Title of Invention

REFRIGERATING APPARATUS

Abstract

This invention relates to a refrigeration system comprising a compressor (I), an evaporator (4) with an air suction side and having conduit in which refrigerant is located , an expansion device (3) and a condenser (2), coupled together; a first temperature detector (20) which is located adjacent to said air suction side of said evaporator (4) for measuring temperature of air entering said evaporator (4); a second temperature detector which is located adjacent said conduit for measuring temperature of refrigerant inside said conduit; and a differential temperature detector (11) for calculating the difference between the temperature measured by the first temperature detector (20) and the temperature measured by the second temperature detector (21) to determine whether refrigerant leak has occurred.

Full Text

FIELD OF THE INVENTION The present invention relates to a refrigerating apparatus using a refrigerant and a heat pump type refrigerating apparatus, and more particularly to a refrigeration system control apparatus for detecting a refrigerant leak. BACKGROUND OF THE INVENTION Recently, from the standpoint of global environmental conservation, regulations on substances destroying the ozone layer are being fortified, and among them, as for chlorofluorocarbons (CFCs) known to have a particularly strong destructive force, total disuse was decided at the end of 1995. At the same time, as for hydrochlorofluorocarbons (HCFCs) relatively small in destructive v force, regulation of total emission started in 1996, and total disuse in future was decided. In this background, refrigerants to replace CFCs and HCFCs are being developed. It is, accordingly, proposed to use hydrofluorocarbons (HFCs) which do not destroy the ozone layer, but as far as known so far, there is no HFC that can be used alone to replace the HCFCs being presently used in the refrigerating machine and air-conditioner. Therefore, a non- azeotropic mixed refrigerant mixing two or more HFC refrigerants is most highly expected. In particular, a mixed refrigerant of HFC-32 and HFC-125 is a most promising candidate as a substitute refrigerant for HCFC-22 (hereinafter called R22). One of its representative examples is R410A (HFC-32/125 = 50/50 wt.%. Fig. 8 is a characteristic diagram showing effects of ratio, of charging refrigerant of R22 or R410A on the temperature of compressor coil in a conventional refrigerating apparatus. The ratio of charging refrigerant refers to the ratio of the actual refrigerant amount to the specified refrigerant amount of the refrigerating machine. As known from Fig. 8, when the refrigerating machine or air-conditioner using conventional R22 runs short of refrigerant, along with elevation of compression ratio, the discharge temperature hikes, and the circulation of the refrigerant drops. As a result, the cooling effect declines, and the temperature of the compressor coil elevates. The shaded area in the diagram refers to an example of compressor stopping point by a compressor overload protective device of a small-sized room air-conditioner mounting a constant speed compressor. Considering this example, it is known that the compressor stops when the ratio of charging refrigerant is about 10% in the refrigerating apparatus using R22,that is, when a refrigerant leak of about 30% occurs. (it must be noted, however, this ratio varies somewhat depending on the type of the overload protective device and air-conditioning load.) Therefore, in a refrigerating apparatus using R22, when a refrigerant leak occurs, the compressor overload protective device is actuated by elevation of discharge temperature. It was therefore possible to detect a refrigerant leak early indirectly. - 2 - In Fig. 8, however, when running short of refrigerant R410A, rise of discharge temperature of compressor coil is smaller than that in the case of R22, and the cooling effect is enhanced by increase of circulation of refrigerant R410A. Accordingly, it is lower than the discharge temperature R22 of the compressor coil when using R410A. This discharge temperature characteristic of the compressor coil in the event of shortage of refrigerant R410A is a feature of a mixed refrigerant of HFC-32/125. As seen therefrom, when an overload protective device of compressor for R22 machine is used in the refrigerating apparatus using R410A, the compressor can operate in a range of up to the ratio of charging refrigerant R410 of about 30%. Hence, as far as the user does not notice shortage of capacity due to insufficient refrigerant, continuous operation may be executed for a long time. Methods for detecting shortage of refrigerant amount are disclosed in Japanese Laid-out Patents 62-158966, 1-107070, and 6-137725. In Japanese Laid-out Patent 62-158966, the outlet temperature and intermediate temperature of a heat exchanger are compared and calculated, and excess or shortage or leak of refrigerant is detected. It involves the following problems. Fig. 9 is a side view of a heat exchanger in a prior art. As shown in Fig. 9, in a heat exchanger 80, there are plural fins 6 between side boards 7, and a heat transfer conduit 5 and U-pipes 32 to 40 penetrate through the - 3 - fins 6. Refrigerant enters from an inlet 31. and is discharged from an outlet 41.' A second temperature detector 21 for detecting the refrigerant temperature in the heat exchanger is provided in a middle part of the heat exchanger. In a method for detecting the temperature at the outlet '40 of the heat exchanger and the temperature in the middle part 36. since a differential temperature of AT occurs at the ratio of charging refrigerant of about 40 to 70%, refrigerant leak can be detected, but the differential temperature AT decreases at about 40%, and refrigerant leak cannot be detected. In Japanese Laid-out Patent 1-107070, on the other hand, in addition to the differential temperature at the inlet and outlet of refrigerant in the heat exchanger, the differential temperature at the inlet and outlet of the air side is also included in the