Title of Invention	FLAME RETARDANTS WHICH CONTAIN PHOSPHORUS, AND FLAME-RETARDANT THERMOPLASTIC MOULDING COMPOSITIONS
Abstract	WE CLAIM: 1. Oligophosphates selected from the group consisting of wherein n in each case denotes an integer from 1 to 30. 2. Oligophosphate as claimed in claim 1 of formula wnerein denotes an integer from 1 to 30.

Full Text

FORM 2 THE PATENTS ACT 1970 [39 OF 1970] COMPLETE SPECIFICATION [See Section 10; rule 13] "FLAME RETARDANTS WHICH CONTAIN PHOSPHORUS, AND FLAME-RETARDANT THERMOPLASTIC MOULDING COMPOSITIONS" BAYER AKTIENGESELLSCHAFT, a German company, of D-51368, Leverkusen, Germany The following specification particularly describes the nature of the invention and the manner in which it is to be performed :- ORIGINAL 597/MUMNP/2003 GRANTED 14/9/2007 Flame retardants which contain phosphorus, and flame-retardant thermoplastic moulding compositions This invention relates to new oligophosphates which act as flame retardants, and 5 to thermoplastic compositions (moulding compositions) which contain them and which exhibit improved dimensional stability under the effect of heat and good processing properties, and also relates to mouldings which are obtainable therefrom. 10 Flame-retardant, impact-resistant modified polycarbonate moulding compositions are known. Compounds which contain phosphorus, particularly aromatic esters of phosphoric acid, are often used as flame retardants on a large industrial scale. 15 US-A 5 061 745 describes polymer mixtures comprising aromatic polycarbonates, ABS graft polymers and/or styrene-containing copolymers and esters of monophosphoric acid as flame retardant additives. One disadvantage of esters of monophosphoric acid is their plasticiser effect, which results in a considerable decrease in the dimensional stability of these polymer compositions 20 under the effect of heat. Moreover, for many applications these compounds are too volatile and exhibit too great a capacity for migration in the polymer composition, which under unfavourable injection moulding conditions can result in the bleeding out of the flame-retardant additive and in unwanted contamination of the surfaces of the injection mould, which is termed a "juicing 25 phenomenon". Said juicing phenomenon can be very substantially suppressed, and the dimensional stability under the effect of heat of the material can easily be increased, by the use of oligomers of esters of phosphoric acid or mixtures of 30 oligo- and monophosphoric acid esters as flame retardants in PC/ABS-moulding compositions, as described in EP-A 0 363 608 and EP-A 0 640 655. For many applications, however, the dimensional stability under the effect of heat which is thereby obtained is still unsatisfactory. WO 99/07779 describes the use of oligophosphates based on biphenylene 5 dihydroxide as flame retardants in PC/ABS moulding compositions These phosphates exert a significantly reduced plasticiser effect on the polymer composition, so that a greater dimensional stability under the effect of heat can be achieved. However, moulding compositions which are provided with this additive exhibit poor flowability, which in many cases is not satisfactory for the 10 processing of the material by injection moulding. Other esters of oligophosphoric acid and the use thereof as flame retardants in PC/ABS moulding compositions are described in EP-A 0 816 434 (oligophosphates based on bisphenol S), EP-A 0 672 717 (alkyl-substituted 15 oligophosphates of the p-hydroquinone type), US 5 455 292 (alkyl-substituted oligophosphates based on bisphenol A), US 5 864 004 (oligophosphates based on bisphenol A) and US 5 183 905 (oligophosphates based on phenolphthalein). PC/ABS moulding compositions which are made flame retardant with these compounds do in fact exhibit dimensional stability under the effect of heat which 20 is improved compared with that achieved with conventional flame retardants, but for many applications still do not exhibit sufficient dimensional stability under the effect of heat or exhibit deficiencies in flowability or toughness. Consequently, the underlying object of the present invention is to provide 25 PC/ABS moulding compositions which exhibit improved dimensional stability under the effect of heat while still exhibiting a good level of toughness and excellent flowability. This object is achieved by a new compound, which contains phosphorus, of 30 general formula which exhibits a flame retardant effect, wherein R1 and R2 can be selected individually and independently of each other for each X, and can denote hydrogen, an alkyl which is substituted or unsubstituted with a halogen, a cycloalkyl or an aryl, each comprising 1 to 20 carbon atoms, preferably comprising 1 to 10 carbon atoms, or R1 and R2, together with the carbon atom X to or a cycloalkyl structure which they are bonded, form the structure which is optionally substituted with a halogen, 10 R3 to R8, independently of each other, are identical or different and can denote an alkyl comprising 1 to 10 carbon atoms or a halogen, x denotes carbon, m denotes an integer from 4 to 7, preferably 4 or 5, n denotes an integer from 1 to 30, preferred from 1 to 15, particularly from 1 to 5, y is 0 or 1, preferably 1, and q denotes numbers which are independent of each other, are identical or different, and can represent an integer from 0 to 5. R1or R2 on a carbon atom X, together with an R1 or R2, on a further carbon atom X', can also form a cyclic structure, for example a cycloalkyl or a cycloalkyl which is substituted with a halogen. 5 The structure can be cited as an example, wherein R9 and R10 are identical or different, and, independently of each other, denote hydrogen, an alkyl comprising 1 to 4 carbon atoms or a halogen, and q denotes numbers which are independent of each other, 10 are identical or different, and can represent an integer from 0 to 4. It is also possible for up to two carbon units R1 R2 which are contained in the cyclic structure R1 R2 15 to be substituted by heteroatom units, for example -0-, -S-, -N-R1 - or -P-R The present invention further relates to the aforementioned compounds as thermoplastic compositions which contain flame retardants, particularly 20 polycarbonate compositions which can also be impact-modified, and to mouldings which contain said thermoplastic compositions. The flame retardants according to the invention make it possible to produce thermoplastic compositions or mouldings which exhibit significantly improved dimensional stability under the effect of heat, good flowability and improved properties in relation to solvents (ESC behaviour). 5 The oligophosphates according to the invention can be used as flame retardants in thermoplastic compositions in amounts of 1 to 40 % by weight, preferably 2 to 25 % by weight, most preferably 3 to 20 % by weight, with respect to the weight of the composition. 