Title of Invention

METHOD FOR PRODUCING ACRYLIC ACID FROM PROPANE IN THE ABSENCE OF MOLECULAR OXYGEN.

Abstract The present invention discloses a method for the production of acrylic acid from propane, wherein: (a) a gaseous mixture devoid of molecular oxygen and comprising propane, water vapour, as well as, if appropriate, an inert gas, is introduced into a first reactor with a moving catalyst bed, (b) at the outlet of the first reactor, the gases are separated from the catalyst, (c ) the catalyst is returned into a regenerator, (d) the gases are introduced into a second reactor with a moving catalyst bed, (e) at the outlet of the second reactor, the gases are separated from the catalyst and the acrylic acid contained in the separated gases is recovered, (f) the catalyst is returned into the regenerator, and (g) the regenerated catalyst from the regenerator is reintroduced into the first and second reactors.
Full Text METHOD FOR THE PRODUCTION OF ACRYLIC ACID FROM PROPANE. IN THE ABSENCE OF MOLECULAR OXYGEN
The present invention relates to the production of acrylic acid from propane in the absence of molecular oxygen.
It is known from European patent apphcation No. EP-A-608838 how to prepare an imsaturated carboxylic acid from an alkane according to a catalytic oxidation reaction in vapour phase in the presence of a catalyst containing a mixed metal oxide comprising as essential components. Mo, V, Te, O, as well as at least one element chosen from the group constituted by niobium, tantalum, tungsten, titanium, aluminium, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, platinum, antimony, bismuth, boron, indium and cerium, these elements being present in very precise proportions. The uses of such a catalyst devoid of silicon described in the examples of this document lead to good acrylic acid selectivities but they are implemented in the presence of air.
Moreover, patents such as the American patents No. 4 606 810, 4 966 681, 4 874 503, 4 830 728, 5 198 590 and 6 287 522 use two or more reactors, called "Risers', however these patents only relate to applications in the refinery of petroleum cuts.
The aim of the invention is therefore to provide a method for the production of acrylic acid from propane and in the absence of-molecular.oxygen,,which,allows a high conversion of the propane to be obtained while having a high selectivity.
The Applicant has discovered that this aim can be achieved by passing a gaseous mixture of propanfe and water vapour, and if appropriate, of an inert gas, over a particular catalyst, which acts as a redox system and provides the oxygen necessary for the reaction and by using an apparatus having two reaction zones.
The advantages of this novel method are the following:
- the limitation of the overoxidation of the products formed which takes place in the presence of molecular oxygen; according to the present invention, due the fact of operating in the absence of molecular oxveen. the formation of COv (carbon monoxide and carbon dioxide), degradation products,is.reduced, which allows the acrylic acid selectivity to be increased;
the acrylic acid selectivity is maintained at a good level;
the conversion is increased without loss of selectivity;
the catalyst does not undergo a low reduction and therefore a progressive
loss of its activity; it can easily be regenerated by heating in the presence of
oxygen or of a gas containing oxygen after a certain period of use; after

2
regeneration, the catalyst regains its initial activity and can be used in another reaction cycle;
moreover, the separation of the stages of reduction of the catalyst and of regeneration of the latter allows the partial pressure of propane to be increased, such a partial supply pressure of propane no longer being limited by the existence of an explosive zone created by the propane + oxygen mixture. The subject of the present invention is therefore a method for the production of acrylic acid from propane, in which:
a) a gaseous mixture devoid of molecular oxygen and comprising propane, water vapour, as well as, if appropriate, an inert gas, is introduced into a first reactor with a moving catalyst bed,
b) at the outlet of the first reactor, the gases are separated from the catalyst,
c) the catalyst is returned into a regenerator,
d) the gases are introduced into a second reactor with a moving catalyst bed,
e) at the outlet of the second reactor, the gases are separated from the catalyst and the acrylic acid contained in the separated gases is recovered,
f) the catalyst is returned into the regenerator,
g) the regenerated catalyst from the regenerator is reintroduced into the first and second reactors,
and in which the catalyst comprises molybdenum, vanadium, tellurium or antimony, oxygen and at least one other element X chosen from niobium, tantalum, tungsten, titanium, aluminium, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, platinum, antimony, bismuth, boron, indium and cerium.
This method allows an acrylic acid selectivity to be obtained of close to 60% and a high conversion of the propane.
Other characteristics and advantages of the invention will now be described in detail in the following description which is given with reference to the single attached figure, which diagrammatically represents an apparatus which is suitable for the implementation of the method according to the invention. DETAILED DESCRIPTION OF THE INVENTION
The operation of the method according to the invention can be explained with reference to the attached figure.