operation to detect shortage of refrigerant and leak of refrigerant. However, in the method of detecting the differential temperature of the inlet and outlet of refrigerant, the refrigerant temperature at the evaporator inlet drops suddenly along with decline of suction pressure due to shortage of refrigerant, and hence it is not effective for detection of refrigerant leak. Moreover, these methods require two or more sensors for detecting temperature in the evaporator, and the cost is increased. Or, in the method of detecting the inlet and outlet temperature at the air side, it also adds to the cost because a temperature detecting sensor is needed in the blow-out part of the indoor unit - 4 - side. In Japanese Laid-out Patent 6-137725, meanwhile, the refrigerant temperature in the refrigeration system is detected at specific time intervals, and the refrigerant leak is judged from its J changing amount. This method is, however, constituted to detect the refrigerant temperature in the refrigeration system at specific time intervals, and judge the refrigerant leak by the changing amount of the superheat, and accordingly, same as in the method of detecting the differential temperature at the refrigerant inlet and outlet, capacity drop of evaporator due to refrigerant shortage cannot be detected precisely. In this method, yet, since the changing amount of the refrigerant temperature in the refrigeration system is always stored in order to judge refrigerant leak, the operation is complicated. It is hence an object of the invention to present a refrigeration system operation control apparatus using HFC refrigerant capable of detecting refrigerant leak securely and at . low cost. SUMMARY OF THE INVENTION The refrigerating apparatus of the invention comprises a refrigeration system using a hydrofluorocarbon refrigerant, including a compressor, an evaporator, an expansion device, and a condenser, being sequentially coupled together annularly through a - 5 - conduit, a first temperature detector for detecting the air temperature at the suction port of the evaporator,' a second temperature detector for detecting the refrigerant temperature at an intermediate part of the evaporator, and a differential temperature detector for calculating the differential pressure of the air' temperature and refrigerant temperature which are output values from the first temperature detector and second temperature detector, so that a refrigerant leak is judged from the differential temperature. Preferably, this constitution further comprises a running-time detector for storing the cumulative running time of the compressor, so that a refrigerant leak is judged from the differential temperature and the cumulative running time. In this constitution, if the refrigerant leaks and the refrigerant amount in the refrigeration system becomes insufficient, the circulation of the refrigerant decreases, and therefore the refrigerant average temperature in the evaporator becomes closer to the air temperature at the suction port of the evaporator as compared with the normal running state. By the differential temperature of the refrigerant temperature in the middle part of the evaporator provided to detect the refrigerant average temperature in the evaporator precisely and the air temperature at the suction port of the evaporator, capacity drop due to refrigerant leak can be detected. Moreover, by simultaneously monitoring the cumulative runn- - 6 - ing time of the compressor in order to prevent detection error during stop of the compressor, if a refrigerant leak occurs, it can be detected early and securely. BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS Fig. 1 is a block diagram showing a constitution of a refrigeration control apparatus in an embodiment of the invention. Fig. 2 is an evaporator temperature distribution characteristic diagram in the event of leakage of R410A refrigerant in a refrigeration control apparatus in an embodiment of the invention. Fig. 3 is a characteristic diagram of ratio of charging refrigerant and differential temperature of evaporator (suction air - refrigerant) in a refrigeration control apparatus in an embodiment of the invention. Fig. 4 is a flowchart relating to refrigerant leak detection in a refrigeration control apparatus in an embodiment of the invention. Fig. 5 is an explanatory diagram of a section from the side of an evaporator showing the position for detecting the refrigerant temperature of the evaporator in a refrigeration control apparatus in an embodiment of the invention. Fig. 6 is a block diagram showing a constitution of a refrigeration control apparatus in an embodiment of the invention. Fig. 7 is a characteristic diagram of ratio of charging refrigerant and first heat exchanger differential temperature - 7 - (suction air - refrigerant temperature ) in an embodiment of the invention. Fig. 8 is a characteristic diagram showing effects of ratio of charging refrigerant on the compressor coil temperature and refrigerant quantity in a conventional refrigerating apparatus. Fig. 9 is an explanatory diagram of a section from the side of the evaporator showing the position for detecting the refrigerant temperature of the evaporator in a prior art. REFERENCE NUMERALS 1 Compressor 2 Condenser 2a Fan for condenser, 3 Expansion device 4 Evaporator, 4a Fan for evaporator 5 Heat transfer conduit 6 Fin 7 Side board 10 Microcomputer 11 Differential temperature detector 12 Compressor running time detector 13 Means for deciding the leak of refrigerant 14 Display apparatus 15 Running apparatus - 8 - 20 First temperature detector 21 Second temperature detector 31 Inlet of refrigerant conduit of evaporator 32~40 U-pipe (36 is a U-pipe in middle part) 41 Outlet of refrigerant conduit of evaporator 51 Reversing valve 52 Second heat exchanger 52a Fan for second heat exchanger 54 First heat exchanger 54a Fan for first heat exchanger 60 Suction air temperature detector for first heat exchanger 61 Refrigerant temperature detector for first heat exchanger 64 Display apparatus 65 Running apparatus 80 