10 The oligophosphates according to the invention can be produced by the esterification of suitable compounds which contain two aromatic hydroxy functions with a phosphoric acid diphenyl ester halide in the presence of a base, for example. One particularly preferred oligophosphate is obtained, for example, 15 by the esterification of trimethylcyclohexyl(TMC)-bisphenol with phosphoric acid diphenyl ester chloride in the presence of triethylamine, according to the following chemical equation: In addition to the flame retardants described above, the thermoplastic 20 compositions according to the invention, particularly polycarbonate compositions, can also contain other thermoplastic polymers, particularly polyester carbonates, polyesters, ABS graft copolymers and vinyl (co)polymers. These constituents, and other components which can be used in said compositions according to the invention, are described below by way of 25 examples. Component A Aromatic polycarbonates and/or aromatic polyester carbonates which are suitable according to the invention for component A are known from the literature or can 5 be produced by methods known from the literature (for the production of aromatic polycarbonates, see Schnell, "Chemistry and Physics of Polycarbonates", Interscience Publishers, 1964, and DE-AS 1 495 626, DE-A 2 232 877, DE-A 2 703 376, DE-A 2 714 544, DE-A 3 000 610 and DE-A 3 832 396, for example; for the production of aromatic polyester carbonates, see DE-A 3 10 077 934 for example). Aromatic polycarbonates are produced, for example, by the reaction of diphenols with carbonic acid halides, preferably phosgene, and/or with aromatic dicarboxylic acid dihalides, preferably benzene-dicarboxylic acid dihalides, by the phase 15 boundary method, optionally with the use of chain terminators, for example monophenols, and optionally with the use of tri-functional branching agents or branching agents which exhibit a functionality greater than three, for example triphenols or tetraphenols. 20 The preferred diphenols for the production of aromatic polycarbonates and/or aromatic polyester carbonate are those of formula (1) wherein 25 A is a single bond, a C1 to C5 alkylene, a C2 to C5 alkylidene, a C5 to C6 cycloalkylidene, -0-, -SO-, -CO-, -S-, -SO2-, or a C6 to C12 arylene, on which other aromatic rings, which optionally contain heteroatoms, can be condensed, or a radical of formulae (II) or (III) (II) (III) wherein B in each case denotes a C1 to C12 alkyl, preferably methyl, or denotes a 5 halogen, preferably chlorine and/or bromine, x denotes numbers which, independently of each other, are 0,1 or 2, p denotes 1 or 0, and R5 and R6 can be selected individually and independently of each other for each X , 10 and denote hydrogen or a C1 to C6 alkyl, preferably hydrogen, methyl or ethyl, X1 denotes carbon, and m is an integer from 4 to 7, preferably 4 or 5, with the proviso that at on least one atom X1, R5 and R6 simultaneously denote an alkyl. 15 The preferred diphenols are hydroquinone, resorcinol, dihydroxydiphenols, bis-(hydroxyphenyl)-C1-C5 alkanes, bis-(hydroxyphenyl)-C5-C6-cycloalkanes, bis-(hydroxyphenyl) ethers, bis-(hydroxyphenyl) sulphoxides, bis-(hydroxyphenyl) ketones, bis-(hydroxyphenyl) sulphones and α,α-bis-(hydroxyphenyl)-diisopropyl- 20 benzenes, as well as derivatives thereof which comprise brominated and/or chlorinated nuclei. The diphenols which are particularly preferred are 4,4'-dihydroxydiphenyl, bisphenol A, 2,4-bis(4-hydroxyphenyl)-2-methylbutane, l,l-bis-(4-hydroxyphenyl)- cyclohexane, 1,1 -bis-(4-hydroxyphenyl)-3.3.5-trimethylcyclohexane, 4,4'- 5 dihydroxy-diphenyl sulphide, 4,4'-dihydroxydiphenylsulphone, and di- and tetrabrominated or chlorinated derivatives thereof, such as 2,2-bis(3-chloro-4-hydroxyphenyl)-propane, 2,2-bis-(3,5-dichloro-4-hydroxyphenyl)-propane, or 2,2- , bis-(3,5-dibromo-4-hydroxyphenyl)-propane. 2,2-bis (4-hydroxyphenyl)-propane (bisphenol A) is particularly preferred. 10 These diphenols can be used individually or as any desired mixtures. They are known from the literature or can be obtained by methods known from the literature. Examples of chain terminators which are suitable for the production of 15 thermoplastic, aromatic polycarbonates include phenol, p-chlorophenol, p-tert-butylphenol or 2,4,6tribromophenol, and also include long chain alkylphenols such as 4-(l,3-tetramethylbutyl)-phenol according to DE-A 2 842 005 or monoalkylphenol or dialkylphenols having a total of 8 to 20 carbon atoms in their alkyl substituents, such as 3,5-di-tert. butyl phenol, p-iso-octylphenol, p-tert.-20 octylphenol, p-dodecylphenol, 2-(3,5dimethylheptyl)-phenol and 4-(3,5-dimethylheptyl)-phenol. The amount of chain terminators used generally ranges between 0.5 mol % and 10 mol %, with respect to the molar sum of the diphenols used in each case. 25 These thermoplastic, aromatic polycarbonates have average (weight average) molecular weights (Mw as measured by ultracentrifuge or of scattered light, for example) from 10,000 to 200,000. preferably from 15,000 to 80,000. The thermoplastic, aromatic polycarbonates can be branched in the known manner, 30 by the incorporation of 0.05 to 2.0 mol %, with respect to the sum of the diphenols used, of trifunctional compounds or compounds with a functionality greater than three, for example those comprising three or more phenolic groups. Both homopolycarbonates and copolycarbonates are suitable. 1 to 25 % by weigh preferably 2.5 to 25 % by weight, with respect to the total amount of diphenol used, of polydiorganosiloxanes comprising hydroxyaryloxy terminal groups ca 5 also be used as component A for the production of copolycarbonates according t the invention. These are known (US 3 419 634) and can be produced by method known from the literature. The production of copolycarbonates which contai polydiorganosiloxanes is described in DE-A 3 334 782. 10 Apart from bisphenol A homopolycarbonates, preferred polycarbonates als include copolycarbonates of bisphenol A comprising up to 15 mol %, with respec to the sum of the moles of diphenols, of other diphenols cited as being preferred c most preferred, particularly 2,2-bis(3,5-dibromo-4-hydroxyphenyl)-propane. 15 The preferred aromatic dicarboxylic acid dihalides for the production of th aromatic polyester carbonates are preferably the diacid dichlorides of isophthali acid, terephthalic acid, diphenylether-4,4'-dicarboxylic acid and naphthalene-2,6 dicarboxylic acid. 20 Mixtures of diacid dichlorides of isophthalic acid and terephthalic acid in a ratio between 1:20 and 20:1 are particularly preferred. During the production of the polyester carbonates, a carbonic acid halide, preferably phosgene, is used in conjunction as a Afunctional derivative of an acid. 25 Apart from the aforementioned monophenols, suitable chain terminators for the production of the aromatic polyester carbonates include chlorocarbonic acid esters thereof, as well as acid chlorides of aromatic monocarboxylic acids, which may optionally be substituted by C1 to C22 alkyl groups or by halogen atoms, as well as 30 aliphatic C2 to C22 monocarboxylic acid chlorides. The amount of chain terminators preferably ranges from 0.1 to 10 mol %, which in the case of phenolic chain terminators is given with respect to moles of diphenol and in the case of monocarboxylic acid chloride chain terminators is given with respect to moles of dicarboxylic acid dichloride. 5 The aromatic polyester carbonates can also contain incorporated aromatic hydroxycarboxylic acids. The aromatic polyester carbonates can either be linear or can be branched in the 10 known manner (see DE-A 2 940 024 and DE-A 3 007 934 in this respect). Examples of suitable branching agents include trifunctional carboxylic acid chlorides, or acid chlorides with a functionality greater than three, such as trimesic acid trichloride, cyanuric acid trichloride, 3,3'-,4,4'-benzophenone- 15 tetracarboxylic acid tetrachloride, 1,4,5,8-napthalene-tetracarboxylic acid tetrachloride or pyromellitic acid tetrachloride, in amounts of 0.01 to 1.0 mol % (with respect to the dicarboxylic acid dichloride used) or tri- or multi-functional phenols such as phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)- heptene-2,4,4-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4- 20 hydroxyphenyl)-benzene, l,l,l-tri-(4-hydroxyphenyl) ethane, tri-(4- hydroxyphenyl)-phenylmethane} 2,2-bis[4,4-bis(4-hydroxy-phenyl)-cyclohexyl]- prqpane, 2,4-bis(4-hydroxyphenyl-isopropyl)-phenol, tetra-(4-hydroxyphenyl)— methane, 2,6-bis(2-hydroxy-5-methyl-benzyl)-4-methyl-phenol, 2-(4- hydroxyphenyl)-2(2,4-dihydroxyphenyl)-propane, tetra-(4-[4-hydroxy-phenyl- 25 isopropyl]-phenoxy)methane or l,4-bis[4,4'-dihydroxytri-phenyl)-methyl]-benzene, in amounts of 0.01 to 1.0 mol % with respect to the diphenols used. Phenolic branching agents can be placed in the reaction vessel with diphenols, and acid chloride branching agents can be added together with the acid dichlorides. 