Title of Invention

"LAUNDRY DETERGENT COMPOSITIONS AND MEHTODS FOR PROVIDING SOIL RELEASE TO COTTON FABRIC"

Abstract

Laundry detergent compositions that provide soil release benefits to all fabric comprising modified polyamine cotton soil release agents and non-cotton soil release agents, and a method for providing soil release benefits to cotton fabric by contacting cotton articles with a water soluble and/or dispersible, modified polyamine having functionalized backbone moieties and improved stability toward bleach. The present invention further relates to providing soil release benefits to all fabric in the laundry wash load in the presence of a bleaching agent.

Full Text

LAUNDRY DETERGENT COMPOSITIONS AND METIIODS-FOR. PROVIDING SOIL RELEASE TO COTTOK FABRIC FIELD OF THE INVENTION The present invention relates to laundry detergent compositions that provide soil release benefits to all fabric comprising modified polyamine cotton soil release agents and non-cotton soil release agents. The present invention also relates to a method for providing soil release benefits to cotton fabric by contacting cotton articles with a water soluble and/or dispersible, modified polyamine having functionalized backbone moieties and improved stability toward bleach. The present invention further relates to providing soil release benefits to all fabric in the laundry wash load in the presence of a bleaching agent. BACKGROUND OF THE INVENTION, A wide variety of soil release agents for use in domestic and industrial fabric treatment processes such as laundering, fabric drying in hot air clothes dryers, and the like are known in the art. Various soil release agents have been commercialized and are currently usexi in detergent compositions and fabric softener/antistatic articles and compositions. Such soil release polymers typically comprise an oligomeric or polymeric ester "backbone". Soil release polymers are generally very effective on polyester or other synthetic fabrics where the grease, oil or similar hydrophobic stains spread out and form a attached film and thereby are not easily removed in an aqueous laundering process. Many soil release polymers have a less dramatic effect on "blended" fabrics, that is on fabrics that comprise a mixture of cotton and synthetic material, and have little or no effect on cotton articles. The reason for the affinity of many soil release agents for synthetic fabric is that the backbone of a polyester soil release polymer typically comprises a mixture of terephthalate residues and ethyleneoxy or propyleneoxy polymeric units; the same materials that comprise the polyester fibers of synthetic fabric. This similar structure of soil release agents and synthetic fabric produce an intrinsic affinity between these compounds. Extensive research in this area has yielded significant improvements in the effectiveness of polyester soil release agents yielding materials with enhanced product performance and formulatability. Modifications of the polymer backbone as well as the selection of proper end-capping groups has produced a wide variety of polyester soil release polymers, For example, end-cap modifications, such as the use of sulfoaryl moieties and especially the tow cost isethionate-derived end-capping units, have increased the range of solubility and adjunct ingredient compatibility of these polymers without sacrifice to soil release effectiveness. Many polyester soil release polymers can now be formulated into both liquid as well as solid (i.e., granular) detergent! As in the case of polyester soil release agents, producing an oligomeric or polymeric material that mimics the structure of cotton has not resulted in a cotton soil release polymer. Although cotton and polyester fabric are both comprised of long chain polymeric materials, they are chemically very different, Cotton is comprised of cellulose fibers that consist of anhydroglucose units joined by 1-4 linkages. These glycosidic linkages characterize the cotton cellulose as a polysaccharide whereas polyester soil release polymers are generally a combination of terephthalate and ethylene/propylene oxide residues. These differences in composition account for the difference in the fabric properties of cotton versus polyester fabric, Cotton is hydrophilic relative to polyester. Polyester is hydrophobic and attracts oily or greasy dirt and can easily be "dry cleaned". Importantly, the terephthalate and ethyleneoxy/propyleneoxy backbone of polyester fabric does not contain reactive sites, such as the hydroxyl moieties of cotton, that react with stains in different manner than synthetics. Many cotton stains become "fixed" and can only be resolved by bleaching the fabric. Until now the development of an effective cotton soil release agent for use in a laundry detergent has been elusive. Attempts by others to apply the paradigm of matching the structure of a soil release polymer with the structure of the fabric, a method successful in the polyester soil release polymer field, has nevertheless yielded marginal results when applied to cotton fabric soil release agents. The use of methylcellulose, a cotton polysaccharide with modified oligomeric units, proved to be more effective on polyesters than on cotton. For example, U.K. 1,314,897, published April 26,1973 teaches a hydroxypropyl methyl cellulose material for the prevention of wet-soil redeposition and improving stain release on laundered fabric. While this material appears to be somewhat effective on polyester and blended fabrics, the disclosure indicates these materiale to be unsatisfactory at producing the desired results on cotton fabric. Other attempts to produce a soil release agent for cotton fabric have usually taken the form of permanently modifying the chemical structure of the cotton fibers themselves by reacting a substrate with the polysaccharide polymer backbone. For example, U. S Patent No. 3,897,026 issued to Kearney, discloses cellulosic textile materials having improved soil release and stain resistance properties obtained by reaction of an ethylene-maleic anhydride co-polymer with the hydroxyl moieties of the cotton polymers One perceived drawback of this method is the desirable hydrophilic properties of the cotton fabric are substantially modified by this process. Non-permanent soil release treatments or finishes have also been previously attempted, U.S. Patent No. 3,912,681 issued to Dickson teaches a composition for applying a non-permanent soil release finish comprising a polycarboxylate polymer to a cotton fabric However, this material must be applied at a pH less than 3, a process not suitable for consumer use nor compatible with laundry detergents which typically have a pH greater than 85. U.S. Patent No. 3,948,838 issued to Hinton, et alia describes high molecular weight (500,000 to 1,500,000) polyacrylic polymers for soil release. These materials are used prefenbly with other fabric treatments, for example, durable press textile reactants such as formaldehyde. This process is also not readily applicable for use by consumers in a typical washing machine. U.S. Patent 4,559,056 issued to Leigh, et alla discloses a process for treating cotton or synthetic fabrics with a composition comprising an organopolysiloxano elastomer, an organosiloxaneoxyalkylene copolymer crosslinking agent and a siloxane curing catalyst. Organosilicone oligomers are well known by those skilled in the art as suds supressors Other soil release agents not comprising terephthalate and mixtures of poiyoxy ethylene/propylene are vinyl caprolactam resins as disclosed by Rupert, et alla U.S. Patent Nos. 4,579,681 and 4,614,519. These disclosed vinyl caprolactam materials have their effectiveness limited to polyester fabrics, blends of cotton and polyester, and cotton fabrics rendered hydrophobic by finishing agents. Examples of alkoxylated polyamines and quatemized alkoxylated polyamines are disclosed in European Patent Application 206,513 as being suitable for use as soil dispersents, however their possible use as a cotton soil release agent is not disclosed. In addition, these materials do not comprise N-oxides, a key modification made to the poryamines of the present invention and a component of the increased bleach stability exhibited by the presently disclosed compounds. It has now been surprisingly discovered that effective soil release agenls for cotton articles can be prepared from certain modified polyamines. This unexpected result has yielded compositions that are key to the present method for providing soil release benefits once available to only synthetic and synthetic-cotton blended fabric. The process or method of the present invention provides for soil release benefits on all cotton articles whether laundered in the presence of a bleaching agent or not. The process or method of the present invention provides for soil release benefits to all fabric in the laundry wash load, as opposed to previous methods that only provided soil release protection to synthetic and cotton-synthetic blended fabric. The present process, because of the stability of the modified polyamines disclosed herein toward bleaching agents, now provides this soil release to white cotton articles which the consumer may choose to launder in the presence of traditional bleaching agents. The process or method of the present invention is equally effective when the laundry detergent compositions disclosed herein are solid or liquid, The solid laundry detergents may be in the form of granules, flakes or laundry bars. The liquid detergents can have a wide range of viscosity and may include heavy concentrates, pourable "ready" detergents, or light duty fabric pre-treatmcnts. The modified polyamines disclosed in the present method are especially compatible with other laundry detergent additives and adjuncts. BACKGROUND ART In addition to the above cited art, the following disclose various soil release polymers or modified polyamines; U.S. Patent 4,548,744, Connor, issued October 22, 1985; U.S. Patent 4,597,898, Vander Meer, issued July 1, 1986; U.S. Patent 4,877,896, Maldonado, et al., issued October 31,1989; U.S. Patent 4,891,160, Vander Meer, issued January 2, 1990; U.S. Patent 4,976,879, Maldonado, et al., issued December 11, 1990; U.S. Patent 5,415,807, Gosselink, issued May 16,1995; U.S. Patent 4,235,735, Marco, et al., issued November 25,1980; WO 95/32272, published November 30,1995; U.K. Patent 1,537,288, published December 29, 1978; U.K. Patent 1,498,520, published January 18, 1978; German Patent DE 28 29 022, issued January 10,1980; Japanese Kokai JP 06313271, published April 27, 1994. SUMMARY OF THE INVENTION The present invention relates to laundry detergent compositions containing cotton soil release agents in combination with suitable non-cotton soil release agents thereby providing laundry detergent compositions that provide soil release benefits to •11 fabric and to methods for providing cotton soil release to fabrics by contacting the compounds of the present invention with cotton fabric. The present invention relates to laundry detergent compositions comprising: a) at least about 0.01% to about 95% by weight, of a detersive surfactant selected from the group consisting of anionic, nonionic, zwitterionic, and ampholytic surfactants, and mixtures thereof; b) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric; c) optionally from about 0.05 to about 30% by weight, of a bleach; d) from about 0.01 to about 10% by weight, a water-soluble or dispersibie, modified polyamine cotton soil release agent comprising a polyamine backbone corresponding to the formula: H j [H2N-R]n+1 -[N-R]m-[N-R]n-NH2 having a modified polyamine formula V(n+ j ^W^Y^ or a polyamine backbone corresponding to the formula: H | R [H2N -RJn-k-H-EN - R)m-[N -R]n-(N -R]khaving a modified polyamine formula V(n-k+1)WmYnY'kZ, wherein k is less than or equal to n, said polyamine backbone prior to modification has a molecular weight greater than about 200 daltons, wherein i) V units are terminal units having the formula: E-N-R— or E-N-R— or E-N-R E E E ii) W units are backbone units having the formula: N-R— or — N-R— or — N-R E E E iii) Y units are branching units having the formula: ; and iv) Z units are terminal units having the formula. wherein backbone linking R units are selected from the group consisting of C2-C12 alkylene, C4-C12 alkenylene, C3-C12 hydroxyalkylene, C4-C12 dihydroxy-alkylene, C8-C12 dialkylarylene, -(R1O)xR1-, -(R1O)xR5(OR1)x, -(CH2CH(OR2)CH2O)z (R1O)yR1(OCH2CH(OR2)CH2)w -C(O)(R4),C(O)-, -CH2CH(OR2)CH2-, and mixtures thereof; wherein R1 is C2-C6 alkylene and mixtures thereof, R2 is hydrogen, -(R1O)xB, and mixtures thereof, R3 is C1-C18 alkyl, C7-C12 arylallcyl, C7-C12 alkyl substituted aryl, C6-C12 aryl, and mixtures thereof, R4 is C1-C12 alkylene, C4-C12 alkenylene, C8-C12 arylaikylene, C6-C10 arylene, and mixtures thereof; R5 is C1-C12alkylene, C3-C12 hydroxyalkylene, C4-C12 dihydroxyalkylene, C8-C12 dialkylarylene, -C(O)-, -C(O)NHR6NHC(O)-, -Rl(OR1)-, - C(O)(R4)rC(O)-, -CH2CH(OH)CH2-, -CH2CH(OH)CH2O(R1O)yR1- OCH2CH(OH)CH2-, and mixtures thereof, R6 is C2-C12 alkylene or C6-C12 arylene; E units are selected from the group consisting of hydrogen, C1-C22 alkyl. C3-C22 alkenyl, C7-C22 arylalkyl, C2-C22 hydroxyalkyl, -(CH2)pCO2M - (CH2)qSO3M, -CH(CH2CO2M)CO2M, -(CH2)pPO3M, -(RlO)xB, -C(O)R3, and mixtures theteof provided that when any E unit of a nitrogen is a hydrogen, said nitrogen is not also an N-oxide; Bis hydrogen, C1-C6alkyl, -(CH2)qSO3M, - (CH2)pCO2M, -(CH2)q(CHSO3M)CH2SO3M, .(CH2)q(CHSO2M)-CH2SO3M, - (CH2)pPO3M, -PO3M, and mixtures thereof; M is hydrogen or a water soluble cation in sufficient amount to satisfy charge balance; X is a water soluble anion; k and k1 have the value from 1 to about 15; m has the value from 4 to about 400; n has the value from 0 to about 200; p has the value from 1 to 6, q has the value from 0 to 6; r has the value of 0 or 1; w has the vilue 0 or 1; x has the value from 1 to 100; y has the value from 0 to 100; z has the value 0 or 1; and e) the balance carrier and adjunct ingredients. The present invention further relates to a method of providing soil release benefits to cotton fabric by contacting said fabric with a laundry composition comprising: a) at least about 0,001% by weight, a water-soluble or dispersible (preferably beach stable), modified polyamine cotton soil release agent according to the present invention; and b) the balance carrier and adjunct ingredients. It is a further purpose of the present invention to provide a method for providing soil release benefits to white cotton fabric in the presence of a bleaching agent by contacting an aqueous solution of a bleach stable soil release agent with white cotton fabric in the presence of a bleaching agent. It is a yet further purpose of the present invention to provide a method for providing soil release benefits to all fabrics that comprise the laundry wash load in the presence of a bleaching agent. All percentages, ratios and proportions herei are by weight, unless otherwise specified. All temperatures are in degrees Celsius (°C) unless otherwise specified. All documents cited are in relevent part, incorporated herein by reference. Statement of the Invention According to the present invention there is provided a laundry detergent composition comprising: a) from 0.01 % to 95% by weight, of a detersive surfactant selected from the group consisting of anionie, nonionic, cationic, zwitterionic, and ampholytic surfactants, and mixtures thereof; b) from 0.01 to 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric such as herein described; c) optionally from 0.05 to 30% by weight, of a bleach; d) from 0.01 to 10% by weight, a water-soluble or dispersible, modified polyamine cotton soild release agent comprising a polyamine backbone prior to modification via qualernizalion, substitution, or oxidation corresponding to the formula: having a modified polyamine formula V(n+1)WmYnZ or a polyamine backbone prior to modification via quaternization, substitution, or oxidation corresponding to the formula: (Formula Removed) having a modified polyamine formula V(n-k+1)WmYn Y'k Z, wherein k is less than or equal to n, said polyamine backbone prior to has a molecular weight greater than 200 daltons, wherein i ) V units are terminal units having a formula selected from : ii) W units are backbone units having a formula selected from: i i i ) Y units arc branching units having a formula selected from: iv) Z units are terminal units having a formula selected from: wherein backbone linking R units are C2-C12 alkylene; R1 is C2-C6 alkylene, and mixtures thereof; E units are selected from the group consisting of hydrogen, C1-C22 alkyl, --(CH2)p CO2 M, -(CH2)q SO3 M, -CH(CH2CO2M)CO2M, --(CH2)P PO3M, -- (R 1O)x B, and mixtures thereof; provided that when any E unit of a nitrogen is a hydrogen, said nitrogen is not also an N-oxide; B is hydrogen, C,-C6 alkyl, -(CH2)q SO3 M. -(CH2)p CO2 M, -(CH2)q (CHSO3 M)CH2 SO, M, -(CH2)q -(CHSO2 M)CH2 SO3 M, - (C'H2)p PO3M, -PO3 M, and mixtures thereof, provided when B is an ionizable unit selected from the group consisting of-(CH2)q SO3 M, -(CH2)p CO2 M, -(CH2)q (CHSO3M)-CH2 SO, M, -(CH2)q (CHSO2 M)CH2 SO3 M, -(CH2)p PO3M, -PO3 M, and mixtures thereof, at least one backbone nitrogen is quaternized; M is hydrogen or a water soluble cation in sufficient amount to satisfy charge balance; X is a water soluble anion; m has the value from 4 to 400; n has the value from 0 to 200; p has the value from 1 to 6, q has the value from 0 to 6; x has the value from 11 to 100: and e) the balance carrier and adjunct ingredients such as herein described. DETAILED DESCRIPTION OF THE INVENTION The compositions of the present invention comprise: a) at least about 0.01% to about 95% by weight, of a detersive surfactant selected from the group consisting of anionic, nonionic, zwitterionic, and ampholytic surfactants, and mixtures thereof; b) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric; c) from about 0.01 to about 10% by weight, a water-soluble or dispersible, modified polyamine cotton soil release agent according to the present invention; and d) the balance carrier and adjunct ingredients. Preferably the laundry detergent compositions comprise: a) at least about 0.01% to about 95% by weight, of a detersive surfactant selected from the group consisting of anionic, nonionic, zwitterionic, and ampholytic surfactants, and mixtures thereof; b) from about 0.01 to about 10% by weight, of an anionic soil release polymer having effective soil release on non-cotton fabric; c) optionally from about 0.05 to about 30% by weight, of a bleach; d) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and e) the balance carrier and adjunct ingredients. More preferred laundry detergent compositions comprise: a) at least about 0.01% to about 95% by weight, of an anionic detersive surfactant, b) at least about 0.01% to about 95% by weight, of a nonionic detersive surfactant; c) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric, d) optionally from about 0,05 to about 30% by weight, of a bleach, e) from about 0,01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and f) the balance carrier and adjunct ingredients. Also preferred laundry detergent compositions comprise: a) at least about 0.01% to about 95% by weight, of an anionic detersive surfactant selected from the group consisting of alkyl sulfates, alkyl ethoxy sulfates, and mixtures thereof; b) at least about 0.01% to about 95% by weight, of a nonionic detersive surfactant; c) from about 0.01 to about 10% by weight, of an anionic soil release polymer having effective soil release on non-cotton fabric; d) optionally from about 0.05 to about 30% by weight, of a bleach; e) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and 0 the balance carrier and adjunct ingredients. A further preferred laundry detergent composition comprises: a) at least about 0.01% to about 95% by weight, of a polyhydroxy fatty acid amide nonionic detersive surfactant; b) from about 0.01 to about 10% by weight, of an anionic soil release polymer having effective soil release on non-cotton fabric; c) optionally from about 0.05 to about 30% by weight, of a bleach; d) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; e) the balance carrier and adjunct ingredients; and 0 sufficient alkaline material to provide the composition with a pH of about 7.2 to about 10.5 when measured as a 10% solution in v/atcr. Non-cotton Soil Release Polymers The Saundry detergent compositions of the present invention must comprise a non-cotton soil release polymer. However, the present invention also relates to methods of providing soil release benefits to cotton fabrics, wherein laundry compositions that do not comprise non-cotton soil release agents are also suitable for use Among the preferred non-cotton soil release polymers suitable for use in the laundry detergent compositions of the present invention are the following. Preferred non-cotton soil release agent - A. Suitable for use in the laundry detergent compositions of the present invention are preferred non-cotton soil release polymers comprising; a) a backbone comprising: i) at least one moiety having the formula: (Formula Removed) ii) at least one moiety having the formula: (Formula Removed) wherein R9 is C2-C6 linear alkylene, C3-C6 branched alkylene, C5-C7 cyclic alkylenc, and mixtures thereof; R10 is independently selected from hydrogen or -L-SO3 -M+; wherein L is a side chain moiety selected from the group consisting of alkylene, oxyalkylene, alkyleneoxyalkytene, arylene, oxyarylene, alkyleneoxyarylene, poly(oxyalkylene), oxyalkyleneoxyarylene, poly(oxyalkylene)oxyartyese, alkylenepoly(oxyalkylene),and mixtures thereof, M is hydrogen or a salt forming cation; i has the value of 0 or 1; iii) at least one trifunctional, ester-forming, branching moiety, iv) at least one 1,2-oxyalkyleneoxy moiety; and b) one or more capping units comprising: i) ethoxylated or propoxylated hydroxyethanesulfonate of ethoxylated or propoxylated hydroxypropanesulfocate units of the formula (M03S)(CH2)m(R11O)n-, where M is a salt forming cation such as sodium or tetralkylammonium, R11 is ethylene or propylene or a mixture thereof, m is 0 or 1, and n is from 1 to 20; ii) sulfoaroyl units of the formula -(0)C(C6H4)(SO3-M+), wherein M is a salt forming cation, iii) modified poly(oxyethylene)oxy monoalkyl ether units of the formula R12O(CH2CH2O)k-, wherein R12 contains from 1 to 4 carbon atoms and k is from about 3 to about 100; and iv) ethoxylated or propoxylated phenolsulfonate end-capping units of the formula MO3S(C6H4XOR13)nO-, wherein n is from 1 to 20; M is a salt-forming cation; and R13 is ethylene, propylene and mixtures thereof. This type of preferred non-cotton soil release polymer of the present invention may be described as having the formula -A-Rl.A-][(R4)t(Cap)] wherein A is a carboxy linking moiety having the formula (Formula Removed) R1 is arylene, preferably a 1,4-phenylene moiety having the formula such that when A uniu and R1 units are taken together in the formula A-R1-A they form t tef ephthalate unit having the formula R2 units are ethyieneoxy or 1,2-propyleneoxy. R2 units are combined with terephthalate moieties to form (A-R1-A-R2) units having the formula —0-CHR'CHR"— wherein R1 and R11 are either hydrogen or methyl provided that R1 and R" are not both methyl at the same time R3 units are trifunctional, ester-forming, branching moieties having the formula (Formula Removed) Preferably R3 units comprise a glycerol moiety which is placed into the soil release polymer backbone to provide a branch point. When R3 units are combined with terephthalate moieties to form units of the polymer backbone, for example, (A-R1-AR3)- A-R1-A units, these units have the formula (Formula Removed) or the formula (Formula Removed) wherein one terephthalate residue is taken to be a part of the (A-R1-A-R3) unit while the second terephthalate comprises a part of another backbone unit, such as a (A-R1- A-R2) unit, a (A-R1A-R5) unit, a -A-R1-A-[CR4)^?)] unit or a second (A-Rl-AR3) unit. The third functional group, which is the beginning of the branching chain, is aJso typically bonded to a terephthalate residue also a part of a (A-Rl-A-R2) unit, a (A-Rl-A-R5) unit, t -A-R'-A-KR^CCap)] unit or another (A-R^A-R3) unit. An example of a section of a soil release polymer containing a "trifundional, ester-forming, branching moiety" R* unit which comprises a glycerol unh, has the formula (Formula Removed) 0«r.O-(CH(CHj)CHjO)— R4 units are R2, R3 or R5 units. R^ units are units having the formula Rio RIO R10 RIO wherein R9 is C2-C$ linear alkylene, C^-C^ branched alkylene. and mixtures thereof; preferably R10 is independently selected from hydrogen or -L-SC^-M* ; wherein L is a side chain moiety selected from the group consisting of alkylene, oxyalkviene, alkyleneoxyalkylene, arylene, oxyarylene, alkyleneoxyarylene, poly (oxyalkviene), oxyallcyleneoxyarylene, poly(oxyalky!ene)oxyarlyene, alkylenepoly(oxyalkvteno),and mixtures thereof; M is hydrogen or a salt forming cation, i has the value of 0 or 1; Each carbon atom of the R9 units is substituted by R10 units that are independently selected from hydrogen or •L-SC^'M4', provided no more than one • L-S(>3"M+ units is attached to an R9 unit; L is a side chain connecting moiety selected from the group consisting of alkylene, oxyalkylcne, alkyleneoxyalkylene, arylene, oxyarylene, alkyleneoxyarylene, poly(oxyalkylene), oxyalkyleneoxyarylene, pohXoxyalkylene)oxyarlyene, alkylenepoly(oxyalkylene),and mixtures thereof. M is a cationic moiety selected from the group consisting of lithium, sodium, potassium, calcium, and magnesium, preferably sodium and potassium. Preferred R3 moieties are essentially R10 substituted Cj-C^ alkylene chains. The R5 units comprise either one C2-C$ alkylene chain substituted by one or more independently selected R10 moieties (preferred) or two C2-C6 alkylene chains said alkylene chains joined by an ether oxygen linkage, each alkylene chain substituted by one or more independently selected R^ moieties, that is R^ may comprise two separate R9 units, each of which is substituted by one or more independently Rejected R10 moieties. Preferably only one carbon atom of each R9 moiety is substituted by an -L-SOj-M* unit with the remaining R10 substituents comprising a hydrogen atom. When the value of the index i is equal to 1 (two R9 units comprise the R5 unit), a preferred formula is RIO RIO RIO RIO l i i i RIO Rio RiO RJO wherein each R^ comprises a €2 alkylene moiety. Preferably one R^ moiety is -LS03* M+, preferably the C2 carbon is substituted by the -L-S03"M^ moiety, and the balance are hydrogen atoms, having therefore a formula: —CHCH2-O-CH2CH2— CH2(OCH2CH2)xS03~M* wherein L is a polyethyleneoxymethyl substituent, x is from 0 to about 20. As used herein, the term "R5 moieties consist essentially of units RIO RIO — 0-R9— (ORIO RIO having the index i equal to 0 wherein R^ units are hydrogen and one R10 units is equal to -L-SC^'M*, wherein L is a side chain connecting moiety selected from the group consisting of alkylene, atkcnylene, alkoxyaUcylene, oxyalJcylene, aiylene, alkyl&rylene, alkoxyarylene and mixtures thereof, refers to the preferred compounds of the present invention wherein the R^ moieties consist of one -L-SOj'M4" moiety and the rest of the R^ moieties are hydrogen atoms, for example a (Formula Removed) which is capable of inclusion into the polymeric backbone of the soil release polymers of the present invention as an -A-R5-A- backbone segment. The units are easily incorporated into the oligomer or polymer backbone by using starting materials having the general formula HO— CF^ — CH— OH CH2(OCH2CH2)xS(VNa* wherein x, for the purposes of the L moiety of the present invention, is from 0 to 20. Other suitable monomers capable of inclusion into the backbone of the type A preferred non-cotton soil release polymers of the present invention as R* moieties (Formula Removed) includes the alkylene poly(oxyaJlcylene)oxyarylene containing monomer having the general formula HO-CH2— CH-OH CHjCOCHjCHo)^— / - SCh'Na' wherein x is 0 to 20. A further example of a preferred monomer resulting in a preferred R5 unit wherein i is equal to 0, are the sodio$ulfopoly(ethyleneoxy)methyl- 1,2-propanediols having the formula HO— CH2— CH-OH (iH wherein x is from 0 to about 20; more preferred are the monomers HO-CH2— CH— CHr~ OH or HO~CH2— ^H' The preferred non-cotton soil release agents of the present invention in addition to the afore-mentioned R', R.2, R^, R*, arid R^ units also comprise one or more capping groups, -(Cap). The capping groups are independently selected from ethoxylatcd or propoxylated hydroxyethane and propanesulfonate units of the formula (MC^SXCHj^Ql^O),,-, where M is a salt forming cation such as sodium or tetraikylammonium as described herein above, R11 is ethylene or propyiene or a mixture thereof, m is 0 or 1, and n is from 1 to 20, preferably n is from 1 to about 4; sulfoa/oyl units of the formula -{OX^C^XSC^'M4), wherein M is a salt forming cation as described herein above; modified poly(oxyethylene)oxy monoalkyl ether UJMU of the formuJi RJ^CHjCfyCOjc wherein R12 contains from 1 to 4 carbon atom*, R12 is preferably methyl, and k is from about 3 to about 100, preferably about 3 to about 50, more preferably 3 to about 30; and ethoxylated or propoxyUted phenolwlforuue end-capping units of the formula M03S(C n U from to 20, M is a salt-forming cation; and R13 is ethylene, propylene and mixtures thereof, Most preferred end capping unit is the isethionate-type end capping unit which ii a hydroxyethane moiety, (M03SXCH2)n)(RnO)r,-, preferably R1 1 is ethyl, m is equal to 0, and n is from 2 to 4. The value of t is 0 or 1; the value of u is from about 0 to about 60; the value of v is from about 0 to about 35; the value of w is from 0 to 35. Preferred non-cotton soil release polymers of the present invention having the formula [(Cap)CR4),][(A-Rl.A-R2)u(A-R«.A-R3)v(A.Rl-A-R5)w can be conveniently expressed as the following generic structural formula (Formula Removed) The following structure is an example of the preferred non-cotton soil release polymers of the present invention. J0.151- Jl.13 The above-described preferred non-cotton soil release agents are fully described in U.S. Patent Applicarion Serial No. 08/545,351 filed November 22, 1995 which is a continuation-in-part of U.S. Patent Application Serial No. 08/355,°38 filed December 14,1994, both of which are incorporated herein by reference. Other noncotton soU release polymers suitable for use in the compositions of the present invention are further described herein below. The preferred non-cotton SRA's can be further described as oligomeric esters comprising: (1) a backbone comprising (a) at least one unit selected from the group consisting of dihydroxysulfonates, polyhydroxy sulfonatd, a unit which is at least tri&nctionjj whereby ester linkages are formed resulting in a branched oligomer backbone, and combinations thereof; (b) at least one unit which is a terephthaloyl moiety, and (c) at least one unsulforuted urJt which is a 1,2-oxyaJkyieneoxy moiety, and (2) one or more capping units selected from nonionic capping units, anionic capping units such as alkoxylated, preferably ethoxylated, isethionates, alkoxylated propanesulfonates, alkoxylated propanedisulfonates, aJkoxylated phenolsulfonates, sulfoaroyi derivatives and mixtures thereof. Preferred are esters of the empiricaJ formula: {(CAP)x(EG/PG)yt(DEG)yM(PEG)ym(T)z(SIP)2l(SEG)q(B)m} wherein CAP, EG/PG, PEG, T and SIP are as defined as terephthaJoyl (T), suifoisophthaioyl (SIP), oxyethyleneoxy and oxy-l,2-propylene (EG/PG) units, endcaps (CAP), poly(ethyleneglycol) (PEG), (DEG) represents di(oxyethylene)oxy units, (SEG) represents units derived from the suifoethyl ether of glycerin and related moiety units, (B) represents branching units which are at least trifunctionaJ whereby ester linkages are formed resulting in a branched oligomer backbone, x is from about 1 to about 12, y is from about 0,5 to about 25, y" is from 0 to about 12, y" is from 0 to about 10, y+y+y* totals from about 0.5 to about 25, z is from about 1.5 to about 25, z' is from 0 to about 12; z + z' totals from about 1.5 to about 25, q is from about 0.05 to about 12; m is from about 0 01 to about 10, and x, /, y", y"1, z, z1, q and m represent the average number of moles of the corresponding units per mole of said ester and said ester has a molecular weight ranging from about 500 to about 5,000. Preferred SEG and CAP monomers for the above esters include Na^-^-,}- dthydroxypropoxy)ethane$ulfonate ("SEG"), Na-2-{2-{2-hydroxyethoxy) ethoxy} ethancsulfonate ("SE3") and its homologs and mixtures thereof and the products of ethoxylating and sulfonating ally! alcohol. Preferred SRA esters in this class include the product of transesterifying and oligomerizing sodium 2-{2- ethoxy}ethaneaulfonate and/or sodium 2-[2-{2-(2-hydroxyethoxy)ethoxy}- ethoxy]elhanesulfonate, DMT, sodium 2-{2,3-dihydroxypropoxy) ethane sulfonate, EG, and PQ uiing an appropriate Ti(IV) catalyst and can be designated ai (CAP)2(T)5(EG/PG)1.4(SEG)2.5(B)0.13 wherein CAP is (Na-K)3S[CH2. CH20J3.5}- and B is a unit from glycerin and the mole ratio EG/PG is about 1.7:1 as measured by conventional gas ch/omatography after complete hydrolysis. Preferred non-cotton soil release agent • B. A second preferred class of suitable SRA's include a wlfonated product of a substantially linear ester oligomer comprised of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and aUyl-derived tulfonated terminal moieties covalently attached to the backbone Such ester oligomers can be prepared by: (a) ethoxyiating ally! alcohol; (b) reacting the product of (a) with dimethyl terephthalate ("DMT") and 1,2-propylcne glycol ("PG") in a two-stage transesterifkation/oligomerization procedure; Lnd (c) reacting the product of (b) with sodium metabisulfite in water. Suitabie for use in the laundry detergent compositions of the present invention are preferred non-cotton soil release polymers comprising: a) one or two terminaJ units selected from the group consisting of iii) -CH2CH2$03M, iv) and mixtures thereof; wherein q has the vaJue from 1 to about 4, M is a water soluble cation, preferably sodium, b) a backbone comprising: i) arylene units, preferably terephthalate units having the formula: u) ethyleneoxy units having the formula: wherein the value of n is from about 1 to about 20; and iii) 1 ,2-propyleneoxy units having the formula: wherein the value of n is from about 1 to about 20, and wherein further th« preferred backbone of this preferred non-cotton soil release polymer has a backbone comprising trylene repeat units which alternate with the ethyleneoxy and 1 ,2- propyleneoxy units, such that the mole ratio of ethyleneoxy to 1 ,2-propyleneoxy units is from 0:1 to about 0.9,0.1, preferably from about 0: 1 to about 0.4:0.6, more preferably the trylene units alternate with essentially 1,2-propyleneoxy units. However, other combinations of the above-identified units may be used to form non-cotton soil release polymers suitable for use in the compositions of the present invention. These combinations are more thoroughly described in U.S. Patent 4,96*,43 1, Scheibd et al., issued November 6, 1990 and incorporated herein by reference. Preferred non-cottpn goil release agent - £ Suitable for use in the laundry detergent compositions of the present invention are preferred non-cotton soil release polymers having the formula (Cap)[(A-Rl.A-R2)u(A.R3.A-R2)v-A-R4-A.](Cap) wherein A is a carboxy linking moiety, preferably A is a carboxy linking moiety having the formula (Formula Removed) R1 is an arylene moiety, preferably 1,4-phenylene moi«y having the formula -0-C— or —C— 0- wherein for R* moieties, the degree of partial substitution with arylene moieties other than 1,4-phenylene should be such that the soil release properties of the compound are not adversely affected to any great extent. GenenJy, the partial substitution which can be tolerated will depend upon the backbone length of the compound. R2 moieties are ethylene moieties or substituted ethylene moieties having GI- €4 alkyl or alkoxy substituems. As used herein, the term Hthe R2 moieties are essentially ethylene moieties or substituted ethylene moieties having Cj"C4 alkyl or alkoxy substituents" refers to compounds of the present invention where the R2 moieties consist entirely of ethylene or substituted ethylene moieties or a partially substituted with other compatible moieties. Examples of these other moieties include 1,3-propylene, 1,4-butylene, 1,5-pentylene, or 1,6-hexylene, 1,2-hydroxyalkytenes and oxyalkytenes. For the R? moieties, the degree of partial subcitution with these other moieties should be such that the soil release properties of the compounds are not adversely affected to any great extent. For example, for polyesters made according to the present invention with a 75:25 mole ratio of diethylene glycol (-CH^CIL 20CH2CH2-) to ethyiene glycol (ethylene) have adequate soil release activity. For the R^ moieties, suitable substituted C2-Cig hydrocarbylene moieties can include substituted Cz-C\2 alkylene, alkenylene, arylene, alkarylene and like moieties, Th« substituted alkylene or alkenylene mokties can be linear, branched or cyclic, also, the R^ can all be the same (e.g. all substituted arylene) or a mixture (e g a mixture of substituted arylenes and substituted alkytenes). Preferred R3 moieties are those which are substituted 1,3-phenylene, preferably 5-sulfo-l,3-phenylene. R3 moieties are also -A-[(R2.A-R4)]-Cap wherein R4 is R1, R.3, and mixtures thereof. The preferred (Cap) moieties comprise units having the formula ~[(R50)m(CH2CH20)n]X wherein R5 is CpC4 alkylene, or the moiety -R2-A-R6- wherein R6 is C2-Cj2 alkylene, alkenylene, arylene or alkarylene moiety, X is C]-C4 alkyl, preferably methyl; the indices m and n are such that the moiety •CHjClH^O- comprises at least 50% by weight of the moiety provided that when R5 is the moiety -R2-A-R6-, m is at least 1; each n is at least about 10, the indices u and v are such that the sum of u + v is from about 3 to about 25, the index w is 0 or at least 1; and when w is at least 1, the indices u, v and v/ have the values such that the sum of u + v + w is from about 3 to about 25. An example of this type of non-cotton soil release block polyester has the formula X^OCHjCHjjc-COC wherein the R2 moieties are essentially ethylene moieties> 1,2-propylene moietifts, and mixtures thereof, the R-* moieties are all potassium or preferably sodium 5-sulfo- 1,3-phenylene moieties; the R4 moieties are R! or R-* moieties, or mixtures thereof; each X is ethyl, methyl, preferably methyl; each n is from about 12 to about 43; when w is 0, u + v is from about 3 to about 10; when w is at least 1, u + v + w is from about 3 to about 10. The above non-cotton soil release polymers of the formula (Cap)[(A-R1-A-R2)u(A.R3-A.R2)v-A.R4-A.](Cap) are further described in detail in U.S. Patent 4,702,857, Gossdink, issued October 27, 1987 and incorporated herein by reference. Preferred non*cptton soil release agent - D: A further preferred non-cotton soil release agent according to the present invention comprises: A) at least about 10% by weight of* substantially linear sulfonated polyethoxy/ propoxy end-capped ester having molecular weight ranging from about 500 to about 8,000; said ester consisting essentially of on • molar basis: from about 1 to about 2 moles of sulfonated poly ethoxy/propoxy end-capping units of the formula: (MS03)(CH2)m(CH2CH20)(RO)nwherein M is a salt-forming cation such as sodium of tertraalkylammonium, m is 0 or 1, R is ethylene, propylene, and mixtures thereof; and n is fro 0 to 2; and mixtures thereof; ii) from about 0.5 to about 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units; b) a mixture of oxyethyleneoxy and oxy- 1 ,2,- propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy of oxy-1,2- propyleneoxy mole ratio ranging from 0.5:1 to about 10:1; and c) a mixture of a) or b) with poly(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymerization of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges fro 0:1 to 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3; the mole ration of poly(oxyethylene)oxy units to total group ii) unit-s ranges from 0:1 to about 0.22:1; and when said poly(oxyethylene)oxy units have a degree of polymerization equal to 4, the mole ratio of poly(oxyethyitne)oxy units to total group ii) units ranges from 0: 1 to about 0. 14: 1 ; ui) from about 1.5 to about 40 moles of terephthaloyl unita; and iv) from 0 to about 26 moles of 5-sulphophthaloyl units of the formula: wherein M is a salt forming cation; and B) from about O.S'/« to about 20*/» by weight of ester, of one or more crystallization-reducing stabilizers. Preferably, such materials are used at a level of from about 0.1% to about 4%, more preferably from about 0.4% to about 2%. Stabilizers useful in this invention should be water soluble or water dispersible The stabilizing agents that are useful herein include sulfonate-type hydrotropes, linear or branched alkylbenzenesuifonates, paraffin sulfonates, and other thermally-stable aJJcyl sulfonate variations with from about 4 to about 20 carbon atoms. Preferred agents include sodium dodecylbenzenesulfonate, sodium cumenesulfonate, sodium toluenesulfonate, sodium xylenesulfonate, and mixtures thereof When higher levels of stabilizers are used, mixtures of hydrotropes and/or other stabilizers are preferred over pure components to insure fall integration into the oligorner and to reduce the possibility of crystallization of the stabilizer. In genera], the level of such agents should be kept as low as possible while providing the primary bene6t, i.e., the reduction in the amount of crystallization that the soil release agent undergoes during manufacture, storage and when introduced to the wash liquor, the composition may comprise from about 0.5% to about 20% stabilizer. Most preferably, these ester compositions comprise an amount sufficient to reduce the crystallization of the oligomer during manufacture and when introduced to the wash liquor, i.e., at least 3% by weight. In addition to the above-described non-cotton soil release polymers, other soil release polymers suitable for use in the liquid laundry detergent compositions of the present invention include the following. Such known polymeric soil release agents can optionally be employed in the present detergent compositions. If utilized, SRA's will generally comprise from 0,01% to 10.0%, typically from 0.1% to 5%, preferably from 0.2% to 3.0% by weight, of the compositions. Preferred SRA's typically have hydrophilic segments to hydrophilize the surface of hydrophobic fibers such as polyester and nylon, and hydrophobic segments to deposit upon hydrophobic fibers and remain adhered thereto through completion of wiahing and rinsing cycles, thereby serving as an anchor for the hydrophilic segment*. This can enable stains occurring subsequent to treatment with the SRA to be more easily cleaned in later washing procedures. SRA's can include a variety of charged, e.g., anionic or even cationic species, ice U.S. 4,956,447, issued September 11,1990 to Gosselink, et al., as well as noncharged monomer units, and their structures may be linear, branched or even starshaped. They may include capping moieties which are especially effective in controlling molecular weight or altering the physical or surface-active properties. Structures and charge distributions may be tailored for application to different fiber or textile type* and for varied detergent or detergent additive products Preferred SRA's include otigomeric terephthalate esters, typically prepared by processes involving at least one transesterification/oligomerization, often with a metal catalyst such as a titanium(IV) alkoxide. Such esters may be made using additional monomers capable of being incorporated into the ester structure through one, two, three, four or more positions, without, of course, forming a densely crossLinked overall structure. Other SRA's include the nonionic end-capped 1,2-propyiene/polyoxyethylene terephthalate polyesters of U.S. 4,711,730, December 8, 1987 to Gosselink et al., for example those produced by transesterification/oligomerization of poly- (ethyleneglycol) methyl ether, DMT, PG and poly(ethyleneglycol) ("PEG"). Other examples of SRA's include: the partly- and fully- anionic-end-capped oligomeric esters of U.S. 4,721,580, January 26, 1988 to Gosselink, such as oligomers from ethylene glycol ("EG"), PG, DMT and Na-3,6-dioxa-8-hydroxyoctanesulfonate:; and the anionic, especially sulfoaroyl, end-capped terephthalate esters of U.S. 4,877,896, October 31, 1989 to Maldonado, the latter being typical of SRA's useful in both laundry and fabric conditioning products, an example being an ester composition made from m-suifobenzoic acid monosodium salt, PG and DMT, optionally but preferably further comprising added PEG, e.g., PEG 3400. SRA's also include: simple copolymeric blocks of ethylene terephthalate or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate, sec U.S. 3,959,230 to Hays, May 25, 1976 and U.S. 3,893,929 to Basadur, July 8, 1975; cellulosic derivatives such as the hydroxyether cellulosic polymers available as METHOCEL from Dow; the C]-C4 alkyl celluloses and €4 hydroxyalkyi celluloses, see U.S. 4,000,093, December 28, 1976 to Nicol, et al.; and the methyl cellulose ethers having an average degree of substitution (methyl) per anbydroglucose unit from about 1.6 to about 2.3 and a solution viscosity of from about 80 to about 120 centipoise measured at 20°C as a 2'/o aqueous solution Such materiali are available as METOLOSE SMI00 and METOLOSE SM200, which are the trade names of methyl cellulose ethers manufactured by Shin-etsu Kagaku Kogyo KK. Suitable SRA's characterised by poly(vinyi ester) hydrophobe segments include graft copotymers of poly(vinyl ester), e.g., Cj-Cg vinyl eaten, preferably poly(vinyl acetate), grafted onto polyalkylene oxide backbones. Sec European Patent Application 0 219 048, published April 22, 1987 by Kud, ct al. Commercially available examples include SOKALAN SRA's such as SOKALAN HP-22, available from BASF, Germany. Other SRA's are polyesters with repeat units containing 10- 15% by weight of ethylene terephthalate together with 80-90% by weight of pciyoxyethylene terephthalate derived from a polyoxyethylene glycol of average molecular weight 300-5,000, Commercial examples include ZELCON 5126 from Dupont and MUEASE T from ICI. Another preferred SRA is an oligomer having empirical formula (CAP)2(EG/PG)s(T)5(SIP)i which comprises terephthaloyl (T). sulfoisophthaloyl (SIP), oxyethyleneoxy and oxy-l,2-propylene (EG/PG) units and which is preferably terminated with end-caps (CAP), preferably modified iselhionaies, as in an oligomer comprising one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy and oxy- 1,2-propyleneoxy units in a defined ratio, preferably about 0.5:1 to about 10:1, and two end-cap units derived from sodium 2-(2-hydroxyethoxy)-ethanesulfonate. Said SRA preferably further comprises from 0,5% to 20%, by weight of the oligomer, of a crystallinity-reducing stabilizer, for example an anionic surfactant such as linear sodium dodecylbenzenesulfonate or a member selected from xyiene-, cumene-, and toluene- sulfonates or mixtures thereof, these stabilizers or modifiers being introduced into the synthesis vessel, all as taught in U.S. 5,415,807, Gosselink, Pan, Keilett and Hall, issued May 16, 1995. Suitable monomers for the above SRA include Na-2 EG and PG. Additional daises of SRA's include: (I) nonionic terephthalates using diisocyanate coupling agents to link polymeric ester structures, see U.S. 4,201,824, VioUand et al. and U.S. 4,240,918 Lagasse et al.; and (IT) SRA's with carboxylate terminal groups made by adding trimellitic anhydride to known SRA's to convert terminal hydroxyl groups to trimcUiute esters. With the proper selection of catalyst, the trimellitic anhydride forms linkages to the terminals of the polymer through an ester of the isolated carboxylic acid of trimellitic anhydride rather than by opening of the anhydride linkage. Either nonionic or anionic SRA's may be used as starting materials as long as they have hydroxyl terminal groups which may be esterified. See U.S. 4,525,524 Tunjj et al.. Other dasses include: (HI) anionic terephthalate-based SRA's of the urethaike-Unked variety, see U.S. 4,201,824, VioUand et al.; (IV) poly(vinvl caprolactam) and related co-polymeri with monomers such as vinyl pyrroUdone and/or dimethylaminoethyi methacrylate, including both nonionic and cationic polymer*, see U.S. 4,579,681, Ruppert et al.; (V) graft copolymers, in addition to the SOKALAN types from BASF, made by grafting acrylic monomers onto sulfonated polyesters. These SRA's assertedry have soil release and anti • redeposition activity similar to known cellulose ethers: sec EP 279,134 A, 1988, to Rhonc-Poulervc Chemie. Still other classes include: (VI) grafts of vinyl monomers such as acrylic add and vinyl acetate onto proteins such as caseins, see EP 457,205 A to BASF (1991), and (VII) poiyester-polyamide SRA's prepared by condensing