Title of Invention

SHAFT FURNACE

Abstract The invention relates to a shaft furnace, especially a direct reduction shaft furnace, with a charge of lump materials (2), especially materials containing iron oxide and/or spore iron, which can be introduced into the furnace from above and also comprising a plurality of inlets (3) for a reduction gas arranged on a plane in the region of the lower third part of the furnace, whereby the profile of the furnace has an extended diameter (7) and a cavity (8) is formed between the gas inlets (3) and the charge (2). The inventive furnace enables gas to be supplied and distributed in a uniform manner along the periphery of said furnace.
Full Text FORM 2
THE PATENTS ACT 1970
[39 OF 1970]
&
THE PATENTS RULES, 2003
COMPLETE SPECIFICATION
[See Section 10; rule 13]
"SHAFT FURNACE"
VOEST-ALPINE INDUSTRIEANLAGENBAU GMBH, an Austrian company, of Turmstrasse 44, A-4020 Linz, Austria,
The following specification particularly describes the invention and the manner in which it is to be performed:




The invention relates to a shaft furnace., in particular a direct-reduction" shaft furnace, with a charge composed of particulate material, in particular particulate material containing iron oxide and/or sponge iron, the said material being capable of being fed into the shaft furnace from above, and with-, arranged in one plane, a multiplicity of gas-inlet orifices for a reduction gas in the region of the lower third of the shaft furnace, the shaft furnace being surrounded externally by an annular space which is connected to the gas-inlet orifices downwards by means of gas supply ducts.
Shaft furnaces, in particular direct-reduction shaft furnaces of the type described above, are known in many forms from the prior art. Such a shaft furnace, designed essentially as a cylindrical hpllow body, ains, for example, a charge composed of particulate material containing iron oxide and/or sponge iron, the material containing iron oxide being fed into the upper part of the shaft furnace. By means of a plurality of gas-inlet orifices arranged over the circumference of the shaft furnace and lopated in the region of the lower third of the latterj a reduction gas emanating, for example, from a melt-down gasifier is injected into -the shaft furnace and consequently into the solid charge. The hot dust-laden reduction gas flows upwards through the solid charge and, at the same time, reduces the iron oxide of the charge completely or partially to sponge iron.
The completely or partially reduced iron oxide is conveyed out of the shaft furnace by means of discharge devices arranged between the bottom region of the shaft furnace • and the region of the gas-inlet orifices, the charge column located in the shaft furnace sinking downwards due to gravity.
A shaft furnace must, by virtue of its design, ensure that a uniform reaction course, which is as
2

complete as possible, and uniform sinking of the charge
material can take place in it.
AT B 387,037 discloses a shaft furnace for the
thermal treatment of charge materials by means of
gaseous media. In this case, for the supply of
reduction gas, gas-inlet orifices are provided, which
are covered by an annular skirt relative to the charge
materials introduced in the shaft . furnace. An annular
cavity is provided between the annular skirt and an
annular widening of the casing of the shaft furnace, so
that the reduction gas. | introduced can be delivered to
the charge materials so as to be distributed over the.
circumference of the shaft furnace.
« i
This design of the gas supply system has major
disadvantages. The inner walls of shaft furnaces are
conventionally lined with refractory material, for
example fireclay. However, such an annular ,ekirt cannot
be produced from individualreclay bricks, since it
is connected only via its upper circumference to the
casing of the shaft furnace. In principle, however,
this type of gas supply system is capable of being
produced monolithically, that is to say so as to be
manufactured from one piece. Nevertheless, for this
purpose, individual segments of the shaft-furnace
casing, together with that part of the annular skirt
which is suspended on the said casing, would have to be
manufactured in each case from a single piece of
refractory material. It is scarcely possible for this
to be carried out, however, because of the size of the
segments and because of their complex geometry.
Furthermore, an annular skirt produced in this
way would collapse during the first loading of the
shaft furnace. The lateral forces arising from charges,
for example due to process-dependent increases in
volume, are considerable. The annular skirt would
therefore break away outwards immediately.
IN 163456 discloses an
arrangement consisting of a gasifier and of a
3