3
The gaseous mixture comprising propane, water vapour, as well as, if appropriate, an inert gas, is introduced into a first reactor (Riser 1) containing the moving catalyst bed.
Then, at the outlet of the first reactor, the effluents are separated into gases and the moving bed catalyst.
The catalyst is sent into a regenerator.
The gases are introduced into a second reactor (Riser 2) also containing a moving catalyst bed.
At the outlet of the second reactor, the effluents are separated into gases and the catalyst.
The catalyst is sent into a regenerator.
The gases are treated in a known way, generally by absorption and purification, with a view to recovering the acryliic acid produced.
The regenerated catalyst is reintroduced into the first reactor as well as into the second reactor.
The method thus operates continuously, the circulation of the catalyst between the reactors and the regenerator is carried out in a regular and generally continuous way.
Of course, the single regenerator can be replaced by two or more regenerators. Moreover, it is possible to add, after the second reactor, other reactors which also have a catalyst circulating between each of these reactors and the regenerator or other regenerators.
Preferably, the first and second reactors are vertical and the catalyst is transported upwards by the gas flow.
As regards the conversion of propane to acrylic acid using the catalyst, it is carried out according to the following redox reaction (1):
SOLTDoxidized + PROPANE - SOLIDreduced + ACRYLIC ACID (1) Generally, this redox reaction (1) is carried out at a temperature of 200 to 500 C, preferably 250 to 450 C, even more preferably, 350 to 400 C.
The pressure in the reactors is generally from l.OlxlO4 to 1.01x106 Pa (0.1 to 10 atmospheres), preferably from 5.05x104 to 5.05x105 Pa (0.5-5 atmospheres).
The residence time in each reactor is generally from 0.01 to 90 seconds, preferably, from 0.1 to 30 seconds.
The propane/water vapour volume ratio in the gas phase is not critical and can vary within wide limits.
Similarly, the proportion of inert gas, which can be helium, krypton, a mixture of these two gases, or nitrogen, carbon dioxide, etc., is also not critical and can also vary within wide limits.

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As regards the order of magnitude of the proportions of the initial mixture, the following ratio can be mentioned (in volumes):
propane/inert (He-Kr)/H20 (vapour): 10-30/40-50/40-50
As regards the catalyst, the proportions of its constituent elements can meet the following conditions:
in which rMo,rv, rTe or rsb and rx represent the mole fractions, respectively, of Mo, V, Te and X, in relation to the sum of the number of moles of all the elements of the catalyst, with the exception of oxygen. Such a catalyst can be prepared according to the teaching of the above-mentioned European patent application No. 608 838. Reference can be made in particular, to the catalyst of formula M01Vo.3Teo.23Nbo.12On the preparation of which is described in Example 1 of this patent application.
According to a preferred embodiment of the invention, the catalyst corresponds to formula (I) or to formula (la) below:
Mo1VaTebNbcSidOx (I) Mo1,VaSbbNbcSidOx (la) in which:
- a is comprised between 0.006 and 1, inclusive;
- b is comprised between 0.006 and 1, inclusive; c is comprised between 0.006 and 1, inclusive;
d is comprised between 0 and 3.5, inclusive; and
x is the quantity of oxygen bound to the other elements and depends on their oxidation state. Advantageously:
- a is comprised between 0.09 and 0.8, inclusive;
- b is comprised between 0.04 and 0.6, inclusive;
c is comprised between 0.01 and 0.4, inclusive; and
d is comprised between 0.4 and 1.6, inclusive. The oxides of the different metals included in the composition of the catalyst of formula (I) or (la) can be used as raw materials in the preparation of this catalyst, but the raw materials are not limited to the oxides; as other raw materials, there may be mentioned:
- in the case of molybdenum, ammonium molybdate, ammonium
paramolybdate, ammonium heptamolybdate, molybdic acid, molybdenum halides or
oxyhalides such as M0CI5, organometallic compounds of molybdenum such as
molybdenum alkoxides such as Mo(OC2H5)5, acetylacetone molybdenyl;

