Title of Invention	"A PROCESS FOR RECOVERING PENTAFLUOROETHANE"
Abstract	The present invention involves processes that utilize an olefinic compound in particular, hexafluoropropene (HFP) or ehlorotrifluoroethene ((.'1 o'(.'-1 1 13) as extracting agents in the purification of pentunuorocthane (III'(.'-125). These processes can utilize recovered HFP as a precursor for the production of heptafluoropropane (HFC-227) or other derivatives.

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"A PROCESS FOR RECOVERING PENTAFLUOROETHANE" FIELD OF INVENTION The present invention relates to processes for separating pentafluoroethane (CHF2-CF3, HFC-125) from a mixture comprising HFC-125 and chloropentafluoroethane (CF3-CClF2, CFC-115). The present invention further relates to the production of heptafluoropropane (CF3CHFCF3 or CF3CF2CHF2, HFC-227ea or HFC-227ca, collectively HFC-227). BACKGROUND OF THE INVENTION In the recent years, there has been an increasing concern about global warming. As a result, several chlorofluorocarbons (CFC's) that are known to have an adverse environmental impact have been removed from the marketplace. In their place, new compounds have been introduced as flooding agents, streaming agents, blowing agents, propellants, and refrigerants. However, some of these new compounds do not meet environmental safety requirements. Consequently, there is a constant need to develop fluorocarbon compounds, especially hydrofluorocarbons, which have no chlorine. Two hydrofluorocarbons that are known to have desirable properties are pentafluoroethane (HFC-125) and heptafluoropropane (HFC-227). HFC-125 is a valuable hydrofluorocarbon (HFC) that is especially useful as a refrigerant, blowing agent, propellant. or fire-extinguishing agent. HFC-125 can be prepared by a multi-step process starting with fluorination of tetrachloroethene (C2Cl4). The end products of the multi-step process include a mixture containing HFC-125, chloropentafluoroethane (CFC-115), and small amounts of other fluorinated compounds. HFC-227 is another valuable hydrofluorocarbon. One known starting material for the production of HFC-227 is hexafluoropropene (CF3CF=CF2, HFP). HFP can be hydro fluorinated with hydrogen fluoride (HF) in the presence of a suitable catalyst to form HFC-227 and other byproducts. Typically, in the final step of HFC-227 purification, these byproducts are separated out by simple distillation. 1 CFC-115 is an undesirable compound because it contains chlorine, and, as a result, its use is highly regulated. Thus, in the production of HFC-125 for commercial use, it is necessary to separate HFC-125 from CFC-115. Unfortunately, the mixture of HFC-125 and CFC-115 forms a near-azeotrope. At high concentrations of HFC-125, the relative volatility of HFC-125 to CFC-115 is close to 1.0, making recovery of pure HFC-125 from a mixture of HFC-125 and CFC-115 by simple distillation difficult. An azeotrope is a liquid mixture that exhibits a maximum or minimum boiling point relative to the boiling points of its components. An azeotrope is homogeneous if only one liquid phase is present. An azeotrope is heterogeneous if more than one liquid phase is present. Regardless, a characteristic of azeotropes is that the bulk liquid composition is identical to the vapor composition in equilibrium therewith, and distillation of the azeotropic mixture is ineffective as a separation technique. For the purposes of this discussion, a near-azeotrope means a composition which behaves like an azeolrope (i.e., has constant-boiling characteristics or a tendency not to fractionate upon boiling or evaporation). Thus, the composition of the vapor formed during boiling or evaporation of such compositions is the same as or substantially the same as the original liquid composition. Hence, during boiling or evaporation, the liquid composition, if it changes at all, changes only to a minimal or negligible extent. This is to be contrasted with non-azeotrope compositions in which during boiling or evaporation, the liquid composition changes to a substantial degree. Accordingly, the essential features of an azeotrope or a near-azeotrope are that at a given pressure, the boiling point of the liquid composition is fixed and that the composition of the vapor above the boiling composition is essentially that of the boiling liquid composition (i.e., no fractionation of the components of the liquid composition takes place). It is recognized in the art that both the boiling