shaft furnace has, above its bottom, screw conveyers which are arranged in a star-shaped manner and by means of which particulate material is conveyed out of the shaft furnace. The inner ends of the screw conveyers
5 are mounted in a conical fitting in the middle of the shaft furnace. This conical fitting is connected downwards to the melt-down gasifier, so that reduction gas can flow out of the melt-down gasifier through the conical fitting into the shaft furnace. Furthermore,
0 reduction gas is supplied to the shaft furnace via at least one gas-inlet orifice which opens into an annular space formed by an annular skirt and the shaft-furnace casing. The same applies to this annular skirt as to that in AT B 387,037, that is to say it would
15 immediately break away laterally and/or, on account of the abrazing forces of the charge moving past it, would be ground off. This is all the more relevant as the conical fitting located at the same height as the annular skirt constitutes, from the point of view of
20 I the charge material, a reduction in the free cross section of the shaft furnace. Consequently, the laterally effective forces arising from the charge in the region of the conical fitting and of the annular skirt are also substantially higher than in other
25 regions of the shaft furnace. Moreover, in regions of reduced cross section the charge preferentially forms baked areas, agglomerations and bridges. This prevents the charge material from sinking uniformly.
The prior art, for example US Patent 3,816,101
30 or US Patent 4,046,557, discloses shaft furnaces, in which a reduction gas is first introduced into a cavity which annularly surrounds the shaft furnace and from which a plurality of gas supply ducts open into a frustoconical widening of the shaft furnace casing.
35 This annular cavity has a rectangular cross-sectional surface in vertical section, and the gas supply ducts opening into the shaft furnace lead away from the bottom and/or from the inner wall of this annular space.

This gas supply system is unsuitable when the reduction gas is to be supplied so as to be distributed uniformly over the circumference of the shaft furnace. Since the charge material rests directly against each 5 gas-inlet orifice, the number of points for the inlet of gas into the shaft furnace and therefore into the charge is only in each case as large as the number of gas-inlet orifices.
If a dust-laden reduction gas is used, dust may
10 settle at the mouth of the gas supply ducts into the shaft furnace and reduce the gas permeability of the charge there, with the result that further dust settles, and so on and so forth, ultimately clogging the gas supply ducts. Further dust may also be
15 deposited on the bottom of the annular space. In an extreme situation, even particulate material from the charge may pass into the annular space. It is not possible to remove the solids which have settled in the
, gas supply system, without decommissioning and emptying
20 the shaft furnace. Faults in the passage of gas through the charge, which are caused by clogged gas supply ducts, lead to an uneven reduction of the charge material and a reduction in the product quality.
The object of the invention is, therefore, to
25 provide a shaft furnace, in particular a direct-reduction shaft furnace, the gas supply system of which is designed in such a way that the disadvantages known from the prior art are avoided.
In particular, this gas supply system is to be
30 capable of being produced in a simple way from conventional refractory material and is to have sufficient mechanical stability relative to the laterally acting forces arising from the charge.
5 Dust-laden reduction gas is to be capable of being distributed uniformly on the circumference of the shaft furnace and therefore, as a further consequence, also in the charge, and the clogging of gas supply channels is to be avoided.

This object is achieved, according to the invention, in that the shaft contour has a diametral widening in the region of the gas-inlet orifices and the wall of shaft furnace is designed in such a way 5 that an annular cavity is formed between the gas-inlet orifices arranged in the region of this diametral widening and the charge.
By means of the inventive design of the gas supply system, it is possible, for the first time, to
10 supply gas to a shaft furnace so as to be distributed uniformly over its circumference, without the need to provide a mechanically unstable annular skirt which it is scarcely possible to produce from conventional refractory bricks.
15 According to another advantageous feature, a
number of means for dividing the annular cavity into sections separated from one another are arranged in the region of the diametral widening and are fastened to or in the wall of the shaft furnace.
20 Of these means for dividing the annular cavity,
for example 2 to 16, but preferably 4 to 8, are arranged essentially at an approximately uniform distance from one another in the region of the diametral widening, so that the annular cavity is
25 subdivided into as many sections.
Preferably, these means for dividing the cavity are formed by vertically arranged metal sheets and/or plates which, in any event, are dimensioned in such a way that, in each case, such a means passes at least
30 completely through the vertical cross section of the cavity.
According to a further advantageous embodiment, in addition to the means for dividing the cavity, further means for dividing the annular space into
35 portions separated from one another are arranged in the annular space, gas being capable of being supplied from outside the shaft furnace, in each case independently, to each of the portions separated from one another.
6