5
- in the case of vanadium, ammonium melavanadate, vanadium halides or oxyhalides such as VCL4, VCI5 or VOCI3, the organometalic compounds of vanadium such as vanadium alkoxides such as VO(OC2H5)3;
- in the case of tellurium, tellurium, telluric acid and Te02;
- in the case of niobium, niobic acid, Nb2(C204)5, niobium tartrate, niobium hydrogen oxalate, oxotrioxalatoanunonium niobate {(NH4)3[NbO(C204)3] •1.5H2O, niobium and ammonium oxalate, niobium oxalate and tartrate, nobium halides or oxyhalides such as NbCb3, NbCl5 and organometallic compounds of niobium such as niobium alkoxides such as Nb(OC2H5)5, Nb(0-n-Bu)5;
and, generally, all the compounds which are able to form an oxide by calcination, namely, the metallic salts of organic acids, the metallic salts of mineral acids, the metal complex compounds, etc.
The source of silicon is generally constituted by colloidal sihca and/or polysilicic acid.
According to particular embodiments, the catalyst of formula (I) can be prepared by mixing aqueous solutions of niobic acid, ammonium heptamolybdate, ammonium metavanadate, telluric acid under stirring, by the addition preferably of colloidal silica, then by precalcinating under air at approximately 300 C and by calcinating under nitrogen at approximately 600 C
Preferably, in the catalyst of formula (I) or(Ia): a is comprised between 0.09 and 0.8, inclusive;
- b is comprised between 0.04 and 0.6, inclusive; c is comprised between 0.01 and 0.4, inclusive; and d is comprised between 0.4 and 1.6, inclusive.
During the redox reaction (1), the catalyst undergoes reduction and a progressive loss of its activity. This is why, once the catalyst has at least partially changed to the reduced state, its regeneration is carried out according to reaction (2):
SOLIDrduced + 02- SOLIDoxidized (2) by heating in the presence of oxygen or a gas containing oxygen at a temperature of 250 to 500 C, for a time necessary for the reoxidation of the catalyst.
Generally the method is carried out until the reduction ratio of the catalyst is comprised between 0.1 and 10 g of oxygen per kg of catalyst.
This reduction ratio can be monitored during the reaction through the quantity of products obtained. Then the equivalent quantity of oxygen is calculated. It can also be monitored through the exothermicity of the reaction .
After regeneration, which can be carried out under temperature and pressure conditions which are identical to, or different from those of the redox reaction, the catalyst regains an initial activity and can be reintroduced into the reactors.

6
A method of operating with only one passage or with recycHng of the products leaving the second reactor can be used.
According to a preferred embodiment of the invention, after treatment of the gas originating from the second reaictor, the propylene produced as by-product and/or the propane which has not reacted are recycled (or returned) to the inlet of the reactor, i.e. they are reintroduced at the inlet of the first reactor, in a mixture or in parallel with the initial mixture of propane, water vapour and if appropriate of inert gas or gases.
According to an advantageous embodiment of tlie invention, the gas mixture also passes over a cocatalyst.
This has the advantage of reducing the production of propionic acid, which is generally a by-product of the conversion reaction and which poses problems in certain applications of acrylic acid when it is present in too great a quantity.
Thus, the propionic acid /acrlic acid ratio is greatly reduced at the outlet of the reactor.
Moreover', the formation of acetone, which is also a by-product of the production of acrylic acid from propane, is reduced.
To this end, at least one of the reactors comprises a cocatalyst with the following formula (II):
Mo1BiaFebCocNid-Kc-SbfTig.Sih'Ca1.NbjTek-PbrWm,-Cun-(II) in which:
a' is comprised between 0.OO6 and 1, inclusive;
- b' is comprised between 0 and 3.5, inclusive;
c* is comprised between 0 and 3.5, inclusive;
d' is comprised between 0 and 3.5, inclusive;
e' is comprised between 0 and 1, inclusive;
f is comprised between 0 and 1, inclusive; g* is comprised between 0 and 1, inclusive; h' is comprised between 0 and 3.5, inclusive; i' is comprised between 0 and 1, inclusive;
- j' is comprised between 0 and 1, inclusive;
- k' is comprised between 0 and 1, inclusive; r is comprised between 0' and 1, inclusive;
- m' is comprised between 0 and 1, inclusive; and
- n' is comprised between 0 and 1, inclusive.
Such a cocatalyst can be prepared in the same way as the catalyst of formula
(I).
^\HIRSCH6^BREVETS\Bl^lc:15M%O0\196O4OB doc - ler fevritr 20Ci5 - 6/17