30 In the thermoplastic, aromatic polyester carbonates, the proportion of carbonate structural units can be arbitrarily varied. The proportion of carbonate groups preferably ranges up to 100 mol %, particularly up to 80 mol %, most preferably up to 50 mol %, with respect to the sum of the ester groups and carbonate groups. Both the ester and the carbonate constituents of the aromatic polyester carbonates can exist in the form of blocks or can be randomly distributed in the 5 condensation polymer. The relative solution viscosities (η rel) of the aromatic polycarbonates and polyester carbonates falls within the range from 1.18 to 1.4, preferably 1.20 to 1.32 (as measured on solutions of 0.5 g polycarbonate or polyester carbonate in 100 ml 10 methylene chloride at 25°C). The thermoplastic, aromatic polycarbonates and polyester carbonates can be used on their own on in any admixture. 15 Component A is preferably contained in the compositions according to the invention in an amount of 5 to 95 % by weight, more preferably 10 to 90 % by weight, most preferably 20 to 80 % by weight, with respect to the weight of the composition. 20 Component B Component B comprises one or more graft polymers of B.l 5 to 95, preferably 30 to 90 % by weight, of at least one vinyl monomer on 25 B.2 95 to 5, preferably 70 to 10 % by weight of one or more graft bases with glass transition temperatures 30 Graft base B.2 generally has an average particle size (d50 value) of 0.05 to 10 pm, preferably 0.1 to 5 µm, most preferably 0.2 to 1µm. Monomers B.l are preferably mixtures of B.1.1 50 to 99 parts by weight of aromatic vinyl compounds and/or aromatic vinyl compounds comprising substituted nuclei (e.g. styrene, a- 5 methylstyrene, p-methylstyrene, p-chlorostyrene) and/or Ci-Cg alkyl esters of methacrylic acid (such as methyl methacrylate, ethyl methacrylate) and B.l.2 1 to 50 parts by weight of vinyl cyanides (unsaturated nitriles such as acrylonitrile and methacrylonitrile) and/or C1 - C8 alkyl esters of methacrylic 10 acid (such as methyl methacrylate, n-butyl acrylate, tert-butyl acrylate) and/or derivatives (such as anhydrides and imides) of unsaturated carboxylic acids (for example maleic anhydride and N-phenyl-maleinimide). 15 The preferred monomers B.1.1 are selected from at least one of the monomers styrene, a-methylstyrene and methyl methacrylate; the preferred monomers B.l.2 are selected from at least one of the monomers acrylonitrile, maleic anhydride and methyl methacrylate. 20 Monomers which are particularly preferred are styrene as B.1.1. and acrylonitrile as B.l.2. Examples of suitable graft bases B.2 for graft polymer B include diene rubbers, EP(D)M rubbers, namely those based on ethylene/propylene, and optionally diene, 25 acrylate, polyurethane, silicone chloroprene and ethylene/vinyl acetate rubbers. The preferred graft bases B.2 are diene rubbers (e.g. those based on butadiene or isoprene) or mixtures of diene rubbers, or copolymers of diene rubbers, or mixtures thereof with, other copolymerisable monomers (e,g. according, to B.1.1 30 and B.l .2), with the proviso that the glass transition temperature of component B.2 is Pure polybutadiene rubber is particularly preferred. Examples of particularly preferred polymers B include ABS polymers (emulsion, bulk and suspension ABS), such as those described in DE-A 2 035 390 (=US-PS 3 5 644 574) or in DE-A 2 248 242 (=GB-PS 1 409 275) and in Ullmanns Enzyklopadie der Technischen Chemie, Volume 19 (1980), page 280 et seq., for example. The gel content of graft base B.2 is at least 30 % by weight, preferably at least 40 % by weight (as measured in toluene). 10 Graft copolymers B are produced by radical polymerisation, e.g. by emulsion, suspension, solution or bulk polymerisation, preferably by emulsion or bulk polymerisation. Particularly suitable graft rubbers also include ABS polymers which are 15 produced by redox initiation using an initiator system comprising an organic hydroperoxide and ascorbic acid according to US-P 4 937 285. Since, as is known, graft monomers are not necessarily grafted completely on to the graft base during graft reaction, graft polymers B are also to be understood 20 according to the invention as those products which are obtained by (co)polymerisation of the graft monomers in the presence of the graft base and which are also present after work-up. Suitable acrylate rubbers B.2 of polymers B are preferably polymers of acrylic 25 acid alkyl esters, optionally with up to 40 % by weight, with respect to B.2, of other polymerisable, ethylenically unsaturated monomers. The preferred polymerisable acrylic acid esters comprise C1 to C8 alkyl esters, for example methyl, ethyl, butyl, n-octyl- and 2-ethylhexyl esters; halogenoalkyl esters, preferably halogeno-C1 - C8 alkyl esters such as chloromethyl acrylate, as well as 30 mixtures of these monomers. Monomers comprising more than one polymerisable double bond can be copolymerised to effect crosslinking. Preferred examples of crosslinking monomers include esters of unsaturated monocarboxylic acids comprising 3 to 8 C atoms and unsaturated monohydric alcohols comprising 3 to 12 C atoms, or 5 saturated polyols comprising 2 to 4 OH groups and 2 to 20 C atoms, such as ethylene glycol dimethacrylate, allyl methacrylate; multiply-unsaturated heterocyclic compounds, such as trivinyl- and triallyl cyanurates; poly-functional vinyl compounds, such as di- and trivinylbenzenes; and also triallyl phosphate and diallyl phthalate. 10 The preferred crosslinking monomers are allyl methacrylate, ethylene glycol dimethacrylate, diallyl phthalate and heterocyclic compounds which contain at least three ethylenically unsaturated groups. 15 Crosslinking monomers which are particularly preferred are the cyclic monomers triallyl cyanurate, triallyl isocyanurate, triacryloyl hexahydro-s-triazine, and triallylbenzenes. The amount of crosslinked monomer is preferably 0.02 to 5, particularly 0.05 to 2 % by weight, with respect to the graft base B.2. 20 When using cyclic crosslinking monomers comprising at least three ethylenically unsaturated groups, it is advantageous if the amount thereof is limited to less than 1 % by weight of graft base B.2. Examples of preferred "other" polymerisable, ethylenically unsaturated 25 monomers which can optionally be employed apart from esters of acrylic acid for the production of graft base B.2, include acrylonitrile, styrene, a-methylstyrene, acrylamide, vinyl-(C1-C6 alkyl) ethers, methyl methacrylate and butadiene. The preferred acrylate rubbers for use as graft base B.2 are emulsion polymers which have a gel content of at least 60 % by weight. 30 Other suftable graft bases B.2 are silicone rubbers with graft-active sites, such as those described in DE-A 3 704 657, DE-A 3 704 655, DE-A 3 631 540 and DE-A 3 631539. 