Title of Invention

A PROCESS FOR PREPARING RANDOM PROPYLENE COPOLYMERS CONTAINING COPOLYMERIZED C2-C10-ALK-1-ENES

Abstract A process for the preparation of random propylene copolymers contairing copolymerized Cz-C1o-alk-l-enes by polymerization of propylene and Cz-C1o-alk-l- enes in the presence of a Ziegler-Natta catalyst system comprising a titanium- containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the Cz-C1o-alk-l-enes are polymerized with one another at from 50 to 100°C at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 J.tm, a mean particle diameter of the primary particles of from 1 to 10 J.tm and voids or channels having a mean diameter of from 1 to 10 J.tffi, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
Full Text

Improved random propylene copolymers
The present invention relates to random propylene copolymers containing copolymerized C2-C10-alk-l-enes obtainable by polymerization of propylene and C2-C10-alk-l~enes in the presence of a Ziegler-Natta catalyst system comprising a
titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c)r where propylene and the C2-Ci0-alk-l-enes are polymerized with one another at from 50 to 100*C at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200μm, a mean particle diameter of the primary particles of from 1 to 10 μm and voids or channels having a mean diameter of from 1 to 10 μm, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
In addition, the present invention relates to a process for preparing such random propylene copolymers and their use as films, fibers and moldings.
Catalyst systems of the Ziegler-Natta type are known, for example, from EP-B 014523, EP-A 023425, EP-A 045975 and EP-A 195497. These systems are used, in particular, for the polymerization of C2-Cio-alk-l-enes and contain, inter alia, compounds of polyvalent titanium, aluminum halides and/or aluminum alkyls, and also electron donor compounds, in particular silicon compounds, ethers, carboxylic esters, ketones and lactones which are used both in connection with the titanium component and also as cocatalyst.
The Ziegler-Natta catalysts are customarily prepared in two steps. The titanium-containing solid component is prepared first and subsequently reacted with the cocatalyst. The polymerization is-then carried out by means of the catalysts thus obtained.
Furthermore, US-A 48 57 613 and US-A 52 88 824 describe catalyst systems of the Ziegler-Natta type comprising not only a titanium-containing solid component and an aluminum compound but also organic silane compounds as external electron donor compounds. The catalyst systems thus obtained have a good productivity and give polymers of propylene having a high


For some applications of propylene polymers, it is necessary for these to have a high stiffness and only a small proportion of xylene-soluble polymer particles. This is the case, for example, for food films produced from such propylene polymers.
The propylene polymers known from US-A 4 857 613 and
US-A 5 288 824 do not meet these requirements to a sufficient
extent.
It is an object of the present invention to develop, starting from the propylene polymers described in US-A 4 857 613 and US-A 5 288 824, further improved propylene polymers which do not have the abovementioned disadvantages.
We have found that this object is achieved by the random propylene copolymers defined in the introduction.
The random propylene copolymers of the present invention are obtainable by polymerization in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c).
'"itanium compounds used for preparing the titanium-containing iolid component a) are generally halides or alkoxides of :rivalent or tetravalent titanium, with the chlorides of :itanium, particularly titanium tetrachloride, being preferred. Che titanium-containing solid component additionally contains silica gel as support.
Compounds of magnesium are also used, inter alia, in the preparation of the titanium-containing solid component. Suitable magnesium compounds are, in particular, magnesium halides, magnesium alkyls and magnesium aryls, and also magnesium alkoxy and magnesium aryloxy compounds, with preference being given to using magnesium dichloride, magnesium dibromide and di(C1-C10~alkyl)magnesium compounds. In addition, the titanium-containing solid component can contain additional halogen, preferably chlorine or bromine.