7
The oxides of the different metals included in the composition of the cocatalyst of formula (II) can be used as raw materials in the preparation of this cocatalyst, but the raw materials are not limited to the oxides; as other raw materials, the corresponding nitrates can be mentioned in the case of nickel, cobalt, bismuth, iron or potassium.
Generally, the cocatalyst is present in the form of a moving bed and it is regenerated and circulates in the same way as the catalyst.
Preferably, in the cocatalyst of formula (II):
- a' is comprised between 0.01 and 0.4, inclusive;
- b, is comprised between 0.2 and 1.6, inclusive;
- c' is comprised between 03 and 1.6, inclusive;
- d' is comprised between 0.1 and 0.6, inclusive;
- e' is comprised between 0.006 and O.Ol, inclusive.
- f is comprised between 0 and 0.4, inclusive;
- g' is comprised between 0 and 0.4, inclusive;
- h' is comprised between 0.01 and 1.6, inclusive; - i' is comprised between 0 and 0.4, inclusive;
- j, is comprised between 0 and 0.4, inclusive;
- k' is comprised between 0 and 0.4, inclusive;
- r is comprised between 0 and 0.4, inclusive;
- m, is comprised between 0 and 0.4, inclusive; and
- n' is comprised between 0 and 0.4, inclusive.
The weight ratio of the catalyst to the cocatalyst is generally greater than 0.5 and preferably at least 1.
Advantageously, the cocatalyst is present in the two reactors.
The catalyst and the cocatalyst are present in the form of solid catalytic compositions.
They can each be in the form of pellets, generally of 20 to 300 /m in diameter, the catalyst and cocatalyst pellets generally being mixed before implementation of the method according to the invention.
The catalyst and the cocatalyst can also be present in the form of a solid catalytic composition composed of pellets each of which comprises both the catalyst and the cocatalyst. EXAMPLES
The following examples illustrate the present invention without limiting its scope.
In the formulae given in Example 1, x is the quantity of oxygen bound to the other elements and depends on their oxidation states.

8
The conversions, selectivities and yields are defined as follows:
Number of moles of propane having reacted
Conversion(%) = x 100
of the propane Number of moles of propane introduced
Number of moles of acrylic acid formed
Selectivity(%) = xlOO
for acrylic Number of moles of propane having reacted
acid
Number of moles of acrylic acid formed
Yield(%)= xlOO
of acrylic Number of moles of propane introduced
acid
The selectivities and yields relating to the other compounds are calculated in a similar way.
The conversion ratio is the weight of catalyst (in kg) required to convert 1 kg of propane. Example 1 Preparation of the catalyst ofiV0.33 Nb0.11 Te0.22
a) Preparation of a solution of niobium
640 g of distilled water then 51.2g of niobic acid (i.e. 0.304 moles of niobium) are introduced into a 5 1 beaker. Then 103.2 g (0.816 moles) of dihydrated oxalic acid is added.
The molar ratio oxalic acid/niobium is therefore 2.69.
The solution obtained previously is heated at 60 C for 2 hours, being covered so as to avoid evaporation and with stirring. Thus a white suspension is obtained which is left to cool to 30 Cunder stirring, which takes approximately 2 hours.
b) Preparation of a solution of Mo, V and Te
2120 g of distilled water, 488 g of ammonium heptamolybdate (i.e.2.768 moles of molybdenum), 106.4 g of ammonium metavanadate NH4VO3 (i.e.0.912 moles of vanadium) and 139.2 g of telluric acid (supplier: FLUKA) (i.e. 0.608 moles of tellurium) are introduced into a 5 1 beaker.
The solution obtained previously is heated at 60 C for 1 hour and 20 minutes, being covered so as to avoid evaporation and with stirring. In this way a clear red