point and the weight percentages of each component of the azeotropic composition may change when the azeotrope or near-azeotrope liquid composition is subjected to boiling at different pressures. Thus, an azeotrope or a near-azeotrope may be defined in terms of the unique relationship that exists among components or in terms of the compositional ranges of the components or in terms of exact weight percentages of each component of the composition characterized by a fixed boiling point at a 2 specified pressure. It is also recognized in the art that various azeotropic compositions including their boiling points at particular pressures may be calculated (see, e.g., W. Schotte, Ind. Eng. Chem. Process Des. Dev. 1980, 19, pp 432-439). Experimental identification of azeotropic compositions involving the same components may be used to confirm the accuracy of such calculations and/or to modify the calculations for azeotropic compositions at the same or other temperatures and pressures. It is known that pure HFC-125 as a near-azeotropic mixture with CFC-115 can be recovered by a process of extractive distillation. In this process, a suitable extracting agent that changes the relative volatility of a component or the azeotrope is used. Examples of extracting agents used in the purification of HFC-125 are disclosed in U.S. Patent Nos. 5,087,329 and 5,928,479. Extractive distillation processes for the purification of HFC-125 usually include a step of separating the extracting agent from either HFC-125 or CFC-115 subsequent to the completion of the extractive distillation. This additional separation process may add to the cost of HFC-125 production even though the extracting agent may be reused. SUMMARY OF INVENTION The present invention provides processes for the production of halogenated hydrocarbons either alone or in combination with the synthesis of olefinic derivatives. In one embodiment of the present invention, at least one halogenated hydrocarbon is purified from a near-azeotropic mixture comprising at least one halogenated hydrocarbon and at least one halocarbon by extractive distillation using an olefinic extracting agent. In this particular embodiment, the olefinic extracting agent is converted into a derivative compound. In another embodiment of the present invention, HFC-125 is purified from a mixture containingCFC-1 115 by extrative distillation, using hexaflubropropene (HFP) or chlorotrifluoroethene (CC1F=CF2, CFC-1113) as an extracting agent. One feature of this particular embodiment is that the extracting agent can be recovered and reused in the purification of HFC-125 as set forth herein. In an alternative 3 embodiment, the recovered extracting agent can be used as a starting material for the production of fluorocarbons like HFC-227. In a specific embodiment of the present invention, the process of recovering HFC-125 comprises the steps of: (a) providing a first mixture comprising HFC-125 and CFC-115, (b) distilling the first mixture in the presence of hexafluoropropene (HFP) to separate HFC-125 from a second mixture comprising HFP and CFC-115. The distilling process may be extractive distillation, in which HFP is an extracting agent. According to another embodiment of the invention, the process may further include the steps of: (c) recovering HFC-125 as an overhead product and (d) recovering the second mixture as a bottom product. According to a further embodiment, the process may further include the step of: (e) purifying HFP from the second mixture to produce a third mixture comprising CFC-115 and the step of (f) recovering HFP. Optionally, the process may include the step of re-using the recovered HFP as an extracting agent, as described herein. Another embodiment of the present invention is directed to a process comprising the steps of: (a)-(d), as described, and the steps of: (g) adding HF to the second mixture to form a fourth mixture, (h) converting HFP in the fourth mixture by hydrofluorination in the presence of a suitable catalyst to HFC-227 to produce a fifth mixture, (i) separating the fifth mixture into HFC-227 and a sixth mixture comprising CFC-115, and (j) recovering HFC-227. A further embodiment of the present invention is directed to a process comprising the steps of: (a)-(f), as described, and the steps of: (k) adding HF to the recovered HFP, (1) converting the recovered HFP by hydrofluorination to HFC-227 in the presence of a suitable catalyst to produce a seventh mixture, (m) separating the seventh mixture Into HFC-227 and byproducts, and (n) recovering HFC-227. In another embodiment, the process comprises the steps of: (a)-(f), as described, and the step of converting HFP to at least one HFP derivative or a fluoropolymer. 