Title of Invention

A METHOD OF PRODUCING A HOT-ROLLED STAINLESS STEEL STRIP

Abstract

(57) Abstract: The invention relates to a method of working a hot-rolled stainless steel strip, particularly an austenitic stainless strip, with the intention of reducing the thickness and enhancing the mpchanical strength of the strip. The method is characterized by cold-rolling the hot-rolled strip with at least a 10% thickness reduction to a thickness which is at least 2% and at most 10% greater than the intended final thickness of the fished product; annealing the thus cold-rolled sit-in at a temperature of between 1,050°C and 1,250°C; and cold-stretching the strip after the annealing process so as to plasticize and permanently elongate the strip and therewith reducing its thickness by 2-10%.

Full Text

stainless steel strip, in particular an austenitic stainless steel strip, for the purpose of reducing thickness, enlacing mechanical strength and providing a good surface finish. DESCRIPTION OF THE BACKGROUND ART Stainless steel strips can be hot-rolled to a final thickness of the order of 3 mm. After surface conditioning the strips, including among other things pickling the strip, the hot-rolled strips can be used without ftirther thickness reduction in certain applications. However, subsequent cold-rolling of the hot-rolled strips is required in many other applications. This subsequent cold-rolling process is intended to achieve one or more or all of the following effects, via to further reduce the thickness of the strips, to enhance the mechanical strength and/or to improve the surfaces of the strips. Before being cold-rolled, the hot-rolled strips are aimealed and pickled, and scrap-ends are welded onto both ends of the strips. The actual cold-rolling process is earned out conventionally in several passes trilogy a cold-rolling mill, therewith enabling the thicbiess to be reduced by up to about 80%, tonally 10-60%, for instance for cold-rolled strips which intended for use as construction materials after having been slit into narrower strips. The scrap-ends must be removed before the strip can finally be coiled. Cold-rolling dramatically increases the mechanical strength of the steel, which is in itself desirable for many applications, and this particulai'ly concerns cold-rolling of austenitic stainless steel,. However, the strips also become practically impossible to work, e.g. to bend, stamp, emboss, etc.; properties which are in many cases necessary in order to enable the strips to be used as construction materials. It is therefore necessary to amyl the strips upon completion of the cold-rolling process, by heating the strips to a temperature above the re-crystallization temperature of the steel, i.e. to a temperature above 1,050°C. This treatment greatly reduces the mechanical strength of the strip, normally to an order of magnitude of 250 MPa yield point. According to current standards, a yield point of 190-220 MPa must be calculated for in construction work. The properties obtained with conventional teclmiques, for instance a relatively low yield point, are desirable properties in the majority of cases, although conventional, techniques are irrational in aspects. However, improvements have been proposed with the intention of rationalizing manufacture. For instance, it is proposed in SE 467 055 (WO 93/19211) to reduce thickness in conjunction with an annealing process by stretching the hot strip. However, a higher mechanical strength is a desirable property in certain applications, such as for constructional applications. The properties of the final cold-rolled strip are not improved in this latter respect when practicing the aforesaid method, and neither is such improvement intended. SUMMARY OF THE INVENTION The object of the invention is to produce stainless steel strips, particularly stainless austenitic steel strips, having a desired thin thickness and a higher mechanical strength than that achieved in the conventional manufacture of cold-rolled stainless steel strips while obtaining an acceptable surface finish at the same time. These and other objects can be achieved by cold-rolling a hot-rolled strip with an at least 10% thickness reduction to a thickness which is at least 2% and at most 10% greater than the intended final thickness of the finished product, by annealing the thus cold-rolled strip at a temperature of between 1,050°C and 1,200°C, and cold-stretching the strip alter said annealing process so as to plasticize and permanently elongate the strip, therewith obtaining a reduction in thickness of 2-10%. The strip which is subjected to cold-rolling in accidence with the invention ma;.' consist of a hot-rolled strip that has not undergone any treatment other than being cooled and coiled after being hot-rolled. Thus, in this case, cold-rolling is performed on a hot-rolled strip on which oxide scale still remains on the surfaces thereof. However, the starting material for the cold-rolling process also may consist of a snip which has been surface-treated by a process teclmique