9
solution is obtained which is left to cool to 30 C under stirring, which takes approximately 2 hours. c) Introduction of the silica
393.6g of Ludox sihca (containing 40% by weight of silica, supplied by Dupont) is introduced under stirring into the previously prepared solution of Mo, V and Te. The latter retains its limpidity and its red colouring.
Then the previously prepared solution of niobium is added. In this way a fluorescent orange gel is obtained after stirring for a few minutes. This solution is then dried by atomization. The atomizer used is a laboratory atomizer (ATSELAB from Sodeva). The atomization takes place in a nitrogen atmosphere (in order to prevent any oxidation and any untimely combustion of the oxalic acid present in the slurry).
The working parameters are globally:
- flow rate of nitrogen of the order of 45 Nm3/h;
- flow rate of slurry of the order of 500 g/h;
- inlet temperature of the gas comprised between 155°C and 170°C;
- outlet temperature of the gas comprised between 92°C and 100°C.
Then the product recovered (355.2g), which has a particle size less than 40 microns, is placed in an oven overnight at 130 C, in a teflon-covered plate.
hi this way 331 g of dry product is obtained. d) calcination
The precalcinations and calcinations were carried out under air and nitrogen flow in steel capacitors. These capacitors are directly installed in muffle furnaces and the air is supplied via the flue. An internal thermometer well allows precise monitoring of the temperature. Th.e cover is useful to prevent air returning towards the catalyst.
Firstly, the 33 Ig of precursor obtained previously are precalcinated for 4 hours at 300 Cunder air flow of 47.9ml/min/g of precursor.
The solid obtained is then calcinated for 2 hours at 600°C under a nitrogen flow of 12.8 ml/min/g of solid.
In this way the desired catalyst is obtained. Example 2 Catalyst tests a) Apparatus
In order to simulate the method according to the invention, simulations were carried out in a laboratory fixed bed reactor, by generating propane pulses and oxygen pulses. Using a loading of the reactor with two superposed catalyst beds, we

10
can thus simulate the behaviour of the catalyst and what it would have experienced in two successive reactors with a rising moving bed called "risers".
i) A single reactor (by way of comparison):
test called "single RISER"
The following are loaded from the bottom to the top of a vertical reactor with cylindrical shape and made of pyrex:
- a first height of I ml of silicon carbide in the form of particles of 0.125 mm in diameter,
- a second height of 1 ml of silicon carbide in the form of particles of 0.062 mm in diameter,
- a third height of 5 g of catalyst In the form of particles of 0.02 to 1 mm diluted with 5 ml of silicon carbide in the form of particles of 0.062 mm in diameter,
- a fourth height of 1 ml of silicon carbide in the form of particles of 0.062 mm in diameter,
- a fifth height of 3 ml of silicon carbide in the form of particles of 0.125 mm in diameter,
- a sixth height of 1 ml of silicon carbide in the form of particles of 0.062 mm in diameter,
- a seventh height of 5 ml of silicon carbide in the form of particles of 0.062 mm in diameter,
- an eighth height of 1 ml of silicon carbide in the form of particles of 0.062 mm in diameter,

- a ninth height of 2 ml of silicon carbide in the form of particles of 0.125 mm in diameter,
- then, a tenth height of silicon carbide in the form of particles of 1.19 mm so as to fill all of the reactor.
ii) Two reactors (according to the invention):
test called «double RISER»
The apparatus is the same as previously, except that the seventh height of 5 ml silicon carbide is replaced by 5 g of catalyst diluted with 5 ml of silicon carbide 0.062 mm, the same as the third catalyst height.
Two catalyst beds are therefore loaded, one above the other in the reactor, which allows simulation of the behaviour of an apparatus with 2 reactors such as the one represented in the attached figure.

11
b) Operating method
The reactor is then heated to 250 C and the vaporiser to 200 C The electric initiation of the water pump is actuated.
Once the reactor and the vaporiser have reached the temperatures given above, the water pump is actuated and the temperature of the reactor is raised to the desired test temperature.
The hot spot of the reactor is then left to stabilize for 30 minutes.
Then, oxygen is introduced in 10 pulses of 23 seconds each in order to sufficiently oxidize the catalyst. The catalyst is considered to be totally oxidized when the temperature of the hot spot has stabilized, i.e. when there is no more exothermal activity due to the reaction (by monitoring the catalyst temperature measured using a thermocouple placed in the catalyst bed, the fluctuations in temperature can be seen as a function of the pulses).
The pressure at the inlet of the reactor was approximately 1.2 to 1.8 bars (absolute) and the pressure drop across the reactor is approximately 0.2 to 0.8 bars (relative).
As regards the production itself of acrylic acid, a redox balance is composed of 60 redox cycles. A redox cycle represents;
13.3 seconds of propane in a continuous flow of helium-krypton/water,
- 45 seconds of continuous flow of helium-krypton/water,
- 20 seconds of oxygen in a continuous flow of helium-krypton/water, 45 seconds of continuous flow of hehum-krypton/water.
During the balancing, four samples are taken, each representing 15 cycles. 4 samples of gas are also carried out using gas bags, each sample representing 15 cycles. (The gas samples are carried out over a period corresponding to a multiple of the duration of a cycle, in order to be able to know the theoretical quantity of propane injected).
Each small gas-washing bottle (with a 25 ml capacity and filled with 20 ml of water) is equipped with a gas bag, and when the bottle is connected to the outlet of the reactor (as soon as the liquid bubbles), the bag is open and the chronometer is started.
In order to verify the oxidation state of the catalyst, another series of ten 23-second pulses of oxygen is carried out. It shows that the oxidation state of the solid has been maintained during the balancing (no exothermal activity).
The liquid effluents are analyzed on a HP 6890 chromatograph, after having carried out a specific calibration.
The gases are analyzed during the balancing on a Chrompack micro-GC chromatograph.