1
The division of the annular cavity into sections separated from one another, together with the division of the annular space into portions separated from one another, proves advantageous, because it 5 avoids or reduces the risk that, in the case of temporary faults in the passage of gas through the charge, the reduction gas will follow the path of least resistance and, as a result, reduction gas will flow through part-regions of the charge to an increased 10 extent and other part-regions will be "under-supplied" with reduction gas.
Preferably, in this case, the means for dividing the annular space and the means for dividing the cavity are arranged in such a way that, in each 15 case, a portion of the annular space is assigned to a number of sections of the cavity, with the result that gas can be supplied via the respective portion to the section or sections corresponding to it.
It is particularly preferred, in this case, 20 that the number of means for dividing the annular space be equal to the number of means for dividing the cavity and that a portion be assigned in each case to one section.
Subdividing the annular space and the cavity by 25 suitable means, for example refractory material, metal sheets, etc., gives rise to closed-off regions which can be subjected to gas quantities individually and in a controlled way. For example, it is possible, despite locally varying charge permeability, to introduce the 30 same gas quantity into each region of the charge. It is, however, also possible, if the conduct of the process so requires, to introduce different gas quantities per region into the charge deliberately.
According to a further advantageous embodiment 35 of the shaft furnace according to the invention, the vertical cross section of each portion of the annular space is designed to taper in the circumferential direction from the location of gas supply to the respective portion ends.
7

The result of this is that the velocity of the dust-laden gas from the location of gas supply as far as the respective portion end does not decrease or does not decrease as greatly as would be the case if the cross section of the annular space were constant in a circumferential direction. The gas velocity therefore remains sufficiently high at all the locations of the annular space, in order to avoid dust deposits in the annular space.
According to a further advantageous embodiment, to a number of gas supply ducts is assigned in each case a cleaning device which is capable of being operated from outside the shaft furnace and by means of which caked-on accumulations can be cleaned off from the gas supply ducts or from the annular space which precedes the gas supply ducts in the gas flow direction.
Process faults may also lead to deposits/caked-on accumulations in the annular space or the gas supply ducts. These deposits can be cleaned off by means of the cleaning device or cleaning devices. It is particularly advantageous that the cavity formed by the diametral widening affords a sufficiently large volume for receiving the released material, whereas, otherwise, this would lead merely to clogging of the gas supply ducts. Complicated shaft emptying or the outward extraction of the material is thus avoided.
In the simplest instance, in each case one
cleaning device is expediently designed as a poker
30 device, the poker device passing through the outer wall
of the annular space essentially in each case in the
extension of a respective gas supply duct.
According to a preferred embodiment, the
diametral widening forms a frustoconical generated
35 surface, the generatrix of which encloses with the
horizontal an angle which is smaller than the angle of
repose of the material located in the shaft furnace.
This results in the formation of an annular cavity which is delimited by the frustoconical

generated surface, by part of the vertical inner wall of the shaft furnace and by the charge and in which the gas supplied thro-agh the gas-inlet orifices can be distributed uniformly. The term "angle of repose" is 5 intended, in this case, to refer to the natural angle of repose which the generatrix of the generated surface of a charging cone forms with the horizontal.
Preferably, the angle which the generatrix of the generated surface encloses with the horizontal is 0 10 to 25°, whereby the diametral widening widens from the top downwards. The angle of repose of is about 35 to 40°. The difference between these two angles is therefore sufficiently large to give rise to an annular 15 space, in which the reduction gas can be distributed optimally.
Particularly preferably, the angle which the generatrix of the generated surface encloses with the horizontal is 0°. In this design, the distance between 20 the charge and the generated surface or the gas-inlet orifices arranged in the generated surface is such that the risk that dust-like or particulate material from the charge may pass into one of the gas supply ducts is minimized.
25 The gas supply system also has outstanding mechanical stability, since the dimensions of the gas supply ducts which pass through the wall of the shaft furnace can be kept so small that the gas-inlet orifices or the gas supply system formed by the gas 30 supply ducts and by the refractory material surrounding the gas supply ducts can withstand the effective lateral forces arising from the charge.
The gas supply system is also capable of being produced in a simple way from conventional refractory 35 material, for example fireclay bricks, since each part of the gas supply system is supported by parts located below it. No arrangements, such as, for example, an annular skirt, are provided, which would be connected
9