4 In an alternative embodiment of the present invention, the process comprises the steps of: (o) providing a first mixture comprising HFC-125 and CFC-115, (p) distilling the first mixture in the presence of CFC-1113 to separate HFC-125 from an eighth mixture comprising CFC-1113 and CFC-115, (q) recovering HFC-125 as an overhead product, and (r) recovering the eighth mixture as a bottom product. The distilling process may be extractive distillation, in which HFP is an extracting agent. In still another embodiment, the process comprises the steps of (o)-(r) and the steps of: (s) adding HF to the eighth mixture to produce a ninth mixture, (t) converting CFC-1113 in the ninth mixture in the presence of a suitable catalyst to a fluoroethane to make a tenth mixture, and recycling the tenth mixture to a hydrofluorocarbon production process. In one embodiment, the fluoroethane is 1-chloro-l,2,2,2-tetrafluoroethane (CHC1FCF3, HCFC-124). The above and other embodiments, aspects, alternative and advantages of the present invention will become more apparent from the following detailed description of the present invention taken in conjunction with the examples. DETAILED DESCRIPTION OF THE INVENTION Embodiments of the present invention overcome the shortcomings of the prior art by providing innovative processes for producing hydrofluorocarbons by separating mixtures of near-azeotrope halogenated hydrocarbons with extracting agents and subsequently converting the extracting agent to a derivative compound that can be separated from at least one of the halogenated hydrocarbons from the near-azeotropic mixture. In one embodiment, the present invention involves the use of an extracting agent, namely HFP, that can be used to purify HFC-125 from a mixture comprising HFC-125 and CFC-115. The mixture may contain mostly HFC-125 and only minute amounts of CFC-115 and other fluorocarbon byproducts. HFP is an important monomer used to produce organic fluorine materials and is readily available in the marketplace. The use of HFP as an extracting agent for the separation of alkanes has never been described in the prior art. It is commonly known that similar compounds are attracted to each other. Thus, typically, in order to separate chlorine containing alkanes from non-chlorine containing alkanes, another chlorine containing alkane is used as an extracting agent. As an alkene, HFP is structurally different from the alkanes disclosed as extracting agents in the U.S. Patent No. 5,087,329. This structural difference in combination with the fact that HFP contains no chlorine made its usefulness as an extracting agent for separating HFC-125 from CFC-115 unexpected. The use of HFP and fluorinated alkenes as extracting agents is demonstrated below in non-limiting Example 1. EXAMPLE 1 Screening of extracting agents for vapor phase separation of HFC-125 and CFC-115 A 50 cc stainless steel sample cylinder fitted with a pressure gauge and valve with a septum port was chilled to -78°C and a known amount of HFC-125 and CFC-115 was charged to the cylinder. This mixture was shaken and allowed to warm to ambient temperature and the vapor phase was sampled for subsequent analysis by gas chromatography (GC). The cylinder was then re-cooled to -78°C and a desired amount of the chosen extraction solvent was added to the vessel. The mixture was then allowed to warm to ambient temperature , at which time, it was shaken and allowed to equilibrate for 3 to 12 hours before it was re-sampled for GC analysis. 6 All GC data of this and the following examples were taken by sampling a collection or storage vessel or the appropriate sample port with a 50 to 250 µL airtight syringe fitted with an on/off valve. This collected sample was injected on either an HP-5890 or 589011 GC equipped with a Varian plot fused silica column (30m x 0.32mm ID). All analyses were done using a time-temperature program which had an initial temperature and time of 70°C and 15 min followed by a ramp to 140°C at a rate of 15°C/min and a final time of 20 min. Selection of column type, sample size and analysis conditions are well known to those skilled in the art of GC. All amounts noted were based on area percent. To verify the identity of each compound, analyses