he titanium-containing solid component a) additionally contains ilectron donor compounds, for example monofunctional or polyfunctional carboxylic acids, carboxylic anhydrides and :arboxylic esters, also ketones, ethers, alcohols, lactones, or organophosphorus and organosilicon compounds. As electron donor :ompounds within the titanium-containing solid component, rreference is given to using phthalic acid derivatives of the general formula (II)

where X and Y are each a chlorine atom or a C1-C10-alkoxy radical or together are oxygen. Particularly preferred electron donor compounds are phthalic esters where X and Y are each a C1-C-alkoxy radical, for example a methoxy, ethoxy, propyloxy or butyloxy radical.
Further preferred electron donor compounds within the titanium-containing solid component are, inter alia, diesters of 3- or 4-membered, unsubstituted or substituted cycloalkyl-1,2-dicarboxylic acids, and also monoesters of unsubstituted or substituted benzophenone-2-carboxylic acids. The hydroxy compounds used for forming these esters are the alcohols customary in esterification reactions, for example C1-C15-alkanols, C5-C7-cycloalkanols, which can in turn bear C1-C10-alkyl groups, also C6-C10-phenols.
The titanium-containing solid component can be prepared by methods known per se. Examples of such methods are described, inter alia, in EP-A 45 975, EP-A 45 977, EP-A 86 473, EP-A 171 200, GB-A 2 111 066, US-A 48 57 613 and US-A 52 88 824.
In the preparation of the titanium-containing solid component a), the following two-stage process is preferably employed:
In the first stage, silica gel (Si02) as finely divided support, which generally has a mean particle diameter of from 5 to 200μm, in particular from 20 to 70 μm, a pore volume of from 0.1 to 10 cm3/g, in particular from 1.0 to 4.0 cm3/g, and a specific surface area of from 10 to 1000 m2/g, in particular from 100 to . 500 m2/g, is first reacted with a solution of the magnesium-containing compound in a liquid alkane, after which this mixture is stirred for from 0.5 to 5 hours at from 10 to

20*C. Preferably, from 0,1 to 1 mol of the magnesium compound is sed per mole of the support. Subsequently, a halogen or a ydrogen halide, in particular chlorine or hydrogen chloride, in in at least two-fold, preferably at least five-fold, molar excess >ased on the magnesium-containing compound is added while itirring continually. After about 30-120 minutes, this reaction product is admixed at from 10 to 150*C with a C1-C8-alkanol, in >articular ethanol, a halide or an alkoxide of trivalent or :etravalent titanium, in particular titanium tetrachloride, and also an electron donor compound. Here, from 1 to 5 mol of the :rivalent or tetravalent titanium and from 0.01 to 1 mol, in particular from 0.2 to 0.6 mol, of the electron donor compound are used per mole of magnesium in the solid obtained from the Eirst stage. This mixture is stirred for at least 30 minutes at from 10 to 150°C, the solid thus obtained is subsequently filtered off and washed with a C7-C10-alkylbenzene, preferably with ethylbenzene.
In the second stage, the solid obtained from the first stage is extracted for at least one hour at from 100 to 150*C with excess titanium tetrachloride or an excess of a solution of titanium tetrachloride in an inert solvent, preferably an alkylbenzene, with the solvent containing at least 5% by weight of titanium tetrachloride. The product is then washed with a liquid alkane until the titanium tetrachloride content of the washings is less than 2% by weight.
The titanium-containing solid component obtainable in this way is used together with a cocatalyst as Ziegler-Natta catalyst system. An example of a suitable cocatalyst is an aluminum compound b).
Aluminum compounds b) suitable as cocatalysts are trialkylaluminum and also such compounds in which an alkyl group is replaced by an alkoxy group or by a halogen atom, for example by chlorine or bromine. Preference is given to using trialkylaluminum compounds whose alkyl groups each have from 1 to 8 carbon atoms, for example trimethylaluminum, triethylaluminum or methyldiethylaluminum.
Preferably, use is made not only of the aluminum compound b) but also, as further cocatalyst, electron donor compounds c) such as, for example, monofunctional or polyfunctional carboxylic acids, carboxylic anhydrides and carboxylic esters, also ketones, ethers, alcohols, lactones, or organophosphorus and organosilicon 45.compounds. Preferred electron donor compounds are here organosilicon compounds of the general formula (I)