5 The gel content of graft base B.2 is determined at 25°C in a suitable solvent (M. Hoffmann, H. Kromer, R. Kuhn, Polymeranalytik I and II, Georg Thieme-Verlag, Stuttgart 1977). The average particle size d50 is the diameter above and below which 50 % by weight 10 of the particles occur. It can be determined by ultracentrifuge measurements (W. Scholtan, H. Lange, Kolloid, Z. and Z. Polymere 250 (1972), 782-1796). Component B is preferably contained in the compositions according to the invention in an amount ranging from 1 to 60 % by weight, more preferably from 1 to 40 % by 15 weight, most preferably from 2 to 30 % by weight, with respect to the weight of the composition. Component C 20 Component C comprises one or more thermoplastic vinyl (co)polymers C.l and/or polyalkylene terephthalates C.2. Polymers which are suitable as vinyl (copolymers C.l are polymers of at least one monomer from the group comprising aromatic vinyl compounds, vinyl cyanides 25 (unsaturated nitriles), (C1 to C8) alkyl esters of (meth)acrylic acid, unsaturated carboxylic acids, and derivatives (such as anhydrides and imides) of unsaturated carboxylic acids. Polymers which are particularly suitable are (co)polymers of C.l.l 50 to 99, preferably 60 to 80 parts by weight of aromatic vinyl compounds 30 and/or of aromatic vinyl compounds comprising substituted nuclei, such as styrene, a-methyl-styrene, p-methylstyrene, p-chlorostyrene, and/or (Ci to Cg) alkyl esters of (meth)acrylic acid such as methyl methacrylate or ethylmethacrylate), and C.1.2 1 to 50, preferably 20 to 40 parts by weight of vinyl cyanides (unsaturated 5 nitriles) such as acrylonitrile and methacrylonitrile, and/or (Ci to Cg) alkyl esters of (meth)acrylic acid (such as methyl methacrylate, n-butyl acrylate, tert.-butylacrylate) and/or unsaturated carboxylic acids (such as maleic acid) and/or derivatives (such as anhydrides and imides) of unsaturated carboxylic acids (for example maleic anhydride and N-phenyl-maleinimide). 10 (Co)polymers C. 1 are resin-like, thermoplastic and free from rubber. A particularly preferred copolymer is that formed from styrene as C.l.l and acrylonitrile as C. 1.2. 15 (Co)polymers as defined by C.l are known, and can be produced by radical polymerisation, particularly by emulsion, suspension, solution or bulk polymerisation. These (co)polymers preferably have average molecular weights Mw (weight average molecular weights, as determined by light scattering or 20 sedimentation) between 15,000 and 200,000. The polyalkylene terephthalates of component C.2 are reaction products formed from aromatic dicarboxylic acids or reactive derivatives thereof, such as dimethyl esters or anhydrides, and aliphatic, cycloaliphatic or araliphatip diols, as well as 25 mixtures of said reaction products. The preferred polyalkylene terephthalates contain at least 80 % by weight, preferably at least 90 % by weight, with respect to the dicarboxylic acid component, of terephthalic acid radicals, and at least 80 % by weight, preferably at 30 least 90 mol %, with respect to the diol component, of ethylene glycol and/or 1,4-butanediol radicals. Apart from terephthalic acid radicals, the preferred polyalkylene terephthalates can contain up to 20 mol %, preferably up to 10 mol %, of radicals of other aromatic or cycloaliphatic dicarboxylic acids comprising 8 to 14 C atoms, or of aliphatic dicarboxylic acids comprising 4 to 12 C atoms, such as radicals of phthalic acid, isophthalic acid, naphthalene-2,6-dicarboxylic acid, 4,4'-diphenyldicarboxylic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, cyclohexane-diacetic acid. Apart from ethylene glycol or 1,4-butanediol radicals, the preferred polyalkylene terephthalates can contain up to 20 mol %, preferably up to 10 mol %, of other aliphatic diols comprising 3 to 12 C atoms or of cycloaliphatic diols comprising 6 to 21 C atoms, e.g. radicals of 1,3-propanediol, 2-ethylpropanediol-l,3, neopentyl glycol, 1,5-pentanediol, 1,6-hexanediol, cyclohexane-dimethanol-1,4, 3-ethylpentanediol-2,4, 2methylpentanediol-2,4, 2,2,4-trimethylpentanediol-l,3, 2-ethylhexane-diol-1,3, 2,2diethylpropanediol-l,3, 2,5-hexanediol, l,4-di-(B-hydroxyethoxy)-benzene, 2,2-bis-(4- hydroxycyclohexyl)-propane, 2,4-dihydroxy-1,1,3,3-tetramethyl-cyclobutane, 2,2-bis-(4B-hydroxyethoxy-phenyl)-propane, and 2,2-bis-(4-hydroxypropoxyphenyl)-propane (DE-A 2 407 674, 2 407 776, 2 715 932). The polyalkylene terephthalates can be branched by the incorporation of relatively small amounts of tri- or tetrahydric alcohols or tri- or tetrabasic carboxylic acids, e.g. according to DE-A 1 900 270 and US-PS 3 692 744. Examples of preferred branching agents include trimesic acid, trimellitic acid, trimethylolethane and -propane and pentaerythritol. Polyalkylene terephthalates are particularly preferred which are produced solely from terephthalic acid and reactive derivatives thereof (e.g. dialkyl esters thereof) and ethylene glycol and/or 1,4-butanediol, as well as mixtures of said polyalkylene terephthalates. Mixtures of polyalkylene terephthalates contain from 1 to 50 % by weight, preferably from 1 to 30 % by weight, of polyethylene terephthalate and from 50 to 99 % by weight, preferably from 70 to 99 % by weight, of polybutylene terephthalate. 5 The polyalkylene terephthalates which are preferably used generally have a limiting viscosity of 0.4 to 1.5 dl/g, preferably 0.5 to 1.2 dl/g, as measured in phenol/o-dichlorobenzene (in a 1:1 ratio by weight) at 25°C in an Ubbelohde viscometer. The polyalkylene terephthalates can be produced by known methods (e.g. 10 Kunststoff-Handbuch, Volume VIII, page 695 et seq., Carl-Hanser-Verlag, Munich 1973). Component C is preferably contained in the compositions according to the invention in an amount from 0 to 50 % by weight, more preferably up to 30 % by 15 weight and most preferably up to 20 % by weight, with respect to the weight of the composition. Component D 20 Component D comprises very finely divided inorganic powders. The very finely divided inorganic powders D which are used according to the invention preferably consist of one or more metals of Main Groups 1 to 5 or Subgroups 1 to 8 of the periodic table, preferably of Main Groups 2 to 5 or 25 Subgroups 4 to 8, most preferably of Main Groups 3 to 5 or Subgroups 4 to 8, or are compounds of these metals with at least one element selected from oxygen, hydrogen, sulphur, phosphorus, boron, carbon, nitrogen or silicon. Examples of preferred compounds include oxides, hydroxides, hydrated oxides, 30 sulphates, sulphites, sulphides, carbonates, carbides, nitrates, nitrites, nitrides, borates, silicates, phosphates, hydrides, phosphites or phosphonates. The very finely divided inorganic powders preferably consist of oxides, phosphates or hydroxides, most preferably of TiO2, SiO2, SnO2, ZnO, ZnS, boehmite, ZrO2, A12O3, aluminium phosphate or iron oxides, or of TiN, WC, A1O(OH), SB2O3, NaSO4, vanadium oxides, zinc borate, silicates such as Al 5 silicates, Mg silicates, and one-, two and three-dimensional silicates. Mixtures and doped compounds can also be used. Moreover, these nano-scale particles can be surface-modified with organic molecules in order to improve the compatibility thereof with polymers. 10 Hydrophobic or hydrophilic surfaces can be produced in this manner. Hydrated aluminas such as boehmite, or TiO2, are particularly preferred. The average particle diameters of the nano-particles are less than or equal to 15 1000 mn, preferably less than or equal to 500 nm, particularly 1 to 100 nm. The terms "particle size" and "particle diameter" always denote the average particle diameter d50 as determined by ultracentrifuge measurements according to W. Scholtan et al., Kolloid-Z. and Z. Polymere 250 (1972), pages 782-796. 20 The inorganic powders are incorporated in the thermoplastic moulding composition in amounts from 0 to 40, preferably from 0 to 25, most preferably from 0.1 to 15 % by weight, with respect to the thermoplastic material. 25 The inorganic compounds can be present as powders, pastes, sols, dispersions or suspensions. Powders can be obtained by precipitation from dispersions, sols or suspensions. The powders can be incorporated in the thermoplastic moulding compositions by 30 customary methods, for example by the direct kneading or extrusion of moulding compositions and the very finely divided inorganic powders. Component E The flame retardants according to the invention can be used in combination with what are termed anti-dripping agents, which reduce the tendency of the material 5 to drip as burning droplets in the event of fire. Examples of suitable anti-dripping agents include compounds from the classes of substances comprising fluorinated polyolefines, silicones and aramid fibres. These can also be used in the compositions according to the invention. Fluorinated polyolefines are preferably used as anti-dripping agents. 