to the wall of the shaft furnace solely via an .upper edge.
As a result of an advantageous refinement, the gas supply ducts have an essentially rectangular cross section and are designed to taper from the bottom upwards, the inner edges of the gas supply ducts being rounded. This ensures that gas supply ducts, in which a build—up of material occurs in spite of the material—free annular cavity formed inside the shaft furnace, are cleaned again automatically, that is to say by means of the downward movement of the material in the shaft furnace.
According to- a further advantageous refinement, the transition between the annular space, which externally surrounds the shaft furnace annularly, and the gas supply ducts is designed to descend obliquely downwards. Consequently, dust-like material from the reduction gas cannot accumulate in the annular space and, also, material which comes from the charge and which passes into the annular space due to process—induced faults cannot remain there. Instead, due to gravity, such material is returned to the shaft furnace again through the gas-inlet orifices which widen downwards.
The shaft furnace according to the invention is explained in more detail below by means of Fig. 1 to Fig. 5 of the accompanying drawings in which:
Fig. 1 shows an overall illustration of the shaft
furnace
Fig. 2 shows the diametral widening of the shaft furnace with a gas supply duct and an annular space
Fig. 3 shows the section A-A from Fig. 1
Fig. 4 shows the section B-B from Fig. 2
Fig. 5 shows the section C-C from Fig. 2
Fig. 1 shows the shaft furnace 1 according to the invention with a charge composed of particulate material 2 which is capable of being fed to the shaft furnace 1 from above (the feed device is not shown). A
10


multiplicity of gas-inlet orifices 3 are arranged in one plane in the region of the lower third of the shaft furnace 1. A reduction gas is injected into the charge 2 through these gas-inlet orifices 3. Screw conveyers 6 4, by means of which the particulate material is discharged from the shaft furnace 1, are arranged above the bottom of the said shaft furnace 1.
Fig. 2 illustrates one of the gas-inlet orifices 3, with the annular space 5 surrounding the
10 shaft furnace 1 externally and with one of the gas supply ducts 6 which connect the gas-inlet orifices to the annular space 5. The diametral widening 7 of the shaft contour is designed as a horizontal setback in the casing of the shaft furnace 1, so that an annular
15 cavity 8 is formed between the gas-inlet orifices 3 and the charge 2. The reduction gas supplied through the gas supply ducts 6 and the gas-inlet orifices 3 can be distributed optimally in this cavity 8. Fig. 2 also illustrates by broken lines a means 11 for dividing the
20 cavity and means 12 for dividing the annular space 5, the said means in each case being designed here as a vertically arranged metal sheet. A cleaning orifice 13 passes through the outer casing of the annular space 5, in such a way that the central axis of the cleaning

25 orifice 13 coincides with the central axis of the gas supply duct 6. The cleaning orifices 13 is designed to be sealingly closeable externally. When necessary, deposits can be cleaned off from the gas supply duct 6 and part of the annular space 5, for example by means of a rod 14 (straight or bent).

Fig. 3 illustrates a section through A-A of Fig. 1, the viewing direction vertically from below in the direction of one of the gas supply ducts 6 being selected. The inner edges 9 of the gas supply ducts 6 are rounded and the gas supply ducts 6 are designed to taper upwards. This ensures that dust-like material from the reduction gas does not settle in the gas supply ducts 6 or that, in the event of a build-up of material, the gas supply ducts 6 are automatically


cleaned again in the course of the downward movement of the particulate material.
Fig. 4 shows a section through B-B of Fig. 2, as seen from inside the shaft. The gas supply ducts 6 5 widen from the top downwards and the transitions 10 from the annular space 5 to the gas supply ducts 6 are designed to descend obliquely downwards. This, too, is intended to ensure? that dust-like material from the reduction gas does not settle in the annular space 5,
10 but is introduced, together wit"n the reduction gas, into the shaft furnace 1.
Fig. 5 shows a section through C-C of Fig. 2, the annular space 5 being illustrated with a cross section which decreases in the circumferential 15 direction from the location of gas supply 15 to the portion ends 12.
The invention is not restricted to the exemplary embodiment illustrated in Fig. 1 to Fig. 5 of the drawings, but also comprises all means which are 20 known to the person skilled in the art and which may be employed in order to implement the invention.
For example, the metal sheets or plates are not restricted to the shape and size illustrated in Fig. 2, but may, depending on material-related and 25 process-related requirements, also have, for example, rectangular contours or contours similar to a segment of a circle and also smaller dimensions, so that they do not project into the charge as far as is illustrated in Fig. 2.
30 As illustrated in the exemplary embodiments,
the annular space way be connected structurally to the shaft, but it is also possible for the annular space to be formed by a ring pipeline which concentrically surrounds the shaft at a distance from the latter. The

35 connection between the ring pipeline and the gas supply ducts is then made via widening spur conduits inclined downwards. This affords further advantages in the design of the reduction shaft, in particular in the

refractory design, and improved accessibility of the annular space for cleaning purposes.