were performed using mass spectrometry. TABLE I is a result of the GC analyses of vapor phase content of HFC-125 and CFC-115 in the starting mixture and the mixture with extracting agent that absorbs CFC-115. As shown in TABLE I, relative volatility of CFC-115 changed with the addition of different solvents. The volatility of CFC-115 was relatively low with the addition of the CFC-solvents, like l,l,2-trichloro-l,2,2-trifiuoroethane (CC12FCC1F2, CFC-113) and l,2-dichloro-l,l,2,2-tetrafluoroethane (CC1F2CF2C1, CFC-114). Thus, these solvents, CFC-113 and CFC-114, performed well in the separation of CFC-115 from HFC-125, as shown by the increase in the percent of HFC-125 or the decrease in the percent of CFC-115 in the vapor phase. As expected, the similar compounds like dichlorohexafluoropropane (C3F6Cl2, CFC-216) and chloroheptafluoropropane (C3F7Cl, CFC-217) also exhibited good extracting ability for CFC-115. However, being chlorofluorocarbons, these compounds are not desirable extracting agents because they are highly regulated suspect ozone depleting compounds. The efficiency of the fluoro-olefins, namely CFC-1113, HFP, HFC-1243zf (CF3CH=CH2, TFP), and HFC-1225zc (CF3CH=CF2, PFP) varied. CFC-1113 and HFP demonstrated a surprising ability to extract CFC-115 from HFC-125. However, since HFP contains no chlorine, it may be more useful as an extracting agent. In contrast to HFP and CFC-1113, the olefins HFC-1243zf and HFC-1225zc had little or no extractive power. In addition, chloroform (CHCl3) did not appear to be an effective extracting agent for the separation of CFC-115. 7 TABLE I; GC Analysis of the vapor phase content of HFC-125 and CFC-115 in starting mixture and mixture with extracting agent that absorbs CFC-115 In certain embodiments, the present invention involves utilizing olefinic extracting agents in two different ways. First, the olefinic extracting agent can be used to purify HFC-125 from a mixture comprising HFC-125 and CFC-115. Relatively pure HFC-125 is recovered as the overhead product, while the majority of the olefinic extracting agent is recovered as a mixture with CFC-115 as a bottom product. In one embodiment, the olefinic extracting agent is HFP. In another embodiment, the olefinic extracting agent is CFC-1113. 8 Second, after it is used as an extracting agent, the olefinic extracting agent can be recovered and used as a precursor for the production of extracting agent derivatives or fluoropolymers. As an olefin, the recovered extracting agent lends itself to hydrohalogenation by addition across the double bond. In one embodiment, HF is added across the double bond of HFP to produce HFC-227. In another embodiment, HF may be added across the double bond of CFC-1113 to produce HCFC-124. In these embodiments, the relative volatility of the extracting agent derivative is sufficiently disparate from CFC-115 that the derivative can be readily separated by known chemical separation techniques such as distillation. Further, CFC-1113 may also be converted to HFC-125 or a mixture of HFC-125 and HCFC-124, in which case it may be recycled to the HFC-125/CFC-115 purification process to produce more HFC-125. These types of hydrohalogenation reactions are commonly performed in the presence of a catalyst. Suitable gas phase catalysts include activated carbon, chromium oxide, nickel, copper, iron, or aluminum oxide. Suitable liquid phase catalysts include antimony chloride, molybdenum, and tantalum. It is contemplated that other compounds and synthetic schemes can be used to derivatize the extracting agent. The resulting compound may be recovered or recycled back to the separation process. According to a specific embodiment of the present invention, a process for separating HFC-125 from CFC-115 is provided. The process includes a step of (a) providing a first mixture comprising HFC-125 and CFC-115. The first mixture may be derived from a hydrotluorination reaction of tetrachloroethene, or other similar processes. The first mixture may also contain small amounts of other hydrofluorination byproducts such as l,l,2-trichloro-l,2,2-trifluoroethane (CFC-113), l,2-dichloro-l,l,2,2-tetrafluoroethane (CFC-114), 2,2-dichloro-l,l,l-trifluoroethane (HCFC-123), or hexafluoroethane (FC-116). The percent concentration of HFC-125 and CFC-115 in the first mixture may vary. The first mixture may contain more than 90% of HFC-125. The first mixture is fed to a fractionation column. In this specific embodiment of the invention, the