tere
are identical or different and are each a C1-C20-alkyl group, a - to 7-membered cycloalkyl group which in turn can bear a .-C10-alkyl group, or a C6-C20~aryl or arylalkyl group, R2 are ientical or different and are each a C1-C20-alkyl group and n is r 2 or 3. Particular preference is here given to those compounds i which R1 is a C1-C8-alkyl group or a 5- to 7-membered ycloalkyl group, and R2 is a C1-C4alkyl group and n is 1 or 2.
mong these compounds, particular emphasis may be given to imethoxydiisopropylsilane, dimethoxyisobutylisopropylsilane, imethoxydiisobutylsilane, dimethoxydicyclopentylsilane, imethoxyisobutylsec-butylsilane, dimethoxyisopropylsec-utylsilane, diethoxydicyclopentylsilane and iethoxyisobutylisopropylsilane.
he individual compounds b) and, if desired, c) can be used as :ocatalyst either individually in any order or as a mixture of ;wo components.
according to the present invention, the silica gel used in the :itanium-containing solid component a) is a finely divided silica gel having a mean particle diameter of from 5 to 200 μm, in particular from 20 to 70 jxm, and a mean particle diameter of the primary particles of from 1 to 10 -Ci-Ciμm, in particular from 1 to 3 [Am. The primary particles mentioned here are porous, granular silica gel particles which are obtained from an Si02 hydrogel by tiilling, possibly after appropriate sieving.
Furthermore, the finely divided silica gel to be used according to the present invention also has voids or channels having a mean diameter of from 1 to 10 μm, in particular from 1 to 5 μm, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%, in particular in the range from 5 to 15%. The finely divided silica gel also has, in particular, a pore volume of from 0.1 to 10 cm3/g, preferably from 1.0 to 4.0 cm3/g, and a specific surface area of from 10 to 1000 m2/g, preferably from 100 to 500 μ2/g.
Owing to the voids or channels present in the finely divided silica gel, there is a significantly improved distribution of the active catalyst components in the support material. In addition, a material containing such voids and channels has a positive effect on the diffusion-controlled supply of monomers and cocatalysts and thus also on the polymerization kinetics. Such a

nely divided silica gel is obtainable, inter aliaf by spray ying milled, appropriately sieved Si02 hydrogel, which for this Lrpose is mixed to a paste with water or an aliphatic alcohol, >wever, such a finely divided silica gel is also commercially railable.
be silica gel is preferably present in the titanium-containing dlid component a) in such amounts that from 0.1 to 1.0 mol, in irticular from 0.2 to 0.5 mol, of the magnesium compound is resent per 1 mol of the silica gel.
le cocatalytic compounds b) and c) can be allowed to act on the itanium-containing solid component a) either successively or ogether. This is usually done at from 0 to 150*C, in particular rom 20 to 90*C, and at pressures of from 1 to 100 bar, in articular from 1 to 40 bar.
he cocatalysts b) and c) are preferably used in such an amount hat the atomic ratio of aluminum from the aluminum compound to
Itanium from the titanium-containing solid component a) is from 0:1 to 800:1, in particular from 20:1 to 200:1, and the molar atio of the aluminum compound to the electron donor compound c)
ised as cocatalyst is from 1:1 to 250:1, in particular from 10:1
:o 80:1.
The preparation of the random propylene copolymers of the present Invention can be carried out in the customary reactors used for the polymerization of C2-C10-alk-l-enes either batchwise or preferably continuously, for example as a suspension polymerization or preferably as a gas-phase polymerization. Suitable reactors include continuously operated stirred reactors containing a fixed bed of finely divided polymer which is customarily kept in motion by suitable stirring equipment. Of course, the reaction can also be carried out in a plurality of reactors connected in series.
The process leading to the random propylene copolymers of the present invention, which process is likewise subject matter of the present invention, is carried out by polymerizing propylene together with the C2-C10-alk-l-enes at from 50 to 100 C, pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours. Preference is given to temperatures of from 60* to 90*C, pressures of from 20 to 35 bar and mean residence times of from 0.5 to 3 hours.

