidone, propamocarb, propanosine-sodium, propiconazole, propineb, pyrazophos, pyrifenox, pyrimethanil, pyroquilon, pyroxyfur, 20 quinconazole, quintozene (PCNB), sulphur and sulphur preparations, tebuconazole, tecloftalam, tecnazene, tetcyclacis, tetraconazole, thiabendazole, thicyofen, thifluzamide, thiophanate-methyl, thiram, tioxymid, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazbutil, triazoxide, trichlamide, tricyclazole, 25 tridemorph, triflumizole, triforine, triticonazole, uniconazole, validamycin A, vinclozolin, viniconazole, zarilamide, zineb, ziram and also Dagger G, OK-8705, OK-8801, 30 a-(l, 1 -dimethylethyl)-p-(2-phenoxyethyl)-1H-1,2,4-triazole-1 -ethanol, a-(2,4-dichlorophenyl)-p-fluoro-p-propyl-1H-1,2,4-triazole-1-ethanol, Le A 35 188-Foreign Countries -56 a-(2,4-dichlorophenyl)-p-methoxy-a-methyl-1H-1,2,4-triazole-1 -ethanol, a-(5-methyl-1,3-dioxan-5-yl)-β-[[4-(trifluoromethyl)-phenyl]-methyIene]- 1H-1,2,4- a triazole-1-ethanol, (5RS,6RS)-6-hydroxy-2,2,7,7-tetramethyl-5-(lH-l,2,4-triazol-1-yl)3-octanone, .. 5 (E)-a-(methoxyimino)-N-methyl-2-phenoxy-phenylacetamide, 1 -isopropyl {2-methyl-1 -[[[ 1 -(4-methylphenyl)-ethyl]-amino]-carbonyl]-prppyl} - carbamate, 1 -(2,4-dichlorophenyl)-2-( 1H-1,2,4-triazol-1 -yl)-ethanone-0-(phenylmethyl)-oxime, 1 -(2-methyl-1 -naphthalenyl)-1 H-pyrrole-2,5-dione, 10 1 -(3,5-dichlorophenyl)-3-(2-propenyl)-2,5-pyrrolidinedione, l-[(diiodomethyl)-sulphonyl]-4-methyl-benzene, l-[[2-(2,4-dichlorophenyl)-l,3-dioxolan-2-yl]-methyl]-lH-imidazole, l-[[2-(4-chlorophenyl)-3-phenyloxiranyl]-methyl]-lH-l,2,4-triazole, 1 -[1 -[2-[(2,4-dichlorophenyl)-rnethoxy]-phenyl]-ethenyl]-1 H-imidazole, 15 1 -methyl-5-nonyl-2-(phenylmethyl)-3-pyrrolidinole, 2',6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoro-methyl-l,3-thiazole-5- carboxanilide, 2,2-dichloro-N-[l-(4-chlorophenyl)-ethyl]-l-ethyl-3-methyl-cyclopropanecarboxamide, 2,6-dichloro-5-(methylthio)-4-pyrimidinyl-thiocyanate, 20 2,6-dichloro-N-(4-trifluoromethylbenzyl)-benzamide, 2,6-dichloro-N-[[4-(trifluoromethyl)-phenyl]-methyl]-benzamide, 2-(2,3,3-triiodo-2-propenyl)-2H-tetrazole, 2-[(l-methylethyl)-sulphonyl]-5-(trichloromethyl)-l,3,4-thiadiazole, 2-[[6-deoxy-4-0-(4-0-methyl-p-D-glycopyranosyl)-a-D-glucopyranosyl]-amino]-4- 25 methoxy-1 H-pyrrolo[2,3-d]pyrimidine-5-carbonitrile, 2-aminobutane, 2-bromo-2-(bromomethyl)-pentanedinitrile, 2-chloro-N-(2,3-dihydro-1,1,3-trimethyl-1 H-inden-4-yl)-3-pyridinecarboxamide, 2-chloro-N-(2,6-dimethylphenyl)-N-(isothiocyanatomethyl)-acetamide, 30 2-phenylphenol (OPP), 3,4-dichloro-l-[4-(difluoromethoxy)-phenyl]-lH-pyrrole-2,5-dione, Le A 35 188-Foreign Countries -57- 3,5-dichloro-N-[cyano[(l-methyl-2-propynyl)-oxy]-methyl]-benzamide, 3-( 1,1 -dimethylpropyl-1 -oxo-1 H-indene-2-carbonitrile, 3-[2-(4-chIorophenyl)-5-ethoxy-3-isoxazolidinyl]-pyridine, 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1 H-imidazole- 1-sulphonamide, 5 4-methyl-tetrazolo[l,5-a]quinazolin-5(4H)-one, 8-(l,l-dimethylethyl)-N-ethyl-N-propyl-l,4-dioxaspiro[4.5]decanei2-methanamine, 8-hydroxyquinoline sulphate, 9H-xanthene-2-[(phenylamino)-carbonyl]-9-carboxylic hydrazide, bis-(l-methylethyl)-3-methyl-4-[(3-methylbenzoyl)-oxy]-2,5-thiophenedicarboxylate, 10 cis-1 -(4-chlorophenyl)-2-( 1H-1,2,4-triazol-1 -yl)-cycloheptanol, cis-4-[3-[4-(l, 1 -dimethylpropyl)-phenyl-2-methylpropyl]-2,6-dimethyl-morpholine hydrochloride, ethyl [(4-chlorophenyl)-azo] -cyanoacetate, potassium bicarbonate, 15 methanetetrathiol-sodium salt, methyl 1 -(2,3 -dihydro-2,2-dimethyl-1 H-inden-1 -yl)-1 H-imidazole-5-carboxylate, methyl N-(2,6-dimethylphenyl)-N-(5-isoxazolylcarbonyl)-DL-alaninate, methyl N-(chloroacetyl)-N-(2,6-dimethylphenyl)-DL-alaninate, N-(2,3 -dichloro-4-hydroxyphenyl)-1 -methyl-cyclohexanecarboxamide, 20 N-(2,6-dimethylphenyl)-2-methoxy-N-(tetrahydro-2-oxo-3-furanyl)-acetamide, N-(2,6-dimethylphenyl)-2-methoxy-N-(tetrahydro-2-oxo-3-thienyl)-acetamide, N-(2-chloro-4-nitrophenyl)-4-methyl-3-nitro-benzenesulphonamide, N-(4-cyclohexylphenyl)-1,4,5,6-tetrahydro-2-pyrimidinamine, N-(4-hexylphenyl)-1,4,5,6-tetrahydro-2-pyrimidinamine, 25 N-(5-chloro-2-methylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)-acetamide, N-(6-methoxy-3-pyridinyl)-cycIopropanecarboxamide, N-[2,2,2-trichloro-1 -[(chloroacetyl)-amino]-ethyl]-benzamide, N-[3-chloro-4,5-bis(2-propinyloxy)-phenyl]-N'-methoxy-methanimidamide, N-formyl-N-hydroxy-DL-alanine-sodium salt, 3 0 0,0-diethyl [2-(dipropylamino)-2-oxoethyl]-ethylphosphoramidothioate, O-methyl S-phenyl phenylpropylphosphoramidothioate, Le A 35 188-Foreign Countries -58- S-methyl 1,2,3-benzothiadiazole-7-carbothioate, spiro[2H]-l-benzopyran-2,r(3'H)-isobenzofuran-3'-one , Bactericides: 5 bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbarhate,. kasugamycin, octhilinone, furancarboxylic acid, oxytetracyclin, probenazole, streptomycin, tecloftalam, copper sulphate and other copper preparations. Insecticides / acaricides / nematicides: 10 abamectin, acephate, acetamiprid, acrinathrin, alanycarb, aldicarb, aldoxycarb, alpha- cypermethrin, alphamethrin, amitraz, avermectin, AZ 60541, azadirachtin, azamethiphos, azinphos A, azinphos M, azocyclotin, Bacillus popilliae, Bacillus sphaericus, Bacillus subtilis, Bacillus thuringiensis, baculoviruses, Beauveria bassiana, Beauveria tenella, bendiocarb, benfuracarb, 15 bensultap, benzoximate, betacyfluthrin, bifenazate, bifenthrin, bioethanomethrin, biopermefhrin, BPMC, bromophosA, bufencarb, buprofezin, butathiofos, butocarboxim, butylpyridaben, cadusafos, carbaryl, carbofuran, carbophenothion, carbosulphan, cartap, chloethocarb, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, 20 chlormephos, chlorpyrifos, chlorpyrifos M, chlovaporthrin, cis-resmethrin, cispermethrin, clocythrin, cloethocarb, clofentezine, cyanophos, cycloprene, cycloprothrin, cyfluthrin, cyhalothrin, cyhexatin, cypermethrin, cyromazine, deltamethrin, demeton M, demeton S, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, diflubenzuron, dimethoate, dimethylvinphos, diofenolan, disulfoton, 25 docusat-sodium, dofenapyn, eflusilanate, emamectin, empenthrin, endosulfan, Entomopfthora spp., eprinomectin, esfenvalerate, ethiofencarb, ethion, ethoprophos, etofenprox, etoxazole, etrimfos, fenamiphos, fenazaquin, fenbutatin oxide, fenitrothion, fenothiocarb, fenoxacrim, fenoxycarb, fenpropathrin, fenpyrad, fenpyrithrin, fenpyroximate. fenvalerate, 30 fipronil, fluazuron, flubrocythrinate, flucycloxuron, flucythrinate, flufenoxuron, flutenzine, fluvalinate, fonophos, fosmethilan, fosthiazate, fubfenprox, furathiocarb, Le A 35 188-Foreign Countries -59- granulosis viruses, halofenozide, HCH, heptenophos, hexaflumuron, hexythiazox, hydroprene, imidacloprid, isazofos, isofenphos, isoxathion, ivermectin, nuclear polyhedrosis viruses, 5 lambda-cyhalothrin, lufenuron, malathion, mecarbam, metaldehyde, methamidophos, Metharhizium anisopliae, Metharhizium flavoviride, methidathion, methiocarb, methomyl, methoxyfenozide, metolcarb, metoxadiazone, mevinphos, milbemectin, monocrotophos, naled, nitenpyram, nithiazine, novaluron, 10 omethoate, oxamyl, oxydemethon M, Paecilomyces fumosoroseus, parathion A, parathion M, permethrin, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimicarb, pirimiphos A, pirimiphos M, profenofos, promecarb, propoxur, prothiofos, prothoate, pymetrozine, pyraclofos, pyresmethrin, pyrethrum, pyridaben, pyridathion, pyrimidifen, 15 pyriproxyfen, quinalphos, ribavirin, salithion, sebufos, selamectin, silafluofen, spinosad, sulphotep, sulprofos, tau-fluvalinate, tebufenozide, tebufenpyrad, tebupirimiphos, teflubenzuron, 20 tefluthrin, temephos, temivinphos, terbufos, tetrachlorvinphos, theta-cypermethrin, thiamethoxam, thiapronil, thiatriphos, thiocyclam hydrogen oxalate, thiodicarb, thiofanox, thuringiensin, tralocythrin, tralomethrin, triarathene, triazamate, triazophos, triazuron, trichlophenidine, trichlorfon, triflumuron, trimethacarb, vamidothion, vaniliprole, Verticillium lecanii, 25 YI 5302, zeta-cypermethrin, zolaprofos, (lR-cis)-[5-(phenylmethyl)-3-furanyl]-methyl-3-[(dihydro-2-oxo-3(2H)-furanylidene)-methyl]-2,2-dimethylcyclopropanecarboxylate, (3-phenoxyphenyl)-methyl-2,2,3,3-tetramethylcyclopropanecarboxylate, 30 1 -[(2-chloro-5-thiazolyl)methyl]tetrahydro-3,5-dimethyl-N-nitro-l ,3,5-triazine- 2(lH)-imine, Le A 35 188-Foreign Countries -60- 2-(2-chloro-6-fluorophenyl)-4-[4-(l,l-dimethylethyl)phenyl]-4,5-dihydro-oxazole, 2-(acetyloxy)-3-dodecyl-l,4-naphthalenedione, 2-chloro-N-[[[4-(l-phenylethoxy)-phenyl]-amino]-carbonyl]-benz^nide, 2-chloro-N-[[[4-(2,2-dichloro-1,1 -difluoroethoxy)-phenyl]-amino]-carbonyl]- 5 benzamide, 3-methylphenyl propylcarbamate. 4- [4-(4-ethoxyphenyl)-4-methylpenty 1]-1 -fluoro-2-phenoxy-benzefte, 4-chloro-2-(l, 1 -dimethylethyl)-5-[[2-(2,6-dimethyl-4-phenoxyphenoxy)ethyl]thio]-3 (2H)-pyridazinone, 10 4-chloro-2-(2-chloro-2-methylpropyl)-5-[(6-iodo-3-pyridinyl)methoxy]-3(2H)- pyridazinone, 4-chloro-5 - [(6-chloro-3 -pyridinyl)methoxy]-2-(3,4-dichlorophenyl)-3 (2H)-pyridazinone, Bacillus thuringiensis strain EG-2348, 15 [2-benzoyl-1 -(1,1 -dimethylethyl)-hydrazinobenzoic acid, 2,2-dimethyl-3-(2,4-dichlorophenyl)-2-oxo-1 -oxaspiro[4.5]dec-3-en-4-yl butanoate, [3 - [(6-chloro-3 -pyridinyl)methyl]-2-thiazolidinylidene]-cyanamide, dihydro-2-(nitromethylene)-2H-1,3 -thiazine-3 (4H)-carboxaldehyde, ethyl [2-[[l,6-dihydro-6-oxo-l-(phenylmethyl)-4-pyridazinyl]oxy]ethyl]-carbamate, 20 N-(3,4,4-trifluoro-1 -oxo-3 -buteny l)-glycine, N-(4-chlorophenyl)-3-[4-(difluoromethoxy)phenyl]-4,5-dihydro-4-phenyl-lH-pyrazole-1 -carboxamide, N-[(2-chloro-5-thiazolyl)methyl]-N'-methyl-N"-nitro-guanidine, N-methyl-N' -(1 -methyl-2-propenyl)-1,2-hydrazinedicarbothioamide, 25 N-methyl-N'-2-propenyl-1,2-hydrazinedicarbothioamide, 0,0-diethyl [2-(dipropylamino)-2-oxoethyl]-ethylphosphoramidothioate It is also possible to admix other known active compounds, such as herbicides, fertilizers and growth regulators. 30 Le A 35 188-Foreign Countries -61- When used as insecticides, the active compounds according to the invention, can furthermore be present in their commercially available formulations and in the use forms, prepared from these formulations, as a mixture with synergistic agents. Syner- gistic agents are compounds which increase the action of the active compounds 5 according to the invention, without it being necessary for the synergistic agent added to be active itself. The active compound content of the use forms prepared from the commercially available formulations can vary within wide limits. The active compound concen- 10 tration of the use forms can be from 0.0000001 to 95% by weight of active com- pound, preferably between 0.0001 and 1% by weight. The compounds are employed in a customary manner appropriate for the use forms. 