process further comprises the step of (b) distilling the first 9 mixture in the presence of HFP to separate HFC-125 from a second mixture comprising HFP and CFC-115. During this step, HFP is added to the upper section of the fractionation column. As much as about 50% HFP by weight of HFC-125 may be used, although more than 50% HFP by weight of HFC-125 may be used if desired. However, preferably 20% HFP by weight of HFC-125 is used. The distillation is performed at a condition that allows HFC-125 to pass substantially free of CFC-115 to the top of the column where it is condensed. Some of the HFC-125 may be returned as reflux. Simultaneously, HFP and CFC-115 pass to the bottom of the column as a second mixture. It is possible for the second mixture to also contain residual HFC-125 and other compounds that are present in the first mixture. Finally, in a particular embodiment, the process includes the steps of (c) recovering HFC-125 as an overhead product and (d) recovering the second mixture as a bottom product. One embodiment of this process is demonstrated below in non-limiting Example 2. EXAMPLE 2 Vapor phase separation of HFC-125 from CFC-115 using HFP as an extracting agent This procedure demonstrates the effective removal of CFC-115 from streams of the first mixture comprising HFC-125 and CFC-115, by the use of HFP as an extracting agent. The apparatus used was a 92 in. packed, schedule 40, carbon steel distillation column fitted with a reboiler, overhead condenser, overhead reflux loop, timed takeoff valves, and multiple feed points. This evacuated column was charged with 584 g of the first mixture comprising 97.928% of HFC-125 and 2.073 % of CFC-115, by weight. This mixture was allowed to equilibrate at a reflux ranging from 14 to 29 cc/min. HFP was then fed into the column at an average rate of 1.98 g/min, while taking off CFC-115 and HFP at a rate of 1.75 g/min as the bottom product from the reboiler. The operation was continued over 2348 minutes. The total amount of HFP added was 4438 g. During this time, the relative ratio of HFC-125 to CFC-115 in the 10 overhead of the column increased from 87 to 8194 (TABLE II). This ratio represents approximately 121 ppm (0.0121 % GC-Area) of CFC-115 remaining in the overhead fraction (TABLE II). The recovery from the reboiler shows that most of the HFP was recaptured in the reboiler or the bottom fraction. This bottom fraction also contained CFC-115 and residual HFC-125 (TABLE II). At the end of the operation, the initial charge, including the amount of the first mixture and the total amount of HFP used, is compared to the final recovery in both the reboiler and the overhead fractions. The results show a total mass balance accountability of 96.6%. 11 TABLE II: Extractive distillation using HFP as an extracting agent to separate HFC-125 from CFC-115 In another embodiment of the present invention, the process further includes the step of (e) purifying HFP in the second mixture to produce relatively pure HFP and a third mixture comprising CFC-115 and the step of (f) recovering HFP. The third mixture may include residual HFP and HFC-125. In addition, the third mixture may also include small amounts of byproducts, as indicated above. The recovered HFP from this purification step may contain a minute amount of CFC-115 and other byproducts. The purification step may involve any appropriate technique including 12 distillation. The purification of HFP by simple distillation is demonstrated below in non-limiting Example 3. EX-AMPLE 3 Purification of HFP To demonstrate this process, 507 grams of a mixture containing 90.17% of HFP, 9.798% of HFC-125, and 0.025% of CFC-115 (see TABLE III) was charged to an apparatus consisting of a 92 in. packed, schedule 40, carbon steel distillation column fitted with a reboiler, overhead condenser, and overhead reflux loop. This mixture was allowed to equilibrate with a steady reflux for 224 minutes. The distillation was run at a pressure of about 122-123 psig. The boiler temperature was set at about 31.4°C, and the overhead temperature was set at about 27°C. The overhead and reboiler compositions were checked by GC analysis. The column was then equilibrated for another 100 minutes to obtain further homogeneity of the HFP in the reboiler of the column (see TABLE III). This demonstrates that the longer the distillation was run, the higher purity of HFP was obtained. This level of purity is acceptable for recycle to the HFC-125 extractive distillation system or to be used as a raw material in subsequent downstream reactions. 