The comonomers propylene and the C2-C10-alk-l-ene(s) are here usually used in such amounts that the partial pressure ratio of propylene to the C2-C10-alk-l-ene(s) is from 2:1 to 100:1, in particular from 5:1 to 80:1. The term C2-C10~alk-l-enes here means, in particular , ethylene, 1-butene , 1-pentene, 1-hexene, 1-heptene or 1-octene or mixtures of these, with preference being given to using ethylene, 1-butene or mixtures of ethylene and 1-butene. If a mixture of ethylene and 1-butene is used as C2-C10-alk-l-ene, the partial pressure ratio of propylene, ethylene and 1-butene should be maintained in the range from 2:0.5:1 to 100:50:1, in particular in the range from 5:1:1 to 80:20:1.
The molecular weight of the random propylene copolymers can be controlled and adjusted over a wide range by addition of regulators customary in polymerization technology, for example hydrogen. Furthermore, it is possible to concomitantly use inert solvents such as toluene or hexane, inert gas such as nitrogen or argon and relatively small amounts of polypropylene powder. The random propylene copolymers of the present invention preferably have molecular weights (weight average) of from 20,000 to 500,000. Their melt flow indices at 230*C and under a load of 2.16 kg in accordance with DIN 53 735 are in the range from 0.1 to 100 g/10 min, in particular in the range from 0.5 to 50 g/10 min.
In comparison with random propylene copolymers known hitherto, the random propylene copolymers of the present invention are notable, in particular, for reduced amounts of xylene-soluble material, ie. they have an improved stereospecificity and a higher stiffness. The productivity of the process used for preparing these random propylene copolymers is significantly increased in comparison with the known processes.
Owing to their good mechanical properties, the random propylene copolymers of the present invention are particularly suitable for the production of films, fibers and moldings.
Examples 1 to 3 and Comparative Examples A to C
/ Example 1
a) Preparation of the titanium-containing solid component (1)
In a first stage, finely divided silica gel (Si02) having a
particle diameter of from 20 to 45 μm, a pore volume of
1.5 cm3/g and a specific surface area of 260 m2/g was admixed

with a solution of n-butyloctylmagnesium in n-heptane, with 0.3 mol of the magnesium compound being used per mole of Si02. The finely divided silica gel additionally had a mean particle size of the primary particles of 3-5 μm and voids and channels having a diameter of 3-5 μm, with the macroscopic proportion by volume of the voids and channels based on the total particle being about 15%. The mixture was stirred for about 45 minutes at 95*C, then cooled to 20*C, after which 10 times the molar amount, based on the organomagnesium compound, of hydrogen chloride was passed in. After 60 minutes, the reaction product was admixed while stirring continually with 3 mol of ethanol per mole of magnesium. This mixture was stirred for 0.5 hours at 80*C and subsequently admixed with 7.2 mol of titanium tetrachloride and 0.5 mol of di-n-butyl phthalate, in each case based on 1 mol of magnesium. Subsequently, the mixture was stirred for 1 hour at 100*C, the solid thus obtained was filtered off and washed a number of times with ethylbenzene.
The solid product obtained in this way was extracted for 3 hours at 125*C with a 10% strength by volume solution of titanium tetrachloride in ethylbenzene. The solid product was then separated from the extractant by filtration and washed with n-heptane until the washings contained only 0.3% by weight of titanium tetrachloride.
The titanium-containing solid component comprised

The particle diameter was determined by Coulter Counter analysis (particle size distribution of the silica gel particles), the pore volume and the specific surface area were determined by nitrogen adsorption in accordance with DIN 66131 or by mercury porosimetry in accordance with DIN 66133. The mean particle size of the primary particles, the diameter of the voids and channels and their macroscopic proportion by volume were determined by means of scanning electron microscopy or electron pfrobe microanalysis, in each case on particle surfaces and on particle cross sections of the silica gel.