15 When used against hygiene pests and pests of stored products, the active compound is distinguished by an excellent residual action on wood and clay as well as a good stability to alkali on limed substrates. As already mentioned above, it is possible to treat all plants and their parts according 20 to the invention. In a preferred embodiment, wild plant species and plant cultivars, or those obtained by conventional biological breeding, such as crossing or protoplast fusion, and parts thereof, are treated. In a further preferred embodiment, transgenic plants and plant cultivars obtained by genetic engineering, if appropriate in combination with conventional methods (Genetically Modified Organisms), and 25 parts thereof are treated. The term "parts" or "parts of plants" or "plant parts" has been explained above. Particularly preferably, plants of the plant cultivars which are in each case commercially available or in use are treated according to the invention. 30 Le A 35 188-Foreign Countries -62- / Depending on the plant species or plant cultivars, their location, and growth conditions (soils, climate, vegetation period, diet), the treatment according to^the invention may also result in superadditive ("synergistic") effects Thus, for example; reduced application rates and/or a widening of the activity spectrum and/or an- 5 increase in the activity of the substances and compositions to be used according to the invention, better plant growth, increased tolerance to high or low tempeifatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better quality and/or a higher nutritional value of the harvested products, better storage 10 stability and/or processability of the harvested products are possible which exceed the effects which were actually to be expected. The preferred transgenic plants or plant cultivars (i.e. those obtained by genetic engineering) which are to be treated according to the invention include all plants 15 which, in the genetic modification, received genetic material which imparted particular advantageous useful properties ("traits") to these plants. Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better 20 quality and/or a higher nutritional value of the harvested products, better storage stability and/or processability of the harvested products. Further and particularly emphasized examples of such properties are a better defence of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and/or viruses, and also increased tolerance of the plants to certain 25 herbicidally active compounds. Examples of transgenic plants which may be mentioned are the important crop plants, such as cereals (wheat, rice), maize, soya beans, potatoes, cotton, oilseed rape and also fruit plants (with the fruits apples, pears, citrus fruits and grapevines), and particular emphasis is given to maize, soya beans, potatoes, cotton and oilseed rape. Traits that are emphasized are in particular 30 increased defence of the plants against insects by toxins formed in the plants, in particular those formed by the genetic material from Bacillus thuringiensis (for Le A 35 188-Foreign Countries -63- example by the genes CrylA(a), CrylA(b), CrylA(c), CryllA, CrylllAf CryfttB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and also combinations thereof) (hereinbelow referred to as "Bt plants"). Traits that are furthermore particularly emphasized are the ' increased tolerance of the plants to certain herbicidally active compounds, for 5 example imidazolinones, sulphonylureas, glyphosate or phosphinotricin (for example the "PAT" gene). The genes which impart the desired traits in question can also be present in combination with one another in the transgenic plants. Examples of "Bt plants" which may be mentioned are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD® 10 (for example maize, cotton, soya beans), KnockOut® (for example maize), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants which may be mentioned are maize varieties, cotton varieties and soya bean varieties which are sold under the trade names Roundup Ready® (tolerance to glyphosate, for example maize, cotton, 15 soya bean), Liberty Link® (tolerance to phosphinotricin, for example oilseed rape), IMI® (tolerance to imidazolinones) and STS® (tolerance to sulphonylureas, for example maize). Herbicide-resistant plants (plants bred in a conventional manner for herbicide tolerance) which may be mentioned include the varieties sold under the name Clearfield® (for example maize). Of course, these statements also apply to 20 plant cultivars having these or still to be developed genetic traits, which plants will be developed and/or marketed in the future. The plants listed can be treated according to the invention in a particularly advantageous manner with the compounds of the general formula (I) or the active 25 compound mixtures according to the invention. The preferred ranges stated above for the active compounds or mixtures also apply to the treatment of these plants. Particular emphasis is given to the treatment of plants with the compounds or the mixtures specifically mentioned in the present text. 30 The active compounds according to the invention act not only against plant, hygiene and stored product pests, but also in the veterinary medicine sector against animal Le A 35 188-Foreign Countries -64- parasites (ectoparasites), such as hard ticks, soft ticks, mange mites leaf mites.flies (biting and licking), parasitic fly larvae, lice, hair lice, feather lice and fleas. .These parasites include: 5 From the order of the Anoplurida, for example, Haematopinus spp., Linognath^us spp., Pediculus spp., PhtiruS spp. and Solenopotes spp. From the order of the Mallophagida and the suborders Amblycerina and Ischnocerina, for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola 10 spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp. and Felicola spp. From the order of the Diptera and the suborders Nematocerina and Brachycerina, for example, Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., 15 Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp. and Mdophagus spp. 20 From the order of the Siphonapterida, for example, Pulex spp., Ctenocephalides spp., Xenopsylla spp. and Ceratophyllus spp. From the order of the Heteropterida, for example, Cimex spp., Triatoma spp., 25 Rhodnius spp. and Panstrongylus spp. From the order of the Blattarida, for example, Blatta orientalis, Periplaneta americana, Blattella germanica and Supella spp. 30 From the subclass of the Acaria (Acarida) and the orders of the Meta- and Mesostigmata, for example, Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Le A 35 188-Foreign Countries -65- Amblyomma spp., Boophilus spp., Dermacentor spp., HaemophysaK^ epp., Hyalomma spp., Rhipicephalus spp., Dermanyssus sppf., Raillietia spp., Pneumonyssus spp., Sternostoma spp. and Varroa spp. 5 From the order of the Actinedida (Prostigmata) und Acaridida (Astigmata), .For example, Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobla"spp,*, Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., 10 Knemidocoptes spp., Cytodites spp. and Laminosioptes spp. They have, for example, excellent activity against the development stages of ticks such as, for example, Amblyomma hebraeum, against parasitic flies such as, for example, Lucilia cuprina and against fleas such as, for example, Ctenocephalides 15 felis. The active compounds of the formula (I) according to the invention are also suitable for controlling arthropods which infest agricultural productive livestock, such as, for example, cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, 20 chickens, turkeys, ducks, geese and bees, other pets, such as, for example, dogs, cats, caged birds and aquarium fish, and also so-called test animals, such as, for example, hamsters, guinea pigs, rats and mice. By controlling these arthropods, cases of death and reduction in productivity (for meat, milk, wool, hides, eggs, honey etc.) should be diminished, so that more economic and easier animal husbandry is possible by use 25 of the active compounds according to the invention. The active compounds according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, potions, drenches, granules, pastes, boluses, the feed-through process and 30 suppositories, by parenteral administration, such as, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants, by Le A 35 188-Foreign Countries -66- •■ ' \. •• * nasal administration, by dermal use in the form, for example, of dipping or bathing, , spraying, pouring on and spotting on, washing and powdering, and also ,with the aid -• i of moulded articles containing the active compound, such as collars, ear marks, tail marks, limb bands, halters, marking devices and the like. 5 ■' y. When used for cattle, poultry, pets and the like, the active compounds of the formula (I) according to the invention can be used as formulations (for example powders, emulsions, free-flowing compositions), which comprise the active compounds according to the invention in an amount of 1 to 80% by weight, directly or after 100 10 to 10 000-fold dilution, or they can be used as a chemical bath. It has furthermore been found that the compounds according to the invention have a strong insecticidal action against insects which destroy industrial materials. The following insects may be mentioned as examples and as preferred - but without a 15 limitation: Beetles, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticomis, Dendrobium pertinex, Ernobius mollis, Priobium 20 carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec, Tryptodendron spec, Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec, Dinoderus minutus. 