10 Fluorinated polyolefines are known, and are described in the EP-A 0 640 655 for example. They are sold by DuPont under the Trade Mark Teflon® 30N. These fluorinated polyolefines can be used either in pure form or in the form of a 15 coagulated mixture comprising emulsions of fluorinated polyolefines with emulsions of the graft polymers (component B) or with an emulsion of a copolymer, preferably a styrene/acrylonitrile-based copolymer, wherein the fluorinated polyolefine is mixed as an emulsion with an emulsion of the graft polymer or of the copolymer and is subsequently coagulated. 20 Furthermore, fluorinated polyolefines can be used as a preliminary compound with the graft polymer (component B) or with a copolymer, preferably a styrene/acrylonitrile based copolymer. The fluorinated polyolefines are mixed as powders with a powder or with granules of the graft polymer or copolymer and 25 are compounded in the melt, generally at temperatures from 200 to 330°C in customary processing units such as internal kneaders, extruders or twin-shaft continuous screw devices. The fluorinated polyolefines can also be used in the form of a master batch 30 which is produced by the emulsion polymerisation of at least one monoethylenically unsaturated monomer in the presence of an aqueous dispersion of the fluorinated polyolefine. The preferred monomer components are styrene, acrylonitrile and mixtures thereof. After precipitation by acid and subsequent drying, the polymer is used as a free-flowing powder. The coagulates, preliminary compounds or master batches usually have solids 5 contents of fmorinated polyolefines from 5 to 95 % by weight, preferably 7 to 60 % by weight. The compositions can contain fluorinated polyolefines in amounts from 0 to 4 % by weight, preferably up to 2 % ty weight, and most preferably from 0.1 to 0.5 % by weight, with respect to the weight of the composition. 10 F. Other additives The moulding compositions according to the invention can also contain at least one of the customary additives such as internal lubricants and demoulding agents, for example pentaerythritol tetrastearate, nucleating agents, anti-static 15 agents, stabilisers, fillers and reinforcing agents such as glass or carbon fibres, talc, wollastonite, mica, kaolin, CaCC>3 and glass flakes, as well as colorants and pigments. The moulding compositions according to the invention can contain up to 35 % by 20 weight, with respect to the moulding composition, of a further flame retardant which optionally has a synergistic effect. Examples of further flame retardants include compounds which contain phosphorus, such as organophosphates, organophosphonates, phosphonatamines or phosphazenes, organic halogen compounds such as decabromobisphenyl ether, tetrabromobisphenol, inorganic 25 halogen compounds such as ammonium bromide, nitrogen compounds such as melamine and melamineformaldehyde resins, inorganic hydroxide compounds such as Mg or Al hydroxide, inorganic compounds such as antimony oxide, barium metaborate, hydroxoantimonate, zirconium oxide, zirconium hydroxide, molybdenum oxide, ammonium molybdate, zinc borate, ammonium borate, barium 30 metaborate, talc, silicates, aluminosilicates, silica and tin oxide, as well as siloxane compounds. Apart from the very finely divided inorganic powders cited as component D, talc is also preferably used as a synergistic flame retardant (FR). The term "talc" is to be understood to mean a naturally occurring or synthetically produced talc which is optionally calcined. 5 The chemical composition of pure talc corresponds to the formula 3MgO.4SiO2.H2O and it thus has an MgO content of 31.9 % by weight, an SiO2 content of 63.4 % by weight and a content of chemically bound water of 4.8 % by weight. It is a silicate with a layer structure. 10 Naturally occurring talc materials generally do not have the aforementioned ideal composition, since they are contaminated due to the partial replacement of the magnesium by other elements, by the partial replacement of silicon by aluminium for example, and/or by growths of other minerals such as dolomite, magnesite or 15 chlorite. Particularly high purity types of talc are preferably used, which are characterised by an MgO content of 28 to 35 % by weight, preferably 30 to 33 % by weight, most preferably 30.5 to 32 % by weight, and an SiO2 content of 55 to 65 % by 20 weight, preferably 58 to 64 % by weight, most preferably 60 to 62.5 % by weight. The most preferred types of talc are further characterised by an A12O3 content less than 5 % by weight, most preferably less than 1 % by weight, particularly less than 0.7 % by weight. 25 The talc according to the invention is advantageously used in the form of finely ground types which are optionally surface-modified (silanised), with a largest average particle size d50 of 30 The moulding compositions according to the invention are produced by mixing the respective constituents in the known manner and by compounding and extruding them in the melt at temperatures from 200°C to 300°C in customary processing units such as internal kneaders, extruders and twin-shaft continuous screw devices. Mixing of the individual constituents can be effected in the known manner, either 5 successively or simultaneously, and can be conducted either at about 20°C (room temperature) or at an elevated temperature. The moulding compositions according to the invention can be used for the production of mouldings of any type, which can be produced by injection 10 moulding, extrusion or blow-moulding methods. Another form of processing is the production of mouldings by thermoforming them from previously produced sheet or film. Example of these mouldings are sheeting, sections, housing parts of all types, 15 e.g. for domestic appliances such as juice presses, coffee machines, mixers; for office equipment such as monitors, printers, copiers; sheeting, tubes, electrical installation conduits, windows, doors and other sections for the construction industry (interior fittings and exterior applications), as well as electrical and electronic parts such as switches, plugs and sockets. 20 In particular, the moulding compositions according to the invention can also be used for the production of the following mouldings or moulded components, for example: 25 Interior fitting components for railway vehicles, ships, aircraft, buses and other motor vehicles, exterior bodywork parts in the automobile industry, housings for electrical appliances which contain miniature transformers, housings for information processing and transmission devices, housings and coverings for medical equipment, massage equipment and housings for it, toy vehicles for 30 children, sheet-like wall elements, housings for safety devices, thermally insulated transport containers, apparatuses for housing or transporting small animals, mouldings for sanitary and bath fittings, covering grilles for ventilation penings, mouldings for garden buildings and tool sheds or housings for garden equipment. The following examples explain the invention in more detail. 5 Example 1 5 Examples 1 to 4 illustrate the production of flame retardants according to the invention A compound containing phosphorus according to the invention was obtained by the following reaction: 1.1 kg 3,3,5-trimethylcyclohexyl(TMC)-bisphenol and 1.0 1 triethylamine were 10 introduced at 5°C in 2.0 1 tetrahydrofuran. 