13 TABLE ITT; Separation of HFP from HFC-125 and CFC- 115 by distillation The recovered HFP may be recycled to be used as an extracting agent in the process of recovering HFC-125 described herein. In another embodiment, the recovered HFP may be converted to at least one of HFP derivatives such as HFC-227, or polymers such as elastomers, plastomers, resins, and fluoropolymers. Another specific embodiment of the present invention comprises the steps of (a)-(d), as described herein, and the further steps of (g) adding HF to the second mixture to form a fourth mixture and (h) converting HFP in the fourth mixture to HFC-227 by hydrofluorination to form a fifth mixture. The benefits of this embodiment are demonstrated by way of non-limiting Example 4 below. EXAMPLE 4 Converting HFP to HFC-227 by selective hydrofluorination in the presence of HFC-125 and CFC-115 A 34 cc alloy-600 reactor tube was charged with 13.1 g of activated carbon catalyst and dried overnight at 155°C with a nitrogen purge. The reaction outlet was configured with an aqueous scrubber filled with dilute caustic followed by a Drierite 14 tube, GC sampling port, and optional cold trap. Three different mixtures were used as the starting material in the reaction runs (# 1-3). Each mixture comprises HFP and minute amounts of CFC-115 and HFC-125 (see TABLE IV). In the reaction run # 4, relatively pure HFP was used as the starting material for comparison. TABLE IV: Composition (% GO of starting material for four reaction runs of fluorination of HFP to HFC-227 Specific conditions of each fluorination reaction run using the materials shown in TABLE IV are shown in TABLE V. For each run, the starting material was supplied to the reactor tube described above. HF was first added to the reactor tube at a rate of about 70 to 74 cc/min. The flow rate of the starting material was about 47 to 60 cc/min. The ratio of HF to HFP ranged from 1.28 to 1.60. The fluorination reaction was run at a temperature of about 200° C (see TABLE V). The contact time ranged from 9.16 to 10.08 seconds. 15 TABLE V; Fluorination conditions of four fluorination reaction runs using four starting materials shown in TABLE IV The result of each fluorination reaction run shown in TABLE V is reported in TABLE VI. Percent conversion of HFP to HFC-227 ranged from about 92.13 to 97.24, while selectivity ranged from about 85 to about 99 %. The amounts of HFC-125 and CFC-115 did not substantially change from what was present in the starting materials (see TABLE IV and VI). Thus, the data in TABLE VI indicate that olefins can be selectively fluorinated without causing any serious side reactions or lowering of conversion while allowing HFC-125 and CFC-115 to pass through the system essentially unchanged. 16 TABLE VI: The results of the fluorination process based on the conditions shown in TABLE V In accordance with another embodiment of the present invention, a process includes the steps of (a)-(d), (g)-(h), and the step (i) separating the fifth mixture into HFC-227 and a sixth mixture comprising CFC-115. The sixth mixture may further comprise HFC-125 and other fluorination byproducts. The separation can be performed by distillation. Finally, this specific embodiment further includes the step of (j) recovering relatively pure HFC-227. This embodiment is demonstrated below by way of non-limiting Example 5. EXAMPLE 5 Separation of HFC-227 from HFC-125 and CFC-115 A mixture containing mainly HFC-227 (57.24%), HFC-125 (29.44% ), and CFC-115 (13.32%) was used as the starting material to demonstrate the process of HFC-227 separation. An evacuated apparatus consisting of a 92 in. packed, schedule 40, carbon steel distillation column fitted with a reboiler, overhead condenser, and overhead reflux loop was charged with 719 grams of the above described mixture. This mixture was allowed to equilibrate at a reflux ranging from 1.86 to 2.46 cc/min over a 1417 minute time period. The overhead product and the bottom product were collected at three different distillation conditions (see TABLE VII). The content of both the overhead and the bottom products was determined by GC. The results 17 shown in TABLE VII indicate that the majority of HFC-227 was separated in the bottom fraction while HFC-125 and CFC-115 were removed as distillates. When the reboiler temperature was increased from 28.2°C to 55.3°C and the vapor pressure was raised