25 Hymenopterons, such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Termites, such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes 30 flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. Le A 35 188-Foreign Countries -67- Bristletails, such as Lepisma saccanna. Industrial materials in the present connection are to be understood-as- meaning non¬ living materials, such as, preferably, plastics, adhesives, sizes, papers and cards* 5 leather, wood and processed wood products and coating compositions. Wood and processed wood products are materials to be protected, especially preferably, from insect infestation. Wood and processed wood products which can be protected by the agents according 10 to the invention or mixtures comprising these are to be understood as meaning, for example: building timber, wooden beams, railway sleepers, bridge components, boat jetties, wooden vehicles, boxes, pallets, containers, telegraph poles, wood panelling, wooden 15 window frames and doors, plywood, chipboard, joinery or wooden products which are used quite generally in house-building or in building joinery. The active compounds according to the invention can be used as such, in the form of concentrates or in generally customary formulations, such as powders, granules, 20 solutions, suspensions, emulsions or pastes. The formulations mentioned can be prepared in a manner known per se, for example by mixing the active compounds according to the invention with at least one solvent or diluent, emulsifier, dispersing agent and/or binder or fixing agent, a water 25 repellent, if appropriate siccatives and UV stabilizers and if appropriate dyestuffs and pigments, and also other processing auxiliaries. The insecticidal compositions or concentrates used for the preservation of wood and wood-derived timber products comprise the active compound according to the 30 invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight. Le A 35 188-Foreign Countries -68- The amount of the compositions or concentrates employed depends on the nature and occurrence of the insects and on the medium. The optimum amount employed can be determined for the use in each case by series of tests. In general, 'howe*v§r,',it is sufficient to employ 0.0001 to 20% by weight, preferably 0.001 jib 10% by weight, :of 5 the active compound, based on the material to be preserved. Solvents and/or diluents which are used are an organic chemical solvent or solvent mixture and/or an oily or oil-like organic chemical solvent or solvent mixtureof low volatility and/or a polar organic chemical solvent or solvent mixture and/or water, 10 and if appropriate an emulsifier and/or wetting agent. Organic chemical solvents which are preferably used are oily or oil-like solvents having an evaporation number above 35 and a flashpoint above 30°C, preferably above 45°C. Substances which are used as such oily or oil-like water-insoluble 15 solvents of low volatility are appropriate mineral oils or aromatic fractions thereof, or solvent mixtures containing mineral oils, preferably white spirit, petroleum and/or alkylbenzene. Mineral oils having a boiling range from 170 to 220°C, white spirit having a boiling 20 range from 170 to 220°C, spindle oil having a boiling range from 250 to 350°C, petroleum and aromatics having a boiling range from 160 to 280°C, terpentine oil and the like, are advantageously employed. In a preferred embodiment, liquid aliphatic hydrocarbons having a boiling range 25 from 180 to 210°C or high-boiling mixtures of aromatic and aliphatic hydrocarbons having a boiling range from 180 to 220°C and/or spindle oil and/or monochloronaphthalene, preferably a-monochloronaphthalene, are used. The organic oily or oil-like solvents of low volatility which have an evaporation 30 number above 35 and a flashpoint above 30°C, preferably above 45°C, can be replaced in part by organic chemical solvents of high or medium volatility, provided Le A 35 188-Foreign Countries -69- that the solvent mixture likewise has an evaporation number above 35 and a flashpoint above 30°C, preferably above 45°C, and that the insecticide/fungicide mixture is soluble or emulsifiable in this solvent mixture. 5 According to a preferred embodiment, some of the organic chemical solvent, or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent' mixture. Aliphatic organic chemical solvents containing hydroxyl and/or ester and/or ether groups, such as, for example, glycol ethers, esters or the like, are preferably used. 10 Organic chemical binders which are used in the context of the present invention are the synthetic resins and/or binding drying oils which are known per se, are water-dilutable and/or are soluble or dispersible or emulsifiable in the organic chemical solvents employed, in particular binders consisting of or comprising an acrylate 15 resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin, such as indene-coumarone resin, silicone resin, drying vegetable oils and/or drying oils and/or physically drying binders based on a natural and/or synthetic resin. 20 The synthetic resin used as the binder can be employed in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances can also be used as binders in an amount of up to 10% by weight. Dyestuffs, pigments, water-repelling agents, odour correctants and inhibitors or anticorrosive agents and the like which are known 25 per se can additionally be employed. It is preferred according to the invention for the composition or concentrate to comprise, as the organic chemical binder, at least one alkyd resin or modified alkyd resin and/or a drying vegetable oil. Alkyd resins having an oil content of more than 30 45% by weight, preferably 50 to 68% by weight, are preferably used according to the invention. Le A 35 188-Foreign Countries -70- All or some of the binder mentioned can be replaced by a fixing agent (mixture) or a plasticizer (mixture). These additives are intended to prevent evaporation of the active compounds and crystallization or precipitation. They preferably replace- 0.01 to 30% of the binder (based on 100% of the binder employed). , , The plasticizers originate from the chemical classes of phthalic acid esters, such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters, such as, tribuyl phosphate, adipic acid esters, such as di-(2-ethylhexyl) adipate, stearates, such as butyl stearate or amyl stearate, oleates, such as butyl oleate, glycerol ethers or higher 10 molecular weight glycol ethers, glycerol esters and p-toluenesulphonic acid esters. Fixing agents are based chemically on polyvinyl alkyl ethers, such as, for example, polyvinyl methyl ether or ketones, such as benzophenone or ethylenebenzophenone. 15 Possible solvents or diluents are, in particular, also water, if appropriate as a mixture with one or more of the abovementioned organic chemical solvents or diluents, emulsifiers and dispersing agents. Particularly effective preservation of wood is achieved by impregnation processes on 20 a large industrial scale, for example vacuum, double vacuum or pressure processes. The ready-to-use compositions can also comprise other insecticides, if appropriate, and also one or more fungicides, if appropriate. 25 Possible additional mixing partners are, preferably, the insecticides and fungicides mentioned in WO 94/29 268. The compounds mentioned in this document are an explicit constituent of the present application. Especially preferred mixing partners which may be mentioned are insecticides, such 30 as chlorpyriphos, phoxim, silafluofin, alphamethrin, cyfluthrin, cypermethrin, delta- methrin, permethrin, imidacloprid, NI-25, flufenoxuron, hexaflumuron, transfluthrin, Le A 35 188-Foreign Countries 71 - * thiacloprid, methoxyfenozide and triflumuron, and also fungicides/such as epoxy-conazole, hexaconazole, azaconazole, propiconazole, tebucomzolb, cyproconazqle, metconazole, imazalil, dichlorfluanid, tolylfluanid, 34odo-2-propinyl-bufyrt carbamate, N-octyl-isothiazolin-3-one and 4,5-dichloro-N-octyli»rh;%zolin-3-on^. ^ ; The compounds according to the invention can at the same time be employed for protecting objects which come into contact with saltwater or brackish water, such as hulls, screens, nets, buildings, moorings and signalling systems, against fouling. 10 Fouling by sessile Oligochaeta, such as Serpulidae, and by shells and species from the Ledamorpha group (goose barnacles), such as various Lepas and Scalpellum species, or by species from the Balanomorpha group (acorn barnacles), such as Balanus or Pollicipes species, increases the frictional drag of ships and, as a consequence, leads to a marked increase in operation costs owing to higher energy 15 consumption and additionally frequent residence in the dry dock. Apart from fouling by algae, for example Ectocarpus sp. and Ceramium sp., fouling by sessile Entomostraka groups, which come under the generic term Cirripedia (cirriped crustaceans), is of particular importance. 20 Surprisingly, it has now been found that the compounds according to the invention, alone or in combination with other active compounds, have an outstanding antifouling action. 25 Using the compounds according to the invention, alone or in combination with other active compounds, allows the use of heavy metals such as, for example, in bis(trialkyltin) sulphides, tri-H-butyltin laurate, tri-«-butyltin chloride, copper(I) oxide, triethyltin chloride, tri-«-butyl(2-phenyl-4-chlorophenoxy)tin, tributyltin oxide, molybdenum disulphide, antimony oxide, polymeric butyl titanate, phenyl- 30 (bispyridine)-bismuth chloride, tri-w-butyltin fluoride, manganese ethylenebisthio- carbamate, zinc dimethyldithiocarbamate, zinc ethylenebisthiocarbamate, zinc salts Le A 35 188-Foreign Countries 72- and copper salts of 2-pyridinethiol 1-oxide, bisdimethyldithieabamoyJzinc ethylene-bisthiocarbamate, zinc oxide, copper(I) ethylene-bisdithicarbamate, copper thiocyanate, copper naphthenate and tributyltin halides to be dispensed with, or the concentration of these compounds to be substantially reduced. 5 If appropriate, the ready-to-use antifouling paints can additionally comprise other active compounds, preferably algicides, fungicides, herbicides, molluscicides, or other antifouHng active compounds. 10 Preferably suitable components in combinations with the antifouHng compositions according to the invention are: algicides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-l,3,5-triazine, dichlorophen, 15 diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn; fungicides such as benzo[b]thiophenecarboxylic acid cyclohexylamide S,S-dioxide, dichlofluanid, 20 fluorfolpet, 3-iodo-2-propinyl butylcarbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazole, propiconazole and tebuconazole; molluscicides such as 25 fentin acetate, metaldehyde, methiocarb, niclosamid, thiodicarb and trimethacarb; or conventional antifouHng active compounds such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatryl sulphone, 2-(N,N-dimethylthiocarbamoylthio)-5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol 1-oxide, pyridine-triphenylborane, tetrabutyldistannoxane, 2,3,5,6- 30 tetrachloro-4-(methylsulphonyl)-pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetra- methylthiuram disulphide and 2,4,6-trichlorophenylmaleimide. Le A 35 188-Foreign Countries From the order of the Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium 5 spp., Stomoxys calcitrans and Tipula paludosa. From the order of the Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella and Tineola bisselliella. From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans and Xenopsylla cheopis. 