adipic acid, caprolactam, and polyethylene glycol, especially for treating pciyarnide fabrics, see Bevan et al., DE 2.33S.044 to Unilever N. V., 1974. Other u«rul SRA's are described in U.S. Patents 4,240,918, 4,787,989 and 4,525,524. Any other anionic non-cotton soil release agent is suitable for u« in the compositions of the present invention alone or in combination, except for carboxymethylcellulose (CMC) which according to the present invention when used alone is used at a level above 02%, and preferably above 0.5%, Preferably, CMC is used at a level of from about 1% to about 10%, preferably from about 1% to about 6%, more preferably about 5%, Cotton Soil The cotton soil release agents of the present invention are water-soluble or dispersible, modified polyamines. These polyamines comprise backbones that can be either linear or cyclic. The polyamine backbones can also comprise polyamino branching chains to a greater or lesser degree, In general, the polyamine backbones described herein are modified in such a manner that each nitrogen of the polyamine chain is thereafter described in terms of a unit that is substituted, quatemired, oxidized, or combinations thereof. For the purposes of the present invention the term "modification* is defined u replacing & backbone -NH hydrogen atom by an E unit (substitution), quaternizing a backbone nitrogen (quatemued) or oxidizing a backbone nitrogen to the N'-oxide (oxidized). The terms "modification" and "substitution" are used interchangably when referring to the process of replacing a hydrogen atom attached to a backbone nitrogen with an E unit. Quatemization or oxidation may take place in some circumstance* without substitution, but preferably substitution is accompanied by oxidation or quaternization of at least one backbone nitrogen. The linear or non-cyclic polyamine backbones that comprise the cotton soil release Agents of the present invention have the general formula: said backbones prior to subsequent modification, comprise primary, secondary and tertiary amine nitrogens connected by R 'linking" units. The cyclic pcfyimine backbones comprising the cotton soil release agents of the present invention have the general formula: H R said backbones prior to subsequent modification, comprise primary, secondary find tertiary amine nitrogens connected by R "linking" units For the purpose of the present invention, primary amine nitrogens comprising the backbone or branching chain once modified are defined as V or Z "terminal" units. For example, when a primary amine moiety, located at the end of the main poiyamine backbone or branching chain having the structure H2N-R]. is modified according to the present invention, it is thereafter defined as a "terminal" unit, or simply a V unit. However, for the purposes of the present invention, some or ail of the primary amine moieties can remain unmodified subject to the restrictions further described herein below. These unmodified primary annine moieties by virtue of their position in the backbone chain remain "terminal" units. Likewise, when a primary amine moiety, located at the end of the main polyamine backbone having the structure -NH2 is modified according to the present invention, it is thereafter defined as a Z "terminal" unit, or simply a Z unit. This unit can remain unmodified subject to the restrictions further described herein below. In • similar manner, secondary amine nitrogens comprising the backbone or branching chain once modified are defined as W "backbone" units. For example, when & secondary amine moiety, the major constituent of the backbones and breaching chains of the present invention, having the structure H — {N-RJ— is modified •ccording to the present invention, it is thereafter defined as a W "backbone* unit, or jimply § W unit. However, for the purposes of the present invention, some or all of the secondary amine moieties can remain unmodified. These unmodified secondary amine moieties by virtue of their position in the backbone chain remain "backbone" units. In t further similar manner, tertiary amine nitrogens comprising the btckbone or branching chain once modified are further referred to as Y "branching" units. For eximple, when • tertiary tmino moiety, which is t chain branch point of cither the polyimine backbone or other branching chains or rings, having the structure is modified according to the present invention, it is thereafter defined as a Y "branching" unit, or simply a Y unit. However, for the purposes of the present invention, some or all or the tertiary amine moieties can remain unmodified These unmodified tertiary amine moieties by virtue of their position in the backbone chain remain "branching" units. The R units associated with the V, W and Y unit nitrogens which serve to connect the polyamine nitrogens, are described herein below. The final modified structure of the polyamines of the present invention can be therefore represented by the general formula for linear polyamine cotton soil release polymers and by the general formula for cyclic poiyamine cotton soil release polymers. For the case of polyamines comprising rings, a Y* unit of the formula R servcs as a branch point for a backbone or branch ring. For every Y1 unit there, is a Y unit having the formula tfuu will form the connection pouu of the ring to the main polymer chain or brunch. la the unique case where the backbone is a complete ring, the polyamine backbone haf the formula H therefore comprising no Z terminal unit and having the formula wherein k is the number of ring forming branching units. Preferably the polyamine backbones of the present invention comprise no rings. In the case of non-cyclic polyamines, the ratio of the index n to the index m relates to the relative degree of branching. A fully non-branched linear modified poh/amine according to the present invention has the formula that is, n is equal to 0. The greater the value of n (the lower the ratio of m to n), the greater the degree of branching in the molecule. Typically the value for m ranges from a minimum value of 4 to about 400, however larger values of m, especially when the value of the index n is very low or nearly 0, are also preferred. Each polyamine nitrogen whether primary, secondary or tertiary, once modified according to the present invention, is further defined as being a member of one of three general classes, simple substituted, quaternLred or oxidized. Those polyamine nitrogen units not modified are classed into V, W, Y, or Z units depending on whether they are primary, secondary or tertiary nitrogens. That is unmodified primary amine nitrogens are V or Z units, unmodified secondary amine nitrogens are W units and unmodified tertiary amine nitrogens are Y units for the purposes of the present invention. Modified primary amine moieties are defined as V "terminal" units having one of three forms: a) simple substituted units having the structure: E-N-R— E b) quatcrmzed units having the structure; E-N-RE wheran X is a suitable counter ion providing charge balance; and c) oxidized units having the structure: Modified secondary amine moieties are defined as W 'backbone' units having on of three forms; a) simple substituted units having the structure; -N-RE b) quatemized units having the structure E wherein X is a suitable counter ion providing charge balance; and c) oxidized units having the structure: 0 —N-RModified tertiary amine moieties are defined u Y "branching" units having one of three forms: a) unmodified units having the structure: b) quatemized units having the structure: wherein X is a suitable counter ion providing charge balance; and c) oxidized units having the structure: —N-RCertain modified primary amine moieties are defined as Z "terminal" units having one of three formi: a) simple substituted units having the structure: b) quatemized units having the structure: wherein X is a suitable counter ion providing charge balance; and c) oxidized units having the structure: When my position on a nitrogen is unsubstituted of unmodified, it is understood that hydrogen will substitute for E. For example, a primary tTiine unit comprising one E unit in the form of a hydroxyethyl moiety is a V termini! unit having the formula (HOCH2CH2)Hhk For the purposes of the present invention there are two types of chain terminating units, the V and Z units. The Z "terminal" unit derives from i terminal primary amino moiety of the structure -NH2- Non-cyclic polyamine backbones according to the present invention comprise only one Z unit whereas cycsc polyamines can comprise no Z units. The Z "terminal" unit can be substituted with any of the E units described further herein below, except when the Z unit is modified to fbnn an N-oxid«. In the case where the Z unit nitrogen is oxidized to in N-oxide, U nitrogen must be modified and therefore E cannot be a hydrogen. The potyamines of the present invention comprise backbone R "linking" units that serve to connect the nitrogen atoms of the backbone. R units comprise units that for th« purposes of the present invention are refened to as "hydrocrtyl R" units and "oxy R" units. The "hydrocarbyl" R units are C2«Ci2 alkylene, €4^12 alkenylene, C3-Ci2 hydroxyalkylene wherein the hydroxyi moiety may uke hny position on the R unit chain except the carbon atoms directly connected to the polyamine backbone nitrogens; C4«Cj2 dihydroxyalkylene wherein the hydroxyi moieties may occupy any two of the carbon atoms of the R unit chain except those carbon atoms directly connected to the polyamine backbone nitrogens; dialkylarylene which for the purpose of the present invention are arylene moieties having two alkyl substituent groups as part of the linking chain. For example, a dialkylarylene unit has the formula (Formula Removed) or although the unit need not be 1,4-substituted, but can also be 1,2 or 1,3 substituted CrC12 alkyiene, preferably ethylene, 1,2-propylene, and mixtures thereof, more preferably ethylene. The "oxy" R units comprise •(R10)XR5(OR1)X-, CH2CH(OR2)CH20)z(R10)yRl(OCH2CH(OR2)CH2)vv-1-CH2CH(OR2)CH2.) (RjQR1-, and mixtures thereof. Preferred R units are C2-Ci2 alkyiene, €3-012 hydroxyalkylene, C^-C^ dihydroxyalkylene, Cg-Cj2 dialkylarylene, -, more preferred R units are C2«Ci2 alkyiene, C3-Ci2 hydroxyaikylene, C4-Ci2 dihydroxyalkylene, -{RlQ^R1-, -{R^R^CR1^-, KCH2CH(OH)CH20)Z(R1 O^R^OCr^CH-iOHKr^V- and mixtures thereof, even more preferred R units are C2-Cj2 alkyiene, €3 hydroxyalkylene, and mixtures thereof, most preferred arc C2-C£ alkyiene. The most preferred backbones of the present invention comprise at least 50% R units that are ethylene. Rl units are C2-C$ alkyiene, and mixtures thereof, preferably ethylene R^ is hydrogen, and -(R^O^B, preferably hydrogen. R3 is Ci-Cjg alkyl, C-j-C\2 arylalkylene, C7«Ci2 alkyl substituted aryl, C6- ^12 "yl* ^ mixture* thereof, preferably Cj-C|2 alkyl, C7-C}2 arylalkylene, more preferably Ci-C|2 1^» "^^ preferably methyl. R^ units s«rve aa part of E units described herein below. R4 ii Cj-Ci2 •Ikylenc, C4-Cj2 alkenylene, Cg-Ci2 arylalkylene, Cg-Cio uykoe, preferably CJ-CIQ alkyiene, Cg-Cj2 arylalkylene, more preferably Cp.-Cg alkyiene, most preferably ethylene or butyl ene. R.5 is Ci-Ci2 ilkylene, C3-Ci2 hydroxyalkylene, €4^12 dihydroxyalkylene, Cg-Cn dialkyUrylene, -C(OX -C(0)NHR6NHC(0>, -C(OXR4)rC(OK .RHOR1^, -CH2CH(OHX^20{R10)yR1OCH2CH(OH)CH2-, -C(OXR4)iC(0)-, -CH2CH(OH)CH2', R5 U preferably ethylene, -C(0)-, (OHKH2-, more preferably -CH2CH(OH)CH2-. R6 ii C2-Ci2 tlkylene or Cg-C^ trylcne Th« preferred "oxy" R units are further defined in terms of the R1, R2, and Rs units. Preferred "oxy" R uniti comprise the preferred R1, R2, and R5 units. The preferred cotton soil release agents of the present invention comprise at least 50% R1 units thai are ethylene. Preferred R.1, R^, and R^ units are combined with the "oxy" R units to yield the preferred "0x7" R units in the following manner. i) Substituting more preferred R5 into - yieIds-(CH2CH20)xCH2CHOHCH2(OCH2CH2)x-. ii) Substituting preferred R1 and R2 into (R10)yR10(CH2CH(OR2KH2)w- yields -(CH2CH(OH)CH20)Z- (CH2CH20)yCH2CH20(CH2CH(OH)CH2Xvill) Substituting preferred R2 into -CH2CH(OR2)CH2- yields -CH2CH(OH)CH2-. E units are selected from the group consisting of hydrogen, C\-Ci2 C3-C22 alkenyi, C7-C22 arylalkyl, C2-C22 hydroxyalkyl, -(CH2)pC02M, - (CH2)qS03M, -CH(CH2C02M)C02M, KCH2)pP03M, -(RlO)mB, -C(0)R3, preferably hydrogen, C2-C22 hydroxyalkylene, benzyl, Ci'C22 allcylene, -(R^O)mB, -C(0)R3, -{CH^pCC^M, - Ci-C22 alkylene, -(R^^B, -C(0)R3, -(CH2)pC02M, ^CH^SOjM, -CH(CH2CO2MK02H most preferably C 1-622 aUcylene, .(RlQ^B, and -C(0)R3. When no modification or substitution is made on a nitrogen then hydrogen atom will remain as the moiety representing E. E units do not comprise hydrogen atom when the V, W or Z units are oxidized, that is the nitrogens are N-oxides. For example, the backbone chain or branching chains do not comprise units of the following structure: H-N— R or — or N— H Additionally, E units do not comprise carbonyl moieties directly bonded to a nitrogen atom when the V, W or Z units are oxidized, that is, the nitrogens are Noxides. According to the present invention, the E unit -C(0)R3 moiety is not bonded to an N-oxide modified nitrogen, that is, there are no N-oxide amides having the structure (Formula Removed) or combinations thereof. B is hydrogen, C^ alkyl, -(CH2)qS03M, -(CH2)pC02M, -(CH2)q- (CHS03M)CH2S03M, -(CH2)q(CHS02M)CH2S03M, -(CH2)pP03M, preferably hydrogen, - (CHS02M)CH2S03M, more preferably hydrogen or -(CH2)qS03M. M is hydrogen or a water soluble cation in sufficient amount to satisfy charge balance, For example, a sodium cation equally satisfies -(CF^pCC^M, and -(CH2)qS03M, thereby resulting in -(CH2)pCO2Na, and -(CH2)qS03Nfa moieties. More than one monovalent cation, (sodium, potassium, etc.) can be combined to satisfy the required chemical charge balance. However, more than one anionic group may be charge balanced by a divalent cation, or more than one mono-valent cation may be necessary to satisfy the charge requirements of a poly-anionic radical. For example, a -(CH2)pP03M moiety substituted with sodium atoms has the formula - (CH2)pP03Na3. Divalent cations such as calcium (Ca?-4) or magnesium (Mg.^4") may be substituted for or combined with other suitable mono-valent water soluble cations. Preferred cations are sodium and potassium, more preferred is sodium. X is a water soluble anion such as chlorine (Cl"), bromine (Br) and iodine (I") or X can be any negatively charged radical such as sulfate (SC>42') and methosulfate (013803 •). The formula indices have the following values: p has the value from 1 to 6, q hat the value from 0 to 6; r has the value 0 or 1; w has the value 0 or 1, x has the value from 1 to 100; y has the value from 0 to 100; z has the value 0 or 1; k is less than or equal to the value of n; m has the value from 4 to about 400, n !ias the value from 0 to about 200; m + n has the value of at least 5. The preferred cotton soil release agents of the present invention comprise polyamine backbones wherein less than about 50% of the R groups comprise "oxy" R units, preferably less than about 20%, more preferably less than 5%, most preferably the R unita comprise no "oxy" R units. The most preferred cotton soil release agents which comprise no "oxy" R units comprise polyamine backbones wherein less than 50% of the R groups comprise more than 3 carbon atoms. For example, ethylene, 1,2-propylene, and 1,3- propylene comprise 3 or less carbon atoms and are the preferred "hydrocarbyl" R units. That is when backbone R units are Ci-C^ aikyiene, preferred is CvC3 aikylene, mo$: preferred is ethylene. The cotton soil release agents of the present invention comprise modified homogeneous and non-homogeneous polyamine b&ckbones, wherein 100% or less of the -NH units are modified. For the purpose of the present invention the term "homogeneous polyamine backbone" is defined as a polyamine backbone having R units that are the same (i.e., all ethylene). However, this sameness definition does not exclude polyamines that comprise other extraneous units comprising the polymer backbone which are present due to an artifact of the chosen method of chemical synthesis. For example, it is known to those skilled in the art that ethanolamine may be used as an "initiator" in the synthesis of polyethyleneimines, therefore a sample of polyethyleneimine that comprises one hydroxyethvi moiety resulting from the polymerization "initiator8 would be considered to comprise a homogeneous polyamine backbone for the purposes of the present invention. A polyamine backbone comprising all ethylene R units wherein no branching Y units are present is a homogeneous backbone. A polyamine backbone comprising all ethylene R units is a homogeneous backbone regardless of the degree of branching or the number of cyclic branches present. For the purposes of the present invention the term "non-homogeneous polymer backbone" refers to polyamine backbones that are a composite of various R unit lengths and R unit types. For example, a non-homogeneous backbone comprises R units that are a mixture of ethylene and 1,2-propylene units. For the purposes of the present invention a mixture of "hydrocarbyl" and "oxy" R units is not necessary to provide i non-homogeneous backbone. The proper manipulation of these "R unit chain lengths1 provides the formulator with the ability to modify the solubility and fabric subsuntivity of the cotton soil release agents of the present invention. Preferred cotton soU release polymers of the present invention comprise horoogeivxxis polyamine backbones that are totally or partiaily substituted by polyeth>ieneoxy moieties, totally or partially quatemized amines, nitrogens totally or putUUy oxidized to N-oxides, and mixtures thereof However, not all backbone amine nitrogens must b« modified in the same manner, the choice of modification being left to the specific needs of the formulator. The degree of ethoxylation is also determined by the specific requirements of the formulator. The preferred polytmines that comprise the backbone of the compounds of the present invention ire generally polyiJkyieneamines (PAA's), polyalkyleneimines (PATs), preferably polyethyleneamine (PEA's), polyethyleneimines (PEFs), or PEA's or PEFn connected by moieties having longer R units than the parent PAA's, I'AI's, PEA's or PEl's. A common polyalkyleneamine (PAA) is tetrabutylenepentamine. PEA's are obtained by reactions involving ammonia and cthylene dichloride, followed by fractional distillation. The common PEA's obtained are triethylenetetramine (TETA) and teraethyienepentamine (TEPA). Above the pent&mines, i.e., the hexamines, heptamines, octamines and possibly nonamines, the cogenericaily derived mixture does not appear to separate by distillation and can include other materials such as cyclic amines and particularly piperazines. There can also be present cyclic amines with side chains in which nitrogen atoms appear. See U S. Patent 2,192,312, Dickinson, issued May 14, 1957, which describes the preparation of PEA's, Preferred amine polymer backbones comprise R units that are C^ aikylene (ethylene) units, also known as polyethylenimines (PEr$). Preferred PErs haw at least moderate branching, that is the ratio of m to n is less than 4: 1, however PEFs having a ratio of m to n of about 2: 1 are most preferred. Preferred backbones, prior to modification have the general formula: wherein m and n are the same as defined herein above. Preferred PEI's, prior to modification, will have a molecular weight greater than about 200 daltons. The relative proportions of primary, secondary and tertiary amine unils in the polyamine backbone, especially in the case of PErs, will vary, depending on the manner of preparation. Each hydrogen atom attached to each nitrogen itom of the polyamine backbone chain represents a potential site for subsequent substitution, qualernization or oxidation. These poryamines can be prepared, for example, by polymerizing ethykneirnine in the presence of a catalyst such as carbon dioxide, sodium bisulfite, sutfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc. Specific methods for preparing these polyamine backbones are disclosed in U.S. Patent 2,182,306, Ulrich et •!., issued December 5, 1939; U.S. Patent 3,033,746, Mayle et ai., issued May 8, 1962; U.S. Patent 2,208,095, Esselmann et al., issued July 1 6, 1940; U.S. Patent 2,806,839, Crowther, issued September 17, 1957; and U.S. Patent 2,553,696, Wilson, issued May 21, 1951; all herein incorporated by reference. Examples of modified cotton soil release polymers of the present invention comprising PErs, are illustrated in Formulas I - IV: Formula I depicts a cotton soil release polymer comprising a PE1 backbone wherein aU substitutable nitrogens are modified by replacement of hydrogen with a polyoxyalkyieneoxy unit, -(CH^C^O^M, having the formula Formula I This is an example of a cotton soil release polymer that is fully modified by one type of moiety. Formula II depicts a cotton soil release polymer comprising a PEI backbone wherein all substitutable primary amine nitrogens are modified by replacement of hydrogen with a polyoxyalkyleneoxy unit, -(CH2CH2O)7H. the molecule is then modi6ed by subsequent oxidation of all oxidlzable primary and secondary nitrogens to N-oxides, said cotton soil release agent having the formula Formula n FormuU 133 depicts a cotton soil release polymer comprising a PEI backbone wherein all backbone hydrogen atoms are substituted and some backbone amine units are quaternized. The substituems are polyoxyalkyleneoxy units, -{CH^CHlQW or methyl groups. The modified PEI cotton soil release polymer has the formula Formula ffl Formula IV depicts a cotton soil release polymer comprising a P£I backbone wherein the backbone nitrogens are modified by substitution (i.e. by -(Cf^CHjO^H or methyl), quaternized, oxidized to N-oxides or combinations thereof. The resulting cotton soil release polymer has the formula o Formula IV In the above examples, not all nitrogens of a unit class comprise the same modification. The present invention allows the formula: or to have a portion of the secondary amine nitrogens ethoxytated while having other secondary amine nitrogens oxidized to N-oxides. This also applies to the primary amine nitrogens, in thai the formulator may choose to modify all or a portion of the primary amine nitrogens with one or more substituents prior to oxidation or quaternizat'ion. Any possible combination of E groups can be substituted on the primary and secondary amine nitrogens, except for the restrictions described herein above. The formulator may take advantage of the possibility to modify the poh/amine backbones of the present invention in a manner that affords only the minimal amount of oxidizing the substrate backbones. For example, bleach "tempering" may be accomplished prior to or after formulation. For the purposes of the present invention, the term "bleach tempering" is defined as treating the modified polyamine with sufficient bleaching agent to oxidize the backbone against the [Conditions of formulation, By way of demonstration, a polyamine backbone does not necessarily require full modification by quatemkation or N-oxidation to be stable towards bleach When a sample of modified polyamine backbone is exposed to a suitable bleaching system (eg. nbnanoyloxywnzenesulfonate/perborate) any backbone nitrogens oxidizable under these conditions will oxidized. However, due to the exact structural properties of the backbone, some or all or the pre-bleach treatment nitrogens may remain un-effected. Once this tempering has taken place, the formulator may combine the modified polyamine with the bleaching system and remain confident that the polyamine will not consume the bulk of the bleaching agent. Those skilled in the art of bleach formulation will recognize that the ble&ch tempering will have its limitations and that a weaker tempering bleach should not be used in place of the formulation bleach. In another mode, the formulator may wish to add excess bleaching agent to the laundry detergent composition during formulation in order to conduct suitable in situ bleach "tempering" during storage and handling of the formulation, A preferred embodiment of the present invention involves the use of polyhydroxy fatty acid amide surfactants in combination with the modified polyamines described herein. This combination of nonionic surfactant and modified polyamine is especially useful at low pH formulations, that is at a pH less than about 10. A preferred laundry detergent composition according to the present invention comprises the low pH formula comprising: a) at least about 0.01% to about 95% by weight, of a polyhydroxy fatty acid amide nonionic detersive surfactant; b) from about 0.01 to about 10% by weight, of an anionic soil release polymer having effective soil release on norniotton fabric; c) optionally from about 0.05 to about 30% by weight, of a bleach; d) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and e) the balance carrier and adjunct ingredients; wherein the composition has a pH of about 7.2 to about 8.9 when measured as a 10*/o solution in water. The poryhydroxy fatty add amidei suitable for use in the low pH embodiment of the present invention may be combined with other suitable detersive surfactants such as anionic, amphoiytic, zwitterionic surfactants, and mixtures thereof. METHOD OF USE Present invention relates to methods of providing soil release benefits to fabric. The present invention relates to providing soil release benefits to cotton fabric by contacting said cotton fabric with a laundry composition comprising: a) at least about 0.001% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and b) the balance carrier and adjunct ingredients. The present invention also relates to methods of providing soil release to ail fabrics that comprise the laundry wash load, wherein said fabric is contacted with a laundry detergent composition comprising: a) at least 0,01% by weight, of a detersive surfactant selected from the group consisting of anionic, cationic, nonionic, zwitterionic, and amphoiytic surfactants, and mixtures thereof, b) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric; c) optionally from about 0.05 to about 30% by weight, of a bleach; d) from about 0,1 to about 10% by weight, a modified polyamine cotton soil release polymer according to the present invention; and e) the balance carrier and adjunct ingredients. The methods of the present invention are suitable for use when the fabric being treated for soil release is also in need of bleaching. Compositions comprising bleaching agents commonly used to clean white fabrics are compatible with the cotton soil release polymers of the present invention. The present invention also provides a method for cleaning soiled cotton fabric by contacting said fabric with an aqueous solution of the laundry compositions or the laundry detergent compositions of the present invention. Because of the substantive nature of the compounds of the present invention, the methods described herein provide cotton soil release benefits for several treatments or laundry washes after the present method has been withdrawn. The process also results in cotton fabric having a cleaner appearance and in the case of white cotton fabric, a whiter appearance, For the purposes of the methods for providing cotton soil release to cotton fabric, the backbone of the polyamine does not require modification, that is no backbone nitrogens require oxidation of quaterniation. This is especially true in the case of methods that do not use bleaching materials. For example, a suitable cotton soil release agent has the structure (Formula Removed) wherein the polyamine backbone is substitued with polyethyleneoxy units and no backbone nitrogen units are quaternized or oxidized. However, cotton soil release agents of the above type can not be combined with bleaching agents except in the cases where these substrates are the starting materials for "bleach tempered" cotton soil release agents where the "tempered" cotton soil release agents are pre-fonned or "tempered" in situ. Adjunct Ingredients Detersive surfactants The detersive surfactants suitable for use in the present invention arc cationic, anionic, nonionic, ampholytic, zwitterionic, and mixtures thereof, further described herein below. The laundry detergent composition may. be in any suitable form, for example, high density liquids, light liquids or other pourable forms in addition to granules or laundry bars. The cotton soil release polymers of the present invention can be formulated into any detersive matrix chosen by the formulator. The laundry detergent compositions according to the present invention may additionally comprise at least about 0.01%, preferably at least about 0.1%, more preferably at least about 1% by weight, of the following detersive surfactants. Nonlimiting examples of surfactants useful herein typically at levels from abouti 1% tc about 55%, by weight, include the conventional C 11-C18 alkyl benzene sulfonates ("LAS") and primary, branched-chain and random C 10-C20 alkyl sulfates ("AS"), the C10-Cl8 secondary (2,3) allcyl sulfates of the formula CH3(CH2)x(CHOSO3-M+) CH3 and CH3(CH2)x(CHOSO3-M+)CH2CH3 where x and (y + 1) are integers of at least about 7, preferably at least about 9, and M is t wster-solubilizing cation, especially sodium, unsaturated sulfates such as oleyl sulfate, the C10-Cl8 alkyl alkoxy sulfates ("AExS"; especially EO 1-7 ethoxy sulfates), C10-Cl8 alkyl alkcoxy carboxylates (especially the EO 1-5 ethoxycarboxylates), the C10-Cl8glycerol ethers, the C10-Cl8 alkyl polyglycosides and their corresponding sulfated polygiycosides, and C 12-C18 alpha-sulfonated fatty acid esters If desired, the conventional nonionic and amphoteric surfactants such as the C 12-C18 alkyl ethoxyiates ("AE") including the so-called narrow peaked alkyl ethoxylates and C6-C18 alkyl phenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), C 12-C18 betaines and sulfobetaines ("sultaines"), C 10-C18 amine oxides, and the like, can also be included in the overall compositions. The C 10-C18 N-alkyl polyhydroxy fatty acid amides can also be used Typical examples include the C 12-C18 N-methylglucamides. See WO 9,206,154 Other sugar-derived surfactants include the N-alkoxy polyhydroxy fatty acid amides, such as C 10-C18 N-(3-methoxypropyl) glucamide. The N-propyl through N-hexyl C 12-C18 glucamides can be used for low sudsing. C 10-C18 conventional soaps may also be used. If high sudsing is desired, the branched- chain C 10-C16soaps may be used. Mixtures of anionic and nonionic surfactants arc especially useful. Other conventional useful surfactants are listed in standard texts. The preferred compositions of the present invention comprise at least about 0.01%, preferably at least 0.1% more preferably from about 1% to about 95%, most preferably from about 1% to about 80% by weight, of an anionic detersive surfactant. Alkyl sulfate surfactants, either primary or secondary, are a type of anionic surfactant of importance for use herein, Alkyl sulfates have the general formula ROSO3M wherein R preferably is a C10-C24 hydroorbyi, preferably an alkyl straight or branched chain or hydroxyalkyi having a C10-C20 alkyli component, more preferably a C 12-C18 alkyl or hydroxyalkyi, and M is hydrogen or a water soluble cation, e.g., an alkali metal cation (e.g., sodium potassium, lithium), substituted or unsubstituted ammonium cations such as methyl-, dimethyl-, and trimethyl ammonium and quaternary ammonium cations, e.g., tetramethyl-ammonium and dimethyl piperdinium, and cations derived from alkanolamines such as ethanolamine, diethinolamine, triethanolamine, and mixtures thereof and the like. Typically, alkyl chains of C12-C16 are preferred for lower wash temperatures (e.g., below about 50°C) and C 16-C18 alkyl chains are preferred for higher wash temperatures (e.g., about 50°C). Alkyl alkoxylated sulfate surfactants are another category of preferred anionic surfactant. These surfactants are water soluble salts or acids typically of the formula RO(A)mS03M wherein R is an unsubstituted C10-C24 alkyl or hydroxyalkyl group having a C10-C24 alkyl component, preferably a C 12-C20 alkyl or hydroxyalkyl, more preferably C 12-C18 alkyl or hydroxyalkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is hydrogen or a water soluble cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or substitute-ammonium catioa Alkyl ethoxylated sulfates as well as alkyl propoxylated sulfates are contemplated herein. Specific examples of substituted ammonium cations include methyl-, dimethyl-, trimethyl-ammonium and quaternary ammonium cations, such as tetramethyUammonium, dimethyl piperdinium and cations derived from alkanolamines, e.g., monoethanolamine, diethanolamine, and triethanolamine, and mixtures thereof. Exemplary surfactants are C12-C18 alkyl polyethoxylate (1,0) sulfate, C12-C18 alkyl polyethoxylate (2.25) sulfate, C12-C18 alkyl polyethoxylate (3.0) sulfate, and C12-C18 alkyl polyethoxylate (4.0) sulfate wherein M is conveniently selected from sodium and potassium. The laundry detergent compositions according to the present invention may additionally comprise at least about 0.01%, preferably at least about 0. 1%, more preferably at least about 1% by weight, of conventional C11-C18 alkyl beruene sulfonates ("LAS"), preferably in laundry bar embodiments and in granular Laundry detergent compositions. The preferred compositions of the present invention also comprise at least about 0,01%, preferably at least 0. 1%, more preferably from about 1% to about 95%, most preferably from about 1% to about 80% by weight, of an nonionic detersive surfactant. Preferred nonionic surfactants such as C12-C18 alkyl ethoxylates ("AE") including the so-called narrow peaked alkyl ethoxylates and C6-C12 alkyl phenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), block alkylene oxide condensate of C6 to C12 alkyl phenols, alkylene oxide condensates of C8-C22 alkanols and ethylene oxide/propylcne oxide block polymers (Pluronic™-BASF Corp.), as well as semi polar nonionics (e.g., amine oxides and phosphine oxides) can be used in the present compositions. An extensive disclosure of these types of surfactants is found in U.S. Pat, 3,929,678, Laughlin et al., issued December 30, 1975, incorportted herein by reference. Alkylpolysaccharides such as disclosed in U.S. Pat. 4,565,647 Llenado (incorportted herein by reference) are also preferred nonionic surfactants in the compositions of the invention. More preferred nonionic surfactants are the polyhydroxy fatty acid imides having the formula: (Formula Removed) wherein R7 is C5-C31 alkyl, preferably straight chain C9-C17 alkyl or alkenyl, more preferably straight chain C9-C17 alkyl or alkenyl, most preferably straight chain C11-C15 alkyl or alkenyl, or mixtures thereof; R8 is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 hydroxyalkyt, preferably methyl or ethyl, more preferably methyl. Q is t polyhydroxyalkyl moiety having a linear alkyl chain wiith at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (hereof; preferred alkoxy is ethoxy or propoxy, and mixtures thereof. Preferred Q is derived from a reducing sugar in a reductive amination reaction. More preferably Q is a glycityl moiety. Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose. As raw materials, high dextrose com syrup, high fructose corn syrup, and high maltose com syrup can be utilized as well as the individual sugars listed above. These com syrups may yield a mix of sugar components for Q. It should be understood that it is by no means intended to exclude other suitable raw materials. Q is more preferably selected from the group consisting of -CH2(CHOH)nCH20H, -CH(CH2OH)(CHOH)n-1CH2pH, -CH2(CHOH)2-(CHOR)CHOH)2OH, and alkoxylated derivatives thereof, wherein n is art integer from 3 to 5, inclusive, and R1 is hydrogen or a cyclic or aliphatic monosaccharide. Most preferred substituents for the Q moiety are glycityls wherein n is 4, particularly -CH2(CHOH)4CH2OH. R7CO-N R8 can be, for example, methyl, ethyl, propyl, isopropyl, butyl, 2-hydroxy ethyl, or 2-hydroxy propyi Q can be 1-deoxyglucityl, 2-deoxyfructityl, 1-deoxymaltityl, 1-deoxylactityl, 1-deoxygalactityl, 1-deoxymannityl, l-deoxymaltotriotityl, etc. A particularly desirable surfactant of this type for use in the compositions herein is alkyl-N-methyl glucomide, a compound of the above formula wherein R7 is alkyl (preferably C11-C13), R8, is methyl and Q is 1-deoxyglucityl. Other sugar-derived surfactants include the N-alkoxy polyhydroxy fatty add amides, such as C11-C18 N-(3-methoxypropyl) glucamide. The N-propyl through N-hexylC12-C18 glucamides can be used for low sudsing. C10-C20conventional soaps may also be used. If high sudsing is desired, the branched-chain C10-C16 soaps may be used. Bleaching Compounds - Bleaching Agents and Bleach Activitors The detergent compositions herein may optionally contain bleaching agents or bleaching compositions containing a bleaching agent and one or more bleach activators, When present, bleaching agents will be at levels of from about 0.05% to about 30%, more preferably from about 1% to about 30%, most preferably from about 5% to about 20%, of the detergent composition, especially for fabric laundering. If present, the amount of bleach activators will typically be from about 0.1% to about 60%, more typically from about 0.5% to about 40% of the bleaching composition comprising the bleaching agent-plus-bleach activator. The peroxygen bleaching compounds useful herein are those capable of yielding hydrogen peroxide in an aqueous liquor. These compounds are well known in the an and include hydrogen peroxide and the alkali metal peroxides, organic peroxide bleaching compounds such as urea peroxide, and inorganic persalt bleaching compounds, such as the alkali metal perborates, percarbonates, perphosphates, and the like. Mixtures of two or more such bleaching compounds can also be used, if desired. Preferred peroxygen bleaching compounds include sodium perborate, commercially available in the form of mono-, tri-, and tetra-hydrate, sodium pyrophosphate peroxyhydrate, urea peroxy-hydrate, sodium peroxide, peroxyphthalate and sodium percarbonate. Particularly preferred are sodium perborate tetrahydrate, sodium perborate monohydrate and sodium percarbonete. Sodium percarbonate is especially preferred because it is very stable during storage and yet still dissolves very quickly in the bleaching liquor. It is believed that such rapid dissolution results in the formation of higher levels of percarboxylic acid and, thus, enhanced surface bleaching performance. Another category of bleaching agent that can be used without restriction encompasses percarboxylic acid bleaching agents and salts thereof. Suiuble examples of this class of agents include magnesium monoperoxyphthalate hexahydrate, the magnesium salt of metachloro perbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid and diperoxydodecanedioic acid. Such bleaching agents are disclosed in U.S. Patent 4,483,781, Hartman, issued November 20, 1984, U.S. Patent Application 740,446, Bums et al, filed June 3,1985, European Patent Application 0,133,354, Banks et al, published February 20, 1985, and U.S. Patent 4,412,934, Chung et al, issued November 1, 1983. Highly preferred bleaching agents also include 6-nonylamino-6-oxopcroxycaproic acid as described in U.S. Patent 4,634,551, issued January 6,1987 to Bums et al. A preferred percarbonate bleach comprises dry panicles having an average particle size in the range from about 500 micrometers to about 1,000 micrometers, not more thin about 10% by weight of said particles being smaller than about 200 micrometers and not more than about 10% by weight of said particles being larger than about 1,250 micrometers. Optionally, the percarbonate can be coated with silicate, borate or water-soluble surfactants. Percarbonate is available from various commercial sources such as FMC, Solvty and Tokai Denka. Mixtures of bleaching agents can also be used. Peroxygen bleaching agents, the perborates, the percarbonates, etc., are preferably combined with bleach activators, which lead to the in situ production in aqueous solution (i.e., during the washing process) of the peroxy acid corresponding to the bleach activator Various nonlimiting examples of activators are disclo.sed in U.S. Patent 4,915,854, issued April 10, 1990 to Mao et al, and US. Patent 4,412,934. The nonanoyloxybenzene sulfonate (NOBS) and tetraacetyl ethylone diamine (TAED) activators are typical, and mixtures thereof can also be used. See also U.S. 4,634,551 for other typical bleaches and activators useful herein. Another class of bleach activators comprises the benzoxazin-type activators disclosed by Hodge et al in U.S. Patent 4,963,723, issued October 30, 1990, incorporated herein by reference. A highly preferred activator of the benzoxaan-type is: (Formula Removed) Still another class of preferred bleach activators includes the acyl lactain activators, especially acyl caprolactams and acyl valerolactams of the formulae: (Formula Removed) wherein R6 is H or in alkyl, aryl, alkoxyaryl, or alkaryl group containing from 1 to about 12 carbon atoms. Highly preferred lactam activators include benzoyl caprolactam, octanoyl caprolactam, 3,5,5-trimethylhexanoyl caprolactam, nonanoyl caprolactam, decanoyl caprolactam, undecenoyl caprolactam, benzoyl valerolactam, octanoyl valerolactam, decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactum, 3,5,5-trimethylhexanoyl valerolictam and mixtures thereof. See also U.S. Patent 4,545,784, issued to Sanderson, October 8, 1985, incorporated herein by reference, which diidosw acyl caprol ictams, including benzoyl caprotactam, adsorbed into sodium perborate. For compositions according to the present invention comprising a bleach, preferred are peroxyacid bleaching agents, of which amide substituted peroxy acid precursor compounds ire more preferred, including those having the formula: (Formula Removed) wherein R1 is C1-C14 alkyl, aryl, alkylaryl, and mixtures thereof, R2 is C1-C14 alkylene, arylene, alkylarylene, and mixtures thereof; R5 is hydrogen, C1-C10 alkyl, aryl alkylaryl, and mixtures thereof; L is any suitable leaving group (a preferred leaving group is phenyl sulfonate), R1 preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. R1 may contain where applicable, branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, halogen, nitrogen, sulphur and other typical substiruent groups or organic compounds. R5 is preferably H or methyl. R1 and R5 should not contain more than 18 carbon atoms in total. Amide substituted bleach activator compounds of this type are described in EP-A-0170386. Preferred examples of bleach activators of the above formulae include (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamidocaproyi)oxybenzene,f;ul-fonate, (6-decanarnido-caproyl)oxybeozenesulfonate, and mixtures thereof as described in U.S. Patent 4,634,551, incorporated herein by reference. The modified polyamines of the present invention may optionally be combined with bleaching agents and bleach activator. The preferred laundry detergent compositions comprising bleaching agents comprise: a) at least about 0.01% to about 95% by weight, of an anionic detersive surfactant; b) at least about 0,01% to about 95% by weight, of a nonionic detersive surfactant; c) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric; d) from about 0.05 to about 30% by weight, of a bleach; e) from about 0.05 to about 30% by weight, of a bleach activitor, f) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and g) the balance carrier and adjunct ingredients. Still more preferably the bleach containing compositions of the present invention comprise oxygen bleaches. These oxygen bleach containing compositions comprise: a) at least about 0.01% to about 95% by weight, of an anionic detersive surfactant; b) at least about 001% to about 95% by weight, of a nonionic detersive surfactant; c) from about 0.01 to about 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric; d) optionally from about 0.05 to about 30% by weight, of a peroxygen bleach selected from the group consisting of alkali metal percarbonate, perborate, monoperphthalate, pyrophosphate peroxyhydrate, urea peroxy-hydrate and mixtures thereof; e) optionally from about 0.05 to about 30% by weight, of a bleach activator having the formula (Formula Removed) and mixtures thereof, wherein R1 is C1-C14alkyl, aryl, alkylaryl, and mixtures thereof, R2 is C1-C14 aJkylene, arylene, alkylarylene, and mixtures thereof; R5 is hydrogen, C1-C10 alkyl, aryl, alkylaryl, and mixtures thereof; L is any suitable leaving group; f) from about 0.01 to about 10% by weight, a water-soluble or dispersible, bleach stable, modified polyamine cotton soil release agent according to the present invention; and g) the balance carrier and adjunct ingredients. Bleaching agents other than oxygen bleaching agents are also known in the art and can be utilized herein. One type of non-oxygen bleaching agent of particular interest includes photoactivated bleaching agents such as the sulfonated zinc arid/or aluminum phthauocyanines. See U.S. Patent 4,033,718, issued July 5, 1977 to Holcombc et a1. If used, detergent compositions will typically contain from about 0,025% to about 1.25%, by weight, of such bleaches, especially sulfonate zinc phthalocyanine. If desired, the bleaching compounds can be catalyzed by means of a manganese compound. Such compounds are well known in the art and include, for example, the manganese-based catalysts disclosed in U.S. Pat. 5,246,621, U.S. Pat, 5,244,594; U.S. Pat. 5,194,416; U.S. Pat. 5,1 14,606; and European Pat. App. Pub. Nos. 549.271A1, 549.272A1, 544.440A2, and 544.490A1; Preferred examples of these catalysts include MnIV2(u-O)3(1,4,7-trimethyl-1,4,7-triazacyclo- nonane)2(PF6)2, MnIII2(u-O)l(u-OAc)2(1,4,7-trimethyl-1,4,7--triazacydononine)2-(C104)2, MnIV4(u-O)6(l,4,7-triazacyclononane)4(CI04)4, MnIIIMnIV4(u-O)1(u- OAc)2.