from 132 psig to 143 psig, the reflux increased from 1.85 cc/min to 2.46 cc/min, and a significant increase in purity of the HFC-227 in the bottom fraction was observed. Essentially pure HFC-227 (99.92%) could be recovered under one of the conditions tested (144 psig, reboiler temperature 54.8°C, overhead temperature 21.9°C, reflux 2.46 cc/min), while only a small amount of HFC-227 was removed in the overhead fraction. The levels of HFC-227 purity recovered were acceptable for commercial use. The resulting CFC-115 and HFC-125 can either be destroyed, recycled or reacted to form other desirable and useful materials. TABLE VII ; Separation of HFC-227 at three different distillation conditions A further embodiment of the present invention involves a process which comprises the steps of (a)-(f) and the steps of: (k) adding HF to the purified HFP, (1) converting the purified HFP by hydrofluorination to HFC-227 in the presence of a 18 suitable catalyst to form a seventh mixture, (m) separating the seventh mixture into HFC-227 and fluorination byproducts, and (n) recovering relatively pure HFC-227. An example of converting relatively pure HFP to HFC-227 is demonstrated in TABLES IV-VI (see run #4). According to one embodiment, the suitable catalyst is active carbon, but other catalysts that have been previously described are contemplated. Additional objects, advantages, and other novel features of the invention will become apparent to those skilled in the art upon examination of the foregoing or may be learned with practice of the invention. The foregoing description of the embodiments of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Obvious modifications or variations are possible in the light of the above teachings. Embodiments were chosen and described to provide the best illustrations of the principals of the invention and their practical application, thereby enabling one of ordinary skill in the art to utilize the invention in various embodiments and with various modifications as are suited to the particular use contemplated. All such modifications and variations are within the scope of the invention as determined by the appended claims when interpreted in accordance with the breadth to which they are fairly, legally, and equitably entitled. 19 WE CLAIM: 1. A process for recovering pentafluoroethane comprising: providing a first mixture comprising pentafluoroethane and chloropentafluoroethane; and separating at least some of the pentafluoroethane from the first mixture, wherein the separating occurs in the presence of hexafluoropropene. 2. The process as claimed in claim 1 comprising, after separating at least some of the pentafluoroethane from the first mixture, converting the hexafluoropropene to at least one hexafluoropropene derivative. 3. The process as claimed in claim 1 comprising, after separating at least some of the pentafluoroethane from the first mixture, converting the hexafluoropropene to at least one fluoropolymer. 4. The process as claimed in claim 1 comprising, after separating at least some of the pentafluoroethane from the first mixture, recycling the hexafluoropropene to a process for producing pentafluoroethane. 5. The process as claimed in claim 1 comprising: recovering a second mixture comprising hexafluoropropene and chloropentafluoroethane; and separating at least some of hexafluoropropene from the second mixture. 6. The process as claimed in claim 1 comprising, after separating at least some of the pentafluoroethane from the first mixture: recovering a second mixture comprising hexafluoropropene and chloropentafluoroethane; 20 converting the hexafluoropropene of the second mixture to heptafluoropropane to produce a third mixture comprising heptafluoropropane and chloropentafluoroethane; and separating at least some of the heptafluoropropane from the third mixture. 7. The process as claimed in claim 1 comprising, after separating at least some of the pentafluoroethane from the first mixture: recovering a second mixture comprising hexafluoropropene and chloropentafluoroethane; converting the hexafluoropropene of the second mixture to heptafluoropropane to produce a third mixture comprising heptafluoropropane and chloropentafluoroethane; and separating at least some of the chloropentafluoroethane from the third mixture and providing the chloropentafluoroethane to a fluorochemical production process. 8. The process as claimed in claim 7 wherein the fluorochemical production process is a pentafluoroethane production process. 