10 From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp. and Tetramorium caespitum. From the order of the Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis and Phthirus pubis. 15 From the order of the Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus and Triatoma infestans. In the field of household insecticides, they are used alone or in combination with other suitable active compounds, such as phosphoric acid esters, carbamates, 20 pyrethroids, growth regulators or active compounds from other known classes of insecticides. They are used as aerosols, unpressurized spray products, for example pump and atomizer sprays, automatic misting systems, foggers, foams, gels, evaporator 25 products with evaporator tablets made of cellulose or polymer, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-free, or passive evaporation systems, moth papers, moth bags and moth gels, as granules or dusts, in baits for spreading or in bait stations. The present invention relates to ∆1-pyrrolines of the formula (I) in which R1 represents halogen or methyl, R2 represents hydrogen or halogen, R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents arylene or 5-membered heteroarylene having 1 to 3 heteioatoms, containing 0 to 3 nitrogen atoms, 0 to 1 oxygen atom and/oi 0 to I sulphur atom, or 6-membered heteioarylene having 3 nitrogen atoms or 6-membeied heteioaiylene having 1 nitrogen atom and 1 to 2 further heteroatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms, each arylene ot heteioaiylene being optionally substituted from one to four times by identical or different substituents R5, and. Y represents O (oxygen) or S (sulphur), asd X represents O (oxygen), S (sulphur) orNR8, b) A represents pyridinylene, pyrimidinyleae, pyraaanylcne or pyridazinylene each optionally substituted once or twice by identica] or different substituents R5, and. Y represents 0 (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or c) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different substituents R5 ,and Y represents S (sulphur), and. X represents O (oxygen), or d) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical oi different substituents R5, aad Y represents O (oxygen), and X represents O (oxygen), and R4 and R5 independently of one another represent halogen, alkyl, alcoxy, alkvlthio, haloalkyl, haloalkoxy or haloalkylthio, m represents 0, I, 2, 3 or 4, R6 represents hydrogen or alkyl, R7 and R8 independently of one another represent hydrogen or represent alkyl or alkenyi each optionally substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkylcarbonyl, aJkylcarbonyloxy, alkylamino, dialkylamino, alcoxy, alkylthio, alkoxyalkoxy, haloalkoxy, haloslkylthio and halogenalkoxyalkoxy; or represent cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, saturated or unsaturated 5- to 10-membered heterocyclyl or heterocyclylalkyl each of which is optionally substituted one or more times by identical or different substitotents selected from the group consisting of halogen, alkyl, haloalkyl, aJkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylcarbonyl and alkoxycarbonyl, R6 and R7 Anther together represent alkylene optionally substituted one or more times by alkyl, or R7 and R8 further, together with the nitrogen atom to which they are attached, represent a satuiated or unsaturated 5- to 10-membeied heterocycle which may optionally contain a further heteioatom group from the series -0-, -S- and -NR9- and which may optionally be substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy and haloalkylthio, and R9 represents hydrogen, alkyl or alkenyl The present invention also relates to process for preparing compounds of formula (I) and pesticides comprising the compounds of formula (I). 0 The preparation and use of the substances according to the invention is shown in the examples below. ' ' '■' Le A 35 188-Foreign Countries From the order of the Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium 5 spp., Stomoxys calcitrans and Tipula paludosa. From the order of the Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella and Tineola bisselliella. From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans and Xenopsylla cheopis. 10 From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp. and Tetramorium caespitum. From the order of the Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis and Phthirus pubis. 15 From the order of the Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus and Triatoma infestans. In the field of household insecticides, they are used alone or in combination with other suitable active compounds, such as phosphoric acid esters, carbamates, 20 pyrethroids, growth regulators or active compounds from other known classes of insecticides. They are used as aerosols, unpressurized spray products, for example pump and atomizer sprays, automatic misting systems, foggers, foams, gels, evaporator 25 products with evaporator tablets made of cellulose or polymer, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-free, or passive evaporation systems, moth papers, moth bags and moth gels, as granules or dusts, in. baits for spreading or in bait stations. 'he present invention relates to ∆1-pyrrolines of the formula (I) in which R1 represents halogen or methyl, R2 represents hydrogen or halogen, R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents arylene or 5-membered heteroarylene having 1 to 3 heteioatoms, containing 0 to 3 nitrogen atoms, 0 to 1 oxygen atom and/or 0 to 1 sulphur atom, or 6-membered heteioarylene having 3 nhrogen atoms or 6-membered heteioarylene having 1 nitrogen atom and 1 to 2 fiuthei heteioatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms, each arylene or heteioarylene being optionally substituted from one to four times by identical or different substituents R3, and. Y represents O (oxygen) or S (sulphur),and X represents O (oxygen), S (sulphur) or NR8, b) A represents pyridinylene, pyrimidinylene, pyraziaylene or pyridozinylene each optionally substituted once or twice by identical or different substituenta R5, and Y represents O (oxygen) or S (sulphur), and; X represents S (sulphur) or NR8, or c) A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and, Y represents S (sulphur), and X represents O (oxygen), or d) A represents pyridinylene, pyrimidinylene, pyrazinylens or pyridazinylene each optionally substituted once or twice by identical or different substituents R5, and Y represents O (oxygen), and X represents O (oxygen), R4 and R5 independently of one anothei represent halogen, alky!, alkoxy, alkylthio, haloalkyl, haloalioxy or haloalkyhhio, m represents 0, 1, 2, 3 or 4, R6 represents hydrogen or alkyl, R7 and R8 i.ndependently of one another represent hydrogen or represent alkyl or alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkylcarbonyl, alkylcarbonyloxy, aikylamino, dialkylamino, aflcoxy, alkylthio, aJkoxyalkoxy, haloaikoxy, haloalkyltnio and halogenalkoxyalkoxy; or represent cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, saturated or unsaturated 5- to 10-membered heterocyclyl or heterocyclylalkyl each of which is optionally substituted one or more times by identical or different substitutents selected from the group consisting of halogen, alkyl, haloalkyl, alkoxy, haloaikoxy, alkylthio, haloalkyltnio, alkylcarbonyl and alkoxycarbonyl, R6 and R7 further together represent alkylene optionally substituted one or more times by alkyl, or R7 and R8 fuither, togethei with the nitrogen atom to which they ate attached, repiesent a saturated or unsaturated 5- to 10-membeied heterocycle which may optionally contain a fuither heteaoatom group from the series -0-, -S- and -NR9- and which may optionally be substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloaikoxy and haloalkylthio, and R9 represents hydrogen, alkyl or alkenyl The present invention also relates to process for preparing compounds of formula (I) and pesticides comprising the compounds of formula (I). ,0 The preparation and use of the substances according to the invention is shown in the examples below. Le A 35 188-Foreign Countries Preparation Examples Example 1 5-(2,6-Difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)phenyl]-3,4-dihydro-2H-pyrrole (0.96 g, 2.50 mmol) is dissolved in 10 ml of N,N-dimethylacetamide. Methyl 4-bromophenylcarbamate (III-1) (0.69 g, 10 3.00 mmol), PdCl2[dppf] (0.05 g, 0.07 mmol) and 3.75 ml of sodium carbonate solution (2 M) are added in succession and the mixture is subsequently stirred at 80°C for 16 h. It is cooled to room temperature and extracted with water/ethyl acetate and the organic phase is separated off, dried over magnesium sulphate, filtered and concentrated under reduced pressure. The crude product is purified by silica gel 15 chromatography (cyclohexane/ethyl acetate 91:9→ 80:20, each v/v). This gives 0.35 g (32% of theory) of methyl 4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H-pyrrol-2-yl]-1,1'-biphenyl-4-ylcarbamate. 20 HPLC: log P (pH 2.3) = 2.31 (purity: 93 %) log P(pH 7.5) = 3.52 Le A 35 188-Foreign Countries Example 2 5 5-(2,6-Difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3,4- dihydro-2H-pyrrole (0.96 g, 2.50 mmol) and n-propyl 4-bromophenylcarbamate (III-2) (0.77 g, 3.00 mmol) are dissolved in 10 ml of 1,2-dimethoxyethane. PdCydppf] (0.05 g, 0.07 mmol) and 3.75 ml of sodium carbonate solution (2 M) are added in succession and the mixture is subsequently stirred at 80°C for 16 h. It is 10 cooled to room temperature and extracted with water/ethyl acetate and the organic phase is separated off, dried over magnesium sulphate, filtered and concentrated under reduced pressure. The crude product is purified by silica gel chromatography (cyclohexane/ethyl acetate 20:1→ 6:1→ 2:1, each v/v). 15 This gives 0.28 g (25% of theory) of n-propyl 4'-[5-(2,6-difluorophenyl)-3,4- dihydro-2H-pyrrol-2-yl]-l,1-biphenyl-4-ylcarbamate. HPLC: log P (pH 2.3) = 3.02 (purity: 98 %) log P (pH 7.5) - 4.24 Le A 35 188-Foreign Countries Example 3 5 5-(2,6-Difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)phenyl]-3,4- dihydro-2H-pyrrole (0.96 g, 2.50 mmol) is dissolved in 20 ml of N,N-dimethylacetamide. n-Butyl 4-bromophenyl(methyl)carbamate (III-3) (0.86 g, 3.00 mmol), PdCl2[dppfJ (0.05 g, 0.07 mmol) and 3.75 ml of sodium carbonate solution (2 M) are added in succession and the mixture is subsequently stirred at 10 90°C for 16 h. It is cooled to room temperature and the reaction mixture is concentrated under reduced pressure. The residue is taken up in ethyl acetate and washed with water. The organic phase is separated off, dried over magnesium sulphate, filtered and concentrated under reduced pressure. The crude product is purified by silica gel chromatography (cyclohexane/ethyl acetate 10:1 → 6:1, each 15 v/v). This gives 0.48 g (41% of theory) of n-butyl 4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H-pyrrol-2-yl]-l,l'-biphenyl-4-yl(methyl)carbamate. 