Heat exchanger DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Fig. 1 shows a constitution of a refrigeration system control apparatus in a first embodiment of the invention. In Fig. 1, the refrigerating apparatus comprises a refrigeration system and a control apparatus. The refrigeration system is composed of a compressor 1, a condenser 2, an expansion device 3, and an evaporator 4, coupled together through a conduit. Heat exchangers such as the condenser 2 and evaporator 4 exchange heat with air through a fan for condenser 2a and a fan for evaporator 4a. A first - 9 - temperature detector 20 for detecting the suction temperature of the evaporator and a second temperature detector 21 for detecting the refrigerant temperature at the middle part of the evaporator are provided, and are coupled to a microcomputer 10. The microcomputer incorporates a differential temperature detector 11 for detecting the differential temperature of air temperature and refrigerant temperature, a running time detector 12 for storing the cumulative running time of the compressor, and means for deciding the leak of refrigerant 13 for judging refrigerant leak by comparing the differential temperature detector 11 and running time detector 12. A display apparatus 14 and a running apparatus 15 are also connected to the microcomputer 10. The refrigeration system is packed with R410A. Thus, the refrigeration system control apparatus is constituted. The operation is described below. When a refrigerant leaks, using R410A, the relation between the detecting position and refrigerant temperature of the evaporator is shown in Fig. 2. A characteristic diagram showing the relation between the ratio of charging refrigerant and evaporator is given in Fig. 3. A flowchart for detection of refrigerant leak is shown in Fig. 4. In Fig. 2, when the refrigerant amount decreases, it is known that the refrigerant temperature Tern at the middle part of the evaporator (position 36) detected by the second temperature detector 21 becomes gradually closer to the evaporator suction air temperature Tai detected by the first temperature detector 20. This differential - 10 - temperature AT (= Tai - Tem), that is, the capacity of heat exchanger becomes smaller as the refrigerant amount decreases as shown in Fig. 3. Therefore, when the differential temperature AT becomes lower than a specific value, it may be judged that the refrigerating capacity is lowered due to refrigerant leak or refrigerant shortage. However, when stopping operation in the compressor, when operating the inverter type compressor at low speed, or in a transient state when starting up operation, since the differential temperature AT approaches 0, a detection error may occur by the detection of differential temperature alone. Accordingly, in the condition where the refrigerating apparatus requires a refrigerating capacity, the compressor is not stopped, or an inverter compressor is operated continuously at a rated rotating speed, and considering from such relation, the cumulative running time t of the compressor is detected by the running time detector 12 for storing the running state of the compressor, and when the cumulative time t exceeds a specific value, it may be judged that the refrigerating capacity is lowered due to refrigerant leak or refrigerant shortage. Therefore, as shown in the flowchart in Fig. 4 for detecting refrigerant leak, when the differential temperature AT is lower than a criterion K1, and the cumulative running time t of the compressor exceeds a criterion tK1, a refrigerant leak is judged. According to this judgement, a failure display of refrigerant leak is shown in the display apparatus 14 in Fig. 1, and, if necessary, the operation of the compressor is stopped by the - 11 - running apparatus 15. The position for detecting the temperature by the second temperature detector 21 is described below while referring to the drawing. A lateral view of a multi-row and multi-stage compressor of one row or more (herein 2 rows and 10 stages) is shown in Fig. 5. In the heat exchanger 4, there are plural fins 6 between side boards 7, and a heat transfer conduit 5 and U-pipes 32 to 40 penetrate through the fins 6. A refrigerant is fed through an inlet 31, and is discharged through an outlet 41. The position for installing the second temperature detector 21 for detecting the refrigerant temperature of the evaporator should exclude the inlet and outlet of refrigerant conduit of evaporator 31, 41 of the evaporator 4, and the refrigerant conduit close to the inlet and outlet of the evaporator. The reason for specifying the position for installing the second temperature detector 21 is described below. In Fig. 5, if the position for installing the second temperature detector is limited by the constitution of the evaporator or air-conditioner, it may not be installed at the U-pipe 36 at the middle part of the evaporator. The detecting position is reviewed herein. As shown in Fig. 2, as the evaporator inlet pressure drops due to refrigerant leak, the refrigerant temperature in the U-pipe 32 close to the inlet of refrigerant conduit of evaporator 31 and conduit inlet is lowered, whereas the U-pipe 40 near the outlet of refrigerant conduit of evaporator 41 and conduit - 12 - outlet is lowered in the refrigerant temperature because overheat is likely to cool down. However, the refrigerant temperature in other refrigerant conduits, herein, U-pipes 33 to 39, is not influenced by decline of temperature at inlet and outlet of evaporator, so that the refrigerant temperature at the middle part of the evaporator can be detected. Therefore, by installing the second temperature detector 21 at other positions than the inlet and outlet of refrigerant conduit and the refrigerant conduit close to the inlet and outlet of evaporator, drop of refrigerating capacity due to refrigerant leak can be detected. Incidentally, as the first temperature detector and second temperature detector, for example, various temperature sensors, elements, devices, and thermistors can be used. A second embodiment