It is also possible for the reduction in cross section of the portions of the annular space not to be 5 designed merely as a reduction in the horizontal diameter, as illustrated in Fig. 5, but, alternatively or additionally, as a reduction in the vertical diameter of the annular space or, in the case of a ring pipeline, as a conical constriction.


WE CLAIM:
1. Shaft furnace (1), in particular direct-reduction shaft furnace, with a charge composed of particulate material (2), in particular particulate material containing iron oxide and/or sponge iron, the said material being capable of being fed into the shaft furnace (1) from above, and with, arranged in one plane, a multiplicity of gas-inlet orifices (3) for a reduction gas in the region of the lower third of the shaft furnace (1), the shaft furnace (1) being surrounded externally by an annular space (5) which is connected to the gas-inlet orifices (3) downwards by means of gas supply ducts (6), characterized in that the shaft contour has a diametral widening (7) in the region of the gas-inlet orifices (3) and the wall of the shaft furnace (1) is designed in such a way that an annular cavity (8) is formed between the gas-inlet orifices (3) is substantially free of charge, arranged in the region of this diametral widening (7) and the charge (2), the diametral widening being in the shape of a frusto conical surface having a generatrix which forms an angle with the horizontal which is smaller than the angle of repose of the charge material.
2. Shaft furnace (1) as claimed in claim 1, wherein a number of means (11) for dividing the cavity (8) into sections separated from one another are arranged in the region of the diametral widening (7) and are fastened to or in the wall of the shaft furnace.
3. Shaft furnace (1) as claimed in claim 2, wherein 2 to 16, preferably 4 to 8 means (11) for dividing the cavity (8) are arranged in the region of the diametral widening (7) essentially at a uniform distance from one another.
4. Shaft furnace (1) as claimed in one of the claims 2 or 3, wherein the means (11) for dividing the cavity (8) are formed by vertically arranged metal sheets and/or plates.
5. Shaft furnace (1) as claimed in one of claims 2 to 4, wherein in
addition to the means (11) for dividing the cavity (8), further means (12) for
dividing the annular space (5) into portions separated from one another are
arranged in the annular space (5), gas being capable of being supplied (15)

from outside the shaft furnace (1), in each case independently of one another, to each of the portions separated from one another.
6. Shaft furnace (1) as claimed in claim 5, wherein the means (12) for
dividing the annular space (5) and the means (11) for dividing the cavity (8)
arc arranged in such a way that, in each case, a portion of the annular space
(5) is assigned to a number of sections of the cavity (8), with the result that
gas can be supplied via the respective portion to the section or sections
corresponding to it.
7. Shaft furnace (1) as claimed in claim 6, wherein the number of means (12) for dividing the annular space (5) is equal to the number of means (11) for dividing the cavity (8) and a portion is assigned in each case to one section.
8. Shaft furnace (1) as claimed in one of claims 5 to 7, wherein the vertical cross section of each portion of the annular space (5) is designed to taper in the circumferential direction from the location of gas supply (15) to the respective portion ends (12).
9. Shaft furnace (1) as claimed in one of claims 1 to 8, wherein a number of gas supply ducts (6) are assigned in each case a cleaning device (13, 14) which is capable of being operated from outside the shaft furnace (1) and by means of which caked-on accumulations can be cleaned off from the gas supply ducts (6) or from the annular space (5) preceding the gas supply ducts
(6) in the gas flow direction.
10. Shaft furnace (1) as claimed in claim 9, wherein, in each case, a cleaning device (13, 14) is designed as a poker device, the poker device passing through the outer wall of the annular space (5) essentially in each case in the extension of a gas supply duct (6).
11. Shaft furnace (1) as claimed in one of claims 1 to 10, wherein the diametral widening (7) widens from the tap downwards, and in that the generatrix of the frustoconical generated surface encloses with the horizontal