20 HPLC: log P (pH 2.3) = 3.76 (purity: 98 %) log P (pH 7.5) = 4.92 Le A 35 188-Foreign Countries Example 4 .■■;■' • 5 5-(2,6-Difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)phenyl]-3,4- dihydro-2H-pyrrole (0.96 g, 2.50 mmol) is dissolved in 20 ml of N,N-dimethylacetamide. 3-(4-Bromophenyl)-l,3-oxazolidin-2-one (III-4) (0.73 g, 3.00 mmol), PdCl2[dppf] (0.05 g, 0.07 mmol) and 3.75 ml of sodium carbonate solution (2 M) are added in succession and the mixture is subsequently stirred at 10 90°C for 16 h. It is cooled to room temperature, water is added, and the precipitate is filtered off with suction. The crude product is purified by silica gel chromatography (cyclohexane/acetone 20:1 → 10:1, each v/v). This gives 0.75 g (66% of theory) of 3-{4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H- 15 pyrrol-2-yl]-1,1' -biphenyl-4-yl} -1,3-oxazolidin-2-one. HPLC: log P (pH 2.3) = 2.13 (purity: 92 %) log P (pH 7.5) = 3.28 Le A 35 188-Foreign Countries Example 5 5 5-(2,6-Difluorophenyl)-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3,4- dihydro-2H-pyrrole (0.96 g, 2.50 mmol) and N-(4-bromophenyl)-4-morpholine-carboxamide (III-5) (0.86 g, 3.00 mmol) are dissolved in 10 ml of 1,2-dimethoxyethane. PdCl2[dppf] (0.05 g, 0.07 mmol) and 3.75 ml of sodium carbonate solution (2 M) are added in succession and the mixture is subsequently 10 stirred at 80°C for 16 h. It is cooled to room temperature and extracted with water/ethyl acetate and the organic phase is separated off, dried over magnesium sulphate, filtered and concentrated under reduced pressure. The crude product is purified by silica gel chromatography (cyclohexane/ethyl acetate 2:1→1:1, each v/v). 15 This gives 0.35 g (30% of theory) of N-{4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H-pyrrol-2-yl]-l, 1 '-biphenyl-4-yl}-4-morpholinecarboxamide. HPLC: log P (pH 2.3) = 1.87 (purity: 100 %) 20 log P (pH 7.5) = 2.96 In analogy to Examples 1 to 5 above and in accordance with the general preparation details, the compounds of the formula (I) indicated in the following table are 25 obtained. Le A 35 188-Foreign Countries (I) No. Rl R2 R4 -A-R3 log P 6 F F 2.62a) 3.85b) 7 F F 3.00a) 4.19b) 8 F F 3.32a) 4.54b) 9 F F 3.44a) 4.60b) 10 F F 3.88a) 1.68b) 11 F F 2.1 la) 12 F F 2.53a) 3.71b) Le A 35 188-Foreign Countries No. Rl R2 R4 **■ m -A-R3 logP 13 F F t * 1.7\a) 14 F F 4.36$ 3.18b) 15 F F 2.48a) 3.47b) 16 F F 3.82a> 4.77b) 17 F F 4.82b) 18 F F 3.87a> 4.89b) 19 F F 4.46a) 5.26b) 20 F F 3.63a) 21 F F 3.72a) Le A 35 188-Foreign Countries No. Rl R2 R4 -A-R3 log P 22 F F 3.98b) 23 F F 3.76 a) • 24 F F 3.76a) 25 F F 3.62a) 4.64b) 26 F F 3.01a) 4.10b) 27 F F 3.28a) 4.36b) 28 F F 5.13a) 5.97b) 29 F F 1.74a) 5.52b) 30 F F 1.37a) Le A 35 188-Foreign Countries No. Rl R2 R4m -A-R3 log P 31 F F / 3.45b) ■ 32 F F 2.52a) 3.75b) 33 F F 3.82a) 34 F F 3.70a) 4.73b) 35 F F 2.58a) 3.79b) 36 F F 3.32a) 4.52b) 37 F F 2.92a) 4.16b) 38 F F 2.40a) Le A 35 188-Foreign Countries Preparation of starting materials of the formula (III) Example (III-l) (III-l) 10 A solution of 4-bromophenyl isocyanate (3.26 g, 16.46 mmol) in 15 ml of toluene is added dropwise at room temperature to 1 ml of methanol and 20 ml of toluene and the mixture is stirred at room temperature for a further 16 hours. The reaction mixture is concentrated under reduced pressure. The crude product is purified by silica gel chromatography (cyclohexane/ethyl acetate 2:1, v/v). Le A 35 188-Foreign Countries This gives 3.65 g (88% of theory) of methyl 4-bromophenylcarbamate. HPLC: log P (pH 2.3) = 2.27 (purity: 92 %) Example (IH-2) (III-2) 1.85 ml of n-propanol is introduced in 10 ml of toluene under an argon atmosphere. 10 4-Bromophenyl isocyanate (3.26 g, 16.46 mmol) is added in portions at room temperature and the reaction mixture is stirred at room temperature for a further 16 hours. The reaction mixture is concentrated under reduced pressure. The crude product is purified by silica gel chromatography (cyclohexane/ethyl acetate 2:1, v/v). 15 This gives 4.13 g (95% of theory) of n-propyl 4-bromophenylcarbamate. HPLC: log P (pH 2.3) = 3.12 (purity: 98 %) Example (III-3) 20 (III-3) 25 N-(4-Bromophenyl)-N-methylamine (1.50 g, 8.06 mmol) is introduced in 15 ml of dichloromethane under an argon atmosphere and then N,0-bis(trimethylsilyl)-acetamide (1.97 g, 9.67 mmol) is added and the mixture is stirred at room temperature for 1 hour. It is then cooled to 0°C and butyl chloroformate (1.23 ml, Le A 35 188-Foreign Countries 9.67 mmol) is added dropwise. The mixture is warmed to room temperature and j - ■ stirred at this temperature for a further 16 hours. It is cooled again to 0.C, quenched with potassium dihydrogen phosphate/disodium hydrogen phosphatk btrffer pH 7 and extracted with dichloromethane and the organic phase is separated of washed with saturated sodium chloride solution, dried over magnesium sulphate, filtered and' concentrated under reduced pressure. This gives 1.13 g (98% of theory) of n-butyl-4-bromophenyl(methyl)carbamate. HPLC: log P (pH 2.3) = 3.88 (purity: 96 %) 10 Example (III-4) (III-4) 15 4-Bromophenyl isocyanate (2.00 g, 10.10 mmol) is introduced in 15 ml of dimethyl sulphoxide under an argon atmosphere and then dioxolan-2-one (0.89 g, 10.10 mmol) and caesium fluoride (0.15 g, 1.01 mmol) are added, whereupon a white precipitate is formed. The mixture is stirred at 140°C under argon for 2 hours. The reaction 20 mixture is cooled and poured into ice-water and the precipitate formed is filtered off with suction, dried and recrystallized from isopropanol. This gives 1.55 g (61% of theory) of 3-(4-bromophenyl)-l,3-oxazolidin-2-one. HPLC: log P (pH 2.3) = 2.02 (purity: 96 %) 25 Le A 35 188-Foreign Countries Example (III-5) (III-5) 10 1.96 ml of morpholine is introduced in 15 ml of dioxane under an argon atmosphere. At room temperature, 4-bromophenyl isocyanate (2.97 g, 15.00 mmol) is added in portions and the reaction mixture is stirred at room temperature for a further 16 hours. The crude product is subsequently filtered off with suction and isolated by silica gel chromatography (cyclohexane/ethyl acetate 2:1, v/v). This gives 3.13 g (66% of theory) of N-(4-bromophenyl)-4-morpholinecarboxamide. HPLC: log P (pH 2.3) = 1.75 (purity: 91 %) 15 Preparation of starting materials of the formula (VII) Example (VII-1) 20 (VII-1) Methyl 4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H-pyrrol-2-yl]-l,r-biphenyl-4-yl-carbamate (Example 1) (0.23 g, 0.53 mmol) is dissolved in 2 ml of ethanol. Following addition of potassium hydroxide (0.03 g, 0.53 mmol) the mixture is stirred Le A 35 188-Foreign Countries under reflux for 16 hours. The precipitate is filtered off with suction and the crude, product is purified by silica gel chromatography (cyclohexane/ethyl acetate 2:1, v\)?s This gives 0.13 g (69% of theory) of 4'-[5-(2,6-difluorophenyl)-3,4-dihydro-2H 5 pyrrol-2-yl]-l,r-biphenyl-4-amine. HPLC: log P (pH2.3)- 1.25 (purity: 97%) The logP values stated in the above tables and Preparation Examples are determined in accordance with EEC Directive 79/831 Annex V.A8 by HPLC (High Performance 10 Liquid Chromatography) using a reversed-phase column (C 18). Temperature: 43°C. In the acidic range at pH2.3 the determination takes place using 0.1% aqueous phosphoric acid and acetonitrile as the mobile phases; linear gradient from 10% acetonitrile to 90% acetonitrile. Corresponding results are marked in the tables by 15 "a)" In the neutral range at pH 7.5 the determination takes place using O.Olmolar aqueous phosphate buffer solution and acetonitrile as the mobile phases; linear gradient from 10% acetonitrile to 90% acetonitrile. Corresponding results are marked in the tables 20 by "b)" Calibration is carried out using unbranched alkan-2-ones (having 3 to 16 carbon atoms), with known logP values (the logP values determined on the basis of the retention times using linear interpolation between two successive alkanones). Le A 35 188-Foreign Countries Use examples Example A Heliothis vireseens test ■ Solvent: Emulsifier: 7 parts by weight of dimethylformamide 2 parts by weight of alkylaryl polyglycol ether 10 To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration. Soya bean shoots (Glycine max) are treated by being dipped into the preparation of 15 active compound of the desired concentration and are populated with Heliothis vireseens caterpillars whilst the leaves are still moist. 20 After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars has been killed. In this test, at an active compound concentration of 100 ppm, for example, the compounds 2 and 6-8 from the Preparation Examples exhibit a good activity of at least 95%. The test results can be seen in detail from Table A below. Le A 35 188-Foreign Countries Table A Plant-damaging insects Heliothis virescens test Active compounds Active compound Kill rate in^%' concentration in after 7d ppm Le A 35 188-Foreign Countries -92- Example B 5 Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the 10 concentrate is diluted with emulsifier-containing water to the desired concentration. Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with larvae of the mustard beetle {Phaedon cochleariae) whilst the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all beetle larvae have been killed; 0% means that none of the beetle larvae has been killed. 20 In this test, at an active compound concentration of 100 ppm, for example, the compounds 1, 2, 6, 7, 16, 18-21, 24, 25, 27, 29, 32, 35, 37 from the Preparation Examples exhibit a good activity of at least 85%. The test results can be seen in detail from Table B below. Le A 35 188-Foreign Countries Table B plant-damaging insects Phacdon larvae test Active compounds Active compound Kill rate in % concentration in after 7d ppm 1 100 100 (6) 100 100 (2) 100 100 p CH. (7) 100 100 100 100 (10) 100 100 Le A 35 188-Foreign Countries 94 Table B plant-damaging insects Phacdon larvae test Active compounds -i—=»—(■ Active compound Kill rate in concentration in after 7d ppm (11) 100 100 (12) 100 100 CH, (16) 100 100 (18) 100 100 (19) 100 100 Le A 35 188-Foreign Countries 95 Table B plant-damaging insects Phaedon larvae test Active compounds Active compbuad Kill rate in \ * centration |n after 7d ppm; . Le A 35 188-Foreign Countries 96 Table B plant-damaging insects Phaedon larvae test Active compounds Active compound Kill rate In\% concentration after 7d ppm Le A 35 188-Foreign Countries ` Example C Plutella test, sensitive strain ■ ""*■ ^ ' 5 Solvent: 7 parts by weight of dimethylformamide . To produce a suitable preparation of active compound, 1 part by weight of Active compound is mixed with the stated amounts of solvent and emulsifier, and the 10 concentrate is diluted with emulsifier-containing water to the desired concentration. Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with caterpillars of the cabbage moth (Plutella xylostella, sensitive strain) whilst the leaves are still 15 moist. After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars has been killed. 20 In this test, at an active compound concentration of 100 ppm, for example, the compounds 2, 6-8 and 23 from the Preparation Examples exhibit a good activity of at least 95%. The test results can be seen in detail from Table C below. Le A 35 188-Foreign Countries Table C plant-damaging insects Plutella test, sensitive strain Active compounds Active compound Kill rate in % • concentration in after 7d ppm (6) 100 100 (2) 100 100 o CH, JL JL (7) 100 100 o (8) 100 CH, 100 (23) 100 100 H,C CH3 * Le A 35 188-Foreign Countries Example D Plutella test, resistant strain Solvent: 7 parts by weight of dimethylformamide : 5 Emulsifier: 2 parts by weight of alkylaryl polyglycol etljeC To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, aftdfthe concentrate is diluted with emulsifier-containing water to the desired concentration. 10 Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with caterpillars of the cabbage moth (Plutella xylostella, sensitive strain) whilst the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the beetle larvae has been killed. In this test, at an active compound concentration of 100 ppm, for example, the 20 compounds 2, 6-8 and 23 from the Preparation Examples exhibit a good activity of at least 95%. The test results can be seen in detail from Table D below. Le A 35 188-Foreign Countries Table D plant-damaging insects Plutella test, resistant strain Active compounds Active compound Kill rate in.%, concentration in after 7d ppm Le A 35 188-Foreign Countries Example E Spodoptera exigua test Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the 10 concentrate is diluted with emulsifier-containing water to the desired concentration. Cabbage leaves (Brassica oleraced) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with army worm (Spodoptera exigua) caterpillars whilst the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars has been killed. In this test, at an active compound concentration of 100 ppm, for example, the 20 compounds 2, 6-8 and 23 from the Preparation Examples exhibit a good activity of at least 95%. The test results can be seen in detail from Table E below. Le A 35 188-Foreign Countries Table E plant-damaging insects Spodoptera exigua test Active compounds Active compound Kill rpte in % concentration in after ppm Le A 35 188-Foreign Countries Example F sodoptera frugiperda test Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the 10 concentrate is diluted with emulsifier-containing water to the desired concentration. Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with army worm (Spodoptera frugiperda) caterpillars whilst the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars has been killed. In this test, at an active compound concentration of 100 ppm, for example, the 20 compounds 1, 2, 4-7, 9, 10, 12, 14, 17, 18, 20-23, 25-28, 30, 31, 33, 34 and 37 from the Preparation Examples exhibit a good activity of at least 95%. The test results can be seen in detail from Table F below. Le A 35 188-Foreign Countries Table F plant-damaging insects Spodoptera frugiperda-Test Active compounds • Active compqufid Kill rate in % concentration in after 7d' ppm * .■"—*- Le A 35 188-Foreign Countries Table F plant-damaging insects Spodoptera frugiperda-Test Active compounds Active compound Kill rate in % concentration in after 7d ppm Le A 35 188-Foreign Countries Table F plant-damaging insects Spodoptera frugiperda-Test Active compounds - Active comppand Kill rate in % concentratibnrin after 7d. ppm Le A 35 188-Foreign Countries Table F plant-damaging insects Spodoptera frugiperda-Test Active compounds Active compound -'Kill rate in % concentration in after 7d Ppm A 35 188-Foreign Countries Table F plant-damaging insects Spodoptera frugiperda-Test Active compounds Active compound Kill rate in % concentration in ' after 7d ppm Le A 35 188-Foreign Countries Example G I " Tetranychus test (OP resistant/dip treatment) 5 Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the 10 concentrate is diluted with emulsifier-containing water to the desired concentration. Bean plants (Phaseolus vulgaris) which are heavily infested by all stages of the greenhouse red spider mite (Tetranychus urticae) are dipped into a preparation of active compound of the desired concentration. 15 After the desired period of time, the effect in % is determined. 100% means that all spider mites have been killed; 0% means that none of the spider mites have been killed. 20 In this test, at an active compound concentration of 100 ppm, for example, the compounds 1, 2, 4, 6, 7, 17, 19, 22-24, 26-30 und 32-35 from the Preparation Examples exhibit a good activity of at least 85%. The test results can be seen in detail from Table G below. Le A 35 188-Foreign Countries Active compounds Table G plant-damaging insects Tetranychus test (OP-resistant/dip treatment) ' Active compound. Kill rate in %t concentration in after.7d ? ppm Le A 35 188-Foreign Countries Table G plant-damaging insects / Tetranychus test (OP-resistant/dip treatment) Active compounds concentration in after 7d Active compoifrid Kill rate in ^o concentration in after 7d ppm » Le A 35 188-Foreign Countries Table G plant-damaging insects Tetranychus test (OP-resistant/dip treatment]! *'■ ".. Active compounds Active compound Kill rate in % concentration in. after 7d ppm Le A 35 188-Foreign Countries Table G plant-damaging insects Tetranychus test (OP-resistant/dip treatment) Active compounds Actiye cohipound Kill rate in % concentration in after 7d ppm Le A 35 188-Foreign Countries Example H Diabrotica balteata test (larvae in soil) Critical concentration test / soil insects - treatment of transgenic plaits 5 l . Solvent: 7 parts by weight of dimethylformamide Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active 10 compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration. The preparation of active compound is poured onto the soil. Here, the concentration 15 of the active compound in the preparation is virtually immaterial; only the amount by weight of active compound per volume unit of soil, which is stated in ppm (mg/1), matters. The soil is filled into 0.25 1 pots, and these are allowed to stand at 20°C. Immediately after the preparation, 5 pregerminated maize corns of the cultivar 20 YIELD GUARD (trade mark of Monsanto Comp., USA) are placed into each pot. After 2 days, the corresponding test insects are placed into the treated soil. After a further 7 days, the efficacy of the active compound is determined by counting the number of maize plants that have emerged (1 plant = 20% activity). Le A 35 188-Foreign Countries Example J •*', Heliothis virescens test (treatment of transgenic plants) 5 Solvent: 7 parts by weight of dimethylformamide Emulsifier: 1 part by weight of alkylaryl polyglycol ether V To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of 10 emulsifier, and the concentrate is diluted with water to the desired concentration. Soya bean shoots (Glycine max) of the cultivar Roundup Ready (trade mark of Monsanto Comp. USA) are treated by being dipped into the preparation of active compound of the desired concentration and populated with the tobacco budworm 15 caterpillar Heliothis virescens whilst the leaves are still moist. After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars has been killed. Le A 35 188-Foreign Countries Example K Test with Boophilus microplus resistant/SP-resistant Parkhurst strain s 5 Test animals: Adult satiated females Solvent: Dimethyl sulphoxide 20 mg of active compound are dissolved in 1 ml of dimethyl sulphoxide. /Lower concentrations are prepared by dilution in the same solvent. 10 The test is carried out in 5 replications. 1 ul of the solutions is injected into the abdomen, and the animals are transferred to dishes and kept in a climate-controlled room. After 7 days, activity is checked by examination for deposition of fertile eggs. Eggs whose fertility is not externally visible are stored in glass tubes in a controlled- 15 environment cabinet until the larvae have hatched. An activity of 100% denotes that none of the ticks has laid fertile eggs. In this test, for example, the following compounds from the Preparation Examples exhibit very good activity: JLe A 35 188-Foreign Countries Table K Test with Boophilus microplus resistant/SP-resistant Parkliurst strain Active compounds Concentration in Activity/ (ig/animal ; kill in % Le A 35 188-Foreign Countries -Example L Test with flies (Musca domestica) ( \ * | . 5 Test animals: Adult Musca domestica, Reichswald strain (OP, SF carbamate-resistant) _ . . Solvent: Dimethyl sulphoxide 20 mg of active compound are dissolved in 1 ml dimethyl sulphoxide. Lower 10 concentrations are prepared by dilution with distilled water. 2 ml of this active compound preparation are pipetted on filter paper discs (0 9.5 cm) in Petri dishes of corresponding dimensions. After the filter discs have been dried, 25 test animals are transferred to the Petri dishes, which are then covered. 15 After 1, 3, 5, 24 and 48 hours the activity of the active compound preparation is measured. 100% means that all flies have been killed, 0% means that no fly has been killed. 20 In this test, for example, the following compound from the Preparation Examples exhibits very good activity: r Le A 35 188-Foreign Countries Table L Test mit Fliegen (Musca domestical Active compound Concentration in Activity/ ppm kill in % (13) 100/20 30/0 WE LAIM: l.