is described below while referring to the drawing. A constitution of the refrigerating apparatus in the second embodiment of the invention is shown in Fig. 6. This embodiment shows a heat pump type refrigerating apparatus as an example of refrigerating apparatus. In Fig. 6, the refrigerating apparatus comprises a heat pump type refrigeration system and a control apparatus. The heat pump type refrigeration system is composed of a compressor 1, a reversing valve 51, a first heat exchanger 54, an expansion device 3, and a second heat exchanger 52, being coupled together through a conduit. Heat exchangers such as the second heat exchanger 52 and first heat exchanger 54 exchange heat with air through a fan for second heat - 13 - exchanger 52a and a fan for first heat exchanger 54a. A first temperature detector 60 for detecting the suction temperature of the first heat exchanger and a second temperature detector 61 for detecting the refrigerant temperature at the middle part of the first heat exchanger are provided, and are coupled to a microcomputer 10. The microcomputer 10 incorporates a differential temperature detector 11 for detecting the differential temperature of air temperature and refrigerant temperature, a running time detector 12 for storing the cumulative running time of the compressor, and means for deciding the leak of refrigerant 13 for judging refrigerant leak by comparing the differential temperature detector 11 and running time detector 12. A display apparatus 64 and a running apparatus 65 are also connected to the microcomputer 10. The refrigeration system is packed with R410A. Thus, the heat pump type refrigerating apparatus is constituted. In cooling operation (solid line), that is, when the first heat exchanger 54 is used as evaporator, the operation is same as in the first embodiment, and the explanation is omitted. In heating operation (dotted line), that is, when the first heat exchanger is used as condenser, the differential temperature of the first heat exchanger refrigerant temperature Tern and first heat exchanger suction air temperature Tai , AT (= Tcm - Tai), at the refrigerant quantity, that is, the first heat exchanger capacity decreases as the refrigerant amount decreases as shown in Fig. 7. Therefore, when the differential temperature AT becomes lower than a specific - 14 - value, it is judged that the first heat exchanger capacity is lowered due to refrigerant leak or refrigerant shortage. Herein, the method of detecting the running state of the compressor is same as shown in the first embodiment. Accordingly, in judgement of refrigerant leak shown in the embodiment in Fig. 3, by setting the judging constants in the flowchart for detecting refrigerant leak in Fig. 4 at K2, tK2 for heating, when the differential temperature AT is lower than the criterion K2 and the cumulative running time of the compressor t is over the criterion tK2, refrigerant leak is judged. According to this judgement, a failure display of refrigerant leak is shown in a display apparatus 64 in Fig. 6, and the compressor operation is stopped, if necessary, by a running apparatus 65. In the foregoing embodiments, R410A is used, but when a single refrigerant of HFC-32 of which saturation pressure at same temperature is higher than in R22, or a mixed refrigerant of HFC-32/125 is used, the operation is nearly the same, and it is possible to use without being defined by the ratio of the mixed refrigerant. As clear from the description herein, according to the refrigerating apparatus of the invention, in the refrigerating apparatus using HFC refrigerant, a refrigerant, leak can be directly detected as drop of evaporator capacity, and by detecting the running state of the compressor at the same time, a refrigerant leak can be detected early and securely, and failure display or operation stopping is effected. As a result, the following effects are - 15 - obtained. 1) A refrigerant leak is detected early and securely. 2) Energy loss due to prolonged operation in refrigerant leak state is prevented. 3) Possibility of trouble of refrigerating apparatus due to abnormal operation in refrigerant leak state is lowered. 4) The existing apparatus of R22 refrigerating machine can be used, and it is low in cost. 5) The refrigerant temperature detecting means can be installed at a position corresponding to the constitution of the air-conditioner or heat exchanger. Moreover, a refrigerant leak in the evaporator of the refrigerating apparatus or the heat pump apparatus can be detected directly as capacity drop of heat exchanger, so that: 6) A refrigerant leak in heating operation can be detected; and 7) A refrigerant leak can be detected by the same apparatus, whether in cooling or heating operation, and therefore a simple and inexpensive heat pump type refrigerating apparatus can be presented. - 16 - 17 We Claim: 1. A refrigeration system comprising: - a compressor(1), an evaporator (4) having an air suction side and comprising a conduit ft which refrigerant is located, a fan (4a, 54a) for generating a flow of air for said evaporator, an expansion device (3), a condenser, and a leak detector (20, 21,11) for detecting leakage of refrigerant from said system, - the leak detector comprising a first temperature detector (20) which is located adjacent to said air suction side of said evaporator for measuring the temperature of air entering said evaporator, characterized In that:. - the refrigerant is one of (a) HFC-32; and (b) HFC-32 and HFC-125; and In that: - the leak detector comprises: • a second temperature detector (21) which is located adjacent said conduit for measuring the temperature of refrigerant Inside said conduit; and - a differential temperature detector (11) for calculating the difference between (a) the temperature measured by the second temperature detector (20) and (b) the temperature measured by the second temperature detector (21) to determine whether a refrigerant leak has occurred. 