(1,4,7-trimethyl-l,4,7-triazacyclcnonane)2(C104)3,MnIV(lt4,7-trimethyl-1,4,7-triazacyclononane)- (OCH3)3(PF6), and mixtures thereof. Other metal-based bleach catalysts include those disclosed in U.S. Pat. 4,430,243 and U.S. Pat. 5,114,611. The use of manganese with various complex ligands to enhance bleaching is also reported in the following United States Patents: 4,728,455; 5,284,944; 5,246,612; 5,256,779; 5,280,117; 5,274,147; 5,153,161; and 5,227,034. As a practical matter, and not by way of limitation, the compositions and processes herein can be adjusted to provide on the order of at least one part per ten million of the active bleach catalyst species in the aqueous washing liquor, and will preferably provide from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm, of the catalyst species in the laundry liquor. A wide variety of other ingredients useful in detergent compositions can be included in the compositions herein, including other active ingredients, carriers, hydrotropes, processing aids, dyes or pigments, solvents for liquid formulations, solid fillers for bar compositions, etc. If high sudsing is desired, suds boosters such as the C10-C16 alkanolamides can be incorporated into the compositions, typically al 1%-10% levels, The C10-C14 monoethanol and diethanol amides illustrate a typical class of such suds boosters. Use of such suds boosters with high sudsing adjunct surfactants such as the amine oxides, betaines and sultaines noted above is also advantageous. If desired, soluble magnesium salts such as MgCl2, MgSO4, and the like, can be added at levels o£ typically, 0.1%-2%, to provide additional suds ?nd to enhance grease removal performance. Various detersive ingredients employed in the present compositions optionally can be further stabilized by absorbing said ingredients onto a porous hydrophobic substrate, then coating said substrate with a hydrophobic coating. Preferably, the detersive ingredient is admixed with a surfactant before being absorbed into the porous substrate. In use, the detersive ingredient is released from the substrate into the aqueous washing liquor, where it performs its intended detersive function. To illustrate this technique in more detail, a porous hydrophobic silica (trademark SIPERNAT D10, DeGussa) is admixed with a proteolytic enzyme solution containing 3%-5% of C13-15 ethoxylated alcohol (EO 7) nonionic surfactant. Typically, the enzyme/surfactant solution is 2.5 X the weight of silica. The resulting powder is dispersed with stirring in silicone oil (various silicone oil viscosities in the range of 500-12,500 can be used). The resulting silicone oil dispersion is emulsified or otherwise added to the final detergent matrix. By this means, ingredients such as the aforementioned enzymes, bleaches, bleach activators, bleach catalysts> photoactivators, dyes, fluorescers, fabric conditioners and hydrolyzable surfactants can be "protected" for use in detergents, including liquid laundry detergent compositions. Liquid detergent compositions can contain water and other solvents as carriers. Low molecular weight primary or secondary aJcohoIs exemplified by methanol, ethanol, propanol, and isopropanol are suitable. Monohydric alcohols are preferred for solubilizing surfactant, but polyols such as those containing from 2 to about 6 carbon atoms and from 2 to about 6 hydroxy groups (e.g., 1,3-propanediol, ethylene glycol, glycerin, and 1,2-propanediol) can also be used. The compositions may contain &om 5% to 90%, typically 10% to 50% of such carriers. The detergent compositions herein will preferably be formulated such that, during use in aqueous cleaning operations, the wash water will have a pH of between about 6.5 and about 1 1, preferably between about 7,5 and 10.5. Laundry products are typically at pH 9-1 1 . Techniques for controlling pH at recommended usage levels include the use of buffers, alkalis, acids, etc., and are well known to those skilled in the art, Enzymes Enzymes can be included in the present detergent compositions for a variety of purposes, Including removal of protein-based, carbohydrate-based, or triglyceride-based stains from surfaces such as textiles, for the prevention of refugee dye transfer, for example in laundering, and for fabric restoration. Suitable enzymes include proteases, amylases, lipases, cellulases, peroxidases, and mixtures thereof of any suitable origin, such as vegetable, animal, bacterial, fungal and yeast origin. Preferred selections arc influenced by factors such as pH-activity and/or stability optima, thermostability, and stability to active detergents, builders and the like. In this respect bacterial or fungal enzymes are preferred, such as bacterial amylases and proteases, and fungal ceilulases. "Detersive enzyme", as used herein, means any enzyme having a cleaning, stain removing or otherwise beneficial effect in a laundry, hard surface cleaning or personal ore detergent composition. Preferred detersive enzymes are hydrokises such as proteases, amylases and lipases. Preferred enzymes for laundry purposes include, but are not limited to, proteases, ceUuIases, lipases and peroxidases. Enzymes are normally incorporated into detergent or detergent additive compositions at levels sufficient to provide a "cleaning-effective amount'. The term "cleaning effective amount" refers to any amount capable of producing a clearing, stain removal, soil removal, whitening, deodorizing, or freshness improving effect on substrates such as fabrics. In practical terms for current commercial preparations, typical amounts are up to about 5 mg by weight, more typically 0.01 mg to 3 mg, of active enzyme per gram of the detergent composition. Stated otherwise, the compositions herein will typically comprise from 0.001% to 5%, preferably 0.01%-l% by weight of a commercial enzyme preparation. Protease enzymes are usually present in such commercial preparations at levels sufficient to provide from 0.005 to 0 1 Anson units (AU) of activity per gram of composition. For certain detergents, it may be desirable to increase the active enzyme content of the commercial preparation in order to minimize the total amount of non-catalytically active materials and thereby improve spotting/filming or other end-resuits. Higher active levels may also be desirable in highly concentrated detergent formulations. Suitable examples of proteases are the subtilisins which are obtained from particular strains of B. subtilis and B. licheniformis. One suitable protease is obtained from a strain of Bacillus, having maximum activity throughout the pH range of 8-12, developed and sold as ESPERASE® by Novo Industries A/S of Denmark, hereinafter "Novo". The preparation of this enzyme and analogous enzymes wi described in GB 1,243,784 to Novo. Other suitable proteases include ALCAI.ASE® and SAVINASE® from Novo and MAXATASE® from International Bio-Synthetics, Inc., The Netherlands; as well as Protease A as disclosed in EP 130,756 A, January 9, 1985 and Protease B as disclosed in EP 303,761 A, April 28, 1987 and EP 130,756 A, January 9, 1985. Set also a high pH protease from Bacillus sp. NCIMB 40338 described in WO 9318140 A to Novo. Enzymatic detergents comprising protease, one or more other enzymes, and a reversible protease inhibitor are described in WO 9203529 A to Novo. Other preferred proteases include those of WO 9510591 A to Procter & Gamble. When desired, a protease having decreased adsorption and increased hydrolysis is available as described in WO 9507791 to Procter & Gamble. A recombinant trypsin-like protease for detergents suitable herein is described in WO 9425583 to Novo. In more detail, an esptcially preferred protease, referred to as "Protease D" is a carbonyl hydrolase variant having an amino acid sequence not found in nature, which is derived from a precursor carbonyl hydrolase by substituting a different amino acid for a plurality of amino acid residues at a position in said carbonyi hydrolase equivalent to position +76, preferably also in combination with one or more amino acid residue positions equivalent to those selected from the group consisting of+99, +101, +103, +104, +107, +123, +27, +105, +109, +126, +128, +135, +156, -4-166, +195, +197, +204, +206, +210, +216, +217, +218, +222, +260, +265, and/or +274 according to the numbering of Bacillus amyloliquefaciens subtilisin, as described in WO 95/10615 published April 20, 1995 by Genencor International Useful proteases are also described in PCT publications: WO 95/30010 published Novenber 9, 1995 by The Procter & Gamble Company; WO 95/30011 published Novenber 9, 1995 by The Procter & Gamble Company; WO 95/29979 published Novenber 9, 1995 by The Procter & Gamble Company. Amylases suitable herein include, for example, a-amylases described in GB 1,296,839 to Novo; RAPIDASE®, International Bio-Synthetics, Inc. and TERMAMYL®, Novo. FUNGAMYL® from Novo is especially useful. Engineering of enzymes for improved stability, e.g., oxidative stability, is known. See, for example J. Biological Chem., Vol. 260, No. 11, June 1985, pp 6518-6521. Certain preferred embodiments of the present compositions can make use of amylases having improved stability in detergents, especially improved oxidative stability as measured against a reference-point of TERMAMYL® in commercial use in 1993. These preferred amylases herein share the characteristic of being "stability-enhanced" amylases, characterized, at a minimum, by a measurable improvement in one or more of: oxidative stability, e.g., to hydrogen peroxide / tetraacetylethylenediamine in buffered solution at pH 9-10; thermal stability, eg., at common wash temperatures such as about 60°C; or alkaline stability, e.g., at u pH from about 8 to about 11, measured versus the above-identified reference-point amylase. Stability can be measured using any of the art-disclosed technical tests. See, for example, references disclosed in WO 9402597. Stability-enhanced amyiasts can be obtained from Novo or from Genencor International, One class of highly preferred amyiases herein have the commonality of being derived using site-directed mutagenesis from one or more of the Baccillus amylases, especialy the Bacillus a* amylases, regardless of whether one, two or multiple amylase strains are the immediate precursors. Oxidative stability-enhanced amylases vs. the above-identified reference aim/Use are preferred for use, especially in bleaching, more preferably oxygen bleaching, as distinct from chlorine bleaching, detergent compositions herein. Such preferred amylases include (a) an amylase according to the hereinbefore incorporated WO 9402597, Novo, Feb. 3,1994, as further illustrated by a mutant in which substitution is made, using alanine or threonine, preferably threonine, of the methionine residue located in position 197 of the B. licheniform alpha-amylase, known as TERMAMYL®, or the homologous position variation of a similar parent amylase such as B. amylollquefaciens, B.sub tilis, or B.stearothermophilus; (b) stability-enhanced amylases as described by Genencor International in a paper entitled "Oxidatively Resistant alpha-Amylases" presented at the 207th American Chemical Society National Meeting, March 13-17 1994, by C. Mitchinson. Therein it was noted that bleaches in automatic dishwashing detergents inactivate alpha-amylases but that improved oxidative stability amylases have been made by Gtuencor from B.lichemformis NCIB8061 . Metnionine (Met) was identified as the most likely residue to be modified. Met was substituted, one at a time, in positions 8, 15, 197, 256, 304, 366 and 438 leading.to specific mutants, particularly important being M197L and M197T with the M197T variant being the most stable expressed variant; (c) particularly preferred amylases herein include amylase variants having additional modification in the immediate parent as described in WO 95 10603 A and are available from the assignee, Novo, as DURAMYL®. Other particularly preferred oxidative stability enhanced amylase include those described in WO 9418314 to Genencor International and WO 9402597 to Novo. Any other oxidative stability-enhanced amylase can be used, for example as derived by site-directed mutagenesis from known chimeric, hybrid or simple mutant parent forms of available amylases. Other preferred enzyme modifications are accessible. Sec WO 9509909 A to Novo. Cellulases usable herein include both bacterial and fungal types, preferably having a pH optimum between 5 and 9.5. U.S. 4,435,307, Barbesgoard et al, March 6, 1984, discloses suitable fungal cellulascs from Humicola insolens or Humicola strain DSM1800 or a cellulasc 212-producing fungus belonging to the genus Aeromonas, and cellulase extracted from the hepatopancreas of a marine mollusk, Dolabella Auricula Solander. Suitable cellulascs are also disclosed in GB-A-2.075,028; GB-A-2.095.275 and DE-OS-2.247,832. CAREZYME® (Novo) is especially useful. See also WO 9117243 to Novo. Suitable Upase enzymes for detergent usage include those produced by microorganisms of the Pstudomonas group, such as Pseudomonas slutzeri ATCC 19.154, as disclosed in GB 1,372,034. See also lipases in Japanese Patent Application 53,20487, laid open Feb. 24, 1978. This lipase is available from Amano Pharmaceutical Co. Ltd., Nagoya, Japan, under the trade name Lipase P "Amano," or "Amano-P." Other suitable commercial lipases include Amano-CES, lipases ex Chromabacter viscosum, e.g. Chromobacter viscosum var. lipolyticum NRRLB 3673 from Toyo Jozo Co., Tagata, Japan; Chromobacter viscosum Upases from U.S. Biochemical Corp., U.S.A. and Disoynth Co., The Netherlands, and lipases ex Pseudomonas gladioli. LIPOLASE® enzyme derived from Humicola lanuginosa and commercially available from Novo, sec also EP 341,947, is a preferred lipase for use herein. Lipase and amylase variants stabilized against peroxidase enzymes are described in WO 9414951 A to Novo. See also WO 9205249 and RD 94359044, Cutinase enzymes suitable for use herein are described in WO 8809367 A to Genencor, Peroxidase enzymes may be used in combination with oxygen sources, e.g., percarbonate, perborate, hydrogen peroxide, etc., for "solution bleaching" or prevention of transfer of dyes or pigments removed from substrates during th; wash to other substrates present in the wash solution. Known percxidases include horseradish peroxidase, ligninase, and haloperoxidases such as chloro- or bromo-peroxidase Peroxidase-containing detergent compositions are disclosed in WO 89099813 A, October 19, 1989 to Novo and WO 8909813 A to Novo. A range of enzyme materials and means for their incorporation into synthetic detergent compositions is also disclosed in WO 9307263 A and WO 9307260 A to Genencor International, WO 8908694 A to Novo, and U.S. 3,553,139, January 5, 1971 to McCarty et al. Enzymes are further disclosed in U.S. 4,101,457, Plane et al, July 18, 1978, and in U.S. 4,507,219, Hughes, March 5.6, 1985 Enzyme materials useful for liquid detergent formulations, and their incorporation into such formulations, arc disclosed in U.S. 4,261,868, Hora et al, April 14, 1981. Enzymes for use in detergents can be stabilized by various techniques. Enzyme stabilization techniques are disclosed and exemplified in U.S. 3,600,319, August 17, 1971, Gcdge et al, EP 199,405 and EP 200,586, October 29, 1986, Venegas. Enzyme stabilization systems arc also described, for example, in U.S. 3,519,570. A useful Bacillus, sp. AC13 giving proteases, xylanases and celluloses, is described in WO 9401532 A to Novo, Enzyme Stabilizing System Enzyme-containing, including but not limited to, liquid compositions, herein may comprise from about 0.001% to about 10%, preferably from about 0,005% to about 8%, most preferably from about 0.01% to about 6%, by weight of an enzyme stabilizing system. The enzyme stabilizing system can be any stabilizing system which is compatible with the detersive enzyme. Such a system may be inherently provided by other formulation actives, or be added separately, e.g., by the formulator or by a manufacturer of detergent-ready enzymes. Such stabilizing systems am, for example, comprise calcium ion, boric acid, propylene glycol, short chain carboxylic acids, boronic acids, and mixtures thereof, and are designed to address different stabilization problems depending on the type and physical form of the detergent composition. One stabilizing approach is the use of water-soluble sources of calcium and/or magnesium ions in the finished compositions which provide such ions to the enzymes. Calcium ions are generally more effective than magnesium ions and are preferred herein if only one type of cation is being used. Typical detergent compositions, especially liquids, will comprise from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 8 to about 12 millimoles of calcium km per liter of finished detergent composition, though variation is possible depending on factors including the multiplicity, type and levels of enzymes incorporated. Preferably water-soluble calcium'or magnesium saJts are employed, including for example calcium chloride, calcium hydroxide, calcium formate, calcium malate, calcium maleate, calcium hydroxide and calcium acetate; more generally, calcium sulfate or magnesium salts corresponding to the exemplified calcium salts may be used. Further increased levels of Calcium and/or Magnesium may of course be useful, for example for promoting the grease-cutting action of certain types of surfactant. Another stabilizing approach is by use of borate species. See Severson, U.S. 4,537,706. Borate stabilizers, when used, may be at levels of up to 10% or more of the composition though more typically, levels of up to about 3% by weight of boric acid or other borate compounds such as borax or orthoborate are suitable for liquid detergent use. Substituted boric acids such as phenylboronic acid, butaneboronic acid, p-bromophenylboronic acid or the like can be used in place of boric acid and reduced levels of total boron in detergent compositions may be possible though the use of such substituted boron derivatives. Stabilizing systems of certain cleaning compositions may further comprise from 0 to about 10%, preferably from about 0.01% to about 6% by weight, of chlorine bleach scavengers, added to prevent chlorine bleach species present in many water supplies from attacking and inactivating the enzymes, especially under alkaline conditions. While chlorine levels in water may be small, typically in the range from about 0.5 ppm to about 1.75 ppm, the available chlorine in the total volume of water that comes in contact with the enzyme, for example during fabric-washing, can be relatively large; accordingly, enzyme stability to chlorine in-use is sometimes problematic. Since perborate or percarbonate, which have the ability to react with chlorine bleach, may present in certain of the instant compositions in amounts accounted for separately from the stabilizing system, the use of additional stabilizers against chlorine, may, most generally, not be essential, though improved results may be obtainable from their use. Suitable chlorine scavenger anions are widely known and readily available, and, if used, can be salts containing ammonium cations with sulfite, bisulfite, thiosulfite, thiosulfate, iodide, etc. Antioxidants such as carbamate, ascorbate, etc, organic amines such as ethylenediaminetetracetic acid (EDTA) or alkali metal salt thereof, monoethanolamine (MEA), and mixtures thereof can likewise be used, Likewise, special enzyme inhibition systems can be incorporated such that different enzymes have maximum compatibility. Other conventional scavengers such as bisulfate, nitrate, chloride, sources of hydrogen peroxide such as sodium perborate tetrahydrate, sodium perborate monohydrate and sodium percarbonate, as well as phosphate, condensed phosphate, acetate, benzoate, citrate, formate, lactate, malate, tartrate, salicylate, etc., and mixtures thereof can be used if desired. In general, since the chlorine scavenger function can be performed by ingredients separately listed under better recognized functions, (e.g., hydrogen peroxide sources), there is no absolute requirement to add a separate chlorine scavenger unless a compound performing that function to the desired extent is absent from an enzyme-containing embodiment of the invention; even then, the scavenger is added only for optimum results. Moreover, the formulator will exercise a chemist's normal skill in avoiding the use of any enzyme scavenger or stabilizer which is majorty incompatible, as formulated, with other reactive ingredients, if used. In relation to the use of ammonium salts, such salts can be simply admixed with the detergent composition but are prone to adsorb water and/or liberate ammonia during storage, Accordingly, such materials, if present, are desirably protected in a particle such as that described in US 4,652,392, Baginski et al. The compositions herein can also optionally include one or more other detergent adjunct materials or other materials for assisting or enhancing cleaning performance, treatment of the substrate to be cleaned, or to modify the aesthetics of the detergent composition (e.g., perfumes, colorants, dyes, etc.). The following are illustrative examples of such adjunct materials. Builden Detergent builders can optionally be included in the compositions herein to assist in controlling mineral hardness. Inorganic as well as organic builders can be used. Builders are typically used in fabric laundering compositions to assist in the removal of particulate soils. The level of builder can vary widely depending upon the end use of the composition and its desired physical form. When present, the compositions will typically comprise at least about 1% builder. Liquid formulations typically comprise from about 5% to about 50%, more typically about 5% to about 30%, by weight, of detergent builder. Granular formulations typically comprise from about 10% to about 80%, more typically from about 15% to about 50% by weight, of the detergent builder. Lower or higher levels of builder, however, are not meant to be excluded. Inorganic or P-containing detergent builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates (exemplified by the tripolyphosphates, pyrophosphates, and glassy polymeric meta-phosphates), phosphonates, phyiic acid, silicates, carbonates (including bicarbonates and sesquicarbonates), sulphates and aluminosilicates However, non-phosphate builders are required in some locales. Importantly, the compositions herein function surprisingly well even in the presence of the so-called 'weak" builders (as compared with phosphates) such as citrate, or in the so-called "underbuilt" situation that may occur with zeolite or layered silicate builders. Examples of silicate builders are the alkali metaJ silicates, particularly those having a SiO2:Na20 ratio in the range 1.6:1 to 3.2:1 and layered silicates, such as the layered sodium silicates described in U.S. Patent 4,664,839, issued May 12, 1987 to H. P Rieck. NaSKS-6 is the trademark for a crystalline layered silicate marketed by Hoechst (commonly abbreviated herein as "SKS-6"). Unlike zeolite builders, the Na SKS-6 silicate builder does not contain aluminum. NaSKS-6 has the delta-Na2SiO5 morphology form of layered silicate. It can be prepared by methods such as those described in German DE-A-3,4 17,649 and DE-A-3,742,043. SKS-6 is a highly preferred layered silicate for use herein, but other such layered silicates, such as those having the general formula NaMSix02x+ryH2Owherein M is sodium or hydrogen, x is a number from 1 .9 to 4, preferably 2, and y is a number from 0 to 20, preferably 0 can be used herein. Various other layered silicates from Hoechst include NaSKS-5, NaSKS-7 and NaSKS-1 1, as the alpha, beta and gamma forms. As noted above, the delta-Na2SiO5 (NaSKS-6 form) is most preferred for use herein. Other silicates may also be useful such as for example magnesium silicate, which can serve as a crisperung agent in granular formulations, as a stabilizing agent for oxygen bleaches, and as a component of suds control systems. Examples of carbonate builders are the alkaline earth and alkali metal carbonates as disclosed in German Patent Application No. 2,321,001 published on November 15, 1973. Aluminosilicate builders are useful in the present invention. Aluminosilicate builders are of great importance in most currently marketed heavy duty granular detergent compositions, and can also be a significant builder ingredient in liquid detergent formulations. Aluminosilicate builders include those having the empirical formula: Mz(zA102)y] xH20 wherein z and y are integers of at least 6, the molar ratio of z to y is in the range from 1 .0 to about 0.5, and x is an integer from about 15 to about 264. Useful aluminosilicate ion exchange materials are commercially available. These alummosilicates can be crystalline or amorphous in structure and can be naturally-occurring aluminosilicates or synthetically derived. A method for producing aluminosilicate ion exchange materials is disclosed in U.S. Patent 3,985,669, Krummel, et al, issued October 12, 1976. Preferred synthetic crystalline aluminosilicate ion exchange materials useful herein are available under the designations Zeolite A, Zeolite P (B), Zeolite MAP and Zeolite X, In an especially preferred embodiment, the crystalline aluminosilicate ion exchange material has the formula: Na12[(A102)12(Si02)12]-xH20 wherein x is from about 20 to about 30, especially about 27. This material is known as Zeolite A. Dehydrated zeolites (x - 0 - 10) may also be used herein. Preferably, the aluminosilicate has a panicle size of about 0.1-10 microns in diameter Organic detergent builders suitable for the purposes of the preser.: invention include, but are not restricted to, a wide variety of polycarboxylate compounds. AJ used herein, "polycarbcocylate" refers to compounds having a plurality of carboxylate groups, preferably at least 3 carboxylates. Polycarboxylate builder can generally be added to the composition in acid form, but can also be added in the form of a neutralized salt. When utilized in salt form, alkali metals, such as sodium, potassium, and lithium, or alkanolammonium salts are preferred. Included among the polycarboxylate builders are a variety of categories of useful materials. One important category of polycarboxylate builders encompasses the ether polycarboxylates, including oxydisuccinate, as disclosed in Berg, U.S. Patent 3,128,287, issued April 7, 1964, and Lambert! et aJ, U.S. Patent 3,635,830, issued January 18, 1972. See also "TMS/TDS" builders of U.S. Patent 4,663,071, issued to Bush et al, on May 5,1987. Suitable ether polycarboxylates also include cyclic compounds, particularly alicyclic compounds, such as those described in U.S Patents 3,923,679; 3,835,163; 4,158,635; 4,120,874 and 4,102,903. Other useful detergency builders include the ether hydroxypolycarboxylates, copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1, 3,5-trihydroxy benzene-2,4,6-trisulphonic add, and carboxymethyloxysuccinic acid, the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids such as ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well as polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and soluble salts thereof. Citrate builders, e.g., citric acid and soluble salts thereof (particularly sodium salt), are polycarboxylate builders of particular Importance for heavy duty liquid detergent formulations due to their availability from renewable resources and their biodegradability. Citrates can also be used in granular compositions, especially in combination with zeolite and/or layered silicate builders. Oxydisuccinates are also especially useful in such compositions and combinations. Also suitable in the detergent compositions of the present invention are the 3,3-dicarboxy-4-oxa-l,6-hexanedi08tes and the related compounds disclosed in U.S. Patent 4,566,984, Bush, issued January 28, 1986. Useful succinic acid builders include the C5-C20 alkyl and alkenyl succinic acids and salts thereof. A particularly preferred compound of this type is dodecenylsuccinic acid. Specific examples of succinate builders include: laurylsuccinate, myrisrylsuccinate, palmitylsuccinat?, 2-dodecenylsuccinate (preferred), 2-pentadecenylsuccinate, and the like. Laurylsuccinates are the preferred builders of this group, and are described in European Patent Application 86200690.5/0,200,263, published November 5, 1986. Other suitable polycarboxylates are disclosed in U.S. Patent 4,144,226, Crutchfield et al, issued March 13, 1979 and in U.S. Patent 3,308,067, Diehl, issued March 7, 1967. See also Diehl U.S. Patent 3,723,322. Fatty acids, eg., C12-C18 monocarboxylic acids, can also be incorporated into the compositions alone, or in combination with the aforesaid builders, especially citrate and/or the succinate builders, to provide additional builder activity. Such use of fatty acids will generally result in a diminution of sudsing, which should be taken into account by the formulator. In situations where phosphorus-based builders can be used, and especially in the formulation of bars used for hand-laundering operations, the various alkali metal phosphates such u the well-known sodium tripolyphosphates, sodium pyrophosphate and sodium orthophosphate can be used. Phosphonate builders such as ethanol-hydroxy-l,l-diphosphonate and other known phosphonates (see, for example, U.S. Patents 3,159,581; 3,213,030; 3,422,021; 3,400,148 and 3,422,137) can also be used Cheating Agents The detergent compositions herein may also optionally contain one or more iron and/or manganese chelating agents. Such chdating agents can be selected from the group consisting of amino carboxylates, amino phosphonates, polyfunctionally-substituted aromatic chelating agents and mixtures therein, all as hereinafter defined. Without intending to be bound by theory, it is believed that the benefit of theses materials U due in part to their exceptional ability to remove iron and manganese ions from washing solutions by formation of soluble chelates. Amino carboxylates useful as optional chdating agents include cthylenediaminetetracetates, N-hydroxyethylcthylenediaminetriacetatcs, nitrilo- triacetates, ethylenediamine tetraproprionates, triethylenetetraaminehexacetates, diethyienetriaminepentaacetates, diethylenetriaminepentarnethyl phosphonic acid, and ethanoldiglycmes, alkali metal, ammonium, and substituted ammonium salts therein and mixtures therein. Also suitable for use as a chelant is methylglycine di-acetic acid (MGDA) Amino phosphonates are also suitable for use as chelating agents in the compositions of the invention when at lease low levels of total phosphorus are permitted in detergent compositions, and include ethylenediarninetetrakis (methylenephosphonates) as DEQUES!. Preferred, these amino phosphonatei to not contain alkyl or alkenyl groups with more than about 6 carbon atoms. Polyfunctionally-substituted aromatic chelating agents are also useful in the compositions herein. See U.S. Patent 3,812,044, issued May 21, 1974, to Connor et al. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as l,2-dihydroxy-3,5-disuIfobenzene. A preferred biodegradable chelator for use herein is ethylenediamine disuccinate ("EDDS"), especially the [S,S] isomer as described in U.S. Patent 4,704,233, November 3, 1987, to Hartman and Perkins. If utilized, these chelating agents will generally comprise from about 0.1% to about 10% by weight of the detergent compositions herein. More preferably, ifF utilized, the chelating agents will comprise from about 0.1% to about 3.0% by weight of such compositions. Clay Soil Removal/Anti-redeposition Agents The compositions of the present invention can also optionally contain water-soluble ethoxylated amines having clay soil removal and antiredeposition properties. Granular detergent compositions which contain these compounds typically contain from about 0.01% to about 10.0% by weight of the water-soluble ethoxylates amines; liquid detergent compositions typically contain about 0.01% to about 5%. The most preferred soil release and anti-redeposition agent is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in U.S. Patent 4,597,898, VanderMeer, issued July 1,1986. Another group of preferred clay soil removal-antiredeposition agents are the cationic compounds disclosed in European Patent Application 111,965, Oh and Gosselink, published June 27,1984. Other clay soil removal/antiredeposition agents which can be used include the ethoxylated amine polymers disclosed in European Patent Application 111,981, Gosselink, published June 27,1984; the zwitterionic polymers disclosed in European Patent Application 112,592, Gosselink, published July 4, 1984, and the amine oxides disclosed in U.S. Patent 4,548,744, Connor, issued October 22, 1985. Other clay soil removal and/or anti redeposkion agents known in the art can also be utilized in the compositions herein. Another type of preferred anttredeposition agent includes the carboxy methyl cellulose (CMC) materials These materials are well known in the art, Polymeric Dispersing Agents Polymeric dispersing agents can advantageously be utilized at levels from about 0, 1% to about 7%, by weight, in the compositions herein, especially in the presence of zeolite and/or layered silicate builders. Suitable polymeric dispersing agents include polymeric polycarboxylates and polyethylene glycols, although cithers known in the an can also be used. It is believed, though it is not intended to be limited by theory, that polymeric dispersing agents enhance overall detergent builder performance, when used in combination with other builders (including lower molecular weight polycarboxylates) by crystal growth inhibition, paniculate soil release pepdzation, and anti-redeposition. Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in their acid form. Unsaturated monomeric acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid and methylenemalonic acid. The presence in the polymeric polycarboxylates herein or monomeric segments, containing no carboxylate radicals such as vinylmethyl ether, styrene, ethylene. etc. is suitable provided that such segments do not constitute more than about 40% liy weight. Particularly suitable polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers which are useful herein are the water-soluble salts of polymerized acrylic acid. The average molecular weight of such polymers in the acid form preferably rangesfrom about 2,000 to 10,000, more preferably from about 4,000 to 7,000 and most preferably from about 4,000 to 5,000, Water- soluble salts of such acrylic acid polymers can include, for example, the alkali metal, ammonium and substituted ammonium salts. Soluble polymers of this type are known materials. Use of polyacrylates of this type in detergent compositions has been disclosed, for example, in Diehl, U.S. Patent 3,308,067, issued march 7, 1967. Acrylic/maleic-based copolymers may also be used as a preferred component of the dtspersing/anti-redeposition agent. Such materials include the water-soluble salts of copolymers of acrylic acid and maleicacid. The average molecular weight of such copolymers in the acid form preferably ranges from about 2,000 to 100,000, more preferably from about 5,000 to 75,000, most preferably from about 7,000 to 65,000, The ratio of acrylate to maleate segments in such copolymers will generally range from about 30:1 to about 1:1, more preferably from about 10:1 to 2:1. Water-soluble salts of such acrylic acid/maleic acid copolymers can include, for example, the alkali metal, ammonium and substituted ammonium salts. Soluble acrylate/maloate copolymers of this type are known materials which are described in European Patent Application No. 66915, published December 15, 19S2. as well as in EP 193,360, published September 3, 1986, which also describes such polymers comprising hydroxypropylacrylate. Still other useful dispersing agents include the maleic/'acrylic/vinyl alcohol terpolymers. Such materials are also disclosed in EP 193,360, including, for example, the 45/45/10 terpolymer of acrylic/maleic/vinyl alcohol. Another polymeric material which can be included is polyethylene glycol (PEG), PEG can exhibit dispersing agent performance as well as act as a clay soil removal-antiredeposition agent. Typical molecular weight ranges for these purposes range from about 500 to about 100,000, preferably from about 1,000 to about 50,000, more preferably from about 1,500 to about 10,000. Polyaspartate and polyglutamate dispersing agents may also be used, especially in conjunction with zeolite builders. Dispersing agents such as polyaspartate preferably have a molecular weight (avg) of about 10,000. Brightener Any optical brighteners or other brightening or whitening agents known in the art can be incorporated at levels typically from about 0.05% to about 1,2%, by weight, into the detergent compositions herein. Commercial optical brighteners which may be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiphene-5,5-dioxide, azoles, 5-and 6-membered-ring heterocycles, and other miscellaneous agents. Examples of such brighteners are disclosed in "The Production and Application of Fluorescent Brightening Agents", M. Zahradnik, Published by John Wiley & Sons, New York (1982). Specific examples of optical brighteners which are useful in the present compositions are those identified in U.S. Patent 4,790,856, issued to Wixon on December 13,1988. These brighteners include the PHORWHITE series of brighteners from Verona. Other brighteners disclosed in this reference include: Tinopal UNPA, Tinopal CBS and Tinopal 5BM; available from Ciba-Geigy; Artie White CC and Artie White CWD, available from Hilton-Davis, located in Italy, the 2-(4-stryl-phenyl)-2H-napthol[l,2-d]triazoles; 4,4'-bis- (l,2,3-triazol-2-yl)-stil. benes; 4,4'-bis(stryl)bisphenyls, and the aminocoumants. Specific examples of these brighteners include 4.methyl-7-diethyl~ amino coumarin; J ,2-bis(-venzimidazol-2-yl)ethylene; 1,3-diphenyl-phrazolines; 2,5-bis(benzoxazol-2-yl)thiophene; 2-stryl-napth-[ 1,2-d]oxazole; and 2-(stilbene-4-yl)-2H-naphtho- [ 1,2-d]triazole. See also U.S. Patent 3,646,015, issued February 29, 1972 to Hamilton. Anionic brighteners are preferred herein. Suds Suppressors Compounds for reducing or suppressing the formation of suds can be incorporated into the compositions of the present invention. Suds suppression can be of particular importance in the so-called "high concentration cleaning process" as described in U.S, 4,489,455 and 4,489,574 ar.d in front-loading European-style washing machines. A wide variety of materials may be used as suds suppressors, and suds suppressors are well known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979). One category of suds suppressor of particular interest encompasses monocarboxylic fatty acid and soluble salts therein. See U.S. Patent 2,954,347, issued September 27, 1960 to Wayne St. John. The monocarboxylic fatty acids and salts thereof used as suds suppressor typically have hydrocarbyl chains of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include the alkali metal salts such as sodium, potassium, and lithium salts, and ammonium and alkanolammonium salts. The detergent compositions herein may also contain non-surfactant suds suppressors. These include, for example: high molecular weight hydrocarbons such as paraffin, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monovanient alcohols, aliphatic C18-C40 ketones (e.g., stearone), etc. Other suds inhibitors include N-alkylated amino triazines such as tri- to hexa-alkylmelamines or di- to tetra-alkyldiarnine chlortriazines formed as products of cyanuric chloride with two or three moles of a primary or secondary amine containing 1 to 24 carbon atoms, propylene oxide, and monostearyl phosphates such as monostearyl alcohol phosphate ester and monostearyl di-alkali metal (e.g., K, Na, and Li) phosphates and phosphate esters. The hydrocarbons such as paraffin and haloparaffin can be utilized in liquid form. The liquid hydrocarbons will be liquid at room temperature and atmospheric pressure, and will have a pour point in the range of about -40°C and about 50°C, and a minimum boiling point not less than about 110°C (atmospheric pressure). It is also known to utilize waxy hydrocarbons, preferably having a melting point below about 100°C. The hydrocarbons constitute a preferred category of suds suppressor for detergent compositions. Hydrocarbon suds suppressors are described, for example, in U.S. Patent 4,265,779, issued May 5, 1981 to Gandolfo et al. The hydrocarbons, thus, include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsatur?.ted hydrocarbons having from about 12 to about 70 carbon atoms. The term "paraffin," as used in this suds suppressor discussion, is intended to include mixtures of true paraffins and cyclic hydrocarbons. Another preferred category of non-surfactant suds suppressors comprises silicone suds suppressors. This category includes the use of polyorganosiloxane oils, such as polydimethylsiloxane, dispersions or emulsions of polyorganosiioxane oils or resins, and combinations of polyorganosiloxane with silica particles wherein the polyorganosiloxane is chemisorbed or fused onto the silica. Silicone suds suppressors are well known in the art and are, for example, disclosed in U.S. Patent 4,265,779, issued May 5, 1981 to Gandolfo et al and European Patent Application No, 89307851.9, published February 7, 1990, by Starch, M. S. Other silicone suds suppressors are disclosed in U.S. Patent 3,455,839 which relates to compositions and processes for defoaming aqueous solutions by incorporating therein small amounts of polydimethylsiloxane fluids. Mixtures of silicone and silanated silica are described, for instance, in German Patent Application DOS 2,124,526. Silicone defoamers and suds controlling agents in granular detergent compositions are disclosed in U.S. Patent 3,933,672, Bartolotta et al, and in U.S. Patent 4,652,392, Baginski ct al, issued March 24, 1987. An exemplary silicone based suds suppressor for use herein is »suds suppressing amount of a suds controlling agent consisting essentially of: (i) polydimethylsiloxane fluid having a viscosity of from about 20 cs. to about 1,500 cs. at 25°C; (ii) from about 5 to about 50 parts per 100 parts by weight of (i) of siloxane resin composed of (CH3)3 SiO1/2 units of SO2 units in a ratio of from (CH3)3 SiO1/2 units and to SiO2 units of from about 0.6:1 to about 1.2:1; and (iii) from about 1 to about 20 parts per 100 parts by weight of (i) of a solid silica gel. In the preferred silicone suds suppressor used herein, the solvent for a continuous phase is made up of certain polyethylene glycols or polyethylene-polypropylene glycol copolymers or mixtures thereof (preferred), or polypropylene glycol. The primary silicone suds suppressor is branched/crosslinked and preferably not linear. To illustrate this point further, typical liquid laundry detergent compositions with controlled suds will optionally comprise from about 0.001 to about 1, preferably from about 0.01 to about 0.7, most preferably from about 0.05 to about 0.5, weight % of said silicone suds suppressor, which comprises (1) a nonaqueous emulsion of a primary antifoam agent which is a mixture of (a) a polyorganosiloxane, (b) a resinous siloxane or a silicone resin-producing silicone compound, (c) a finely divided filler material, and (d) a catalyst to promote the reaction of mixture components (a), (b) and (c), to form stlanolates; (2) at least one nonionic silicone surfactant; and (3) polyethylene glycol or a copolymer of polyethylene-polypropylene glycol having a solubility in water at room temperature of more than about 2 weight %; and without polypropylene glycol. Similar amounts can be used in granular compositions, gels, etc. Sec also U.S. Patents 4,978,471, Starch, issued December 18, 1990, and 4,983,316, Starch, issued January 8, 1991, 5,288,431, Huberet al., issued February 22, 1994, and U.S. Patents 4,639,489 and 4,749,740, Aizawa et al at column 1, line 46 through column 4, line 35. The silicone suds suppressor herein preferably comprises polyethylene glycol and a copolymer of polyethylene glycol/potypropylene glycol, all having an average molecular weight of less than about 1,000, preferably between about 100 and 800. The polyethylene glycol and polyethylene/polypropylene copolymers herein have a solubility in water at room temperature of more than about 2 weight %, preferably more than about 5 weight %, The preferred solvent herein is polyethylene glycol having an avenge molecular weight of less than about 1,000, more preferably between about 100 and 800, most preferably between 200 and 400, and a copolymer of polyethylene glycol/polypropylene glycol, preferably PPG 200/PEG 300. Preferred is a weight ratio of between about 1:1 and 1:10, most preferably between 1:3 and 1:6, of polyethylene glycol:copolymer of polyethylene-polypropylene glycol. The preferred silicone suds suppressors used herein do not contain polypropylene glycol, particularly of 4,000 molecular weight. They also preferably do not contain block copolymers of ethylene oxide and propylene oxide, like PLURON1CL101. Other suds suppressors useful herein comprise the secondary alcohols (e.g., 2-alkyi alkanols) and mixtures of such alcohols with silicone oils, such as the silicones disclosed in U.S. 4,798,679,4,075,118 and EP 150,872. The secondary alcohols include the C6-C16 alkyl alcohols having a C1-C16 chain. A preferred alcohol is 2-butyl octanol, which is available from Condea under the trademark ISOFOL1 2. Mixtures of secondary alcohols are available under the trademark ISALCHEM 123 from Enichem Mixed suds suppressors typically comprise mixtures of alcohol + silicons at a weight ratio of 1:5 to 5:1. For any detergent compositions to be used in automatic laundry washing machines, suds should not form to the extent that they overflow the washing machine. Suds suppressors, when utilized, are preferably present in a "suds suppressing amount. By "suds" suppressing amount" is meant that the formulator of the composition can select an amount of this suds controlling agent that will sufficiently control the suds to result in a low-sudsing laundry detergent for use in automatic laundry washing machines. The compositions herein will generally comprise from 0% to about 5% of suds suppressor. When utilized as suds suppressors, monocarboxylic fatty acids, and salts therein, will be present typically in amounts up to about 5%, by weight, of the detergent composition. Preferably, from about 0.5% to about 3% of fatty monocarboxylate suds suppressor is utilized. Silicone suds suppressors are typically utilized in amounts up to about 2.0%, by weight, of the detergent composition, although higher amounts may be used. This upper limit is practical in nature, due primarily to concern with keeping costs minimized and effectiveness of lower amounts for effectively controlling sudsing. Preferably from about 0.01% to about 1% of silicone suds suppressor is used, more preferably from about 0.25% to about 0.5%. As used herein, these weight percentage values include any silica that may be utilized in combination with polyorganosiloxane, as well as any adjunct materials that may be utilized. Monostearyl phosphate suds suppressors are generally utilized in amounts ranging from about 0.1% to about 2%, by weight, of the composition. Hydrocarbon suds suppressors are typically utilized in amounts ranging from about 0.01% to about 5,0%, although higher levels can be used. The alcohol suds suppressors are typically used at 0.2%-3% by weight of the finished compositions. Fabric Softeners Various through-the-wash fabric softeners, especially the impalpable smectite clays of U.S. Patent 4,062,647, Storm and Nirschl, issued December 13, 1977, as well as other softener clays known in the art, can optionally be used typically at levels of from about 0.5% to about 10% by weight in the present compositions to provide fabric softener benefits concurrently with fabric cleaning. Clay softeners can be used in combination with amine and cationic softeners as disclosed, for example, in U.S. Patent 4,375,416, Crisp et al, March 1, 1983 and U.S. Patent 4,291,071, Harris et al, issued September 22, 1981. Dye Transfer Inhibiting Agents -The compositions of the present invention may also include one or more materials effective for inhibiting the transfer of dyes from one fabric to another during the cleaning process. Generally, such dye transfer inhibiting agents include polyvinyl pyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidases, and mixtures thereof, If used, these agents typically comprise from about 0.01% to-about 10% by weight of the composition, preferably from about 0.01% to about 5%, and more preferably from about 0.05% to about 2%. More specifically, the polyamine N-oxide polymers preferred for use herein contain units having the following structural formula: R-AX-P; wherein P is a polymerizable unit to which an N-0 group can be attached or the N-0 group can form pan of the polymerizable unit or the N-0 group can be attached to both units; A is one of the following structures: -NC(0)-, -C(0)0-, -S-,-0-, -N-; x is 0 or 1 ; and R is aliphatic, ethoxylated aliphatics, aromatics, heterocyclic or alicyclic groups or any combination thereof to which the nitrogen of the N-0 group can be attached or the N-0 group is part of these groups. Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyridine, pyrrole, imidazole, pyrrolidine, piperidine and derivatives thereof. The N-O group can be represented by the following general structures (Formula Removed) wherein R1, R2, R3 Are aliphatic, aromatic, heterocyclic or alicyclic groups or combinations thereof, x, y and z are 0 or 1; and the nitrogen of the N-0 group can be attached or form part of any of the aforementioned groups. The amine oxide unit of the poLyamine N-oxides has a pKa Any polymer backbone can be used as long as the amine oxide poryme' formed IS water-soluble and has dye transfer inhibiting properties. Examples of suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, poryamide, polyimides, poryacrylates and mixtures thereof. These polymers include random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide. The amine N-oxide polymers typically have a ratio of amine to the amine N-oxide of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or by an appropriate degree of N-oxidation. The polyamine oxides can be obtained in almost any degree of polymerization. Typically, the average molecular weight is within the range of 500 to 1,000,000; more preferred 1,000 to 500,000; most preferred 5,000 to 100,000. This preferred class of materials can be referred to as "PVNO". The most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) which as an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4. Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (referred to as a class as "PVPVI") are also preferred for use herein. Preferably the PVPVI has an average molecular weight range from 5,000 to 1,000,000, more preferably from 5,000 to 200,000, and most preferably from 10,000 to 20,000. (The average molecular weight range is determined by light scattering as described in Barth, et ali., Chemical Analysis, Vol 113. "Modern Methods of Polymer Characterization", the disclosures of which are incorporated herein by reference.) The PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone from 1:1 to 0.2:1, more preferably from 0.8:1 to 0.3:1, most preferably from 0.6:1 to 0.4:1. These copolymers can be either linear or branched. The present invention compositions also may employ a polyvinylpyrrolidone ("PVP") having an average molecular weight of from about 5,000 to about 400,000, preferably from about 5,000 to about 200,000, and more preferably from about 5,000 to about 50,000. PVP's are known to persons skilled in the detergent fidd; sec, for example, EP-A-262,897 and EP-A-256,696, incorporated herein by reference. Compositions containing PVP can also contain polyethylene glycol ("PEG") hiving an average molecular weight from about 500 to about 100,000, preferably from about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP on a ppm basis delivered in wash solutions is from about 2:1 to about 50:1, and more preferably from about 31 to about 10,1. The detergent compositions herein may also optionally contain from about 0.005% to 5% by weight of certain types of hydrophilic optical brighteners wluch also provide a dye transfer inhibition action. If used, the compositions herein will preferably comprise from about 0.01V% to 1% by weight of such optical brighteners. The hydrophilic optical brighteners useful in the present invention are those having the structural formula: (Formula Removed) wherein R1 is selected from anilino, N-2-bis-hydroxyethyl and NK-2-hydroxyeihyl; R2 is selected from N-2-bis-hydroxyethyl, N-2-hydroxyethyl-N-methylarnino, morphilino, chloro and amino; and M is a salt-forming cation such as sodium 01 potassium. When in the above formula, R1 is anilino, R2 is N-2-bis-hydroxyethyl and M is a cation such as sodium, the brightener is 4,4',-bis[(4-3rulino-6-(N-2-bis-hydroxyethyl)-s-triazine-2-yl)amino]-2,2'-sulbenedisulforuc acid and disodium salt. This particular brightener species is commercially marketed under the tradenaitie Tinopal-UNPA-GX by Ciba-Geigy Corporation. Tinopal-UNPA-GX is the preferred hydrophilic optical brightener useful in the detergent compositions herein. When in the above formula, R1 is anilino, R2 is N-2-hydroxyethyl-N-2-methylamino and M is a cation such as sodium, the brightener is 4,4'-bis[(4.