2.0 kg phosphoric acid diphenyl ester chloride were steadily added drop-wise over a period of 2.5 hours at 5 to 9°C. The batch was subsequently stirred for 18 hours at room temperature. The salts were filtered off under suction and washed with tert.-butyl methyl ether (3 x 400 ml). The combined organic phases were washed with 1 N sodium hydroxide 15 solution (3 x 500 ml) and water (500 ml), dried over magnesium sulphate and concentrated by evaporation. The residue was dissolved in dichloromethane (1000 ml) and was once again extracted with 1 N sodium hydroxide solution (3 x 1000 ml), and was then dried over magnesium sulphate and concentrated by evaporation. 2.0 kg of the white solid target compound (1) were thus obtained in 20 a purity of 99 %, corresponding to 73 % theoretical. The following analysis results were obtained for this substance: HPLC-MS: purity > 99 % of area MS (ES+): 775 (24) [MH+], 792 (100) [M+ + H20] 25 P: elemental analysis: 7.9 % (theoretical value 8.0 %) DIN acid number: 0.25 Melting point: 89°C Example 2 A compound containing phosphorus according to the invention was obtained by the following reaction: (2) 5 0.5 kg cyclohexyl-l,l-bis(4-phenol) and 0.40 kg triethylamine were introduced at 0°C into 1.5 1 tetrahydrofuran. 1.05 kg phosphoric acid diphenyl ester chloride were steadily added drop-wise over a period of 3.5 hours at -5 to 12°C. The batch was subsequently stirred for 18 hours at room temperature. The salts were filtered off 10 under suction and washed with tert.-butyl methyl ether (4 x 1000 ml). The combined organic phases were washed with 1 N sodium hydroxide solution (5 x 500 ml) and water (500 ml), dried over magnesium sulphate and concentrated by evaporation. 1.25 kg of compound (2) were thus obtained in a purity of 100 %, corresponding to 91 % theoretical. The following analysis results were obtained for this substance: 15 HPLC: purity: 100% of area MS (ES4): 733 (100) [MH+] P: elemental analysis: 8.0 % (theoretical value 8.4 %) DIN acid number: 0.76 20 Example 3 A compound containing phosphorus according to the invention was obtained by the following reaction: 0.5 kg 3-methylcyclohexyl-l,l-bis(4-phenol) and 0.38 kg triethylamine were introduced at 0°C into 1.5 1 tetrahydrofuran. 1.00 kg phosphoric acid diphenyl 5 ester chloride was steadily added drop-wise over a period of 4.3 hours at -8 to 13°C. The batch was subsequently stirred for 18 hours at room temperature. The salts were filtered off under suction and washed with THF (1500 ml) and tert.-butyl methyl ether (2 x 1000 ml). The combined organic phases were washed with 1 N sodium hydroxide solution (5 x 500 ml) and water (500 ml), dried over 10 magnesium sulphate and concentrated by evaporation. 1.27 kg of compound (3) were thus obtained in a purity of 100 %, corresponding to 96 theoretical. The following analysis results were obtained for this substance: HPLC: purity: 100 % of area 15 MS (ES+): 747 (100) [MH+] P: elemental analysis: 8.0 % (theoretical value 8.3 %) DIN acid number: 0.54 Example 4 20 (4) A compound containing phosphorus according to the invention was obtained by the following reaction: 0.15 kg decahydronaphthyl-2,2-bis(4-phenol) and 0.10 kg triethylamine were introduced at 0°C into 1.0 1 tetrahydrofuran. 0.26 kg phosphoric acid diphenyl ester chloride was steadily added drop-wise over a period of 2.5 hours at -2 to 18°C. The batch was subsequently stirred for 18 hours at room temperature . The salts were 5 filtered off under suction and washed with tert.-butyl methyl ether (3 x 700 ml). The combined organic phases were washed with 1 N sodium hydroxide solution (5 x 500 ml) and water (500 ml), dried over magnesium sulphate and concentrated by evaporation. 0.36 kg of compound (4) was thus obtained in a purity of 67 % (balance: triphenyl phosphate), corresponding to 66 % theoretical. The following 10 analysis results were obtained for this substance: HPLC: purity: 67 % of area MS(ES4): 787(100)[MH+] P: elemental analysis: 7.9 % (theoretical value 7.9 %) 15 DIN acid number: 0.27 General methods of analysis HPLC - HPLC measurements on the substance from Example 1 were performed 20 using an Agilent 1100 chromatograph with an HTS PAL injector supplied by CTC Analytics. Separations were made on an Inertsil ODS-3 stationary phase (length: 250 mm, inside diameter 2.1 mm, particle size 5 urn) at 40°C and at a flow rate of 0.2 ml/min. The liquid phase consisted of a gradient of A (water + 0.01 % formic acid) and B (acetonitrile + 0.05 % formic acid) comprising 5 % B at 0 minutes and a 25 gradient of up to 100 % B at 20 minutes, and then 100 % B at 30 minutes. UV measurements were made at λ = 214 nm. HPLC measurements on the substances from Examples 2 to 4 were performed using an Agilent 1100 chromatograph with an HTS PAL injector supplied by CTC 30 Analytics. Separations were made on a Nucleosil C18 stationary phase (length: 50 mm, inside diameter 2 mm, particle size 3 µm) at 35°C and at a flow rate of 0.5 ml/min. The liquid phase consisted of a gradient of A (water + 0.05 % formic acid) and B (acetonitrile + 0.05 % formic acid) comprising 5 % B at 0 minutes and a gradient of up to 100 % B at 12 minutes, and then 100 % B at 15 minutes. UV measurements were made at X = 210 to 500 nm. 5 MS - Mass spectra of the substance from Example 1 were measured using a Finnigan TSQ 700 spectrophometer with (+) electrospray in the m/z range from 200 to 1500. Mass spectra of the substances from Examples 2 to 4 were measured using a 10 Waters ZMD 2000 spectrophometer with (+) electrospray in the m/z range from 110 to 1500. Acid number - The acid number was determined at least twice according to DIN 53 402. The average value is given. About 1 g sample was accurately weighed (to 15 0.001 g) into the titration vessel and was dissolved in 50 ml of a mixture comprising 2 parts by volume toluene and 1 part by volume ethanol (95 % by volume). For difficultly soluble substances, it was possible to increase the amount of solvent by up to three times, or up to 25 ml acetone was added. After adding 2 to 3 drops of phenolphthalein solution at room temperature, the solution was 20 rapidly titrated with alcoholic KOH (prepared by dissolving 5.611 g KOH in ethanol (95 % by volume) until the red coloration which was formed remained for at least 10 seconds (consumption a). During the titration it had to be ensured that no precipitates formed. The latter could be re-dissolved if necessary by adding a little solvent. A blank test was performed in the same manner but without any 25 sample (consumption b). The acid number in mg KOH/g was calculated from the following equation: For c(KOH) = 0.1 mol/1: acid number - (a-b)x5.61 30 E where a consumption in ml of KOH solution during the titration of the sample b consumption in ml of KOH solution in blank test E amount weighed in (g) 5.61 factor for converting ml KOH solution, c(KOH) = 0.1 mol/1, into mg KOH 5 Production and testing of moulding compositions according to the invention and of comparison moulding compositions Thermoplastic polycarbonate moulding compositions 1 to 5 (according to the invention) and VI and V2 (comparison) were produced using the oligophosphates 10 from Examples 1 to 4 and using known oligophosphates. The compositions of the moulding compositions are given in Table 1. The components listed in Table 1, which are briefly explained below, were compounded in a 3 litre internal kneader or in a ZSK-25 device at 240°C. The 15 mouldings were produced in an Arburg 270 E injection moulding machine at 240°. Component A. 1 A linear polycarbonate based on bisphenol A with a relative solution viscosity of 20 1.24, as measured in CH2C12 as the solvent at 25°C and at a concentration of 0.5 g/100ml. Component A.2 25 A linear polycarbonate based on bisphenol A with a relative solution viscosity of 1.25, as measured in CH2Cl2 as the solvent at 25°C and at a concentration of 0.5 g/100 ml. Component B.l 30 A graft polymer comprising 40 parts by weight of a copolymer of styrene and acrylonitrile in a ratio of 73:27 on 60 parts by weight of particulate crosslinked poly- butadiene rubber (average particle diameter d50 = 0-3 µm), produced by emulsion polymerisation. Component B.2 A graft polymer comprising 84 parts by weight of a copolymer of styrene and acrylonitrile in a ratio of 73:27 on 16 parts by weight of crosslinked polybutadiene rubber produced by bulk polymerisation. Component C A styrene/acrylonitrile copolymer with a ratio by weight of styrene to acrylonitrile of 72:28 and a limiting viscosity of 0.55 dl/g (as measured in dimethylformamide at 20°C). Component D. 1 An oligophosphate based on bisphenol A Component D.2 The TMC-bisphenol diphosphate from Example 1. Component P. 3 The methylcyclohexyl-bisphenol diphosphate from Example 3. Component D.4 The cyclohexyl-bisphenol diphosphate from Example 2. 