that includes pickling of the hot-rolled strip. In principle, the cold-rolling process can be carried out in several passes a con-esponding number of mutually sequential roll stands, although it will preferably be canoed out in one single pass. The maximum reduction in thickness that can be achieved in one single pass will depend on the steel grade, the initial dimensions of the strip, and the capacity of the rolling mill. It can be said generally that one single pass will result in a maximum thickness reduction of about 30%, normally at maximum 25%. This means that in the majority of cases, the thickness of the hot rolled strip will be reduced by 10 to 60%, preferably by 10 to 40% when practicing the indention, this reduction being dependent on the initial thickness of the strip and the final thickness desired. The strip is annealed at a temperature of between 1,050°C and 1,200°C and then cooled to room temperature before being cold-stretched. strip is cold-stretched in a strip stretching mill which may be of any known kind, for instance the kind used to de-scale the surfaces of hot-rolled strips prior to pickling. The strip is preferably cold-stretched by a combination of high stretches and bending of the strip around rolls. The cold-stretching process is carried out to., a degree such as to penne neatly elongate the strip and therewith obtain a thickness reduction of 2-10%. As a result of the combination of high stretches and bending of the strip around rolls of relatively small diameter, the decrease in width will be minimal and practically negligible. The reduction in strip thickness will therefore coaespondtng essentially to the degree of elongation achieved. The material is plasticized as a result of the cold-stretching process, the yield point increasing in the order of 100 MPa, and still higher in the case of certain steel grades. A characteristic feature of the inventive method is that it takes place continuously, by which is meant the various steps or like In order to make a continuous process possible, the manufacturing line preferably includes, in a known manner, strip magazines, so called loppers, at the beginning and at the end of the manufacturing chain, i.e. prior to cold-roiling id subsequent to cold-stretching of the strip. The inventive method will normally also include pickling of the annealed strip. The strip is preferably pickled prior to being cold-stretched, although it is also conceivable to pickle the strip after the cold-stretching process. The strip is preferably shot-blasted prior to being pickled. Accordingly, the present invention provides a method of producing a hot-rolled stainless steel strip, particularly an austenitic stainless strip, in order to reduce the thickness and enhance the mechanical strength of said strip, characterized by cold-rolling the hot-rolled strip with at least a 10% thickness reduction to a thickness which is at least 2% and at most 10% greater than the intended final thickness of the finished product; annealing the thus cold-rolled strip at a temperature of between 1,050°C and 1,250°C; and cold-stretching the strip after said annealing process so as to plasticize and permanently elongate the strip and therewith reducing its thickness by 2-10%. Further characteristic fealties and aspects of the invention and advantages afforded tolerably, together with the properties of the product produced will be apparent from the following detailed description of the invention and from the following claims. BRIEF DESCRIPTION OF THE DRAWINGS The invention will now be described in more detail with reference to the accompanying drawings, in which Fig. 1 illustrates very schematically the principles of the invention according to a first preferred embodiment; Fig. 2 illustrates in more detail the manufacturing line according to the preened embodiment; Fig. 3 illustrates in larger scale and in more detail a cold-stretching mill used in the inventive method; Fig. 4 is a bar chili illustrating the 0.2 proof stress values achieved before and after cold-stretching; Fig. 5 illustrates achieved ultimate tensile strengths in a corresponding manner; Fig. 6 is a bar chart illustrating the thickness reduction achieved with different degrees of cold-stretching; Fig. 7 illustrates the reduction in width with different degrees of cold-stretching in a coaespondtng manner; and Fig. 8 illustrates highly schematically a modified manufactui-ing line on which the inventive method is applied. DETAILED DESCRIPTION OF THE INVENTION The manufacturing line illustrated very schematically in Fig. 1 comprises a coil loaf (reminder) hot-rolled strip to be uncoiled, uncoiling capstan 1, a cold-rolling mill 2 consisting of one single roll stand 2 of the so-called Z-high . an annealing furnace 3, a cooling box 4. a shot-blasting machine 16, a pickling bath 5, a cold-stretching mill 6 and a recoiled 7 which takes up the finished steel strip. Fig. 2 shows the manufacturing line in more detail, wherein the same reference numerals ha\'e been used for units that find coirespondence in