Title of Invention

A TWO-COMPARTMENT DISPENSER

Abstract ABSTRACT 429/MAS/2003 A two-compartment dispenser The present invention relates to a two-compartment dispenser comprising a first compartment containing a aqueous composition having a pH of great than 2 but less than 7 comprising a hydrogen peroxide or an organic peracid; a second compartment containing an acidic component and a dispensing means adapted to dispense at least part of the contents of the first compartment and the second compartment either sequentially or simultaneously to form a mixture of the aqueous composition of the first compartment with the acidic component of the second compartment to form a mixture having a pH of 2 or less.
Full Text

The present application relates to an improved process for carrying out bleaching and/or limescale removal at a surface.
The use of oxygen bleaches in compositions for bleaching household surfaces has been known for a long time and many such compositions are available. However a common difficulty in formulating such a composition is to ensure that it remains stable during storage but is sufficiently active on use. This is particularly difficult to achieve in liquid bleaching compositions. Many solutions have here. proposed to this problem but most of these require the use of expensive stabilizing components or of complex formulation processes.
One solution has been to formulate liquid peroxygen bleaches at pHs between about 3 and 7 to produce a stable composition, but in practice such compositions do not provide sufficient bleaching power to be useful for many household situations. Attempts have therefore also been made to formulate liquid peroxygen bleach compositions at pHs above this range to improve the bleaching power. However these generally require expensive stabilizing compounds to prevent loss of activity after manufacturing.
The present invention provides a peroxide bleach product which has =acceptable stability after manufacture, but which is capable of providing effective bleaching power when used by the consumer.

Commercial products capable of removing limescale from domestic surfaces are well known. Most of these products are based on acids which simply dissolve the limescale. Many surfaces require botch timescale removal and bleaching, but no commercially available products are truly capable of both functions.
Furthermore, it would be convenient to the consumer to purchase one product which could be used either for limescale removal or bleaching as required, even when both functions are not required simultaneously.
The present invention provides a product which is capable of carrying out effective bleaching and/or limescale removal at a surface.
According to the invention, there is provided a process for bleaching and/or providing limescale removal at a surface, comprising applying to that surface an aqueous composition of hydrogen peroxide or an organic peracid, which composition has a pH of 2 or less and comprises a mixture of:
a) an aqueous composition comprising hydrogen
peroxide or an organic peracid having a pH of greater
than 2 but less than 7 (hereinafter component (a)), and
b) an acidic composition (hereinafter component
(b)) ,
wherein components (a) and (b) are mixed not more than two hours before being applied to the surface requiring bleaching and/or limescale removal.
Compositions suitable for carrying out the invention may be provided in ready-to-use form or, preferably, may

be provided as separate components suitable for mixing by the consumer. Where the compositions are suitable for mixing they may be mixed either directly at the surface or remote from the surface before application.
According to a further aspect of the invention, there is provided a process for preparing an aqueous bleaching and/or limescale removing composition having a pH of 2 or less by mixing
a) an aqueous composition comprising hydrogen peroxide or an organic peracid having a pH of greater than 2 but less than 7 (hereinafter component (a)), and
b) an acidic composition (hereinafter component (b)),
wherein components (a) and (b) are mixed not more than two hours before being applied to the surface requiring bleaching and/or limescale removal.
The organic peracids are preferably compounds of the formula XC(0)OOH, wherein X is H or CH3(CH2)n and n is from 0 to 8, most preferably peracetic acid (n=0), peroxy propionic acid (n=l) or peroxy hexanoic acid (n=4).
By "acidic composition" is meant a composition comprising at least one acid (in liquid or solid form), such that when mixed in suitable proportions with the aqueous composition comprising hydrogen peroxide or an organic peracid the resultant mixture has a pH of 2 or less .
Component (a) preferably comprises hydrogen peroxide or peracetic acid.

Component (b) may be a solid (ie granular or powder) acidic composition or, preferably, an aqueous liquid acidic composition.
Where component (b) is an aqueous liquid, it preferably comprises hydrochloric acid, sulphamic acid, tartaric acid, phosphoric acid, oxalic acid, citric acid or salicylic acid; most preferably hydrochloric acid, sulphuric acid, phosphoric acid or citric acid.
Where component (b) is solid, it preferably comprises tartaric acid, phosphoric acid, ascorbic acid, oxalic acid, citric acid or salicylic acid; most preferably phosphoric acid or citric acid.
In accordance with the invention, the two components
(a) and (b) may be mixed in any suitable proportions,
depending upon their initial concentrations, suitably
such that the finally applied mixture comprises 0.01-30%
w/w of hydrogen peroxide or an organic peracid.
Preferably, the ratio of component (a) to component (b)
is from 10:1 to 1:10, most preferably from 2:1 to 1:2.
It is preferred that the two components (a) and (b) are mixed no more than 10 minutes before application to the surface requiring bleaching and/or limescale removal.
It is most preferred that the two components (a) and
(b) are mixed at the surface requiring bleaching and/or
limescale removal, so that the improved bleaching effect
may occur immediately.
In this aspect component (a) may be applied to the surface followed by component (b) or vice versa. Alternatively (and preferably) components (a) and (b) are applied to the surface requiring bleaching and/or limescale removal substantially simultaneously.