-anilino-6-(N-2-hydroxyethyl"N-methylarruno)-s-triazine-2-yl)amino]2,2'-sti;benedisulfonic acid disodium salt. This particular brightener species is commercially marketed under the tradename Tinopal 5BM-GX by Ciba-Gtigy Corporation. When in the above formula, R1 is anilino, R2 is morphilino and M is a cation such as sodium, the brightener is 4,4'-bis[(4-anilino-6-morprulino-s-triazine-2-yl)amino]2,2'-stilbenedisulfonic acid, sodium salt. This particular brightener species is commercially marketed under the tradename Tinopal AMS-GX by Ciba Geigy Corporation. The specific optical brightener species selected for use in the present invention provide especially effective dye transfer inhibition performance benefits when used in combination with the selected polymeric dye transfer inhibiting agents hereinbefore described. The combination of such selected polymeric materials (e.g., PVNO and/or PVPVI) with such selected optical brighteners (e.g., Tinopal UNPA-GX, Tinopal 5BM-GX and/or Tinopal AMS-GX) provides significantly better dye transfer inhibition in aqueous wash solutions than does either of these two detergent composition components when used alone. Without being bound by theory, it is believed that such brighteners work this way because they have high affinity for fabrics in the wash solution and therefore deposit relatively quick on these fabrics. The extent to which brighteners deposit on fabrics in the wash solution can be defined by a parameter called the "exhaustion coefficient". The exhaustion coefficient is in general as the ratio of a) the brightener material deposited on fabric to b) the initial brightener concentration in the wash liquor. Brighteners with relatively high exhaustion coefficients are the most suitable for inhibiting dye transfer in the context of the present invention. Of course, it will be appreciated that other, conventional optical brightener types of compounds can optionally be used in the present compositions to provide conventional fabric "brightness" benefits, rather than a true dye transfer inhibiting effect. Such usage is conventional and well-known to detergent formulations. The modified polyamines of the present invention useful as cotton soil release agents are suitably prepared by the following methods. EXAMPLE1 Preparation of PHI 1800 E7 The ethoxylation is conducted in a 2 gallon stirred stainless steel autoclave equipped for temperature measurement and control, pressure measurement, vacuum and inert gas purging, sampling, and for introduction of ethylene oxide as a liquid. A -20 tb. net cylinder of ethylene oxide (ARC) is set up to deliver ethylene oxide as a liquid by a pump to the autoclave with the cylinder placed on a scale so that the weight change of the cylinder could be monitored. A 750 g portion of polyethyieneimine (PET) (Nippon Shokubal, Epomin SP-018 having a listed average molecular weight of 1800 equating to about 0.417 moles of polymer and 17.4 moles of nitrogen functions) is added to the autoclave. The autoclave is then sealed and purged of air (by applying vacuum to minus 28" Hg followed by pressurization with nitrogen to 250 psia, then venting to atmospheric pressure) The autoclave contents are heated to 130 °C while applying vacuum. After about one hour, the autoclave is charged with nitrogen to about 250 psia while cooling the autoclave to about 105 °C. Ethylene oxide is then added to the autoclave incrementally over time while dosely monitoring the autoclave pressure, temperature, and ethylene oxide flow rate. The ethylene oxide pump is turned off and cooling is applied to limit my temperature increase resulting from any reaction exotherm. The temperature is maintained between 100 and 110°C while the total pressure it-allowed to gradually increase during the course of the reaction. After a total of 750 grams of ethylene oxide has been charged to the autoclave (roughly equivalent to one mole ethylene oxide per PEI nitrogen function), the temperature is increased to 110 ° C and the autoclave is allowed to stir for an additional hour. At this point, vacuum is applied to remove any residual unreacted ethylene oxide. Next, vacuum is continuously applied while the autoclave is cooled to about 50 °C while introducing 376 g of a 25% sodium methoxide in methanol solution (1.74 moles, to achieve a 10% catalyst loading based upon PEI nitrogen functions). The methoxide solution is sucked into the autoclave under vacuum and then the autoclave temperature controller setpoint is increased to 130 °C. A device is used to monitor the power consumed by the agitator. The agitator power is monitored along with the temperature and pressure Agitator power and temperature values gradually increase as methane 1 is removed from the autoclave and the viscosity of the mixture increases and stabilizes in about 1 hour indicating that most of the methanol has been removed. The mixture is further heated and agitated under vacuum for an additional 30 minutes. Vacuum is removed and the autoclave is cooled to 105 °C while it is being charged with nitrogen to 250 psia and then vented to ambient pressure. The autoclave is charged to 200 psia with nitrogen. Ethylene oxide is again added to the autoclave incrementally as before while closely monitoring the autoclave pressure, temperature, and ethylene oxide flow rate while maintaining the temperature between 100 and 130 °C and limiting any temperature increases due to reaction exotherm. After the addition of 4500 g of ethylene oxide (resulting in a total of 7 moles of ethylene oxide per mole of PEI nitrogen function) is achieved over several hours, the temperature is increased to 110 °C and the mixture stirred for an additional hour. The reaction mixture is then collected in nitrogen purged containers and eventually transferred into a 22 L three neck round bottomed flask equipped with heating and agitation. The strong alkali catalyst is neutralized by adding 167 g methanesulfonic acid (1.74 moles). The reaction mixture is then deodorized by passing about 100 cu. ft. of inert gas (argon or nitrogen) through a gas dispersion frit and through the reaction mixture while agitating and heating the mixture to 130 °C. The final reaction product is cooled slightly and collected in glass containers purged with nitrogen. In other preparations the neutralization and deodorization is accomplished in the reactor before discharging the product. EXAMPLE 2 4.7% Quaternization of PEI 1800 E7 To a 500ml erlenmeyer flask equipped with a magnetic stirring bar is added polyethyleneimine), MW 1800 ethoxylated to a decree of 7 (224g, 0.637 mol nitrogen, prepared as in Example 1) and acetonitrile (Baker, 150g, 3,65 mol). Dimethyl sulfate (Aldrich, 3.8g, 0.030 mol) is added all at once to the rapidly stirring solution, which is then stoppered and stirred at room temperature overnight. The acetonitrile it evaporated on the rotary evaporator at ~60°C, followed by a Kugelrohr apparatus (Aldrich) at ~80°C to afford ~220g of the desired material as a dark brown viscous liquid. A 13C-NMR (D20) spectrum shows the absence of a peak at ~58ppm corresponding to dimethyl sulfate. A 1H-NMR (D2O) spectrum shows the partial shifting of the peak at 2.5ppm (methylenes attached to unquaternized nitrogens) to ~3.0ppm. EXAMPLE 3 Oxidation of 4.7% Ouaternized PEI 1800 E7 To a 500ml erlenmeyer flask equipped with a magnetic stirring bar is added poly(ethylenelmine), MW 1800 which has been ethoxylated to a degree of 7, and -4,7% quaternized with dimethyl sulfate (121.7g, -0.32 mol oxid'izeable nitrogen, prepared as in Example 3), hydrogen peroxide (AJdrich, 40g of a SO wt% solution in. water, 0 588 mol), and water (109.4g). The flask is stoppered, and after an initial exotherm the solution is stirred at room temperature overnight. A1H-NMR (D2O) spectrum shows the total shining of the methylene peaks at 2.5-3.0ppm to -3.5ppm., To the solution is added ~5g of 05% Pd on alumina pellets, and the solution is allowed to stand at room temperature for -3 days. Peroxide indicator paper shows that no peroxide is left in the system. The material is stored as a 46.5% solution in water. EXAMPLE 4 Formation of amine oxide of PEI 1800 E7 To a 500 mL Erlenmeyer flask equipped with a magnetic stirring bar is added polyethyleneimine having a molecular weight of 1800 and ethoxylated to a degree ocf about 7 ethoxy groups per nitrogen (PEI-1800, E7) (209 g, 0.595 mol nitrogen, prepared as in Example I), and hydrogen peroxide (120 g of a 30 wt % solution in water, 1.06 mol). The flask is stoppered, and after an initial exotherm the solution is stirred at room temperature overnight. 1H-NMR (D20) spectrum obtained on a sample of the reaction mixture indicates complete conversion. The resonances ascribed to methylene protons adjacent to unoxidized nitrogens have shifted fr om the original position at ~2.5 ppm to -3.5 ppm. To the reaction solution is added approximately 5 g of 0.5% Pd on alumina pellets, and.the solution is allowed to stand at room temperature for approximately 3 days. The solution is tested and found to be negative for peroxide by indicator paper. The material as obtained is suitably stored as 151.1% active solution in water. EXAMPLE5 Preparation pf PEI 1200 E7 The ethoxylation is conducted in a 2 gallon stirred stainless steel autoclave equipped for temperature measurement and control, pressure measurement, vacuum and inert gas purging, sampling, and for introduction of ethylene oxide as a liquid. A -20 1b. net cylinder of ethylene oxide (ARC) is set up to deliver ethylene oxide as & liquid by a pump to the autoclave with the cylinder placed on a scale so that the weight change of the cylinder could be monitored. A 750 g portion of polyethyleneimine (PEI) ( having a listed average molecular weight of 1200 equating to about 0.625 moles of polymer and 17.4 moles of nitrogen functions) is added to the autoclave. The autoclave is then sealed and purged of air (by applying vacuum to minus 28" Hg followed by pressurization with nitrogen to 250 psia, then venting to atmospheric pressure), The autoclave contents are heated to 130 °C while applying vacuum. After about one hour, the autoclave is charged with nitrogen to about 250 psia while cooling the autoclave to about 105 °C Ethylene oxide is then added to the autoclave incrementally over time while closely monitoring the autoclave pressure, temperature, and ethylene oxide flow rate. The ethylene oxide pump is turned off and cooling is applied to limit any temperature increase resulting from any reaction exotherm. The temperature is maintained between 100 and 110 °C while the total pressure is allowed to gradually increase during the course of the reaction. After a total of 750 grams of ethylene oxide has been charged to the autoclave (roughly equivalent to one mole ethylene oxide per PEI nitrogen function), the temperature is increased to 110 °C and the autoclave is allowed to stir for an additional hour. At this point, vacuum is applied to remove any residual unreacted ethylene oxide. Next, vacuum is continuously applied while the autoclave is cooled to about 50 °C while introducing 376 g of a 25% sodium methoxide in methanol solution (1.74 moles, to achieve a 10% catalyst loading based upon PEI nitrogen functions). The methoxide solution is sucked into the autoclave under vacuum and then the autoclave temperature controller setpoint is increased to 130 °C. A device is used to monitor the power consumed by the agitator. The agitator power is monitored along with the temperature and pressure. Agitator power and temperature values gradually increase as methanol is removed from the autoclave and the viscosity of the mixture increases and stabilizes in about 1 hour indicating that most of the methanol has been removed. The mixture is further heated and agitated under vacuum for an additional 30 minutes, Vacuum is removed and the autoclave is cooled to 105 °C while h is being charged with nitrogen to 250 psia and then vented to ambient pressure. The autoclave is charged to 200 psia with nitrogen. Ethylene oxide is again added to tl autoclave incrementally as before while closely monitoring the autoclave pressur temperature, and ethylene oxide flow rate while maintaining the temperature ben 100 and 110 °C and limiting any temperature increases due to reaction exo After the addition of 4500 g of ethylene oxide (resulting in a total of 7 ethylene oxide per mole of PEI nitrogen function) is achieved over seve temperature is increased to 110 °C and the mixture stirred for an addti The reaction mixture is then collected in nitrogen purged containers and eventually transferred into a 22 L three neck round bottomed flask equipped with heating and agitation. The strong alkali catalyst is neutralized by adding 157 g methanesulfonic acid (1.74 moles). The reaction mixture is then deodorized by passing about 100 cu, ft. of inert gas (argon or nitrogen) through a gas dispersion frit and through ths reaction mixture while agitating and heating the mixture to 130 °C. The final reaction product is cooled slightly and collected in glass containers purged with nitrogen, In other preparations the neutralization and deodorizanon is accomplished in the reactor before discharging the product. EXAMPLE 6 9,7% Ouaterrmization of PEI 1200 E7 To a 500ml erlenmeyer flask equipped with a magnetic stirring bar is added poly(ethyleneimine), MW 1200 ethoxylated to a degree of 7 (248.4g, 0.707 mol nitrogen, prepared as in Example 5) and acetonitrile (Baker, 200 mL). Dimethyl sulfate (Aldrich, 8.48g, 0.067 mol) is added all at once to the rapidly stirring solution, which is then stoppered and stirred at room temperature overnight. The acetonitrile is evaporated on the rotary evaporator at ~60°C, followed by a Kugelrohr apparatus (Aldrich) at ~80°C to afford ~220g of the desired material as a dark brown viscous liquid. A 13C-NMR (D20) spectrum shows the absence of a peak at ~58ppm corresponding to dimethyl sulfate. A 1H-MMR (D20) spectrum shows the partial shifting of the peak at 2.5ppm (methylenes attached to unquatemized nitrogens) to ~3.0ppm. EXAMPLE7 4.7% Oxidation of 9.5% Ouatenized PEI 1200 E7 To • 500ml erlenmeyer flask equipped with a magnetic stirring bar is added poly(ethyleneimine), MW 1200 which has been ethoxylated to i degree of 7, and -9.5% quaternized with dimethyl sulfate (144g, ~0.37 mol oxidizeable nitrogen, prepared as in Example 6), hydrogen peroxide (Aldrich, 35.4g of a 50 wt% solution in water, 0,52 mol), and water (lOOg). The flask is stoppered, and after an initial exotherm the solution is stirred at room temperature overnight. A 1H-NMR (D2O)) spectrum shows the total shifting of the methylene peaks at 2.5-3.0ppm to ~3.5ppm. To the solution is added just enough sodium bisulfite as a 40% water solution to bring the residual peroxide level down to l-5ppm. The sodium sulfate which forms causes an aqueous phase to separate which contains salts, but little or no organics The aqueous salt phase is removed and the desired oxidized polyethyleneimine derivative is obtained and stored as a 52% solution in water. EXAMPLE8 Preparation of Non-cotton Soil Release Polymers Synthesis of Sodium 2-(2.3.Dihydroxypropoxy)ethanesulfonate Monomer To a 500ml, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, ind temperature controller (Therm-O-WatchTM, I2R) is added isethionic acid, sodium salt (Aldrich, 50.0g, 0.338 mol), sodium hydroxide (2.7g, 0.0675 mol), and glycerin (Baker, 310.9g, 3.38 mol). The solution is heated at 190°C under argon overnight as water distills from the reaction mixture. A 13C-NMR(DMSO-d6) shows that the reaction is complete by the virtual disappearance of the isethionate peaks at -53.5 ppm and -57,4 ppm, and the emergence of product peaks at ~51.4 ppm (-CH2SO3Na) and C7.5 ppm (CH2CH2S03Na). The solution is cooled to~100°C and neutralized to pH 7 with methanesulfonic acid (Aldrich). The desired n« t material is obtained by adding 0.8 mol% of potassium phosphate, monobasic as buffer and heating on a Kugelrohr apparatus (Aldrich) at 200°C for - 3 hn. at -1 mm Hg to afford 77g of yellow waxy solid. As an alternative, not all of the glycerin is removed before use in making the oligomers. The use of glycerin solutions of SEG can be a convenient way of handling this sulfonated monomer. EXAMPLE 9 Synthesis of Sodium 2-[2-(2-Hydroxyethoxy)ethoxy1ethancsulfonate Monomer To a 1L, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, and temperature controller (Therm-O-Watch™, I2R) is added isethionic acid, sodium salt (Aldrich, l00.0g, 0.675 mol) and distilled water (-90 ml). After dissolution, one drop of hydrogen peroxide (Aldrich, 30% by wt. in water) is added to oxidize traces of bisulfite. The solution is stirred for one hour. A peroxide indicator strip shows a very weak positive test. Sodium hydroxide pellets (MCB, 2.5g, 0.0625 moi) we added, followed by diethylene glycol (Fisher, 303.3g, 2,86 mol). The solution is heated at 190C° under argon overnight as water distills from the reaction mixture. A 13C-NMR(DMSO-d6) shows that the reaction is complete by the disappearance of the isethionate peaks at -53.5 ppm and -57.4 ppm. The solution is cooled to room temperature and neutralized to pH 7 with 57.4g of a 16.4% solution of p-toluenesulfonic acid monohydrate in diethylene glycol. (Alternatively, methanesulfonic acid may be used.) The 13C-NMR spectrum of the product shows resonances at -51 ppm (-CH2SO3Na), ~60ppm (-CH2OH), and at -69 ppm, -72 ppm, and -77 ppm for the remaining four methylenes. Small resonances are also visible for the sodium p-toluenesulfonate which formed during neutralization. The reaction affords 45 Ig of a 35,3% solution of sodium 2-[2-(2-hydroxyethoxy)ethoxy]ethanesulfonate in diethylene glycol. The excess diethylene glycol is removed by adding 0.8 mo!% of monobasic potassium phosphate (Aldrich) as a buffer ajid heating on a Kugelrohr apparatus (Aldrich) at 150C° for ~ 3 hrs. at -I mm Fig to give the desired "SE3" (as defined herein above) as an extremely viscous oil or glass. EXAMPLE 10 Synthesis of Sodium 2-(2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy}ethanesulfonate Monomer To a 1L, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, and temperature controller (Therm-0-Watch™, I2R) is added isethionic acid, sodium salt (Aldrich, 205.0g, 1.38 mol) and distilled water (-200 ml). After dissolution, one drop of hydrogen peroxide (Aldrich, 30% by wt, in water) is added to oxidize traces of bisulfite The solution is stirred for one hour. A peroxide indicator strip shows a very weak positive test. Sodium hydroxide pellets (MCB, 5.5g, 0.138 mol) are added, followed by triethylene glycol (Aldrich, 448.7g, 3.0 mol). Optionally, the triethylene glycol can be purified by heating with strong base such as NaOH until color stabilizes and then distilling off the purified glycol for use in the synthesis. The solution is heated at 190C° under argon overnight as water distills from the reaction mixture. A 13C-NMR(DMSO-d6) shows that the reaction is complete by the disappearance of the isethionate peaks at -53.5 ppm and ~57.4 ppm, and the emergence of product peaks at ~5lppm (-CH2SO3Na), ~60ppm (-CH2OH), and at ~67 ppm, -69 ppm, and ~72 ppm for the remaining methylenes. The solution is cooled to room temperature and neutralized to pH 7 with methanesulfonic acid (Aldrich). The reaction affords 650g of a 59.5% solution of sodium 2-{2-[2-(2-hydroxyethoxy)ethoxy]ethoxy}ethanesulfonate in triethylene glycol. The excess triethylene glycol is removed by adding 0.8 mol% of monobasic potassium phosphate (Aldrich) is a buffer and heating on a Kugelohr apparatus (Aldrich) at 180C° for -5.5 hrs. at -1 mm Hg to give the desired material as a brown solid. It is found that a more soluble buffer can be more effective in controlling pH during the stripping of excess triethylene glycol. One example of such a more soluble buffer is the salt of N-methylmorpholine with methanesulfonic add. Alternatively, the pH can be controlled by frequent or continuous addition of acid such as methanesulfonic add to maintain a pH near neutral during the stripping of excess glycol. The material is believed to contain a low level of the disulfonate arising from reaction of both ends of the triethylene glycol with isethionate. However, the crude material is used without further purification as an anionic capping groups for polymer preparations Other preparations use a larger excess of triethviene glycol such as 5 to 10 moles per mole of isethionate. EXAMPLE 11 Synthesis of an Oligomer of Sodium 2-[2-(2-Hydroxtethoxy)ethoxyethanesulfonate. Dimethyl Tereohthalatc. Sodium 2.(2.3-Dihydroxypropoxy)ethanesulfonate, Glycerin. Ethylene Glycol. and Propylene Glycol) To a 250ml, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, and temperature controller (Therm-O-Watch®, I2R) is added sodium 2.-[2-{2-hydroxyethoxy)ethoxy]ethanesulfonate (7.0g, 0.030 mol), dimethyl terephthalate (14.4g, 0,074 mol), sodium 2-(2,3-dihydroxypropoxy)ethanesulfonate (3.3g, 0.015 mol), glycerin (Baker, 1.4g, 0.015 mol), ethylene glycol (Baker, 14.0g, 0.225 mol), propylene glycol (Fisher, 17.5g, 0.230 mol), and titanium (IV) propoxide (O.Olg, 0.02% of total reaction weight). This mixture is heated to 180°C and maintained at that temperature overnight under argon as methanol and water distill from the reaction vessel The material is transferred to a 500ml, single neck, round bottom flask and heated gradually over about 20 minutes to 240°C in a Kugelrohr apparatus (Aldrich) at about 2 mm Hg and maintained there for 1.5 hours. The reaction flask is then allowed to air cool quite rapidly to near room temperature under vacuum (-30 min.) The reaction affords 21.3g of the desired oligomer as a brown glass, A 13C-NMR(DMSO-d6) shows a resonance for -C(0)0CH2CH20(0)C- at -63,2 ppm (diester) and a resonance for -C(0)0CH2CH20H at -59.4 ppm (monoester). The ratio of the diester peak height to the monoester peak height is about 10. Resonances at -51,5 ppm and -51.6 ppm representing the sulfoethoxy groups (-CH2S03Na) are also present. A lH-NMR(DMSO-d6) shows a resonance at -7.9 ppm representing terephthalate aromatic hydrogens. Analysis by hydrolysis-gas chromatography shows that the mole ratio of incorporated ethylene glycol to incorporated propylene glycol is 1.7:1. It also shows thai about 0.9% of the final polymer weight consists of glycerin. If all glycerin monomer has been incorporated as esters of glycerin, it would represent approximately 4% of final oligomer weight. The solubility is tested by weighing a small amount of material into a vial, adding enough distilled water to make a 35% by weight solution, and agitating the vial vigorously. The material is readily soluble under these conditions. EXAMPLE 12 Synthesis of an Oligomer of Sodium 2-[2-( 2.Hydroxyethoxy)ethoxy]ethanesulfonate Dimethyl Terephthalate. Sodium 2-(2,2-Dihydroxypropoy)ethanesu!fonate, Ethylene Glycol. and Propylene Glycol) To a 250ml, three neck, round bottom flask equipped with a magnetic stirring bar, modified ClaJsen head, condenser (set for distillation), thermometer, and temperature controller (Therm-0-Watch®, I2R) is added sodium 2-[2-(2-hydroxyethoxy)ethoxyjethanesulfonate (7.0g, 0.030 mol), dimethyl terephthalate (14,4g, 0 074 -ol), sodium 2-{2,3-dihydroxypropoxy)ethanesulfonate (6.6g, 0.030 mol), ethylene glycol (Baker, 14.0g, 0,225 mol), propylene glycol (Fisher, 18 3g, 0,240 mol), and titanium (IV) propoxide (0.0lg, 0.02% of total reaction weight). This mixture is neated to 180°C and maintained at that temperature overnight under argon as methanol distills from the reaction vessel. The material is transferred to a 500ml, single neck, round bottom flask and heated gradually over about 20 minutes to 240°C in a Kugelrohr apparatus (Aldrich) at about 0.1 mm Hg and maintained there for 110 rrjnutes. The reaction flask is then allowed to air cool quite rapidly to near room temperature under vacuum (-30 min.) The reaction affords 24.4g of the desired oligomer as a brown glass. A 13C-NMR(DMSO-d6) shows a resonance for -C(0)OCH2CH20(0)C- at -63.2 ppm (diester) and a resonance for -C(0)0CH2CH20H at -59.4 ppm (monoester). The ratio of the diester peak to monoester peak is measured to be 8. Resonances at -51.5 ppm and -51.6 ppm representing the sulfoethoxy groups (-CH2S03Na) are also present. A1H-NMR(DMSO-d6) shows a resonance at -7.9 ppm representing terephthaJate aromatic hydrogens. Analysis by Hydrolysis-GC shows that the mole ratio of incorporated ethylene grycol to incorporated propylene glycol is 1.6:1. The solubility is tested by weighing a small amount of material into a vial, adding enough distilled water to make 135% by weight solution, and agitating the vial vigorously. The material is readily soluble under these conditions. EXAMPLE 13 Synthesis of an Oligomer of Sodium 2-[2-(2-Hydroxoethoxy)ethoxy1ethanesulfonate. Dimethyl Terephthalate, Sodium 2-(2.3'Dihydroxypropoxy)ethanesulfonate. Glycerin. Ethylene Glycol, and Propylene Glycol 1 To a 250ml, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, and temperature controller (Therm-0-Watch®, I2R) is added sodium 2-[2-{2-hydroxyethoxy)ethoxy]ethanesulfonate (7.0g, 0.030 mol), dimethyl terephthalate (9.6g, 0.049 mol), sodium 2-{2,3-dihydroxypropoxt)ethanesulfonate (2.2g, 0 010 mol), glycerin (Baker, l.8g, 0.020 mol), ethylene glycol (Baker. 