Fig. 1. In addition to the aforesaid units, the manufacturing line also includes a shearing unit 8, a welding machine 9, a strip feeder 10 which feeds hot-rolled strip 11 taken from the rewinder 1 to the shearing unit 8 and the welding machine 9, a hot-rolled strip looper generally referenced 12, a thickness measuring means 13 which measures the thickness of the hot-rolled strip 11 u]~stream of the rolling mill 2, and a thickness measuring means 14 which measures the thickness of the cold-rolled strip 1 IB downstream of the cold-rolling mill 2, the shot-blasting machine 16, a wiping and rinsing box 17 downstream of the pickling bath 5, a pair of guide rollers 18, the cold-stretching mill 6, a looper generally referenced 20 for the storage of cold-rolled and cold-stretched finished strip 1 IF, a front feeder 21, and a drive motor and power transmission means together referenced 22 for operating the recoiled 7. The manufacturing line also includes a large number of guide rollers, direction changing rollers, and an S- comprises two or four rolls. The S- is thus comprised of a two-roll S-mill 25 downstream of the welding machine 9, a two-roll S-mill 26 upstream of the cold-rolling mill 2, a four-roll S-mill 27 between the cold-rolling mill 2 and the annealing furnace 3, a four-roll S-mill 28 upstream of the cold-stretching mill 6, a two-roll S-mill 29 downstream of the cold-stretching mill 6, a strip centre guide 19, the strip magazine 20, and a terminating two-rah S-unit 31 between the looper 20 and the mill is to increase or decrease the tension in the strip and to keep the strip in tension. The hot-rolled strip looper 12 includes direction changing rollers 34, 35, 36 and 37, of which the roller 35 is coupled to a strip tensioning unit in a known manner. ,, Correspondingly, the cold-rolled strip looper 20 includes direction changing rollers 39, 40. 41, 42, 43 and 44, of which the roller 40 is connected to a strip tensioning unit, also in a known manner. The manufacturing line illustrated in Fig. 2 operates in the following manner. It is assumed that manufacture is in the phase illustrated in tile Figure, i.e. that the hot-rolled strip looper 12 and the cold-rolled strip looper 20 contain initial thickness of 3 to 4 mm and is reduced by 10-30% in the cold-rolling mill 2. The roll nip is adjusted in accordance with the results of the thickness measurements so as to obtain a cold-rolled strip 1 IB of desired thickness, corresponding to 2-10% greater than the intended finished dimension after cold-stretching the strip in the terminating part of the manufacturing line. The cold-rolling process imparts a high degree of hardness to the strip 1 IB, and the strip is therefore passed into the annealing furnace 3 after passed the four roller S-mill 27. The strip 11B is heated throughout its thickness in the emailing furnace 3 to a temperature of between 1,050°C and 1,200°C, i.e. to a temperature above the re-crystallization temperature of the austenitic steel, and is maintained at this temperature long enough for the steel to re-crystallize completely. The strip is then cooled in the cooling box 4. When heating the strip in the annealing furnace 3, which in accordance with the present embodiment does not take place in a protecting gas atmosphere (something which would be possible per se), oxides foci on the sides of the strip, partially in the form of oxide scale. The strip is substantially de-scaled in the shot-blasting machine 6, and then pickled in the pickling bath 5 comprised of appropriate pickling chemicals, wherein the pickling process can be effected in a kowari manner. The thus cold-rolled, annealed and pickled strip HE is led through the wiping and rinsing box 17-and thereafter through the cold-stretching mill 16 between the four-roller S-mill 28 and the two-roller S-mill 29 which function to hold the strip in tension and the same from sliding. Fig. 3 illustrates the design of the cold-stretching mill 6. The cold-stretching mill 6 comprises three strip-stretching units 47, 48 and 49, Each stretching unit includes a respec¬tive lower roller 50, 51, 52 joumalled in a stationary base 53, 54, 55, and a respective upper stretching roller 56, 57, 58 joumaled in a respective roller holder 59, 60, 61. The positions of the roller holders in relation to the strip and in relation to the lower stretching rollers 50. 51. 