5 Component E.l Talc: Naintsch® A3 (Naintsch Mineral werke GmbH, Graz, Austria) with an average particle diameter of 1.2 µm. 10 Component E.2 Pural® 200, a nano-scale aluminium hydroxide [AIO(OH)], average particle size approximately 50 nm (supplied by Condea, Hamburg, Germany) 15 Component F. 1 A tetrafluorethylene polymer as a coagulated mixture comprising a SAN graft polymer emulsion of the aforementioned component B in water and a 5 tetrafluorethylene polymer emulsion in water. The ratio by weight of graft polymer B to tetrafluorethylene polymer E in the mixture was 90 % by weight to 10 % by weight. The tetrafluorethylene polymer emulsion had a solids content of 60 % by weight and an average particle diameter between 0.05 and 0.5 µm. The SAN graft polymer emulsion had a solids content of 34 by weight and an average 10 latex particle diameter of d50 = 0.3 µm. The emulsion of tetrafluorethylene polymer (Teflon® 30 N) was mixed with the emulsion of SAN graft polymer B and was stabilised with 1.8 % by weight, with respect to polymer solids, of phenolic antioxidants. The mixture was coagulated 15 at 85 to 95°C with an aqueous solution of MgSO4 (Epsom salts) and acetic acid at pH 4 to 5, filtered, and washed until it was practically free from electrolytes; it was then freed from the bulk of the water by centrifugation and thereafter was dried at 100°C to form a powder. 20 Component F.2 Blendex® 449: A PTFE preparation supplied by of General Electric Plastics, comprising 50 % by weight PTFE and 50 % by weight of an SAN copolymer. 25 Component G.l A phosphite stabiliser Component G.2 30 Pentaerythritol tetrastearate (PETS) as a demoulding agent Testing of the moulding compositions according to the invention The Vicat B and HDT/A resistances to thermal deformation was determined according to DIN 53 460 (ISO 306) and ISO 75, respectively, on bars of 5 dimensions 80 mm x 10 mm x 4 mm. The notched bar impact value at was determined according to ISO 180/1 A. The behaviour in fire of the samples was measured according to UL 94 V on bars 10 of thickness 1.6 and 3.2 mm. The UL 94 V-Test was performed as follows: Samples of substances were moulded into bars of dimensions 127 mm x 12.7 mm 15 x 1.6 (3.2) mm. The bars were mounted vertically so that the underside of the specimen was situated 305 mm above a strip of wadding material. Each test bar was ignited individually by means of two successive ignition operations of 10 seconds duration, the burning properties after each ignition were observed, and thereafter the sample was assessed. A Bunsen burner with a blue flame 10 mm (3.8 20 inches) high was used to ignite the samples. The gas supplied to the burner was natural gas with a calorific value of 3.73 x 104kj/m3 (1000 BTU per cubic foot). The UL 94 V-0 Classification covers the properties of materials described below, which were tested according to the UL 94 V regulations. The moulding 25 compositions in this class contained no samples which burned for longer than 10 seconds after each application of the test flame; they did not exhibit a total after-burn time of more than 50 seconds after two applications of the flame to each set of specimens comprising five bars; they contained no specimens which burned away completely down to the holding clamp fixed to the upper end of the 30 specimen; they comprised no specimens which ignited the wadding under the specimen due to burning drops or particles; they also contained no specimens which glowed for longer than 30 seconds after the test flame was removed. Other UL 94 Classifications designate specimens which are less flame-retardant or less self-extinguishing, because they give off flaming droplets or particles and/or exhibit longer total after-burn times. These classifications are denoted by 5 UL 94 V-1 and V-2. N.R. denotes "non-resistant", and is the classification of specimens for which repeated after-burn times of > 30 seconds were observed on the first and/or second application of the flame, or for which the total after-burn time exceeded 250 seconds on all 10 applications of the flame. 10 The stress cracking behaviour (ESC behaviour) was tested on bars of dimensions 80 mm x 10 mm x 4 mm. A mixture of toluene (60 % by volume) and isopropanol (40 by volume) was used as the test medium. The specimens were pre-stretched by means of a template in the form of a circular arc (pre-stretching in percent) and were stored in the test medium at room temperature. The stress 15 cracking behaviour was assessed via the formation of cracks or breaks in the test medium as a function of pre-stretching. The melt viscosity was determined at 260°C and at a shear rate of 1000 sec*1 according to DIN 54811. The MVR (melt volume rate) was determined 20 according to ISO 1133 at 240°C using a plunger load of 5 kg. The properties of the compositions according to the invention or of mouldings obtained therefrom are listed in Table 1. Table 1 WE CLAIM: 1. Oligophosphates selected from the group consisting of wherein n in each case denotes an integer from 1 to 30. 2. Oligophosphate as claimed in claim 1 of formula wnerein denotes an integer from 1 to 30. 3. Oligophosphate as claimed in claim 1 of formula wherein n denotes an integer from 1 to 30.. Oligophosphate as claimed in claim 1 of formula wherein n denotes an integer from 1 to 30. 5. A thermoplastic composition containing at least one thermoplastic resin and an oligophosphate as claimed in any one of claims 1 to 4. 6. A thermoplastic composition as claimed in claim 5, wherein the thermoplastic resin is selected from a polycarbonate, a polyester carbonate, a polyphenylene oxide, a polyester, a polyamide, a polyester amide, vinyl (co)polymers and acrylic/butadiene/styrene (ABS) copolymers. 7. A thermoplastic composition as claimed in claim 5 or 6, comprising a polycarbonate, wherein, with respect to the weight of the composition, said composition contains up to 50 % by weight of a graft polymer comprising 5 to 95 % by weight of at least one vinyl monomer on 95 to 5 % by weight of at least one graft base having a glass transition temperature lower than about 10°C. 8. A thermoplastic composition as claimed in claim 7, wherein the graft polymer is a diene-, EP(D)M-, acrylate- or silicone rubber-based polymer. 9. A thermoplastic composition as claimed in any one of claims 7 or 8 which contains emulsion- or bulk-polymerised ABS or mixtures thereof as a graft polymer. 10. A thermoplastic composition as claimed in any one of claims 5 to 9, which contains a fluorinated polyolefin. 11. A thermoplastic composition as claimed in any one of claims 5 to 10, which contains a nano-scale inorganic material or talc. 12. A moulding composition containing a thermoplastic composition as claimed in any one of claims 5 to 11. Dated this June 12 ,2003. (DR. ANUSHRI GUPTA) OF REMFRY AND SAGAR ATTORNEY FOR THE APPLICANTS