2. The refrigeration system as claimed in claim 1, wherein the leak detector comprises: - a running time detector(12) for measuring running time of said refrigeration system, wnerein the difference between the temperature measured by the first temperature detector (20) and the temperature measured by the second temperature detector (21) and the accumulated running time of said refrigeration system are used to determine whether refrigerant leak has occurred . 3. The refrigeration system as claimed In claims 1 and 2, wherein said evaporator (4) comprises an inlet (31) coupled to said expansion device (3), and an outlet (41) coupled to said compressor(1); and wherein said second temperature detector (21) Is located away from said inlet (31) and said outlet (41) of said evaporator (4). 4. A heat pump system comprising; - a compressor (1), a reversing valve (51), a first heat exchanger (54) having an air suction side and having a conduit in which refrigerant is located, a fan (4a, 54a) for generating a flow of air for the first heat exchanger, an expansion device (3), a second heat exchanger (52), and a leak detector (20, 21, 11) for detecting leakage of refrigerant from said system, - the teak detector comprising a first temperature detector(20) which Is located adjacent to said air suction side of said first heat exchanger for measuring the temperature of air entering said first heat exchanger, characterised in that: the refrigerant is one of (a) HFC-32; and (b) HFC-32 and HFC-125; and in that the teak detector comprises: - a second temperature detector (21) which is located adjacent said conduit for measuring the temperature of refrigerant Inside said conduit; and - a differential temperature detector (11) for calculating the difference between (a) the temperature measured DV the first temperature detector and (b) the temperature measured by the second - temperature detector, to determine whether a refrigerant teak has occurred. 5. The heat pump system as claimed to claim 4, wherein the teak detector comprises: - a running time detector for measuring running time of said heat pump system, wherein the difference between the temperature measured by the first temperature detector(20) and the temperature measured by the second temperature detector (21) and the accumulated running time of said heat pump system are used to determine whether a refrigerant teak has occurred. 6. The heat pump system as claimed in claim 4, wherein: - said first heat exchanger is located adjacent a first location; - said second heat exchanger is located adjacent a second location; - and said first heat exchanger operates as an evaporator when said first location has a lower temperature than said second location. 7. The heat pump system as claimed in claim 4 or 6, wherein said first heat exchanger (54) comprises a first coupler and a second coupler, wherein said first coupler is one of an inlet or outlet, and said second coupler Is another of the inlet or the outlet, wherein said second temperature detector (21) is located between said inlet and said outlet of said heat exchanger. 8. A method of detecting refrigerant leakage In a refrigeration system which comprises a compressor (1), an evaporator (4) having an air suction side and having a conduit in which refrigerant is located, a fan (4a, 54a) for generating a flow of air for said evaporator, an expansion device (3), and a 7. -20- condenser (2) coupled together, wherein said method comprises the steps of: (a) measuring the temperature of air entering said evaporator; characterized in that: - sard refrigerant is one of (a) HFC-32, and (b) HFC-32 and HFC- 125; and said method comprises; (b) measuring the temperature of refrigerant Inside said conduit; (c) calculating the difference between the temperature measured In steps(a) and (b) for determining whether a refrigerant leakage has occurred; (d) measuring an accumulated running time of said refrigeration system; and - using the difference calculated in step (c) and the running time measured in step (d) to determine whether a refrigerant leakage has occurred. 9. A method for detecting refrigerant leakage in a heat pump system which comprises a compressor (1), a reversing valve (51), a first heat exchanger (54) having an air suction side and having a conduit in which refrigerant Is located, a fan (4a, 54a) for generating a flow of air for said evaporator, an expansion device (3), and a second heat exchanger (52) coupled together, wherein said method comprises the steps of: (a) measuring the temperature of air entering the first heat exchanger; - characterized In that: - said refrigerant is one (a) HFC-32, and (b) HFC-32 and HFC-125; and said method comprises: (b) measuring the temperature of refrigerant inside said conduit; and 21 (c) calculating the difference between the temperature measured in steps (a) and (b) for determining whether a refrigerant leakage has occurred, (d) measuring an accumulated running time of said refrigeration system; and - using the difference calculated in step (c) and the running time measured In step (d) to determine whether a refrigerant leakage has occurred 10. The method as claimed In claim 11, wherein the first heat exchanger is operable as an evaporator when the location of said first heat exchanger has a lower temperature than the location of said second heat exchanger. Dated this 7th of August, 1997. This invention relates to a refrigeration system comprising a compressor (I), an evaporator (4) with an air suction side and having conduit in which refrigerant is located , an expansion device (3) and a condenser (2), coupled together; a first temperature detector (20) which is located adjacent to said air suction side of said evaporator (4) for measuring temperature of air entering said evaporator (4); a second temperature detector which is located adjacent said conduit for measuring temperature of refrigerant inside said conduit; and a differential temperature detector (11) for calculating the difference between the temperature measured by the first temperature detector (20) and the temperature measured by the second temperature detector (21) to determine whether refrigerant leak has occurred.