an angle or 0° to 25°.
12. Shaft furnace (1) as claimed in claim 11, wherein the generatrix of the frustoconical generated surface forms with the horizontal an angle of 0°.
13. Shaft furnace (1) as claimed in claim 12, the gas supply ducts (6) having an essentially rectangular cross section, wherein the gas supply ducts (6) are designed to taper from the bottom upwards and wherein the inner edges of the gas supply ducts (6) are rounded.
14. Shaft furnace (1) as claimed in claim 13, wherein the transitions (10) from the annular space (5), which surrounds the shaft furnace (1) externally, to the gas supply ducts (6) are designed to descend obliquely downwards.

Dated this 23rd day of January, 2001.

Documents:

abstract1.jpg

in-pct-2001-00091-mum-assignment(22-8-2000).pdf

in-pct-2001-00091-mum-cancelled pages(15-3-2005).pdf

in-pct-2001-00091-mum-cancelled pages(19-1-2004).pdf

in-pct-2001-00091-mum-claims(19-6-2000).pdf

in-pct-2001-00091-mum-claims(granted)-(25-05-2005).doc

in-pct-2001-00091-mum-claims(granted)-(25-5-2005).pdf

in-pct-2001-00091-mum-correspondence(19-1-2004).pdf

in-pct-2001-00091-mum-correspondence(23-3-2006).pdf

in-pct-2001-00091-mum-correspondence(ipo)-(16-11-2009).pdf

in-pct-2001-00091-mum-correspondence(ipo)-(19-5-2005).pdf

in-pct-2001-00091-mum-description(complete)-(19-6-2000).pdf

in-pct-2001-00091-mum-drawing(19-1-2004).pdf

in-pct-2001-00091-mum-drawing(25-3-2005).pdf

in-pct-2001-00091-mum-form 1(15-3-2005).pdf

in-pct-2001-00091-mum-form 19(6-4-2004).pdf

in-pct-2001-00091-mum-form 2(19-6-2000).pdf

in-pct-2001-00091-mum-form 2(granted)-(25-05-2005).doc

in-pct-2001-00091-mum-form 2(granted)-(25-5-2005).pdf

in-pct-2001-00091-mum-form 2(title page)-(19-6-2000).pdf

in-pct-2001-00091-mum-form 3(15-3-2005).pdf

in-pct-2001-00091-mum-form 3(19-1-2004).pdf

in-pct-2001-00091-mum-form 5(15-3-2005).pdf

in-pct-2001-00091-mum-general power of authority(19-1-2004).pdf

in-pct-2001-00091-mum-petition under rule 137(19-1-2004).pdf

in-pct-2001-00091-mum-petition under rule 138(19-1-2004).pdf

in-pct-2001-00091-mum-power of authority(15-3-2005).pdf

in-pct-2001-00091-mum-power of authority(4-6-2001).pdf

in-pct-2001-00091-mum-specification(amended)-(19-1-2004).pdf

in-pct-2001-00091-mum-wo international publication report(19-6-2000).pdf


Patent Number 210894
Indian Patent Application Number IN/PCT/2001/00091/MUM
PG Journal Number 43/2007
Publication Date 26-Oct-2007
Grant Date 15-Oct-2007
Date of Filing 23-Jan-2001
Name of Patentee VOEST-ALPINE INDUSTRIEANLAGENBAU GMBH
Applicant Address TURMSTRASSE 44, A-4020 LINZ,
Inventors:
# Inventor's Name Inventor's Address
1 LEOPOLD WERNER KEPPLINGER LAHHOLDSTRASSE 7, A-4060 LEONDING,
2 RAINER WALTER KASTNER BERGERFELD 16, A-4180 ZWETTL A.D. RODL,
3 KURT WIEDER AISTTALSTRASSE 26, A-4311 SCHWERTBERG,
4 WILHELM SCHIFFER LINZERSTRASSE 23/15, A-4050 TRAUN,
5 WILHELM STASTNY BERBERSDORF 15, A-4211 ALBERNDORF,
PCT International Classification Number C21B13/02 F27B1/10
PCT International Application Number PCT/EP99/04875
PCT International Filing date 1999-07-12
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 A 1392/98 1998-08-13 Austria