∆1-Pyrrolines of the formula (I) (I) in which R1 represents halogen or methyl, R2 represents hydrogen or halogen, R3 represents -N(R6)-C(=Y)-X-R7, and a) A represents arylene or 5-membered heteroaiylene having 1 to 3 heteroatoms, containing 0 to 3 nitrogen atoms, 0 to 1 oxygen atom and/or 0 to 1 sulphur atom, or 6-membered heteioarylene having 3 nitrogen atoms or 6-membered heteioaiylene having 1 nitrogen atom and 1 to 2 further heteroatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms, each arylene or heteioarylene being optionally substituted from one to four times by identical or different substitueots R5, and Y represents O (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) orNR8, or b) A represents pyridinylene, pyrimidinylene, pyiuzinylene oi pyridazinylene each optionally substituted once or twice by identica] or different substituenta R5, and Y represents 0 (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or c) A represents pyiidinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different 3ab3tituents R5. and Y represents S (sulphur), and X represents O (oxygen), or d) A represents pyridinylene, pyrimidinylene^ pyrazinylene or pyridazinyiene each optionally substituted once or twee by identical or different substitueats R5,and Y represents O (oxygen), and X represents O (oxygen), and R4 and R5 independently of one anothei represent halogen, alkyl. alkoxy, alkvlthio, haloalkyl, haloalkoxy or haloalkytthio, m represents 0, I, 2, 3 or 4, R6 represents hydrogen or alkyl, R7 and R8 independently of one another represent hydrogen or represent alkyl or alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkylcaibonyl, alkylcarbonyloxy, alkylamino, dialkylamino, alkoxy, alkylthio, alkoxyalkoxy, haloalkoxy, haloalkylthio and halogenaikoxyalkoxy; or represent cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, saturated or unsaturated 5- to 10-membered heterocyclyl or heterocyclylalkyl each of which is optionally substituted one or more times by identical or different substitutents selected from the group consisting of halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylcarbonyl and alkoxycarbonyl, R6 and R7 further together represent alkylene optionally substituted one or more times by alkyl, or R7 and Rs fuither, togethei with the nitrogen atom to which they are attached, represent a saturated or unsaturated 5- to 10-membered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- and -NR9- and which may optionally be substituted one or more times by identical or different substituents selected from the group consisting of halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy and haloalkylthio, and R9 represents hydrogen, alkyl or alkenyi A^Pyriolines of the formula (I) as claimed in Claim 1, in which R1 represents fluorine, chlorine, bromine or- methyl, R2 represents hydrogen, fluorine, chlorine or bromine, R3 represents -N(R6)-C(=Y)-X-R7, A represents arylene (especially phenylene) or 5-membered heteroarylene having 1 to 3 heteroatoms, containing 0 to 3 mtaogen atoms, 0 to 1 oxygen atom and/or 0 to 1 sulphur atom (in particular from the series pyrrolylene, fuiylene, thienylene, pyrarylene, imidazylene, triazylene, thiazylene or oxazylene), or 6-membered heteroarylene having 3 nitrogen atoms (especially tr iazinylene) or 6-membered heteioaiylene having 1 nitrogen atom and I to 2 further heteroatoms, of which 0 to 2 may be oxygen atoms and/or 0 to 2 may be sulphur atoms fin particular Bom the series oxazinyleue or thiazinylene), each being optionally substituted from one to three times by identical or different substituents R5, and. Y represents O (oxygen) or S (sulphui) and X represents O (oxygen), S (sulphur) or NR8, A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazinylene each optionally substituted once or twice by identical or different substituents R5,and} Y represents O (oxygen) or S (sulphur), arid X represents S (sulphur) or NRS, A represents pyridinylene, pyrimidinylene, pyrazinylene oi pyridazinylene each optionally substituted once or twice by identical or different substituents RA, and. Y represents S (sulphur), and X represents O (oxygen), or d) A represents pyridinyleae, pyrimidinylene, pyraanylene or pyridazinylene each optionally substituted once or twice by identical or different substituentg R5, ajfii Y represents O (oxygen), and. X represents O (oxygen), and R4 and R5 independently of one anothei repiesents fluorine, chlorine, biomine, C1-C6-alfcyf, C1-C6-alkoxy, C1-C6-alkyfcriio, C1-C6-haloalkyl, C1-C6-haloalkoxy or C1-C6-haloalkylthio, m represents 0, 1, 2 or 5, R6 i epr esents hy drogen or C1-C6-aiky I, R7 and Rs independently of one anothei represent hydrogen or represent C1-C20-alkyl orC2-C20-alkenyl each optionally substituted one or more times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C10-alkylcarbonyl, C1-C6-alkyicaibonylaxy, C1-C6-alkylamino, di-(C1-C6-alcyI)amino, C1-C10-alkoxy, C1-C10-alkylthio, C1-C10-alkoxy-C1- C10-alkoxy, C1-C10-haloalkoxy, C1-C10-haloalkylthio and C1-C10-lialoalkoxy-C1-C10-alkoxy, or represent C3-C12-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, aryl, aryi-C1- C4alkyl, saturated or unsaturated 5- to 10-metnbered heterocyclyl or heterocyclyiC1-C4-alkyl having 1 to 4 heteroatoms, containing 0 to 4 nitrogen atoms, 0 to 2 non-adjacent oxygen atoms and/or 0 to 2 non-adjacent sulphur atoms (especially tetiazolyl, furyi, furfuryl, benzoruryl, tetiahydrofuryl, thienyl, thenyl, benzotbienyl, thiolanyl, pynoryl, indolyl, pyrrolinyl, pyrrolidiayl, oxazolyl, benzoxazolyl, isoxazolyl, imidazolyl, pyrazolyl, thiazolyl, benzothiazolyl, thiazolidinyl, pyridinyl, pyrimidrayl, pyiidazyl, pyrazbyl, piperidinyl, morpholinyl, thiomorpholinyl, triazinyl, triazolyl, quinolinyl or isoquinolinyl) each optionally substituted from one to four times by identical or different substttuents selected from the group consisting of fluorine, chloiine, bromine, C1-C6 alkyl, C1-C6-alkoxy, C1-C6alkyithio, C1-C6-haloalfcyl, C1-C6haloalkoxy, C1-C6-haloalkylthio, C1-C6-alkylcarbonyt and C1-C6-alkoxycaibonyt, R6 and R7 further together represent C2-C4alkylene optionally substituted fiom one to four times by C1-C4alkyl, or R7 and R8 further represent, together with the nitrogen atom to which they are attached, a saturated or unsaturated 5- to l0-membered het©recycle which may optionally contain a further heteioatom gioup from the series -0-, -S- or -NR9- and which may optionally be substituted from one to fow times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C6-alkyl, C1-C6-alkoxy, C1-C6 alkylthio, C1-C6 -haloalkyl, C1-C6-haloalkoxy and/or C1-C6-haloalkylthio, and R9 represents hydrogen, C1-C6-alkyl or C2-C6-alkenyl. 3 A'-Pyirolines of the formula (I) as claimed in Claim 1, in which R] represents fluorine, chlorine or methyl, R2 represents hydrogen, fluorine or chlorine, R3 represents -N(R6)-C(=Y)-X-R7, a) A represents phenyleae, pyrrolylene, furylene, tbiehylene, pyrazylene, imidazyleae, tiiazylene, thiazylene or oxazyleae each optionally substituted once or twice by identical or different substituents R5and. Y represents 0 (oxygen) or S (sulphur), and X represents O (oxygen), S (sulphur) or NR8, or b) A represents pyiidinylene, pyrimidinylene, pyrazinyleae or pyndazinylene each optionally substituted once or twice by identical or different substituents R5, and Y represents O (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or c) A represents pyiidinylene, pyiimidinylene, pyrazicylene or pyndazinylene each optionally substituted once or twice by identical or different substitueata R5, and Y represents S (sulphur), and X represents 0 (oxygen), or d) A represents pyridinylene, pyrimtdbylene, pyiazmyJece or pyndazinylene each optionally substituted once or twice by identical or different substituents R5, and Y represents O (oxygen), and. X represents 0 (oxygen), and R4 and R5 independently of one another represent fluorine, chloiine, C1-C4alkyl, C1 -C4alkoxy, C1-C4alkylthio; C1-C4-haIoalkyi,C1-C4-haloalfcoxy or C1-C4-haloalkylthio having in each case I to 9 fluorine, chloiine anaVor bromine atoms, m represents 0, 1 ot 2, R6 repiesents hydrogen or C1-C4-alkyl, R7 and R8 independently of one another represent hydrogen or represent C1-C16alkyI or C2-C16-a]kenyl each optionally substituted one or more times by identical 01 different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4alkylcarbonyl, C1-C4alkylcarbonyloxy, C1-C4-alkylaminc, di-[C1-C4-alkyl)ainino, C1-C10-alkoxy, C1-C10-altyltbio, C1-C10-alkoxy-C1- C6-alkoxy, C1-C10-haloalkcxy, C1-C10-haIoalkyhhio and C1-C10-b.aloalkoxy-C1-C6-alkoxy having in each case 1 to 21 fluorine, chlorine and\or bromine atoms; 0r represent C1-C10-cycloaikyl, C1-C6cycloalkyl-C1-C4-alkyl, phenyl, benzyl, phenylethyl, tetiazolyl, furyl, furftuyl, benzofuiyl, tetrahydrofuiyl, tbienyl. thenyl, benzothienyl, thiolanyl, pynolyl, indolyl, pyrrolinyl, pyiiolidinyl, oxazolyl, benzoxazolyl, isoxazolyl, imidazolyl, pyrazolyl, thiazolyl, benzothiazolyi, thiazolidinyl, pyridinyi, pyrimidinyl, pyridazyl, pyrazinyi, piperidinyl, morpholbiyl, thiomorpholinyl, triazinyl, triazolyl, quinolinyl or isoquinoiinyl each optionally substituted from one to three times by identical or different substituents selected from the group consisting of fluorine, chloiine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C4alkylthio, C1-C4haloalkyl C1- C4-haloalkoxy, C1-C4taloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, C1-C4-alkylcarbonyl and C1-C4 alkoxycarbonyL, R6 and R7 flirthct together represent C2-C3akyieao optionally substituted fiom one to three times by C1-C4alkyl, or R7 and R8 fuither represent, together with the nibtogen atom to which they are attached, a saturated or unsaturated 5- to 7-merabered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- or -NR5- (to particular fiom the series piperidino, morpholino, thiomoipholkto, pipemino, pyrrolidino, oxazolidko, uuazolidino, 4H-1-oxazinyl, 4H-l-thiaziayl) and which may optionally be substituted from one to four timss by identical or different substituents selected fiom the group consisting of fluorine, chlorine, C1-C4alcyl, C1-C4-alkoxy, C1-C4alkylthio, C1-C4haloalkyl,C1-C4haloalkoxy and/orC1-C4haloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, and R9 represents hydrogen, C1-C4alkyl or C2-C4-alkenyl Al-Pyttolines of the formula (1) as claimed in Claim 1, in which Rl represents fluorine or chlorine, R2 represents hydrogen or rmoiine, R3 repiesents -N(R6)-C(-Y>X-R7, and a) A represents 1,2-phenylene, 1,4-pheoylene, 2,5-pynolylene, 2,5-fiiryiene, 2,4-tuiylene, 2,5-thienylene, 2,4-thienylene, 2,5-thiazylene, 2,4-thiazylene, 2,5-oxazyleae or 2,4-oxazyleae each optionally substituted once by R5, and Y represents O (oxygen) or S (sulphur), and. X represents O (oxygen), S (sulphur) or NR8, R6 and R7 further together represent C2-C3-alkyiene optionally substituted from one to three times by C1-C4alkyl, or R7 and R8 father represent, together with the nibogen atom to which they are attached, a saturated or unsaturated 5- to 7-membered heterocycle which may optionally contain a further heteroatom group from the series -0-, -S- or -NR9- (in particular from the series piperidino, morpholino, tbioraorpholho, piperaziao, pyrrolidine, oxazoltdino, thiazolidino, 4H-I-oxaziny], 4H-l-thiazinyl) and