b) Polymerization
The polymerization was carried out in a vertically stirred gas-phase reactor having a utilizable capacity of 800 1 in the presence of hydrogen as molecular weight regulator at 80*C and under a pressure of 23 bar. The reactor contained an agitated fixed bed of finely divided polymer.
A gaseous mixture of propylene and ethylene was passed into the gas-phase reactor, with the ratio of the partial pressure of propylene to that of ethylene being 78:1. Polymerization was carried out continuously at a mean residence time of 1.5 hours with the aid of the titanium-containing solid component a) described in Example la), using 7.5 g/h of the titanium-containing solid component a) and 450 mmol/h of triethylaluminum and 45 mmol/h of dimethoxyisobutylisopropylsilane as cocatalyst.
After the gas-phase polymerization was complete, a random propylene copolymer containing 2.6% by weight of copolymerized ethylene and having a melt flow index of 2.4 g/10 min at 230*C and 2.16 kg (in accordance with DIN 53 7 35) was obtained.
Comparative Example A
Propylene and ethylene were polymerized by a method similar to Example 1 according to the present invention using the same catalyst system and the same conditions, but using a titanium-containing solid component a) made from a granular silica gel having the following properties:

After the gas-phase polymerization was complete, a/random propylene copolymer containing 2.4% by weight of copolymerized ethylene and having a melt flow index of 2.7 g/10 min at 230*C and 2.16 kg (in accordance with DIN 53 735) was obtained.
15 Example 2

The procedure of Example 1 according to the present invention was repeated, with a gaseous mixture of propylene and ethylene having a ratio of the partial pressure of propylene to that of ethylene of 35:1 being polymerized at a mean residence time of 1.5 hours.
After the gas-phase polymerization was complete, a random propylene copolymer containing 3.5% by weight of copolymerized ethylene and having a melt flow index of 1.9 g/10 min at 230*C and 2.16 kg (in accordance with DIN 53 735) was obtained.
Comparative Example B
Propylene and ethylene were polymerized by a method similar to Example 2 according to the present invention using the same catalyst system and the same conditions, but using a titanium-containing solid component a) made from a granular silica gel having the following properties:

After the gas-phase polymerization was complete, a random propylene copolymer containing 3.4% by weight of copolymerized ethylene and having a melt flow index of 2.0 g/10 min at 230*C and 2.16 kg (in accordance with DIN 53 735) was obtained.
Example 3
Using a method similar to Example 1 according to the present invention, a mixture of propylene, ethylene and 1-butene was polymerized in the gas-phase reactor at 70*C and a pressure of 20 bar. The partial pressure ratio of propylene to ethylene and 1-butene was 20:1.0:0.9, the mean residence time of the reaction mixture was 1.5 hours.
After the gas-phase polymerization was complete, a/random propylene copolymer containing 4.0% by weight of copolymerized ethylene and 2.1% by weight of copolymerized 1-butene was obtained. The melt flow index (HLMI) of this random propylene copolymer was 105 g/10 min at 230*C and 21.6 kg (in accordance with DIN 53 735).

Comparative Example C
Propylene and ethylene were polymerized by a method similar to Example 2 according to the present invention using the same catalyst system and the same conditions, but using a citanium-containing solid component a) made from a granular silica gel having the following properties:

After the gas-phase polymerization was complete, a random propylene copolymer containing 3,9% by weight of copolymerized ethylene and 2.0% by weight of copolymerized 1-butene was obtained. The melt flow index (HLMI) of this random propylene copolymer was 120 g/10 min at 230*C and 21.6 kg (in accordance with DIN 53 735).
The Table below shows, both for the Examples 1 to 3 according to the present invention and for the Comparative Examples A to C, the productivity of the catalyst system used and also the following properties of the random propylene copolymers obtained in each case: proportion of xylene-soluble material (measure of the stereospecificity of the polymer), stiffness (G modulus) and melt flow index.