Documents:

01466-cal-1997-abstract.pdf

01466-cal-1997-claims.pdf

01466-cal-1997-correspondence.pdf

01466-cal-1997-description(complete).pdf

01466-cal-1997-drawings.pdf

01466-cal-1997-form-1.pdf

01466-cal-1997-form-2.pdf

01466-cal-1997-form-3.pdf

01466-cal-1997-form-5.pdf

01466-cal-1997-gpa.pdf

01466-cal-1997-priority document(other).pdf

01466-cal-1997-priority document.pdf

1466-cal-1997-granted-abstract.pdf

1466-cal-1997-granted-claims.pdf

1466-cal-1997-granted-correspondence.pdf

1466-cal-1997-granted-description (complete).pdf

1466-cal-1997-granted-drawings.pdf

1466-cal-1997-granted-examination report.pdf

1466-cal-1997-granted-form 1.pdf

1466-cal-1997-granted-form 2.pdf

1466-cal-1997-granted-form 3.pdf

1466-cal-1997-granted-form 5.pdf

1466-cal-1997-granted-gpa.pdf

1466-cal-1997-granted-letter patent.pdf

1466-cal-1997-granted-priority document.pdf

1466-cal-1997-granted-reply to examination report.pdf

1466-cal-1997-granted-specification.pdf