Title of Invention

FOOD PRODUCTS COMPRISING FAT AND A SALT

Abstract Savoury food composition comprising 5-80 % wt, preferably 10-70% wt., of triglycerides of fatty acids, 2-80 % wt, preferably 5-70% wt., of an edible salt, 0.1-50% wt. of any one or more of herbs, spices, tomato powder, vegetable pieces and monosodium glutamate and which composition contains less than 15% wt., preferably less than 10% wt., of water, wherein the amount of H3 (triglyceride of 3 saturated fatty acids of 16 or more carbon atoms) and H2U (triglyceride of 2 saturated fatty acids of 16 or more carbon atoms 1 cis-unsaturated fatty acid) taken together is at least 55 wt% based on the total amount of triglyceride, the composition being in the form of a particulate soup or sauce concentrate, which yields a soup or sauce upon mixing and heating with an aqueous liquid, and which composition is substantially free from animal fat and wherein the composition is particulate matter.
Full Text F7678
FORM - 2
THE PATENTS ACT, 1970
(39 of 1970)
&
The Patents Rules, 2003
COMPLETE SPECIFICATION
(See Section 10 and Rule 13)
FOOD PRODUCTS COMPRISING FAT AND A SALT
HINDUSTAN LEVER LIMITED, a company incorporated under the Indian Companies Act, 1913 and having its registered office at Hindustan Lever House, 165/166, Backbay Reclamation, Mumbai-400 020, Maharashtra, India


The following specification particularly describes the invention and the manner in which it is to be performed.

Original 21/11/2007
402/MUMNP/2005

FOOD PRODUCTS COMPRISING FAT AND A SALT
Field of the invention
The present invention relates to savoury food compositions which contain fat and a salt, and in particular savoury food compositions comprising triglycerides of fatty acids, wherein the composition is low in triglycerides of trans-unsaturated fatty acids.
Background of the invention
Savoury food compositions contain in many cases fat. This is especially the case for particulate and/or pasty compositions, which are often dry. Dry in this context is to be understood as comprising less than 15% (wt), preferably less than 10% (wt) of water. Particulate in this context is to be understood as powder, flakes, cubes, pellets etcetera. Examples of such products are e.g. bouillon cubes, culinary cubes, soup- and sauce mixes, etcetera.
The fats in such savoury compositions usually comprise a considerable amount triglycerides of fatty acids (hereinafter for short: triglycerides). Fats are usually mixtures of various triglycerides. The type of fat or fat blend used for a given purpose is determined (next to availability and price) by e.g. the properties the fat has and how it performs in a given product, and in the manufacture of such product/The fat should perform well on e.g. taste, melting in the mouth, taste keepability, but also on ability to be processed into a suitable product as well as performance in the packed product, e.g. keepability (in particular fat staining for cubes packaged in cardboard).
The triglycerides (which form part or all of the fat) are usually obtained from vegetable sources and may have been subjected to various treatments, such as fractionation (dry or wet), purification, hardening, interesterification, blending etcetera, to give the fat the desired product properties. Hardening unsaturated fat or triglycerides to saturated or partially unsaturated fat or triglycerides is in particular a tool used to obtain the desired melting behaviour. In this way, oils or soft fats can be turned into fats showing more suitable properties for solid or dry formulations.
The hardening process may lead to formation of a certain amount of so-called trans-unsaturated fatty acids (and/or triglycerides of such trans-unsaturated fatty acids), in short TFA's. For various reasons it may be desired to reduce or eliminate the amount of trans-