Comparison of the Examples 1 to 3 according to the present invention with the Comparative Examples A to C makes it clear that the process of the present invention has a higher productivity and leads to random propylene copolymers having an increased stereospecificity (lower proportions of xylene-soluble material) and an increased stiffness (higher G modulus).



We claim:
A random propylene copolymer containing copolymerized C2-C10-alk-l-enes obtainable by polymerization of propylene and C2-Ci0-alk-l-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C2-C10-alk-l-enes are polymerized with one another at from 50 to 100#C at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 μm, a mean particle diameter of the primary particles of from 1 to 10 μm and voids or channels having a mean diameter of from 1 to 10 μm, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
2. A random propylene copolymer as claimed in claim 1, wherein the silica gel used has voids and channels having a mean diameter of from 1 to 5 μm, which voids and channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 15%.
3. A random propylene copolymer as claimed in claim 1 or 2, wherein the silica gel used has been spray dried.
4. A random propylene copolymer as claimed in any of claims 1 to 3, wherein the further electron donor compound c) used is an organosilicon compound of the general formula (I)

where R1 are identical or different and are each a C1-C20-alkyl group, a 5- to 7-membered cycloalkyl group which 1 in turn can bear a C1-C10~alkyl group, or a C1-C20~aryl or
arylalkyl group, R2 are identical or different and are each a C1~C20~alkyl group and n is 1, 2 or 3.
5. A process for preparing random propylene copolymers
containing copolymerized C2-C10-alk-l-enes obtainable by
polymerization of propylene and C2-C10-alk-l-enes in the
presence of a Ziegler-Natta catalyst system comprising a

titanium-containing sona component, a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C2-Cio-alk-l-enes are polymerized with one another at from 50 to 100*C at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours, wherein the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 [im, a mean particle diameter of the primary particles of from 1 to 10 |im and voids or channelsNhaving a mean diameter of from 1 to 10 \xm, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
6. A process as claimed in claim 5, wherein the polymerization
is carried out at mean residence times of from 0.5 to 3
hours.
7. A process as claimed in claim 5, wherein ethylene is used as
C2-C!o-alk-l-ene.
8. A process as claimed in claim 5, wherein a mixture of
ethylene and 1-butene is used as C2-C10-alk-l-ene.
9. Use of the random propylene copolymers as claimed in any of
claims 1 to 4 as films, fibers and moldings.
10. A random propylene copolymer, substantially as hereinabove described and exemplified.


Documents:

2163-mas-1996-abstract.pdf

2163-mas-1996-assignment.pdf

2163-mas-1996-claims duplicate.pdf

2163-mas-1996-claims original.pdf

2163-mas-1996-correspondance others.pdf

2163-mas-1996-correspondance po.pdf

2163-mas-1996-description complete duplicate.pdf

2163-mas-1996-description complete original.pdf

2163-mas-1996-form 1.pdf

2163-mas-1996-form 26.pdf

2163-mas-1996-form 3.pdf

2163-mas-1996-form 4.pdf


Patent Number 206809
Indian Patent Application Number 2163/MAS/1996
PG Journal Number 26/2007
Publication Date 29-Jun-2007
Grant Date 11-May-2007
Date of Filing 03-Dec-1996
Name of Patentee M/S. NOVOLEN TECHNOLOGY HOLDINGS C V
Applicant Address OOSTDUINLAAN 75, 2596 JJ
Inventors:
# Inventor's Name Inventor's Address
1 MEINOLF KERSTING IN DER ACHEN 26,67435 NEUSTADT
2 STEPHAN HUFFER WEIMARER STR.50, 67071LUDWIGSHAFEN
3 FRANZ LANGHAUSER SALINENSTR.103,67098 BAD DURKHEIM
4 RAINER ALEXANDER WERNER WELLSRING 33,67098 BAD DURKHEIM
5 PATRIK MULLER JOHANNISKREUZER STR.67,67661 KAISERSLAUTERN
6 JURGEN KERTH WATTENHEIMER STR.15,67316 CARLSBERG
PCT International Classification Number C 0 8 F210/02
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 195 45 499.5 1995-12-06 Germany