which may optionally be substituted from one to four times by identical or different substituents selected from the group consisting of fluorine, chlorine,C1-C4alky!, C1-C4-alkoxy5 C1-C4alkyhhio, C1-C4-haloalkyl, C1-C4-haloalkoxy and/or C1-C4-haloalkylthio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, and R9 represents hydrogen, C1-C4-alkyl or C1-C4-alkenyl A'-Pytiolines of the foiraula (I) as claimed in Claim 1, in which Rl represents fluorine oi chlorine, R2 represents hydrogen or fluoiine, R3 repiesents -N(R«)-C(=Y)-X-R7, and a) A. iepresents 1,2-phenylene, 1,4-phenylene, 2,5-pyrroiylene, 2,5-fuiylene, 2,4-fiuylene, 2,5-thienylene, 2,4-thienylene, 2,5-thlazylene, 2,4-thlazylene, 2,5-oxazylene or 2,4-oxazyiene each optionally substituted once by R3, and Y represents O (oxygen) or S (sulphur), and. X represents O (oxygen), S (sulphur) or NR8, or b) A represents 2,5-pyridio.ylene, 2,5-pyrimidinytene, 2,5-pyrazinylene or 3,6-pyridazmylene each, optionally substituted once by R5, and. Y reprsents O (oxygen) or S (sulphur), and X represents S (sulphur) or NR8, or c) A represents 2,5-pyridinylene, 2,5-pyrirnidinylene, 2,5-pyrazinylene or 3,6-pyridazinylene each optionally substituted once by R5, and Y represents S (sulphur), and X represents O (oxygen), or d) A lepj^esents 2,5-pyiidinyiene, 2,5-pyiimidinylene, 2,5-pyrazkylene or 3,6-pyiidazinylece each optionally substituted once by R5, and Y represents O (oxygen), and X represents O (oxygen), and R4 and R5 independently of one another represent fluorine, chlorine, raethyl, ethyl, n-propyl, i-propyl, n-butyl. j-butyl, s-butyl, t-butyl, methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, i-butoxy, s-butoxy, t-butoxy, methylthio, ethylthio, n-propy!thio, i-propylthio, n-butylthio, i-butyltbio, s-butylthio, t-butylthio, triauoromethyl, toifluoroethyl, ttifluoromethoxy, trifluoroethoxy, trifluoromethylthio or trifluoroethylthio, m represents 0 or 1, R6 represents hydrogen, methyl, ethyl, n-propyl, i-propyl, n-butyi, i-butyl, s-fautyl ort-buty], R7 aod R8 independently of one another represent hydrogen or represent C1-C10-alkyl or C2-C10-alknyl (especially methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl, t-butyj, the isomeric pentyls, the isomeric hexyis) each optionally substituted one or more times by identical or different substituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4aikylcaibonyl, C1-C4alky]carbonyloxy,C1-C4-atkylamino, di-(C1-C4alkyl)arnino, C1-C10 alkoxy, C1-C8-alkoxy-C1-C6-aikoxy, C1-C10-alkylthio, C1-C10-haloalkoxy, C1-C10-haloalkylthio having in each case 1 to 21 fluorine, chlorine and/or bromine atoms, C1-C8-haloalkoxy-C1-C6-alkoxy having 1 to 17 fluotine, chlorine and/or bromine atoms; or represent C3-C8cycloalkyl, cyclopropylmethyl, cyclopentylmethyl, cyciohexylmethyl, cyclopropylethyl, cyclopentylethyi, cydohexylethyl, phenyl, benzyl, phenylethyl, tetrazolyl. finyL furtuivl, benzofuiyl, tetiahydiofuiyi, thienyl, thenyl, benzothienyJ, thiolanyl, pynolyl, indolyt pyrrolinyl, pynclidinyl, oxazolyl, benzoxazolyl isoxazoh/l, imidazolyl, pyrazoly], thiazolyl, benzotbiazolyl, thiazolidinyl, pyridiayl, pyiimidinyl, pyridazyl, pyrazinyl, piperidinyl, morpholinyl, thiomoipholinyl, triazinyl, triazolyl, quinolinyl oi isoquinolinyl each optionally substituted from one to three times by identical or different aubstituents selected from the group consisting of fluorine, chlorine, bromine, C1-C4-alkyl C1-C4alkoxy, C1-C4- alkylthio,C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio having in each case 1 to 9 fluorine, chloiine and/or bromine atoms,C1-C4-aIkylcarbonyl and C1-C4-alkoxycaibonyl, R6 and R7 further together represent methylene or ethylene each optionally substituted once or twice by identical or different methyl, ethyl, n-propyl or i-propyl substituents, or R7 and R8 further represent, together with the nttiogen atom to which they are attached, a 5- to 6-membered heterocycle from the series piperidmo, morpholino, thiomoipholiiio, piperazhio, pyrroHdino, oxazohdino, thiazolidiao, 4H-l-oxaanyl, 4H-l-thia2inyt which may optionally be substituted from one to four times by identical or different substituents aelected from the gioup consisting of fluorine, chlorine, brotnine, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyi, s-butyl, t-butyi, methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, i-butoxy, s-butoxy, t-butoxy, methyfthio, ethylthio, n-piopylthio, i-propylthio, n-butylfhio, i-butylthio, s-butyWdo, t-butytthio,C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4haloaDtykhio having in each case 1 to 9 fluorine, chlorine and/or bromine atoms, the pipeiazino radical being substituted on the second nitrogen atom by R9, and R9 represents hydrogen, methyl, ethyl, n-propyt, i-propyl, n-butyl. i-butyi, s-butyl, t-butyl, vinyl or ally! A'-Pyitolines of the formulae (1-1) aad (1-2) (6-2) (1-1) as claimed in claim 1, in each of which a) represents O (oxygen) oi S (sulphur), and ► X represents O (oxygen), S (sulpiair) or NR8, and R1, R2 R4, R5, m, R6, R7, R8 have the meanings given in Claim 1 6 Ai-Pynolines of the formulae (1-3) to (1-8) (1-3) (1-4) (6-5) (1-6) N Y fl-T) d-8) as claimed in claim 1, in each of which p represents 0, 1 or 2, anA b) Y i epi esents O (oxygen) or S (sulphur), and X .represents S (sulphur) or NR8 or c) Y represents S (sulphur), and X represents O (oxygen), or d) Y represents O (oxygen), and X represents O (oxygen), and R1, R2, R4, R5, m, R6, R7 and R8 have the meanings given in Claim 1 7 ∆1Pyrrolines of the fonnula (I) as claimed in Claim 1, in which A represents phenylene, preferably 1,4-phanylene 8 ∆1-Pyrrolines of the foimula (I) as claimed in Claim 1, in which A represents pyridinylene, pyrimidinylene, pyrazinylene or pyridazkiylene, preferably 2,5-pyridinylene, 2,5-pyrimidinylene, 2,5-pytazmylene oi 3,6-pyridazinykne 9 ∆1Pyirolmes of the formula (I) as claimed in Claim 1, in which Y represents 0 (oxygen) 10 ∆1-Pyrrolines of the fonnula (I) as claimed in Claim 1, in which X represents O (oxygen) or NR8, preferably represents O (oxygen) 11 ∆1Pyrrolincs of the foimula (1) as claimed in Claim 1, in which Y and X each represent 0 (oxygen) 12 ∆1-Pyridines of the formula (I) as claimed in Claim I. in which Y represents 0 (oxygen) and X represents NRS 13 ∆1-Pyrrolines of the foimula (I) as claimed in Claim 1, in which A represents phenylene, preferably 1,4-phenylene, Y represents 0 (oxygen) or S (sulphur), preferably 0 (oxygen), and X lepresents 0 (oxygen), S (sulphur) or NR8, preferably O (oxygen) or NR8, with particular preference 0 (oxygen) 14 ∆1-Pytroluies of the fonnula (I) as claimed in Claim I, in which R1 and R2 each represent fluorine 15 ∆1-Pyirolines of the fonnula (I) as claimed in Claim 1, in which R1 represents methyl and R2 represents hydrogen 16 ∆1-Pyrrolines of the formula (1) as claimed in Claim 1, in which R1 represents chioiine and R2 iepresents hydrogen 17 ∆1Pyrrolines of the formula (1) as claimed in Claim t, in which R1 represents chlorine and R2 represents fluorine. 18 ∆1-Pyrrolines of the formula (I) as claimed in Claim 1, in which K6 represents hydrogen 19 ∆1-Pyirolines of the formula (1-a) as claimed in claim 1, with (R) configuration in position 5 of the pyrroline ring (I-a) in which which R1, R2, A, R3, R4 and m have the meanings given in Claim 1 20 Process for preparing compounds of the formula (1) as claimed in Claim 1, characterized by A) reacting ∆1-pyrrolrocs of the formula (II) (II) in which R1, R2, R4 and m have the meanings given in Claim 1 and Z1 represents chlorine, bromine, iodine, -OSO2CF3 or -OSO2(CF2)CF3 in a tandem reaction with (hetero)cycles of the foimula (III) (Ill) in which A, R6 and R7 have the meanings given in Claim 1, Y1 represents O (oxygen), X1 represents 0 (oxygen) or NR8, E represents chlorine, bromine, iodine, -OSO2CF3 or -OSO2(CF2)CF3 in the presence of a catalyst, in the presence of a diboronic ester and, where appropriate, in the presence of an acid binder and, where appropriate, in the presence of a diluent, reacting Ai-pyirolines of the formula (IV) (IV) R1, R2, R4 and ra have the meanings given in Claim 1, Z2 represents -B(OH)^, (4,4,5,54etramethyl-t,3;2-dioxaborolan)-2-yl, (5,5- dimethyl-1,3,2-dioxaborinan)-2-yl, (4,4,6-trimethyl-l ,3,2- dioxaborinan)-2-yl or ])3,2-ben2odioxaborol-2-yl, with (hetero)cycles of the formula (III) (ni) in which A,, R6 and R7 have the meanings given in Claim 1, E, Y1 and X1 have the above given meanings, in the presence of a catalyst, where appropriate in the presence of an at binder and, where appi optiate, in the presence of a diluent, or C) reacting ∆1pyirolines of the formula (II) in which R1, R2, R.4 and m Z1 have the meanings given in Claim 1, Z1 have the meanings given above, with boronic acid derivatives of the formula (V) (^) in which A, R6 and R7 have the meanings given in Claim 1, Z2, Y1 and X1 have the meanings given above, in the presence of a catalyst, where appropriate in the presence of an acid binder and, where appiopiiate, in the presence of a diluent, °r D) reacting ∆1pyrrolines of the formula (H-a) in which Rl, R2, R4 and m have the meanings given in Claim 1, Z3 represents bromine or iodine with organometallic compounds of the formula (VI) (VI) in which ∆, R6 and R7 have the meanings given in Claim 1, Y' and X1 have the meanings given above, M represents ZnCl, SnfMeJ-j or Sn(n-Bu)3, in the presence of a catalyst, wheie appropriate in the presence of an acid binder and, where appropriate, in the presence of a diluent, or E) reacting ∆1-pynolines of the fonoula (VH) (VII) Rl, R2, A, R4 and m have the meanings given in Claim 1 either with an iso(thio)cyanate of the formula (VIII) (VIII) in which Y and R7 have the meanings given in Claim 1 of with a (thio)caibonate of the formula (IX) (IX) in which Y and R7 have the meanings given in Claim 1, X2 represents O (oxygen) or S (sulphur), in each case where appropriate in the presence of a diluent and, where appropriate, in the presence of an acid binder 21. Pesticides, wherein they comprise at least one compound of the formula (I) as claimed in claim 1 in a weight ratio of 0,1% to 95% in addition to extenders and/or surface-active substances. |2. Ai-Pyrrolines of the formula [I]substantially as hereinbefore described with reference to the foregoing examples. 23. Process for preparing compounds of the formula [I] substantially as herinbefore described with reference to the forgoing examples. 24. Pesticides substantially as hereinbefore described with reference to the foregoing examples. Dated this on 03/09/2002 (DR. ANUSHRI GUPTA) OF REMFRY 8B SAGAR ATTORNEY FOR THE APPLICANTS

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