According to a preferred embodimenc of the present Invention, the concentration of hydrogen peroxide or organic peracid in the composition immediately after nixing is from 0.01 to 10% w/w. This would mean for example in a 1:1 mix of component (a) to (b) that :omponent (a) prior to the mixing would contain from 0 . 02 :o 20% w/w of hydrogen peroxide or an organic peracid.
Where component (a) comprises hydrogen peroxide it Ls most preferred that the concentration of hydrogen 3eroxide in the mixture immediately after mixing should De from 1.5 to 5% w/w. For example, if a 1:1 mixture of :omponents (a) and (b) is to be mixed, then comiponent (a) should comprise from 3 to 10% w/w hydrogen peroxide.
The concentration of the acid in component (b) will oe chosen such that the pH of the mixture of components (a) and (b) will be 2 or less. Accordingly this will iepend upon the acid chosen, the proportion of components (a) and (b) to be mixed, the initial pH of the component (a) , and the intended pH of the mixture of components (a) and (b).
The process of the present invention alleviates the leed to use further stabilising components when preparing commercial products.
The compositions suitable for use in the process according to the invention may further include any other conventional additives known to the art. Examples of these include fragrances, surfactants (for example anionic, cationic, nonionic, amphoteric or mixtures thereof), thickeners, dyes, sequesterants, chelating agents, germicides, preservatives, corrosion inhibitors or antioxidants. Most preferably the compositions

suitable for carrying out the present invention will contain at least one of the following:
an anionic surfactant (e.g. sodium xylene sulphonate),
a nonionic surfactant (e.g. an alkyl alcohol ethoxylate),
a cationic surfactant (e.g. a quaternary ammonium
surfactant),
a thickener (e.g. xanthan gum),
a dye,
a fragrance.
The above auxiliary components may be included in the compositions suitable for use in the process of the present invention at concentrations of from 0.01% w/w to 10% w/w. These auxiliary ingredients may be included in either component (a), or component (b) or both if appropriate.
According to a further aspect of the present invention, there is provided the use of an aqueous composition of hydrogen peroxide or an organic peracid, which composition has a pH of 2 or less, to remove limescale at a surface or to both bleach and remove limescale at a surface.
Compositions suitable for use in the process according to the present invention may be stored in any appropriate containers known to the art. For example, the two components may be stored in two-compartment packs suitable for sequential or simultaneous dispensing.
Where both components (a) and (b) are liquids, most preferably they may be stored in a two-compartment dispenser, one compartment containing each component and the dispenser being adapted to dispense each component on

to a surface, either sequentially or, preferably, simultaneously.
According to a further aspect of the invention, there is provided a two-compartment dispenser comprising
a first compartment containing an aqueous composition comprising hydrogen peroxide or an organic peracid and having a pH of greater than 2 but less than 7;
a second compartment containing an acidic component; and
dispensing means adapted to dispense the contents (or a part thereof )of the compartments on to a surface either sequentially or simultaneously to form a mixture thereof; whereby the pH of the acidic component is so selected, and/or the dispensing means is so adapted that the mixture has a pH of less than 2.
Preferably, the first compartment contains an aqueous composition comprising 3 to 10% w/w hydrogen peroxide; and the second compartment contains an aqueous composition comprising hydrochloric acid.
A process according to the present invention may be used to bleach and/or remove limescale from any suitable acid-resistant household surface, for example ceramic surfaces such as lavatory surfaces or tiles.
The invention will now be illustrated by the following Examples.

Accordingly the present invention provides a two-compartment dispenser comprising a first compartment containing a aqueous composition having a pH of great than 2 but less than 7 comprising a hydrogen peroxide or an organic peracid; a second compartment containing an acidic component; and a dispensing means adapted to dispense at least part of the contents of the first compartment and the second compartment either sequentially or simultaneously to form a mixture of the aqueous composition of the first compartment with the acidic component of the second compartment to form a mixture having a pH of 2 or less.