52 can be adjusted by means of jacks 62, 63, 64 respectively. The upper strip-stretching rollers 56, 57, 58 are initially in upper positions (not shown), so that the strip 1 IE, which is held stretched between the S-mills 28 and 29, will extend straight through the cold-stretching mill 6. Starting from this initial position, the upper stretching rollers 56, 57 and 58 are lowered by means of the jacks 62, 63, 64 to the positions shown in Fig. 3, whereby the strip IIE-IIF will foci a winding passway, as shown in Fig. 3, while at the same time being stretched in its cold state to a degree of such high magnitude as to plasticize the strip. According to the illustrated embodiment, the lower stretching rollers 50, 51 and 52 have diameters of 70, 200 and 70 mm respectively, whereas the upper stretching rollers 56, 57 and 58 have diameters of 70, 70 and 200 mm respectively. As a result of the chosen setting of the adjustable upper strip-stretching rollers 56, 57, 58 and by virtue of the chosen diameters of the rollers, that part of the strip which passes trilogy the cold-strctchingmill will be thickness can be obtained by adapting the reduction in strip thickness achieved by cold-rolling the strip in the cold-rolling mill 2 to the thickness reduction obtained by cold-stretching the strip in the cold-stretching mill 6, or vice versa, said strip being coiled onto the recoiler 7 after having passed trilogy the cold-rolled strip looper 20. The drive machinery of the integrated manufacturing line described above consists of the drive machinery 22 coupled to' the strip recoiler 7. When desiring greater reductions than those with a cold-rolling mill that comprises only one roll stand and only one cold-stretching mill, a plurality of roll stands 2A, 2B, etc., can be coupled sequentially in series, as illustrated in Fig. 8. This Figure also illustrates the possibility of placing the pickling bath 5 downstream of lire cold-stretching mill 6. In this case, the cold-stretching mill may also function to de-scale lily strip surfaces, therewith possibly eliminating the need for a shot-blasting machine upstream of the pickling bath. 15 DESCRIPTION OF TESTS CARRIED OUT Three different standardized austenitic stainless steel grades were used in the tests, ASTM 304, 316L and 316 Ti. The mechanical properties of the material were determined prior to and after cold-stretching the material, which had earlier been cold-rolled and then annealed 20 (re-crystallization treated). The mechanical strength properties of the tested 304-material are set forth in Table 1, where e = nominal elongation in % RpO.2 = 0.2% proof stress in the transverse direction, MPa 25 Rm = ultimate tensile strength in the transverse direction, MPa Table 1 Cold-rolled & annealed strip e = 0% Cold-rolled, annealed & cold-stretched strip Test Steel grade Elongation e % RpO.2 Rm RpO.2 Rm 1 ASTM 304 4.0% 283 653 394 696 2 ASTM 304 4.8% 283 614 405 661 -» J ASTM 304 5.0% 273 619 418 674 Table 2 shows measured strip widths and strip thicknesses prior to and after the strip has been cold-stretched, and also shows the percentile reductions in thickness and widths 5 achieved in the cold-stretching process. Table 2 Cold rolled & annealed strip s= 0% Cold rolled, annealed & cold stretched strip Difference Test Elongation s % Width Thickness Width Thickness Width % Thick¬ness % A 3.2% 1036 4.20 1033 4.07 0.29% 3.10% B 3.5% 1275 2.85 1271 2.75 0.31% 3.51% C 4.8% 1269 2.50 1265 2.40 0.32% 4.00% D 4.8% 1294 2.50 1290 2.39 0.31% 4.40% The results shown in Table 1 anil Table 2 dire also illustrated graphically in Figs. 4 and 5 10 and in Figs. 6 and 7. WE CLAIM: 1. A method of producing a hot-rolled stainless steel strip, particularly an austenitic stainless strip in order to reduce the thickness and enhance the mechanical strength of said strip, characterized by cold-rolling the hot-rolled strip with at least a 10% thickness reduction to a thickness which is at least 2% and at most 10% greater than the intended foal thickness of the finished product; annealing the thus cold-rolled strip at a temperature of between Iosco and 1,250 and cold-stretching the strip after said annealing process so as to plasticize and permanently elongate the strip and therewith reducing its thickness by 2-10%. 2. The method as claimed in claim 1, wherein the cold-stretching process is effected by the combination of stretching the strip and bending the strip about rolls as the strip is being stretched. 3. The method as claimed in claim 1, wherein during the stretching step, the strip is pressed against the rolls and curved with a radius of curvature smaller than 200 mm, preferably with a radius of at least 20 mm and at most 150 mm. 4. The method as claimed in any one of claims 1 to 3, wherein said hot-rolled strip is cold rolled prior to said annealing treatment to achieve a thickness reduction of 10 to 60%. 5. The method as claimed in claim 4, wherein said hot-rolled strip is cold rolled prior to said annealing treatment to obtain a thickness reduction of 10 to 30%. 6. The method as claimed in any one of claims 1 to 5, wherein said strip is continuously cold-stretched after said annealing treatment so as to permanently elongate tiie strip and to reduce its thickness by 3 to 5%. 7. A method of producing a hot-rolled stainless steel strip substantially as herein described with reference to the accompanying drawings.

Documents:

642-mas-1996 abstract.pdf

642-mas-1996 claims.pdf

642-mas-1996 correspondence others.pdf

642-mas-1996 correspondence po.pdf

642-mas-1996 description (complete).pdf

642-mas-1996 drawings.pdf

642-mas-1996 form-1.pdf

642-mas-1996 form-26.pdf

642-mas-1996 form-4.pdf

642-mas-1996 form-6.pdf

642-mas-1996 others.pdf

642-mas-1996 petition.pdf