12
An assay of the acidity is carried out on each bottle during the balancing, in order to determine the exact number of moles of acid produced and to validate the chromatographic analyses. c) Results
The final results correspond to the average of the microbalances carried out on the 4 gas-washing bottles and the 4 gas bags.
A balance is composed of 60 cycles with partial pressures of propane and of oxygen corresponding to the following ratios:
for the reaction: Propane/He-Kr/H20: 10/45/45
for the regeneration: 02/He-Kr/H20: 20/45/45
The flow rate of He/Kr is 4.325 Nl/h (Nl = litre of gas at 0 C and under 760 mm Hg)
V>HlRSCH6\BREVETSMtrcvcls\19600\l9604GBdo<:- ler fevtiti> The results are brought together in the following table:


13

(*): in the double RISER test, the oxygen consun^tion was calculated on the total mass of catalyst (sum of the two beds).
It is seen that on 1 or 2 beds, the same quantity of oxygen is extracted from the catalyst (in g/kg catalyst), and withi the same flow rate (same flow values g/kg.s). By contrast, the conversion ratio is calculated by considering only one bed, because it reflects the flow rate of solid necessary to convert 1 kg of propane. Since the unit operates at a maximum density (limited by the flow of catalyst), the only way to fijrther increase the conversion is therefore to remove the spent catalyst and to replace it with fresh catalyst, this occurring, without changing the flow of catalyst. It is therefore the conversion ratio on 1 bed which is used to calculate the dimensions of the unit.
The results are good, the selectivity for acrylic acid (AA) being close to 60% at 360 C and at 380 C
The conversion of the propane (Pan) with the method according to the invention is clearly greater than that of the method used comparatively, it is practically twice as great at 360 C.
The yields of acrylic acid are greater than 17.5% at all the temperatures tested, while according to the comparative method they are less than 15.5%.
Thus, the use of the two reactors allows a gain in conversion per pass to be obtained, without loss of selectivity. This allows the conversion ratio to be reduced, recalculated per reactor, but taking account of the total conversion, because the use of a second reactor involves incre;ising the flow of catalyst, in a unit which is often already at the maximum of solid density.

- 15 -
Claims
A process of producing synthetic threads from a polymer mixture which consists of a base polymer and at least one additive polymer, wherein the polymer mixture is pressed through nozzle openings as polymer melt with extrusion speeds (s) in the range from 18 to 160 m/min and the filaments thus formed are cooled, combined to threads, the threads are drawn off are spooled by forming at least one thread spool, characterized in that the base polymer is polyamide (PA), that the content of additive polymer in the polymer mixture is not less than M wt-% and not more than 2.5 wt-%, where M is derived from 0.0001 • V - 0.4, where v is the draw-off speed of the thread, and v lies in the range from 4500 to 8000 m/min, that the additive polymer is amorphous and virtually insoluble in the polymer melt,.where the additive polymer in the spooled thread is present in the base polymer in a fibril structure, and that the ratio s : v lies in the range from 1 : 50 to 1 : 250.
The process as claimed in claim 1, characterized in that the specific spooling tension, as measured directly before the spooler, is 0.04 to 0.2 g/dtex.
The process as claimed in claim 1 or 2, characterized in that upon spooling the thread spool has a weight of the spooled thread of at least 4 kg.
The process as claimed in claim 1 or any of the preceding claims, characterized in that the relative increase in elongation (D) in the spooled thread is at least 1,02, where D = a/b
with a = elongation at break of the thread consisting of the polymer mixture, and b = elongation at break of the thread which only consists of the base polymer.