Example 1
The following two aqueous compositions are prepared.
Composition (a)
Hydrogen peroxide (35% aqueous solution) 9g
Water 91g
Composition (b)
Hydrochloric acid (36 Twaddle) 25g
Water 75g
The two compositions (a) and (b) are mixed together in a beaker and the resulting composition has a pH of approximately 0.
Samples of the composition are immediately applied to surfaces requiring bleaching, and left in contact for 2 0 minutes. The surfaces are then rinsed with water. The mixed composition produces improved bleaching of the surface compared to either composition (a) or (b) alone when diluted with an equal volume of water.
Example 2
The following compositions are prepared.
parts w/w Composition (a)
Hydrogen peroxide (35% aqueous solution) 9.00
Sodium xylene sulphonate (3 0%) 2.4 0
Hexadecyl trimethylammonium chloride (30%) 3.77
Citric acid 0.31
Fragrance 0.2 0

Dye 0.005
Water 84.315
pH 2.6
Composition ,(b) Parts w/w
Hydrochloric acid (36 Twaddle) 25.00
Tallow trimethyl ammonium chloride (50% in
IPA/water) 0.60
Tallow bis (2-hydroxyethyl) amine 1.2 0
Fatty (C12/C14) alcohol ethoxylate (12 mole) 0.27
Water 72.93
Equal proportions of the two compositions are mixed to give a composition having an initial hydrogen peroxide concentration of 1.55% and an initial pH of approximately 0.
Example 3
The following compositions are prepared
Composition (a) Parts w/w
Hydrogen Peroxide (35% aqueous solution) 9.00
Surfactants-
Arquad 16/29 (AKZO) 3.77
Sodium Xylene Sulphonate(30%) 2.40
Citric Acid (Anhydrous) 0.31
Fragrance (Parfex 43174 (Givaudan Roure)) 0.20
Dye (Sandolun Turquoise EVS (Sandoz dyes)) 0.006
Water 84.31

Composition (b)
Pre-mix Parts w/w
Soft Water 33.83
Surfactants -
Arquad T-50 3.86
Ethomeen T12 8.00
Lutensol (80%) 1.78
Dye(Flexonyl B2G (Hoechst)) 0.0253
Main Mix
Hydrochloric Acid (36 Twaddle) 25.00
Pre-mix 15.00
Soft Water 60.00
Equal proportions of the two compositions (a) and (b) are mixed to give a composition having an initial hydrogen peroxide concentration of 1.575% and an initial pH of less than 1.
Example 4
The improved bleaching performance of the compositions of the invention is tested by the following procedure.
Three ceramic tiles are covered in blue absorbent laboratory paper (Kimberley Clarke). Three mis of one of the following compositions are applied to the tiles.
i) Example 1, Composition (a), diluted to 50% w/w with water (1.575% w/w hydrogen peroxide);
ii) Example 1, Composition (b), diluted to 50% w/w with water (4.5% w/w active hydrochloric acid);



WE CLAIM:
1. A two compartment dispenser comprising, a first compartment
containing a aqueous composition living a pH of great than 2 but less than 7
comprising a hydrogen peroxide or an organic per acid a second
compartment containing an acidic component; and a dispensing means
adapted to dispense at least part of the contents of the first compartment and
the second compartment either sequentially or simultaneously to form a
mixture of the aqueous composition of the first compartment with the acidic
component of the second compartment to form a mixture having a pH of 2
or less.
2. The two compartment dispenser as claimed in claim 1, wherein
the first compartment contains an aqueous composition comprising 3 to 10%
w/w hydrogen peroxide.
3. The two compartment dispenser as claimed in claim 1 or 2,
wherein the second compartment contains an aqueous composition
comprising hydrochloric acid.
4. A two compartment dispenser substantially as herein described
and exemplified.


Documents:

0429-che-2003 others.pdf

0429-che-2003 abstract duplicate.pdf

0429-che-2003 abstract.pdf

0429-che-2003 claims duplicate.pdf

0429-che-2003 claims.pdf

0429-che-2003 correspondence others.pdf

0429-che-2003 correspondence po.pdf

0429-che-2003 description (complete) duplicate.pdf

0429-che-2003 description (complete).pdf

0429-che-2003 form-1.pdf

0429-che-2003 form-19.pdf

0429-che-2003 form-26.pdf

0429-che-2003 form-3.pdf

0429-che-2003 form-5.pdf


Patent Number 198898
Indian Patent Application Number 429/CHE/2003
PG Journal Number 30/2009
Publication Date 24-Jul-2009
Grant Date 07-Mar-2006
Date of Filing 23-May-2003
Name of Patentee M/S. RECKITT & COLMAN PRODUCTS LIMITED
Applicant Address ONE BURLINGTON LANE, LONDON W4 2RW, UK.
Inventors:
# Inventor's Name Inventor's Address
1 BONETT HEATHER ELIZABETH 266 ALLIANCE AVENUE, HULL, NORTH HUMBERSIDE HU3 6QZ, UK.
PCT International Classification Number A45D 33/00
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 NA