unsaturated fatty acids (and triglycerides thereof) in products. For spreads (margerines and the like) a wide range of possible alternative fats and triglycerides are proposed, as is disclosed in e.g. WO 97/16978 and WO 96/39855.
The triglycerides mentioned in such applications frequently contain lauric acid (C12 saturated fatty acid). It has been found that when one wishes to find an alternative for the trans-unsaturated fatty acids (and fats containing them) in savoury applications lauric acid is undesired. Lauric acid and triglycerides containing lauric acid may show a range of desirable properties, in particular melting behaviour, but in a savoury application triglycerides of lauric acid were found to lead to a (soapy) off-flavour, especially after prolonged storage.
Hence, there is a desire for dry and/or particulate savoury products which contain triglyceride fats which are low in trans-unsaturated fatty acids (e.g. below 5% of the total fats present, preferably less than 2%), but which still should perform well in a savoury composition, in particular concerning processability, fat staining, crystallisation, mouth feel, and other characteristics as mentioned above. Preferably, such product should also be low in lauric acid or triglycerides thereof (e.g. below 10% of the total fats present, preferably less than 3%, most preferably less than 0.5% wt of the total fats present).
Triglyceride fats can be grouped according to the fatty acids of which they consist (i.e. the acyl moiety of triacyl glycerides). Such groups can be identified by a letter, and herein: H means saturated fatty acid of 16 carbon atoms or longer (C16+, e.g. up to C24) U means unsaturated fatty acids in cis conformation (any chain length) E means unsaturated fatty acids in trans conformation (any chain length) M means saturated fatty acids of 10-14 carbon atoms (C10-C14)
As the present application is about triglycerides of such fatty acids, the fatty acid composition of the triglycerides is given by for example:
H3 (meaning a triglyceride of 3 saturated fatty acids of 16 or more carbon atoms) H2E (meaning a triglyceride of 2 saturated fatty acids of 16 or more carbon atoms and 1 trans-unsaturated fatty acid)
H2M (meaning a triglyceride of 2 saturated fatty acids of 16 or more carbon atoms and 1 saturated fatty acid of 10-14 carbon atoms)
H2U (meaning a triglyceride of 2 saturated fatty acids of 16 or more carbon atoms and 1 cis-unsaturated fatty acid)

HE2 (meaning a triglyceride of 1 saturated fatty acid of 16 or more carbon atoms and 2 trans-unsaturated fatty acids), and so on for other 3 letter codes.
Fat compositions can thus be characterised in containing certain weight percentages (based on the total amount of triglycerides) of triglycerides of the above codes.
Although it is mentioned for E and U that they may have any length, it is to be understood that this relates to fatty acids of approx. 8-24 carbon atoms, and more usually 16-20 carbon atoms.
Summary of the invention
Thus according to the basic object of the present invention there is provided Savoury food
composition comprising 5-80 % wt, preferably 10-70% wt., of triglycerides of fatty acids, 2-80 % wt, preferably 5-70% wt, of an edible salt, 0.1-50% wt. of any one or more of herbs, spices, tomato powder, vegetable pieces and monosodium glutamate and which composition contains less than 15% wt., preferably less than 10% wt. , of water, wherein the amount of H3 (triglyceride of 3 saturated fatty acids of 16 or more carbon citoms.X.and JH.2U (triglyceride of 2 saturated fatty acids of 16 or more carbon atoms 1 cis-unsaturated fatty acid) taken together is at least 55 wt% based on the total amount of triglyceride, the composition being in the form of a particulate soup or sauce concentrate, which yields a soup or sauce upon mixing and heating with an aqueous liquid, and which composition is substantially free from animal fat and wherein the composition is particulate matter.
This means that of the total amount of triglycerides present in the composition according to the invention at least 55% wt (preferably at least 20% wt) are triglycerides of fully saturated C16 and longer chains (e.g. C16, C18, C20, C22 and C24) and/or triglycerides containing one cis-unsaturated fatty acid of any chain length and two saturated fatty acids of 16 or more carbon atoms. In connection to this, it is believed that the dry and/or particulate and/or pasty savoury food compositions as currently on the market comparable to the compositions according to the invention contain about 30%-50% of such H3+H2U triglycerides as part their fats.
4.
Following the invention, it is now possible to manufacture a savoury food composition comprising 5-70% wt of di- and/or triglycerides of fatty acids, 2-50% wt (preferably 5-40% wt) of an edible salt and which composition contains less than 15% wt of water (preferably less than 10% wt), wherein the triglycerides are selected such that they contain less than 5% preferably less than 2% wt of trans-unsaturated fatty acids, and preferably having less than 10% wt (more preferably less than 3%, most preferably less than 0.5%) of lauric acid, and wherein the fats still have appropriate melting and crystallization behaviour.