- 16
The process as claimed in claim 1 or any of the preceding claims, characterized in that the ratio of the melt viscosities of the additive polymer and the base polymer is 1.2 : 1 to 12 : 1.
The process as claimed in claim 1 or any of the preceding claims, characterized in that the additive polymer is an addition polymerization product of at least one ethylenically unsaturated monomer.
The process as claimed in claim 6, characterized in that the additive polymer is a polymer of the following monomer unit:

where R1 and R2 are substituents consisting of the optional atoms C, H, 0, S, P and halogen atoms, and the sum of the molecular weights of R1 and R2 is at least 40.
The process as claimed in claim 7, characterized in that the additive polymer is a polystyrene.
The process as claimed in claim 1, characterized in that the additive polymer is a polymethyl methacrylate.
The process as claimed in claim 1 to 6, characterized in that the additive polymer is a copolymer which contains

- 17 -
at least one of the monomers acrylic acid, methacrylic acid or CH2=CR-C00R', where R is an H atom or CH3, and R' is a C1-15 alkyl radical or a C5-12 cycloalkyl radical or a C6-14 aryl radical.
The process as claimed in claim 1 or any of the preceding claims, characterized in that a FOY thread with an elongation at break of at least 50 % is produced, which is spooled without draft, the spooling speed being 1.0 to 0.95 times the draw-off speed.
The process as claimed in any of claims 1 to 10, characterized in that there is produced a drafted, smooth thread with an elongation at break of less than 50 %, the spooling speed being 1.0 to 1.5 times the draw-off speed.
The present invention discloses a method for the production of acrylic acid from propane, wherein: (a) a gaseous mixture devoid of molecular oxygen and comprising propane, water vapour, as well as, if appropriate, an inert gas, is introduced into a first reactor with a moving catalyst bed, (b) at the outlet of the first reactor, the gases are separated from the catalyst, (c ) the catalyst is returned into a regenerator, (d) the gases are introduced into a second reactor with a moving catalyst bed, (e) at the outlet of the second reactor, the gases are separated from the catalyst and the acrylic acid contained in the separated gases is recovered, (f) the catalyst is returned into the regenerator, and (g) the regenerated catalyst from the regenerator is reintroduced into the first and second reactors.

Documents:

00412-kolnp-2005-abstract.pdf

00412-kolnp-2005-assignment.pdf

00412-kolnp-2005-claims.pdf

00412-kolnp-2005-correspondence.pdf

00412-kolnp-2005-description(complete).pdf

00412-kolnp-2005-drawings.pdf

00412-kolnp-2005-form-1.pdf

00412-kolnp-2005-form-18.pdf

00412-kolnp-2005-form-3.pdf

00412-kolnp-2005-form-5.pdf

00412-kolnp-2005-g.p.a.pdf

00412-kolnp-2005-letters patent.pdf

00412-kolnp-2005-reply f.e.r.pdf

412-kolnp-2005-granted-abstract.pdf

412-kolnp-2005-granted-assignment.pdf

412-kolnp-2005-granted-claims.pdf

412-kolnp-2005-granted-correspondence.pdf

412-kolnp-2005-granted-description (complete).pdf

412-kolnp-2005-granted-drawings.pdf

412-kolnp-2005-granted-form 1.pdf

412-kolnp-2005-granted-form 18.pdf

412-kolnp-2005-granted-form 3.pdf

412-kolnp-2005-granted-form 5.pdf

412-kolnp-2005-granted-gpa.pdf

412-kolnp-2005-granted-letter patent.pdf

412-kolnp-2005-granted-reply to examination report.pdf

412-kolnp-2005-granted-specification.pdf


Patent Number 213653
Indian Patent Application Number 412/KOLNP/2005
PG Journal Number 02/2008
Publication Date 11-Jan-2008
Grant Date 09-Jan-2008
Date of Filing 14-Mar-2005
Name of Patentee ARKEMA
Applicant Address 4/8, COURS MICHELET FRANCE
Inventors:
# Inventor's Name Inventor's Address
1 DUBOIS JEAN-LUC 190, RUE DU COPTEAU FRANCE
PCT International Classification Number CO7C 51/215
PCT International Application Number PCT/FR2003/002608
PCT International Filing date 2003-08-29
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 02/11196 2002-09-10 France