6.1g, 0 100 mol), propylene glycol (Fisher, 7.5g, 0.100 mol), and titanium (IV) propoxide (0.01 g, 0.02% of total reaction weight). This mixture is heated to 180°;C and maintained at that temperature overnight under argon as methanol distills from the reaction vessel, The material is transferred to a 250ml, single neck, round bottom flask and heated gradually over about 20 minutes to 240CC in a Kugelrohr apparatus (Aldrich) at about 3 mm Hg and maintained there for 1.5 hours. The reaction flask is then allowed to air cool quite rapidly to near room temperature under vacuum (-30 min.) The reaction affords 18,lg of the desired oligomer as a brown glass. A 13C-NMR(DMSO-d6) shows a resonance for -C(0)0CH2CH20(0)C- at ~63.2 ppm (diester), A resonance for -C(0)OCH2CH20H at -59.4 ppm (monoester) is not detectable and is at least 12 times smaller than the diester peak. Resonances at -51.5 ppm and -51.6 ppm representing the sulfoethoxy groups (-CH2S03Na) are also present. A 1H-NMR(DMSO-d6) shows a resonance at -7.9 ppm representing terephthaJate aromatic hydrogens. Analysis by HydroIysis-GC shows that the mole ratio of incorporated ethylene glycot to incorporated propylene glycol is 1.6;). The incorporated glycerin is found to be 0.45 weight% of the final poiymer. The solubility is tested by weighing a small amount of material into a vial, adding enough distilled water to make a 35% by weight solution, and agitating the vial vigorously. The material is readily soluble under these conditions. EXAMPLE 14 Synthesis of an Oligomer of Sodium 2-[2-(2.-Hydroxyethopxy)ethoxy]ethanesulfonate. Dimethyl Terephthalate. Sodium2-(2,3-Dihydroxypropoxy)ethanesulfonate. G lycerol. Ethvlene Glycol. and Propylene GIycol) To a 250ml, three neck, round bottom flask equipped with a magnetic stirring bar, modified Claisen head, condenser (set for distillation), thermometer, and temperature controller (Therm-0-Watch®, l2R) is added sodium 2-[2-(2-hydroxyethoxy)ethoxy]ethanesulfonate (2.7g, 0.011 mol, as in Example 2), dimethyl terephthalate (12.0g, 0.062 mol, Aldrich), sodium 2-{2,3-dihydroxypropoxy)ethanesulfonate (5.0g, 0.022 mol, as in Example 1), grycaol (Baker, O.SOg, 0.0055 mol), ethylene glycol (Baker, 6.8g, 0.110 mol), propylene glycol (Baker, 8.5g, 0.112 mol), and titanium (IV) propoxide (O.Olg, 0.02% of total reaction weight). This mixture is heated to 180°C and maintained at that temperature overnight under argon as methanol and water distill from the reaction vessel. The material is transferred to a 500ml, single neck, round bottom flask and heated gradually over about 20 minutes to 240°C in a Kugelrohr apparatus (Aldrich) at about 0.5 mm Hg and maintained there for 150 minutes. The reaction flask is then allowed to air cool quite rapidly to near room temperature under vacuum (-30 min.) The reaction affords 16.7g of the desired oligomer as a brown glass. A 13C-NMR(DMSO-d6) shows a resonance for -C(0)0CH2CH20(0)C- at -63.2 ppm (diester) and a resonance for -C(0)0CH2CH2OH at -59.4 ppm (monoester). The ratio of the peak height for the diester resonance to that of the monoester resonance is measured to be 6.1. Resonances at-51.5 ppm and-51.6 ppm representing the sulfoethoxy groups (-CH2S03Na) are also present. A lH-NMR(DMSO-d6) shows a resonance at -7.9 ppm representing terephthalate aromatic hydrogens. Analysis by hydrolysis-gas chromatography shows that the mole ratio of incorporated ethylene glycol to incorporated propylene glycol is 1.42:1. The solubility is tested by weighing a small amount of material into a vial, adding enough distilled water to make a 35% by weight solution, and agitating the vial vigorously The material is readily soluble under these conditions, A -9g sample of this material is further heated at 240°C in a Kugelrohr apparatus at about 0.5 mm Hg and maintained there for 80 minutes. A 13C-NMR(DMSO-d6)shows delectable peak for monoester at -59,4 ppm The peak for diester at -63.2 ppm is at least 11 times larger than the monoester peak. The solubility of this material is tested as above and it is also found to be readily soluble under these conditions, EXAMPLES 15-21 The following describe high density liquid detergent compositions according to the present invention: TABLE I(Table Removed) 1. Minors - includes optical brightener and enzymes (protease, lipase, cellulase, and amylase). 2. Non-Cotton Soil Release Polymer according to U.S. Patent 4,968,451, Scheibei et al. 3. Soil release polymer according to Example 4. TABLE II(Table Removed) 1. C12-C13 alkyl E9 ethoxylate as sold by Shell Oil Co 2. Bacillus atnyhliquefaciens subtilisin as described in WO 95/10615 published April 20, 1995 by Genencor International. 3. Derived from Humicola lanuginosa and commercially available from Novo. 4 Disclosed in WO 9510603 A and available from Novo. 5. As described in Example 7 above. 6. Terephtnalate co-polymer as disclosed in U.S. Patent 4,968,451, Scheibel et al., issued November 6, 1990, EXAMPLES 22 - 25 Compositions of the present invention are also prepared by preparing high density granular formulas according to this example utilizing the cotton soil release polymers alone or in combination with other soil release polymers. TABLE III(Table Removed) 1. Non-cotton soil release polymer according to U.S. Patent 4,968,451, Scheibel et al., issued November 6, 1990, 2. Non-cotton soil release polymer according to U.S. Patent 5,415,807, Gosselink, Pan, Kellett and Hall, issued May 16, 1995. 3. Non-cotton soil release polymer according to U.S. Patent 4,702,857, Gossslink, issued October 27, 1987. 4 Cotton soil release agent according to Example 4. 5, Balance to 100% can, for example, include minors like optical brightener, perfume, suds suppressor, soil dispersant, protease, lipase, cellulase, chelating agents, dye transfer inhibiting agents, additional water, and fillers, including CaCO3, talc, silicates, etc. EXAMPLES 26 - 29 Suitable granular laundry detergent compositions comprising the cotton soil release agents of the present invention can be formulated without linear alkyl benezene sulfonates (LAS), for example: TABLE IV (Table Removed) 1. As sold by the Shell Oil Co. 2 Non-cotton soil release polymer according to U.S. Patent 4,968,451, Scheibel et al., issued November 6, 1990. 3. Non-cotton soil release polymer according to U.S. Patent 5,415,807, Gosselink, Pan, Kellett and Hall, issued May 16, 1995. 4. Non-cotton soil release polymer according to U.S. Patent 4,702,857, Gossclink, issued October 27, 1987, 5. Cotton soil release agent according to Example 4, 6. Balance to 100% can, for example, include minors like optical brightener, perfume. suds suppresses soil dispersant, protease, lipase, cellulase, chelating agents, dye transfer inhibiting agents, additional water, and fillers, including CaCO3, talc, silicates, etc, Aqueous crutcher mixes of heat and alkali stable components of the detergent compositions are prepared and spray-dried and the other ingredients are admixed so that they contain the ingredients tabulated at the levels shown. The soil releasee agents of the present invention can be, for example, pulverized and admixed in an amount sufficient for use at a level of 0.5% by weight in conjunction with the detergent compositions. An example of the method of the present invention is outlined below: The detergent granules comprising cotton soil release polymers are added (99.5 parts/0.5 parts by weight, respectively) together with a 6 Ib. load of previously laundered fabrics (load composition: 10 wt % polyester fabrics/50 wt % polyester-cotton/40 wt */« cotton fabrics) to a Sears KENMORE washing machine. Actual weights of detergent and soil release agent compositions are take to provide a 995 ppm concentration of the former and 5 ppm concentration of the latter in the 1.7 gallon (65 liter) water-fill machine. The water used has 7 grains/gallon hardness and a pH of 7 to 7.5 prior to (abut 9 to about 10.5 after) addition of the detergent and ester compositions. The fabrics are laundered at 35° C (95° F) for a full cycle (12 min.) and rinsed at 21° C (70° F). the fabrics are then line dried and are exposed to a variety of soils (by wear or controlled application;. The entire cycle of laundering and soiling is repeated several limes for each of the detergent compositions. Separate fabric bundles are reserved for use with each of the detergent compositions. AJ1 cotton-containing fabrics display significantly improved whiteness during laundering compared with fabrics which have not beer, exposed to the compositions of the present invention. Cotton soil release agents of the present invention are especially useful in conventional laundry detergent compositions such as those typically found in granular detergents or laundry bars. U.S. Patent 3,178,370, Okenfuss, issued April 13, 1965, describes laundry detergent bars and processes for making them. Philippine Patent 13,778, Anderson, issued September 23, 1980, describes synthetic detergent laundry bars. Methods for making laundry detergent bars by various extrusion methods are well known in the art. EXAMPLE 30 Ingredients Weight % C12 linear alkyl benzene sulfonate 30 Phosphate (as sodium tripolyphosphate) 7 Sodium carbonate 25 Sodium pyrophosphate 7 Coconut monoethanolamide 2 Zeolite A, (0,1 -10 micro n) 5 Carboxycellulose 0.2 Ethylenediamine disuccinate chelant(EDDS) 0.4 Polyarylate(MW-l400) 0.2 Norianotyoxybenzenesulfonate 5 Cotton Soil release agent1 0.5 Non-cotton toil release agent2 0.5 Sodium percarborute3 5 Brightener, perfume 0.2 Protease 0.3 Calcium sulfate 1 Magnesium sulfate 1 Water 4 Filer4 Balance to 100 1. Soil release polymer according to Example 7. 2. Non-cotton soil release agent according to U.S. Patent 4,968,451, J : Scheibel and E P Gosselink, issued November 6, 1990. 3 Average particle size of 400 to 1200 microns. 4 Can be selected from convenient materials such as Calcium carbonate talc, clay, silicates, and the like. EXAMPLES 31-32 The detergent bars are processed in conventional soap or detergent bar making equipment as commonly used in the art. The soil release agent is pulverized and admixed in an amount sufficient for use at a level of 0.5% by weight in conjunction with the detergent compositions. TABLE V Laundry bars suitable for hand-washing soiled fabrics are prepared by standard extrusion processes and comprise the following: (Table Removed) 1. Non-cotton soil release polymer according to U.S. Patent 4,968,451. Schtibel et al., issued November 6, 1990. 2. Cotton soil release agent according to Example 4. 3. Cotton soil release agent according to Example 5. 4, Can be selected from convenient materials such as Calcium carbonate, talc, clay, silicates, and the like. EXAMPLES 33 - 36 Granular Laundry Detergent Compositions..Comprising Oxygen Bleach (Table Removed) 1. C45 ethoxylated (7) alcohol as sold by Shell Oil Co. 2. As described in Example 4 hereinabove. 3. Soil release agent as disclosed in U.S. 5,415,807, Gosselink et al.( issued May 16, 1995. EXAMPLES 37 - 40 Granular Laundry Detergent Compositions (Table Removed) 1. C45 ethoxylated (7) alcohol as sold by Shell Oil Co. 2. As described in Example 1 hereinabove. 3. Soil release agent as disclosed in U.S. 5,415,807, Gosselink et al., issued May 16, 1995. 4. Zinc phthalocyanine sulfonate photobleach according to U.S. Patent 4,033,718 Holcombe et al., issued Jury 5, 1977. The present composition is a synergistic composition wherein the ingredients are interacting but not reacting to give extra exceptional properties. It is not an admixture. WE CLAIM: 1, A laundry detergent composition comprising: a) from 0.01% to 95% by weight, of a detersive surfactant selected from the group consisting of anionic, nonionic, cationic, zwitterionic, and ampholytic surfactants, and mixtures thereof: b) from 0.01 to 10% by weight, of a soil release polymer having effective soil release on non-cotton fabric such as herein described; c) optionally from 0.05 to 30% by weight, of a bleach; d) from 0.01 to 10% by weight, a water-soluble or dispersible, modified polyamine cotton soild release agent comprising a polyamine backbone prior to modification via quaternization, substitution, or oxidation corresponding to the formula: (Formula Removed) having a modified polyamine formula V(n+l)WmYnZ or a polyamine backbone prior to modification via quaternization, substitution, or oxidation corresponding to the formula: (Formula Removed) having a modified polyamine formula V(n.k+1)WmYn Y'kZ, wherein k is less than or equal to n, said polyamine backbone prior to has a molecular weight greater than 200 daltons, wherein i) V units are terminal units having a formula selected from : (Formula Removed) ii) W units are backbone units having a formula selected from: (Formula Removed) iii) Y units are branching units having a formula selected from: (Formula Removed) iv) Z units are terminal units having a formula selected from: (Formula Removed) wherein backbone linking R units are C2-C12 alkylene; R1 is C2-C6 alkylene, and mixtures thereof; E units are selected from the group consisting of hydrogen, C1-C2, alkyl, --(CH2)p CO2 M. -(CH2)q SO3 M. --CH(CH2CO2M)CO2M, -(CH2)p PO3M, -(R1O)X B, and mixtures thereof ; provided that when any E unit of a nitrogen is a hydrogen, said nitrogen is not also an N- oxide; B is hydrogen. C1-C6 alkyl, -(CH2)q SO3 M, -(CH2)p CO2 M, -(CH2)q (CHSO3 M)CH2 SO3 M, -(CH2)q -(CHSO2 M)CH2 SO3 M, -(CH2)P PO3M, -PO3 M, and mixtures thereof, provided when B is an ionizable unit selected from the group consisting of -(CH2)q SO3 M, - (CH2)PCO2 M, (CH2)q (CHSO3M)-CH2 SO3 M, -(CH2)q (CHSO2 M)CH2 SO3 M, -(CH2)p PO3M, -PO3 M, and mixtures thereof, at least one backbone nitrogen is quaternized; M is hydrogen or a water soluble cation in sufficient amount to satisfy charge balance; X is a water soluble anion; m has the value from 4 to 400; n has the value from 0 to 200; p has the value from 1 to 6, q has the value from 0 to 6; x has the value from 11 to 100; and e) the balance carrier and adjunct ingredients such as herein described. 2. A laundry detergent composition as claimed in claim 1, wherein the adjunct ingredients are selected from the group consisting of builders, optical brighteners, bleaches, bleach boosters, bleach activators, soil release polymers, dye transfer agents, dispersants, enzymes, suds suppressers, dyes, perfumes, colorants, filler salts, hydrotropes, and mixtures thereof. 3. A laundry detergent composition as claimed in claim 1 or claim 2 wherein R is C2-C4 alkylene, and mixtures thereof. 4. A laundry detergent composition as claimed in claim 3 wherein R is ethylene. 5. A laundry detergent composition as claimed in claim any of the preceding claims wherein R1 is at least 50% ethylene. 6. A laundry detergent composition as claimed in claim 5 wherein R1 is ethylene. 7. A laundry detergent composition as claimed in any of the preceding claims wherein E units are hydrogen, -(R1O)X B, -(CH2)p CO2 M, -(CH2)q SO3 M, -CH(CH2 CO2 M)CO2 M, and mixtures thereof. 8. A laundry detergent composition as claimed in claim 7 wherein E units are hydrogen, (R1O)XB, and mixtures thereof. l). A laundry detergent composition as claimed in claim 8 wherein E units are - ((R'O)XB. 10. A laundry detergent composition as claimed in claim 7 wherein B units are hydrogen, -(CH2)qSO1M, -(CH2)q(CHSO3M)CH2SO3M,-(CH2)q(CHSO2M)-CH2SO3M, and mixtures thereof, wherein q has the value from 0 to 3. 11. A laundry detergent composition as claimed in claim 10 wherein B is hydrogen, - (CH2)9SO3M, and mixtures thereof, wherein q has the value from 0 to 3. 12. A laundry detergent composition as claimed in any of the preceding claims wherein said non-cotton soil release polymer comprises: a) a backbone comprising: i) at least one moiety having the formula: (Formula Removed) ii) at least one moiety having the formula: (Formula Removed) wherein R9 is C2-C6 linear alkylene, C3-C6 branched alkylene, C5-C7 cyclic alkylene, and mixtures thereof, R10 is independently selected from hydrogen or - L-SO3~M+; wherein L is a side chain moiety selected from the group consisting of alkylene, oxyalkylene, alkyleneoxyalkylene, arylene, oxyarylene, alkyleneoxyarylene, poly(oxyalkylene), oxy-alkyleneoxyarylene, poly(oxyalkylene)oxyarlyene, alkylene-poly(oxyalkylene), and mixtures thereof; M is hydrogen or a salt forming cation; i has the value of 0 or 1; iii) at least one trifunctional, ester-forming,branching moiety; iv) at least one 1. 2-oxyalkyleneoxy moiety; and b) one or more capping units comprising: i) ethoxylated or propoxylated hydroxyethanesulfonate or ethoxylated or propoxylated hydroxypropanesulfonale untis of the formula (MO3S)(CH2)m (R11O)n -, wherein M is a salt forming cation, R11 is ethylene, propylene, and mixtures thereof, m is 0 or 1, and n is from 1 to 20; ii) sulfoaroyl units of the formula (O)C(C6H4)(SO3 -M+), wherein M is a salt forming cation; iii) modified poly(oxyethylene)oxy monoalkyl ether units of the formula -R12O(C2CH2CH, O) -, wlierein R12 contains from 1 to 4 carbon atoms and k is from 3 to 100; and iv) ethoxylated or propoxylated phenolsulfonate end-capping units of the formula MO3 S(C6H4)OR13)nO-, wherein n is from 1 to 20; M is a salt-forming cation; and R13 is ethylene, propylene, and mixtures thereof. 13. A laundry detergent composition as claimed in claim 1, wherein the non-cotton soil release agent comprises a sulfonated oligomeric ester composition comprising the sulfonated product of a pre-formed, substantially linear ester oligomer, said linear ester oligomer comprising, per mole, a) 2 moles of terminal units wherein from 1 mole to 2 moles of said terminal units are derived from an olefinically unsaturated component selected from the group consisting of allyl alcohol and methallyl alcohol, and any remaining of said terminal units are other units of said linear ester oligomer; b) from 1 mole to 4 moles of nonionic hydrophile units, said hydrophile units being derived from alkyleneoxides, said alkylene oxides comprising from 50% to 100% ethylene oxide; c) from 1.1 moles to 20 moles of repeat units derived from an aryldicarbonyl component wherein said aryldicarbonyl component is comprised of from 50% to 100% dimethylterephthalate, whereby the repeat units derived from said dimethylterephthalate are terephthaloyl; and d) from 0.1 moles 10 19 moles of repeat units derived from a diol component selected from the group consisting of C2C4 glycols; wherein the extent of sulfonation of said sulfonated oligomeric ester composition is such that said terminal units are chemically modified by e) from 1 mole to 4 moles of terminal unit substituent groups of formula - SOXM wherein x is 2 or 3, said terminal unit substituent groups being derived from a bisulfite component selected from the group consisting of HSO3M wherein M is a conventional water- soluble cation. 14. A laundry detergent composition as claimed in claim 1 wherein the non-cotton soil release agents comprise compounds of the formula X[OCH2 CH2)n (OR5)m][(A-R'-A-R2)a (A-R3 -A-R2)]-A-R4-A[(R5O)m (CH2 CH2 O)n]X wherein each of the A moieties is selected from the group consisting of (Formula Removed) and combinations thereof, each of the R' moieties is selected from the group consisting of 1,4-phenylene and combinations thereof with 1,3-phenylene, 1,2phenylene, 1,8-naphthylene, 1.4-naphthylene, 2, 2 -biphenylene, 4,4-biphenylene, C1-C8 alkylene, C1-C8 alkenylene and mixtures thereof the R1 moieties are each selected from the group consisting of ethylene moieties, substituted ethylene moieties having C1-C4 alkyl, alkoxy substitiuents, and mixtures thereof; the R moieties are substituted C1-C18 hydrocarbylene moieties having at least one -CO2M. -O[(R5O)m (CH2 CH. O)n]X or -A[R2 AR4A)]w [R5O)m (CH2 CH2 O)n]X substituent; the R4 moieties are R1 or R3 moieties, or mixtures thereof; R5 is C1 C4 alkylene, or the moiety -R2-A-R5 --wherein R6 is a C1-C12 alkylene,alkenylene, arylene, or alkarylene moiety; each M is hydrogen or a water-soluble cation; each X is C1 C4 alkyl; the indices m and n have the values such that the moiety - (CH2 CH2O)- comprises at least 50% by weight of the moiety [(R5O))m (CH2 CH2 O)n], provided that when R5 is the moiety -R2-A-R6, m is l; each n is at least 10: the indices u and v have the value such that the sum of u+v is from 3 to 25; the index w is 0 or al least 1; and when w is at least 1 u, v and w have the value such that the sum of u+v+w is from 3 to 25, 15. A laundry detergent composition as claimed in claim 1 wherein the non-cotton soil release agent comprises: A) at least 10% by weight of a substantially linear sulfonated polyethoxy/propoxy end-capped ester having molecular weight ranging from 500 to 8,000; said ester consisting essentially of on a molar basis: i) from I to 2 moles of sulfonated poly ethoxy/propoxy end-capping units of the formula: (MSO3)(CH2)n, (CH2 CH2 O)(RO)n - wherein M is a salt-form ing cation such as sodium of tertraalkylammonium, m is 0 or 1, R is ethylene, propylene, and mixtures thereof; and n is from 0 to 2; and mixtures thereof; ii) from 0.5 to 66 moles of units selected from the group consisting of: a) oxyethyleneoxy units: b) a mixture of oxyethyleneoxy and oxy-1, 2,-propyleneoxy units wherein said oxyethyleneoxy units are present in an oxyethyleneoxy of oxy-1, 2-propyleneoxy mole ratio ranging from 0.5:1 to 10:1; and c) a mixture of a) or b) with poty(oxyethylene)oxy units have a degree of polymerization of from 2 to 4; provided that when said poly(oxyethylene)oxy units have a degree of polymeri/ation of 2, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to 0.33:1; and when said poly(oxyethylene)oxy units have a degree of polymerization of 3, the mole ratio of poly(oxyethylene)oxy units have a degree of polymerization equal to 4, the mole ratio of poly(oxyethylene)oxy units to total group ii) units ranges from 0:1 to 0.14:1; iii) from 1.5 to 40 moles of terephthaloyl units; and iv) from 0 to 26 moles of 5-sulphophthaloyl units of the formula; -(O)C(C6H3)(SO3M)C(O)- wherein M is a salt form ing cation; and B) from 0,5% to 20% by weight of ester, of one or more crystallization-reducing stabilizers 16. A laundry detergent composition as claimed in claim 1 wherein the non-cotton soil release agent comprises greater than 0.2% carboxy methyl cellulose. 17. A laundry detergent composition as claimed in claim 1 wherein the detersive surfactant is not linear alkyl benzene sulfonate. 18. A laundry detergent composition, substantially as hereinbefore described in any of the Examples.

Documents:

1309-del-1996-abstract.pdf

1309-del-1996-assignment.pdf

1309-del-1996-claims.pdf

1309-del-1996-correspondence-others.pdf

1309-del-1996-correspondence-po.pdf

1309-del-1996-description (complete).pdf

1309-del-1996-form-1.pdf

1309-del-1996-form-2.pdf

1309-del-1996-form-3.pdf

1309-del-1996-form-4.pdf

1309-del-1996-form-6.pdf

1309-del-1996-gpa.pdf

1309-del-1996-petition-138.pdf