Detailed description of the invention
In the composition according to the invention it is preferred that the amount of H3 (triglyceride of 3 saturated fatty acids of 16 or more carbon atoms) is at least 15% wt based on the total amount of triglycerides, preferably at least 20%. Likewise, it is preferred that the amount of H2U (triglyceride of 2 saturated fatty acids of 16 or more carbon atoms and 1 cis-unsaturated fatty acid) taken together is at least 40% wt based on the total amount of triglycerides.
Apart from the amounts of H3 and H2U it can be preferred to use fats of such composition in a particular ratio. In this case, the ratio H3/H2U is preferably between 0.5 and 1.2.
Regarding the basic fatty acid composition, it is preferred that the amount of H (i.e. saturated fatty acids of 16 or more carbon atoms) is between 60 and 75% wt based on total amount of fatty acids. Normally, only fatty acids are used with even number of carbon atoms. Similarly, it is preferred that the amount of U (cis-unsaturated fatty acids of any suitable chain length) is between 20 and 45% wt based on total amount of fatty acids.
In the composition according to the invention the amount of palmitic fatty acid (C16:0) in the triglycerides is preferably between 30 and 70% wt based on the total amount of fatty acids. Likewise, the amount of stearic fatty acid (C18:0) is preferably between 0 and 20% wt based on the total amount of fatty acids.
The savoury food compositions according to the invention can be any physical format, but the invention is most suitable for savoury compositions which are in the form of pasty or particulate matter. Examples of this are bouillon or seasoning (different name: culinary) cubes and dry mixes for soups and sauces. Particulate matter is herein to be understood to comprise e.g. flakes, granules, powder, cubes, pellets, tablets. The savoury food compositions according to the invention will usually comprise (e.g. in an amount of 0.1-50% wt) one or more of the following ingredients: herbs and/or spices, tomato powder, vegetable pieces, monosodium glutamate and other components. What above is mentioned pasty also encompasses bouillon or culinary cubes, which may look as a solid, but are to some extent plastic matter (i.e. can be deformed by moderate pressure by hand) and thus by persons skilled in the art recognised as "pasty". Thus, bouillon or culinary cubes which are as such particulates, can consist of pasty matter. Also, complex compositions can be prepared using the material according to the invention. For example, for e.g. bouillon, culinary or seasoning


cubes filled with fluid or liquid matter, the shell may be of bouillon or seasoning materail according to the present invention.
The invention also encompasses compositions as set out above, in the form of a particulate soup- or sauce concentrate, which yields a soup or sauce upon mixing and heating with an aqueous liquid. Likewise, compositions as set out above, in the form of a bouillon or broth cube, which yields a bouillon or broth upon mixing and heating with an aqueous liquid.
Following the above, it is now possible to manufacture e.g. dry soup or sauce concentrates which contain a large proportion of vegetable fats, which composition is substantially free from trans-fatty acids or triglycerides thereof. Thus, the invention further relates to a savoury food composition comprising 5-80% wt (preferably 10-70% wt) of triglycerides of fatty acids, 2-80% wt (preferably 5-70%) of an edible salt and which composition contains less than 15% wt (preferably less than 10% wt) of water, wherein at least 50% of the fats is of vegetable origin, and which composition is substantially free from trans-unsaturated fatty acids or triglycerides thereof. Preferably, the compositions according to the invention are substantially free from animal fat.
EXAMPLES
Fat blends 1-6 were prepared from various known fats and fats specifically produced according to the top half of table 1. PO is palm oil. POs is a dry-fractionated palm stearin with a melting point of approx. 53°C. P058 is fully hardened palm oil. The fatblend "Mix A" was prepared by interesterification of a 60% palm oil, 40% rape 68 blend. P044 is obtained by hardening palm oil to a melting point of approx. 44°C. In the second half of table 1 the fatty acid composition is given in accordance with the definitions as herein defined, as is the ratio symmetric: asymmetric triglycerides for H2U.
The same data are given for fats in 3 comparative products as have appeared on the market (A-C).


Table 1

Note: the numbers of all the fats given do not add up to 100%, as some minor amounts of other fats are also present.
The fat blends 1-4 have been developed in order to provide a fat blend having suitable properties on melting, crystallisation, mouthfeel, fat staining, etcetera, but without substantial amounts of trans-unsaturated fatty acids, while keeping the amount of lauric acid in the triglycerides low (1% maximum).
The fat blends have been used in the following compositions.
Bouillon cubes
Bouillon cubes were prepared containing 18% fat, 60% salt/MSG mixture, 20% flavours, herbs and spices, 2% water. The fat blends used were fat blends 1, 2, 5, and 6 of table 1. The cubes was prepared by using conventional processing. The product could be prepared in a similar equipment and fashion as conventional bouillon cube, and had good properties (e.g. oral melt, processability, no fat staining).