9. The process as claimed in claims 6, 7, or 8 wherein the converting the hexafluoropropene of the second mixture to heptafluoropropane comprises exposing the second mixture to HF. 10. The process as claimed in claims 6, 7, or 8 wherein the converting the hexafluoropropene of the second mixture to heptafluoropropane comprises exposing the second mixture to HF at a temperature of at least 200°C. 11. The process as claimed in claims 6, 7, or 8 wherein the converting the hexafluoropropene of the second mixture to heptafluoropropane comprises exposing the second mixture to HF at a temperature between 200 and 21 0°C. 21 12. A process for recovering pentafluoroethane comprising: providing a first mixture comprising pentafluoroethane and chloropentafluoroethane; and separating at least some of the pentafluoroethane from the first mixture, wherein the separating occurs in the presence of chlorotrifluoroethene. 13. The process as claimed in claim 12 comprising, after separating at least some of the pentafluoroethane from the first mixture, converting the chlorotrifluoroethene to at least one chlorotrifluoroethene derivative. 14. The process as claimed in claim 12 comprising, after separating at least some of the pentafluoroethane from the first mixture, converting the chlorotrifluoroethene to at least one fluoropolymer. 15. The process as claimed in claim 12 comprising, after separating at least some of the pentafluoroethane from the first mixture, recycling the chlorotrifluoroethene to a process for producing pentafluoroethane. 16. The process as claimed in claim 12 comprising : recovering a second mixture comprising chlorotrifluoroethene and chloropentafluoroethane; and separating at least some of chlorotrifluoroethene from the second mixture. 17. The process as claimed in claim 12 comprising, after separating at least some of the pentafluoroethane from the first mixture: recovering a second mixture comprising chlorotrifluoroethene and chloropentafluoroethane; converting the chlorotrifluoroethene of the second mixture to 1 - chloro-1, 2,2,2-tetrafluoroethane to produce a third mixture comprising 1 -chloro-1, 2,2,2-tetrafluoroethane and chloropentafluoroethane; and 22 separating at least some of the 1 -chloro-1, 2,2,2-tetrafluoroethane from the third mixture. 18. The process as claimed in claim 12 comprising, after separating at least some of the pentafluoroethane from the first mixture: recovering a second mixture comprising chlorotrifluoroethene and chloropentafluoroethane; converting the chlorotrifluoroethene of the second mixture to 1-chloro-1, 2,2,2-tetrafluoroethane to produce a third mixture comprising 1-chloro-1, 2,2,2-tetrafluoroethane and chloropentafluoroethane; and separating at least some of the chloropentafluoroethane from the third mixture and providing the chloropentafluoroethane to a fluorochemical production process. 19. The process as claimed in claim 18 wherein the fluorochemical production process is a pentafluoroethane production process. 20. The process as claimed in claims 17, 18, or 19 wherein converting the chlorotrifluoroethene of the second mixture to 1 -chloro-1, 2,2,2-tetrafluoroethane comprises exposing the second mixture to HF. 21. The process as claimed in claims 17, 18, or 19 wherein converting the chlorotrifluoroethene of the second mixture to 1 -chloro-1, 2,2,2-tetrafluoroethane comprises exposing the second mixture to HF at a temperature of at least 200°C. 22. The process as claimed in claims 17, 18 or 19 wherein converting the chlorotrifluoroethene of the second mixture to 1 -chloro-1, 2,2,2-tetrafluoroethane comprises exposing the second mixture to HF at a temperature between 200 and 210°C. 23 The present invention involves processes that utilize an olefinic compound in particular, hexafluoropropene (HFP) or ehlorotrifluoroethene ((.'1 o'(.'-1 1 13) as extracting agents in the purification of pentunuorocthane (III'(.'-125). These processes can utilize recovered HFP as a precursor for the production of heptafluoropropane (HFC-227) or other derivatives.

Documents:

01019-kolnp-2004 abstract.pdf

01019-kolnp-2004 assignment.pdf

01019-kolnp-2004 claims.pdf

01019-kolnp-2004 correspondence.pdf

01019-kolnp-2004 description(complete).pdf

01019-kolnp-2004 form-1.pdf

01019-kolnp-2004 form-18.pdf

01019-kolnp-2004 form-3.pdf

01019-kolnp-2004 form-5.pdf

01019-kolnp-2004 g.p.a.pdf

01019-kolnp-2004 letters patent.pdf

01019-kolnp-2004 reply f.e.r.pdf