Documents:

597-mumnp-2003-cancelled page(14-09-2007).pdf

597-mumnp-2003-claim(granted)-(14-09-2007).pdf

597-mumnp-2003-claims(granted)-(14-09-2007).doc

597-mumnp-2003-correspondence(ipo)-(13-09-2006).pdf

597-mumnp-2003-correspondence1(09-07-2007).pdf

597-mumnp-2003-correspondence2(18-09-2007).pdf

597-mumnp-2003-form 1(12-06-2003).pdf

597-mumnp-2003-form 13(26-07-2007).pdf

597-mumnp-2003-form 18(14-12-2005).pdf

597-mumnp-2003-form 2(granted)-(14-09-2007).doc

597-mumnp-2003-form 2(granted)-(14-09-2007).pdf

597-mumnp-2003-form 3(09-07-2007).pdf

597-mumnp-2003-form 3(12-06-2003).pdf

597-mumnp-2003-form 3(18-11-2003).pdf

597-mumnp-2003-form 5(12-06-2003).pdf

597-mumnp-2003-form-pct-ipea-409(12-06-2003).pdf

597-mumnp-2003-form-pct-isa-210(12-06-2003).pdf

597-mumnp-2003-petition under rule 137(28-08-2003).pdf

597-mumnp-2003-petition under rule 138(09-07-2007).pdf

597-mumnp-2003-power of authority(09-07-2007).pdf

597-mumnp-2003-power of authority(12-06-2003).pdf