Culinary cube
A culinary cube was prepared containing 28% fat, 25% salt/MSG mixture, 47% flavours, herbs
and spices. The fat blend used was fat blend 3 of table 1. The cubes were prepared by using
conventional processing. The product could be prepared in a similar equipment and fashion as
conventional culinary cube, and had good properties (e.g. oral melt, processability, no fat
staining).
Bouillon
An instant bouillon was prepared containing 22% fat, 60% salt/MSG mixture, 14% flavours, herbs and spices, 2% water. The fat blend used was fat blend 4 of table 1. The product could be prepared in a similar equipment and fashion as conventional bouillon composition, and had good properties (e.g. oral melt, processability).
The comparative examples were:
Bouillon cubes
Conventional bouillon cubes from two different European countries were analysed for the fat
composition, which result is given as blends A and B in table 1.
Culinary cube
A conventional culinary cube from a European country was analysed for the fat composition,
which result is given as blend C in table 1.


We Claim:
1. Savoury food composition comprising 5-80 % wt, preferably 10-70% wt., of triglycerides of fatty acids, 2-80 % wt, preferably 5-70% wt., of an edible salt, 0.1-50% wt. of any one or more of herbs, spices, tomato powder, vegetable pieces and monosodium glutamate and which composition contains less than 15% wt., preferably less than 10% wt., of water, wherein the amount of H3 (triglyceride of 3 saturated fatty acids of 16 or more carbon atoms) and H2U (triglyceride of 2 saturated fatty acids of 16 or more carbon atoms 1 cis-unsaturated fatty acid) taken together is at least 55 wt% based on the total amount of triglyceride, the composition being in the form of a particulate soup or sauce concentrate, which yields a soup or sauce upon mixing and heating with an aqueous liquid, and which composition is substantially free from animal fat and wherein the composition is particulate matter.
2. A composition as claimed in claim 1, wherein said amount of H3+H2U is at least 65% wt based on the total amount of triglycerides.
3. A composition as claimed in anyone claims 1 and 2, wherein the amount of H3 (triglyceride of 3 saturated fatty acids of 16 or more carbon atoms) is at least 15% wt based on the total amount of triglycerides, preferably at least 20 wt%.
4. A composition as claimed in any one of claims 1 to 3, wherein the amount of H2U (triglyceride of 2 saturated fatty acids of 16 or more carbon atoms and 1 cis-unsaturated fatty acid) taken together is at least 40% wt based on the total amount of triglycerides.
5. A composition as claimed in any one of claims 1 to 4, wherein the ratio H3/H2U is between 0.5 and 1.2.
6. A composition as claimed in any one of claims 1 to 5, wherein the amount of H is between 60% wt and 75% wt based on total amount of fatty acids.


7. A composition as claimed in any one of claims 1 to 6, wherein the amount of U is between 20 % wt and 45% wt based on total amount of fatty acids.
8. A composition as claimed in any one of claims 1 to 7, wherein the amount of palmitic fatty acid (C16:0) based on the total amount of fatty acids is between 30% wt and 70% wt.
9. A composition as claimed in any one of claims 1 to 8, wherein the particulate matter comprises flakes, granules, powder cubes, pellets, tablets.
10. A composition as claimed in claim 9 in the form of a boullion or broth cube, which yields a boullion or broth upon mixing and heating with an aqueous liquid.

Dated this llth day of May,2005







ANJAN SEN Of Anjan Sen & Associates, (Applicants Agent)

Documents:

402-MUMNP-2005-CANCELLED PAGES(17-7-2007).pdf

402-mumnp-2005-cancelled pages(21-11-2007).pdf

402-MUMNP-2005-CLAIMS(AMENDED)-(25-6-2007).pdf

402-MUMNP-2005-CLAIMS(GRANTED)-(18-3-2008).pdf

402-mumnp-2005-claims(granted)-(21-11-2007).doc

402-mumnp-2005-claims(granted)-(21-11-2007).pdf

402-mumnp-2005-claims.doc

402-mumnp-2005-claims.pdf

402-mumnp-2005-correspondence 1(11-5-2006).pdf

402-mumnp-2005-correspondence 2(26-8-2005).pdf

402-mumnp-2005-correspondence 3(21-11-2007).pdf

402-mumnp-2005-correspondence(ipo)-(15-10-2007).pdf

402-MUMNP-2005-CORRESPONDENCE(IPO)-(8-4-2008).pdf

402-mumnp-2005-correspondence-others.pdf

402-mumnp-2005-correspondence-received-ver-050207.pdf

402-mumnp-2005-correspondence-received-ver-110505.pdf

402-mumnp-2005-correspondence-received-ver-120905.pdf

402-mumnp-2005-descripiton (complete).pdf

402-MUMNP-2005-DESCRIPTION(GRANTED)-(18-3-2008).pdf

402-mumnp-2005-form 1(11-5-2005).pdf

402-mumnp-2005-form 1(17-7-2007).pdf

402-mumnp-2005-form 1(7-2-2007).pdf

402-mumnp-2005-form 13(17-7-2007).pdf

402-mumnp-2005-form 13(7-2-2007).pdf

402-mumnp-2005-form 18(12-9-2005).pdf

402-MUMNP-2005-FORM 2(GRANTED)-(18-3-2008).pdf

402-mumnp-2005-form 2(granted)-(21-11-2007).doc

402-mumnp-2005-form 2(granted)-(21-11-2007).pdf

402-MUMNP-2005-FORM 2(TITLE PAGE)-(11-5-2005).pdf

402-MUMNP-2005-FORM 2(TITLE PAGE)-(GRANTED)-(18-3-2008).pdf

402-mumnp-2005-form 3(11-5-2005).pdf

402-mumnp-2005-form 3(21-11-2007).pdf

402-mumnp-2005-form 5(11-5-2005).pdf

402-mumnp-2005-form 5(11-5-2006).pdf

402-mumnp-2005-form-1.pdf

402-mumnp-2005-form-13.pdf

402-mumnp-2005-form-18.pdf

402-mumnp-2005-form-2.doc

402-mumnp-2005-form-2.pdf

402-mumnp-2005-form-26.pdf

402-mumnp-2005-form-3.pdf

402-mumnp-2005-form-5.pdf

402-mumnp-2005-form-pct-ipea-409(11-5-2005).pdf

402-mumnp-2005-form-pct-ipea-409.pdf

402-mumnp-2005-form-pct-ipea-416.pdf

402-mumnp-2005-form-pct-isa-210(11-5-2005).pdf

402-mumnp-2005-form-pct-separate sheet-409.pdf

402-mumnp-2005-pct-search report.pdf

402-mumnp-2005-petition under rule 137(21-11-2007).pdf

402-mumnp-2005-power of attorney(23-6-2007).pdf

402-mumnp-2005-power of attorney(7-2-2007).pdf

402-MUMNP-2005-SPECIFICATION(AMENDED)-(21-11-2007).pdf


Patent Number 216711
Indian Patent Application Number 402/MUMNP/2005
PG Journal Number 42/2008
Publication Date 17-Oct-2008
Grant Date 18-Mar-2008
Date of Filing 11-May-2005
Name of Patentee HINDUSTAN LEVER LIMITED
Applicant Address HINDUSTAN LEVER HOUSE, 165/166, BACKBAY RECLAMATION, MUMBAI,
Inventors:
# Inventor's Name Inventor's Address
1 JOHANNES CORNELIS BRUG UNILEVER BESTFOODS NEDERLAND BV HERMESWEG 5, 3741 GP BAARN,
2 ECKHARD FLOTER UNILEVER R&D VLAARDINGEN, OLIVIER VAN NOORTLAAN 120, 3133 AT VLAARDINGEN,
3 GABRIEL JACOBUS THEODORUS LANSBERGEN LANGE KERKDAM 62, 2242 BX WASSENAAR,
PCT International Classification Number A23D7/00
PCT International Application Number PCT/EP2003/12031
PCT International Filing date 2003-10-29
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 02079834.4 2002-11-18 EUROPEAN UNION